id sid tid token lemma pos 8k71ng4727d 1 1 scanning scan VERB 8k71ng4727d 1 2 tunneling tunneling NOUN 8k71ng4727d 1 3 microscopy microscopy NOUN 8k71ng4727d 1 4 was be AUX 8k71ng4727d 1 5 used use VERB 8k71ng4727d 1 6 to to PART 8k71ng4727d 1 7 investigate investigate VERB 8k71ng4727d 1 8 the the DET 8k71ng4727d 1 9 dynamics dynamic NOUN 8k71ng4727d 1 10 of of ADP 8k71ng4727d 1 11 gas gas NOUN 8k71ng4727d 1 12 / / SYM 8k71ng4727d 1 13 surface surface NOUN 8k71ng4727d 1 14 reactions reaction NOUN 8k71ng4727d 1 15 as as SCONJ 8k71ng4727d 1 16 they they PRON 8k71ng4727d 1 17 take take VERB 8k71ng4727d 1 18 place place NOUN 8k71ng4727d 1 19 on on ADP 8k71ng4727d 1 20 the the DET 8k71ng4727d 1 21 molecular molecular ADJ 8k71ng4727d 1 22 scale scale NOUN 8k71ng4727d 1 23 . . PUNCT 8k71ng4727d 2 1 experiments experiment NOUN 8k71ng4727d 2 2 between between ADP 8k71ng4727d 2 3 atomic atomic ADJ 8k71ng4727d 2 4 hydrogen hydrogen NOUN 8k71ng4727d 2 5 and and CCONJ 8k71ng4727d 2 6 an an DET 8k71ng4727d 2 7 au(111 au(111 SPACE 8k71ng4727d 2 8 ) ) PUNCT 8k71ng4727d 2 9 surface surface NOUN 8k71ng4727d 2 10 functionalized functionalize VERB 8k71ng4727d 2 11 with with ADP 8k71ng4727d 2 12 a a DET 8k71ng4727d 2 13 1 1 NUM 8k71ng4727d 2 14 - - PUNCT 8k71ng4727d 2 15 adamantanethiolate adamantanethiolate ADJ 8k71ng4727d 2 16 self self NOUN 8k71ng4727d 2 17 - - PUNCT 8k71ng4727d 2 18 assembled assemble VERB 8k71ng4727d 2 19 monolayer monolayer NOUN 8k71ng4727d 2 20 resulted result VERB 8k71ng4727d 2 21 in in ADP 8k71ng4727d 2 22 signicant signicant ADJ 8k71ng4727d 2 23 evidence evidence NOUN 8k71ng4727d 2 24 that that SCONJ 8k71ng4727d 2 25 the the DET 8k71ng4727d 2 26 reconstruction reconstruction NOUN 8k71ng4727d 2 27 of of ADP 8k71ng4727d 2 28 the the DET 8k71ng4727d 2 29 gold gold NOUN 8k71ng4727d 2 30 during during ADP 8k71ng4727d 2 31 monolayer monolayer NOUN 8k71ng4727d 2 32 formation formation NOUN 8k71ng4727d 2 33 is be AUX 8k71ng4727d 2 34 dependent dependent ADJ 8k71ng4727d 2 35 on on ADP 8k71ng4727d 2 36 the the DET 8k71ng4727d 2 37 thiolate thiolate ADJ 8k71ng4727d 2 38 molecule molecule NOUN 8k71ng4727d 2 39 density density NOUN 8k71ng4727d 2 40 on on ADP 8k71ng4727d 2 41 the the DET 8k71ng4727d 2 42 surface surface NOUN 8k71ng4727d 2 43 . . PUNCT 8k71ng4727d 3 1 reactions reaction NOUN 8k71ng4727d 3 2 have have AUX 8k71ng4727d 3 3 also also ADV 8k71ng4727d 3 4 been be AUX 8k71ng4727d 3 5 completed complete VERB 8k71ng4727d 3 6 between between ADP 8k71ng4727d 3 7 atomic atomic ADJ 8k71ng4727d 3 8 chlorine chlorine NOUN 8k71ng4727d 3 9 and and CCONJ 8k71ng4727d 3 10 1 1 NUM 8k71ng4727d 3 11 - - PUNCT 8k71ng4727d 3 12 