id	sid	tid	token	lemma	pos
7h149p30z94	1	1	numerous	numerous	ADJ
7h149p30z94	1	2	polyketide	polyketide	NOUN
7h149p30z94	1	3	natural	natural	ADJ
7h149p30z94	1	4	products	product	NOUN
7h149p30z94	1	5	contain	contain	VERB
7h149p30z94	1	6	methyl	methyl	NOUN
7h149p30z94	1	7	ether	ether	NOUN
7h149p30z94	1	8	functionality	functionality	NOUN
7h149p30z94	1	9	generated	generate	VERB
7h149p30z94	1	10	by	by	ADP
7h149p30z94	1	11	either	either	DET
7h149p30z94	1	12	methoxymalonyl	methoxymalonyl	ADJ
7h149p30z94	1	13	extender	extender	NOUN
7h149p30z94	1	14	units	unit	NOUN
7h149p30z94	1	15	or	or	CCONJ
7h149p30z94	1	16	a	a	DET
7h149p30z94	1	17	selective	selective	ADJ
7h149p30z94	1	18	o	o	ADJ
7h149p30z94	1	19	-	-	NOUN
7h149p30z94	1	20	methyl	methyl	NOUN
7h149p30z94	1	21	transferase	transferase	NOUN
7h149p30z94	1	22	associated	associate	VERB
7h149p30z94	1	23	with	with	ADP
7h149p30z94	1	24	the	the	DET
7h149p30z94	1	25	polyketide	polyketide	NOUN
7h149p30z94	1	26	synthase	synthase	NOUN
7h149p30z94	1	27	(	(	PUNCT
7h149p30z94	1	28	pks	pks	NOUN
7h149p30z94	1	29	)	)	PUNCT
7h149p30z94	1	30	gene	gene	NOUN
7h149p30z94	1	31	cluster	cluster	NOUN
7h149p30z94	1	32	.	.	PUNCT
7h149p30z94	2	1	in	in	ADP
7h149p30z94	2	2	laboratory	laboratory	NOUN
7h149p30z94	2	3	syntheses	synthesis	NOUN
7h149p30z94	2	4	of	of	ADP
7h149p30z94	2	5	such	such	ADJ
7h149p30z94	2	6	natural	natural	ADJ
7h149p30z94	2	7	products	product	NOUN
7h149p30z94	2	8	,	,	PUNCT
7h149p30z94	2	9	discrete	discrete	ADJ
7h149p30z94	2	10	steps	step	NOUN
7h149p30z94	2	11	for	for	ADP
7h149p30z94	2	12	generating	generate	VERB
7h149p30z94	2	13	a	a	DET
7h149p30z94	2	14	hydroxyl	hydroxyl	PROPN
7h149p30z94	2	15	stereogenic	stereogenic	NOUN
7h149p30z94	2	16	center	center	NOUN
7h149p30z94	2	17	and	and	CCONJ
7h149p30z94	2	18	subsequent	subsequent	ADJ
7h149p30z94	2	19	methylation	methylation	NOUN
7h149p30z94	2	20	are	be	AUX
7h149p30z94	2	21	typically	typically	ADV
7h149p30z94	2	22	bracketed	bracket	VERB
7h149p30z94	2	23	by	by	ADP
7h149p30z94	2	24	additional	additional	ADJ
7h149p30z94	2	25	protecting	protect	VERB
7h149p30z94	2	26	group	group	NOUN
7h149p30z94	2	27	manipulation	manipulation	NOUN
7h149p30z94	2	28	steps	step	NOUN
7h149p30z94	2	29	.	.	PUNCT
7h149p30z94	3	1	a	a	DET
7h149p30z94	3	2	fundamentally	fundamentally	ADV
7h149p30z94	3	3	new	new	ADJ
7h149p30z94	3	4	tactic	tactic	NOUN
7h149p30z94	3	5	has	have	AUX
7h149p30z94	3	6	been	be	AUX
7h149p30z94	3	7	designed	design	VERB
7h149p30z94	3	8	and	and	CCONJ
7h149p30z94	3	9	developed	develop	VERB
7h149p30z94	3	10	.	.	PUNCT
7h149p30z94	4	1	this	this	DET
7h149p30z94	4	2	methodology	methodology	NOUN
7h149p30z94	4	3	is	be	AUX
7h149p30z94	4	4	capable	capable	ADJ
7h149p30z94	4	5	of	of	ADP
7h149p30z94	4	6	significantly	significantly	ADV
7h149p30z94	4	7	simplifying	simplify	VERB
7h149p30z94	4	8	the	the	DET
7h149p30z94	4	9	creation	creation	NOUN
7h149p30z94	4	10	of	of	ADP
