id sid tid token lemma pos 9306sx63f68 1 1 the the DET 9306sx63f68 1 2 use use NOUN 9306sx63f68 1 3 of of ADP 9306sx63f68 1 4 molten melt VERB 9306sx63f68 1 5 boric boric ADJ 9306sx63f68 1 6 acid acid NOUN 9306sx63f68 1 7 as as ADP 9306sx63f68 1 8 a a DET 9306sx63f68 1 9 reactive reactive ADJ 9306sx63f68 1 10 flux flux NOUN 9306sx63f68 1 11 in in ADP 9306sx63f68 1 12 the the DET 9306sx63f68 1 13 synthesis synthesis NOUN 9306sx63f68 1 14 of of ADP 9306sx63f68 1 15 trivalent trivalent ADJ 9306sx63f68 1 16 actinide actinide ADJ 9306sx63f68 1 17 borates borate NOUN 9306sx63f68 1 18 has have AUX 9306sx63f68 1 19 been be AUX 9306sx63f68 1 20 explored explore VERB 9306sx63f68 1 21 and and CCONJ 9306sx63f68 1 22 developed develop VERB 9306sx63f68 1 23 over over ADP 9306sx63f68 1 24 the the DET 9306sx63f68 1 25 past past ADJ 9306sx63f68 1 26 several several ADJ 9306sx63f68 1 27 years year NOUN 9306sx63f68 1 28 . . PUNCT 9306sx63f68 2 1 throughout throughout ADP 9306sx63f68 2 2 these these DET 9306sx63f68 2 3 investigations investigation NOUN 9306sx63f68 2 4 , , PUNCT 9306sx63f68 2 5 several several ADJ 9306sx63f68 2 6 unexpected unexpected ADJ 9306sx63f68 2 7 structures structure NOUN 9306sx63f68 2 8 and and CCONJ 9306sx63f68 2 9 results result NOUN 9306sx63f68 2 10 were be AUX 9306sx63f68 2 11 obtained obtain VERB 9306sx63f68 2 12 . . PUNCT 9306sx63f68 3 1 it it PRON 9306sx63f68 3 2 has have AUX 9306sx63f68 3 3 been be AUX 9306sx63f68 3 4 determined determine VERB 9306sx63f68 3 5 that that SCONJ 9306sx63f68 3 6 the the DET 9306sx63f68 3 7 chemistries chemistry NOUN 9306sx63f68 3 8 of of ADP 9306sx63f68 3 9 trivalent trivalent ADJ 9306sx63f68 3 10 plutonium plutonium NOUN 9306sx63f68 3 11 , , PUNCT 9306sx63f68 3 12 americium americium PROPN 9306sx63f68 3 13 , , PUNCT 9306sx63f68 3 14 curium curium NOUN 9306sx63f68 3 15 , , PUNCT 9306sx63f68 3 16 and and CCONJ 9306sx63f68 3 17 californium californium NOUN 9306sx63f68 3 18 within within ADP 9306sx63f68 3 19 a a DET 9306sx63f68 3 20 borate borate ADJ 9306sx63f68 3 21 matrix matrix NOUN 9306sx63f68 3 22 are be AUX 9306sx63f68 3 23 completely completely ADV 9306sx63f68 3 24 different different ADJ 9306sx63f68 3 25 . . PUNCT 9306sx63f68 4 1 this this PRON 9306sx63f68 4 2 has have AUX 9306sx63f68 4 3 lead lead VERB 9306sx63f68 4 4 to to ADP 9306sx63f68 4 5 the the DET 9306sx63f68 4 6 first first ADJ 9306sx63f68 4 7 family family NOUN 9306sx63f68 4 8 of of ADP 9306sx63f68 4 9 compounds compound NOUN 9306sx63f68 4 10 containing contain VERB 9306sx63f68 4 11 the the DET 9306sx63f68 4 12 later later ADJ 9306sx63f68 4 13 actinides actinide NOUN 9306sx63f68 4 14 where where SCONJ 9306sx63f68 4 15 the the DET 9306sx63f68 4 16 