id	sid	tid	token	lemma	pos
br86b27956f	1	1	the	the	DET
br86b27956f	1	2	work	work	NOUN
br86b27956f	1	3	presented	present	VERB
br86b27956f	1	4	in	in	ADP
br86b27956f	1	5	this	this	DET
br86b27956f	1	6	dissertation	dissertation	NOUN
br86b27956f	1	7	investigates	investigate	VERB
br86b27956f	1	8	the	the	DET
br86b27956f	1	9	use	use	NOUN
br86b27956f	1	10	of	of	ADP
br86b27956f	1	11	various	various	ADJ
br86b27956f	1	12	alkali	alkali	ADJ
br86b27956f	1	13	metal	metal	NOUN
br86b27956f	1	14	aggregates	aggregate	NOUN
br86b27956f	1	15	as	as	ADP
br86b27956f	1	16	secondary	secondary	ADJ
br86b27956f	1	17	building	building	NOUN
br86b27956f	1	18	units	unit	NOUN
br86b27956f	1	19	,	,	PUNCT
br86b27956f	1	20	sbus	sbus	ADJ
br86b27956f	1	21	,	,	PUNCT
br86b27956f	1	22	for	for	ADP
br86b27956f	1	23	the	the	DET
br86b27956f	1	24	formation	formation	NOUN
br86b27956f	1	25	of	of	ADP
br86b27956f	1	26	extended	extended	ADJ
br86b27956f	1	27	framework	framework	NOUN
br86b27956f	1	28	materials	material	NOUN
br86b27956f	1	29	.	.	PUNCT
br86b27956f	2	1	three	three	NUM
br86b27956f	2	2	main	main	ADJ
br86b27956f	2	3	avenues	avenue	NOUN
br86b27956f	2	4	of	of	ADP
br86b27956f	2	5	research	research	NOUN
br86b27956f	2	6	have	have	AUX
br86b27956f	2	7	been	be	AUX
br86b27956f	2	8	studied	study	VERB
br86b27956f	2	9	,	,	PUNCT
br86b27956f	2	10	which	which	PRON
br86b27956f	2	11	each	each	PRON
br86b27956f	2	12	consider	consider	VERB
br86b27956f	2	13	different	different	ADJ
br86b27956f	2	14	approaches	approach	NOUN
br86b27956f	2	15	to	to	PART
br86b27956f	2	16	better	well	ADV
br86b27956f	2	17	understand	understand	VERB
br86b27956f	2	18	this	this	DET
br86b27956f	2	19	class	class	NOUN
br86b27956f	2	20	of	of	ADP
br86b27956f	2	21	materials	material	NOUN
br86b27956f	2	22	.	.	PUNCT
br86b27956f	3	1	the	the	DET
br86b27956f	3	2	first	first	ADJ
br86b27956f	3	3	topic	topic	NOUN
br86b27956f	3	4	is	be	AUX
br86b27956f	3	5	concerned	concern	VERB
br86b27956f	3	6	with	with	ADP
br86b27956f	3	7	the	the	DET
br86b27956f	3	8	manipulation	manipulation	NOUN
br86b27956f	3	9	of	of	ADP
br86b27956f	3	10	extended	extended	ADJ
br86b27956f	3	11	supramolecular	supramolecular	ADJ
br86b27956f	3	12	structure	structure	NOUN
br86b27956f	3	13	of	of	ADP
br86b27956f	3	14	lithium	lithium	PROPN
br86b27956f	3	15	aryloxide	aryloxide	NOUN
br86b27956f	3	16	complexes	complex	NOUN
br86b27956f	3	17	using	use	VERB
br86b27956f	3	18	either	either	CCONJ
br86b27956f	3	19	self	self	NOUN
br86b27956f	3	20	-	-	PUNCT
br86b27956f	3	21	assembled	assemble	VERB
br86b27956f	3	22	mixed	mixed	ADJ
br86b27956f	3	23	-	-	PUNCT
br86b27956f	3	24	anion	anion	NOUN
br86b27956f	3	25	species	specie	NOUN
br86b27956f	3	26	or	or	CCONJ
br86b27956f	3	27	solvent	solvent	NOUN
br86b27956f	3	28	additives	additive	NOUN
br86b27956f	3	29	(	(	PUNCT
br86b27956f	3	30	chapters	chapter	NOUN
br86b27956f	3	31	2	2	NUM
br86b27956f	3	32	and	and	CCONJ
br86b27956f	3	33	3	3	NUM
br86b27956f	3	34	)	)	PUNCT
br86b27956f	3	35	.	.	PUNCT
br86b27956f	4	1	our	our	PRON
br86b27956f	4	2	group	group	NOUN
br86b27956f	4	3	has	have	AUX
br86b27956f	4	4	previously	previously	ADV
br86b27956f	4	5	shown	show	VERB
br86b27956f	4	6	that	that	SCONJ
br86b27956f	4	7	molecular	molecular	ADJ
br86b27956f	4	8	cage	cage	NOUN
br86b27956f	4	9	aggregates	aggregate	NOUN
br86b27956f	4	10	of	of	ADP
br86b27956f	4	11	s	s	NOUN
br86b27956f	4	12	-	-	PUNCT
br86b27956f	4	13	block	block	NOUN
br86b27956f	4	14	metal	metal	NOUN
br86b27956f	4	15	complexes	complex	NOUN
