id sid tid token lemma pos fx719k4576t 1 1 this this DET fx719k4576t 1 2 dissertation dissertation NOUN fx719k4576t 1 3 addresses address VERB fx719k4576t 1 4 the the DET fx719k4576t 1 5 utility utility NOUN fx719k4576t 1 6 of of ADP fx719k4576t 1 7 using use VERB fx719k4576t 1 8 rapid rapid ADJ fx719k4576t 1 9 functionalization functionalization NOUN fx719k4576t 1 10 processes process NOUN fx719k4576t 1 11 for for ADP fx719k4576t 1 12 the the DET fx719k4576t 1 13 tailored tailored ADJ fx719k4576t 1 14 design design NOUN fx719k4576t 1 15 of of ADP fx719k4576t 1 16 modified modify VERB fx719k4576t 1 17 nanofiltration nanofiltration NOUN fx719k4576t 1 18 membranes membrane NOUN fx719k4576t 1 19 . . PUNCT fx719k4576t 2 1 the the DET fx719k4576t 2 2 key key ADJ fx719k4576t 2 3 need need NOUN fx719k4576t 2 4 for for ADP fx719k4576t 2 5 introducing introduce VERB fx719k4576t 2 6 additional additional ADJ fx719k4576t 2 7 functionalities functionality NOUN fx719k4576t 2 8 is be AUX fx719k4576t 2 9 to to PART fx719k4576t 2 10 overcome overcome VERB fx719k4576t 2 11 the the DET fx719k4576t 2 12 permeability permeability NOUN fx719k4576t 2 13 / / SYM fx719k4576t 2 14 selectivity selectivity ADJ fx719k4576t 2 15 tradeoff tradeoff NOUN fx719k4576t 2 16 seen see VERB fx719k4576t 2 17 in in ADP fx719k4576t 2 18 size size NOUN fx719k4576t 2 19 - - PUNCT fx719k4576t 2 20 selective selective ADJ fx719k4576t 2 21 membranes membrane NOUN fx719k4576t 2 22 . . PUNCT fx719k4576t 3 1 many many ADJ fx719k4576t 3 2 techniques technique NOUN fx719k4576t 3 3 have have AUX fx719k4576t 3 4 demonstrated demonstrate VERB fx719k4576t 3 5 the the DET fx719k4576t 3 6 positive positive ADJ fx719k4576t 3 7 impact impact NOUN fx719k4576t 3 8 of of ADP fx719k4576t 3 9 introducing introduce VERB fx719k4576t 3 10 additional additional ADJ fx719k4576t 3 11 interactions interaction NOUN fx719k4576t 3 12 between between ADP fx719k4576t 3 13 membranes membrane NOUN fx719k4576t 3 14 and and CCONJ fx719k4576t 3 15 solutes solute NOUN fx719k4576t 3 16 , , PUNCT fx719k4576t 3 17 such such ADJ fx719k4576t 3 18 as as ADP fx719k4576t 3 19 charged charge VERB fx719k4576t 3 20 moieties moiety NOUN fx719k4576t 3 21 , , PUNCT fx719k4576t 3 22 which which PRON fx719k4576t 3 23 can can AUX fx719k4576t 3 24 increase increase VERB fx719k4576t 3 25 the the DET fx719k4576t 3 26 rejection rejection NOUN fx719k4576t 3 27 of of ADP fx719k4576t 3 28 salt salt NOUN fx719k4576t 3 29 ions.beyond ions.beyond NOUN fx719k4576t 3 30 singularly singularly ADV fx719k4576t 3 31 functionalized functionalize VERB fx719k4576t 3 32 membranes membrane NOUN fx719k4576t 3 33 , , PUNCT fx719k4576t 3 34 novel novel ADJ fx719k4576t 3 35 transport transport NOUN fx719k4576t 3 36 properties property NOUN