id	sid	tid	token	lemma	pos
6m311n81n4g	1	1	this	this	DET
6m311n81n4g	1	2	dissertation	dissertation	NOUN
6m311n81n4g	1	3	describes	describe	VERB
6m311n81n4g	1	4	the	the	DET
6m311n81n4g	1	5	development	development	NOUN
6m311n81n4g	1	6	and	and	CCONJ
6m311n81n4g	1	7	application	application	NOUN
6m311n81n4g	1	8	of	of	ADP
6m311n81n4g	1	9	surface	surface	NOUN
6m311n81n4g	1	10	-	-	PUNCT
6m311n81n4g	1	11	enhanced	enhance	VERB
6m311n81n4g	1	12	hyper	hyper	ADJ
6m311n81n4g	1	13	-	-	ADJ
6m311n81n4g	1	14	raman	raman	ADJ
6m311n81n4g	1	15	scattering	scattering	NOUN
6m311n81n4g	1	16	(	(	PUNCT
6m311n81n4g	1	17	sehrs	sehrs	PROPN
6m311n81n4g	1	18	)	)	PUNCT
6m311n81n4g	1	19	as	as	ADP
6m311n81n4g	1	20	a	a	DET
6m311n81n4g	1	21	nonlinear	nonlinear	ADJ
6m311n81n4g	1	22	spectroscopic	spectroscopic	ADJ
6m311n81n4g	1	23	probe	probe	NOUN
6m311n81n4g	1	24	in	in	ADP
6m311n81n4g	1	25	three	three	NUM
6m311n81n4g	1	26	studies	study	NOUN
6m311n81n4g	1	27	.	.	PUNCT
6m311n81n4g	2	1	the	the	DET
6m311n81n4g	2	2	first	first	ADJ
6m311n81n4g	2	3	study	study	NOUN
6m311n81n4g	2	4	explores	explore	VERB
6m311n81n4g	2	5	the	the	DET
6m311n81n4g	2	6	measurement	measurement	NOUN
6m311n81n4g	2	7	of	of	ADP
6m311n81n4g	2	8	sehrs	sehrs	PROPN
6m311n81n4g	2	9	from	from	ADP
6m311n81n4g	2	10	short	short	ADJ
6m311n81n4g	2	11	-	-	PUNCT
6m311n81n4g	2	12	wave	wave	NOUN
6m311n81n4g	2	13	infrared	infrared	NOUN
6m311n81n4g	2	14	(	(	PUNCT
6m311n81n4g	2	15	swir	swir	NOUN
6m311n81n4g	2	16	)	)	PUNCT
6m311n81n4g	2	17	excitation	excitation	NOUN
6m311n81n4g	2	18	sources	source	NOUN
6m311n81n4g	2	19	.	.	PUNCT
6m311n81n4g	3	1	ultrasensitive	ultrasensitive	ADJ
6m311n81n4g	3	2	detection	detection	NOUN
6m311n81n4g	3	3	of	of	ADP
6m311n81n4g	3	4	the	the	DET
6m311n81n4g	3	5	scattered	scatter	VERB
6m311n81n4g	3	6	signal	signal	NOUN
6m311n81n4g	3	7	,	,	PUNCT
6m311n81n4g	3	8	which	which	PRON
6m311n81n4g	3	9	occurs	occur	VERB
6m311n81n4g	3	10	in	in	ADP
6m311n81n4g	3	11	a	a	DET
6m311n81n4g	3	12	"	"	PUNCT
6m311n81n4g	3	13	biological	biological	ADJ
6m311n81n4g	3	14	transparent	transparent	ADJ
6m311n81n4g	3	15	window	window	NOUN
6m311n81n4g	3	16	,	,	PUNCT
6m311n81n4g	3	17	"	"	PUNCT
6m311n81n4g	3	18	is	be	AUX
6m311n81n4g	3	19	accomplished	accomplish	VERB
6m311n81n4g	3	20	for	for	ADP
6m311n81n4g	3	21	three	three	NUM
6m311n81n4g	3	22	analyte	analyte	ADJ
6m311n81n4g	3	23	molecules	molecule	NOUN
6m311n81n4g	3	24	under	under	ADP
6m311n81n4g	3	25	modest	modest	ADJ
6m311n81n4g	3	26	experimental	experimental	ADJ
6m311n81n4g	3	27	conditions	condition	NOUN
