id	sid	tid	token	lemma	pos
7h149p3103n	1	1	cornexistin	cornexistin	PROPN
7h149p3103n	1	2	and	and	CCONJ
7h149p3103n	1	3	hydroxycornexistin	hydroxycornexistin	PROPN
7h149p3103n	1	4	are	be	AUX
7h149p3103n	1	5	natural	natural	ADJ
7h149p3103n	1	6	products	product	NOUN
7h149p3103n	1	7	derived	derive	VERB
7h149p3103n	1	8	from	from	ADP
7h149p3103n	1	9	the	the	DET
7h149p3103n	1	10	fungus	fungus	NOUN
7h149p3103n	1	11	paecilomyces	paecilomyces	PROPN
7h149p3103n	1	12	variotti	variotti	PROPN
7h149p3103n	1	13	.	.	PUNCT
7h149p3103n	2	1	both	both	CCONJ
7h149p3103n	2	2	cornexistin	cornexistin	PROPN
7h149p3103n	2	3	and	and	CCONJ
7h149p3103n	2	4	hydroxycornexistin	hydroxycornexistin	PROPN
7h149p3103n	2	5	are	be	AUX
7h149p3103n	2	6	highly	highly	ADV
7h149p3103n	2	7	potent	potent	ADJ
7h149p3103n	2	8	herbicides	herbicide	NOUN
7h149p3103n	2	9	that	that	PRON
7h149p3103n	2	10	have	have	VERB
7h149p3103n	2	11	the	the	DET
7h149p3103n	2	12	unique	unique	ADJ
7h149p3103n	2	13	quality	quality	NOUN
7h149p3103n	2	14	of	of	ADP
7h149p3103n	2	15	being	be	AUX
7h149p3103n	2	16	harmless	harmless	ADJ
7h149p3103n	2	17	to	to	ADP
7h149p3103n	2	18	corn	corn	NOUN
7h149p3103n	2	19	plants	plant	NOUN
7h149p3103n	2	20	.	.	PUNCT
7h149p3103n	3	1	because	because	SCONJ
7h149p3103n	3	2	of	of	ADP
7h149p3103n	3	3	this	this	DET
7h149p3103n	3	4	quality	quality	NOUN
7h149p3103n	3	5	,	,	PUNCT
7h149p3103n	3	6	both	both	DET
7h149p3103n	3	7	molecules	molecule	NOUN
7h149p3103n	3	8	have	have	AUX
7h149p3103n	3	9	attracted	attract	VERB
7h149p3103n	3	10	research	research	NOUN
7h149p3103n	3	11	interest	interest	NOUN
7h149p3103n	3	12	from	from	ADP
7h149p3103n	3	13	agrochemical	agrochemical	ADJ
7h149p3103n	3	14	companies	company	NOUN
7h149p3103n	3	15	.	.	PUNCT
7h149p3103n	4	1	their	their	PRON
7h149p3103n	4	2	interesting	interesting	ADJ
7h149p3103n	4	3	nine	nine	NUM
7h149p3103n	4	4	-	-	PUNCT
7h149p3103n	4	5	membered	membered	ADJ
7h149p3103n	4	6	ring	ring	NOUN
7h149p3103n	4	7	structure	structure	NOUN
7h149p3103n	4	8	contains	contain	VERB
7h149p3103n	4	9	a	a	DET
7h149p3103n	4	10	maleic	maleic	ADJ
7h149p3103n	4	11	anhydride	anhydride	NOUN
7h149p3103n	4	12	and	and	CCONJ
7h149p3103n	4	13	a	a	DET
7h149p3103n	4	14	key	key	ADJ
7h149p3103n	4	15	exocyclic	exocyclic	NOUN
7h149p3103n	4	16	ethylidene	ethylidene	NOUN
7h149p3103n	4	17	;	;	PUNCT
7h149p3103n	4	18	this	this	DET
7h149p3103n	4	19	structure	structure	NOUN
7h149p3103n	4	20	also	also	ADV
7h149p3103n	4	21	indicates	indicate	VERB
7h149p3103n	4	22	membership	membership	NOUN
7h149p3103n	4	23	in	in	ADP
7h149p3103n	4	24	the	the	DET
7h149p3103n	4	25	nonadride	nonadride	PROPN
