id sid tid token lemma pos hd76rx93d31 1 1 structural structural ADJ hd76rx93d31 1 2 modulation modulation NOUN hd76rx93d31 1 3 of of ADP hd76rx93d31 1 4 metal metal NOUN hd76rx93d31 1 5 - - PUNCT hd76rx93d31 1 6 organic organic ADJ hd76rx93d31 1 7 frameworks framework NOUN hd76rx93d31 1 8 ( ( PUNCT hd76rx93d31 1 9 mofs mof NOUN hd76rx93d31 1 10 ) ) PUNCT hd76rx93d31 1 11 is be AUX hd76rx93d31 1 12 of of ADP hd76rx93d31 1 13 importance importance NOUN hd76rx93d31 1 14 because because SCONJ hd76rx93d31 1 15 it it PRON hd76rx93d31 1 16 can can AUX hd76rx93d31 1 17 be be AUX hd76rx93d31 1 18 used use VERB hd76rx93d31 1 19 to to PART hd76rx93d31 1 20 enhance enhance VERB hd76rx93d31 1 21 the the DET hd76rx93d31 1 22 gas gas NOUN hd76rx93d31 1 23 adsorption adsorption NOUN hd76rx93d31 1 24 abilities ability NOUN hd76rx93d31 1 25 and and CCONJ hd76rx93d31 1 26 heterogeneous heterogeneous ADJ hd76rx93d31 1 27 catalytic catalytic ADJ hd76rx93d31 1 28 performance performance NOUN hd76rx93d31 1 29 of of ADP hd76rx93d31 1 30 mofs mof NOUN hd76rx93d31 1 31 and and CCONJ hd76rx93d31 1 32 their their PRON hd76rx93d31 1 33 pyrolyzed pyrolyzed ADJ hd76rx93d31 1 34 analogues analogue NOUN hd76rx93d31 1 35 . . PUNCT hd76rx93d31 2 1 therefore therefore ADV hd76rx93d31 2 2 , , PUNCT hd76rx93d31 2 3 the the DET hd76rx93d31 2 4 ultimate ultimate ADJ hd76rx93d31 2 5 goal goal NOUN hd76rx93d31 2 6 achieved achieve VERB hd76rx93d31 2 7 in in ADP hd76rx93d31 2 8 this this DET hd76rx93d31 2 9 dissertation dissertation NOUN hd76rx93d31 2 10 is be AUX hd76rx93d31 2 11 to to ADP hd76rx93d31 2 12 1 1 NUM hd76rx93d31 2 13 ) ) PUNCT hd76rx93d31 2 14 synthesize synthesize VERB hd76rx93d31 2 15 novel novel NOUN hd76rx93d31 2 16 mofs mof NOUN hd76rx93d31 2 17 and and CCONJ hd76rx93d31 2 18 2 2 X hd76rx93d31 2 19 ) ) PUNCT hd76rx93d31 2 20 tailor tailor NOUN hd76rx93d31 2 21 / / SYM hd76rx93d31 2 22 modify modify VERB hd76rx93d31 2 23 the the DET hd76rx93d31 2 24 structure structure NOUN hd76rx93d31 2 25 of of ADP hd76rx93d31 2 26 the the DET hd76rx93d31 2 27 mofs mof NOUN hd76rx93d31 2 28 prior prior ADV hd76rx93d31 2 29 to to ADP hd76rx93d31 2 30 pyrolysis pyrolysis NOUN hd76rx93d31 2 31 , , PUNCT hd76rx93d31 2 32 thereby thereby ADV hd76rx93d31 2 33 directing direct VERB hd76rx93d31 2 34 / / SYM hd76rx93d31 2 35 controlling control VERB hd76rx93d31 2 36 the the DET hd76rx93d31 2 37 properties property NOUN hd76rx93d31 2 38 of of ADP hd76rx93d31 2 39 the the DET hd76rx93d31 2 40 resulting result VERB hd76rx93d31 2 41 functional functional ADJ hd76rx93d31 2 42 carbons carbon NOUN hd76rx93d31 2 43 . . PUNCT hd76rx93d31 3 1 zn zn X hd76rx93d31 3 2 - - PUNCT hd76rx93d31 3 3 based base VERB hd76rx93d31 3 4 mofs mof NOUN hd76rx93d31 3 5 ( ( PUNCT hd76rx93d31 3 6 zn zn NOUN hd76rx93d31 3 7 - - PUNCT hd76rx93d31 3 8 mofs mof NOUN hd76rx93d31 3 9 ) ) PUNCT hd76rx93d31 3 10 with with ADP hd76rx93d31 3 11 free free ADJ hd76rx93d31 3 12 pyridine