id	sid	tid	token	lemma	pos
9s161546d9g	1	1	part	part	NOUN
9s161546d9g	1	2	1	1	NUM
9s161546d9g	1	3	:	:	PUNCT
9s161546d9g	1	4	the	the	DET
9s161546d9g	1	5	tetradentate	tetradentate	NOUN
9s161546d9g	1	6	ligand	ligand	NOUN
9s161546d9g	1	7	tbucliph4	tbucliph4	NOUN
9s161546d9g	1	8	(	(	PUNCT
9s161546d9g	1	9	tbucliph4	tbucliph4	NOUN
9s161546d9g	1	10	=	=	PRON
9s161546d9g	1	11	4,4'-di	4,4'-di	NUM
9s161546d9g	1	12	-	-	PUNCT
9s161546d9g	1	13	tert	tert	PROPN
9s161546d9g	1	14	-	-	PUNCT
9s161546d9g	1	15	butyl	butyl	PROPN
9s161546d9g	1	16	-	-	PUNCT
9s161546d9g	1	17	n	n	PROPN
9s161546d9g	1	18	,	,	PUNCT
9s161546d9g	1	19	n'-bis(3,5	n'-bis(3,5	PROPN
9s161546d9g	1	20	-	-	PUNCT
9s161546d9g	1	21	di	di	NOUN
9s161546d9g	1	22	-	-	PUNCT
9s161546d9g	1	23	tert	tert	NOUN
9s161546d9g	1	24	-	-	PUNCT
9s161546d9g	1	25	butyl-2	butyl-2	PROPN
9s161546d9g	1	26	-	-	PUNCT
9s161546d9g	1	27	hydroxyphenyl)-2,2'-diaminobiphenyl	hydroxyphenyl)-2,2'-diaminobiphenyl	SPACE
9s161546d9g	1	28	)	)	PUNCT
9s161546d9g	1	29	forms	form	VERB
9s161546d9g	1	30	molybdenum(vi	molybdenum(vi	PROPN
9s161546d9g	1	31	)	)	PUNCT
9s161546d9g	1	32	complexes	complex	NOUN
9s161546d9g	1	33	with	with	ADP
9s161546d9g	1	34	a	a	DET
9s161546d9g	1	35	varying	vary	VERB
9s161546d9g	1	36	number	number	NOUN
9s161546d9g	1	37	(	(	PUNCT
9s161546d9g	1	38	0	0	NUM
9s161546d9g	1	39	-	-	SYM
9s161546d9g	1	40	2	2	NUM
9s161546d9g	1	41	)	)	PUNCT
9s161546d9g	1	42	of	of	ADP
9s161546d9g	1	43	terminal	terminal	ADJ
9s161546d9g	1	44	oxo	oxo	PROPN
9s161546d9g	1	45	groups	group	NOUN
9s161546d9g	1	46	.	.	PUNCT
9s161546d9g	2	1	the	the	DET
9s161546d9g	2	2	doubly	doubly	ADV
9s161546d9g	2	3	deprotonated	deprotonated	ADJ
9s161546d9g	2	4	cis	cis	NOUN
9s161546d9g	2	5	-	-	PUNCT
9s161546d9g	2	6	dioxo	dioxo	ADJ
9s161546d9g	2	7	complex	complex	NOUN
9s161546d9g	2	8	(	(	PUNCT
9s161546d9g	2	9	tbucliph2)moo2	tbucliph2)moo2	X
9s161546d9g	2	10	readily	readily	ADV
9s161546d9g	2	11	loses	lose	VERB
9s161546d9g	2	12	water	water	NOUN
9s161546d9g	2	13	to	to	PART
9s161546d9g	2	14	form	form	VERB
9s161546d9g	2	15	a	a	DET
9s161546d9g	2	16	series	series	NOUN
9s161546d9g	2	17	of	of	ADP
9s161546d9g	2	18	monooxo	monooxo	PROPN
9s161546d9g	2	19	complexes	complex	NOUN
9s161546d9g	2	20	(	(	PUNCT
9s161546d9g	2	21	tbuclip)moo(l	tbuclip)moo(l	SPACE
9s161546d9g	2	22	)	)	PUNCT
9s161546d9g	2	23	in	in	ADP
