id	sid	tid	token	lemma	pos
6108v982v3t	1	1	non	non	ADJ
6108v982v3t	1	2	-	-	ADJ
6108v982v3t	1	3	innocent	innocent	ADJ
6108v982v3t	1	4	ligands	ligand	NOUN
6108v982v3t	1	5	can	can	AUX
6108v982v3t	1	6	be	be	AUX
6108v982v3t	1	7	versatile	versatile	ADJ
6108v982v3t	1	8	tools	tool	NOUN
6108v982v3t	1	9	in	in	ADP
6108v982v3t	1	10	providing	provide	VERB
6108v982v3t	1	11	catalytic	catalytic	ADJ
6108v982v3t	1	12	function	function	NOUN
6108v982v3t	1	13	to	to	ADP
6108v982v3t	1	14	organometallic	organometallic	ADJ
6108v982v3t	1	15	redox	redox	ADJ
6108v982v3t	1	16	catalysts	catalyst	NOUN
6108v982v3t	1	17	.	.	PUNCT
6108v982v3t	2	1	in	in	ADP
6108v982v3t	2	2	the	the	DET
6108v982v3t	2	3	case	case	NOUN
6108v982v3t	2	4	of	of	ADP
6108v982v3t	2	5	the	the	DET
6108v982v3t	2	6	redox	redox	NOUN
6108v982v3t	2	7	-	-	PUNCT
6108v982v3t	2	8	active	active	ADJ
6108v982v3t	2	9	tbucliph4	tbucliph4	NOUN
6108v982v3t	2	10	ligand	ligand	NOUN
6108v982v3t	2	11	(	(	PUNCT
6108v982v3t	2	12	n	n	PROPN
6108v982v3t	2	13	,	,	PUNCT
6108v982v3t	2	14	n´-bis(2	n´-bis(2	SPACE
6108v982v3t	2	15	-	-	PUNCT
6108v982v3t	2	16	hydroxy-3,5	hydroxy-3,5	NOUN
6108v982v3t	2	17	-	-	PUNCT
6108v982v3t	2	18	di	di	NOUN
6108v982v3t	2	19	-	-	PUNCT
6108v982v3t	2	20	tert	tert	NOUN
6108v982v3t	2	21	-	-	PUNCT
6108v982v3t	2	22	butylphenyl)-2,2´-diamino-4,4´-di	butylphenyl)-2,2´-diamino-4,4´-di	SPACE
6108v982v3t	2	23	-	-	PUNCT
6108v982v3t	2	24	tert	tert	NOUN
6108v982v3t	2	25	-	-	PUNCT
6108v982v3t	2	26	butylbiphenyl	butylbiphenyl	NOUN
6108v982v3t	2	27	)	)	PUNCT
6108v982v3t	2	28	,	,	PUNCT
6108v982v3t	2	29	the	the	DET
6108v982v3t	2	30	ligand	ligand	NOUN
6108v982v3t	2	31	can	can	AUX
6108v982v3t	2	32	undergo	undergo	VERB
6108v982v3t	2	33	2h+/2e−	2h+/2e−	NUM
6108v982v3t	2	34	redox	redox	ADJ
6108v982v3t	2	35	changes	change	NOUN
6108v982v3t	2	36	,	,	PUNCT
6108v982v3t	2	37	shuttling	shuttle	VERB
6108v982v3t	2	38	between	between	ADP
6108v982v3t	2	39	an	an	DET
6108v982v3t	2	40	oxidized	oxidized	ADJ
6108v982v3t	2	41	bis(iminosemiquinone	bis(iminosemiquinone	NOUN
6108v982v3t	2	42	)	)	PUNCT
6108v982v3t	2	43	and	and	CCONJ
6108v982v3t	2	44	a	a	DET
6108v982v3t	2	45	reduced	reduce	VERB
6108v982v3t	2	46	bis(aminophenoxide	bis(aminophenoxide	NOUN
6108v982v3t	2	47	)	)	PUNCT
6108v982v3t	2	48	,	,	PUNCT
6108v982v3t	2	49	when	when	SCONJ
6108v982v3t	2	50	coordinated	coordinate	VERB
6108v982v3t	2	51	to	to	PART
6108v982v3t	2	52	group	group	NOUN
6108v982v3t	2	53	10	10	NUM
6108v982v3t	2	54	metals	metal	NOUN
6108v982v3t	2	55	.	.	PUNCT
6108v982v3t	3	1	the	the	DET
6108v982v3t	3	2	frontier	frontier	NOUN
6108v982v3t	3	3	orbitals	orbital	NOUN