6m311n81n4g	3	28	.	.	PUNCT
6m311n81n4g	4	1	these	these	DET
6m311n81n4g	4	2	results	result	NOUN
6m311n81n4g	4	3	demonstrate	demonstrate	VERB
6m311n81n4g	4	4	that	that	SCONJ
6m311n81n4g	4	5	sehrs	sehrs	PROPN
6m311n81n4g	4	6	-	-	PUNCT
6m311n81n4g	4	7	based	base	VERB
6m311n81n4g	4	8	methods	method	NOUN
6m311n81n4g	4	9	have	have	VERB
6m311n81n4g	4	10	compelling	compelling	ADJ
6m311n81n4g	4	11	potential	potential	NOUN
6m311n81n4g	4	12	for	for	ADP
6m311n81n4g	4	13	chemical	chemical	ADJ
6m311n81n4g	4	14	analysis	analysis	NOUN
6m311n81n4g	4	15	and	and	CCONJ
6m311n81n4g	4	16	molecular	molecular	ADJ
6m311n81n4g	4	17	imaging.the	imaging.the	DET
6m311n81n4g	4	18	second	second	ADJ
6m311n81n4g	4	19	study	study	NOUN
6m311n81n4g	4	20	compares	compare	VERB
6m311n81n4g	4	21	resonance	resonance	NOUN
6m311n81n4g	4	22	hyper	hyper	ADJ
6m311n81n4g	4	23	-	-	ADJ
6m311n81n4g	4	24	raman	raman	ADJ
6m311n81n4g	4	25	scattering	scattering	NOUN
6m311n81n4g	4	26	of	of	ADP
6m311n81n4g	4	27	crystal	crystal	PROPN
6m311n81n4g	4	28	violet	violet	PROPN
6m311n81n4g	4	29	from	from	ADP
6m311n81n4g	4	30	experimental	experimental	ADJ
6m311n81n4g	4	31	sehrs	sehrs	PROPN
6m311n81n4g	4	32	measurements	measurement	NOUN
6m311n81n4g	4	33	and	and	CCONJ
6m311n81n4g	4	34	theoretical	theoretical	ADJ
6m311n81n4g	4	35	calculations	calculation	NOUN
6m311n81n4g	4	36	over	over	ADP
6m311n81n4g	4	37	its	its	PRON
6m311n81n4g	4	38	two	two	NUM
6m311n81n4g	4	39	lowest	lowest	ADV
6m311n81n4g	4	40	-	-	PUNCT
6m311n81n4g	4	41	lying	lie	VERB
6m311n81n4g	4	42	electronic	electronic	ADJ
6m311n81n4g	4	43	states	state	NOUN
6m311n81n4g	4	44	(	(	PUNCT
6m311n81n4g	4	45	12,700	12,700	NUM
6m311n81n4g	4	46	-	-	SYM
6m311n81n4g	4	47	27,400	27,400	NUM
6m311n81n4g	4	48	cm-1	cm-1	X
6m311n81n4g	4	49	)	)	PUNCT
6m311n81n4g	4	50	.	.	PUNCT
6m311n81n4g	5	1	the	the	DET
6m311n81n4g	5	2	qualitative	qualitative	ADJ
6m311n81n4g	5	3	agreement	agreement	NOUN
6m311n81n4g	5	4	between	between	ADP
6m311n81n4g	5	5	theory	theory	NOUN
6m311n81n4g	5	6	and	and	CCONJ
6m311n81n4g	5	7	experiment	experiment	NOUN
6m311n81n4g	5	8	indicates	indicate	VERB
6m311n81n4g	5	9	that	that	SCONJ
6m311n81n4g	5	10	first	first	ADJ
6m311n81n4g	5	11	-	-	PUNCT
6m311n81n4g	5	12	principles	principle	NOUN
6m311n81n4g	5	13	calculations	calculation	NOUN
6m311n81n4g	5	14	capture	capture	VERB
6m311n81n4g	5	15	many	many	ADJ
6m311n81n4g	5	16	of	of	ADP
6m311n81n4g	5	17	the	the	DET
6m311n81n4g	5	18	complex	complex	ADJ
6m311n81n4g	5	19	resonance	resonance	NOUN
