id sid tid token lemma pos hm50tq59w1v 1 1 1h 1h NOUN hm50tq59w1v 1 2 nmr nmr PROPN hm50tq59w1v 1 3 spectra spectra PROPN hm50tq59w1v 1 4 of of ADP hm50tq59w1v 1 5 aldohexopyranosyl aldohexopyranosyl ADJ hm50tq59w1v 1 6 rings ring NOUN hm50tq59w1v 1 7 containing contain VERB hm50tq59w1v 1 8 13c 13c NUM hm50tq59w1v 1 9 - - PUNCT hm50tq59w1v 1 10 enrichment enrichment NOUN hm50tq59w1v 1 11 reveal reveal VERB hm50tq59w1v 1 12 the the DET hm50tq59w1v 1 13 presence presence NOUN hm50tq59w1v 1 14 of of ADP hm50tq59w1v 1 15 long long ADJ hm50tq59w1v 1 16 - - PUNCT hm50tq59w1v 1 17 range range NOUN hm50tq59w1v 1 18 4jc1,h6r 4jc1,h6r SPACE hm50tq59w1v 1 19 / / SYM hm50tq59w1v 1 20 s s NOUN hm50tq59w1v 1 21 and and CCONJ hm50tq59w1v 1 22 4jc3,h6r 4jc3,h6r NUM hm50tq59w1v 1 23 / / SYM hm50tq59w1v 1 24 s s X hm50tq59w1v 1 25 whose whose DET hm50tq59w1v 1 26 magnitudes magnitude NOUN hm50tq59w1v 1 27 depend depend VERB hm50tq59w1v 1 28 mainly mainly ADV hm50tq59w1v 1 29 on on ADP hm50tq59w1v 1 30 the the DET hm50tq59w1v 1 31 o5 o5 PROPN hm50tq59w1v 1 32 - - PUNCT hm50tq59w1v 1 33 c5 c5 PROPN hm50tq59w1v 1 34 - - PUNCT hm50tq59w1v 1 35 c6 c6 PROPN hm50tq59w1v 1 36 - - PUNCT hm50tq59w1v 1 37 o6 o6 PROPN hm50tq59w1v 1 38 torsion torsion NOUN hm50tq59w1v 1 39 angle angle NOUN hm50tq59w1v 1 40 . . PUNCT hm50tq59w1v 2 1 using use VERB hm50tq59w1v 2 2 theoretical theoretical ADJ hm50tq59w1v 2 3 calculations calculation NOUN hm50tq59w1v 2 4 and and CCONJ hm50tq59w1v 2 5 conformationally conformationally ADV hm50tq59w1v 2 6 constrained constrain VERB hm50tq59w1v 2 7 experimental experimental ADJ hm50tq59w1v 2 8 model model NOUN hm50tq59w1v 2 9 compounds compound NOUN hm50tq59w1v 2 10 , , PUNCT hm50tq59w1v 2 11 the the DET hm50tq59w1v 2 12 magnitudes magnitude NOUN hm50tq59w1v 2 13 and and CCONJ hm50tq59w1v 2 14 signs sign NOUN hm50tq59w1v 2 15 of of ADP hm50tq59w1v 2 16 4jc1,h6r 4jc1,h6r SPACE hm50tq59w1v 2 17 / / SYM hm50tq59w1v 2 18 s s NOUN hm50tq59w1v 2 19 and and CCONJ hm50tq59w1v 2 20 4jc3,h6r 4jc3,h6r NUM hm50tq59w1v 2 21 / / SYM hm50tq59w1v 2 22 s s VERB hm50tq59w1v 2 23 have have AUX hm50tq59w1v 2 24 been be AUX hm50tq59w1v 2 25 established establish VERB hm50tq59w1v 2 26 , , PUNCT hm50tq59w1v 2 27 and and CCONJ hm50tq59w1v 2 28 their their PRON hm50tq59w1v 2 29 dependencies dependency NOUN hm50tq59w1v 2 30 on on ADP hm50tq59w1v 2 31 the the DET hm50tq59w1v 2 32 geometry geometry NOUN hm50tq59w1v 2 33 of of ADP hm50tq59w1v 2 34 the the DET hm50tq59w1v 2 35 c1 c1 PROPN hm50tq59w1v 2 36 - - PUNCT hm50tq59w1v 2 37 o5 o5 PROPN hm50tq59w1v 2 38 - - PUNCT hm50tq59w1v 