6108v982v3t	3	4	of	of	ADP
6108v982v3t	3	5	bis(iminosemiquinone	bis(iminosemiquinone	NOUN
6108v982v3t	3	6	)	)	PUNCT
6108v982v3t	3	7	complexes	complex	NOUN
6108v982v3t	3	8	consist	consist	VERB
6108v982v3t	3	9	of	of	ADP
6108v982v3t	3	10	a	a	DET
6108v982v3t	3	11	ligand	ligand	NOUN
6108v982v3t	3	12	-	-	PUNCT
6108v982v3t	3	13	centered	center	VERB
6108v982v3t	3	14	orbital	orbital	NOUN
6108v982v3t	3	15	,	,	PUNCT
6108v982v3t	3	16	and	and	CCONJ
6108v982v3t	3	17	a	a	DET
6108v982v3t	3	18	higher	higher	ADV
6108v982v3t	3	19	-	-	PUNCT
6108v982v3t	3	20	lying	lie	VERB
6108v982v3t	3	21	orbital	orbital	NOUN
6108v982v3t	3	22	that	that	PRON
6108v982v3t	3	23	is	be	AUX
6108v982v3t	3	24	largely	largely	ADV
6108v982v3t	3	25	ligand	ligand	NOUN
6108v982v3t	3	26	-	-	PUNCT
6108v982v3t	3	27	centered	center	VERB
6108v982v3t	3	28	but	but	CCONJ
6108v982v3t	3	29	is	be	AUX
6108v982v3t	3	30	metal	metal	NOUN
6108v982v3t	3	31	-	-	PUNCT
6108v982v3t	3	32	ligand	ligand	NOUN
6108v982v3t	3	33	π	π	NOUN
6108v982v3t	3	34	antibonding	antibonding	NOUN
6108v982v3t	3	35	.	.	PUNCT
6108v982v3t	4	1	these	these	DET
6108v982v3t	4	2	two	two	NUM
6108v982v3t	4	3	orbitals	orbital	NOUN
6108v982v3t	4	4	are	be	AUX
6108v982v3t	4	5	collectively	collectively	ADV
6108v982v3t	4	6	occupied	occupy	VERB
6108v982v3t	4	7	by	by	ADP
6108v982v3t	4	8	two	two	NUM
6108v982v3t	4	9	electrons	electron	NOUN
6108v982v3t	4	10	.	.	PUNCT
6108v982v3t	5	1	the	the	DET
6108v982v3t	5	2	complexes	complex	NOUN
6108v982v3t	5	3	are	be	AUX
6108v982v3t	5	4	always	always	ADV
6108v982v3t	5	5	ground	ground	NOUN
6108v982v3t	5	6	-	-	PUNCT
6108v982v3t	5	7	state	state	NOUN
6108v982v3t	5	8	singlets	singlet	NOUN
6108v982v3t	5	9	,	,	PUNCT
6108v982v3t	5	10	but	but	CCONJ
6108v982v3t	5	11	many	many	ADJ
6108v982v3t	5	12	of	of	ADP
6108v982v3t	5	13	the	the	DET
6108v982v3t	5	14	studied	studied	ADJ
6108v982v3t	5	15	complexes	complex	NOUN
6108v982v3t	5	16	possess	possess	VERB
6108v982v3t	5	17	low	low	ADV
6108v982v3t	5	18	-	-	PUNCT
6108v982v3t	5	19	lying	lie	VERB
6108v982v3t	5	20	triplet	triplet	NOUN
6108v982v3t	5	21	states	state	NOUN
6108v982v3t	5	22	that	that	PRON
6108v982v3t	5	23	can	can	AUX
6108v982v3t	5	24	be	be	AUX
6108v982v3t	5	25	thermally	thermally	ADV
6108v982v3t	5	26	populated	populate	VERB
6108v982v3t	5	27	.	.	PUNCT
6108v982v3t	6	1	measurement	measurement	NOUN
6108v982v3t	6	2	of	of	ADP
6108v982v3t	6	3	the	the	DET
6108v982v3t	6	4	singlet	singlet	NOUN
6108v982v3t	6	5	-	-	PUNCT
6108v982v3t	6	6	triplet	triplet	NOUN
6108v982v3t	6	7	energy	energy	NOUN
6108v982v3t	6	8	gap	gap	NOUN
6108v982v3t	6	9	by	by	ADP