br86b27956f	4	16	can	can	AUX
br86b27956f	4	17	successfully	successfully	ADV
br86b27956f	4	18	be	be	AUX
br86b27956f	4	19	utilized	utilize	VERB
br86b27956f	4	20	as	as	ADP
br86b27956f	4	21	sbus	sbus	ADJ
br86b27956f	4	22	to	to	PART
br86b27956f	4	23	direct	direct	VERB
br86b27956f	4	24	network	network	NOUN
br86b27956f	4	25	assembly	assembly	NOUN
br86b27956f	4	26	.	.	PUNCT
br86b27956f	5	1	for	for	ADP
br86b27956f	5	2	example	example	NOUN
br86b27956f	5	3	,	,	PUNCT
br86b27956f	5	4	tetrameric	tetrameric	NOUN
br86b27956f	5	5	cubanes	cubane	NOUN
br86b27956f	5	6	of	of	ADP
br86b27956f	5	7	specific	specific	ADJ
br86b27956f	5	8	lithium	lithium	NOUN
br86b27956f	5	9	aryloxides	aryloxide	NOUN
br86b27956f	5	10	may	may	AUX
br86b27956f	5	11	be	be	AUX
br86b27956f	5	12	designed	design	VERB
br86b27956f	5	13	such	such	ADJ
br86b27956f	5	14	that	that	SCONJ
br86b27956f	5	15	each	each	DET
br86b27956f	5	16	metal	metal	NOUN
br86b27956f	5	17	center	center	NOUN
br86b27956f	5	18	has	have	VERB
br86b27956f	5	19	a	a	DET
br86b27956f	5	20	single	single	ADJ
br86b27956f	5	21	open	open	ADJ
br86b27956f	5	22	site	site	NOUN
br86b27956f	5	23	for	for	ADP
br86b27956f	5	24	coordination	coordination	NOUN
br86b27956f	5	25	to	to	ADP
br86b27956f	5	26	a	a	DET
br86b27956f	5	27	lewis	lewis	PROPN
br86b27956f	5	28	base	base	NOUN
br86b27956f	5	29	.	.	PUNCT
br86b27956f	6	1	in	in	ADP
br86b27956f	6	2	turn	turn	NOUN
br86b27956f	6	3	,	,	PUNCT
br86b27956f	6	4	employment	employment	NOUN
br86b27956f	6	5	of	of	ADP
br86b27956f	6	6	a	a	DET
br86b27956f	6	7	ditopic	ditopic	ADJ
br86b27956f	6	8	linker	linker	NOUN
br86b27956f	6	9	results	result	NOUN
br86b27956f	6	10	in	in	ADP
br86b27956f	6	11	these	these	DET
br86b27956f	6	12	aggregates	aggregate	NOUN
br86b27956f	6	13	acting	act	VERB
br86b27956f	6	14	as	as	ADP
br86b27956f	6	15	tetrahedral	tetrahedral	ADJ
br86b27956f	6	16	nodes	node	NOUN
br86b27956f	6	17	to	to	PART
br86b27956f	6	18	form	form	VERB
br86b27956f	6	19	3d	3d	NOUN
br86b27956f	6	20	diamondoid	diamondoid	NOUN
br86b27956f	6	21	,	,	PUNCT
br86b27956f	6	22	and	and	CCONJ
br86b27956f	6	23	related	relate	VERB
br86b27956f	6	24	lower	low	ADJ
br86b27956f	6	25	dimensionality	dimensionality	NOUN
br86b27956f	6	26	polymers	polymer	NOUN
br86b27956f	6	27	.	.	PUNCT
br86b27956f	7	1	another	another	DET
br86b27956f	7	2	level	level	NOUN
br86b27956f	7	3	of	of	ADP
br86b27956f	7	4	sophistication	sophistication	NOUN
br86b27956f	7	5	to	to	ADP
br86b27956f	7	6	these	these	DET
br86b27956f	7	7	systems	system	NOUN
br86b27956f	7	8	is	be	AUX
br86b27956f	7	9	presented	present	VERB
br86b27956f	7	10	here	here	ADV
br86b27956f	7	11	through	through	ADP
br86b27956f	7	12	the	the	DET
br86b27956f	7	13	control	control	NOUN
br86b27956f	7	14	of	of	ADP
br86b27956f	7	15	the	the	DET
br86b27956f	7	16	number	number	NOUN
br86b27956f	7	17	of	of	ADP
br86b27956f	7	18	metal	metal	NOUN
br86b27956f	7	19	atoms	atom	NOUN
br86b27956f	7	20	within	within	ADP
br86b27956f	7	21	each	each	DET
br86b27956f	7	22	aggregate	aggregate	NOUN
br86b27956f	7	23	that	that	PRON
br86b27956f	7	24	may	may	AUX
br86b27956f	7	25	act	act	VERB
br86b27956f	7	26	as	as	ADP
br86b27956f	7	27	points	point	NOUN
br86b27956f	7	28	of	of	ADP
br86b27956f	7	29	network	network	NOUN
br86b27956f	7	30	extension	extension	NOUN
br86b27956f	7	31	.	.	PUNCT
br86b27956f	8	1	a	a	DET
br86b27956f	8	2	set	set	NOUN
br86b27956f	8	3	of	of	ADP
br86b27956f	8	4	zero-	zero-	PROPN
br86b27956f	8	5	,	,	PUNCT
br86b27956f	8	6	one-	one-	NOUN
