id	sid	tid	token	lemma	pos
4m90dv15v3z	1	1	this	this	DET
4m90dv15v3z	1	2	dissertation	dissertation	NOUN
4m90dv15v3z	1	3	describes	describe	VERB
4m90dv15v3z	1	4	an	an	DET
4m90dv15v3z	1	5	acceleration	acceleration	NOUN
4m90dv15v3z	1	6	of	of	ADP
4m90dv15v3z	1	7	the	the	DET
4m90dv15v3z	1	8	menshutkin	menshutkin	ADJ
4m90dv15v3z	1	9	reaction	reaction	NOUN
4m90dv15v3z	1	10	,	,	PUNCT
4m90dv15v3z	1	11	a	a	DET
4m90dv15v3z	1	12	distortion	distortion	NOUN
4m90dv15v3z	1	13	of	of	ADP
4m90dv15v3z	1	14	halide	halide	NOUN
4m90dv15v3z	1	15	leaving	leave	VERB
4m90dv15v3z	1	16	group	group	NOUN
4m90dv15v3z	1	17	order	order	NOUN
4m90dv15v3z	1	18	,	,	PUNCT
4m90dv15v3z	1	19	and	and	CCONJ
4m90dv15v3z	1	20	fluorescence	fluorescence	ADJ
4m90dv15v3z	1	21	sensing	sense	VERB
4m90dv15v3z	1	22	of	of	ADP
4m90dv15v3z	1	23	chloroalkanes	chloroalkane	NOUN
4m90dv15v3z	1	24	.	.	PUNCT
4m90dv15v3z	2	1	the	the	DET
4m90dv15v3z	2	2	first	first	ADJ
4m90dv15v3z	2	3	section	section	NOUN
4m90dv15v3z	2	4	is	be	AUX
4m90dv15v3z	2	5	the	the	DET
4m90dv15v3z	2	6	unprecedentedly	unprecedentedly	ADV
4m90dv15v3z	2	7	accelerated	accelerate	VERB
4m90dv15v3z	2	8	menshutkin	menshutkin	ADJ
4m90dv15v3z	2	9	reaction	reaction	NOUN
4m90dv15v3z	2	10	of	of	ADP
4m90dv15v3z	2	11	new	new	ADJ
4m90dv15v3z	2	12	designed	design	VERB
4m90dv15v3z	2	13	macrocyclic	macrocyclic	NOUN
4m90dv15v3z	2	14	amines	amine	NOUN
4m90dv15v3z	2	15	with	with	ADP
4m90dv15v3z	2	16	haloalkanes	haloalkane	NOUN
4m90dv15v3z	2	17	.	.	PUNCT
4m90dv15v3z	3	1	when	when	SCONJ
4m90dv15v3z	3	2	methylene	methylene	PROPN
4m90dv15v3z	3	3	chloride	chloride	PROPN
4m90dv15v3z	3	4	is	be	AUX
4m90dv15v3z	3	5	the	the	DET
4m90dv15v3z	3	6	solvent	solvent	NOUN
4m90dv15v3z	3	7	,	,	PUNCT
4m90dv15v3z	3	8	the	the	DET
4m90dv15v3z	3	9	reaction	reaction	NOUN
4m90dv15v3z	3	10	exhibits	exhibit	NOUN
4m90dv15v3z	3	11	pseudo	pseudo	NOUN
4m90dv15v3z	3	12	first	first	ADJ
4m90dv15v3z	3	13	order	order	NOUN
4m90dv15v3z	3	14	kinetics	kinetic	NOUN
4m90dv15v3z	3	15	,	,	PUNCT
4m90dv15v3z	3	16	and	and	CCONJ
4m90dv15v3z	3	17	the	the	DET
4m90dv15v3z	3	18	reaction	reaction	NOUN
4m90dv15v3z	3	19	half	half	ADJ
4m90dv15v3z	3	20	-	-	PUNCT
4m90dv15v3z	3	21	life	life	NOUN
4m90dv15v3z	3	22	at	at	ADP
4m90dv15v3z	3	23	25	25	NUM
4m90dv15v3z	3	24	ìâå¡c	ìâå¡c	NUM
4m90dv15v3z	3	25	is	be	AUX
