id sid tid token lemma pos gh93gx44p04 1 1 for for ADP gh93gx44p04 1 2 decades decade NOUN gh93gx44p04 1 3 , , PUNCT gh93gx44p04 1 4 cycloaddition cycloaddition NOUN gh93gx44p04 1 5 reactions reaction NOUN gh93gx44p04 1 6 have have AUX gh93gx44p04 1 7 been be AUX gh93gx44p04 1 8 a a DET gh93gx44p04 1 9 staple staple NOUN gh93gx44p04 1 10 in in ADP gh93gx44p04 1 11 the the DET gh93gx44p04 1 12 organic organic ADJ gh93gx44p04 1 13 chemist chemist NOUN gh93gx44p04 1 14 's 's PART gh93gx44p04 1 15 toolbox toolbox NOUN gh93gx44p04 1 16 , , PUNCT gh93gx44p04 1 17 providing provide VERB gh93gx44p04 1 18 access access NOUN gh93gx44p04 1 19 to to ADP gh93gx44p04 1 20 a a DET gh93gx44p04 1 21 variety variety NOUN gh93gx44p04 1 22 of of ADP gh93gx44p04 1 23 biologically biologically ADV gh93gx44p04 1 24 interesting interesting ADJ gh93gx44p04 1 25 heterocyclic heterocyclic NOUN gh93gx44p04 1 26 compounds compound NOUN gh93gx44p04 1 27 . . PUNCT gh93gx44p04 2 1 in in ADP gh93gx44p04 2 2 particular particular ADJ gh93gx44p04 2 3 , , PUNCT gh93gx44p04 2 4 [ [ X gh93gx44p04 2 5 4+n]-cycloadditions 4+n]-cycloaddition NOUN gh93gx44p04 2 6 have have AUX gh93gx44p04 2 7 been be AUX gh93gx44p04 2 8 utilized utilize VERB gh93gx44p04 2 9 extensively extensively ADV gh93gx44p04 2 10 to to ADP gh93gx44p04 2 11 access access NOUN gh93gx44p04 2 12 , , PUNCT gh93gx44p04 2 13 five five NUM gh93gx44p04 2 14 , , PUNCT gh93gx44p04 2 15 six six NUM gh93gx44p04 2 16 , , PUNCT gh93gx44p04 2 17 and and CCONJ gh93gx44p04 2 18 seven seven NUM gh93gx44p04 2 19 - - PUNCT gh93gx44p04 2 20 membered membered NOUN gh93gx44p04 2 21 rings ring NOUN gh93gx44p04 2 22 with with ADP gh93gx44p04 2 23 a a DET gh93gx44p04 2 24 range range NOUN gh93gx44p04 2 25 of of ADP gh93gx44p04 2 26 substitution substitution NOUN gh93gx44p04 2 27 patterns pattern NOUN gh93gx44p04 2 28 . . PUNCT gh93gx44p04 3 1 our our PRON gh93gx44p04 3 2 interest interest NOUN gh93gx44p04 3 3 lied lie VERB gh93gx44p04 3 4 in in ADP gh93gx44p04 3 5 the the DET gh93gx44p04 3 6 [ [ PUNCT gh93gx44p04 3 7 4 4 NUM gh93gx44p04 3 8 + + NUM gh93gx44p04 3 9 1]-construction 1]-construction NUM gh93gx44p04 3 10 of of ADP gh93gx44p04 3 11 potentially potentially ADV gh93gx44p04 3 12 bioactive bioactive ADJ gh93gx44p04 3 13 five five NUM gh93gx44p04 3 14 - - PUNCT gh93gx44p04 3 15 membered membered ADJ gh93gx44p04 3 16 heterocycles heterocycle NOUN gh93gx44p04 3 17 , , PUNCT gh93gx44p04 3 18 which which PRON gh93gx44p04 3 19 are be AUX gh93gx44p04 3 20 commonly commonly ADV