pyridine NOUN hd76rx93d31 3 13 functionalities functionality NOUN hd76rx93d31 3 14 are be AUX hd76rx93d31 3 15 promising promise VERB hd76rx93d31 3 16 materials material NOUN hd76rx93d31 3 17 but but CCONJ hd76rx93d31 3 18 the the DET hd76rx93d31 3 19 synthesis synthesis NOUN hd76rx93d31 3 20 of of ADP hd76rx93d31 3 21 these these DET hd76rx93d31 3 22 mofs mof NOUN hd76rx93d31 3 23 is be AUX hd76rx93d31 3 24 difficult difficult ADJ hd76rx93d31 3 25 due due ADP hd76rx93d31 3 26 to to ADP hd76rx93d31 3 27 the the DET hd76rx93d31 3 28 tendency tendency NOUN hd76rx93d31 3 29 of of ADP hd76rx93d31 3 30 the the DET hd76rx93d31 3 31 pyridine pyridine NOUN hd76rx93d31 3 32 n n CCONJ hd76rx93d31 3 33 to to PART hd76rx93d31 3 34 coordinate coordinate VERB hd76rx93d31 3 35 with with ADP hd76rx93d31 3 36 the the DET hd76rx93d31 3 37 zn zn PROPN hd76rx93d31 3 38 centers center NOUN hd76rx93d31 3 39 . . PUNCT hd76rx93d31 4 1 this this DET hd76rx93d31 4 2 dissertation dissertation NOUN hd76rx93d31 4 3 documents document VERB hd76rx93d31 4 4 synthetic synthetic ADJ hd76rx93d31 4 5 efforts effort NOUN hd76rx93d31 4 6 for for ADP hd76rx93d31 4 7 the the DET hd76rx93d31 4 8 generation generation NOUN hd76rx93d31 4 9 of of ADP hd76rx93d31 4 10 free free ADJ hd76rx93d31 4 11 pyridine pyridine NOUN hd76rx93d31 4 12 - - PUNCT hd76rx93d31 4 13 incorporating incorporate VERB hd76rx93d31 4 14 zn zn NOUN hd76rx93d31 4 15 - - NOUN hd76rx93d31 4 16 mofs mof NOUN hd76rx93d31 4 17 and and CCONJ hd76rx93d31 4 18 their their PRON hd76rx93d31 4 19 characterizations characterization NOUN hd76rx93d31 4 20 . . PUNCT hd76rx93d31 5 1 in in ADP hd76rx93d31 5 2 addition addition NOUN hd76rx93d31 5 3 to to ADP hd76rx93d31 5 4 the the DET hd76rx93d31 5 5 syntheses synthesis NOUN hd76rx93d31 5 6 of of ADP hd76rx93d31 5 7 novel novel NOUN hd76rx93d31 5 8 zn zn NOUN hd76rx93d31 5 9 - - NOUN hd76rx93d31 5 10 mofs mof NOUN hd76rx93d31 5 11 , , PUNCT hd76rx93d31 5 12 the the DET hd76rx93d31 5 13 incorporation incorporation NOUN hd76rx93d31 5 14 of of ADP hd76rx93d31 5 15 pyridines pyridine NOUN hd76rx93d31 5 16 in in ADP hd76rx93d31 5 17 these these DET hd76rx93d31 5 18 zn zn NOUN hd76rx93d31 5 19 - - PUNCT hd76rx93d31 5 20 mofs mof NOUN hd76rx93d31 5 21 motivates motivate VERB hd76rx93d31 5 22 their their PRON hd76rx93d31 5 23 use use NOUN hd76rx93d31 5 24 as as ADP hd76rx93d31 5 25 templates template NOUN hd76rx93d31 5 26 pyrolyzed pyrolyze VERB hd76rx93d31 5 27 to to PART hd76rx93d31 5 28 produce produce VERB hd76rx93d31 5 29 n n ADJ hd76rx93d31 5 30 - - PUNCT hd76rx93d31 5 31 doped dope VERB hd76rx93d31 5 32 carbons carbon NOUN hd76rx93d31 5 33 . . PUNCT hd76rx93d31 6 1 this this DET hd76rx93d31 6 2 dissertation dissertation NOUN hd76rx93d31 6 3 , , PUNCT hd76rx93d31 6 4 hence hence ADV hd76rx93d31 6 5 , , PUNCT hd76rx93d31 6 6 covers cover VERB hd76rx93d31 6 7 the the DET hd76rx93d31 6 8 generation generation NOUN hd76rx93d31 6 9 of of