br86b27956f	8	7	,	,	PUNCT
br86b27956f	8	8	two-	two-	NOUN
br86b27956f	8	9	,	,	PUNCT
br86b27956f	8	10	and	and	CCONJ
br86b27956f	8	11	three	three	NUM
br86b27956f	8	12	-	-	PUNCT
br86b27956f	8	13	dimensional	dimensional	ADJ
br86b27956f	8	14	materials	material	NOUN
br86b27956f	8	15	have	have	AUX
br86b27956f	8	16	been	be	AUX
br86b27956f	8	17	synthesized	synthesize	VERB
br86b27956f	8	18	by	by	ADP
br86b27956f	8	19	systematically	systematically	ADV
br86b27956f	8	20	varying	vary	VERB
br86b27956f	8	21	the	the	DET
br86b27956f	8	22	stoichiometry	stoichiometry	NOUN
br86b27956f	8	23	of	of	ADP
br86b27956f	8	24	the	the	DET
br86b27956f	8	25	two	two	NUM
br86b27956f	8	26	components	component	NOUN
br86b27956f	8	27	,	,	PUNCT
br86b27956f	8	28	2,4,6	2,4,6	NUM
br86b27956f	8	29	-	-	PUNCT
br86b27956f	8	30	me3	me3	NOUN
br86b27956f	8	31	-	-	PUNCT
br86b27956f	8	32	c6h2oli	c6h2oli	NUM
br86b27956f	8	33	(	(	PUNCT
br86b27956f	8	34	aroli	aroli	PROPN
br86b27956f	8	35	)	)	PUNCT
br86b27956f	8	36	and	and	CCONJ
br86b27956f	8	37	me2n(ch2)2oli	me2n(ch2)2oli	PROPN
br86b27956f	8	38	(	(	PUNCT
br86b27956f	8	39	roli	roli	PROPN
br86b27956f	8	40	)	)	PUNCT
br86b27956f	8	41	,	,	PUNCT
br86b27956f	8	42	within	within	ADP
br86b27956f	8	43	single	single	ADJ
br86b27956f	8	44	aggregates	aggregate	NOUN
br86b27956f	8	45	while	while	SCONJ
br86b27956f	8	46	using	use	VERB
br86b27956f	8	47	1,4	1,4	PRON
br86b27956f	8	48	-	-	PUNCT
br86b27956f	8	49	dioxane	dioxane	NOUN
br86b27956f	8	50	(	(	PUNCT
br86b27956f	8	51	diox	diox	PROPN
br86b27956f	8	52	)	)	PUNCT
br86b27956f	8	53	as	as	ADP
br86b27956f	8	54	a	a	DET
br86b27956f	8	55	ditopic	ditopic	ADJ
br86b27956f	8	56	linker	linker	NOUN
br86b27956f	8	57	.	.	PUNCT
br86b27956f	9	1	the	the	DET
br86b27956f	9	2	homoleptic	homoleptic	ADJ
br86b27956f	9	3	complex	complex	NOUN
br86b27956f	9	4	[	[	X
br86b27956f	9	5	{	{	PUNCT
br86b27956f	9	6	(	(	PUNCT
br86b27956f	9	7	aroli)4ì¢	aroli)4ì¢	PROPN
br86b27956f	9	8	ââå¢(diox)2}3(diox	ââå¢(diox)2}3(diox	NUM
br86b27956f	9	9	)	)	PUNCT
br86b27956f	9	10	]	]	PUNCT
br86b27956f	9	11	forms	form	VERB
br86b27956f	9	12	a	a	DET
br86b27956f	9	13	3d	3d	NOUN
br86b27956f	9	14	diamondoid	diamondoid	ADJ
br86b27956f	9	15	extended	extended	ADJ
br86b27956f	9	16	structure	structure	NOUN
br86b27956f	9	17	,	,	PUNCT
br86b27956f	9	18	where	where	SCONJ
br86b27956f	9	19	li4o4	li4o4	PROPN
br86b27956f	9	20	cubanes	cubanes	PROPN
br86b27956f	9	21	act	act	VERB
br86b27956f	9	22	as	as	ADP
br86b27956f	9	23	tetrahedral	tetrahedral	ADJ
br86b27956f	9	24	nodes	node	NOUN
br86b27956f	9	25	.	.	PUNCT
br86b27956f	10	1	attempts	attempt	VERB
br86b27956f	10	2	to	to	PART
br86b27956f	10	3	rationally	rationally	ADV
br86b27956f	10	4	alter	alter	VERB
br86b27956f	10	5	the	the	DET
br86b27956f	10	6	dimensionality	dimensionality	NOUN
br86b27956f	10	7	of	of	ADP
br86b27956f	10	8	the	the	DET
br86b27956f	10	9	network	network	NOUN
br86b27956f	10	10	through	through	ADP
br86b27956f	10	11	the	the	DET
br86b27956f	10	12	sequential	sequential	ADJ
br86b27956f	10	13	replacement	replacement	NOUN
br86b27956f	10	14	of	of	ADP
br86b27956f	10	15	aroli	aroli	PROPN
br86b27956f	10	16	vertices	vertex	NOUN
br86b27956f	10	17	by	by	ADP
br86b27956f	10	18	potentially	potentially	ADV
br86b27956f	10	19	chelating	chelate	VERB
br86b27956f	10	20	roli	roli	NOUN
br86b27956f	10	21	units	unit	NOUN
br86b27956f	10	22	have	have	AUX
br86b27956f	10	23	succeeded	succeed	VERB
br86b27956f	10	24	.	.	PUNCT
br86b27956f	11	1	the	the	DET
