id sid tid token lemma pos bc386h4634k 1 1 the the DET bc386h4634k 1 2 role role NOUN bc386h4634k 1 3 of of ADP bc386h4634k 1 4 electron electron NOUN bc386h4634k 1 5 transfer transfer NOUN bc386h4634k 1 6 between between ADP bc386h4634k 1 7 metal metal NOUN bc386h4634k 1 8 catalyst catalyst NOUN bc386h4634k 1 9 and and CCONJ bc386h4634k 1 10 its its PRON bc386h4634k 1 11 oxide oxide NOUN bc386h4634k 1 12 support support NOUN bc386h4634k 1 13 in in ADP bc386h4634k 1 14 modifying modify VERB bc386h4634k 1 15 the the DET bc386h4634k 1 16 binding binding NOUN bc386h4634k 1 17 of of ADP bc386h4634k 1 18 the the DET bc386h4634k 1 19 molecules molecule NOUN bc386h4634k 1 20 adsorbed adsorb VERB bc386h4634k 1 21 on on ADP bc386h4634k 1 22 the the DET bc386h4634k 1 23 catalyst catalyst NOUN bc386h4634k 1 24 surface surface NOUN bc386h4634k 1 25 is be AUX bc386h4634k 1 26 investigated investigate VERB bc386h4634k 1 27 using use VERB bc386h4634k 1 28 pt pt PROPN bc386h4634k 1 29 / / SYM bc386h4634k 1 30 tio2 tio2 X bc386h4634k 1 31 catalytic catalytic ADJ bc386h4634k 1 32 diode diode NOUN bc386h4634k 1 33 as as ADP bc386h4634k 1 34 a a DET bc386h4634k 1 35 novel novel ADJ bc386h4634k 1 36 model model NOUN bc386h4634k 1 37 catalyst catalyst NOUN bc386h4634k 1 38 system system NOUN bc386h4634k 1 39 . . PUNCT bc386h4634k 2 1 the the DET bc386h4634k 2 2 effect effect NOUN bc386h4634k 2 3 of of ADP bc386h4634k 2 4 electron electron NOUN bc386h4634k 2 5 transfer transfer NOUN bc386h4634k 2 6 is be AUX bc386h4634k 2 7 interpreted interpret VERB bc386h4634k 2 8 and and CCONJ bc386h4634k 2 9 demonstrated demonstrate VERB bc386h4634k 2 10 as as ADP bc386h4634k 2 11 that that PRON bc386h4634k 2 12 of of ADP bc386h4634k 2 13 creating create VERB bc386h4634k 2 14 an an DET bc386h4634k 2 15 electric electric ADJ bc386h4634k 2 16 field field NOUN bc386h4634k 2 17 at at ADP bc386h4634k 2 18 the the DET bc386h4634k 2 19 metal metal NOUN bc386h4634k 2 20 - - PUNCT bc386h4634k 2 21 support support NOUN bc386h4634k 2 22 interface interface NOUN bc386h4634k 2 23 . . PUNCT bc386h4634k 3 1 the the DET bc386h4634k 3 2 effect effect NOUN bc386h4634k 3 3 of of ADP bc386h4634k 3 4 such such ADJ bc386h4634k 3 5 electric electric ADJ bc386h4634k 3 6 fields field NOUN bc386h4634k 3 7 is be AUX bc386h4634k 3 8 studied study VERB bc386h4634k 3 9 by by ADP bc386h4634k 3 10 using use VERB bc386h4634k 3 11 density density NOUN bc386h4634k 3 12 functional functional ADJ bc386h4634k 3 13 theory theory NOUN bc386h4634k 3 14 ( ( PUNCT bc386h4634k 3 15 dft dft NOUN bc386h4634k 3 16 ) ) PUNCT bc386h4634k 3 17 calculations calculation NOUN bc386h4634k 3 18 to to PART bc386h4634k 3 19 simulate simulate VERB bc386h4634k 3 20 adsorption adsorption NOUN bc386h4634k 3 21 of of ADP bc386h4634k 3 22 different different ADJ bc386h4634k 3 23 molecules molecule NOUN bc386h4634k 3 24 under under ADP bc386h4634k 3 25 a a DET bc386h4634k 3 26 uniform