id sid tid token lemma pos 6h440r9861b 1 1 we we PRON 6h440r9861b 1 2 used use VERB 6h440r9861b 1 3 x x NOUN 6h440r9861b 1 4 - - NOUN 6h440r9861b 1 5 ray ray NOUN 6h440r9861b 1 6 absorption absorption NOUN 6h440r9861b 1 7 fine fine ADJ 6h440r9861b 1 8 structure structure NOUN 6h440r9861b 1 9 spectroscopy spectroscopy NOUN 6h440r9861b 1 10 to to PART 6h440r9861b 1 11 study study VERB 6h440r9861b 1 12 the the DET 6h440r9861b 1 13 local local ADJ 6h440r9861b 1 14 molecular molecular ADJ 6h440r9861b 1 15 environment environment NOUN 6h440r9861b 1 16 of of ADP 6h440r9861b 1 17 cadmium cadmium NOUN 6h440r9861b 1 18 adsorbed adsorb VERB 6h440r9861b 1 19 to to ADP 6h440r9861b 1 20 kaolinite kaolinite NOUN 6h440r9861b 1 21 at at ADP 6h440r9861b 1 22 various various ADJ 6h440r9861b 1 23 phs phs NOUN 6h440r9861b 1 24 and and CCONJ 6h440r9861b 1 25 aqueous aqueous ADJ 6h440r9861b 1 26 cadmium cadmium NOUN 6h440r9861b 1 27 concentrations concentration NOUN 6h440r9861b 1 28 . . PUNCT 6h440r9861b 2 1 quantitative quantitative ADJ 6h440r9861b 2 2 analysis analysis NOUN 6h440r9861b 2 3 of of ADP 6h440r9861b 2 4 samples sample NOUN 6h440r9861b 2 5 with with ADP 6h440r9861b 2 6 aqueous aqueous ADJ 6h440r9861b 2 7 cadmium cadmium NOUN 6h440r9861b 2 8 concentration concentration NOUN 6h440r9861b 2 9 of of ADP 6h440r9861b 2 10 100 100 NUM 6h440r9861b 2 11 um um INTJ 6h440r9861b 3 1 and and CCONJ 6h440r9861b 3 2 at at ADP 6h440r9861b 3 3 ph ph PRON 6h440r9861b 3 4 7 7 NUM 6h440r9861b 3 5 shows show VERB 6h440r9861b 3 6 a a DET 6h440r9861b 3 7 single single ADJ 6h440r9861b 3 8 hydration hydration NOUN 6h440r9861b 3 9 sphere sphere NOUN 6h440r9861b 3 10 around around ADP 6h440r9861b 3 11 cadmium cadmium NOUN 6h440r9861b 3 12 , , PUNCT 6h440r9861b 3 13 suggesting suggest VERB 6h440r9861b 3 14 the the DET 6h440r9861b 3 15 formation formation NOUN 6h440r9861b 3 16 of of ADP 6h440r9861b 3 17 outer outer ADJ 6h440r9861b 3 18 sphere sphere NOUN 6h440r9861b 3 19 sorption sorption NOUN 6h440r9861b 3 20 complexes complex NOUN 6h440r9861b 3 21 . . PUNCT 6h440r9861b 4 1 at at ADP 6h440r9861b 4 2 ph ph PROPN 6h440r9861b 4 3 9 9 NUM 6h440r9861b 4 4 , , PUNCT 6h440r9861b 4 5 a a DET 6h440r9861b 4 6 clear clear ADJ 6h440r9861b 4 7 cd cd NOUN 6h440r9861b 4 8 - - PUNCT 6h440r9861b 4 9 m m PROPN 6h440r9861b 4 10 coordination coordination PROPN 6h440r9861b 4 11 ( ( PUNCT 6h440r9861b 4 12 where where SCONJ 6h440r9861b 4 13 m m PROPN 6h440r9861b 4 14 stands stand VERB 6h440r9861b 4 15 for for ADP 6h440r9861b 4 16 either either CCONJ 6h440r9861b 4 17 si si PROPN 6h440r9861b 4 18 or or CCONJ 6h440r9861b 4 19 al al PROPN 6h440r9861b 4 20 ) ) PUNCT 6h440r9861b 4 21 at at ADP 6h440r9861b 4 22 second second ADJ 6h440r9861b 4 23 shell shell NOUN 6h440r9861b 4 24 distance distance NOUN 6h440r9861b 4 25 indicates indicate VERB 6h440r9861b 4 26 the the DET 6h440r9861b 4 27 formation formation NOUN 6h440r9861b 4 28 of of ADP 6h440r9861b 4 29 inner inner ADJ 6h440r9861b 4 30 sphere sphere NOUN 6h440r9861b 4 31 sorption sorption NOUN 6h440r9861b 4 32 complexes