br86b27956f	11	2	mixed	mixed	ADJ
br86b27956f	11	3	-	-	PUNCT
br86b27956f	11	4	anion	anion	NOUN
br86b27956f	11	5	complexes	complex	NOUN
br86b27956f	11	6	[	[	X
br86b27956f	11	7	{	{	PUNCT
br86b27956f	11	8	(	(	PUNCT
br86b27956f	11	9	roli)(aroli)3ì¢	roli)(aroli)3ì¢	NOUN
br86b27956f	11	10	ââå¢(diox)1.5}1/2(c6h14	ââå¢(diox)1.5}1/2(c6h14	PROPN
br86b27956f	11	11	)	)	PUNCT
br86b27956f	11	12	]	]	PUNCT
br86b27956f	11	13	and	and	CCONJ
br86b27956f	11	14	[	[	X
br86b27956f	11	15	(	(	PUNCT
br86b27956f	11	16	roli)4(aroli)2ì¢	roli)4(aroli)2ì¢	NOUN
br86b27956f	11	17	ââå¢(diox	ââå¢(diox	SPACE
br86b27956f	11	18	)	)	PUNCT
br86b27956f	11	19	]	]	PUNCT
br86b27956f	11	20	,	,	PUNCT
br86b27956f	11	21	adopt	adopt	VERB
br86b27956f	11	22	2d	2d	PRON
br86b27956f	11	23	hexagonal	hexagonal	ADJ
br86b27956f	11	24	net	net	NOUN
br86b27956f	11	25	and	and	CCONJ
br86b27956f	11	26	1d	1d	NUM
br86b27956f	11	27	chain	chain	NOUN
br86b27956f	11	28	structures	structure	NOUN
br86b27956f	11	29	,	,	PUNCT
br86b27956f	11	30	respectively	respectively	ADV
br86b27956f	11	31	.	.	PUNCT
br86b27956f	12	1	furthermore	furthermore	ADV
br86b27956f	12	2	,	,	PUNCT
br86b27956f	12	3	the	the	DET
br86b27956f	12	4	two	two	NUM
br86b27956f	12	5	complexes	complex	NOUN
br86b27956f	12	6	[	[	X
br86b27956f	12	7	{	{	PUNCT
br86b27956f	12	8	(	(	PUNCT
br86b27956f	12	9	roli)3(aroli)3ì¢	roli)3(aroli)3ì¢	PROPN
br86b27956f	12	10	ââå¢(diox)0.5}(c6h14	ââå¢(diox)0.5}(c6h14	NOUN
br86b27956f	12	11	)	)	PUNCT
br86b27956f	12	12	]	]	PUNCT
br86b27956f	12	13	and	and	CCONJ
br86b27956f	12	14	[	[	X
br86b27956f	12	15	(	(	PUNCT
br86b27956f	12	16	roli)5(aroli)ì¢	roli)5(aroli)ì¢	NOUN
br86b27956f	12	17	ââå¢(diox)0.5	ââå¢(diox)0.5	SPACE
br86b27956f	12	18	]	]	PUNCT
br86b27956f	12	19	both	both	PRON
br86b27956f	12	20	form	form	VERB
br86b27956f	12	21	unusual	unusual	ADJ
br86b27956f	12	22	0d	0d	NOUN
br86b27956f	12	23	molecular	molecular	ADJ
br86b27956f	12	24	dumbbell	dumbbell	NOUN
br86b27956f	12	25	structures	structure	NOUN
br86b27956f	12	26	in	in	ADP
br86b27956f	12	27	the	the	DET
br86b27956f	12	28	solid	solid	ADJ
br86b27956f	12	29	state	state	NOUN
br86b27956f	12	30	.	.	PUNCT
br86b27956f	13	1	incorporation	incorporation	NOUN
br86b27956f	13	2	of	of	ADP
br86b27956f	13	3	multiple	multiple	ADJ
br86b27956f	13	4	roli	roli	NOUN
br86b27956f	13	5	units	unit	NOUN
br86b27956f	13	6	in	in	ADP
br86b27956f	13	7	the	the	DET
br86b27956f	13	8	mixed	mixed	ADJ
br86b27956f	13	9	-	-	PUNCT
br86b27956f	13	10	anion	anion	NOUN
br86b27956f	13	11	complexes	complex	NOUN
br86b27956f	13	12	not	not	PART
br86b27956f	13	13	only	only	ADV
br86b27956f	13	14	results	result	VERB
br86b27956f	13	15	in	in	ADP
br86b27956f	13	16	reducing	reduce	VERB
br86b27956f	13	17	the	the	DET
br86b27956f	13	18	number	number	NOUN
br86b27956f	13	19	of	of	ADP
br86b27956f	13	20	possible	possible	ADJ
br86b27956f	13	21	sites	site	NOUN
br86b27956f	13	22	for	for	ADP
br86b27956f	13	23	polymer	polymer	NOUN
br86b27956f	13	24	extension	extension	NOUN
br86b27956f	13	25	through	through	ADP
br86b27956f	13	26	chelation	chelation	NOUN
br86b27956f	13	27	,	,	PUNCT
br86b27956f	13	28	but	but	CCONJ
br86b27956f	13	29	also	also	ADV
br86b27956f	13	30	changes	change	VERB
br86b27956f	13	31	the	the	DET
br86b27956f	13	32	aggregation	aggregation	NOUN
br86b27956f	13	33	state	state	NOUN
br86b27956f	13	34	of	of	ADP
br86b27956f	13	35	the	the	DET
br86b27956f	13	36	building	building	NOUN
br86b27956f	13	37	block	block	NOUN
br86b27956f	13	38	from	from	ADP