uniform ADJ bc386h4634k 3 27 external external ADJ bc386h4634k 3 28 electric electric ADJ bc386h4634k 3 29 field field NOUN bc386h4634k 3 30 . . PUNCT bc386h4634k 4 1 experimentally experimentally ADV bc386h4634k 4 2 , , PUNCT bc386h4634k 4 3 the the DET bc386h4634k 4 4 charge charge NOUN bc386h4634k 4 5 transfer transfer NOUN bc386h4634k 4 6 at at ADP bc386h4634k 4 7 metal metal NOUN bc386h4634k 4 8 support support NOUN bc386h4634k 4 9 junction junction NOUN bc386h4634k 4 10 and and CCONJ bc386h4634k 4 11 the the DET bc386h4634k 4 12 resulting result VERB bc386h4634k 4 13 electric electric ADJ bc386h4634k 4 14 field field NOUN bc386h4634k 4 15 is be AUX bc386h4634k 4 16 controlled control VERB bc386h4634k 4 17 by by ADP bc386h4634k 4 18 applying apply VERB bc386h4634k 4 19 an an DET bc386h4634k 4 20 external external ADJ bc386h4634k 4 21 bias bias NOUN bc386h4634k 4 22 voltage voltage NOUN bc386h4634k 4 23 to to ADP bc386h4634k 4 24 the the DET bc386h4634k 4 25 catalytic catalytic ADJ bc386h4634k 4 26 diode diode NOUN bc386h4634k 4 27 . . PUNCT bc386h4634k 5 1 the the DET bc386h4634k 5 2 effect effect NOUN bc386h4634k 5 3 of of ADP bc386h4634k 5 4 controlling control VERB bc386h4634k 5 5 the the DET bc386h4634k 5 6 charge charge NOUN bc386h4634k 5 7 transfer transfer NOUN bc386h4634k 5 8 on on ADP bc386h4634k 5 9 co co NOUN bc386h4634k 5 10 molecules molecule NOUN bc386h4634k 5 11 used use VERB bc386h4634k 5 12 as as SCONJ bc386h4634k 5 13 probe probe NOUN bc386h4634k 5 14 adsorbates adsorbate NOUN bc386h4634k 5 15 is be AUX bc386h4634k 5 16 studied study VERB bc386h4634k 5 17 using use VERB bc386h4634k 5 18 a a DET bc386h4634k 5 19 multilayer multilayer ADJ bc386h4634k 5 20 enhanced enhance VERB bc386h4634k 5 21 reflection reflection NOUN bc386h4634k 5 22 adsorption adsorption NOUN bc386h4634k 5 23 spectroscopy spectroscopy NOUN bc386h4634k 5 24 ( ( PUNCT bc386h4634k 5 25 meiras meiras PROPN bc386h4634k 5 26 ) ) PUNCT bc386h4634k 5 27 technique technique NOUN bc386h4634k 5 28 developed develop VERB bc386h4634k 5 29 in in ADP bc386h4634k 5 30 this this DET bc386h4634k 5 31 work work NOUN bc386h4634k 5 32 . . PUNCT bc386h4634k 6 1 dft dft NOUN bc386h4634k 6 2 calculations calculation NOUN bc386h4634k 6 3 show show VERB bc386h4634k 6 4 that that SCONJ bc386h4634k 6 5 the the DET bc386h4634k 6 6 sensitivity sensitivity NOUN bc386h4634k 6 7 of of ADP bc386h4634k 6 8 adsorption adsorption NOUN bc386h4634k 6 9 energy energy NOUN bc386h4634k 6 10 of of ADP bc386h4634k 6 11 a a DET bc386h4634k 6 12 molecule molecule NOUN bc386h4634k 6 13 on on ADP bc386h4634k 6 14 a a DET bc386h4634k 6 15 metal metal NOUN bc386h4634k 6 16 surface surface NOUN bc386h4634k 6 17 to to ADP bc386h4634k 6 18 the the DET bc386h4634k 6 19 external external ADJ bc386h4634k 6 20 electric electric ADJ bc386h4634k 6 21 field field NOUN bc386h4634k 6 22 depends depend VERB bc386h4634k 6 23 on on ADP bc386h4634k 6 24 its its