2 39 c5 c5 PROPN hm50tq59w1v 2 40 - - PUNCT hm50tq59w1v 2 41 c6 c6 PROPN hm50tq59w1v 2 42 - - PUNCT hm50tq59w1v 2 43 h6r h6r PROPN hm50tq59w1v 2 44 / / SYM hm50tq59w1v 2 45 s s PROPN hm50tq59w1v 2 46 and and CCONJ hm50tq59w1v 2 47 c3 c3 PROPN hm50tq59w1v 2 48 - - PUNCT hm50tq59w1v 2 49 c4 c4 NOUN hm50tq59w1v 2 50 - - PUNCT hm50tq59w1v 2 51 c5 c5 PROPN hm50tq59w1v 2 52 - - PUNCT hm50tq59w1v 2 53 c6 c6 PROPN hm50tq59w1v 2 54 - - PUNCT hm50tq59w1v 2 55 h6r h6r NOUN hm50tq59w1v 2 56 / / SYM hm50tq59w1v 2 57 s s NOUN hm50tq59w1v 2 58 coupling coupling NOUN hm50tq59w1v 2 59 pathways pathway NOUN hm50tq59w1v 2 60 , , PUNCT hm50tq59w1v 2 61 respectively respectively ADV hm50tq59w1v 2 62 , , PUNCT hm50tq59w1v 2 63 were be AUX hm50tq59w1v 2 64 determined determine VERB hm50tq59w1v 2 65 . . PUNCT hm50tq59w1v 3 1 a a DET hm50tq59w1v 3 2 novel novel ADJ hm50tq59w1v 3 3 method method NOUN hm50tq59w1v 3 4 involving involve VERB hm50tq59w1v 3 5 the the DET hm50tq59w1v 3 6 use use NOUN hm50tq59w1v 3 7 of of ADP hm50tq59w1v 3 8 trans trans ADJ hm50tq59w1v 3 9 - - ADJ hm50tq59w1v 3 10 glycoside glycoside ADJ hm50tq59w1v 3 11 j j NOUN hm50tq59w1v 3 12 - - PUNCT hm50tq59w1v 3 13 coupling coupling NOUN hm50tq59w1v 3 14 constants constant NOUN hm50tq59w1v 3 15 is be AUX hm50tq59w1v 3 16 applied apply VERB hm50tq59w1v 3 17 to to PART hm50tq59w1v 3 18 evaluate evaluate VERB hm50tq59w1v 3 19 the the DET hm50tq59w1v 3 20 conformational conformational ADJ hm50tq59w1v 3 21 properties property NOUN hm50tq59w1v 3 22 of of ADP hm50tq59w1v 3 23 structurally structurally ADV hm50tq59w1v 3 24 - - PUNCT hm50tq59w1v 3 25 related relate VERB hm50tq59w1v 3 26 glycosidic glycosidic ADJ hm50tq59w1v 3 27 linkages linkage NOUN hm50tq59w1v 3 28 in in ADP hm50tq59w1v 3 29 oligosaccharides oligosaccharide NOUN hm50tq59w1v 3 30 . . PUNCT hm50tq59w1v 4 1 by by ADP hm50tq59w1v 4 2 incorporating incorporate VERB hm50tq59w1v 4 3 dual dual ADJ hm50tq59w1v 4 4 13c 13c NOUN hm50tq59w1v 4 5 - - PUNCT hm50tq59w1v 4 6 labeling labeling NOUN hm50tq59w1v 4 7 at at ADP hm50tq59w1v 4 8 the the DET hm50tq59w1v 4 9 carbons carbon NOUN hm50tq59w1v 4 10 participating participate VERB hm50tq59w1v 4 11 directly directly ADV hm50tq59w1v 4 12 in in ADP hm50tq59w1v 4 13 the the DET hm50tq59w1v 4 14 linkage linkage NOUN hm50tq59w1v 4 15 and and CCONJ hm50tq59w1v 4 16 measuring measure VERB hm50tq59w1v 4 17 the the DET hm50tq59w1v 4 18 ensemble ensemble NOUN hm50tq59w1v 4 19 of of ADP hm50tq59w1v 4 20 trans trans ADJ hm50tq59w1v 4 21 - - ADJ hm50tq59w1v 4 22 glycoside glycoside ADJ hm50tq59w1v 4 23 j j NOUN