gh93gx44p04 3 21 constructed construct VERB gh93gx44p04 3 22 via via ADP gh93gx44p04 3 23 a a DET gh93gx44p04 3 24 [ [ PUNCT gh93gx44p04 3 25 3 3 NUM gh93gx44p04 3 26 + + NUM gh93gx44p04 3 27 2]-cycloaddition 2]-cycloaddition NUM gh93gx44p04 3 28 reaction reaction NOUN gh93gx44p04 3 29 between between ADP gh93gx44p04 3 30 a a DET gh93gx44p04 3 31 1,3 1,3 NUM gh93gx44p04 3 32 - - PUNCT gh93gx44p04 3 33 dipole dipole NOUN gh93gx44p04 3 34 and and CCONJ gh93gx44p04 3 35 a a DET gh93gx44p04 3 36 dipolarophile dipolarophile NOUN gh93gx44p04 3 37 . . PUNCT gh93gx44p04 4 1 while while SCONJ gh93gx44p04 4 2 this this PRON gh93gx44p04 4 3 is be AUX gh93gx44p04 4 4 an an DET gh93gx44p04 4 5 elegant elegant ADJ gh93gx44p04 4 6 approach approach NOUN gh93gx44p04 4 7 , , PUNCT gh93gx44p04 4 8 it it PRON gh93gx44p04 4 9 is be AUX gh93gx44p04 4 10 limited limit VERB gh93gx44p04 4 11 by by ADP gh93gx44p04 4 12 the the DET gh93gx44p04 4 13 high high ADJ gh93gx44p04 4 14 level level NOUN gh93gx44p04 4 15 of of ADP gh93gx44p04 4 16 reactivity reactivity NOUN gh93gx44p04 4 17 of of ADP gh93gx44p04 4 18 the the DET gh93gx44p04 4 19 starting starting NOUN gh93gx44p04 4 20 materials.with materials.with NOUN gh93gx44p04 4 21 this this PRON gh93gx44p04 4 22 is be AUX gh93gx44p04 4 23 mind mind NOUN gh93gx44p04 4 24 , , PUNCT gh93gx44p04 4 25 we we PRON gh93gx44p04 4 26 anticipated anticipate VERB gh93gx44p04 4 27 that that SCONJ gh93gx44p04 4 28 the the DET gh93gx44p04 4 29 [ [ PUNCT gh93gx44p04 4 30 4 4 NUM gh93gx44p04 4 31 + + NUM gh93gx44p04 4 32 1 1 NUM gh93gx44p04 4 33 ] ] PUNCT gh93gx44p04 4 34 retrosynthetic retrosynthetic ADJ gh93gx44p04 4 35 disconnect disconnect NOUN gh93gx44p04 4 36 would would AUX gh93gx44p04 4 37 be be AUX gh93gx44p04 4 38 an an DET gh93gx44p04 4 39 efficiacious efficiacious ADJ gh93gx44p04 4 40 approach approach NOUN gh93gx44p04 4 41 providing provide VERB gh93gx44p04 4 42 ready ready ADJ gh93gx44p04 4 43 access access NOUN gh93gx44p04 4 44 to to ADP gh93gx44p04 4 45 the the DET gh93gx44p04 4 46 desired desire VERB gh93gx44p04 4 47 heterocycles heterocycle NOUN gh93gx44p04 4 48 without without ADP gh93gx44p04 4 49 the the DET gh93gx44p04 4 50 chemoselectivity chemoselectivity NOUN gh93gx44p04 4 51 and and CCONJ gh93gx44p04 4 52 regioselectivity regioselectivity NOUN gh93gx44p04 4 53 challenges challenge NOUN gh93gx44p04 4 54 that that PRON gh93gx44p04 4 55 can can AUX gh93gx44p04 4 56 arise arise VERB gh93gx44p04 4 57 with with ADP gh93gx44p04 4 58 [ [ PUNCT gh93gx44p04 4 59 3 3 