6m311n81n4g	5	20	contributions	contribution	NOUN
6m311n81n4g	5	21	in	in	ADP
6m311n81n4g	5	22	this	this	DET
6m311n81n4g	5	23	prototypical	prototypical	ADJ
6m311n81n4g	5	24	octupolar	octupolar	ADJ
6m311n81n4g	5	25	system	system	NOUN
6m311n81n4g	5	26	.	.	PUNCT
6m311n81n4g	6	1	the	the	DET
6m311n81n4g	6	2	discrepancies	discrepancy	NOUN
6m311n81n4g	6	3	between	between	ADP
6m311n81n4g	6	4	theory	theory	NOUN
6m311n81n4g	6	5	and	and	CCONJ
6m311n81n4g	6	6	experiment	experiment	NOUN
6m311n81n4g	6	7	are	be	AUX
6m311n81n4g	6	8	investigated	investigate	VERB
6m311n81n4g	6	9	by	by	ADP
6m311n81n4g	6	10	comparing	compare	VERB
6m311n81n4g	6	11	spectra	spectra	NOUN
6m311n81n4g	6	12	obtained	obtain	VERB
6m311n81n4g	6	13	in	in	ADP
6m311n81n4g	6	14	different	different	ADJ
6m311n81n4g	6	15	local	local	ADJ
6m311n81n4g	6	16	environments	environment	NOUN
6m311n81n4g	6	17	as	as	ADV
6m311n81n4g	6	18	well	well	ADV
6m311n81n4g	6	19	as	as	ADP
6m311n81n4g	6	20	from	from	ADP
6m311n81n4g	6	21	higher	high	ADJ
6m311n81n4g	6	22	-	-	PUNCT
6m311n81n4g	6	23	order	order	NOUN
6m311n81n4g	6	24	surface	surface	NOUN
6m311n81n4g	6	25	-	-	PUNCT
6m311n81n4g	6	26	enhanced	enhance	VERB
6m311n81n4g	6	27	spectroscopies	spectroscopy	NOUN
6m311n81n4g	6	28	.	.	PUNCT
6m311n81n4g	7	1	a	a	DET
6m311n81n4g	7	2	comparison	comparison	NOUN
6m311n81n4g	7	3	between	between	ADP
6m311n81n4g	7	4	relative	relative	ADJ
6m311n81n4g	7	5	sehrs	sehrs	ADJ
6m311n81n4g	7	6	band	band	NOUN
6m311n81n4g	7	7	ratios	ratio	NOUN
6m311n81n4g	7	8	plotted	plot	VERB
6m311n81n4g	7	9	as	as	ADP
6m311n81n4g	7	10	a	a	DET
6m311n81n4g	7	11	function	function	NOUN
6m311n81n4g	7	12	of	of	ADP
6m311n81n4g	7	13	excitation	excitation	NOUN
6m311n81n4g	7	14	wavelength	wavelength	NOUN
6m311n81n4g	7	15	and	and	CCONJ
6m311n81n4g	7	16	crystal	crystal	PROPN
6m311n81n4g	7	17	violet	violet	PROPN
6m311n81n4g	7	18	's	's	PART
6m311n81n4g	7	19	absorption	absorption	NOUN
6m311n81n4g	7	20	spectra	spectra	NOUN
6m311n81n4g	7	21	elucidates	elucidate	VERB
6m311n81n4g	7	22	correlations	correlation	NOUN
6m311n81n4g	7	23	between	between	ADP
6m311n81n4g	7	24	groups	group	NOUN
6m311n81n4g	7	25	of	of	ADP
6m311n81n4g	7	26	vibrations	vibration	NOUN
6m311n81n4g	7	27	and	and	CCONJ
6m311n81n4g	7	28	the	the	DET
6m311n81n4g	7	29	excited	excited	ADJ
6m311n81n4g	7	30	-	-	PUNCT
6m311n81n4g	7	31	electronic	electronic	ADJ
6m311n81n4g	7	32	states	state	NOUN
6m311n81n4g	7	33	.	.	PUNCT
6m311n81n4g	8	1	the	the	DET
6m311n81n4g	8	2	results	result	NOUN
6m311n81n4g	8	3	suggest	suggest	VERB
6m311n81n4g	8	4	that	that	SCONJ