structures structure NOUN 9306sx63f68 4 17 are be AUX 9306sx63f68 4 18 neither neither CCONJ 9306sx63f68 4 19 isotypic isotypic ADJ 9306sx63f68 4 20 to to ADP 9306sx63f68 4 21 the the DET 9306sx63f68 4 22 lanthanides lanthanide NOUN 9306sx63f68 4 23 nor nor CCONJ 9306sx63f68 4 24 each each DET 9306sx63f68 4 25 other other ADJ 9306sx63f68 4 26 . . PUNCT 9306sx63f68 5 1 there there PRON 9306sx63f68 5 2 are be VERB 9306sx63f68 5 3 two two NUM 9306sx63f68 5 4 main main ADJ 9306sx63f68 5 5 objectives objective NOUN 9306sx63f68 5 6 of of ADP 9306sx63f68 5 7 this this DET 9306sx63f68 5 8 work work NOUN 9306sx63f68 5 9 . . PUNCT 9306sx63f68 6 1 the the DET 9306sx63f68 6 2 first first ADJ 9306sx63f68 6 3 is be AUX 9306sx63f68 6 4 to to PART 9306sx63f68 6 5 further far ADV 9306sx63f68 6 6 examine examine VERB 9306sx63f68 6 7 the the DET 9306sx63f68 6 8 basic basic ADJ 9306sx63f68 6 9 chemistry chemistry NOUN 9306sx63f68 6 10 and and CCONJ 9306sx63f68 6 11 periodic periodic ADJ 9306sx63f68 6 12 trends trend NOUN 9306sx63f68 6 13 between between ADP 9306sx63f68 6 14 the the DET 9306sx63f68 6 15 lanthanide lanthanide NOUN 9306sx63f68 6 16 and and CCONJ 9306sx63f68 6 17 the the DET 9306sx63f68 6 18 actinide actinide ADJ 9306sx63f68 6 19 elements element NOUN 9306sx63f68 6 20 . . PUNCT 9306sx63f68 7 1 this this PRON 9306sx63f68 7 2 has have AUX 9306sx63f68 7 3 been be AUX 9306sx63f68 7 4 achieved achieve VERB 9306sx63f68 7 5 by by ADP 9306sx63f68 7 6 functionalizing functionalize VERB 9306sx63f68 7 7 the the DET 9306sx63f68 7 8 f f PROPN 9306sx63f68 7 9 - - PUNCT 9306sx63f68 7 10 element element NOUN 9306sx63f68 7 11 centers center NOUN 9306sx63f68 7 12 within within ADP 9306sx63f68 7 13 these these DET 9306sx63f68 7 14 borates borate NOUN 9306sx63f68 7 15 and and CCONJ 9306sx63f68 7 16 by by ADP 9306sx63f68 7 17 fine fine ADJ 9306sx63f68 7 18 tuning tune VERB 9306sx63f68 7 19 the the DET 9306sx63f68 7 20 experimental experimental ADJ 9306sx63f68 7 21 conditions condition NOUN 9306sx63f68 7 22 , , PUNCT 9306sx63f68 7 23 which which PRON 9306sx63f68 7 24 has have AUX 9306sx63f68 7 25 led lead VERB 9306sx63f68 7 26 to to ADP 9306sx63f68 7 27 two two NUM 9306sx63f68 7 28 distinct distinct ADJ 9306sx63f68 7 29 families family NOUN 9306sx63f68 7 30 of of ADP 9306sx63f68 7 31 the the DET 9306sx63f68 7 32 f f PROPN 9306sx63f68 7 33 - - PUNCT 9306sx63f68 7 34 element element NOUN 9306sx63f68 7 35 borates borate NOUN 9306sx63f68 7 36 . . PUNCT 9306sx63f68 8 1 the the DET 9306sx63f68 8 2 second second ADJ 9306sx63f68 8 3 objective objective NOUN 9306sx63f68 8 4 is be AUX 9306sx63f68 8 5 to to PART 9306sx63f68 8 6 better well ADV 9306sx63f68 8 7 understand understand VERB 9306sx63f68 8 