complex NOUN 6h440r9861b 4 33 on on ADP 6h440r9861b 4 34 the the DET 6h440r9861b 4 35 edge edge NOUN 6h440r9861b 4 36 sites site NOUN 6h440r9861b 4 37 . . PUNCT 6h440r9861b 5 1 the the DET 6h440r9861b 5 2 possibility possibility NOUN 6h440r9861b 5 3 of of ADP 6h440r9861b 5 4 precipitation precipitation NOUN 6h440r9861b 5 5 of of ADP 6h440r9861b 5 6 cadmium cadmium NOUN 6h440r9861b 5 7 in in ADP 6h440r9861b 5 8 the the DET 6h440r9861b 5 9 form form NOUN 6h440r9861b 5 10 of of ADP 6h440r9861b 5 11 solid solid ADJ 6h440r9861b 5 12 phases phase NOUN 6h440r9861b 5 13 was be AUX 6h440r9861b 5 14 ruled rule VERB 6h440r9861b 5 15 out out ADP 6h440r9861b 5 16 due due ADP 6h440r9861b 5 17 to to ADP 6h440r9861b 5 18 similar similar ADJ 6h440r9861b 5 19 local local ADJ 6h440r9861b 5 20 environment environment NOUN 6h440r9861b 5 21 around around ADP 6h440r9861b 5 22 cadmium cadmium NOUN 6h440r9861b 5 23 in in ADP 6h440r9861b 5 24 samples sample NOUN 6h440r9861b 5 25 prepared prepare VERB 6h440r9861b 5 26 under under ADP 6h440r9861b 5 27 air air NOUN 6h440r9861b 5 28 and and CCONJ 6h440r9861b 5 29 nitrogen nitrogen NOUN 6h440r9861b 5 30 atmospheres atmosphere NOUN 6h440r9861b 5 31 , , PUNCT 6h440r9861b 5 32 and and CCONJ 6h440r9861b 5 33 by by ADP 6h440r9861b 5 34 the the DET 6h440r9861b 5 35 absence absence NOUN 6h440r9861b 5 36 of of ADP 6h440r9861b 5 37 a a DET 6h440r9861b 5 38 cd cd PROPN 6h440r9861b 5 39 - - PUNCT 6h440r9861b 5 40 cd cd PROPN 6h440r9861b 5 41 coordination coordination NOUN 6h440r9861b 5 42 found find VERB 6h440r9861b 5 43 in in ADP 6h440r9861b 5 44 the the DET 6h440r9861b 5 45 analysis analysis NOUN 6h440r9861b 5 46 of of ADP 6h440r9861b 5 47 a a DET 6h440r9861b 5 48 1000 1000 NUM 6h440r9861b 5 49 um um INTJ 6h440r9861b 5 50 sample sample NOUN 6h440r9861b 5 51 . . PUNCT 6h440r9861b 6 1 finally finally ADV 6h440r9861b 6 2 , , PUNCT 6h440r9861b 6 3 analysis analysis NOUN 6h440r9861b 6 4 of of ADP 6h440r9861b 6 5 samples sample NOUN 6h440r9861b 6 6 with with ADP 6h440r9861b 6 7 cadmium cadmium NOUN 6h440r9861b 6 8 aqueous aqueous ADJ 6h440r9861b 6 9 concentration concentration NOUN 6h440r9861b 6 10 of of ADP 6h440r9861b 6 11 3 3 NUM 6h440r9861b 6 12 um um INTJ 6h440r9861b 6 13 , , PUNCT 6h440r9861b 6 14 10 10 NUM 6h440r9861b 6 15 um um INTJ 6h440r9861b 6 16 , , PUNCT 6h440r9861b 6 17 and and CCONJ 6h440r9861b 6 18 100 100 NUM 6h440r9861b 6 19 um um INTJ 6h440r9861b 6 20 at at ADP 6h440r9861b 6 21 ph ph PRON 6h440r9861b 6 22 9 9 NUM 6h440r9861b 6 23 suggests suggest VERB 6h440r9861b 6 24 the the DET 6h440r9861b 6 25 formation formation NOUN 6h440r9861b 6 26 of of ADP 6h440r9861b 6 27 inner inner ADJ 6h440r9861b 6 28 sphere sphere NOUN 6h440r9861b 6 29 complexes complex NOUN 6h440r9861b 6 30 adsorbed adsorb VERB 6h440r9861b 6 31 to to ADP 6h440r9861b 6 32 both both DET 6h440r9861b 6 33 silanol silanol NOUN 6h440r9861b 6 34 and and CCONJ 6h440r9861b 6 35 aluminol aluminol NOUN 6h440r9861b 6 36 edge edge NOUN 6h440r9861b 6 37 sites site NOUN 6h440r9861b 6 38 in in ADP 6h440r9861b 6 39 different different