id	sid	tid	token	lemma	pos
44558c99f92	1	1	this	this	DET
44558c99f92	1	2	dissertation	dissertation	NOUN
44558c99f92	1	3	concerns	concern	VERB
44558c99f92	1	4	itself	itself	PRON
44558c99f92	1	5	with	with	ADP
44558c99f92	1	6	the	the	DET
44558c99f92	1	7	interaction	interaction	NOUN
44558c99f92	1	8	of	of	ADP
44558c99f92	1	9	diatomic	diatomic	ADJ
44558c99f92	1	10	molecules	molecule	NOUN
44558c99f92	1	11	with	with	ADP
44558c99f92	1	12	heme	heme	NOUN
44558c99f92	1	13	.	.	PUNCT
44558c99f92	2	1	more	more	ADV
44558c99f92	2	2	specifically	specifically	ADV
44558c99f92	2	3	,	,	PUNCT
44558c99f92	2	4	fiveand	fiveand	VERB
44558c99f92	2	5	six	six	NUM
44558c99f92	2	6	-	-	PUNCT
44558c99f92	2	7	coordinate	coordinate	NOUN
44558c99f92	2	8	low	low	ADJ
44558c99f92	2	9	-	-	PUNCT
44558c99f92	2	10	spin	spin	NOUN
44558c99f92	2	11	iron(ii	iron(ii	NOUN
44558c99f92	2	12	)	)	PUNCT
44558c99f92	2	13	porphyrinates	porphyrinate	NOUN
44558c99f92	2	14	will	will	AUX
44558c99f92	2	15	be	be	AUX
44558c99f92	2	16	considered	consider	VERB
44558c99f92	2	17	.	.	PUNCT
44558c99f92	3	1	complexes	complex	NOUN
44558c99f92	3	2	of	of	ADP
44558c99f92	3	3	the	the	DET
44558c99f92	3	4	form	form	NOUN
44558c99f92	3	5	[	[	X
44558c99f92	3	6	fe(porph)(xo)(l	fe(porph)(xo)(l	X
44558c99f92	3	7	)	)	PUNCT
44558c99f92	3	8	]	]	PUNCT
44558c99f92	3	9	(	(	PUNCT
44558c99f92	3	10	x	x	PUNCT
44558c99f92	3	11	=	=	X
44558c99f92	3	12	n	n	X
44558c99f92	3	13	or	or	CCONJ
44558c99f92	3	14	c	c	PROPN
44558c99f92	3	15	and	and	CCONJ
44558c99f92	3	16	l	l	NOUN
44558c99f92	3	17	=	=	SYM
44558c99f92	3	18	1	1	NUM
44558c99f92	3	19	-	-	PUNCT
44558c99f92	3	20	meim	meim	NOUN
44558c99f92	3	21	,	,	PUNCT
44558c99f92	3	22	1,2	1,2	PROPN
44558c99f92	3	23	-	-	PUNCT
44558c99f92	3	24	dimeim	dimeim	PROPN
44558c99f92	3	25	,	,	PUNCT
44558c99f92	3	26	2	2	NUM
44558c99f92	3	27	-	-	PUNCT
44558c99f92	3	28	mehim	mehim	PROPN
44558c99f92	3	29	,	,	PUNCT
44558c99f92	3	30	4	4	NUM
44558c99f92	3	31	-	-	PUNCT
44558c99f92	3	32	mepip	mepip	NOUN
44558c99f92	3	33	,	,	PUNCT
44558c99f92	3	34	co	co	NOUN
44558c99f92	3	35	,	,	PUNCT
44558c99f92	3	36	or	or	CCONJ
44558c99f92	3	37	no	no	DET
44558c99f92	3	38	ligand	ligand	NOUN
44558c99f92	3	39	)	)	PUNCT
44558c99f92	3	40	have	have	AUX
44558c99f92	3	41	been	be	AUX
44558c99f92	3	42	synthesized	synthesize	VERB
44558c99f92	3	43	.	.	PUNCT
44558c99f92	4	1	these	these	DET
44558c99f92	4	2	systems	system	NOUN
44558c99f92	4	3	have	have	AUX
44558c99f92	4	4	been	be	AUX
44558c99f92	4	5	extensively	extensively	ADV
44558c99f92	4	6	studied	study	VERB
44558c99f92	4	7	using	use	VERB
44558c99f92	4	8	x	x	NOUN
44558c99f92	4	9	-	-	NOUN
44558c99f92	4	10	ray	ray	NOUN
44558c99f92	4	11	crystallography	crystallography	NOUN
44558c99f92	4	12	,	,	PUNCT
44558c99f92	4	13	mössbauer	mössbauer	ADJ
44558c99f92	4	14	spectroscopy	spectroscopy	NOUN
44558c99f92	4	15	,	,	PUNCT
44558c99f92	4	16	infrared	infrared	ADJ
44558c99f92	4	17	absorption	absorption	NOUN
44558c99f92	4	18	spectroscopy	spectroscopy	NOUN
44558c99f92	4	19	,	,	PUNCT
44558c99f92	4	20	resonance	resonance	NOUN
44558c99f92	4	21	raman	raman	NOUN
44558c99f92	4	22	spectroscopy	spectroscopy	NOUN
44558c99f92	4	23	,	,	PUNCT
44558c99f92	4	24	and	and	CCONJ
44558c99f92	4	25	nuclear	nuclear	ADJ
44558c99f92	4	26	resonance	resonance	NOUN
44558c99f92	4	27	vibrational	vibrational	NOUN
44558c99f92	4	28	spectroscopy	spectroscopy	NOUN
44558c99f92	4	29	(	(	PUNCT
44558c99f92	4	30	nrvs	nrvs	PROPN
44558c99f92	4	31	)	)	PUNCT