ADP hd76rx93d31 6 10 n n ADJ hd76rx93d31 6 11 - - PUNCT hd76rx93d31 6 12 doped dope VERB hd76rx93d31 6 13 carbons carbon NOUN hd76rx93d31 6 14 derived derive VERB hd76rx93d31 6 15 from from ADP hd76rx93d31 6 16 these these DET hd76rx93d31 6 17 zn zn ADJ hd76rx93d31 6 18 - - ADJ hd76rx93d31 6 19 mof mof VERB hd76rx93d31 6 20 templates template NOUN hd76rx93d31 6 21 . . PUNCT hd76rx93d31 7 1 furthermore furthermore ADV hd76rx93d31 7 2 , , PUNCT hd76rx93d31 7 3 the the DET hd76rx93d31 7 4 structures structure NOUN hd76rx93d31 7 5 of of ADP hd76rx93d31 7 6 these these DET hd76rx93d31 7 7 zn zn NOUN hd76rx93d31 7 8 - - PUNCT hd76rx93d31 7 9 mofs mof NOUN hd76rx93d31 7 10 were be AUX hd76rx93d31 7 11 modulated modulate VERB hd76rx93d31 7 12 to to PART hd76rx93d31 7 13 enhance enhance VERB hd76rx93d31 7 14 the the DET hd76rx93d31 7 15 co2 co2 ADJ hd76rx93d31 7 16 uptake uptake NOUN hd76rx93d31 7 17 in in ADP hd76rx93d31 7 18 the the DET hd76rx93d31 7 19 pyrolyzed pyrolyzed ADJ hd76rx93d31 7 20 zn zn ADJ hd76rx93d31 7 21 - - ADJ hd76rx93d31 7 22 mof mof ADJ hd76rx93d31 7 23 analogues analogue NOUN hd76rx93d31 7 24 . . PUNCT hd76rx93d31 8 1 additionally additionally ADV hd76rx93d31 8 2 , , PUNCT hd76rx93d31 8 3 the the DET hd76rx93d31 8 4 pyrolysis pyrolysis NOUN hd76rx93d31 8 5 of of ADP hd76rx93d31 8 6 desired desire VERB hd76rx93d31 8 7 metal metal NOUN hd76rx93d31 8 8 - - PUNCT hd76rx93d31 8 9 incorporating incorporate VERB hd76rx93d31 8 10 mof mof VERB hd76rx93d31 8 11 templates template NOUN hd76rx93d31 8 12 to to PART hd76rx93d31 8 13 produce produce VERB hd76rx93d31 8 14 metal metal NOUN hd76rx93d31 8 15 - - PUNCT hd76rx93d31 8 16 supported support VERB hd76rx93d31 8 17 on on ADP hd76rx93d31 8 18 carbons carbon NOUN hd76rx93d31 8 19 was be AUX hd76rx93d31 8 20 studied study VERB hd76rx93d31 8 21 . . PUNCT hd76rx93d31 9 1 specifically specifically ADV hd76rx93d31 9 2 , , PUNCT hd76rx93d31 9 3 structural structural ADJ hd76rx93d31 9 4 tuning tuning NOUN hd76rx93d31 9 5 of of ADP hd76rx93d31 9 6 these these DET hd76rx93d31 9 7 mofs mof NOUN hd76rx93d31 9 8 can can AUX hd76rx93d31 9 9 be be AUX hd76rx93d31 9 10 accomplished accomplish VERB hd76rx93d31 9 11 through through ADP hd76rx93d31 9 12 post post ADJ hd76rx93d31 9 13 - - ADJ hd76rx93d31 9 14 synthetic synthetic ADJ hd76rx93d31 9 15 modification modification NOUN hd76rx93d31 9 16 ( ( PUNCT hd76rx93d31 9 17 psm psm ADJ hd76rx93d31 9 18 ) ) PUNCT hd76rx93d31 9 19 . . PUNCT hd76rx93d31 10 1 psm psm ADJ hd76rx93d31 10 2 has have AUX hd76rx93d31 10 3 been be AUX hd76rx93d31 10 4 validated validate VERB hd76rx93d31 10 5 as as ADP hd76rx93d31 10 6 an an DET hd76rx93d31 10 7 excellent excellent ADJ hd76rx93d31 10 8 synthetic synthetic ADJ hd76rx93d31 10 9 route route NOUN hd76rx93d31 10 10 for for ADP hd76rx93d31 10 11 site site NOUN hd76rx93d31 10 12 - - PUNCT hd76rx93d31 10 13 isolating isolate VERB hd76rx93d31 10 14 target target NOUN hd76rx93d31 10 15 