ADJ 6h440r9861b 6 40 ratios ratio NOUN 6h440r9861b 6 41 . . PUNCT 6h440r9861b 7 1 in in ADP 6h440r9861b 7 2 addition addition NOUN 6h440r9861b 7 3 , , PUNCT 6h440r9861b 7 4 we we PRON 6h440r9861b 7 5 used use VERB 6h440r9861b 7 6 molecular molecular ADJ 6h440r9861b 7 7 dynamics dynamic NOUN 6h440r9861b 7 8 simulation simulation NOUN 6h440r9861b 7 9 to to PART 6h440r9861b 7 10 study study VERB 6h440r9861b 7 11 the the DET 6h440r9861b 7 12 mechanisms mechanism NOUN 6h440r9861b 7 13 envolved envolve VERB 6h440r9861b 7 14 in in ADP 6h440r9861b 7 15 the the DET 6h440r9861b 7 16 adsorption adsorption NOUN 6h440r9861b 7 17 of of ADP 6h440r9861b 7 18 various various ADJ 6h440r9861b 7 19 ions ion NOUN 6h440r9861b 7 20 to to ADP 6h440r9861b 7 21 the the DET 6h440r9861b 7 22 basal basal ADJ 6h440r9861b 7 23 surfaces surface NOUN 6h440r9861b 7 24 of of ADP 6h440r9861b 7 25 kaolinite kaolinite PROPN 6h440r9861b 7 26 . . PUNCT 6h440r9861b 8 1 analysis analysis NOUN 6h440r9861b 8 2 of of ADP 6h440r9861b 8 3 simulation simulation NOUN 6h440r9861b 8 4 data datum NOUN 6h440r9861b 8 5 indicates indicate VERB 6h440r9861b 8 6 that that SCONJ 6h440r9861b 8 7 cations cation NOUN 6h440r9861b 8 8 and and CCONJ 6h440r9861b 8 9 anions anion NOUN 6h440r9861b 8 10 adsorb adsorb VERB 6h440r9861b 8 11 preferably preferably ADV 6h440r9861b 8 12 on on ADP 6h440r9861b 8 13 the the DET 6h440r9861b 8 14 siloxane siloxane ADJ 6h440r9861b 8 15 and and CCONJ 6h440r9861b 8 16 gibbsite gibbsite ADJ 6h440r9861b 8 17 surfaces surface NOUN 6h440r9861b 8 18 of of ADP 6h440r9861b 8 19 kaolinite kaolinite PROPN 6h440r9861b 8 20 , , PUNCT 6h440r9861b 8 21 respectively respectively ADV 6h440r9861b 8 22 . . PUNCT 6h440r9861b 9 1 we we PRON 6h440r9861b 9 2 observed observe VERB 6h440r9861b 9 3 strong strong ADJ 6h440r9861b 9 4 inner inner ADJ 6h440r9861b 9 5 sphere sphere NOUN 6h440r9861b 9 6 adsorption adsorption NOUN 6h440r9861b 9 7 of of ADP 6h440r9861b 9 8 chlorine chlorine NOUN 6h440r9861b 9 9 at at ADP 6h440r9861b 9 10 aluminum aluminum NOUN 6h440r9861b 9 11 vacancies vacancy NOUN 6h440r9861b 9 12 on on ADP 6h440r9861b 9 13 the the DET 6h440r9861b 9 14 gibbsite gibbsite ADJ 6h440r9861b 9 15 surface surface NOUN 6h440r9861b 9 16 and and CCONJ 6h440r9861b 9 17 the the DET 6h440r9861b 9 18 occurrence occurrence NOUN 6h440r9861b 9 19 of of ADP 6h440r9861b 9 20 chlorine chlorine NOUN 6h440r9861b 9 21 - - PUNCT 6h440r9861b 9 22 driven drive VERB 6h440r9861b 9 23 inner inner ADJ 6h440r9861b 9 24 sphere sphere NOUN 6h440r9861b 9 25 adsorption adsorption NOUN 6h440r9861b 9 26 of of ADP 6h440r9861b 9 27 cesium cesium NOUN 6h440r9861b 9 28 and and CCONJ 6h440r9861b 9 29 sodium sodium NOUN 6h440r9861b 9 30 on on ADP 6h440r9861b 9 31 the the DET 6h440r9861b 9 32 gibbsite gibbsite ADJ 6h440r9861b 9 33 surface surface NOUN 6h440r9861b 9 34 for for ADP 6h440r9861b 9 35 high high ADJ 6h440r9861b 9 36 ionic ionic ADJ 6h440r9861b 9 37 strengths strength NOUN 6h440r9861b 9 38 . . PUNCT 6h440r9861b 10 1 cesium cesium NOUN 6h440r9861b 10 2 ions ion NOUN 6h440r9861b 