9s161546d9g	2	24	the	the	DET
9s161546d9g	2	25	presence	presence	NOUN
9s161546d9g	2	26	of	of	ADP
9s161546d9g	2	27	donor	donor	NOUN
9s161546d9g	2	28	ligands	ligand	NOUN
9s161546d9g	2	29	.	.	PUNCT
9s161546d9g	3	1	(	(	PUNCT
9s161546d9g	3	2	tbucliph2)moo2	tbucliph2)moo2	PRON
9s161546d9g	3	3	also	also	ADV
9s161546d9g	3	4	reacts	react	VERB
9s161546d9g	3	5	with	with	ADP
9s161546d9g	3	6	3,5	3,5	NUM
9s161546d9g	3	7	-	-	PUNCT
9s161546d9g	3	8	di	di	NOUN
9s161546d9g	3	9	-	-	PUNCT
9s161546d9g	3	10	tert	tert	NOUN
9s161546d9g	3	11	-	-	PUNCT
9s161546d9g	3	12	butylcatechol	butylcatechol	NOUN
9s161546d9g	3	13	to	to	PART
9s161546d9g	3	14	form	form	VERB
9s161546d9g	3	15	oxo	oxo	NOUN
9s161546d9g	3	16	-	-	PUNCT
9s161546d9g	3	17	free	free	ADJ
9s161546d9g	3	18	(	(	PUNCT
9s161546d9g	3	19	tbuclip)mo(3,5	tbuclip)mo(3,5	NOUN
9s161546d9g	3	20	-	-	PUNCT
9s161546d9g	3	21	tbu2cat	tbu2cat	NOUN
9s161546d9g	3	22	)	)	PUNCT
9s161546d9g	3	23	.	.	PUNCT
9s161546d9g	4	1	the	the	DET
9s161546d9g	4	2	facile	facile	NOUN
9s161546d9g	4	3	formation	formation	NOUN
9s161546d9g	4	4	and	and	CCONJ
9s161546d9g	4	5	interconversion	interconversion	NOUN
9s161546d9g	4	6	of	of	ADP
9s161546d9g	4	7	these	these	DET
9s161546d9g	4	8	species	specie	NOUN
9s161546d9g	4	9	highlights	highlight	VERB
9s161546d9g	4	10	the	the	DET
9s161546d9g	4	11	ability	ability	NOUN
9s161546d9g	4	12	of	of	ADP
9s161546d9g	4	13	the	the	DET
9s161546d9g	4	14	amidophenoxide	amidophenoxide	ADJ
9s161546d9g	4	15	ligand	ligand	NOUN
9s161546d9g	4	16	to	to	PART
9s161546d9g	4	17	stabilize	stabilize	VERB
9s161546d9g	4	18	the	the	DET
9s161546d9g	4	19	high	high	ADJ
9s161546d9g	4	20	-	-	PUNCT
9s161546d9g	4	21	valent	valent	ADJ
9s161546d9g	4	22	molybdenum	molybdenum	NOUN
9s161546d9g	4	23	metal	metal	NOUN
9s161546d9g	4	24	center	center	NOUN
9s161546d9g	4	25	by	by	ADP
9s161546d9g	4	26	strong	strong	ADJ
9s161546d9g	4	27	&	&	CCONJ
9s161546d9g	4	28	#	#	SYM
9s161546d9g	4	29	960;-donation	960;-donation	NUM
9s161546d9g	4	30	.	.	PUNCT
9s161546d9g	5	1	(	(	PUNCT
9s161546d9g	5	2	tbuclip)mo(3,5	tbuclip)mo(3,5	NOUN
9s161546d9g	5	3	-	-	PUNCT
9s161546d9g	5	4	tbu2cat	tbu2cat	NUM
9s161546d9g	5	5	)	)	PUNCT
9s161546d9g	5	6	has	have	VERB
9s161546d9g	5	7	lower	low	ADJ
9s161546d9g	5	8	lewis	lewis	PROPN
9s161546d9g	5	9	acidicity	acidicity	NOUN
9s161546d9g	5	10	compared	compare	VERB
9s161546d9g	5	11	to	to	ADP