8 the the DET 9306sx63f68 8 9 differences difference NOUN 9306sx63f68 8 10 in in ADP 9306sx63f68 8 11 bonding bond VERB 9306sx63f68 8 12 that that PRON 9306sx63f68 8 13 exist exist VERB 9306sx63f68 8 14 between between ADP 9306sx63f68 8 15 the the DET 9306sx63f68 8 16 two two NUM 9306sx63f68 8 17 f f PROPN 9306sx63f68 8 18 - - PUNCT 9306sx63f68 8 19 element element NOUN 9306sx63f68 8 20 series series NOUN 9306sx63f68 8 21 . . PUNCT 9306sx63f68 9 1 this this PRON 9306sx63f68 9 2 was be AUX 9306sx63f68 9 3 achieved achieve VERB 9306sx63f68 9 4 by by ADP 9306sx63f68 9 5 density density NOUN 9306sx63f68 9 6 functional functional ADJ 9306sx63f68 9 7 theory theory NOUN 9306sx63f68 9 8 ( ( PUNCT 9306sx63f68 9 9 dft dft NOUN 9306sx63f68 9 10 ) ) PUNCT 9306sx63f68 9 11 studies study NOUN 9306sx63f68 9 12 that that PRON 9306sx63f68 9 13 have have AUX 9306sx63f68 9 14 provided provide VERB 9306sx63f68 9 15 a a DET 9306sx63f68 9 16 more more ADV 9306sx63f68 9 17 detailed detailed ADJ 9306sx63f68 9 18 examination examination NOUN 9306sx63f68 9 19 of of ADP 9306sx63f68 9 20 the the DET 9306sx63f68 9 21 f f NOUN 9306sx63f68 9 22 - - PUNCT 9306sx63f68 9 23 elements element NOUN 9306sx63f68 9 24 which which PRON 9306sx63f68 9 25 , , PUNCT 9306sx63f68 9 26 to to ADP 9306sx63f68 9 27 this this DET 9306sx63f68 9 28 point point NOUN 9306sx63f68 9 29 , , PUNCT 9306sx63f68 9 30 has have AUX 9306sx63f68 9 31 been be AUX 9306sx63f68 9 32 shown show VERB 9306sx63f68 9 33 to to PART 9306sx63f68 9 34 be be AUX 9306sx63f68 9 35 the the DET 9306sx63f68 9 36 same same ADJ 9306sx63f68 9 37 in in ADP 9306sx63f68 9 38 regards regard NOUN 9306sx63f68 9 39 to to ADP 9306sx63f68 9 40 structure structure NOUN 9306sx63f68 9 41 and and CCONJ 9306sx63f68 9 42 bonding bond VERB 9306sx63f68 9 43 analyses analysis NOUN 9306sx63f68 9 44 have have AUX 9306sx63f68 9 45 often often ADV 9306sx63f68 9 46 been be AUX 9306sx63f68 9 47 contradictory contradictory ADJ 9306sx63f68 9 48 . . PUNCT 9306sx63f68 10 1 the the DET 9306sx63f68 10 2 dft dft PROPN 9306sx63f68 10 3 results result NOUN 9306sx63f68 10 4 also also ADV 9306sx63f68 10 5 reveal reveal VERB 9306sx63f68 10 6 real real ADJ 9306sx63f68 10 7 differences difference NOUN 9306sx63f68 10 8 in in ADP 9306sx63f68 10 9 bonding bonding NOUN 9306sx63f68 10 10 in in ADP 9306sx63f68 10 11 the the DET 9306sx63f68 10 12 actinide actinide ADJ 9306sx63f68 10 13 elements element NOUN 9306sx63f68 10 14 . . PUNCT 9306sx63f68 11 1 an an DET 9306sx63f68 11 2 understanding understanding NOUN 9306sx63f68 11 3 of of ADP 9306sx63f68 11 4 these these DET 9306sx63f68 11 5 two two NUM 9306sx63f68 11 6 objectives objective NOUN 9306sx63f68 11 7 will will AUX 9306sx63f68 11 8 aid