6108v982v3t	6	10	variable	variable	ADJ
6108v982v3t	6	11	-	-	PUNCT
6108v982v3t	6	12	temperature	temperature	NOUN
6108v982v3t	6	13	nmr	nmr	NOUN
6108v982v3t	6	14	,	,	PUNCT
6108v982v3t	6	15	in	in	ADP
6108v982v3t	6	16	combination	combination	NOUN
6108v982v3t	6	17	with	with	ADP
6108v982v3t	6	18	uv	uv	NOUN
6108v982v3t	6	19	-	-	PUNCT
6108v982v3t	6	20	vis	vis	X
6108v982v3t	6	21	spectroscopic	spectroscopic	ADJ
6108v982v3t	6	22	data	datum	NOUN
6108v982v3t	6	23	of	of	ADP
6108v982v3t	6	24	the	the	DET
6108v982v3t	6	25	cationic	cationic	ADJ
6108v982v3t	6	26	,	,	PUNCT
6108v982v3t	6	27	neutral	neutral	ADJ
6108v982v3t	6	28	,	,	PUNCT
6108v982v3t	6	29	and	and	CCONJ
6108v982v3t	6	30	anionic	anionic	ADJ
6108v982v3t	6	31	forms	form	NOUN
6108v982v3t	6	32	of	of	ADP
6108v982v3t	6	33	the	the	DET
6108v982v3t	6	34	complex	complex	NOUN
6108v982v3t	6	35	,	,	PUNCT
6108v982v3t	6	36	have	have	AUX
6108v982v3t	6	37	provided	provide	VERB
6108v982v3t	6	38	a	a	DET
6108v982v3t	6	39	comprehensive	comprehensive	ADJ
6108v982v3t	6	40	view	view	NOUN
6108v982v3t	6	41	of	of	ADP
6108v982v3t	6	42	the	the	DET
6108v982v3t	6	43	electronic	electronic	ADJ
6108v982v3t	6	44	nature	nature	NOUN
6108v982v3t	6	45	of	of	ADP
6108v982v3t	6	46	the	the	DET
6108v982v3t	6	47	complexes.group	complexes.group	NOUN
6108v982v3t	6	48	10	10	NUM
6108v982v3t	6	49	bis(iminosemiquinone	bis(iminosemiquinone	NOUN
6108v982v3t	6	50	)	)	PUNCT
6108v982v3t	6	51	metal	metal	NOUN
6108v982v3t	6	52	complexes	complex	NOUN
6108v982v3t	6	53	of	of	ADP
6108v982v3t	6	54	cis	cis	NOUN
6108v982v3t	6	55	geometry	geometry	NOUN
6108v982v3t	6	56	were	be	AUX
6108v982v3t	6	57	hypothesized	hypothesize	VERB
6108v982v3t	6	58	to	to	PART
6108v982v3t	6	59	be	be	AUX
6108v982v3t	6	60	able	able	ADJ
6108v982v3t	6	61	to	to	PART
6108v982v3t	6	62	accomplish	accomplish	VERB
6108v982v3t	6	63	a	a	DET
6108v982v3t	6	64	concerted	concerted	ADJ
6108v982v3t	6	65	transfer	transfer	NOUN
6108v982v3t	6	66	of	of	ADP
6108v982v3t	6	67	a	a	DET
6108v982v3t	6	68	pair	pair	NOUN
6108v982v3t	6	69	of	of	ADP
6108v982v3t	6	70	hydrogen	hydrogen	NOUN
6108v982v3t	6	71	atoms	atom	NOUN
6108v982v3t	6	72	from	from	ADP
6108v982v3t	6	73	an	an	DET
6108v982v3t	6	74	organic	organic	ADJ
6108v982v3t	6	75	substrate	substrate	NOUN
6108v982v3t	6	76	.	.	PUNCT
6108v982v3t	7	1	what	what	PRON
6108v982v3t	7	2	has	have	AUX
6108v982v3t	7	3	been	be	AUX
6108v982v3t	7	4	observed	observe	VERB
6108v982v3t	7	5	is	be	AUX
6108v982v3t	7	6	that	that	SCONJ
6108v982v3t	7	7	the	the	DET
6108v982v3t	7	8	mechanism	mechanism	NOUN
6108v982v3t	7	9	of	of	ADP
6108v982v3t	7	10	hydrogen	hydrogen	NOUN