9s161546d9g	5	12	oxo	oxo	NOUN
9s161546d9g	5	13	and	and	CCONJ
9s161546d9g	5	14	catecholate	catecholate	ADJ
9s161546d9g	5	15	analogues	analogue	NOUN
9s161546d9g	5	16	(	(	PUNCT
9s161546d9g	5	17	tbuclip)moo	tbuclip)moo	ADJ
9s161546d9g	5	18	,	,	PUNCT
9s161546d9g	5	19	mo(3,5	mo(3,5	PROPN
9s161546d9g	5	20	-	-	PUNCT
9s161546d9g	5	21	tbu2cat)3	tbu2cat)3	PROPN
9s161546d9g	5	22	,	,	PUNCT
9s161546d9g	5	23	and	and	CCONJ
9s161546d9g	5	24	(	(	PUNCT
9s161546d9g	5	25	3,5	3,5	NUM
9s161546d9g	5	26	-	-	PUNCT
9s161546d9g	5	27	tbu2cat)2moo	tbu2cat)2moo	NUM
9s161546d9g	5	28	,	,	PUNCT
9s161546d9g	5	29	which	which	PRON
9s161546d9g	5	30	is	be	AUX
9s161546d9g	5	31	apparent	apparent	ADJ
9s161546d9g	5	32	from	from	ADP
9s161546d9g	5	33	rates	rate	NOUN
9s161546d9g	5	34	of	of	ADP
9s161546d9g	5	35	pyridine	pyridine	NOUN
9s161546d9g	5	36	dissociation	dissociation	NOUN
9s161546d9g	5	37	.	.	PUNCT
9s161546d9g	6	1	these	these	DET
9s161546d9g	6	2	amidophenolate	amidophenolate	ADJ
9s161546d9g	6	3	ligands	ligand	NOUN
9s161546d9g	6	4	enable	enable	VERB
9s161546d9g	6	5	oxygen	oxygen	NOUN
9s161546d9g	6	6	atom	atom	NOUN
9s161546d9g	6	7	abstraction	abstraction	NOUN
9s161546d9g	6	8	by	by	ADP
9s161546d9g	6	9	the	the	DET
9s161546d9g	6	10	molybdenum(vi	molybdenum(vi	PROPN
9s161546d9g	6	11	)	)	PUNCT
9s161546d9g	6	12	in	in	ADP
9s161546d9g	6	13	a	a	DET
9s161546d9g	6	14	?	?	VERB
9s161546d9g	6	15	nonclassical	nonclassical	ADJ
9s161546d9g	6	16	?	?	PUNCT
9s161546d9g	6	17	fashion	fashion	NOUN
9s161546d9g	6	18	,	,	PUNCT
9s161546d9g	6	19	as	as	SCONJ
9s161546d9g	6	20	the	the	DET
9s161546d9g	6	21	required	require	VERB
9s161546d9g	6	22	reducing	reduce	VERB
9s161546d9g	6	23	equivalents	equivalent	NOUN
9s161546d9g	6	24	for	for	ADP
9s161546d9g	6	25	oxygen	oxygen	NOUN
9s161546d9g	6	26	reduction	reduction	NOUN
9s161546d9g	6	27	are	be	AUX
9s161546d9g	6	28	drawn	draw	VERB
9s161546d9g	6	29	from	from	ADP
9s161546d9g	6	30	ligand	ligand	NOUN
9s161546d9g	6	31	oxidation	oxidation	NOUN
9s161546d9g	6	32	and	and	CCONJ
9s161546d9g	6	33	not	not	PART
9s161546d9g	6	34	the	the	DET
9s161546d9g	6	35	molybdenum	molybdenum	NOUN
9s161546d9g	6	36	center	center	NOUN
9s161546d9g	6	37	.	.	PUNCT
9s161546d9g	7	1	this	this	PRON
9s161546d9g	7	2	generates	generate	VERB
9s161546d9g	7	3	a	a	DET
9s161546d9g	7	4	reactive	reactive	ADJ