octanethiolate octanethiolate ADJ 8k71ng4727d 3 13 monolayers monolayer NOUN 8k71ng4727d 3 14 , , PUNCT 8k71ng4727d 3 15 we we PRON 8k71ng4727d 3 16 believe believe VERB 8k71ng4727d 3 17 , , PUNCT 8k71ng4727d 3 18 based base VERB 8k71ng4727d 3 19 on on ADP 8k71ng4727d 3 20 a a DET 8k71ng4727d 3 21 number number NOUN 8k71ng4727d 3 22 of of ADP 8k71ng4727d 3 23 methodologies methodology NOUN 8k71ng4727d 3 24 used use VERB 8k71ng4727d 3 25 to to PART 8k71ng4727d 3 26 quantify quantify VERB 8k71ng4727d 3 27 the the DET 8k71ng4727d 3 28 products product NOUN 8k71ng4727d 3 29 , , PUNCT 8k71ng4727d 3 30 that that SCONJ 8k71ng4727d 3 31 atomic atomic ADJ 8k71ng4727d 3 32 chlorine chlorine NOUN 8k71ng4727d 3 33 is be AUX 8k71ng4727d 3 34 more more ADJ 8k71ng4727d 3 35 than than ADP 8k71ng4727d 3 36 five five NUM 8k71ng4727d 3 37 times time NOUN 8k71ng4727d 3 38 more more ADV 8k71ng4727d 3 39 likely likely ADJ 8k71ng4727d 3 40 to to PART 8k71ng4727d 3 41 react react VERB 8k71ng4727d 3 42 in in ADP 8k71ng4727d 3 43 bulk bulk ADJ 8k71ng4727d 3 44 ordered order VERB 8k71ng4727d 3 45 ares are NOUN 8k71ng4727d 3 46 of of ADP 8k71ng4727d 3 47 the the DET 8k71ng4727d 3 48 monolayer monolayer NOUN 8k71ng4727d 3 49 than than ADP 8k71ng4727d 3 50 at at ADP 8k71ng4727d 3 51 defect defect NOUN 8k71ng4727d 3 52 sites site NOUN 8k71ng4727d 3 53 . . PUNCT 8k71ng4727d 4 1 further far ADV 8k71ng4727d 4 2 , , PUNCT 8k71ng4727d 4 3 we we PRON 8k71ng4727d 4 4 have have AUX 8k71ng4727d 4 5 determined determine VERB 8k71ng4727d 4 6 that that SCONJ 8k71ng4727d 4 7 , , PUNCT 8k71ng4727d 4 8 while while SCONJ 8k71ng4727d 4 9 chlorination chlorination NOUN 8k71ng4727d 4 10 and and CCONJ 8k71ng4727d 4 11 sulfur sulfur NOUN 8k71ng4727d 4 12 abstraction abstraction NOUN 8k71ng4727d 4 13 does do AUX 8k71ng4727d 4 14 occur occur VERB 8k71ng4727d 4 15 over over ADP 8k71ng4727d 4 16 extended extended ADJ 8k71ng4727d 4 17 dose dose NOUN 8k71ng4727d 4 18 times time NOUN 8k71ng4727d 4 19 , , PUNCT 8k71ng4727d 4 20 the the DET 8k71ng4727d 4 21 principle principle ADJ 8k71ng4727d 4 22 reaction reaction NOUN 8k71ng4727d 4 23 pathway pathway NOUN 8k71ng4727d 4 24 is be AUX 8k71ng4727d 4 25 likely likely ADJ 8k71ng4727d 4 26 hydrogen hydrogen NOUN 8k71ng4727d 4 27 abstraction abstraction NOUN 8k71ng4727d 4 28 followed follow VERB 8k71ng4727d 4 29 by by ADP 8k71ng4727d 4 30 the the DET 8k71ng4727d 4 31 recombination recombination NOUN 8k71ng4727d 4 32 of of ADP 8k71ng4727d 4 33 surface surface NOUN 8k71ng4727d 4 34 radicals radical NOUN 8k71ng4727d 4 35 , , PUNCT 8k71ng4727d 4 36 leading lead VERB 8k71ng4727d 4 37 to to ADP 8k71ng4727d 4 38 an an DET 8k71ng4727d 4 39 