7h149p3103n	4	26	family	family	NOUN
7h149p3103n	4	27	.	.	PUNCT
7h149p3103n	5	1	we	we	PRON
7h149p3103n	5	2	targeted	target	VERB
7h149p3103n	5	3	this	this	DET
7h149p3103n	5	4	interesting	interesting	ADJ
7h149p3103n	5	5	structure	structure	NOUN
7h149p3103n	5	6	for	for	ADP
7h149p3103n	5	7	total	total	ADJ
7h149p3103n	5	8	synthesis	synthesis	NOUN
7h149p3103n	5	9	for	for	ADP
7h149p3103n	5	10	both	both	CCONJ
7h149p3103n	5	11	its	its	PRON
7h149p3103n	5	12	fascinating	fascinating	ADJ
7h149p3103n	5	13	biological	biological	ADJ
7h149p3103n	5	14	activity	activity	NOUN
7h149p3103n	5	15	and	and	CCONJ
7h149p3103n	5	16	its	its	PRON
7h149p3103n	5	17	highly	highly	ADV
7h149p3103n	5	18	functionalized	functionalize	VERB
7h149p3103n	5	19	structure	structure	NOUN
7h149p3103n	5	20	.	.	PUNCT
7h149p3103n	6	1	cornexistin	cornexistin	PROPN
7h149p3103n	6	2	was	be	AUX
7h149p3103n	6	3	found	find	VERB
7h149p3103n	6	4	to	to	PART
7h149p3103n	6	5	be	be	AUX
7h149p3103n	6	6	susceptible	susceptible	ADJ
7h149p3103n	6	7	to	to	ADP
7h149p3103n	6	8	retro	retro	PROPN
7h149p3103n	6	9	-	-	PUNCT
7h149p3103n	6	10	aldol	aldol	NOUN
7h149p3103n	6	11	opening	opening	NOUN
7h149p3103n	6	12	and	and	CCONJ
7h149p3103n	6	13	reclosure	reclosure	NOUN
7h149p3103n	6	14	of	of	ADP
7h149p3103n	6	15	its	its	PRON
7h149p3103n	6	16	nine	nine	NUM
7h149p3103n	6	17	-	-	PUNCT
7h149p3103n	6	18	membered	membered	ADJ
7h149p3103n	6	19	ring	ring	NOUN
7h149p3103n	6	20	by	by	ADP
7h149p3103n	6	21	workers	worker	NOUN
7h149p3103n	6	22	at	at	ADP
7h149p3103n	6	23	dow	dow	PROPN
7h149p3103n	6	24	agrosciences	agroscience	NOUN
7h149p3103n	6	25	.	.	PUNCT
7h149p3103n	7	1	we	we	PRON
7h149p3103n	7	2	targeted	target	VERB
7h149p3103n	7	3	a	a	DET
7h149p3103n	7	4	retro	retro	NOUN
7h149p3103n	7	5	-	-	PUNCT
7h149p3103n	7	6	aldol	aldol	PROPN
7h149p3103n	7	7	precursor	precursor	PROPN
7h149p3103n	7	8	through	through	ADP
7h149p3103n	7	9	a	a	DET
7h149p3103n	7	10	series	series	NOUN
7h149p3103n	7	11	of	of	ADP
7h149p3103n	7	12	aldol	aldol	ADJ
7h149p3103n	7	13	reactions	reaction	NOUN
7h149p3103n	7	14	.	.	PUNCT
7h149p3103n	8	1	utilizing	utilize	VERB
7h149p3103n	8	2	a	a	DET
7h149p3103n	8	3	johnson	johnson	PROPN
7h149p3103n	8	4	-	-	PUNCT
7h149p3103n	8	5	claisen	claisen	PROPN
7h149p3103n	8	6	rearrangement	rearrangement	NOUN
7h149p3103n	8	7	and	and	CCONJ
7h149p3103n	8	8	an	an	DET
7h149p3103n	8	9	enantioselective	enantioselective	ADJ
7h149p3103n	8	10	evans	evan	NOUN
7h149p3103n	8	11	-	-	PUNCT
7h149p3103n	8	12	type	type	NOUN
7h149p3103n	8	13	aldol	aldol	NOUN
7h149p3103n	8	14	to	to	PART
7h149p3103n	8	15	generate	generate	VERB
7h149p3103n	8	16	the	the	DET
7h149p3103n	8	17	starting	start	VERB