9s161546d9g	7	5	intermediate	intermediate	NOUN
9s161546d9g	7	6	,	,	PUNCT
9s161546d9g	7	7	tentatively	tentatively	ADV
9s161546d9g	7	8	identified	identify	VERB
9s161546d9g	7	9	as	as	ADP
9s161546d9g	7	10	(	(	PUNCT
9s161546d9g	7	11	tbuclipsq)moo2	tbuclipsq)moo2	NOUN
9s161546d9g	7	12	,	,	PUNCT
9s161546d9g	7	13	with	with	ADP
9s161546d9g	7	14	oxidizing	oxidizing	NOUN
9s161546d9g	7	15	equivalents	equivalent	NOUN
9s161546d9g	7	16	stored	store	VERB
9s161546d9g	7	17	in	in	ADP
9s161546d9g	7	18	a	a	DET
9s161546d9g	7	19	bis	bis	ADJ
9s161546d9g	7	20	-	-	PUNCT
9s161546d9g	7	21	semiquinone	semiquinone	ADJ
9s161546d9g	7	22	ligand	ligand	NOUN
9s161546d9g	7	23	.	.	PUNCT
9s161546d9g	8	1	(	(	PUNCT
9s161546d9g	8	2	tbuclipsq)moo2	tbuclipsq)moo2	PRON
9s161546d9g	8	3	can	can	AUX
9s161546d9g	8	4	be	be	AUX
9s161546d9g	8	5	deoxygenated	deoxygenate	VERB
9s161546d9g	8	6	by	by	ADP
9s161546d9g	8	7	dimethylphenylphosphine	dimethylphenylphosphine	NOUN
9s161546d9g	8	8	,	,	PUNCT
9s161546d9g	8	9	establishing	establish	VERB
9s161546d9g	8	10	a	a	DET
9s161546d9g	8	11	closed	close	VERB
9s161546d9g	8	12	loop	loop	NOUN
9s161546d9g	8	13	cycle	cycle	NOUN
9s161546d9g	8	14	for	for	ADP
9s161546d9g	8	15	catalytic	catalytic	ADJ
9s161546d9g	8	16	oxygen	oxygen	NOUN
9s161546d9g	8	17	atom	atom	NOUN
9s161546d9g	8	18	transfer	transfer	NOUN
9s161546d9g	8	19	.	.	PUNCT
9s161546d9g	9	1	part	part	NOUN
9s161546d9g	9	2	2	2	NUM
9s161546d9g	9	3	:	:	PUNCT
9s161546d9g	9	4	silylation	silylation	NOUN
9s161546d9g	9	5	of	of	ADP
9s161546d9g	9	6	the	the	DET
9s161546d9g	9	7	oxidized	oxidized	ADJ
9s161546d9g	9	8	ligand	ligand	NOUN
9s161546d9g	9	9	in	in	ADP
9s161546d9g	9	10	lead(ii	lead(ii	PROPN
9s161546d9g	9	11	)	)	PUNCT
9s161546d9g	9	12	bis(3,5	bis(3,5	SPACE
9s161546d9g	9	13	-	-	PUNCT
9s161546d9g	9	14	di	di	PROPN
9s161546d9g	9	15	-	-	PUNCT
9s161546d9g	9	16	tert	tert	NOUN
9s161546d9g	9	17	-	-	PUNCT
9s161546d9g	9	18	butyl-1,2	butyl-1,2	PROPN
9s161546d9g	9	19	-	-	PUNCT
9s161546d9g	9	20	quinone-(3,5	quinone-(3,5	NOUN
9s161546d9g	9	21	-	-	PUNCT
9s161546d9g	9	22	di	di	NOUN
9s161546d9g	9	23	-	-	PUNCT
9s161546d9g	9	24	tert	tert	NOUN
9s161546d9g	9	25	-	-	PUNCT
9s161546d9g	9	26	butyl-2	butyl-2	ADJ
9s161546d9g	9	27	-	-	PUNCT
9s161546d9g	9	28	oxy-1	oxy-1	NOUN
9s161546d9g	9	29	-	-	PUNCT
9s161546d9g	9	30	phenyl)imine	phenyl)imine	ADJ
9s161546d9g	9	31	)	)	PUNCT