4m90dv15v3z	3	26	2.0	2.0	NUM
4m90dv15v3z	3	27	min	min	NOUN
4m90dv15v3z	3	28	.	.	PUNCT
4m90dv15v3z	4	1	the	the	DET
4m90dv15v3z	4	2	reaction	reaction	NOUN
4m90dv15v3z	4	3	half	half	ADJ
4m90dv15v3z	4	4	-	-	PUNCT
4m90dv15v3z	4	5	life	life	NOUN
4m90dv15v3z	4	6	for	for	ADP
4m90dv15v3z	4	7	a	a	DET
4m90dv15v3z	4	8	structurally	structurally	ADV
4m90dv15v3z	4	9	related	relate	VERB
4m90dv15v3z	4	10	acyclic	acyclic	NOUN
4m90dv15v3z	4	11	amine	amine	NOUN
4m90dv15v3z	4	12	is	be	AUX
4m90dv15v3z	4	13	approximately	approximately	ADV
4m90dv15v3z	4	14	50,000	50,000	NUM
4m90dv15v3z	4	15	times	time	NOUN
4m90dv15v3z	4	16	longer	long	ADV
4m90dv15v3z	4	17	.	.	PUNCT
4m90dv15v3z	5	1	the	the	DET
4m90dv15v3z	5	2	second	second	ADJ
4m90dv15v3z	5	3	section	section	NOUN
4m90dv15v3z	5	4	demonstrates	demonstrate	VERB
4m90dv15v3z	5	5	a	a	DET
4m90dv15v3z	5	6	major	major	ADJ
4m90dv15v3z	5	7	distortion	distortion	NOUN
4m90dv15v3z	5	8	of	of	ADP
4m90dv15v3z	5	9	the	the	DET
4m90dv15v3z	5	10	halide	halide	NOUN
4m90dv15v3z	5	11	leaving	leave	VERB
4m90dv15v3z	5	12	group	group	NOUN
4m90dv15v3z	5	13	order	order	NOUN
4m90dv15v3z	5	14	.	.	PUNCT
4m90dv15v3z	6	1	for	for	ADP
4m90dv15v3z	6	2	example	example	NOUN
4m90dv15v3z	6	3	,	,	PUNCT
4m90dv15v3z	6	4	with	with	SCONJ
4m90dv15v3z	6	5	benzyl	benzyl	NOUN
4m90dv15v3z	6	6	halides	halide	VERB
4m90dv15v3z	6	7	the	the	DET
4m90dv15v3z	6	8	relative	relative	ADJ
4m90dv15v3z	6	9	leaving	leave	VERB
4m90dv15v3z	6	10	group	group	NOUN
4m90dv15v3z	6	11	order	order	NOUN
4m90dv15v3z	6	12	with	with	ADP
4m90dv15v3z	6	13	a	a	DET
4m90dv15v3z	6	14	control	control	NOUN
4m90dv15v3z	6	15	amine	amine	NOUN
4m90dv15v3z	6	16	is	be	AUX
4m90dv15v3z	6	17	cl	cl	PROPN
4m90dv15v3z	6	18	(	(	PUNCT
4m90dv15v3z	6	19	1.0	1.0	NUM
4m90dv15v3z	6	20	)	)	PUNCT
4m90dv15v3z	7	1	<	<	X
4m90dv15v3z	7	2	br	br	PROPN
4m90dv15v3z	7	3	(	(	PUNCT
4m90dv15v3z	7	4	71	71	NUM
4m90dv15v3z	7	5	)	)	PUNCT
4m90dv15v3z	7	6	<	<	X
4m90dv15v3z	7	7	i	i	PRON
4m90dv15v3z	7	8	(	(	PUNCT
4m90dv15v3z	7	9	160	160	NUM
4m90dv15v3z	7	10	)	)	PUNCT
4m90dv15v3z	7	11	,	,	PUNCT
4m90dv15v3z	7	12	whereas	whereas	SCONJ
4m90dv15v3z	7	13	the	the	DET
4m90dv15v3z	7	14	leaving	leave	VERB
4m90dv15v3z	7	15	group	group	NOUN
4m90dv15v3z	7	16	order	order	NOUN
4m90dv15v3z	7	17	with	with	ADP
4m90dv15v3z	7	18	the	the	DET