hm50tq59w1v 4 24 - - PUNCT hm50tq59w1v 4 25 couplings coupling NOUN hm50tq59w1v 4 26 across across ADP hm50tq59w1v 4 27 the the DET hm50tq59w1v 4 28 linkage linkage NOUN hm50tq59w1v 4 29 , , PUNCT hm50tq59w1v 4 30 firm firm ADJ hm50tq59w1v 4 31 qualitative qualitative NOUN hm50tq59w1v 4 32 and and CCONJ hm50tq59w1v 4 33 semi semi ADJ hm50tq59w1v 4 34 - - ADJ hm50tq59w1v 4 35 quantitative quantitative ADJ hm50tq59w1v 4 36 information information NOUN hm50tq59w1v 4 37 can can AUX hm50tq59w1v 4 38 be be AUX hm50tq59w1v 4 39 obtained obtain VERB hm50tq59w1v 4 40 rapidly rapidly ADV hm50tq59w1v 4 41 about about ADP hm50tq59w1v 4 42 whether whether SCONJ hm50tq59w1v 4 43 linkage linkage NOUN hm50tq59w1v 4 44 conformations conformation NOUN hm50tq59w1v 4 45 are be AUX hm50tq59w1v 4 46 similar similar ADJ hm50tq59w1v 4 47 or or CCONJ hm50tq59w1v 4 48 different different ADJ hm50tq59w1v 4 49 . . PUNCT hm50tq59w1v 5 1 a a DET hm50tq59w1v 5 2 simplified simplified ADJ hm50tq59w1v 5 3 cyanohydrin cyanohydrin NOUN hm50tq59w1v 5 4 route route NOUN hm50tq59w1v 5 5 was be AUX hm50tq59w1v 5 6 developed develop VERB hm50tq59w1v 5 7 to to PART hm50tq59w1v 5 8 synthesize synthesize VERB hm50tq59w1v 5 9 isotopically isotopically ADV hm50tq59w1v 5 10 labeled label VERB hm50tq59w1v 5 11 2 2 NUM hm50tq59w1v 5 12 - - PUNCT hm50tq59w1v 5 13 amino-2 amino-2 NUM hm50tq59w1v 5 14 - - PUNCT hm50tq59w1v 5 15 deoxy deoxy NOUN hm50tq59w1v 5 16 - - PUNCT hm50tq59w1v 5 17 d d NOUN hm50tq59w1v 5 18 - - NOUN hm50tq59w1v 5 19 aldohexoses aldohexose NOUN hm50tq59w1v 5 20 and and CCONJ hm50tq59w1v 5 21 their their PRON hm50tq59w1v 5 22 methyl methyl NOUN hm50tq59w1v 5 23 glycosides glycoside NOUN hm50tq59w1v 5 24 by by ADP hm50tq59w1v 5 25 yuping yupe VERB hm50tq59w1v 5 26 zhu zhu NOUN hm50tq59w1v 5 27 and and CCONJ hm50tq59w1v 5 28 other other ADJ hm50tq59w1v 5 29 members member NOUN hm50tq59w1v 5 30 of of ADP hm50tq59w1v 5 31 the the DET hm50tq59w1v 5 32 serianni serianni PROPN hm50tq59w1v 5 33 laboratory laboratory PROPN hm50tq59w1v 5 34 . . PUNCT hm50tq59w1v 6 1 the the DET hm50tq59w1v 6 2 hydrolysis hydrolysis NOUN hm50tq59w1v 6 3 of of ADP hm50tq59w1v 6 4 the the DET hm50tq59w1v 6 5 starting starting NOUN hm50tq59w1v 6 6 materials material NOUN hm50tq59w1v 6 7 for for ADP hm50tq59w1v 6 8 this this DET hm50tq59w1v 6 9 synthesis synthesis NOUN hm50tq59w1v 6 10 , , PUNCT hm50tq59w1v 6 11 the the DET hm50tq59w1v 6 12 aldopentopyranosylamines aldopentopyranosylamine NOUN hm50tq59w1v 6 13 , , PUNCT hm50tq59w1v 6 14 was be AUX hm50tq59w1v 6 15 investigated investigate VERB hm50tq59w1v 