6108v982v3t	7	11	atom	atom	NOUN
6108v982v3t	7	12	transfer	transfer	NOUN
6108v982v3t	7	13	is	be	AUX
6108v982v3t	7	14	stepwise	stepwise	NOUN
6108v982v3t	7	15	in	in	ADP
6108v982v3t	7	16	all	all	DET
6108v982v3t	7	17	investigated	investigate	VERB
6108v982v3t	7	18	reactions	reaction	NOUN
6108v982v3t	7	19	.	.	PUNCT
6108v982v3t	8	1	in	in	ADP
6108v982v3t	8	2	regards	regard	NOUN
6108v982v3t	8	3	to	to	ADP
6108v982v3t	8	4	2h+/2e−	2h+/2e−	NUM
6108v982v3t	8	5	reactivity	reactivity	NOUN
6108v982v3t	8	6	,	,	PUNCT
6108v982v3t	8	7	the	the	DET
6108v982v3t	8	8	palladium	palladium	NOUN
6108v982v3t	8	9	complex	complex	NOUN
6108v982v3t	8	10	(	(	PUNCT
6108v982v3t	8	11	tbuclip)pd	tbuclip)pd	PROPN
6108v982v3t	8	12	dehydrogenates	dehydrogenate	NOUN
6108v982v3t	8	13	hydrazines	hydrazine	NOUN
6108v982v3t	8	14	and	and	CCONJ
6108v982v3t	8	15	hydroxylamines	hydroxylamine	NOUN
6108v982v3t	8	16	to	to	PART
6108v982v3t	8	17	generate	generate	VERB
6108v982v3t	8	18	the	the	DET
6108v982v3t	8	19	(	(	PUNCT
6108v982v3t	8	20	tbucliph2)pd	tbucliph2)pd	NOUN
6108v982v3t	8	21	complex	complex	NOUN
6108v982v3t	8	22	.	.	PUNCT
6108v982v3t	9	1	in	in	ADP
6108v982v3t	9	2	comparison	comparison	NOUN
6108v982v3t	9	3	,	,	PUNCT
6108v982v3t	9	4	the	the	DET
6108v982v3t	9	5	platinum	platinum	NOUN
6108v982v3t	9	6	analogue	analogue	NOUN
6108v982v3t	9	7	is	be	AUX
6108v982v3t	9	8	much	much	ADV
6108v982v3t	9	9	less	less	ADJ
6108v982v3t	9	10	oxidizing	oxidizing	NOUN
6108v982v3t	9	11	,	,	PUNCT
6108v982v3t	9	12	and	and	CCONJ
6108v982v3t	9	13	dehydrogenates	dehydrogenate	VERB
6108v982v3t	9	14	hydrazobenzene	hydrazobenzene	PROPN
6108v982v3t	9	15	reversibly	reversibly	ADV
6108v982v3t	9	16	(	(	PUNCT
6108v982v3t	9	17	∆g	∆g	NUM
6108v982v3t	9	18	°	°	PROPN
6108v982v3t	9	19	=	=	SYM
6108v982v3t	9	20	1.85	1.85	NUM
6108v982v3t	9	21	kcal	kcal	PROPN
6108v982v3t	9	22	/	/	SYM
6108v982v3t	9	23	mol	mol	PROPN
6108v982v3t	9	24	at	at	ADP
6108v982v3t	9	25	22	22	NUM
6108v982v3t	9	26	°	°	NOUN
6108v982v3t	9	27	c	c	NOUN
6108v982v3t	9	28	)	)	PUNCT
6108v982v3t	9	29	.	.	PUNCT
6108v982v3t	10	1	not	not	PART
6108v982v3t	10	2	only	only	ADV
6108v982v3t	10	3	are	be	AUX
6108v982v3t	10	4	the	the	DET
6108v982v3t	10	5	complexes	complex	NOUN
6108v982v3t	10	6	different	different	ADJ
6108v982v3t	10	7	in	in	ADP
6108v982v3t	10	8	terms	term	NOUN
6108v982v3t	10	9	of	of	ADP
6108v982v3t	10	10	their	their	PRON
6108v982v3t	10	11	thermodynamic	thermodynamic	ADJ
6108v982v3t	10	12	reducing	reduce	VERB
6108v982v3t	10	13	power	power	NOUN
6108v982v3t	10	14	,	,	PUNCT
6108v982v3t	10	15	but	but	CCONJ
6108v982v3t	10	16	also	also	ADV