4m90dv15v3z	7	19	macrocyclic	macrocyclic	NOUN
4m90dv15v3z	7	20	amine	amine	NOUN
4m90dv15v3z	7	21	is	be	AUX
4m90dv15v3z	7	22	i	i	PRON
4m90dv15v3z	7	23	(	(	PUNCT
4m90dv15v3z	7	24	0.4	0.4	NUM
4m90dv15v3z	7	25	)	)	PUNCT
4m90dv15v3z	7	26	<	<	X
4m90dv15v3z	7	27	cl	cl	PROPN
4m90dv15v3z	7	28	(	(	PUNCT
4m90dv15v3z	7	29	1.0	1.0	NUM
4m90dv15v3z	7	30	)	)	PUNCT
4m90dv15v3z	7	31	<	<	X
4m90dv15v3z	8	1	br	br	PROPN
4m90dv15v3z	8	2	(	(	PUNCT
4m90dv15v3z	8	3	8.5	8.5	NUM
4m90dv15v3z	8	4	)	)	PUNCT
4m90dv15v3z	8	5	.	.	PUNCT
4m90dv15v3z	9	1	enzyme	enzyme	NOUN
4m90dv15v3z	9	2	-	-	PUNCT
4m90dv15v3z	9	3	like	like	ADJ
4m90dv15v3z	9	4	mechanistic	mechanistic	ADJ
4m90dv15v3z	9	5	studies	study	NOUN
4m90dv15v3z	9	6	indicate	indicate	VERB
4m90dv15v3z	9	7	that	that	SCONJ
4m90dv15v3z	9	8	haloalkanes	haloalkane	NOUN
4m90dv15v3z	9	9	associate	associate	VERB
4m90dv15v3z	9	10	with	with	ADP
4m90dv15v3z	9	11	the	the	DET
4m90dv15v3z	9	12	macrocycle	macrocycle	NOUN
4m90dv15v3z	9	13	to	to	PART
4m90dv15v3z	9	14	form	form	VERB
4m90dv15v3z	9	15	an	an	DET
4m90dv15v3z	9	16	activated	activate	VERB
4m90dv15v3z	9	17	pre	pre	ADJ
4m90dv15v3z	9	18	-	-	ADJ
4m90dv15v3z	9	19	reaction	reaction	ADJ
4m90dv15v3z	9	20	complex	complex	NOUN
4m90dv15v3z	9	21	.	.	PUNCT
4m90dv15v3z	10	1	the	the	DET
4m90dv15v3z	10	2	macrocyclic	macrocyclic	NOUN
4m90dv15v3z	10	3	nitrogen	nitrogen	NOUN
4m90dv15v3z	10	4	subsequently	subsequently	ADV
4m90dv15v3z	10	5	attacks	attack	VERB
4m90dv15v3z	10	6	the	the	DET
4m90dv15v3z	10	7	haloalkanes	haloalkane	NOUN
4m90dv15v3z	10	8	with	with	ADP
4m90dv15v3z	10	9	a	a	DET
4m90dv15v3z	10	10	classic	classic	ADJ
4m90dv15v3z	10	11	sn2	sn2	PROPN
4m90dv15v3z	10	12	trajectory	trajectory	NOUN
4m90dv15v3z	10	13	,	,	PUNCT
4m90dv15v3z	10	14	and	and	CCONJ
4m90dv15v3z	10	15	although	although	SCONJ
4m90dv15v3z	10	16	the	the	DET
4m90dv15v3z	10	17	carbon	carbon	NOUN
4m90dv15v3z	10	18	-	-	PUNCT
4m90dv15v3z	10	19	chlorine	chlorine	NOUN
4m90dv15v3z	10	20	bond	bond	NOUN
4m90dv15v3z	10	21	breaks	break	NOUN
4m90dv15v3z	10	22	,	,	PUNCT
4m90dv15v3z	10	23	the	the	DET
4m90dv15v3z	10	24	chloride	chloride	NOUN
4m90dv15v3z	10	25	leaving	leave	VERB
4m90dv15v3z	10	26	group	group	NOUN
4m90dv15v3z	10	27	does	do	AUX
4m90dv15v3z	10	28	not	not	PART
4m90dv15v3z	10	29	separate	separate	VERB
4m90dv15v3z	10	30	from	from	ADP