6m311n81n4g	8	5	the	the	DET
6m311n81n4g	8	6	spectral	spectral	ADJ
6m311n81n4g	8	7	features	feature	NOUN
6m311n81n4g	8	8	across	across	ADP
6m311n81n4g	8	9	the	the	DET
6m311n81n4g	8	10	range	range	NOUN
6m311n81n4g	8	11	of	of	ADP
6m311n81n4g	8	12	resonance	resonance	NOUN
6m311n81n4g	8	13	excitation	excitation	NOUN
6m311n81n4g	8	14	energies	energy	NOUN
6m311n81n4g	8	15	(	(	PUNCT
6m311n81n4g	8	16	~15,500	~15,500	NOUN
6m311n81n4g	8	17	-	-	SYM
6m311n81n4g	8	18	27,400	27,400	NUM
6m311n81n4g	8	19	cm-1	cm-1	NUM
6m311n81n4g	8	20	)	)	PUNCT
6m311n81n4g	8	21	are	be	AUX
6m311n81n4g	8	22	dominated	dominate	VERB
6m311n81n4g	8	23	by	by	ADP
6m311n81n4g	8	24	strong	strong	ADJ
6m311n81n4g	8	25	a	a	DET
6m311n81n4g	8	26	-	-	PUNCT
6m311n81n4g	8	27	term	term	NOUN
6m311n81n4g	8	28	scattering	scattering	NOUN
6m311n81n4g	8	29	.	.	PUNCT
6m311n81n4g	9	1	the	the	DET
6m311n81n4g	9	2	final	final	ADJ
6m311n81n4g	9	3	study	study	NOUN
6m311n81n4g	9	4	focuses	focus	VERB
6m311n81n4g	9	5	on	on	ADP
6m311n81n4g	9	6	orientation	orientation	NOUN
6m311n81n4g	9	7	effects	effect	NOUN
6m311n81n4g	9	8	in	in	ADP
6m311n81n4g	9	9	the	the	DET
6m311n81n4g	9	10	sehrs	sehrs	PROPN
6m311n81n4g	9	11	of	of	ADP
6m311n81n4g	9	12	rhodamine	rhodamine	NOUN
6m311n81n4g	9	13	6	6	NUM
6m311n81n4g	9	14	g	g	NOUN
6m311n81n4g	9	15	on	on	ADP
6m311n81n4g	9	16	resonance	resonance	NOUN
6m311n81n4g	9	17	with	with	ADP
6m311n81n4g	9	18	its	its	PRON
6m311n81n4g	9	19	lowest	low	ADJ
6m311n81n4g	9	20	electronic	electronic	ADJ
6m311n81n4g	9	21	state	state	NOUN
6m311n81n4g	9	22	s1	s1	PROPN
6m311n81n4g	9	23	.	.	PUNCT
6m311n81n4g	10	1	first	first	ADJ
6m311n81n4g	10	2	-	-	PUNCT
6m311n81n4g	10	3	principles	principle	NOUN
6m311n81n4g	10	4	calculations	calculation	NOUN
6m311n81n4g	10	5	demonstrate	demonstrate	VERB
6m311n81n4g	10	6	the	the	DET
6m311n81n4g	10	7	non	non	ADJ
6m311n81n4g	10	8	-	-	ADJ
6m311n81n4g	10	9	condon	condon	ADJ
6m311n81n4g	10	10	effects	effect	NOUN
6m311n81n4g	10	11	that	that	PRON
6m311n81n4g	10	12	dominate	dominate	VERB
6m311n81n4g	10	13	resonance	resonance	NOUN
6m311n81n4g	10	14	hyper	hyper	ADJ
6m311n81n4g	10	15	-	-	ADJ
6m311n81n4g	10	16	raman	raman	ADJ
6m311n81n4g	10	17	scattering	scattering	NOUN
6m311n81n4g	10	18	produce	produce	VERB
6m311n81n4g	10	19	unique	unique	ADJ
6m311n81n4g	10	20	spectra	spectra	NOUN
6m311n81n4g	10	21	depending	depend	VERB
6m311n81n4g	10	22	on	on	ADP
6m311n81n4g	10	23	molecular	molecular	ADJ
6m311n81n4g	10	24	orientation	orientation	NOUN
6m311n81n4g	10	25	,	,	PUNCT
6m311n81n4g	10	26	thereby	thereby	ADV