fx719k4576t 3 37 emerge emerge VERB fx719k4576t 3 38 when when SCONJ fx719k4576t 3 39 multiple multiple ADJ fx719k4576t 3 40 functionalities functionality NOUN fx719k4576t 3 41 are be AUX fx719k4576t 3 42 integrated integrate VERB fx719k4576t 3 43 within within ADP fx719k4576t 3 44 a a DET fx719k4576t 3 45 membrane membrane NOUN fx719k4576t 3 46 system system NOUN fx719k4576t 3 47 . . PUNCT fx719k4576t 4 1 this this PRON fx719k4576t 4 2 can can AUX fx719k4576t 4 3 be be AUX fx719k4576t 4 4 due due ADJ fx719k4576t 4 5 to to ADP fx719k4576t 4 6 domains domain NOUN fx719k4576t 4 7 interacting interact VERB fx719k4576t 4 8 with with ADP fx719k4576t 4 9 each each DET fx719k4576t 4 10 other other ADJ fx719k4576t 4 11 at at ADP fx719k4576t 4 12 their their PRON fx719k4576t 4 13 interfacial interfacial ADJ fx719k4576t 4 14 junctions junction NOUN fx719k4576t 4 15 , , PUNCT fx719k4576t 4 16 as as ADV fx719k4576t 4 17 well well ADV fx719k4576t 4 18 as as ADP fx719k4576t 4 19 when when SCONJ fx719k4576t 4 20 isolated isolated ADJ fx719k4576t 4 21 domains domain NOUN fx719k4576t 4 22 work work VERB fx719k4576t 4 23 independently independently ADV fx719k4576t 4 24 but but CCONJ fx719k4576t 4 25 in in ADP fx719k4576t 4 26 a a DET fx719k4576t 4 27 coordinated coordinated ADJ fx719k4576t 4 28 manner manner NOUN fx719k4576t 4 29 during during ADP fx719k4576t 4 30 operating operating NOUN fx719k4576t 4 31 conditions condition NOUN fx719k4576t 4 32 . . PUNCT fx719k4576t 5 1 this this DET fx719k4576t 5 2 dissertation dissertation NOUN fx719k4576t 5 3 takes take VERB fx719k4576t 5 4 the the DET fx719k4576t 5 5 approach approach NOUN fx719k4576t 5 6 of of ADP fx719k4576t 5 7 post post ADJ fx719k4576t 5 8 - - ADJ fx719k4576t 5 9 fabrication fabrication ADJ fx719k4576t 5 10 functionalization functionalization NOUN fx719k4576t 5 11 as as ADP fx719k4576t 5 12 a a DET fx719k4576t 5 13 viable viable ADJ fx719k4576t 5 14 method method NOUN fx719k4576t 5 15 to to PART fx719k4576t 5 16 develop develop VERB fx719k4576t 5 17 multi multi ADJ fx719k4576t 5 18 - - ADJ fx719k4576t 5 19 functional functional ADJ fx719k4576t 5 20 membranes membrane NOUN fx719k4576t 5 21 , , PUNCT fx719k4576t 5 22 by by ADP fx719k4576t 5 23 investigating investigate VERB fx719k4576t 5 24 the the DET fx719k4576t 5 25 copper copper NOUN fx719k4576t 5 26 - - PUNCT fx719k4576t 5 27 catalyzed catalyze VERB fx719k4576t 5 28 azide azide NOUN fx719k4576t 5 29 - - PUNCT fx719k4576t 5 30 alkyne alkyne NOUN fx719k4576t 5 31 cycloaddition cycloaddition NOUN fx719k4576t 5 32 ( ( PUNCT fx719k4576t 5 33 cuaac cuaac PROPN fx719k4576t 5 34 ) ) PUNCT fx719k4576t 5 35 reaction reaction NOUN fx719k4576t 5 36 . . PUNCT fx719k4576t 6 1 first first ADV fx719k4576t 6 2 , , PUNCT fx719k4576t 6 3 the the DET