7h149p30z94	4	11	functionality	functionality	NOUN
7h149p30z94	4	12	common	common	ADJ
7h149p30z94	4	13	to	to	ADP
7h149p30z94	4	14	polyketide	polyketide	NOUN
7h149p30z94	4	15	natural	natural	ADJ
7h149p30z94	4	16	products	product	NOUN
7h149p30z94	4	17	by	by	ADP
7h149p30z94	4	18	controlling	control	VERB
7h149p30z94	4	19	the	the	DET
7h149p30z94	4	20	generation	generation	NOUN
7h149p30z94	4	21	of	of	ADP
7h149p30z94	4	22	a	a	DET
7h149p30z94	4	23	stereogenic	stereogenic	NOUN
7h149p30z94	4	24	center	center	NOUN
7h149p30z94	4	25	simultaneous	simultaneous	ADJ
7h149p30z94	4	26	with	with	ADP
7h149p30z94	4	27	ether	ether	NOUN
7h149p30z94	4	28	incorporation	incorporation	NOUN
7h149p30z94	4	29	.	.	PUNCT
7h149p30z94	5	1	in	in	ADP
7h149p30z94	5	2	this	this	DET
7h149p30z94	5	3	thesis	thesis	NOUN
7h149p30z94	5	4	it	it	PRON
7h149p30z94	5	5	is	be	AUX
7h149p30z94	5	6	demonstrated	demonstrate	VERB
7h149p30z94	5	7	that	that	SCONJ
7h149p30z94	5	8	alkoxymethyl	alkoxymethyl	NOUN
7h149p30z94	5	9	-	-	PUNCT
7h149p30z94	5	10	protected	protect	VERB
7h149p30z94	5	11	homoallylic	homoallylic	ADJ
7h149p30z94	5	12	alcohols	alcohol	NOUN
7h149p30z94	5	13	,	,	PUNCT
7h149p30z94	5	14	under	under	ADP
7h149p30z94	5	15	the	the	DET
7h149p30z94	5	16	treatment	treatment	NOUN
7h149p30z94	5	17	of	of	ADP
7h149p30z94	5	18	iodine	iodine	NOUN
7h149p30z94	5	19	monochloride	monochloride	PROPN
7h149p30z94	5	20	(	(	PUNCT
7h149p30z94	5	21	icl	icl	PROPN
7h149p30z94	5	22	)	)	PUNCT
7h149p30z94	5	23	,	,	PUNCT
7h149p30z94	5	24	undergo	undergo	VERB
7h149p30z94	5	25	efficient	efficient	ADJ
7h149p30z94	5	26	alkyl	alkyl	ADJ
7h149p30z94	5	27	ether	ether	NOUN
7h149p30z94	5	28	(	(	PUNCT
7h149p30z94	5	29	for	for	ADP
7h149p30z94	5	30	example	example	NOUN
7h149p30z94	5	31	,	,	PUNCT
7h149p30z94	5	32	methyl	methyl	NOUN
7h149p30z94	5	33	and	and	CCONJ
7h149p30z94	5	34	benzyl	benzyl	NOUN
7h149p30z94	5	35	)	)	PUNCT
7h149p30z94	5	36	transfer	transfer	NOUN
7h149p30z94	5	37	to	to	PART
7h149p30z94	5	38	afford	afford	VERB
7h149p30z94	5	39	syn-1,3	syn-1,3	PROPN
7h149p30z94	5	40	-	-	PUNCT
7h149p30z94	5	41	diol	diol	NOUN
7h149p30z94	5	42	monoalkyl	monoalkyl	VERB
7h149p30z94	5	43	ethers	ether	NOUN
7h149p30z94	5	44	in	in	ADP
7h149p30z94	5	45	good	good	ADJ
7h149p30z94	5	46	yields	yield	NOUN
7h149p30z94	5	47	and	and	CCONJ
7h149p30z94	5	48	with	with	ADP
7h149p30z94	5	49	excellent	excellent	ADJ
7h149p30z94	5	50	diastereocontrol	diastereocontrol	NOUN
7h149p30z94	5	51	.	.	PUNCT
7h149p30z94	6	1	the	the	DET
7h149p30z94	6	2	proposed	propose	VERB
7h149p30z94	6	3	reactive	reactive	ADJ
7h149p30z94	6	4	intermediate	intermediate	NOUN
7h149p30z94	6	5	,	,	PUNCT
7h149p30z94	6	6	bearing	bear	VERB
7h149p30z94	6	7	a	a	DET
7h149p30z94	6	8	chloromethyl	chloromethyl	NOUN
7h149p30z94	6	9	functionality	functionality	NOUN
7h149p30z94	6	10	,	,	PUNCT
7h149p30z94	6	11	was	be	AUX
7h149p30z94	6	12	proven	prove	VERB
7h149p30z94	6	13	by	by	ADP
7h149p30z94	6	14	nmr	nmr	PROPN