9s161546d9g	9	32	,	,	PUNCT
9s161546d9g	9	33	pb(onoq)2	pb(onoq)2	SPACE
9s161546d9g	9	34	,	,	PUNCT
9s161546d9g	9	35	with	with	ADP
9s161546d9g	9	36	chlorosilanes	chlorosilane	NOUN
9s161546d9g	9	37	rsix2cl	rsix2cl	PUNCT
9s161546d9g	9	38	(	(	PUNCT
9s161546d9g	9	39	r	r	NOUN
9s161546d9g	9	40	=	=	X
9s161546d9g	9	41	me	i	PRON
9s161546d9g	9	42	,	,	PUNCT
9s161546d9g	9	43	ph	ph	NOUN
9s161546d9g	9	44	;	;	PUNCT
9s161546d9g	9	45	x	x	PUNCT
9s161546d9g	9	46	=	=	X
9s161546d9g	9	47	me	i	PRON
9s161546d9g	9	48	,	,	PUNCT
9s161546d9g	9	49	ph	ph	PROPN
9s161546d9g	9	50	,	,	PUNCT
9s161546d9g	9	51	cl	cl	NOUN
9s161546d9g	9	52	)	)	PUNCT
9s161546d9g	9	53	results	result	NOUN
9s161546d9g	9	54	in	in	ADP
9s161546d9g	9	55	tetracyclic	tetracyclic	NOUN
9s161546d9g	9	56	,	,	PUNCT
9s161546d9g	9	57	pentacoordinate	pentacoordinate	NOUN
9s161546d9g	9	58	silicon	silicon	NOUN
9s161546d9g	9	59	compounds	compound	VERB
9s161546d9g	9	60	x(y)si(on[r]o	x(y)si(on[r]o	X
9s161546d9g	9	61	)	)	PUNCT
9s161546d9g	9	62	in	in	ADP
9s161546d9g	9	63	which	which	PRON
9s161546d9g	9	64	the	the	DET
9s161546d9g	9	65	aryloxyiminoquinone	aryloxyiminoquinone	NOUN
9s161546d9g	9	66	ligand	ligand	NOUN
9s161546d9g	9	67	is	be	AUX
9s161546d9g	9	68	irreversibly	irreversibly	ADV
9s161546d9g	9	69	reduced	reduce	VERB
9s161546d9g	9	70	.	.	PUNCT
9s161546d9g	10	1	the	the	DET
9s161546d9g	10	2	trigonal	trigonal	ADJ
9s161546d9g	10	3	bipyramidal	bipyramidal	ADJ
9s161546d9g	10	4	silicon	silicon	NOUN
9s161546d9g	10	5	products	product	NOUN
9s161546d9g	10	6	of	of	ADP
9s161546d9g	10	7	migration	migration	NOUN
9s161546d9g	10	8	in	in	ADP
9s161546d9g	10	9	some	some	DET
9s161546d9g	10	10	cases	case	NOUN
9s161546d9g	10	11	form	form	VERB
9s161546d9g	10	12	kinetic	kinetic	ADJ
9s161546d9g	10	13	isomers	isomer	NOUN
9s161546d9g	10	14	,	,	PUNCT
9s161546d9g	10	15	r(cl)si(on[r]o	r(cl)si(on[r]o	PROPN
9s161546d9g	10	16	)	)	PUNCT
9s161546d9g	10	17	with	with	ADP
9s161546d9g	10	18	an	an	DET
9s161546d9g	10	19	equatorial	equatorial	ADJ
9s161546d9g	10	20	chlorine	chlorine	NOUN
9s161546d9g	10	21	substituent	substituent	NOUN
9s161546d9g	10	22	,	,	PUNCT
9s161546d9g	10	23	which	which	PRON
9s161546d9g	10	24	isomerize	isomerize	VERB
9s161546d9g	10	25	to	to	ADP
9s161546d9g	10	26	their	their	PRON
9s161546d9g	10	27	thermodynamically	thermodynamically	ADV
9s161546d9g	10	28	stable	stable	ADJ