fx719k4576t 6 4 desired desire VERB fx719k4576t 6 5 membrane membrane NOUN fx719k4576t 6 6 structure structure NOUN fx719k4576t 6 7 is be AUX fx719k4576t 6 8 readily readily ADV fx719k4576t 6 9 formed form VERB fx719k4576t 6 10 by by ADP fx719k4576t 6 11 tailoring tailor VERB fx719k4576t 6 12 the the DET fx719k4576t 6 13 polymer polymer NOUN fx719k4576t 6 14 chemistry chemistry NOUN fx719k4576t 6 15 and and CCONJ fx719k4576t 6 16 casting cast VERB fx719k4576t 6 17 conditions condition NOUN fx719k4576t 6 18 , , PUNCT fx719k4576t 6 19 resulting result VERB fx719k4576t 6 20 in in ADP fx719k4576t 6 21 membranes membrane NOUN fx719k4576t 6 22 with with ADP fx719k4576t 6 23 azide azide NOUN fx719k4576t 6 24 moieties moiety NOUN fx719k4576t 6 25 lining line VERB fx719k4576t 6 26 the the DET fx719k4576t 6 27 pore pore NOUN fx719k4576t 6 28 wall wall NOUN fx719k4576t 6 29 . . PUNCT fx719k4576t 7 1 second second ADJ fx719k4576t 7 2 , , PUNCT fx719k4576t 7 3 the the DET fx719k4576t 7 4 addition addition NOUN fx719k4576t 7 5 of of ADP fx719k4576t 7 6 a a DET fx719k4576t 7 7 desired desire VERB fx719k4576t 7 8 functionality functionality NOUN fx719k4576t 7 9 is be AUX fx719k4576t 7 10 achieved achieve VERB fx719k4576t 7 11 through through ADP fx719k4576t 7 12 coupling coupling NOUN fx719k4576t 7 13 reactions reaction NOUN fx719k4576t 7 14 with with ADP fx719k4576t 7 15 reactive reactive ADJ fx719k4576t 7 16 solutions solution NOUN fx719k4576t 7 17 of of ADP fx719k4576t 7 18 functional functional ADJ fx719k4576t 7 19 alkynes alkyne NOUN fx719k4576t 7 20 with with ADP fx719k4576t 7 21 the the DET fx719k4576t 7 22 azide azide NOUN fx719k4576t 7 23 lined line VERB fx719k4576t 7 24 pore pore NOUN fx719k4576t 7 25 walls.the walls.the DET fx719k4576t 7 26 ability ability NOUN fx719k4576t 7 27 to to PART fx719k4576t 7 28 isolate isolate VERB fx719k4576t 7 29 functional functional ADJ fx719k4576t 7 30 domains domain NOUN fx719k4576t 7 31 using use VERB fx719k4576t 7 32 this this DET fx719k4576t 7 33 reaction reaction NOUN fx719k4576t 7 34 process process NOUN fx719k4576t 7 35 was be AUX fx719k4576t 7 36 confirmed confirm VERB fx719k4576t 7 37 through through ADP fx719k4576t 7 38 fourier fourier NOUN fx719k4576t 7 39 - - PUNCT fx719k4576t 7 40 transform transform NOUN fx719k4576t 7 41 infrared infrared ADJ fx719k4576t 7 42 spectroscopy spectroscopy NOUN fx719k4576t 7 43 analysis analysis NOUN fx719k4576t 7 44 , , PUNCT fx719k4576t 7 45 which which PRON fx719k4576t 7 46 developed develop VERB fx719k4576t 7 47 protocols protocol NOUN fx719k4576t 7 48 for for ADP fx719k4576t 7 49 synthesizing synthesize VERB fx719k4576t 7 50 reactive reactive ADJ fx719k4576t 7 51 solutions solution NOUN fx719k4576t 7 52 that that PRON fx719k4576t 7 53 achieve achieve