6 16 by by ADP hm50tq59w1v 6 17 nmr nmr PROPN hm50tq59w1v 6 18 to to PART hm50tq59w1v 6 19 determine determine VERB hm50tq59w1v 6 20 optimal optimal ADJ hm50tq59w1v 6 21 reaction reaction NOUN hm50tq59w1v 6 22 conditions condition NOUN hm50tq59w1v 6 23 for for ADP hm50tq59w1v 6 24 the the DET hm50tq59w1v 6 25 cyanide cyanide NOUN hm50tq59w1v 6 26 addition addition NOUN hm50tq59w1v 6 27 reaction reaction NOUN hm50tq59w1v 6 28 . . PUNCT hm50tq59w1v 7 1 multiple multiple ADJ hm50tq59w1v 7 2 13c 13c NOUN hm50tq59w1v 7 3 isotopomers isotopomer NOUN hm50tq59w1v 7 4 of of ADP hm50tq59w1v 7 5 diand diand NOUN hm50tq59w1v 7 6 trisaccharides trisaccharide NOUN hm50tq59w1v 7 7 containing contain VERB hm50tq59w1v 7 8 n n NOUN hm50tq59w1v 7 9 - - PUNCT hm50tq59w1v 7 10 acetyl acetyl NOUN hm50tq59w1v 7 11 - - PUNCT hm50tq59w1v 7 12 d d NOUN hm50tq59w1v 7 13 - - NOUN hm50tq59w1v 7 14 glucosamine glucosamine NOUN hm50tq59w1v 7 15 ( ( PUNCT hm50tq59w1v 7 16 glcnac glcnac ADJ hm50tq59w1v 7 17 ) ) PUNCT hm50tq59w1v 7 18 and and CCONJ hm50tq59w1v 7 19 d d X hm50tq59w1v 7 20 - - PUNCT hm50tq59w1v 7 21 mannose mannose NOUN hm50tq59w1v 7 22 ( ( PUNCT hm50tq59w1v 7 23 man man NOUN hm50tq59w1v 7 24 ) ) PUNCT hm50tq59w1v 7 25 representing represent VERB hm50tq59w1v 7 26 nested nest VERB hm50tq59w1v 7 27 fragments fragment NOUN hm50tq59w1v 7 28 of of ADP hm50tq59w1v 7 29 biologically biologically ADV hm50tq59w1v 7 30 important important ADJ hm50tq59w1v 7 31 n n NOUN hm50tq59w1v 7 32 - - PUNCT hm50tq59w1v 7 33 glycans glycan NOUN hm50tq59w1v 7 34 were be AUX hm50tq59w1v 7 35 synthesized synthesize VERB hm50tq59w1v 7 36 . . PUNCT hm50tq59w1v 8 1 nmr nmr PROPN hm50tq59w1v 8 2 studies study NOUN hm50tq59w1v 8 3 yielded yield VERB hm50tq59w1v 8 4 trans trans NOUN hm50tq59w1v 8 5 - - NOUN hm50tq59w1v 8 6 glycoside glycoside NOUN hm50tq59w1v 8 7 jcc jcc PROPN hm50tq59w1v 8 8 and and CCONJ hm50tq59w1v 8 9 jch jch PROPN hm50tq59w1v 8 10 within within ADP hm50tq59w1v 8 11 related related ADJ hm50tq59w1v 8 12 structures structure NOUN hm50tq59w1v 8 13 , , PUNCT hm50tq59w1v 8 14 providing provide VERB hm50tq59w1v 8 15 new new ADJ hm50tq59w1v 8 16 information information NOUN hm50tq59w1v 8 17 on on ADP hm50tq59w1v 8 18 conformational conformational ADJ hm50tq59w1v 8 19 information information NOUN hm50tq59w1v 8 20 of of ADP hm50tq59w1v 8 21 constituent constituent NOUN hm50tq59w1v 8 22 linkages linkage NOUN hm50tq59w1v 8 23 and and CCONJ hm50tq59w1v 8 24 the the DET hm50tq59w1v 8 25 effect effect NOUN hm50tq59w1v 8 26 of of ADP hm50tq59w1v 8 27 molecular molecular ADJ hm50tq59w1v 8 