9s161546d9g	10	29	stereoisomers	stereoisomer	NOUN
9s161546d9g	10	30	,	,	PUNCT
9s161546d9g	10	31	cl(r)si(on[r]o	cl(r)si(on[r]o	NOUN
9s161546d9g	10	32	)	)	PUNCT
9s161546d9g	10	33	,	,	PUNCT
9s161546d9g	10	34	in	in	ADP
9s161546d9g	10	35	which	which	PRON
9s161546d9g	10	36	the	the	DET
9s161546d9g	10	37	chlorine	chlorine	NOUN
9s161546d9g	10	38	is	be	AUX
9s161546d9g	10	39	axial	axial	ADJ
9s161546d9g	10	40	.	.	PUNCT
9s161546d9g	11	1	the	the	DET
9s161546d9g	11	2	kinetic	kinetic	ADJ
9s161546d9g	11	3	stereoselectivity	stereoselectivity	NOUN
9s161546d9g	11	4	in	in	ADP
9s161546d9g	11	5	these	these	DET
9s161546d9g	11	6	reactions	reaction	NOUN
9s161546d9g	11	7	is	be	AUX
9s161546d9g	11	8	determined	determine	VERB
9s161546d9g	11	9	not	not	PART
9s161546d9g	11	10	only	only	ADV
9s161546d9g	11	11	by	by	ADP
9s161546d9g	11	12	relative	relative	ADJ
9s161546d9g	11	13	barriers	barrier	NOUN
9s161546d9g	11	14	of	of	ADP
9s161546d9g	11	15	migration	migration	NOUN
9s161546d9g	11	16	from	from	ADP
9s161546d9g	11	17	isomeric	isomeric	ADJ
9s161546d9g	11	18	octahedral	octahedral	ADJ
9s161546d9g	11	19	silicon	silicon	NOUN
9s161546d9g	11	20	intermediates	intermediate	NOUN
9s161546d9g	11	21	,	,	PUNCT
9s161546d9g	11	22	but	but	CCONJ
9s161546d9g	11	23	also	also	ADV
9s161546d9g	11	24	from	from	ADP
9s161546d9g	11	25	the	the	DET
9s161546d9g	11	26	reversibility	reversibility	NOUN
9s161546d9g	11	27	in	in	ADP
9s161546d9g	11	28	isomerization	isomerization	NOUN
9s161546d9g	11	29	of	of	ADP
9s161546d9g	11	30	&	&	CCONJ
9s161546d9g	11	31	#	#	SYM
9s161546d9g	11	32	954;3	954;3	NUM
9s161546d9g	11	33	-	-	PUNCT
9s161546d9g	11	34	r(x)(y)si(onoq	r(x)(y)si(onoq	SPACE
9s161546d9g	11	35	)	)	PUNCT
9s161546d9g	11	36	isomers	isomer	NOUN
9s161546d9g	11	37	via	via	ADP
9s161546d9g	11	38	the	the	DET
9s161546d9g	11	39	tetrahedral	tetrahedral	NOUN
9s161546d9g	11	40	&	&	CCONJ
9s161546d9g	11	41	#	#	SYM
9s161546d9g	11	42	954;1	954;1	NUM
9s161546d9g	11	43	-	-	PUNCT
9s161546d9g	11	44	r(x)(y)si(onoq	r(x)(y)si(onoq	NOUN
9s161546d9g	11	45	)	)	PUNCT
9s161546d9g	11	46	.	.	PUNCT
9s161546d9g	12	1	in	in	ADP
9s161546d9g	12	2	reaction	reaction	NOUN
9s161546d9g	12	3	of	of	ADP
9s161546d9g	12	4	me3mcl	me3mcl	PROPN
9s161546d9g	12	5	(	(	PUNCT
9s161546d9g	12	6	m	m	VERB
9s161546d9g	12	7	=	=	NOUN
9s161546d9g	12	8	si	si	X
9s161546d9g	12	9	or	or	CCONJ