PRON bc386h4634k 6 25 dipole dipole NOUN bc386h4634k 6 26 moment moment NOUN bc386h4634k 6 27 and and CCONJ bc386h4634k 6 28 polarizability polarizability NOUN bc386h4634k 6 29 . . PUNCT bc386h4634k 7 1 the the DET bc386h4634k 7 2 dipole dipole NOUN bc386h4634k 7 3 moment moment NOUN bc386h4634k 7 4 varies vary VERB bc386h4634k 7 5 significantly significantly ADV bc386h4634k 7 6 from from ADP bc386h4634k 7 7 one one NUM bc386h4634k 7 8 molecule molecule NOUN bc386h4634k 7 9 to to ADP bc386h4634k 7 10 another another PRON bc386h4634k 7 11 , , PUNCT bc386h4634k 7 12 and and CCONJ bc386h4634k 7 13 changes change NOUN bc386h4634k 7 14 with with ADP bc386h4634k 7 15 the the DET bc386h4634k 7 16 surface surface NOUN bc386h4634k 7 17 adsorbate adsorbate NOUN bc386h4634k 7 18 coverage coverage NOUN bc386h4634k 7 19 due due ADP bc386h4634k 7 20 to to ADP bc386h4634k 7 21 the the DET bc386h4634k 7 22 electrostatic electrostatic ADJ bc386h4634k 7 23 interaction interaction NOUN bc386h4634k 7 24 from from ADP bc386h4634k 7 25 neighboring neighboring NOUN bc386h4634k 7 26 adsorbates adsorbate NOUN bc386h4634k 7 27 on on ADP bc386h4634k 7 28 the the DET bc386h4634k 7 29 surface surface NOUN bc386h4634k 7 30 . . PUNCT bc386h4634k 8 1 vibrational vibrational ADJ bc386h4634k 8 2 frequency frequency NOUN bc386h4634k 8 3 of of ADP bc386h4634k 8 4 molecules molecule NOUN bc386h4634k 8 5 shifting shift VERB bc386h4634k 8 6 linearly linearly ADV bc386h4634k 8 7 with with SCONJ bc386h4634k 8 8 external external ADJ bc386h4634k 8 9 electric electric ADJ bc386h4634k 8 10 field field NOUN bc386h4634k 8 11 is be AUX bc386h4634k 8 12 shown show VERB bc386h4634k 8 13 to to PART bc386h4634k 8 14 be be AUX bc386h4634k 8 15 a a DET bc386h4634k 8 16 key key ADJ bc386h4634k 8 17 experimental experimental ADJ bc386h4634k 8 18 observable observable ADJ bc386h4634k 8 19 useful useful ADJ bc386h4634k 8 20 in in ADP bc386h4634k 8 21 the the DET bc386h4634k 8 22 study study NOUN bc386h4634k 8 23 of of ADP bc386h4634k 8 24 these these DET bc386h4634k 8 25 effects effect NOUN bc386h4634k 8 26 . . PUNCT bc386h4634k 9 1 meiras meiras PROPN bc386h4634k 9 2 is be AUX bc386h4634k 9 3 a a DET bc386h4634k 9 4 new new ADJ bc386h4634k 9 5 form form NOUN bc386h4634k 9 6 of of ADP bc386h4634k 9 7 the the DET bc386h4634k 9 8 fourier fourier NOUN bc386h4634k 9 9 transform transform NOUN bc386h4634k 9 10 infrared infrared ADJ bc386h4634k 9 11 ( ( PUNCT bc386h4634k 9 12 ftir ftir PROPN bc386h4634k 9 13 ) ) PUNCT bc386h4634k 9 14 spectroscopy spectroscopy NOUN bc386h4634k 9 15 performed perform VERB bc386h4634k 9 16 in in ADP bc386h4634k 9 17 reflection reflection NOUN bc386h4634k 9 18 mode mode NOUN bc386h4634k 9 19 , , PUNCT bc386h4634k 9 20 in in ADP bc386h4634k 9 21 which which PRON bc386h4634k 9 22 , , PUNCT bc386h4634k 9 23 the the DET bc386h4634k 9 24 multilayer multilayer PROPN bc386h4634k 9 25 structure structure NOUN bc386h4634k 9 26 of