metal metal NOUN hd76rx93d31 10 16 species specie NOUN hd76rx93d31 10 17 into into ADP hd76rx93d31 10 18 the the DET hd76rx93d31 10 19 mofs mof NOUN hd76rx93d31 10 20 ' ' PART hd76rx93d31 10 21 structures structure NOUN hd76rx93d31 10 22 via via ADP hd76rx93d31 10 23 coordination coordination NOUN hd76rx93d31 10 24 . . PUNCT hd76rx93d31 11 1 ultimately ultimately ADV hd76rx93d31 11 2 , , PUNCT hd76rx93d31 11 3 these these DET hd76rx93d31 11 4 metal metal NOUN hd76rx93d31 11 5 - - PUNCT hd76rx93d31 11 6 modified modify VERB hd76rx93d31 11 7 irmof-3 irmof-3 NOUN hd76rx93d31 11 8 templates template NOUN hd76rx93d31 11 9 were be AUX hd76rx93d31 11 10 synthesized synthesize VERB hd76rx93d31 11 11 and and CCONJ hd76rx93d31 11 12 pyrolyzed pyrolyze VERB hd76rx93d31 11 13 to to PART hd76rx93d31 11 14 produce produce VERB hd76rx93d31 11 15 novel novel ADJ hd76rx93d31 11 16 carbon carbon NOUN hd76rx93d31 11 17 catalysts catalyst NOUN hd76rx93d31 11 18 . . PUNCT hd76rx93d31 12 1 four four NUM hd76rx93d31 12 2 transition transition NOUN hd76rx93d31 12 3 metals metal NOUN hd76rx93d31 12 4 ( ( PUNCT hd76rx93d31 12 5 i.e. i.e. X hd76rx93d31 12 6 , , PUNCT hd76rx93d31 12 7 ru ru PROPN hd76rx93d31 12 8 , , PUNCT hd76rx93d31 12 9 w w PROPN hd76rx93d31 12 10 , , PUNCT hd76rx93d31 12 11 v v NOUN hd76rx93d31 12 12 , , PUNCT hd76rx93d31 12 13 and and CCONJ hd76rx93d31 12 14 ti ti PROPN hd76rx93d31 12 15 ) ) PUNCT hd76rx93d31 12 16 are be AUX hd76rx93d31 12 17 used use VERB hd76rx93d31 12 18 in in ADP hd76rx93d31 12 19 this this DET hd76rx93d31 12 20 study study NOUN hd76rx93d31 12 21 since since SCONJ hd76rx93d31 12 22 these these DET hd76rx93d31 12 23 metals metal NOUN hd76rx93d31 12 24 are be AUX hd76rx93d31 12 25 reported report VERB hd76rx93d31 12 26 as as ADP hd76rx93d31 12 27 active active ADJ hd76rx93d31 12 28 sites site NOUN hd76rx93d31 12 29 for for ADP hd76rx93d31 12 30 converting convert VERB hd76rx93d31 12 31 biomass biomass NOUN hd76rx93d31 12 32 derivatives derivative NOUN hd76rx93d31 12 33 . . PUNCT hd76rx93d31 13 1 the the DET hd76rx93d31 13 2 modified modify VERB hd76rx93d31 13 3 irmof-3 irmof-3 NOUN hd76rx93d31 13 4 intermediates intermediate NOUN hd76rx93d31 13 5 and and CCONJ hd76rx93d31 13 6 their their PRON hd76rx93d31 13 7 pyrolyzed pyrolyzed ADJ hd76rx93d31 13 8 counterparts counterpart NOUN hd76rx93d31 13 9 were be AUX hd76rx93d31 13 10 characterized characterize VERB hd76rx93d31 13 11 and and CCONJ hd76rx93d31 13 12 used use VERB hd76rx93d31 13 13 as as ADP hd76rx93d31 13 14 catalysts catalyst NOUN hd76rx93d31 13 15 for for ADP hd76rx93d31 13 16 catalytic catalytic ADJ hd76rx93d31 13 17 transformation transformation NOUN hd76rx93d31 13 18 of of ADP hd76rx93d31 13 19 biomass biomass NOUN hd76rx93d31 13 20 derivatives derivative NOUN hd76rx93d31 13 21 . . PUNCT hd76rx93d31 14 1 furthermore furthermore ADV hd76rx93d31 14 2 , , PUNCT hd76rx93d31 14 3 the the DET hd76rx93d31 14 4 ti ti NOUN hd76rx93d31 