br86b27956f	13	39	tetrametallic	tetrametallic	NOUN
br86b27956f	13	40	li4o4	li4o4	ADP
br86b27956f	13	41	units	unit	NOUN
br86b27956f	13	42	to	to	ADP
br86b27956f	13	43	hexametallic	hexametallic	PROPN
br86b27956f	13	44	li6o6	li6o6	PROPN
br86b27956f	13	45	units	unit	NOUN
br86b27956f	13	46	.	.	PUNCT
br86b27956f	14	1	the	the	DET
br86b27956f	14	2	second	second	ADJ
br86b27956f	14	3	area	area	NOUN
br86b27956f	14	4	of	of	ADP
br86b27956f	14	5	investigation	investigation	NOUN
br86b27956f	14	6	explores	explore	VERB
br86b27956f	14	7	the	the	DET
br86b27956f	14	8	molecular	molecular	ADJ
br86b27956f	14	9	aggregation	aggregation	NOUN
br86b27956f	14	10	and	and	CCONJ
br86b27956f	14	11	extended	extended	ADJ
br86b27956f	14	12	network	network	NOUN
br86b27956f	14	13	chemistry	chemistry	NOUN
br86b27956f	14	14	of	of	ADP
br86b27956f	14	15	substituted	substituted	ADJ
br86b27956f	14	16	aryloxide	aryloxide	ADJ
br86b27956f	14	17	ligands	ligand	NOUN
br86b27956f	14	18	in	in	ADP
br86b27956f	14	19	combination	combination	NOUN
br86b27956f	14	20	with	with	ADP
br86b27956f	14	21	the	the	DET
br86b27956f	14	22	heavier	heavy	ADJ
br86b27956f	14	23	alkali	alkali	ADJ
br86b27956f	14	24	metals	metal	NOUN
br86b27956f	14	25	na	na	PROPN
br86b27956f	14	26	,	,	PUNCT
br86b27956f	14	27	k	k	PROPN
br86b27956f	14	28	,	,	PUNCT
br86b27956f	14	29	rb	rb	PROPN
br86b27956f	14	30	,	,	PUNCT
br86b27956f	14	31	and	and	CCONJ
br86b27956f	14	32	cs	cs	PROPN
br86b27956f	14	33	(	(	PUNCT
br86b27956f	14	34	chapters	chapter	NOUN
br86b27956f	14	35	4	4	NUM
br86b27956f	14	36	-	-	SYM
br86b27956f	14	37	6	6	NUM
br86b27956f	14	38	)	)	PUNCT
br86b27956f	14	39	.	.	PUNCT
br86b27956f	15	1	in	in	ADP
br86b27956f	15	2	particular	particular	ADJ
br86b27956f	15	3	,	,	PUNCT
br86b27956f	15	4	we	we	PRON
br86b27956f	15	5	reasoned	reason	VERB
br86b27956f	15	6	that	that	SCONJ
br86b27956f	15	7	aggregates	aggregate	NOUN
br86b27956f	15	8	containing	contain	VERB
br86b27956f	15	9	the	the	DET
br86b27956f	15	10	larger	large	ADJ
br86b27956f	15	11	alkali	alkali	ADJ
br86b27956f	15	12	metals	metal	NOUN
br86b27956f	15	13	were	be	AUX
br86b27956f	15	14	appealing	appeal	VERB
br86b27956f	15	15	candidates	candidate	NOUN
br86b27956f	15	16	as	as	ADV
br86b27956f	15	17	sbus	sbus	ADJ
br86b27956f	15	18	for	for	ADP
br86b27956f	15	19	high	high	ADJ
br86b27956f	15	20	-	-	PUNCT
br86b27956f	15	21	connectivity	connectivity	NOUN
br86b27956f	15	22	systems	system	NOUN
br86b27956f	15	23	since	since	SCONJ
br86b27956f	15	24	they	they	PRON
br86b27956f	15	25	should	should	AUX
br86b27956f	15	26	allow	allow	VERB
br86b27956f	15	27	multiple	multiple	ADJ
br86b27956f	15	28	sites	site	NOUN
br86b27956f	15	29	for	for	ADP
br86b27956f	15	30	network	network	NOUN
br86b27956f	15	31	extension	extension	NOUN
br86b27956f	15	32	(	(	PUNCT
br86b27956f	15	33	increased	increase	VERB
br86b27956f	15	34	metal	metal	NOUN
br86b27956f	15	35	solvation	solvation	NOUN
br86b27956f	15	36	)	)	PUNCT
br86b27956f	15	37	,	,	PUNCT
br86b27956f	15	38	leading	lead	VERB
br86b27956f	15	39	to	to	ADP
br86b27956f	15	40	interesting	interesting	ADJ
br86b27956f	15	41	or	or	CCONJ
br86b27956f	15	42	novel	novel	ADJ
br86b27956f	15	43	network	network	NOUN
br86b27956f	15	44	topologies	topology	NOUN
br86b27956f	15	45	.	.	PUNCT
br86b27956f	16	1	ring	ring	NOUN
br86b27956f	16	2	and	and	CCONJ
br86b27956f	16	3	cage	cage	NOUN
br86b27956f	16	4	aggregates	aggregate	NOUN
br86b27956f	16	5	containing	contain	VERB
br86b27956f	16	6	the	the	DET
br86b27956f	16	7	large	large	ADJ