of ADP bc386h4634k 9 27 the the DET bc386h4634k 9 28 sample sample NOUN bc386h4634k 9 29 and and CCONJ bc386h4634k 9 30 its its PRON bc386h4634k 9 31 interaction interaction NOUN bc386h4634k 9 32 with with ADP bc386h4634k 9 33 the the DET bc386h4634k 9 34 incident incident NOUN bc386h4634k 9 35 infrared infrare VERB bc386h4634k 9 36 causes cause VERB bc386h4634k 9 37 a a DET bc386h4634k 9 38 large large ADJ bc386h4634k 9 39 enhancement enhancement NOUN bc386h4634k 9 40 in in ADP bc386h4634k 9 41 the the DET bc386h4634k 9 42 sensitivity sensitivity NOUN bc386h4634k 9 43 . . PUNCT bc386h4634k 10 1 the the DET bc386h4634k 10 2 mechanism mechanism NOUN bc386h4634k 10 3 of of ADP bc386h4634k 10 4 sensitivity sensitivity NOUN bc386h4634k 10 5 enhancement enhancement NOUN bc386h4634k 10 6 is be AUX bc386h4634k 10 7 elucidated elucidate VERB bc386h4634k 10 8 through through ADP bc386h4634k 10 9 experimental experimental ADJ bc386h4634k 10 10 measurement measurement NOUN bc386h4634k 10 11 of of ADP bc386h4634k 10 12 wavelength wavelength NOUN bc386h4634k 10 13 dependent dependent ADJ bc386h4634k 10 14 reflectance reflectance NOUN bc386h4634k 10 15 of of ADP bc386h4634k 10 16 multilayer multilayer ADJ bc386h4634k 10 17 structures structure NOUN bc386h4634k 10 18 and and CCONJ bc386h4634k 10 19 theoretical theoretical ADJ bc386h4634k 10 20 optical optical ADJ bc386h4634k 10 21 analysis analysis NOUN bc386h4634k 10 22 of of ADP bc386h4634k 10 23 infrared infrared ADJ bc386h4634k 10 24 reflection reflection NOUN bc386h4634k 10 25 on on ADP bc386h4634k 10 26 such such ADJ bc386h4634k 10 27 structures structure NOUN bc386h4634k 10 28 . . PUNCT bc386h4634k 11 1 an an DET bc386h4634k 11 2 experimental experimental ADJ bc386h4634k 11 3 setup setup NOUN bc386h4634k 11 4 is be AUX bc386h4634k 11 5 developed develop VERB bc386h4634k 11 6 for for ADP bc386h4634k 11 7 meiras meiras PROPN bc386h4634k 11 8 measurements measurement NOUN bc386h4634k 11 9 , , PUNCT bc386h4634k 11 10 and and CCONJ bc386h4634k 11 11 its its PRON bc386h4634k 11 12 application application NOUN bc386h4634k 11 13 for for ADP bc386h4634k 11 14 study study NOUN bc386h4634k 11 15 of of ADP bc386h4634k 11 16 co co NOUN bc386h4634k 11 17 adsorption adsorption NOUN bc386h4634k 11 18 on on ADP bc386h4634k 11 19 low low ADJ bc386h4634k 11 20 area area NOUN bc386h4634k 11 21 pt pt PROPN bc386h4634k 11 22 thin thin ADJ bc386h4634k 11 23 - - PUNCT bc386h4634k 11 24 film film NOUN bc386h4634k 11 25 and and CCONJ bc386h4634k 11 26 nanowire nanowire NOUN bc386h4634k 11 27 catalysts catalyst NOUN bc386h4634k 11 28 under under ADP bc386h4634k 11 29 in in ADP bc386h4634k 11 30 - - PUNCT bc386h4634k 11 31 situ situ NOUN bc386h4634k 11 32 and and CCONJ bc386h4634k 11 33 co co NOUN bc386h4634k 11 34 oxidation oxidation NOUN bc386h4634k 11 35 reaction reaction NOUN bc386h4634k 11 36 conditions condition NOUN bc386h4634k 11 37 is be AUX bc386h4634k 11 38 