aid VERB 9306sx63f68 11 9 in in ADP 9306sx63f68 11 10 the the DET 9306sx63f68 11 11 development development NOUN 9306sx63f68 11 12 of of ADP 9306sx63f68 11 13 structure structure NOUN 9306sx63f68 11 14 - - PUNCT 9306sx63f68 11 15 property property NOUN 9306sx63f68 11 16 relationships relationship NOUN 9306sx63f68 11 17 for for ADP 9306sx63f68 11 18 advanced advanced ADJ 9306sx63f68 11 19 waste waste NOUN 9306sx63f68 11 20 forms form NOUN 9306sx63f68 11 21 for for ADP 9306sx63f68 11 22 the the DET 9306sx63f68 11 23 actinides actinide NOUN 9306sx63f68 11 24 present present ADJ 9306sx63f68 11 25 in in ADP 9306sx63f68 11 26 nuclear nuclear ADJ 9306sx63f68 11 27 waste waste NOUN 9306sx63f68 11 28 , , PUNCT 9306sx63f68 11 29 the the DET 9306sx63f68 11 30 environmental environmental ADJ 9306sx63f68 11 31 impacts impact NOUN 9306sx63f68 11 32 of of ADP 9306sx63f68 11 33 actinide actinide ADJ 9306sx63f68 11 34 borates borate NOUN 9306sx63f68 11 35 , , PUNCT 9306sx63f68 11 36 and and CCONJ 9306sx63f68 11 37 an an DET 9306sx63f68 11 38 improved improved ADJ 9306sx63f68 11 39 understanding understanding NOUN 9306sx63f68 11 40 of of ADP 9306sx63f68 11 41 bonding bond VERB 9306sx63f68 11 42 in in ADP 9306sx63f68 11 43 the the DET 9306sx63f68 11 44 f f NOUN 9306sx63f68 11 45 - - PUNCT 9306sx63f68 11 46 elements element NOUN 9306sx63f68 11 47 to to PART 9306sx63f68 11 48 be be AUX 9306sx63f68 11 49 exploited exploit VERB 9306sx63f68 11 50 for for ADP 9306sx63f68 11 51 chemical chemical ADJ 9306sx63f68 11 52 separations separation NOUN 9306sx63f68 11 53 . . PUNCT 9306sx63f68 12 1 this this DET 9306sx63f68 12 2 dissertation dissertation NOUN 9306sx63f68 12 3 is be AUX 9306sx63f68 12 4 focused focus VERB 9306sx63f68 12 5 on on ADP 9306sx63f68 12 6 the the DET 9306sx63f68 12 7 borate borate PROPN 9306sx63f68 12 8 crystal crystal NOUN 9306sx63f68 12 9 chemistry chemistry NOUN 9306sx63f68 12 10 of of ADP 9306sx63f68 12 11 plutonium plutonium NOUN 9306sx63f68 12 12 ( ( PUNCT 9306sx63f68 12 13 chapters chapter NOUN 9306sx63f68 12 14 3 3 NUM 9306sx63f68 12 15 , , PUNCT 9306sx63f68 12 16 5 5 NUM 9306sx63f68 12 17 - - SYM 9306sx63f68 12 18 7 7 NUM 9306sx63f68 12 19 ) ) PUNCT 9306sx63f68 12 20 , , PUNCT 9306sx63f68 12 21 americium americium PROPN 9306sx63f68 12 22 ( ( PUNCT 9306sx63f68 12 23 chapters chapter NOUN 9306sx63f68 12 24 3 3 NUM 9306sx63f68 12 25 , , PUNCT 9306sx63f68 12 26 5 5 NUM 9306sx63f68 12 27 , , PUNCT 9306sx63f68 12 28 7 7 NUM 9306sx63f68 12 29 ) ) PUNCT 9306sx63f68 12 30 , , PUNCT 9306sx63f68 12 31 curium curium NOUN 9306sx63f68 12 32 ( ( PUNCT 9306sx63f68 12 33 chapters chapter NOUN 9306sx63f68 12 34 4 4 NUM 9306sx63f68 12 35 , , PUNCT 9306sx63f68 12 36 5 5 NUM 