VERB fx719k4576t 7 54 high high ADJ fx719k4576t 7 55 reactive reactive ADJ fx719k4576t 7 56 rates rate NOUN fx719k4576t 7 57 compared compare VERB fx719k4576t 7 58 to to ADP fx719k4576t 7 59 the the DET fx719k4576t 7 60 diffusive diffusive ADJ fx719k4576t 7 61 rate rate NOUN fx719k4576t 7 62 of of ADP fx719k4576t 7 63 the the DET fx719k4576t 7 64 solution solution NOUN fx719k4576t 7 65 as as SCONJ fx719k4576t 7 66 it it PRON fx719k4576t 7 67 transports transport VERB fx719k4576t 7 68 through through ADP fx719k4576t 7 69 the the DET fx719k4576t 7 70 membrane membrane NOUN fx719k4576t 7 71 . . PUNCT fx719k4576t 8 1 multi multi ADJ fx719k4576t 8 2 - - ADJ fx719k4576t 8 3 functional functional ADJ fx719k4576t 8 4 membranes membrane NOUN fx719k4576t 8 5 with with ADP fx719k4576t 8 6 surface surface NOUN fx719k4576t 8 7 anti anti ADJ fx719k4576t 8 8 - - ADJ fx719k4576t 8 9 fouling foul VERB fx719k4576t 8 10 chemistry chemistry NOUN fx719k4576t 8 11 and and CCONJ fx719k4576t 8 12 underlying underlying ADJ fx719k4576t 8 13 charged charge VERB fx719k4576t 8 14 chemistry chemistry NOUN fx719k4576t 8 15 were be AUX fx719k4576t 8 16 made make VERB fx719k4576t 8 17 which which PRON fx719k4576t 8 18 exhibited exhibit VERB fx719k4576t 8 19 equivalent equivalent ADJ fx719k4576t 8 20 ion ion NOUN fx719k4576t 8 21 rejection rejection NOUN fx719k4576t 8 22 performance performance NOUN fx719k4576t 8 23 compared compare VERB fx719k4576t 8 24 to to ADP fx719k4576t 8 25 fully fully ADV fx719k4576t 8 26 charged charge VERB fx719k4576t 8 27 membranes membrane NOUN fx719k4576t 8 28 , , PUNCT fx719k4576t 8 29 but but CCONJ fx719k4576t 8 30 with with ADP fx719k4576t 8 31 a a DET fx719k4576t 8 32 much much ADV fx719k4576t 8 33 lower low ADJ fx719k4576t 8 34 propensity propensity NOUN fx719k4576t 8 35 for for ADP fx719k4576t 8 36 fouling.the fouling.the DET fx719k4576t 8 37 cuaac cuaac ADJ fx719k4576t 8 38 reaction reaction NOUN fx719k4576t 8 39 was be AUX fx719k4576t 8 40 also also ADV fx719k4576t 8 41 used use VERB fx719k4576t 8 42 to to PART fx719k4576t 8 43 form form VERB fx719k4576t 8 44 surface surface NOUN fx719k4576t 8 45 patterned pattern VERB fx719k4576t 8 46 multi multi ADJ fx719k4576t 8 47 - - ADJ fx719k4576t 8 48 functional functional ADJ fx719k4576t 8 49 membranes membrane NOUN fx719k4576t 8 50 , , PUNCT fx719k4576t 8 51 in in ADP fx719k4576t 8 52 which which PRON fx719k4576t 8 53 asymmetric asymmetric ADJ fx719k4576t 8 54 coverage coverage NOUN fx719k4576t 8 55 of of ADP fx719k4576t 8 56 positive positive ADJ fx719k4576t 8 57 and and CCONJ fx719k4576t 8 58 negative negative ADJ fx719k4576t 8 59 charge charge NOUN fx719k4576t 8 60 resulted result VERB fx719k4576t 8 61 in in ADP fx719k4576t 8 62 unique unique ADJ fx719k4576t 8 63 transport