NUM gh93gx44p04 4 60 + + NUM gh93gx44p04 4 61 2 2 NUM gh93gx44p04 4 62 ] ] PUNCT gh93gx44p04 4 63 cycloadditions cycloaddition NOUN gh93gx44p04 4 64 . . PUNCT gh93gx44p04 5 1 additionally additionally ADV gh93gx44p04 5 2 , , PUNCT gh93gx44p04 5 3 the the DET gh93gx44p04 5 4 variety variety NOUN gh93gx44p04 5 5 of of ADP gh93gx44p04 5 6 four four NUM gh93gx44p04 5 7 atom atom NOUN gh93gx44p04 5 8 components component NOUN gh93gx44p04 5 9 available available ADJ gh93gx44p04 5 10 would would AUX gh93gx44p04 5 11 allow allow VERB gh93gx44p04 5 12 access access NOUN gh93gx44p04 5 13 to to ADP gh93gx44p04 5 14 multiple multiple ADJ gh93gx44p04 5 15 heterocyclic heterocyclic NOUN gh93gx44p04 5 16 motifs motif NOUN gh93gx44p04 5 17 . . PUNCT gh93gx44p04 6 1 towards towards ADP gh93gx44p04 6 2 that that DET gh93gx44p04 6 3 end end NOUN gh93gx44p04 6 4 , , PUNCT gh93gx44p04 6 5 we we PRON gh93gx44p04 6 6 successfully successfully ADV gh93gx44p04 6 7 employed employ VERB gh93gx44p04 6 8 aza aza PROPN gh93gx44p04 6 9 ortho ortho PROPN gh93gx44p04 6 10 - - PUNCT gh93gx44p04 6 11 quinone quinone NOUN gh93gx44p04 6 12 methides methide NOUN gh93gx44p04 6 13 , , PUNCT gh93gx44p04 6 14 aroyl aroyl ADJ gh93gx44p04 6 15 isocyanates isocyanate NOUN gh93gx44p04 6 16 , , PUNCT gh93gx44p04 6 17 vinyl vinyl NOUN gh93gx44p04 6 18 ketenes ketene NOUN gh93gx44p04 6 19 , , PUNCT gh93gx44p04 6 20 and and CCONJ gh93gx44p04 6 21 vinyl vinyl NOUN gh93gx44p04 6 22 allenes allene NOUN gh93gx44p04 6 23 as as ADP gh93gx44p04 6 24 four four NUM gh93gx44p04 6 25 atom atom NOUN gh93gx44p04 6 26 components component NOUN gh93gx44p04 6 27 in in ADP gh93gx44p04 6 28 conjunction conjunction NOUN gh93gx44p04 6 29 with with ADP gh93gx44p04 6 30 metal metal NOUN gh93gx44p04 6 31 - - PUNCT gh93gx44p04 6 32 stabilized stabilize VERB gh93gx44p04 6 33 carbenes carbene NOUN gh93gx44p04 6 34 or or CCONJ gh93gx44p04 6 35 phosphorus phosphorus NOUN gh93gx44p04 6 36 - - PUNCT gh93gx44p04 6 37 based base VERB gh93gx44p04 6 38 carbenoids carbenoid NOUN gh93gx44p04 6 39 as as ADP gh93gx44p04 6 40 c1 c1 NOUN gh93gx44p04 6 41 - - PUNCT gh93gx44p04 6 42 synthons synthon NOUN gh93gx44p04 6 43 to to PART gh93gx44p04 6 44 generate generate VERB gh93gx44p04 6 45 dihydroindoles dihydroindole NOUN gh93gx44p04 6 46 , , PUNCT gh93gx44p04 6 47 oxazolones oxazolone NOUN gh93gx44p04 6 48 , , PUNCT gh93gx44p04 6 49 and and CCONJ gh93gx44p04 6 50 spirooxindole spirooxindole PROPN gh93gx44p04 6 51 cyclopentenones cyclopentenone NOUN gh93gx44p04 6 52 . . PUNCT