7h149p3103n	8	18	fragments	fragment	NOUN
7h149p3103n	8	19	,	,	PUNCT
7h149p3103n	8	20	a	a	DET
7h149p3103n	8	21	series	series	NOUN
7h149p3103n	8	22	of	of	ADP
7h149p3103n	8	23	reactions	reaction	NOUN
7h149p3103n	8	24	was	be	AUX
7h149p3103n	8	25	performed	perform	VERB
7h149p3103n	8	26	to	to	PART
7h149p3103n	8	27	find	find	VERB
7h149p3103n	8	28	the	the	DET
7h149p3103n	8	29	appropriate	appropriate	ADJ
7h149p3103n	8	30	conditions	condition	NOUN
7h149p3103n	8	31	for	for	ADP
7h149p3103n	8	32	a	a	DET
7h149p3103n	8	33	key	key	ADJ
7h149p3103n	8	34	bond	bond	NOUN
7h149p3103n	8	35	-	-	PUNCT
7h149p3103n	8	36	forming	form	VERB
7h149p3103n	8	37	ester	ester	NOUN
7h149p3103n	8	38	enolate	enolate	PROPN
7h149p3103n	8	39	aldol	aldol	PROPN
7h149p3103n	8	40	.	.	PROPN
7h149p3103n	9	1	oxidation	oxidation	NOUN
7h149p3103n	9	2	of	of	ADP
7h149p3103n	9	3	the	the	DET
7h149p3103n	9	4	product	product	NOUN
7h149p3103n	9	5	yielded	yield	VERB
7h149p3103n	9	6	a	a	DET
7h149p3103n	9	7	beta	beta	NOUN
7h149p3103n	9	8	-	-	PUNCT
7h149p3103n	9	9	ketoester	ketoester	NOUN
7h149p3103n	9	10	that	that	PRON
7h149p3103n	9	11	contained	contain	VERB
7h149p3103n	9	12	the	the	DET
7h149p3103n	9	13	complete	complete	ADJ
7h149p3103n	9	14	carbon	carbon	NOUN
7h149p3103n	9	15	skeleton	skeleton	NOUN
7h149p3103n	9	16	of	of	ADP
7h149p3103n	9	17	cornexistin	cornexistin	PROPN
7h149p3103n	9	18	.	.	PUNCT
7h149p3103n	10	1	previous	previous	ADJ
7h149p3103n	10	2	progress	progress	NOUN
7h149p3103n	10	3	towards	towards	ADP
7h149p3103n	10	4	cornexistin	cornexistin	PROPN
7h149p3103n	10	5	included	include	VERB
7h149p3103n	10	6	the	the	DET
7h149p3103n	10	7	use	use	NOUN
7h149p3103n	10	8	of	of	ADP
7h149p3103n	10	9	a	a	DET
7h149p3103n	10	10	diels	diel	NOUN
7h149p3103n	10	11	-	-	PUNCT
7h149p3103n	10	12	alder	alder	ADJ
7h149p3103n	10	13	reaction	reaction	NOUN
7h149p3103n	10	14	to	to	PART
7h149p3103n	10	15	generate	generate	VERB
7h149p3103n	10	16	a	a	DET
7h149p3103n	10	17	[	[	PUNCT
7h149p3103n	10	18	6.5	6.5	NUM
7h149p3103n	10	19	]	]	PUNCT
7h149p3103n	10	20	bicyclic	bicyclic	NOUN
7h149p3103n	10	21	system	system	NOUN
7h149p3103n	10	22	that	that	PRON
7h149p3103n	10	23	was	be	AUX
7h149p3103n	10	24	oxidatively	oxidatively	ADV
7h149p3103n	10	25	cleaved	cleave	VERB
7h149p3103n	10	26	to	to	PART
7h149p3103n	10	27	deliver	deliver	VERB
7h149p3103n	10	28	a	a	DET
7h149p3103n	10	29	cyclononene	cyclononene	ADJ
7h149p3103n	10	30	diketone	diketone	NOUN
7h149p3103n	10	31	.	.	PUNCT
7h149p3103n	11	1	during	during	ADP
7h149p3103n	11	2	the	the	DET
7h149p3103n	11	3	course	course	NOUN
7h149p3103n	11	4	of	of	ADP
7h149p3103n	11	5	analyzing	analyze	VERB