9s161546d9g	12	10	sn	sn	PROPN
9s161546d9g	12	11	)	)	PUNCT
9s161546d9g	12	12	with	with	ADP
9s161546d9g	12	13	h(dopoq	h(dopoq	NOUN
9s161546d9g	12	14	)	)	PUNCT
9s161546d9g	12	15	(	(	PUNCT
9s161546d9g	12	16	dopo	dopo	X
9s161546d9g	12	17	=	=	X
9s161546d9g	12	18	2,4,6,8	2,4,6,8	NUM
9s161546d9g	12	19	-	-	PUNCT
9s161546d9g	12	20	tetra	tetra	NOUN
9s161546d9g	12	21	-	-	PUNCT
9s161546d9g	12	22	tert	tert	PROPN
9s161546d9g	12	23	-	-	PUNCT
9s161546d9g	12	24	butyl-1	butyl-1	PROPN
9s161546d9g	12	25	-	-	PUNCT
9s161546d9g	12	26	oxo-1h	oxo-1h	PROPN
9s161546d9g	12	27	-	-	PUNCT
9s161546d9g	12	28	phenoxazin-9	phenoxazin-9	PROPN
9s161546d9g	12	29	-	-	PUNCT
9s161546d9g	12	30	olate	olate	ADJ
9s161546d9g	12	31	)	)	PUNCT
9s161546d9g	12	32	,	,	PUNCT
9s161546d9g	12	33	tetrahedral	tetrahedral	ADJ
9s161546d9g	12	34	intermediates	intermediate	NOUN
9s161546d9g	12	35	&	&	CCONJ
9s161546d9g	12	36	#	#	SYM
9s161546d9g	12	37	954;1	954;1	NUM
9s161546d9g	12	38	-	-	PUNCT
9s161546d9g	12	39	me3m(onoq	me3m(onoq	NOUN
9s161546d9g	12	40	)	)	PUNCT
9s161546d9g	12	41	can	can	AUX
9s161546d9g	12	42	be	be	AUX
9s161546d9g	12	43	isolated	isolate	VERB
9s161546d9g	12	44	or	or	CCONJ
9s161546d9g	12	45	spectroscopically	spectroscopically	ADV
9s161546d9g	12	46	identified	identify	VERB
9s161546d9g	12	47	.	.	PUNCT
9s161546d9g	13	1	the	the	DET
9s161546d9g	13	2	rates	rate	NOUN
9s161546d9g	13	3	of	of	ADP
9s161546d9g	13	4	methyl	methyl	NOUN
9s161546d9g	13	5	migration	migration	NOUN
9s161546d9g	13	6	from	from	ADP
9s161546d9g	13	7	these	these	DET
9s161546d9g	13	8	intermediates	intermediate	NOUN
9s161546d9g	13	9	indicates	indicate	VERB
9s161546d9g	13	10	that	that	SCONJ
9s161546d9g	13	11	migration	migration	NOUN
9s161546d9g	13	12	from	from	ADP
9s161546d9g	13	13	tetrahedral	tetrahedral	ADJ
9s161546d9g	13	14	tin	tin	NOUN
9s161546d9g	13	15	is	be	AUX
9s161546d9g	13	16	10	10	NUM
9s161546d9g	13	17	^	^	NOUN
9s161546d9g	13	18	4	4	NUM
9s161546d9g	13	19	times	time	NOUN
9s161546d9g	13	20	faster	fast	ADJ
9s161546d9g	13	21	than	than	ADP
9s161546d9g	13	22	migration	migration	NOUN
9s161546d9g	13	23	from	from	ADP
9s161546d9g	13	24	silicon	silicon	NOUN
9s161546d9g	13	25	.	.	PUNCT
9s161546d9g	14	1	in	in	ADP
9s161546d9g	14	2	stark	stark	ADJ
9s161546d9g	14	3	contrast	contrast	NOUN
9s161546d9g	14	4	,	,	PUNCT
9s161546d9g	14	5	methyl	methyl	NOUN
9s161546d9g	14	6	migration	migration	NOUN