demonstrated demonstrate VERB bc386h4634k 11 39 . . PUNCT bc386h4634k 12 1 the the DET bc386h4634k 12 2 effect effect NOUN bc386h4634k 12 3 of of ADP bc386h4634k 12 4 external external ADJ bc386h4634k 12 5 voltage voltage NOUN bc386h4634k 12 6 applied apply VERB bc386h4634k 12 7 to to PART bc386h4634k 12 8 induce induce VERB bc386h4634k 12 9 charge charge NOUN bc386h4634k 12 10 transfer transfer NOUN bc386h4634k 12 11 between between ADP bc386h4634k 12 12 metal metal NOUN bc386h4634k 12 13 - - PUNCT bc386h4634k 12 14 support support NOUN bc386h4634k 12 15 junctions junction NOUN bc386h4634k 12 16 in in ADP bc386h4634k 12 17 a a DET bc386h4634k 12 18 multilayer multilayer NOUN bc386h4634k 12 19 thin thin ADJ bc386h4634k 12 20 - - PUNCT bc386h4634k 12 21 film film NOUN bc386h4634k 12 22 pt pt PROPN bc386h4634k 12 23 / / SYM bc386h4634k 12 24 tio2 tio2 X bc386h4634k 12 25 catalytic catalytic ADJ bc386h4634k 12 26 diode diode NOUN bc386h4634k 12 27 on on ADP bc386h4634k 12 28 adsorbed adsorb VERB bc386h4634k 12 29 co co NOUN bc386h4634k 12 30 molecules molecule NOUN bc386h4634k 12 31 is be AUX bc386h4634k 12 32 studied study VERB bc386h4634k 12 33 using use VERB bc386h4634k 12 34 meiras meira NOUN bc386h4634k 12 35 . . PUNCT bc386h4634k 13 1 the the DET bc386h4634k 13 2 bias bias NOUN bc386h4634k 13 3 voltage voltage NOUN bc386h4634k 13 4 causes cause VERB bc386h4634k 13 5 a a DET bc386h4634k 13 6 reversible reversible ADJ bc386h4634k 13 7 shift shift NOUN bc386h4634k 13 8 in in ADP bc386h4634k 13 9 the the DET bc386h4634k 13 10 vibrational vibrational ADJ bc386h4634k 13 11 frequency frequency NOUN bc386h4634k 13 12 of of ADP bc386h4634k 13 13 co co NOUN bc386h4634k 13 14 adsorbed adsorb VERB bc386h4634k 13 15 near near ADP bc386h4634k 13 16 pt pt PROPN bc386h4634k 13 17 / / SYM bc386h4634k 13 18 tio2 tio2 PROPN bc386h4634k 13 19 interfaces interface NOUN bc386h4634k 13 20 exposed expose VERB bc386h4634k 13 21 through through ADP bc386h4634k 13 22 the the DET bc386h4634k 13 23 cracks crack NOUN bc386h4634k 13 24 in in ADP bc386h4634k 13 25 the the DET bc386h4634k 13 26 pt pt PROPN bc386h4634k 13 27 film film NOUN bc386h4634k 13 28 . . PUNCT bc386h4634k 14 1 these these DET bc386h4634k 14 2 results result NOUN bc386h4634k 14 3 provide provide VERB bc386h4634k 14 4 a a DET bc386h4634k 14 5 direct direct ADJ bc386h4634k 14 6 demonstration demonstration NOUN bc386h4634k 14 7 of of ADP bc386h4634k 14 8 the the DET bc386h4634k 14 9 electronic electronic ADJ bc386h4634k 14 10 effects effect NOUN bc386h4634k 14 11 associated associate VERB bc386h4634k 14 12 with with ADP bc386h4634k 14 13 metal metal NOUN bc386h4634k 14 14 - - PUNCT bc386h4634k 14 15 support support NOUN bc386h4634k 14 16 junctions junction NOUN bc386h4634k 14 17 that that PRON bc386h4634k 14 18 have have AUX bc386h4634k 14 19 been be AUX bc386h4634k 14 20 extensively extensively ADV bc386h4634k 14 21 discussed discuss VERB bc386h4634k 14 