28 context context NOUN hm50tq59w1v 8 29 in in ADP hm50tq59w1v 8 30 dictating dictate VERB hm50tq59w1v 8 31 preferred preferred ADJ hm50tq59w1v 8 32 linkage linkage NOUN hm50tq59w1v 8 33 conformation conformation NOUN hm50tq59w1v 8 34 in in ADP hm50tq59w1v 8 35 solution solution NOUN hm50tq59w1v 8 36 . . PUNCT hm50tq59w1v 9 1 conformations conformation NOUN hm50tq59w1v 9 2 of of ADP hm50tq59w1v 9 3 four four NUM hm50tq59w1v 9 4 glycosidic glycosidic ADJ hm50tq59w1v 9 5 linkages linkage NOUN hm50tq59w1v 9 6 in in ADP hm50tq59w1v 9 7 the the DET hm50tq59w1v 9 8 pentasaccharide pentasaccharide NOUN hm50tq59w1v 9 9 core core NOUN hm50tq59w1v 9 10 were be AUX hm50tq59w1v 9 11 determined determine VERB hm50tq59w1v 9 12 by by ADP hm50tq59w1v 9 13 semi semi ADJ hm50tq59w1v 9 14 - - ADJ hm50tq59w1v 9 15 quantitative quantitative ADJ hm50tq59w1v 9 16 fitting fitting NOUN hm50tq59w1v 9 17 of of ADP hm50tq59w1v 9 18 the the DET hm50tq59w1v 9 19 coupling coupling NOUN hm50tq59w1v 9 20 constants constant NOUN hm50tq59w1v 9 21 to to ADP hm50tq59w1v 9 22 karplus karplus ADJ hm50tq59w1v 9 23 equations equation NOUN hm50tq59w1v 9 24 , , PUNCT hm50tq59w1v 9 25 followed follow VERB hm50tq59w1v 9 26 by by ADP hm50tq59w1v 9 27 filtering filter VERB hm50tq59w1v 9 28 with with ADP hm50tq59w1v 9 29 noe noe PROPN hm50tq59w1v 9 30 data data PROPN hm50tq59w1v 9 31 . . PUNCT hm50tq59w1v 10 1 the the DET hm50tq59w1v 10 2 effect effect NOUN hm50tq59w1v 10 3 of of ADP hm50tq59w1v 10 4 structural structural ADJ hm50tq59w1v 10 5 context context NOUN hm50tq59w1v 10 6 was be AUX hm50tq59w1v 10 7 examined examine VERB hm50tq59w1v 10 8 by by ADP hm50tq59w1v 10 9 comparing compare VERB hm50tq59w1v 10 10 the the DET hm50tq59w1v 10 11 corresponding correspond VERB hm50tq59w1v 10 12 trans trans NOUN hm50tq59w1v 10 13 - - NOUN hm50tq59w1v 10 14 glycoside glycoside ADJ hm50tq59w1v 10 15 j j NOUN hm50tq59w1v 10 16 - - PUNCT hm50tq59w1v 10 17 couplings coupling NOUN hm50tq59w1v 10 18 observed observe VERB hm50tq59w1v 10 19 in in ADP hm50tq59w1v 10 20 the the DET hm50tq59w1v 10 21 trisaccharide trisaccharide NOUN hm50tq59w1v 10 22 ( ( PUNCT hm50tq59w1v 10 23 triman triman NOUN hm50tq59w1v 10 24 ) ) PUNCT hm50tq59w1v 10 25 unit unit NOUN hm50tq59w1v 10 26 to to ADP hm50tq59w1v 10 27 those those PRON hm50tq59w1v 10 28 in in ADP hm50tq59w1v 10 29 the the DET hm50tq59w1v 10 30 individual individual ADJ hm50tq59w1v 10 31 disaccharide disaccharide NOUN hm50tq59w1v 10 32 components.two components.two NUM hm50tq59w1v 10 33 disaccharide disaccharide NOUN hm50tq59w1v 10 34 crystals crystal NOUN