6m311n81n4g	10	27	,	,	PUNCT
6m311n81n4g	10	28	making	make	VERB
6m311n81n4g	10	29	sehrs	sehrs	ADJ
6m311n81n4g	10	30	a	a	DET
6m311n81n4g	10	31	much	much	ADV
6m311n81n4g	10	32	more	more	ADV
6m311n81n4g	10	33	sensitive	sensitive	ADJ
6m311n81n4g	10	34	probe	probe	NOUN
6m311n81n4g	10	35	of	of	ADP
6m311n81n4g	10	36	adsorbate	adsorbate	ADJ
6m311n81n4g	10	37	geometry	geometry	NOUN
6m311n81n4g	10	38	than	than	ADP
6m311n81n4g	10	39	its	its	PRON
6m311n81n4g	10	40	linear	linear	ADJ
6m311n81n4g	10	41	counterpart	counterpart	NOUN
6m311n81n4g	10	42	,	,	PUNCT
6m311n81n4g	10	43	surface	surface	NOUN
6m311n81n4g	10	44	-	-	PUNCT
6m311n81n4g	10	45	enhanced	enhance	VERB
6m311n81n4g	10	46	raman	raman	NOUN
6m311n81n4g	10	47	scattering	scattering	NOUN
6m311n81n4g	10	48	.	.	PUNCT
6m311n81n4g	11	1	comparisons	comparison	NOUN
6m311n81n4g	11	2	between	between	ADP
6m311n81n4g	11	3	theoretical	theoretical	ADJ
6m311n81n4g	11	4	calculations	calculation	NOUN
6m311n81n4g	11	5	and	and	CCONJ
6m311n81n4g	11	6	experimentally	experimentally	ADV
6m311n81n4g	11	7	measured	measure	VERB
6m311n81n4g	11	8	sehrs	sehrs	ADJ
6m311n81n4g	11	9	from	from	ADP
6m311n81n4g	11	10	aggregated	aggregated	ADJ
6m311n81n4g	11	11	silver	silver	NOUN
6m311n81n4g	11	12	colloids	colloid	NOUN
6m311n81n4g	11	13	reveal	reveal	VERB
6m311n81n4g	11	14	r6	r6	PROPN
6m311n81n4g	11	15	g	g	PROPN
6m311n81n4g	11	16	adsorbs	adsorb	NOUN
6m311n81n4g	11	17	mostly	mostly	ADV
6m311n81n4g	11	18	perpendicular	perpendicular	ADJ
6m311n81n4g	11	19	with	with	ADP
6m311n81n4g	11	20	the	the	DET
6m311n81n4g	11	21	nanoparticle	nanoparticle	NOUN
6m311n81n4g	11	22	surface	surface	NOUN
6m311n81n4g	11	23	.	.	PUNCT
6m311n81n4g	12	1	the	the	DET
6m311n81n4g	12	2	predicted	predict	VERB
6m311n81n4g	12	3	geometry	geometry	NOUN
6m311n81n4g	12	4	both	both	PRON
6m311n81n4g	12	5	agrees	agree	VERB
6m311n81n4g	12	6	well	well	ADV
6m311n81n4g	12	7	with	with	ADP
6m311n81n4g	12	8	previous	previous	ADJ
6m311n81n4g	12	9	reports	report	NOUN
6m311n81n4g	12	10	and	and	CCONJ
6m311n81n4g	12	11	adds	add	VERB
6m311n81n4g	12	12	significantly	significantly	ADV
6m311n81n4g	12	13	to	to	ADP
6m311n81n4g	12	14	our	our	PRON
6m311n81n4g	12	15	understanding	understanding	NOUN
6m311n81n4g	12	16	of	of	ADP
6m311n81n4g	12	17	r6	r6	PROPN
6m311n81n4g	12	18	g	g	PROPN
6m311n81n4g	12	19	's	's	PART
6m311n81n4g	12	20	interactions	interaction	NOUN
6m311n81n4g	12	21	with	with	ADP
6m311n81n4g	12	22	metal	metal	NOUN
6m311n81n4g	12	23	colloids	colloid	NOUN
6m311n81n4g	12	24	.	.	PUNCT