br86b27956f	16	8	alkali	alkali	ADJ
br86b27956f	16	9	metals	metal	NOUN
br86b27956f	16	10	potassium	potassium	NOUN
br86b27956f	16	11	or	or	CCONJ
br86b27956f	16	12	rubidium	rubidium	NOUN
br86b27956f	16	13	have	have	AUX
br86b27956f	16	14	proven	prove	VERB
br86b27956f	16	15	to	to	PART
br86b27956f	16	16	be	be	AUX
br86b27956f	16	17	excellent	excellent	ADJ
br86b27956f	16	18	building	building	NOUN
br86b27956f	16	19	blocks	block	NOUN
br86b27956f	16	20	for	for	ADP
br86b27956f	16	21	the	the	DET
br86b27956f	16	22	creation	creation	NOUN
br86b27956f	16	23	of	of	ADP
br86b27956f	16	24	high	high	ADJ
br86b27956f	16	25	-	-	PUNCT
br86b27956f	16	26	connectivity	connectivity	NOUN
br86b27956f	16	27	nets	net	NOUN
br86b27956f	16	28	,	,	PUNCT
br86b27956f	16	29	as	as	SCONJ
br86b27956f	16	30	demonstrated	demonstrate	VERB
br86b27956f	16	31	by	by	ADP
br86b27956f	16	32	their	their	PRON
br86b27956f	16	33	use	use	NOUN
br86b27956f	16	34	as	as	ADP
br86b27956f	16	35	septahedral	septahedral	ADJ
br86b27956f	16	36	and	and	CCONJ
br86b27956f	16	37	nonahedral	nonahedral	ADJ
br86b27956f	16	38	nodes	node	NOUN
br86b27956f	16	39	.	.	PUNCT
br86b27956f	17	1	highlights	highlight	NOUN
br86b27956f	17	2	from	from	ADP
br86b27956f	17	3	this	this	DET
br86b27956f	17	4	work	work	NOUN
br86b27956f	17	5	include	include	VERB
br86b27956f	17	6	the	the	DET
br86b27956f	17	7	characterization	characterization	NOUN
br86b27956f	17	8	of	of	ADP
br86b27956f	17	9	[	[	X
br86b27956f	17	10	(	(	PUNCT
br86b27956f	17	11	4	4	NUM
br86b27956f	17	12	-	-	PUNCT
br86b27956f	17	13	cl-2,6	cl-2,6	PROPN
br86b27956f	17	14	-	-	PUNCT
br86b27956f	17	15	me2	me2	NOUN
br86b27956f	17	16	-	-	PUNCT
br86b27956f	17	17	c6h2ok)2ì¢	c6h2ok)2ì¢	PROPN
br86b27956f	17	18	ââå¢(dioxane)3.5	ââå¢(dioxane)3.5	SPACE
br86b27956f	17	19	]	]	PUNCT
br86b27956f	17	20	and	and	CCONJ
br86b27956f	17	21	[	[	X
br86b27956f	17	22	(	(	PUNCT
br86b27956f	17	23	2,4,6	2,4,6	PROPN
br86b27956f	17	24	-	-	PUNCT
br86b27956f	17	25	me3	me3	SPACE
br86b27956f	17	26	-	-	ADJ
br86b27956f	17	27	c6h2ok)5ì¢	c6h2ok)5ì¢	PROPN
br86b27956f	17	28	ââå¢(dioxane)5	ââå¢(dioxane)5	NOUN
br86b27956f	17	29	]	]	PUNCT
br86b27956f	17	30	,	,	PUNCT
br86b27956f	17	31	which	which	PRON
br86b27956f	17	32	form	form	VERB
br86b27956f	17	33	two	two	NUM
br86b27956f	17	34	new	new	ADJ
br86b27956f	17	35	types	type	NOUN
br86b27956f	17	36	of	of	ADP
br86b27956f	17	37	7	7	NUM
br86b27956f	17	38	-	-	PUNCT
br86b27956f	17	39	connected	connect	VERB
br86b27956f	17	40	nets	net	NOUN
br86b27956f	17	41	,	,	PUNCT
br86b27956f	17	42	and	and	CCONJ
br86b27956f	17	43	[	[	X
br86b27956f	17	44	2	2	NUM
br86b27956f	17	45	-	-	PUNCT
br86b27956f	17	46	ipr	ipr	PROPN
br86b27956f	17	47	-	-	PUNCT
br86b27956f	17	48	c6h4orb)6ì¢	c6h4orb)6ì¢	X
br86b27956f	17	49	ââå¢(dioxane)4.5	ââå¢(dioxane)4.5	SPACE
br86b27956f	17	50	]	]	PUNCT
br86b27956f	17	51	,	,	PUNCT
br86b27956f	17	52	which	which	PRON
br86b27956f	17	53	is	be	AUX
br86b27956f	17	54	the	the	DET
br86b27956f	17	55	first	first	ADJ
br86b27956f	17	56	ever	ever	ADV
br86b27956f	17	57	example	example	NOUN
br86b27956f	17	58	of	of	ADP
br86b27956f	17	59	a	a	DET
br86b27956f	17	60	9	9	NUM
br86b27956f	17	61	-	-	PUNCT
br86b27956f	17	62	connected	connect	VERB
br86b27956f	17	63	net	net	NOUN
br86b27956f	17	64	.	.	PUNCT
br86b27956f	18	1	an	an	DET
br86b27956f	18	2	expected	expect	VERB
br86b27956f	18	3	finding	finding	NOUN
br86b27956f	18	4	during	during	ADP
br86b27956f	18	5	the	the	DET
br86b27956f	18	6	study	study	NOUN