22 and and CCONJ bc386h4634k 14 23 debated debate VERB bc386h4634k 14 24 in in ADP bc386h4634k 14 25 the the DET bc386h4634k 14 26 catalysis catalysis NOUN bc386h4634k 14 27 literature literature NOUN bc386h4634k 14 28 . . PUNCT bc386h4634k 15 1 nanofabrication nanofabrication NOUN bc386h4634k 15 2 techniques technique NOUN bc386h4634k 15 3 are be AUX bc386h4634k 15 4 used use VERB bc386h4634k 15 5 to to PART bc386h4634k 15 6 prepare prepare VERB bc386h4634k 15 7 regular regular ADJ bc386h4634k 15 8 arrays array NOUN bc386h4634k 15 9 of of ADP bc386h4634k 15 10 uniform uniform NOUN bc386h4634k 15 11 and and CCONJ bc386h4634k 15 12 parallel parallel ADJ bc386h4634k 15 13 pt pt PROPN bc386h4634k 15 14 nanowires nanowire NOUN bc386h4634k 15 15 on on ADP bc386h4634k 15 16 tio2 tio2 NOUN bc386h4634k 15 17 in in ADP bc386h4634k 15 18 order order NOUN bc386h4634k 15 19 to to PART bc386h4634k 15 20 control control VERB bc386h4634k 15 21 the the DET bc386h4634k 15 22 fraction fraction NOUN bc386h4634k 15 23 of of ADP bc386h4634k 15 24 pt pt PROPN bc386h4634k 15 25 / / SYM bc386h4634k 15 26 tio2 tio2 PROPN bc386h4634k 15 27 interfaces interface VERB bc386h4634k 15 28 while while SCONJ bc386h4634k 15 29 maintaining maintain VERB bc386h4634k 15 30 electrical electrical ADJ bc386h4634k 15 31 continuity continuity NOUN bc386h4634k 15 32 in in ADP bc386h4634k 15 33 the the DET bc386h4634k 15 34 pt pt PROPN bc386h4634k 15 35 layer layer NOUN bc386h4634k 15 36 . . PUNCT bc386h4634k 16 1 such such ADJ bc386h4634k 16 2 nanostructures nanostructure NOUN bc386h4634k 16 3 incorporated incorporate VERB bc386h4634k 16 4 in in ADP bc386h4634k 16 5 a a DET bc386h4634k 16 6 catalytic catalytic ADJ bc386h4634k 16 7 diode diode NOUN bc386h4634k 16 8 can can AUX bc386h4634k 16 9 provide provide VERB bc386h4634k 16 10 a a DET bc386h4634k 16 11 better well ADJ bc386h4634k 16 12 control control NOUN bc386h4634k 16 13 of of ADP bc386h4634k 16 14 electron electron NOUN bc386h4634k 16 15 - - PUNCT bc386h4634k 16 16 transfer transfer NOUN bc386h4634k 16 17 effects effect NOUN bc386h4634k 16 18 due due ADJ bc386h4634k 16 19 to to ADP bc386h4634k 16 20 larger large ADJ bc386h4634k 16 21 fractions fraction NOUN bc386h4634k 16 22 of of ADP bc386h4634k 16 23 exposed expose VERB bc386h4634k 16 24 pt pt PROPN bc386h4634k 16 25 / / SYM bc386h4634k 16 26 tio2 tio2 PROPN bc386h4634k 16 27 interfaces interface NOUN bc386h4634k 16 28 and and CCONJ bc386h4634k 16 29 potentially potentially ADV bc386h4634k 16 30 lead lead VERB bc386h4634k 16 31 to to ADP bc386h4634k 16 32 tuning tuning NOUN bc386h4634k 16 33 of of ADP bc386h4634k 16 34 catalytic catalytic ADJ bc386h4634k 16 35 activity activity NOUN bc386h4634k 16 36 in in ADP bc386h4634k 16 37 supported support VERB bc386h4634k 16 38 catalysts catalyst NOUN bc386h4634k 16 39 using use VERB bc386h4634k 16 40 bias bias NOUN bc386h4634k 16 41 voltages voltage NOUN bc386h4634k 16 42 . . PUNCT