9s161546d9g	14	7	from	from	ADP
9s161546d9g	14	8	silicon	silicon	NOUN
9s161546d9g	14	9	in	in	ADP
9s161546d9g	14	10	the	the	DET
9s161546d9g	14	11	octahedral	octahedral	ADJ
9s161546d9g	14	12	intermediate	intermediate	ADJ
9s161546d9g	14	13	&	&	CCONJ
9s161546d9g	14	14	#	#	SYM
9s161546d9g	14	15	954;3	954;3	NUM
9s161546d9g	14	16	-	-	PUNCT
9s161546d9g	14	17	mecl2si(dopoq	mecl2si(dopoq	SPACE
9s161546d9g	14	18	)	)	PUNCT
9s161546d9g	14	19	is	be	AUX
9s161546d9g	14	20	at	at	ADV
9s161546d9g	14	21	least	least	ADV
9s161546d9g	14	22	10	10	NUM
9s161546d9g	14	23	^	^	NOUN
9s161546d9g	14	24	7	7	NUM
9s161546d9g	14	25	time	time	NOUN
9s161546d9g	14	26	faster	fast	ADV
9s161546d9g	14	27	than	than	ADP
9s161546d9g	14	28	migration	migration	NOUN
9s161546d9g	14	29	from	from	ADP
9s161546d9g	14	30	tin	tin	NOUN
9s161546d9g	14	31	.	.	PUNCT
9s161546d9g	15	1	the	the	DET
9s161546d9g	15	2	enhanced	enhanced	ADJ
9s161546d9g	15	3	reactivity	reactivity	NOUN
9s161546d9g	15	4	of	of	ADP
9s161546d9g	15	5	the	the	DET
9s161546d9g	15	6	silicon	silicon	NOUN
9s161546d9g	15	7	-	-	PUNCT
9s161546d9g	15	8	carbon	carbon	NOUN
9s161546d9g	15	9	bond	bond	NOUN
9s161546d9g	15	10	in	in	ADP
9s161546d9g	15	11	monomethyl	monomethyl	NOUN
9s161546d9g	15	12	compounds	compound	VERB
9s161546d9g	15	13	results	result	NOUN
9s161546d9g	15	14	from	from	ADP
9s161546d9g	15	15	the	the	DET
9s161546d9g	15	16	increased	increase	VERB
9s161546d9g	15	17	stability	stability	NOUN
9s161546d9g	15	18	of	of	ADP
9s161546d9g	15	19	the	the	PRON
9s161546d9g	15	20	&	&	CCONJ
9s161546d9g	15	21	#	#	SYM
9s161546d9g	15	22	954;3	954;3	NUM
9s161546d9g	15	23	intermediate	intermediate	ADJ
9s161546d9g	15	24	realtive	realtive	ADJ
9s161546d9g	15	25	to	to	ADP
9s161546d9g	15	26	&	&	CCONJ
9s161546d9g	15	27	#	#	SYM
9s161546d9g	15	28	954;1	954;1	NUM
9s161546d9g	15	29	.	.	PUNCT
9s161546d9g	16	1	this	this	DET
9s161546d9g	16	2	inference	inference	NOUN
9s161546d9g	16	3	can	can	AUX
9s161546d9g	16	4	used	use	VERB
9s161546d9g	16	5	to	to	ADP
9s161546d9g	16	6	the	the	DET
9s161546d9g	16	7	drive	drive	NOUN
9s161546d9g	16	8	the	the	DET
9s161546d9g	16	9	desired	desire	VERB
9s161546d9g	16	10	reactivity	reactivity	NOUN
9s161546d9g	16	11	of	of	ADP
9s161546d9g	16	12	silicon	silicon	NOUN
9s161546d9g	16	13	and	and	CCONJ
9s161546d9g	16	14	tin	tin	NOUN
9s161546d9g	16	15	.	.	PUNCT