6108v982v3t	10	17	in	in	ADP
6108v982v3t	10	18	how	how	SCONJ
6108v982v3t	10	19	the	the	DET
6108v982v3t	10	20	initial	initial	ADJ
6108v982v3t	10	21	hydrogen	hydrogen	NOUN
6108v982v3t	10	22	atom	atom	NOUN
6108v982v3t	10	23	transfer	transfer	NOUN
6108v982v3t	10	24	affects	affect	VERB
6108v982v3t	10	25	the	the	DET
6108v982v3t	10	26	transfer	transfer	NOUN
6108v982v3t	10	27	of	of	ADP
6108v982v3t	10	28	the	the	DET
6108v982v3t	10	29	second	second	ADJ
6108v982v3t	10	30	hydrogen	hydrogen	NOUN
6108v982v3t	10	31	atom	atom	NOUN
6108v982v3t	10	32	.	.	PUNCT
6108v982v3t	11	1	the	the	DET
6108v982v3t	11	2	(	(	PUNCT
6108v982v3t	11	3	tbucliph2)pd	tbucliph2)pd	NOUN
6108v982v3t	11	4	complex	complex	NOUN
6108v982v3t	11	5	shows	show	VERB
6108v982v3t	11	6	practically	practically	ADV
6108v982v3t	11	7	no	no	DET
6108v982v3t	11	8	coupling	coupling	NOUN
6108v982v3t	11	9	between	between	ADP
6108v982v3t	11	10	the	the	DET
6108v982v3t	11	11	two	two	NUM
6108v982v3t	11	12	hydrogen	hydrogen	NOUN
6108v982v3t	11	13	atom	atom	NOUN
6108v982v3t	11	14	transfer	transfer	NOUN
6108v982v3t	11	15	events	event	NOUN
6108v982v3t	11	16	,	,	PUNCT
6108v982v3t	11	17	both	both	CCONJ
6108v982v3t	11	18	thermodynamically	thermodynamically	ADV
6108v982v3t	11	19	and	and	CCONJ
6108v982v3t	11	20	kinetically	kinetically	ADV
6108v982v3t	11	21	.	.	PUNCT
6108v982v3t	12	1	the	the	DET
6108v982v3t	12	2	platinum	platinum	NOUN
6108v982v3t	12	3	complex	complex	NOUN
6108v982v3t	12	4	displays	display	VERB
6108v982v3t	12	5	much	much	ADV
6108v982v3t	12	6	stronger	strong	ADJ
6108v982v3t	12	7	coupling	coupling	NOUN
6108v982v3t	12	8	between	between	ADP
6108v982v3t	12	9	the	the	DET
6108v982v3t	12	10	two	two	NUM
6108v982v3t	12	11	hydrogen	hydrogen	NOUN
6108v982v3t	12	12	atom	atom	NOUN
6108v982v3t	12	13	transfer	transfer	NOUN
6108v982v3t	12	14	events	event	NOUN
6108v982v3t	12	15	and	and	CCONJ
6108v982v3t	12	16	favors	favor	VERB
6108v982v3t	12	17	two	two	NUM
6108v982v3t	12	18	electron	electron	NOUN
6108v982v3t	12	19	chemistry	chemistry	NOUN
6108v982v3t	12	20	more	more	ADJ
6108v982v3t	12	21	than	than	ADP
6108v982v3t	12	22	the	the	DET
6108v982v3t	12	23	palladium	palladium	NOUN
6108v982v3t	12	24	complex	complex	NOUN
6108v982v3t	12	25	.	.	PUNCT
6108v982v3t	13	1	while	while	SCONJ
6108v982v3t	13	2	the	the	DET
6108v982v3t	13	3	extent	extent	NOUN
6108v982v3t	13	4	of	of	ADP
6108v982v3t	13	5	coupling	coupling	NOUN
6108v982v3t	13	6	in	in	ADP
6108v982v3t	13	7	the	the	DET
6108v982v3t	13	8	analogous	analogous	ADJ
6108v982v3t	13	9	nickel	nickel	NOUN
6108v982v3t	13	10	complex	complex	NOUN