10 3 form form VERB 6h440r9861b 10 4 strong strong ADJ 6h440r9861b 10 5 inner inner ADJ 6h440r9861b 10 6 sphere sphere NOUN 6h440r9861b 10 7 complexes complex NOUN 6h440r9861b 10 8 at at ADP 6h440r9861b 10 9 ditrigonal ditrigonal ADJ 6h440r9861b 10 10 cavities cavity NOUN 6h440r9861b 10 11 on on ADP 6h440r9861b 10 12 the the DET 6h440r9861b 10 13 siloxane siloxane ADJ 6h440r9861b 10 14 surface surface NOUN 6h440r9861b 10 15 . . PUNCT 6h440r9861b 11 1 outer outer ADJ 6h440r9861b 11 2 sphere sphere PROPN 6h440r9861b 11 3 cesium cesium NOUN 6h440r9861b 11 4 is be AUX 6h440r9861b 11 5 highly highly ADV 6h440r9861b 11 6 mobile mobile ADJ 6h440r9861b 11 7 and and CCONJ 6h440r9861b 11 8 only only ADV 6h440r9861b 11 9 weak weak ADJ 6h440r9861b 11 10 adsorption adsorption NOUN 6h440r9861b 11 11 may may AUX 6h440r9861b 11 12 occur occur VERB 6h440r9861b 11 13 . . PUNCT 6h440r9861b 12 1 a a DET 6h440r9861b 12 2 small small ADJ 6h440r9861b 12 3 amount amount NOUN 6h440r9861b 12 4 of of ADP 6h440r9861b 12 5 sodium sodium NOUN 6h440r9861b 12 6 adsorbs adsorb NOUN 6h440r9861b 12 7 on on ADP 6h440r9861b 12 8 the the DET 6h440r9861b 12 9 siloxane siloxane ADJ 6h440r9861b 12 10 surface surface NOUN 6h440r9861b 12 11 as as ADP 6h440r9861b 12 12 inner inner ADJ 6h440r9861b 12 13 sphere sphere NOUN 6h440r9861b 12 14 complexes complex NOUN 6h440r9861b 12 15 at at ADP 6h440r9861b 12 16 diffuse diffuse NOUN 6h440r9861b 12 17 sites site NOUN 6h440r9861b 12 18 . . PUNCT 6h440r9861b 13 1 like like ADP 6h440r9861b 13 2 cesium cesium NOUN 6h440r9861b 13 3 , , PUNCT 6h440r9861b 13 4 sodium sodium NOUN 6h440r9861b 13 5 onlys onlys NOUN 6h440r9861b 13 6 forms form NOUN 6h440r9861b 13 7 very very ADV 6h440r9861b 13 8 weak weak ADJ 6h440r9861b 13 9 outer outer ADJ 6h440r9861b 13 10 sphere sphere NOUN 6h440r9861b 13 11 complexes complex NOUN 6h440r9861b 13 12 on on ADP 6h440r9861b 13 13 this this DET 6h440r9861b 13 14 surface surface NOUN 6h440r9861b 13 15 . . PUNCT 6h440r9861b 14 1 inner inner ADJ 6h440r9861b 14 2 sphere sphere PROPN 6h440r9861b 14 3 complexes complex NOUN 6h440r9861b 14 4 of of ADP 6h440r9861b 14 5 cadmium cadmium NOUN 6h440r9861b 14 6 and and CCONJ 6h440r9861b 14 7 lead lead NOUN 6h440r9861b 14 8 do do AUX 6h440r9861b 14 9 not not PART 6h440r9861b 14 10 occur occur VERB 6h440r9861b 14 11 on on ADP 6h440r9861b 14 12 either either DET 6h440r9861b 14 13 surface surface NOUN 6h440r9861b 14 14 . . PUNCT 6h440r9861b 15 1 relatively relatively ADV 6h440r9861b 15 2 strong strong ADJ 6h440r9861b 15 3 outer outer ADJ 6h440r9861b 15 4 sphere sphere NOUN 6h440r9861b 15 5 cadmium cadmium NOUN 6h440r9861b 15 6 and and CCONJ 6h440r9861b 15 7 lead lead NOUN 6h440r9861b 15 8 complexes complex NOUN 6h440r9861b 15 9 are be AUX 6h440r9861b 15 10 present present ADJ 6h440r9861b 15 11 on on ADP 6h440r9861b 15 12 the the DET 6h440r9861b 15 13 siloxane siloxane ADJ 6h440r9861b 15 14 surface surface NOUN 6h440r9861b 15 15 at at ADP 6h440r9861b 15 16 ditrigonal ditrigonal ADJ 6h440r9861b 15 17 cavities cavity NOUN 6h440r9861b 15 18 . . PUNCT