br86b27956f	18	7	of	of	ADP
br86b27956f	18	8	the	the	DET
br86b27956f	18	9	potassium	potassium	NOUN
br86b27956f	18	10	2	2	NUM
br86b27956f	18	11	-	-	PUNCT
br86b27956f	18	12	tert	tert	NOUN
br86b27956f	18	13	-	-	PUNCT
br86b27956f	18	14	butylphenoxide	butylphenoxide	NOUN
br86b27956f	18	15	system	system	NOUN
br86b27956f	18	16	was	be	AUX
br86b27956f	18	17	the	the	DET
br86b27956f	18	18	encapsulation	encapsulation	NOUN
br86b27956f	18	19	of	of	ADP
br86b27956f	18	20	molecular	molecular	ADJ
br86b27956f	18	21	water	water	NOUN
br86b27956f	18	22	inside	inside	ADP
br86b27956f	18	23	a	a	DET
br86b27956f	18	24	k6o6	k6o6	PROPN
br86b27956f	18	25	hexameric	hexameric	PROPN
br86b27956f	18	26	drum	drum	PROPN
br86b27956f	18	27	,	,	PUNCT
br86b27956f	18	28	forming	form	VERB
br86b27956f	18	29	[	[	X
br86b27956f	18	30	{	{	PUNCT
br86b27956f	18	31	(	(	PUNCT
br86b27956f	18	32	2	2	NUM
br86b27956f	18	33	-	-	PUNCT
br86b27956f	18	34	tbu	tbu	NOUN
br86b27956f	18	35	-	-	PUNCT
br86b27956f	18	36	c6h4ok)6(h2o)}ì¢	c6h4ok)6(h2o)}ì¢	PROPN
br86b27956f	18	37	ââå¢(dioxane)4	ââå¢(dioxane)4	NOUN
br86b27956f	18	38	]	]	PUNCT
br86b27956f	18	39	.	.	PUNCT
br86b27956f	19	1	encapsulation	encapsulation	NOUN
br86b27956f	19	2	of	of	ADP
br86b27956f	19	3	neutral	neutral	ADJ
br86b27956f	19	4	molecules	molecule	NOUN
br86b27956f	19	5	within	within	ADP
br86b27956f	19	6	alkali	alkali	ADJ
br86b27956f	19	7	metal	metal	NOUN
br86b27956f	19	8	aggregates	aggregate	NOUN
br86b27956f	19	9	is	be	AUX
br86b27956f	19	10	rare	rare	ADJ
br86b27956f	19	11	.	.	PUNCT
br86b27956f	20	1	the	the	DET
br86b27956f	20	2	scope	scope	NOUN
br86b27956f	20	3	and	and	CCONJ
br86b27956f	20	4	cause	cause	NOUN
br86b27956f	20	5	of	of	ADP
br86b27956f	20	6	this	this	DET
br86b27956f	20	7	unusual	unusual	ADJ
br86b27956f	20	8	behavior	behavior	NOUN
br86b27956f	20	9	was	be	AUX
br86b27956f	20	10	studied	study	VERB
br86b27956f	20	11	in	in	ADP
br86b27956f	20	12	detail	detail	NOUN
br86b27956f	20	13	(	(	PUNCT
br86b27956f	20	14	chapter	chapter	NOUN
br86b27956f	20	15	5	5	NUM
br86b27956f	20	16	)	)	PUNCT
br86b27956f	20	17	.	.	PUNCT
br86b27956f	21	1	the	the	DET
br86b27956f	21	2	final	final	ADJ
br86b27956f	21	3	part	part	NOUN
br86b27956f	21	4	of	of	ADP
br86b27956f	21	5	the	the	DET
br86b27956f	21	6	dissertation	dissertation	NOUN
br86b27956f	21	7	explores	explore	VERB
br86b27956f	21	8	the	the	DET
br86b27956f	21	9	synthesis	synthesis	NOUN
br86b27956f	21	10	of	of	ADP
br86b27956f	21	11	organometallic	organometallic	ADJ
br86b27956f	21	12	polymers	polymer	NOUN
br86b27956f	21	13	assembled	assemble	VERB
br86b27956f	21	14	from	from	ADP
br86b27956f	21	15	cation	cation	NOUN
br86b27956f	21	16	-	-	PUNCT
br86b27956f	21	17	pi	pi	NOUN
br86b27956f	21	18	interactions	interaction	NOUN
br86b27956f	21	19	(	(	PUNCT
br86b27956f	21	20	chapter	chapter	NOUN
br86b27956f	21	21	7	7	NUM
br86b27956f	21	22	)	)	PUNCT
br86b27956f	21	23	.	.	PUNCT
br86b27956f	22	1	the	the	DET
br86b27956f	22	2	objective	objective	NOUN
br86b27956f	22	3	was	be	AUX
br86b27956f	22	4	to	to	PART
br86b27956f	22	5	utilize	utilize	VERB
br86b27956f	22	6	ferrocene	ferrocene	NOUN
br86b27956f	22	7	,	,	PUNCT
br86b27956f	22	8	the	the	DET
br86b27956f	22	9	prototypical	prototypical	ADJ
br86b27956f	22	10	metallocene	metallocene	NOUN
br86b27956f	22	11	,	,	PUNCT
br86b27956f	22	12	as	as	ADP
br86b27956f	22	13	a	a	DET
br86b27956f	22	14	neutral	neutral	ADJ
br86b27956f	22	15	,	,	PUNCT
br86b27956f	22	16	linear	linear	ADJ
br86b27956f	22	17	,	,	PUNCT