extensively extensively ADV 8k71ng4727d 4 40 cross cross ADJ 8k71ng4727d 4 41 - - ADJ 8k71ng4727d 4 42 linked linked ADJ 8k71ng4727d 4 43 surface surface NOUN 8k71ng4727d 4 44 . . PUNCT 8k71ng4727d 5 1 increasing increase VERB 8k71ng4727d 5 2 the the DET 8k71ng4727d 5 3 throughput throughput NOUN 8k71ng4727d 5 4 of of ADP 8k71ng4727d 5 5 instrumentation instrumentation NOUN 8k71ng4727d 5 6 already already ADV 8k71ng4727d 5 7 present present ADJ 8k71ng4727d 5 8 in in ADP 8k71ng4727d 5 9 the the DET 8k71ng4727d 5 10 lab lab NOUN 8k71ng4727d 5 11 has have AUX 8k71ng4727d 5 12 been be AUX 8k71ng4727d 5 13 a a DET 8k71ng4727d 5 14 major major ADJ 8k71ng4727d 5 15 goal goal NOUN 8k71ng4727d 5 16 . . PUNCT 8k71ng4727d 6 1 a a DET 8k71ng4727d 6 2 high high ADJ 8k71ng4727d 6 3 - - PUNCT 8k71ng4727d 6 4 voltage voltage NOUN 8k71ng4727d 6 5 supply supply NOUN 8k71ng4727d 6 6 capable capable ADJ 8k71ng4727d 6 7 of of ADP 8k71ng4727d 6 8 supplying supply VERB 8k71ng4727d 6 9 280 280 NUM 8k71ng4727d 6 10 v v NOUN 8k71ng4727d 6 11 to to ADP 8k71ng4727d 6 12 the the DET 8k71ng4727d 6 13 tunnel tunnel NOUN 8k71ng4727d 6 14 junction junction NOUN 8k71ng4727d 6 15 has have AUX 8k71ng4727d 6 16 been be AUX 8k71ng4727d 6 17 constructed construct VERB 8k71ng4727d 6 18 to to PART 8k71ng4727d 6 19 make make VERB 8k71ng4727d 6 20 in in ADP 8k71ng4727d 6 21 vacuum vacuum NOUN 8k71ng4727d 6 22 tip tip NOUN 8k71ng4727d 6 23 changes change NOUN 8k71ng4727d 6 24 possible possible ADJ 8k71ng4727d 6 25 . . PUNCT 8k71ng4727d 7 1 an an DET 8k71ng4727d 7 2 electrochemical electrochemical ADJ 8k71ng4727d 7 3 tip tip NOUN 8k71ng4727d 7 4 etcher etcher NOUN 8k71ng4727d 7 5 has have AUX 8k71ng4727d 7 6 been be AUX 8k71ng4727d 7 7 built build VERB 8k71ng4727d 7 8 and and CCONJ 8k71ng4727d 7 9 used use VERB 8k71ng4727d 7 10 to to PART 8k71ng4727d 7 11 prepare prepare VERB 8k71ng4727d 7 12 sharp sharp ADJ 8k71ng4727d 7 13 spm spm NOUN 8k71ng4727d 7 14 tips tip NOUN 8k71ng4727d 7 15 with with ADP 8k71ng4727d 7 16 a a DET 8k71ng4727d 7 17 reproducible reproducible NOUN 8k71ng4727d 7 18 etched etch VERB 8k71ng4727d 7 19 length length NOUN 8k71ng4727d 7 20 to to ADP 8k71ng4727d 7 21 apex apex ADJ 8k71ng4727d 7 22 diameter diameter NOUN 8k71ng4727d 7 23 aspect aspect NOUN 8k71ng4727d 7 24 ratio ratio NOUN 8k71ng4727d 7 25 , , PUNCT 8k71ng4727d 7 26 and and CCONJ 8k71ng4727d 7 27 a a DET 8k71ng4727d 7 28 novel novel NOUN 8k71ng4727d 7 29 thermoelectrically thermoelectrically ADV 8k71ng4727d 7 30 cooled cool VERB 8k71ng4727d 7 31 stm stm PROPN 8k71ng4727d 7 32 was be AUX 8k71ng4727d 7 33 constructed construct VERB 8k71ng4727d 7 34 that that PRON 8k71ng4727d 7 35 