7h149p3103n	11	6	the	the	DET
7h149p3103n	11	7	relative	relative	ADJ
7h149p3103n	11	8	stereochemistry	stereochemistry	NOUN
7h149p3103n	11	9	of	of	ADP
7h149p3103n	11	10	the	the	DET
7h149p3103n	11	11	diels	diel	NOUN
7h149p3103n	11	12	-	-	PUNCT
7h149p3103n	11	13	alder	alder	NOUN
7h149p3103n	11	14	reaction	reaction	NOUN
7h149p3103n	11	15	,	,	PUNCT
7h149p3103n	11	16	analog	analog	NOUN
7h149p3103n	11	17	synthesis	synthesis	NOUN
7h149p3103n	11	18	and	and	CCONJ
7h149p3103n	11	19	x	x	NOUN
7h149p3103n	11	20	-	-	NOUN
7h149p3103n	11	21	ray	ray	NOUN
7h149p3103n	11	22	crystallography	crystallography	NOUN
7h149p3103n	11	23	was	be	AUX
7h149p3103n	11	24	used	use	VERB
7h149p3103n	11	25	to	to	PART
7h149p3103n	11	26	unambiguously	unambiguously	ADV
7h149p3103n	11	27	determine	determine	VERB
7h149p3103n	11	28	the	the	DET
7h149p3103n	11	29	structure	structure	NOUN
7h149p3103n	11	30	of	of	ADP
7h149p3103n	11	31	the	the	DET
7h149p3103n	11	32	cycloadduct	cycloadduct	NOUN
7h149p3103n	11	33	.	.	PUNCT
7h149p3103n	12	1	through	through	ADP
7h149p3103n	12	2	ozonolysis	ozonolysis	NOUN
7h149p3103n	12	3	,	,	PUNCT
7h149p3103n	12	4	regioselective	regioselective	ADJ
7h149p3103n	12	5	titanium	titanium	NOUN
7h149p3103n	12	6	-	-	PUNCT
7h149p3103n	12	7	mediated	mediate	VERB
7h149p3103n	12	8	olefination	olefination	NOUN
7h149p3103n	12	9	and	and	CCONJ
7h149p3103n	12	10	further	further	ADJ
7h149p3103n	12	11	functional	functional	ADJ
7h149p3103n	12	12	group	group	NOUN
7h149p3103n	12	13	manipulation	manipulation	NOUN
7h149p3103n	12	14	,	,	PUNCT
7h149p3103n	12	15	highly	highly	ADV
7h149p3103n	12	16	complex	complex	ADJ
7h149p3103n	12	17	nine	nine	NUM
7h149p3103n	12	18	-	-	PUNCT
7h149p3103n	12	19	membered	membered	NOUN
7h149p3103n	12	20	ring	ring	NOUN
7h149p3103n	12	21	structures	structure	NOUN
7h149p3103n	12	22	were	be	AUX
7h149p3103n	12	23	generated	generate	VERB
7h149p3103n	12	24	.	.	PUNCT
7h149p3103n	13	1	finally	finally	ADV
7h149p3103n	13	2	,	,	PUNCT
7h149p3103n	13	3	ring	ring	NOUN
7h149p3103n	13	4	-	-	PUNCT
7h149p3103n	13	5	closing	closing	NOUN
7h149p3103n	13	6	metathesis	metathesis	NOUN
7h149p3103n	13	7	and	and	CCONJ
7h149p3103n	13	8	tamaofleming	tamaofleme	VERB
7h149p3103n	13	9	oxidation	oxidation	NOUN
7h149p3103n	13	10	produced	produce	VERB
7h149p3103n	13	11	the	the	DET
7h149p3103n	13	12	key	key	ADJ
7h149p3103n	13	13	ethylidene	ethylidene	ADJ
7h149p3103n	13	14	moiety	moiety	NOUN
7h149p3103n	13	15	of	of	ADP
7h149p3103n	13	16	both	both	CCONJ
7h149p3103n	13	17	cornexistin	cornexistin	ADJ
7h149p3103n	13	18	and	and	CCONJ
7h149p3103n	13	19	hydroxycornexistin	hydroxycornexistin	NOUN
7h149p3103n	13	20	.	.	PUNCT