4m90dv15v3z	10	31	the	the	DET
4m90dv15v3z	10	32	newly	newly	ADV
4m90dv15v3z	10	33	formed	form	VERB
4m90dv15v3z	10	34	cationic	cationic	ADJ
4m90dv15v3z	10	35	macrocycle	macrocycle	NOUN
4m90dv15v3z	10	36	,	,	PUNCT
4m90dv15v3z	10	37	such	such	ADJ
4m90dv15v3z	10	38	that	that	SCONJ
4m90dv15v3z	10	39	the	the	DET
4m90dv15v3z	10	40	product	product	NOUN
4m90dv15v3z	10	41	is	be	AUX
4m90dv15v3z	10	42	a	a	DET
4m90dv15v3z	10	43	tightly	tightly	ADV
4m90dv15v3z	10	44	associated	associate	VERB
4m90dv15v3z	10	45	ion	ion	NOUN
4m90dv15v3z	10	46	-	-	PUNCT
4m90dv15v3z	10	47	pair	pair	NOUN
4m90dv15v3z	10	48	.	.	PUNCT
4m90dv15v3z	11	1	in	in	ADP
4m90dv15v3z	11	2	additon	additon	PROPN
4m90dv15v3z	11	3	,	,	PUNCT
4m90dv15v3z	11	4	the	the	DET
4m90dv15v3z	11	5	free	free	ADJ
4m90dv15v3z	11	6	energy	energy	NOUN
4m90dv15v3z	11	7	of	of	ADP
4m90dv15v3z	11	8	activation	activation	NOUN
4m90dv15v3z	11	9	is	be	AUX
4m90dv15v3z	11	10	selectively	selectively	ADV
4m90dv15v3z	11	11	decreased	decrease	VERB
4m90dv15v3z	11	12	for	for	ADP
4m90dv15v3z	11	13	organohalides	organohalide	NOUN
4m90dv15v3z	11	14	having	have	VERB
4m90dv15v3z	11	15	smaller	small	ADJ
4m90dv15v3z	11	16	and	and	CCONJ
4m90dv15v3z	11	17	more	more	ADV
4m90dv15v3z	11	18	charge	charge	NOUN
4m90dv15v3z	11	19	dense	dense	ADJ
4m90dv15v3z	11	20	leaving	leave	VERB
4m90dv15v3z	11	21	groups	group	NOUN
4m90dv15v3z	11	22	.	.	PUNCT
4m90dv15v3z	12	1	likely	likely	ADJ
4m90dv15v3z	12	2	reasons	reason	NOUN
4m90dv15v3z	12	3	for	for	ADP
4m90dv15v3z	12	4	this	this	DET
4m90dv15v3z	12	5	selective	selective	ADJ
4m90dv15v3z	12	6	enhancement	enhancement	NOUN
4m90dv15v3z	12	7	effect	effect	NOUN
4m90dv15v3z	12	8	are	be	AUX
4m90dv15v3z	12	9	:	:	PUNCT
4m90dv15v3z	12	10	(	(	PUNCT
4m90dv15v3z	12	11	a	a	X
4m90dv15v3z	12	12	)	)	PUNCT
4m90dv15v3z	12	13	increased	increase	VERB
4m90dv15v3z	12	14	transition	transition	NOUN
4m90dv15v3z	12	15	-	-	PUNCT
4m90dv15v3z	12	16	state	state	NOUN
4m90dv15v3z	12	17	stabilization	stabilization	NOUN
4m90dv15v3z	12	18	due	due	ADP
4m90dv15v3z	12	19	to	to	ADP
4m90dv15v3z	12	20	hydrogen	hydrogen	NOUN
4m90dv15v3z	12	21	bonding	bonding	NOUN
4m90dv15v3z	12	22	in	in	ADP
4m90dv15v3z	12	23	the	the	DET
4m90dv15v3z	12	24	macrocyclic	macrocyclic	NOUN
4m90dv15v3z	12	25	pocket	pocket	NOUN
4m90dv15v3z	12	26	and	and	CCONJ
4m90dv15v3z	12	27	(	(	PUNCT