7h149p30z94	6	15	analysis	analysis	NOUN
7h149p30z94	6	16	.	.	PUNCT
7h149p30z94	7	1	it	it	PRON
7h149p30z94	7	2	was	be	AUX
7h149p30z94	7	3	also	also	ADV
7h149p30z94	7	4	observed	observe	VERB
7h149p30z94	7	5	that	that	SCONJ
7h149p30z94	7	6	this	this	DET
7h149p30z94	7	7	intermediate	intermediate	NOUN
7h149p30z94	7	8	has	have	VERB
7h149p30z94	7	9	decent	decent	ADJ
7h149p30z94	7	10	stability	stability	NOUN
7h149p30z94	7	11	so	so	SCONJ
7h149p30z94	7	12	that	that	SCONJ
7h149p30z94	7	13	it	it	PRON
7h149p30z94	7	14	's	be	AUX
7h149p30z94	7	15	reactivity	reactivity	NOUN
7h149p30z94	7	16	can	can	AUX
7h149p30z94	7	17	be	be	AUX
7h149p30z94	7	18	fully	fully	ADV
7h149p30z94	7	19	explored	explore	VERB
7h149p30z94	7	20	,	,	PUNCT
7h149p30z94	7	21	allowing	allow	VERB
7h149p30z94	7	22	formation	formation	NOUN
7h149p30z94	7	23	of	of	ADP
7h149p30z94	7	24	a	a	DET
7h149p30z94	7	25	variety	variety	NOUN
7h149p30z94	7	26	of	of	ADP
7h149p30z94	7	27	synthetically	synthetically	ADV
7h149p30z94	7	28	useful	useful	ADJ
7h149p30z94	7	29	fragments	fragment	NOUN
7h149p30z94	7	30	that	that	PRON
7h149p30z94	7	31	can	can	AUX
7h149p30z94	7	32	potentially	potentially	ADV
7h149p30z94	7	33	be	be	AUX
7h149p30z94	7	34	used	use	VERB
7h149p30z94	7	35	in	in	ADP
7h149p30z94	7	36	syntheses	synthesis	NOUN
7h149p30z94	7	37	of	of	ADP
7h149p30z94	7	38	complex	complex	ADJ
7h149p30z94	7	39	molecules	molecule	NOUN
7h149p30z94	7	40	.	.	PUNCT
7h149p30z94	8	1	the	the	DET
7h149p30z94	8	2	mechanism	mechanism	NOUN
7h149p30z94	8	3	of	of	ADP
7h149p30z94	8	4	the	the	DET
7h149p30z94	8	5	ether	ether	NOUN
7h149p30z94	8	6	transfer	transfer	NOUN
7h149p30z94	8	7	reaction	reaction	NOUN
7h149p30z94	8	8	initiated	initiate	VERB
7h149p30z94	8	9	by	by	ADP
7h149p30z94	8	10	n	n	NOUN
7h149p30z94	8	11	-	-	PUNCT
7h149p30z94	8	12	iodosuccinimide	iodosuccinimide	ADJ
7h149p30z94	8	13	(	(	PUNCT
7h149p30z94	8	14	nis	nis	X
7h149p30z94	8	15	)	)	PUNCT
7h149p30z94	8	16	has	have	AUX
7h149p30z94	8	17	also	also	ADV
7h149p30z94	8	18	been	be	AUX
7h149p30z94	8	19	studied	study	VERB
7h149p30z94	8	20	.	.	PUNCT
7h149p30z94	9	1	by	by	ADP
7h149p30z94	9	2	incorporating	incorporate	VERB
7h149p30z94	9	3	isotopic	isotopic	ADJ
7h149p30z94	9	4	labels	label	NOUN
7h149p30z94	9	5	in	in	ADP
7h149p30z94	9	6	the	the	DET
7h149p30z94	9	7	products	product	NOUN
7h149p30z94	9	8	followed	follow	VERB
7h149p30z94	9	9	by	by	ADP
7h149p30z94	9	10	product	product	NOUN
7h149p30z94	9	11	analyses	analysis	NOUN
7h149p30z94	9	12	with	with	ADP
7h149p30z94	9	13	nmr	nmr	NOUN
7h149p30z94	9	14	spectroscopy	spectroscopy	NOUN
7h149p30z94	9	15	and	and	CCONJ
7h149p30z94	9	16	comparison	comparison	NOUN
7h149p30z94	9	17	with	with	ADP
7h149p30z94	9	18	the	the	DET
7h149p30z94	9	19	results	result	NOUN
7h149p30z94	9	20	from	from	ADP
7h149p30z94	9	21	non	non	ADJ
7h149p30z94	9	22	-	-	ADJ
7h149p30z94	9	23	labeled	label	VERB
7h149p30z94	9	24	experiments	experiment	NOUN