6108v982v3t	13	11	remains	remain	VERB
6108v982v3t	13	12	unknown	unknown	ADJ
6108v982v3t	13	13	,	,	PUNCT
6108v982v3t	13	14	it	it	PRON
6108v982v3t	13	15	is	be	AUX
6108v982v3t	13	16	estimated	estimate	VERB
6108v982v3t	13	17	to	to	PART
6108v982v3t	13	18	be	be	AUX
6108v982v3t	13	19	more	more	ADV
6108v982v3t	13	20	like	like	ADP
6108v982v3t	13	21	the	the	DET
6108v982v3t	13	22	platinum	platinum	NOUN
6108v982v3t	13	23	complex	complex	NOUN
6108v982v3t	13	24	in	in	ADP
6108v982v3t	13	25	this	this	PRON
6108v982v3t	13	26	regard.in	regard.in	NUM
6108v982v3t	13	27	the	the	DET
6108v982v3t	13	28	reactions	reaction	NOUN
6108v982v3t	13	29	involving	involve	VERB
6108v982v3t	13	30	the	the	DET
6108v982v3t	13	31	bis(iminosemiquinone	bis(iminosemiquinone	NOUN
6108v982v3t	13	32	)	)	PUNCT
6108v982v3t	13	33	complexes	complex	NOUN
6108v982v3t	13	34	with	with	ADP
6108v982v3t	13	35	hydrazobenzene	hydrazobenzene	NOUN
6108v982v3t	13	36	,	,	PUNCT
6108v982v3t	13	37	all	all	DET
6108v982v3t	13	38	three	three	NUM
6108v982v3t	13	39	complexes	complex	NOUN
6108v982v3t	13	40	display	display	VERB
6108v982v3t	13	41	exceedingly	exceedingly	ADV
6108v982v3t	13	42	large	large	ADJ
6108v982v3t	13	43	primary	primary	ADJ
6108v982v3t	13	44	kinetic	kinetic	ADJ
6108v982v3t	13	45	isotope	isotope	NOUN
6108v982v3t	13	46	effects	effect	NOUN
6108v982v3t	13	47	that	that	PRON
6108v982v3t	13	48	are	be	AUX
6108v982v3t	13	49	beyond	beyond	ADP
6108v982v3t	13	50	the	the	DET
6108v982v3t	13	51	theoretical	theoretical	ADJ
6108v982v3t	13	52	limit	limit	NOUN
6108v982v3t	13	53	for	for	ADP
6108v982v3t	13	54	a	a	DET
6108v982v3t	13	55	classical	classical	ADJ
6108v982v3t	13	56	hydrogen	hydrogen	NOUN
6108v982v3t	13	57	atom	atom	NOUN
6108v982v3t	13	58	transfer	transfer	NOUN
6108v982v3t	13	59	.	.	PUNCT
6108v982v3t	14	1	such	such	ADJ
6108v982v3t	14	2	large	large	ADJ
6108v982v3t	14	3	kies	ky	NOUN
6108v982v3t	14	4	are	be	AUX
6108v982v3t	14	5	interpreted	interpret	VERB
6108v982v3t	14	6	to	to	PART
6108v982v3t	14	7	arise	arise	VERB
6108v982v3t	14	8	from	from	ADP
6108v982v3t	14	9	hydrogen	hydrogen	PROPN
6108v982v3t	14	10	atom	atom	NOUN
6108v982v3t	14	11	tunneling	tunneling	PROPN
6108v982v3t	14	12	.	.	PUNCT
6108v982v3t	15	1	the	the	DET
6108v982v3t	15	2	reactivity	reactivity	NOUN
6108v982v3t	15	3	with	with	ADP
6108v982v3t	15	4	the	the	DET
6108v982v3t	15	5	palladium	palladium	NOUN
6108v982v3t	15	6	complex	complex	NOUN
6108v982v3t	15	7	also	also	ADV
6108v982v3t	15	8	has	have	VERB
6108v982v3t	15	9	a	a	DET
6108v982v3t	15	10	non	non	ADJ
6108v982v3t	15	11	-	-	ADJ
6108v982v3t	15	12	linear	linear	ADJ