9306sx63f68 12 37 , , PUNCT 9306sx63f68 12 38 7 7 NUM 9306sx63f68 12 39 ) ) PUNCT 9306sx63f68 12 40 , , PUNCT 9306sx63f68 12 41 californium californium PROPN 9306sx63f68 12 42 ( ( PUNCT 9306sx63f68 12 43 chapter chapter NOUN 9306sx63f68 12 44 11 11 NUM 9306sx63f68 12 45 ) ) PUNCT 9306sx63f68 12 46 , , PUNCT 9306sx63f68 12 47 and and CCONJ 9306sx63f68 12 48 the the DET 9306sx63f68 12 49 lanthanides lanthanide NOUN 9306sx63f68 12 50 ( ( PUNCT 9306sx63f68 12 51 chapters chapter NOUN 9306sx63f68 12 52 5 5 NUM 9306sx63f68 12 53 -10 -10 PUNCT 9306sx63f68 12 54 ) ) PUNCT 9306sx63f68 12 55 . . PUNCT 9306sx63f68 13 1 while while SCONJ 9306sx63f68 13 2 there there PRON 9306sx63f68 13 3 are be VERB 9306sx63f68 13 4 several several ADJ 9306sx63f68 13 5 advancements advancement NOUN 9306sx63f68 13 6 of of ADP 9306sx63f68 13 7 more more ADJ 9306sx63f68 13 8 applied apply VERB 9306sx63f68 13 9 applications application NOUN 9306sx63f68 13 10 gained gain VERB 9306sx63f68 13 11 from from ADP 9306sx63f68 13 12 this this DET 9306sx63f68 13 13 work work NOUN 9306sx63f68 13 14 , , PUNCT 9306sx63f68 13 15 the the DET 9306sx63f68 13 16 most most ADV 9306sx63f68 13 17 important important ADJ 9306sx63f68 13 18 academic academic ADJ 9306sx63f68 13 19 and and CCONJ 9306sx63f68 13 20 fundamental fundamental ADJ 9306sx63f68 13 21 insight insight NOUN 9306sx63f68 13 22 is be AUX 9306sx63f68 13 23 that that SCONJ 9306sx63f68 13 24 the the DET 9306sx63f68 13 25 chemistries chemistry NOUN 9306sx63f68 13 26 of of ADP 9306sx63f68 13 27 the the DET 9306sx63f68 13 28 later later ADJ 9306sx63f68 13 29 actinides actinide NOUN 9306sx63f68 13 30 and and CCONJ 9306sx63f68 13 31 lanthanides lanthanide NOUN 9306sx63f68 13 32 can can AUX 9306sx63f68 13 33 be be AUX 9306sx63f68 13 34 vastly vastly ADV 9306sx63f68 13 35 different different ADJ 9306sx63f68 13 36 and and CCONJ 9306sx63f68 13 37 care care NOUN 9306sx63f68 13 38 must must AUX 9306sx63f68 13 39 be be AUX 9306sx63f68 13 40 taken take VERB 9306sx63f68 13 41 when when SCONJ 9306sx63f68 13 42 making make VERB 9306sx63f68 13 43 assumptions assumption NOUN 9306sx63f68 13 44 about about ADP 9306sx63f68 13 45 these these DET 9306sx63f68 13 46 highly highly ADV 9306sx63f68 13 47 underexplored underexplored ADJ 9306sx63f68 13 48 actinides actinide NOUN 9306sx63f68 13 49 based base VERB 9306sx63f68 13 50 on on ADP 9306sx63f68 13 51 the the DET 9306sx63f68 13 52 chemistry chemistry NOUN 9306sx63f68 13 53 of of ADP 9306sx63f68 13 54 either either CCONJ 9306sx63f68 13 55 the the DET 9306sx63f68 13 56 lanthanides lanthanide NOUN 9306sx63f68 13 57 or or CCONJ 9306sx63f68 13 58 other other ADJ 9306sx63f68 13 59 actinides actinide NOUN 9306sx63f68 13 60 . . PUNCT