7h149p30z94	9	25	,	,	PUNCT
7h149p30z94	9	26	relative	relative	ADJ
7h149p30z94	9	27	rates	rate	NOUN
7h149p30z94	9	28	of	of	ADP
7h149p30z94	9	29	different	different	ADJ
7h149p30z94	9	30	pathways	pathway	NOUN
7h149p30z94	9	31	as	as	ADV
7h149p30z94	9	32	well	well	ADV
7h149p30z94	9	33	as	as	ADP
7h149p30z94	9	34	the	the	DET
7h149p30z94	9	35	stereoselectivity	stereoselectivity	ADJ
7h149p30z94	9	36	preference	preference	NOUN
7h149p30z94	9	37	within	within	ADP
7h149p30z94	9	38	each	each	PRON
7h149p30z94	9	39	has	have	AUX
7h149p30z94	9	40	been	be	AUX
7h149p30z94	9	41	investigated	investigate	VERB
7h149p30z94	9	42	and	and	CCONJ
7h149p30z94	9	43	identified	identify	VERB
7h149p30z94	9	44	.	.	PUNCT
7h149p30z94	10	1	this	this	DET
7h149p30z94	10	2	stereoselective	stereoselective	ADJ
7h149p30z94	10	3	ether	ether	NOUN
7h149p30z94	10	4	transfer	transfer	NOUN
7h149p30z94	10	5	methodology	methodology	NOUN
7h149p30z94	10	6	has	have	AUX
7h149p30z94	10	7	also	also	ADV
7h149p30z94	10	8	been	be	AUX
7h149p30z94	10	9	successfully	successfully	ADV
7h149p30z94	10	10	applied	apply	VERB
7h149p30z94	10	11	to	to	ADP
7h149p30z94	10	12	the	the	DET
7h149p30z94	10	13	total	total	ADJ
7h149p30z94	10	14	synthesis	synthesis	NOUN
7h149p30z94	10	15	of	of	ADP
7h149p30z94	10	16	the	the	DET
7h149p30z94	10	17	family	family	NOUN
7h149p30z94	10	18	of	of	ADP
7h149p30z94	10	19	all	all	DET
7h149p30z94	10	20	-	-	PUNCT
7h149p30z94	10	21	syn	syn	NOUN
7h149p30z94	10	22	isotactic	isotactic	ADJ
7h149p30z94	10	23	polymethoxy	polymethoxy	ADJ
7h149p30z94	10	24	natural	natural	ADJ
7h149p30z94	10	25	products	product	NOUN
7h149p30z94	10	26	.	.	PUNCT
7h149p30z94	11	1	two	two	NUM
7h149p30z94	11	2	syntheses	synthesis	NOUN
7h149p30z94	11	3	examples	example	NOUN
7h149p30z94	11	4	of	of	ADP
7h149p30z94	11	5	this	this	DET
7h149p30z94	11	6	product	product	NOUN
7h149p30z94	11	7	family	family	NOUN
7h149p30z94	11	8	are	be	AUX
7h149p30z94	11	9	shown	show	VERB
7h149p30z94	11	10	in	in	ADP
7h149p30z94	11	11	this	this	DET
7h149p30z94	11	12	thesis	thesis	NOUN
7h149p30z94	11	13	.	.	PUNCT
7h149p30z94	12	1	in	in	ADP
7h149p30z94	12	2	addition	addition	NOUN
7h149p30z94	12	3	,	,	PUNCT
7h149p30z94	12	4	a	a	DET
7h149p30z94	12	5	generalized	generalized	ADJ
7h149p30z94	12	6	,	,	PUNCT
7h149p30z94	12	7	convergent	convergent	ADJ
7h149p30z94	12	8	synthetic	synthetic	ADJ
7h149p30z94	12	9	strategy	strategy	NOUN
7h149p30z94	12	10	aiming	aim	VERB
7h149p30z94	12	11	toward	toward	ADP
7h149p30z94	12	12	synthesis	synthesis	NOUN
7h149p30z94	12	13	of	of	ADP
7h149p30z94	12	14	any	any	DET
7h149p30z94	12	15	member	member	NOUN
7h149p30z94	12	16	of	of	ADP
7h149p30z94	12	17	these	these	DET
7h149p30z94	12	18	polymer	polymer	NOUN
7h149p30z94	12	19	-	-	PUNCT
7h149p30z94	12	20	like	like	ADJ
7h149p30z94	12	21	compounds	compound	NOUN
7h149p30z94	12	22	is	be	AUX
7h149p30z94	12	23	also	also	ADV
7h149p30z94	12	24	proposed	propose	VERB
7h149p30z94	12	25	.	.	PUNCT