transport NOUN fx719k4576t 8 64 phenomena phenomenon NOUN fx719k4576t 8 65 of of ADP fx719k4576t 8 66 asymmetric asymmetric ADJ fx719k4576t 8 67 salts salt NOUN fx719k4576t 8 68 , , PUNCT fx719k4576t 8 69 such such ADJ fx719k4576t 8 70 as as ADP fx719k4576t 8 71 magnesium magnesium NOUN fx719k4576t 8 72 chloride chloride PROPN fx719k4576t 8 73 ( ( PUNCT fx719k4576t 8 74 mgcl2 mgcl2 PROPN fx719k4576t 8 75 ) ) PUNCT fx719k4576t 8 76 and and CCONJ fx719k4576t 8 77 potassium potassium NOUN fx719k4576t 8 78 sulfate sulfate NOUN fx719k4576t 8 79 ( ( PUNCT fx719k4576t 8 80 k2so4 k2so4 PROPN fx719k4576t 8 81 ) ) PUNCT fx719k4576t 8 82 . . PUNCT fx719k4576t 9 1 the the DET fx719k4576t 9 2 utility utility NOUN fx719k4576t 9 3 of of ADP fx719k4576t 9 4 the the DET fx719k4576t 9 5 thiol thiol NOUN fx719k4576t 9 6 - - PUNCT fx719k4576t 9 7 yne yne NOUN fx719k4576t 9 8 coupling coupling NOUN fx719k4576t 9 9 reaction reaction NOUN fx719k4576t 9 10 for for ADP fx719k4576t 9 11 surface surface NOUN fx719k4576t 9 12 patterning patterning NOUN fx719k4576t 9 13 of of ADP fx719k4576t 9 14 multi multi ADJ fx719k4576t 9 15 - - ADJ fx719k4576t 9 16 functional functional ADJ fx719k4576t 9 17 membranes membrane NOUN fx719k4576t 9 18 was be AUX fx719k4576t 9 19 also also ADV fx719k4576t 9 20 investigated investigate VERB fx719k4576t 9 21 by by ADP fx719k4576t 9 22 introducing introduce VERB fx719k4576t 9 23 specific specific ADJ fx719k4576t 9 24 domains domain NOUN fx719k4576t 9 25 for for ADP fx719k4576t 9 26 the the DET fx719k4576t 9 27 targeted target VERB fx719k4576t 9 28 adsorption adsorption NOUN fx719k4576t 9 29 of of ADP fx719k4576t 9 30 heavy heavy ADJ fx719k4576t 9 31 metals.these metals.these NOUN fx719k4576t 9 32 results result NOUN fx719k4576t 9 33 demonstrate demonstrate VERB fx719k4576t 9 34 the the DET fx719k4576t 9 35 unique unique ADJ fx719k4576t 9 36 abilities ability NOUN fx719k4576t 9 37 and and CCONJ fx719k4576t 9 38 transport transport NOUN fx719k4576t 9 39 properties property NOUN fx719k4576t 9 40 that that SCONJ fx719k4576t 9 41 multi multi ADJ fx719k4576t 9 42 - - ADJ fx719k4576t 9 43 functional functional ADJ fx719k4576t 9 44 membranes membrane NOUN fx719k4576t 9 45 can can AUX fx719k4576t 9 46 achieve achieve VERB fx719k4576t 9 47 . . PUNCT fx719k4576t 10 1 the the DET fx719k4576t 10 2 knowledge knowledge NOUN fx719k4576t 10 3 for for ADP fx719k4576t 10 4 creating create VERB fx719k4576t 10 5 multi multi ADJ fx719k4576t 10 6 - - ADJ fx719k4576t 10 7 functional functional ADJ fx719k4576t 10 8 membranes membrane NOUN fx719k4576t 10 9 can can AUX fx719k4576t 10 10 improve improve VERB fx719k4576t 10 11 many many ADJ fx719k4576t 10 12 separation separation NOUN fx719k4576t 10 13 processes process NOUN fx719k4576t 10 14 . . PUNCT