4m90dv15v3z	12	28	b	b	X
4m90dv15v3z	12	29	)	)	PUNCT
4m90dv15v3z	12	30	reduced	reduce	VERB
4m90dv15v3z	12	31	entropic	entropic	ADJ
4m90dv15v3z	12	32	penalty	penalty	NOUN
4m90dv15v3z	12	33	in	in	ADP
4m90dv15v3z	12	34	the	the	DET
4m90dv15v3z	12	35	transition	transition	NOUN
4m90dv15v3z	12	36	state	state	NOUN
4m90dv15v3z	12	37	due	due	ADP
4m90dv15v3z	12	38	to	to	ADP
4m90dv15v3z	12	39	an	an	DET
4m90dv15v3z	12	40	increased	increase	VERB
4m90dv15v3z	12	41	fraction	fraction	NOUN
4m90dv15v3z	12	42	of	of	ADP
4m90dv15v3z	12	43	pre	pre	ADJ
4m90dv15v3z	12	44	-	-	ADJ
4m90dv15v3z	12	45	reaction	reaction	ADJ
4m90dv15v3z	12	46	complexes	complex	NOUN
4m90dv15v3z	12	47	that	that	PRON
4m90dv15v3z	12	48	are	be	AUX
4m90dv15v3z	12	49	oriented	orient	VERB
4m90dv15v3z	12	50	in	in	ADP
4m90dv15v3z	12	51	a	a	DET
4m90dv15v3z	12	52	near	near	ADJ
4m90dv15v3z	12	53	attack	attack	NOUN
4m90dv15v3z	12	54	conformation	conformation	NOUN
4m90dv15v3z	12	55	.	.	PUNCT
4m90dv15v3z	13	1	the	the	DET
4m90dv15v3z	13	2	last	last	ADJ
4m90dv15v3z	13	3	portion	portion	NOUN
4m90dv15v3z	13	4	of	of	ADP
4m90dv15v3z	13	5	this	this	DET
4m90dv15v3z	13	6	dissertation	dissertation	NOUN
4m90dv15v3z	13	7	describes	describe	VERB
4m90dv15v3z	13	8	as	as	ADP
4m90dv15v3z	13	9	pet	pet	ADJ
4m90dv15v3z	13	10	fluorescent	fluorescent	NOUN
4m90dv15v3z	13	11	sensors	sensor	NOUN
4m90dv15v3z	13	12	two	two	NUM
4m90dv15v3z	13	13	structurally	structurally	ADV
4m90dv15v3z	13	14	related	relate	VERB
4m90dv15v3z	13	15	macrocyclic	macrocyclic	NOUN
4m90dv15v3z	13	16	amines	amine	NOUN
4m90dv15v3z	13	17	with	with	ADP
4m90dv15v3z	13	18	naphthalene	naphthalene	NOUN
4m90dv15v3z	13	19	groups	group	NOUN
4m90dv15v3z	13	20	for	for	ADP
4m90dv15v3z	13	21	reactive	reactive	ADJ
4m90dv15v3z	13	22	chloroalkanes	chloroalkane	NOUN
4m90dv15v3z	13	23	,	,	PUNCT
4m90dv15v3z	13	24	including	include	VERB
4m90dv15v3z	13	25	the	the	DET
4m90dv15v3z	13	26	common	common	ADJ
4m90dv15v3z	13	27	industrial	industrial	ADJ
4m90dv15v3z	13	28	solvent	solvent	PROPN
4m90dv15v3z	13	29	methylene	methylene	NOUN
4m90dv15v3z	13	30	chloride	chloride	PROPN
4m90dv15v3z	13	31	and	and	CCONJ
4m90dv15v3z	13	32	carcinogenic	carcinogenic	PROPN
4m90dv15v3z	13	33	chloromethyl	chloromethyl	NOUN
4m90dv15v3z	13	34	methylether	methylether	ADV
4m90dv15v3z	13	35	.	.	PUNCT