14 5 - - PUNCT hd76rx93d31 14 6 supported support VERB hd76rx93d31 14 7 carbon carbon NOUN hd76rx93d31 14 8 was be AUX hd76rx93d31 14 9 also also ADV hd76rx93d31 14 10 employed employ VERB hd76rx93d31 14 11 as as ADP hd76rx93d31 14 12 a a DET hd76rx93d31 14 13 catalyst catalyst NOUN hd76rx93d31 14 14 in in ADP hd76rx93d31 14 15 the the DET hd76rx93d31 14 16 oxidation oxidation NOUN hd76rx93d31 14 17 of of ADP hd76rx93d31 14 18 dibenzothiophene dibenzothiophene PROPN hd76rx93d31 14 19 . . PUNCT hd76rx93d31 15 1 in in ADP hd76rx93d31 15 2 addition addition NOUN hd76rx93d31 15 3 , , PUNCT hd76rx93d31 15 4 the the DET hd76rx93d31 15 5 pyrolysis pyrolysis NOUN hd76rx93d31 15 6 of of ADP hd76rx93d31 15 7 active active ADJ hd76rx93d31 15 8 v v PROPN hd76rx93d31 15 9 species species NOUN hd76rx93d31 15 10 - - PUNCT hd76rx93d31 15 11 incorporating incorporate VERB hd76rx93d31 15 12 mil-47 mil-47 PROPN hd76rx93d31 15 13 ( ( PUNCT hd76rx93d31 15 14 v v NOUN hd76rx93d31 15 15 ) ) PUNCT hd76rx93d31 15 16 template template NOUN hd76rx93d31 15 17 is be AUX hd76rx93d31 15 18 envisioned envision VERB hd76rx93d31 15 19 to to PART hd76rx93d31 15 20 produce produce VERB hd76rx93d31 15 21 carbon carbon NOUN hd76rx93d31 15 22 - - PUNCT hd76rx93d31 15 23 supported support VERB hd76rx93d31 15 24 v v NOUN hd76rx93d31 15 25 catalysts catalyst NOUN hd76rx93d31 15 26 . . PUNCT hd76rx93d31 16 1 this this PRON hd76rx93d31 16 2 was be AUX hd76rx93d31 16 3 motivated motivate VERB hd76rx93d31 16 4 by by ADP hd76rx93d31 16 5 our our PRON hd76rx93d31 16 6 previous previous ADJ hd76rx93d31 16 7 studies study NOUN hd76rx93d31 16 8 about about ADP hd76rx93d31 16 9 the the DET hd76rx93d31 16 10 use use NOUN hd76rx93d31 16 11 of of ADP hd76rx93d31 16 12 pyrolyzed pyrolyzed ADJ hd76rx93d31 16 13 mil-125 mil-125 PROPN hd76rx93d31 16 14 ( ( PUNCT hd76rx93d31 16 15 ti ti NOUN hd76rx93d31 16 16 ) ) PUNCT hd76rx93d31 16 17 analogues analogue NOUN hd76rx93d31 16 18 as as ADP hd76rx93d31 16 19 catalysts catalyst NOUN hd76rx93d31 16 20 for for ADP hd76rx93d31 16 21 oxidizing oxidize VERB hd76rx93d31 16 22 dibenzothiophene dibenzothiophene NOUN hd76rx93d31 16 23 . . PUNCT hd76rx93d31 17 1 specifically specifically ADV hd76rx93d31 17 2 , , PUNCT hd76rx93d31 17 3 mil-47 mil-47 PROPN hd76rx93d31 17 4 ( ( PUNCT hd76rx93d31 17 5 v v NOUN hd76rx93d31 17 6 ) ) PUNCT hd76rx93d31 17 7 was be AUX hd76rx93d31 17 8 pyrolyzed pyrolyze VERB hd76rx93d31 17 9 at at ADP hd76rx93d31 17 10 different different ADJ hd76rx93d31 17 11 pyrolysis pyrolysis NOUN hd76rx93d31 17 12 temperatures temperature NOUN hd76rx93d31 17 13 and and CCONJ hd76rx93d31 17 14 the the DET hd76rx93d31 17 15 resulting result VERB hd76rx93d31 17 16 v v NOUN hd76rx93d31 17 17 catalysts catalyst NOUN hd76rx93d31 17 18 were be AUX hd76rx93d31 17 19 tested test VERB hd76rx93d31 17 20 in in ADP hd76rx93d31 17 21 this this DET hd76rx93d31 17 22 reaction reaction NOUN hd76rx93d31 17 23 . . PUNCT