hm50tq59w1v 10 35 were be AUX hm50tq59w1v 10 36 studied study VERB hm50tq59w1v 10 37 by by ADP hm50tq59w1v 10 38 x x NOUN hm50tq59w1v 10 39 - - NOUN hm50tq59w1v 10 40 ray ray NOUN hm50tq59w1v 10 41 crystallography crystallography NOUN hm50tq59w1v 10 42 . . PUNCT hm50tq59w1v 11 1 methyl methyl NOUN hm50tq59w1v 11 2 alpha alpha NOUN hm50tq59w1v 11 3 - - PUNCT hm50tq59w1v 11 4 lactoside lactoside NOUN hm50tq59w1v 11 5 , , PUNCT hm50tq59w1v 11 6 c13h24o11 c13h24o11 PROPN hm50tq59w1v 11 7 , , PUNCT hm50tq59w1v 11 8 has have VERB hm50tq59w1v 11 9 glycosidic glycosidic ADJ hm50tq59w1v 11 10 torsion torsion NOUN hm50tq59w1v 11 11 angles angle VERB hm50tq59w1v 11 12 phi phi NOUN hm50tq59w1v 11 13 ( ( PUNCT hm50tq59w1v 11 14 o5gal o5gal PROPN hm50tq59w1v 11 15 - - PUNCT hm50tq59w1v 11 16 c1gal c1gal SPACE hm50tq59w1v 11 17 - - PUNCT hm50tq59w1v 11 18 o1gal o1gal ADJ hm50tq59w1v 11 19 - - PUNCT hm50tq59w1v 11 20 c4glc c4glc NOUN hm50tq59w1v 11 21 ) ) PUNCT hm50tq59w1v 11 22 and and CCONJ hm50tq59w1v 11 23 psi psi PROPN hm50tq59w1v 11 24 ( ( PUNCT hm50tq59w1v 11 25 c1gal c1gal ADJ hm50tq59w1v 11 26 - - PUNCT hm50tq59w1v 11 27 o1gal o1gal ADJ hm50tq59w1v 11 28 - - PUNCT hm50tq59w1v 11 29 c4glc c4glc PROPN hm50tq59w1v 11 30 - - PUNCT hm50tq59w1v 11 31 c5glc c5glc NOUN hm50tq59w1v 11 32 ) ) PUNCT hm50tq59w1v 11 33 of of ADP hm50tq59w1v 11 34 -93.52 -93.52 PROPN hm50tq59w1v 11 35 ( ( PUNCT hm50tq59w1v 11 36 13 13 NUM hm50tq59w1v 11 37 ) ) PUNCT hm50tq59w1v 12 1 -144.83 -144.83 PROPN hm50tq59w1v 12 2 ( ( PUNCT hm50tq59w1v 12 3 11)åá 11)åá NUM hm50tq59w1v 12 4 , , PUNCT hm50tq59w1v 12 5 respectively respectively ADV hm50tq59w1v 12 6 . . PUNCT hm50tq59w1v 13 1 methyl methyl PROPN hm50tq59w1v 13 2 beta beta PROPN hm50tq59w1v 13 3 - - PUNCT hm50tq59w1v 13 4 l l NOUN hm50tq59w1v 13 5 - - PUNCT hm50tq59w1v 13 6 lactoside lactoside NOUN hm50tq59w1v 13 7 , , PUNCT hm50tq59w1v 13 8 c13h24o11 c13h24o11 PROPN hm50tq59w1v 13 9 , , PUNCT hm50tq59w1v 13 10 has have VERB hm50tq59w1v 13 11 glycosidic glycosidic ADJ hm50tq59w1v 13 12 torsion torsion NOUN hm50tq59w1v 13 13 angles angle VERB hm50tq59w1v 13 14 phi phi NOUN hm50tq59w1v 13 15 and and CCONJ hm50tq59w1v 13 16 psi psi NOUN hm50tq59w1v 13 17 of of ADP hm50tq59w1v 13 18 93.89 93.89 NUM hm50tq59w1v 13 19 ( ( PUNCT hm50tq59w1v 13 20 13 13 NUM hm50tq59w1v 13 21 ) ) PUNCT hm50tq59w1v 13 22 and and CCONJ hm50tq59w1v 13 23 -127.43 -127.43 PROPN hm50tq59w1v 13 24 ( ( PUNCT hm50tq59w1v 13 25 13)å 13)å NUM hm50tq59w1v 13 26 _ _ NOUN hm50tq59w1v 13 27 , , PUNCT hm50tq59w1v 13 28 respectively respectively ADV hm50tq59w1v 13 29 . . PUNCT