will will AUX 8k71ng4727d 7 36 go go VERB 8k71ng4727d 7 37 on on ADP 8k71ng4727d 7 38 to to PART 8k71ng4727d 7 39 allow allow VERB 8k71ng4727d 7 40 the the DET 8k71ng4727d 7 41 lab lab NOUN 8k71ng4727d 7 42 to to PART 8k71ng4727d 7 43 complete complete VERB 8k71ng4727d 7 44 thermally thermally ADV 8k71ng4727d 7 45 activated activate VERB 8k71ng4727d 7 46 reaction reaction NOUN 8k71ng4727d 7 47 studies study NOUN 8k71ng4727d 7 48 in in ADP 8k71ng4727d 7 49 a a DET 8k71ng4727d 7 50 controlled control VERB 8k71ng4727d 7 51 environment environment NOUN 8k71ng4727d 7 52 . . PUNCT 8k71ng4727d 8 1 further far ADV 8k71ng4727d 8 2 , , PUNCT 8k71ng4727d 8 3 we we PRON 8k71ng4727d 8 4 have have AUX 8k71ng4727d 8 5 designed design VERB 8k71ng4727d 8 6 and and CCONJ 8k71ng4727d 8 7 developed develop VERB 8k71ng4727d 8 8 a a DET 8k71ng4727d 8 9 new new ADJ 8k71ng4727d 8 10 ultra ultra ADJ 8k71ng4727d 8 11 - - ADJ 8k71ng4727d 8 12 high high ADJ 8k71ng4727d 8 13 vacuum vacuum NOUN 8k71ng4727d 8 14 , , PUNCT 8k71ng4727d 8 15 cryogenically cryogenically ADV 8k71ng4727d 8 16 cooled cool VERB 8k71ng4727d 8 17 stm stm NOUN 8k71ng4727d 8 18 capable capable ADJ 8k71ng4727d 8 19 of of ADP 8k71ng4727d 8 20 reevaluating reevaluate VERB 8k71ng4727d 8 21 the the DET 8k71ng4727d 8 22 reactions reaction NOUN 8k71ng4727d 8 23 between between ADP 8k71ng4727d 8 24 h h NOUN 8k71ng4727d 8 25 atoms atom NOUN 8k71ng4727d 8 26 and and CCONJ 8k71ng4727d 8 27 thiolate thiolate VERB 8k71ng4727d 8 28 sams sam NOUN 8k71ng4727d 8 29 previously previously ADV 8k71ng4727d 8 30 completed complete VERB 8k71ng4727d 8 31 in in ADP 8k71ng4727d 8 32 the the DET 8k71ng4727d 8 33 lab lab NOUN 8k71ng4727d 8 34 , , PUNCT 8k71ng4727d 8 35 but but CCONJ 8k71ng4727d 8 36 now now ADV 8k71ng4727d 8 37 , , PUNCT 8k71ng4727d 8 38 at at ADP 8k71ng4727d 8 39 low low ADJ 8k71ng4727d 8 40 - - PUNCT 8k71ng4727d 8 41 temperature temperature NOUN 8k71ng4727d 8 42 . . PUNCT 8k71ng4727d 9 1 this this PRON 8k71ng4727d 9 2 will will AUX 8k71ng4727d 9 3 hopefully hopefully ADV 8k71ng4727d 9 4 allow allow VERB 8k71ng4727d 9 5 us we PRON 8k71ng4727d 9 6 to to PART 8k71ng4727d 9 7 further far ADV 8k71ng4727d 9 8 elucidate elucidate VERB 8k71ng4727d 9 9 the the DET 8k71ng4727d 9 10 kinetics kinetic NOUN 8k71ng4727d 9 11 of of ADP 8k71ng4727d 9 12 chemical chemical ADJ 8k71ng4727d 9 13 reactions reaction NOUN 8k71ng4727d 9 14 taking take VERB 8k71ng4727d 9 15 place place NOUN 8k71ng4727d 9 16 at at ADP 8k71ng4727d 9 17 surfaces surface NOUN 8k71ng4727d 9 18 on on ADP 8k71ng4727d 9 19 the the DET 8k71ng4727d 9 20 molecular molecular ADJ 8k71ng4727d 9 21 level level NOUN 8k71ng4727d 9 22 . . PUNCT