6108v982v3t	15	13	dependence	dependence	NOUN
6108v982v3t	15	14	of	of	ADP
6108v982v3t	15	15	rate	rate	NOUN
6108v982v3t	15	16	on	on	ADP
6108v982v3t	15	17	mole	mole	ADJ
6108v982v3t	15	18	fraction	fraction	NOUN
6108v982v3t	15	19	protium	protium	NOUN
6108v982v3t	15	20	.	.	PUNCT
6108v982v3t	16	1	the	the	DET
6108v982v3t	16	2	proposed	propose	VERB
6108v982v3t	16	3	explanation	explanation	NOUN
6108v982v3t	16	4	is	be	AUX
6108v982v3t	16	5	that	that	SCONJ
6108v982v3t	16	6	a	a	DET
6108v982v3t	16	7	change	change	NOUN
6108v982v3t	16	8	in	in	ADP
6108v982v3t	16	9	the	the	DET
6108v982v3t	16	10	fate	fate	NOUN
6108v982v3t	16	11	of	of	ADP
6108v982v3t	16	12	the	the	DET
6108v982v3t	16	13	intermediate	intermediate	ADJ
6108v982v3t	16	14	hydrazyl	hydrazyl	NOUN
6108v982v3t	16	15	radical	radical	ADJ
6108v982v3t	16	16	(	(	PUNCT
6108v982v3t	16	17	disproportionation	disproportionation	NOUN
6108v982v3t	16	18	vs.	vs.	ADP
6108v982v3t	16	19	further	further	ADJ
6108v982v3t	16	20	reactivity	reactivity	NOUN
6108v982v3t	16	21	with	with	ADP
6108v982v3t	16	22	palladium	palladium	NOUN
6108v982v3t	16	23	)	)	PUNCT
6108v982v3t	16	24	,	,	PUNCT
6108v982v3t	16	25	depending	depend	VERB
6108v982v3t	16	26	on	on	ADP
6108v982v3t	16	27	its	its	PRON
6108v982v3t	16	28	isotopic	isotopic	ADJ
6108v982v3t	16	29	composition	composition	NOUN
6108v982v3t	16	30	,	,	PUNCT
6108v982v3t	16	31	alters	alter	VERB
6108v982v3t	16	32	the	the	DET
6108v982v3t	16	33	stoichiometric	stoichiometric	ADJ
6108v982v3t	16	34	factor	factor	NOUN
6108v982v3t	16	35	of	of	ADP
6108v982v3t	16	36	the	the	DET
6108v982v3t	16	37	hydrogen	hydrogen	NOUN
6108v982v3t	16	38	atom	atom	NOUN
6108v982v3t	16	39	transfer	transfer	NOUN
6108v982v3t	16	40	events	event	NOUN
6108v982v3t	16	41	,	,	PUNCT
6108v982v3t	16	42	and	and	CCONJ
6108v982v3t	16	43	therefore	therefore	ADV
6108v982v3t	16	44	the	the	DET
6108v982v3t	16	45	observed	observe	VERB
6108v982v3t	16	46	rates	rate	NOUN
6108v982v3t	16	47	of	of	ADP
6108v982v3t	16	48	reaction	reaction	NOUN
6108v982v3t	16	49	.	.	PUNCT
6108v982v3t	17	1	in	in	ADP
6108v982v3t	17	2	exploring	explore	VERB
6108v982v3t	17	3	the	the	DET
6108v982v3t	17	4	hydrogen	hydrogen	NOUN
6108v982v3t	17	5	atom	atom	NOUN
6108v982v3t	17	6	transfer	transfer	NOUN
6108v982v3t	17	7	with	with	ADP
6108v982v3t	17	8	alkynes	alkyne	NOUN
6108v982v3t	17	9	,	,	PUNCT
6108v982v3t	17	10	only	only	ADV
6108v982v3t	17	11	the	the	DET
6108v982v3t	17	12	bis(aminophenoxide)platinum	bis(aminophenoxide)platinum	NUM
6108v982v3t	17	13	complex	complex	NOUN
6108v982v3t	17	14	was	be	AUX
6108v982v3t	17	15	observed	observe	VERB
6108v982v3t	17	16	to	to	PART