br86b27956f	22	18	ditopic	ditopic	PROPN
br86b27956f	22	19	pi	pi	PROPN
br86b27956f	22	20	-	-	PUNCT
br86b27956f	22	21	linker	linker	NOUN
br86b27956f	22	22	to	to	ADP
br86b27956f	22	23	bridge	bridge	NOUN
br86b27956f	22	24	between	between	ADP
br86b27956f	22	25	preformed	preform	VERB
br86b27956f	22	26	alkali	alkali	ADJ
br86b27956f	22	27	metal	metal	NOUN
br86b27956f	22	28	aggregates	aggregate	NOUN
br86b27956f	22	29	the	the	DET
br86b27956f	22	30	combination	combination	NOUN
br86b27956f	22	31	of	of	ADP
br86b27956f	22	32	m(hmds	m(hmds	NOUN
br86b27956f	22	33	)	)	PUNCT
br86b27956f	22	34	,	,	PUNCT
br86b27956f	22	35	where	where	SCONJ
br86b27956f	22	36	m	m	VERB
br86b27956f	22	37	=	=	X
br86b27956f	22	38	na	na	PROPN
br86b27956f	22	39	,	,	PUNCT
br86b27956f	22	40	k	k	PROPN
br86b27956f	22	41	,	,	PUNCT
br86b27956f	22	42	rb	rb	PROPN
br86b27956f	22	43	,	,	PUNCT
br86b27956f	22	44	cs	cs	PROPN
br86b27956f	22	45	,	,	PUNCT
br86b27956f	22	46	with	with	ADP
br86b27956f	22	47	ferrocene	ferrocene	NOUN
br86b27956f	22	48	gives	gives	AUX
br86b27956f	22	49	rise	rise	VERB
br86b27956f	22	50	to	to	ADP
br86b27956f	22	51	one	one	NUM
br86b27956f	22	52	-	-	PUNCT
br86b27956f	22	53	dimensional	dimensional	ADJ
br86b27956f	22	54	polymeric	polymeric	ADJ
br86b27956f	22	55	chains	chain	NOUN
br86b27956f	22	56	of	of	ADP
br86b27956f	22	57	dimeric	dimeric	ADJ
br86b27956f	22	58	ring	ring	NOUN
br86b27956f	22	59	amides	amide	NOUN
br86b27956f	22	60	bridged	bridge	VERB
br86b27956f	22	61	through	through	ADP
br86b27956f	22	62	ferrocene	ferrocene	NOUN
br86b27956f	22	63	.	.	PUNCT
br86b27956f	23	1	in	in	ADP
br86b27956f	23	2	addition	addition	NOUN
br86b27956f	23	3	,	,	PUNCT
br86b27956f	23	4	the	the	DET
br86b27956f	23	5	rubidium	rubidium	NOUN
br86b27956f	23	6	and	and	CCONJ
br86b27956f	23	7	cesium	cesium	NOUN
br86b27956f	23	8	analogues	analogue	NOUN
br86b27956f	23	9	have	have	VERB
br86b27956f	23	10	close	close	ADJ
br86b27956f	23	11	intermolecular	intermolecular	ADJ
br86b27956f	23	12	agostic	agostic	ADJ
br86b27956f	23	13	interactions	interaction	NOUN
br86b27956f	23	14	with	with	ADP
br86b27956f	23	15	neighboring	neighboring	NOUN
br86b27956f	23	16	chains	chain	NOUN
br86b27956f	23	17	,	,	PUNCT
br86b27956f	23	18	such	such	ADJ
br86b27956f	23	19	that	that	SCONJ
br86b27956f	23	20	the	the	DET
br86b27956f	23	21	supramolecular	supramolecular	ADJ
br86b27956f	23	22	structures	structure	NOUN
br86b27956f	23	23	may	may	AUX
br86b27956f	23	24	be	be	AUX
br86b27956f	23	25	considered	consider	VERB
br86b27956f	23	26	as	as	ADP
br86b27956f	23	27	two	two	NUM
br86b27956f	23	28	-	-	PUNCT
br86b27956f	23	29	dimensional	dimensional	ADJ
br86b27956f	23	30	square	square	ADJ
br86b27956f	23	31	planar	planar	ADJ
br86b27956f	23	32	nets	net	NOUN
br86b27956f	23	33	.	.	PUNCT
br86b27956f	24	1	these	these	DET
br86b27956f	24	2	studies	study	NOUN
br86b27956f	24	3	demonstrate	demonstrate	VERB
br86b27956f	24	4	that	that	SCONJ
br86b27956f	24	5	cation	cation	NOUN
br86b27956f	24	6	-	-	PUNCT
br86b27956f	24	7	pi	pi	NOUN
br86b27956f	24	8	interactions	interaction	NOUN
br86b27956f	24	9	can	can	AUX
br86b27956f	24	10	be	be	AUX
br86b27956f	24	11	used	use	VERB
br86b27956f	24	12	to	to	PART
br86b27956f	24	13	rationally	rationally	ADV
br86b27956f	24	14	build	build	VERB
br86b27956f	24	15	extended	extended	ADJ
br86b27956f	24	16	networks	network	NOUN
br86b27956f	24	17	using	use	VERB
br86b27956f	24	18	appropriate	appropriate	ADJ
br86b27956f	24	19	conditions	condition	NOUN
br86b27956f	24	20	.	.	PUNCT