6108v982v3t	17	17	have	have	VERB
6108v982v3t	17	18	reactivity	reactivity	NOUN
6108v982v3t	17	19	.	.	PUNCT
6108v982v3t	18	1	however	however	ADV
6108v982v3t	18	2	,	,	PUNCT
6108v982v3t	18	3	rather	rather	ADV
6108v982v3t	18	4	than	than	ADP
6108v982v3t	18	5	the	the	DET
6108v982v3t	18	6	stepwise	stepwise	NOUN
6108v982v3t	18	7	hydrogen	hydrogen	NOUN
6108v982v3t	18	8	atom	atom	NOUN
6108v982v3t	18	9	transfer	transfer	NOUN
6108v982v3t	18	10	seen	see	VERB
6108v982v3t	18	11	between	between	ADP
6108v982v3t	18	12	these	these	DET
6108v982v3t	18	13	complexes	complex	NOUN
6108v982v3t	18	14	and	and	CCONJ
6108v982v3t	18	15	nitroso	nitroso	NOUN
6108v982v3t	18	16	/	/	SYM
6108v982v3t	18	17	azo	azo	NOUN
6108v982v3t	18	18	substrates	substrate	NOUN
6108v982v3t	18	19	,	,	PUNCT
6108v982v3t	18	20	(	(	PUNCT
6108v982v3t	18	21	tbucliph2)pt	tbucliph2)pt	VERB
6108v982v3t	18	22	engages	engage	VERB
6108v982v3t	18	23	in	in	ADP
6108v982v3t	18	24	ene	ene	ADJ
6108v982v3t	18	25	-	-	PUNCT
6108v982v3t	18	26	type	type	NOUN
6108v982v3t	18	27	reactivity	reactivity	NOUN
6108v982v3t	18	28	with	with	ADP
6108v982v3t	18	29	cyclooctyne	cyclooctyne	NOUN
6108v982v3t	18	30	.	.	PUNCT
6108v982v3t	19	1	the	the	DET
6108v982v3t	19	2	evident	evident	ADJ
6108v982v3t	19	3	stereoselectivity	stereoselectivity	NOUN
6108v982v3t	19	4	and	and	CCONJ
6108v982v3t	19	5	regioselectivity	regioselectivity	NOUN
6108v982v3t	19	6	of	of	ADP
6108v982v3t	19	7	the	the	DET
6108v982v3t	19	8	product	product	NOUN
6108v982v3t	19	9	,	,	PUNCT
6108v982v3t	19	10	along	along	ADP
6108v982v3t	19	11	with	with	ADP
6108v982v3t	19	12	results	result	NOUN
6108v982v3t	19	13	from	from	ADP
6108v982v3t	19	14	radical	radical	ADJ
6108v982v3t	19	15	trapping	trap	VERB
6108v982v3t	19	16	experiments	experiment	NOUN
6108v982v3t	19	17	,	,	PUNCT
6108v982v3t	19	18	strongly	strongly	ADV
6108v982v3t	19	19	suggest	suggest	VERB
6108v982v3t	19	20	a	a	DET
6108v982v3t	19	21	concerted	concerted	ADJ
6108v982v3t	19	22	addition	addition	NOUN
6108v982v3t	19	23	reaction	reaction	NOUN
6108v982v3t	19	24	.	.	PUNCT
6108v982v3t	20	1	(	(	PUNCT
6108v982v3t	20	2	tbucliph2)pt	tbucliph2)pt	ADJ
6108v982v3t	20	3	was	be	AUX
6108v982v3t	20	4	also	also	ADV
6108v982v3t	20	5	observed	observe	VERB
6108v982v3t	20	6	to	to	PART
6108v982v3t	20	7	have	have	VERB
6108v982v3t	20	8	unique	unique	ADJ
6108v982v3t	20	9	reactivity	reactivity	NOUN
6108v982v3t	20	10	with	with	ADP
6108v982v3t	20	11	other	other	ADJ
6108v982v3t	20	12	electron	electron	NOUN
6108v982v3t	20	13	withdrawing	withdraw	VERB
6108v982v3t	20	14	alkynes	alkyne	NOUN
6108v982v3t	20	15	.	.	PUNCT