44558c99f92	4	32	,	,	PUNCT
44558c99f92	4	33	thereby	thereby	ADV
44558c99f92	4	34	providing	provide	VERB
44558c99f92	4	35	new	new	ADJ
44558c99f92	4	36	information	information	NOUN
44558c99f92	4	37	regarding	regard	VERB
44558c99f92	4	38	structural	structural	ADJ
44558c99f92	4	39	and	and	CCONJ
44558c99f92	4	40	vibrational	vibrational	ADJ
44558c99f92	4	41	characteristics	characteristic	NOUN
44558c99f92	4	42	of	of	ADP
44558c99f92	4	43	hemes	heme	NOUN
44558c99f92	4	44	coordinated	coordinate	VERB
44558c99f92	4	45	with	with	ADP
44558c99f92	4	46	diatomic	diatomic	ADJ
44558c99f92	4	47	molecules	molecule	NOUN
44558c99f92	4	48	.	.	PUNCT
44558c99f92	5	1	the	the	DET
44558c99f92	5	2	first	first	ADJ
44558c99f92	5	3	structural	structural	ADJ
44558c99f92	5	4	characterization	characterization	NOUN
44558c99f92	5	5	of	of	ADP
44558c99f92	5	6	a	a	DET
44558c99f92	5	7	5	5	NUM
44558c99f92	5	8	-	-	PUNCT
44558c99f92	5	9	coordinate	coordinate	NOUN
44558c99f92	5	10	heme	heme	NOUN
44558c99f92	5	11	-	-	PUNCT
44558c99f92	5	12	co	co	NOUN
44558c99f92	5	13	,	,	PUNCT
44558c99f92	5	14	bis	bis	ADJ
44558c99f92	5	15	-	-	PUNCT
44558c99f92	5	16	carbonyl	carbonyl	ADJ
44558c99f92	5	17	ligated	ligated	ADJ
44558c99f92	5	18	heme	heme	NOUN
44558c99f92	5	19	,	,	PUNCT
44558c99f92	5	20	and	and	CCONJ
44558c99f92	5	21	completely	completely	ADV
44558c99f92	5	22	ordered	order	VERB
44558c99f92	5	23	six	six	NUM
44558c99f92	5	24	-	-	PUNCT
44558c99f92	5	25	coordinate	coordinate	NOUN
44558c99f92	5	26	heme	heme	NOUN
44558c99f92	5	27	-	-	PUNCT
44558c99f92	5	28	no	no	PRON
44558c99f92	5	29	are	be	AUX
44558c99f92	5	30	reported	report	VERB
44558c99f92	5	31	.	.	PUNCT
44558c99f92	6	1	temperature	temperature	NOUN
44558c99f92	6	2	-	-	PUNCT
44558c99f92	6	3	dependent	dependent	ADJ
44558c99f92	6	4	information	information	NOUN
44558c99f92	6	5	has	have	AUX
44558c99f92	6	6	also	also	ADV
44558c99f92	6	7	been	be	AUX
44558c99f92	6	8	acquired	acquire	VERB
44558c99f92	6	9	.	.	PUNCT
44558c99f92	7	1	this	this	DET
44558c99f92	7	2	information	information	NOUN
44558c99f92	7	3	reveals	reveal	VERB
44558c99f92	7	4	the	the	DET
44558c99f92	7	5	temperature	temperature	NOUN
44558c99f92	7	6	dependence	dependence	NOUN
44558c99f92	7	7	of	of	ADP
44558c99f92	7	8	the	the	DET
44558c99f92	7	9	structural	structural	ADJ
44558c99f92	7	10	and	and	CCONJ
44558c99f92	7	11	vibrational	vibrational	ADJ
44558c99f92	7	12	parameters	parameter	NOUN
44558c99f92	7	13	of	of	ADP
44558c99f92	7	14	heme	heme	NOUN
44558c99f92	7	15	complexes	complex	NOUN
44558c99f92	7	16	,	,	PUNCT
44558c99f92	7	17	especially	especially	ADV
44558c99f92	7	18	the	the	DET
44558c99f92	7	19	biologically	biologically	ADV
44558c99f92	7	20	relevant	relevant	ADJ
44558c99f92	7	21	fe	fe	PROPN
44558c99f92	7	22	-	-	PUNCT
44558c99f92	7	23	his	his	PRON
44558c99f92	7	24	bond	bond	NOUN
44558c99f92	7	25	,	,	PUNCT
44558c99f92	7	26	and	and	CCONJ
44558c99f92	7	27	relates	relate	VERB
44558c99f92	7	28	them	they	PRON
44558c99f92	7	29	to	to	ADP
44558c99f92	7	30	thermal	thermal	ADJ
44558c99f92	7	31	expansion	expansion	NOUN
44558c99f92	7	32	and	and	CCONJ
44558c99f92	7	33	contraction	contraction	NOUN
44558c99f92	7	34	in	in	ADP
44558c99f92	7	35	the	the	DET
44558c99f92	7	36	solid	solid	ADJ
44558c99f92	7	37	state	state	NOUN
44558c99f92	7	38	.	.	PUNCT
44558c99f92	8	1	finally	finally	ADV
44558c99f92	8	2	,	,	PUNCT
44558c99f92	8	3	the	the	DET
44558c99f92	8	4	nrvs	nrvs	NOUN
44558c99f92	8	5	technique	technique	NOUN
44558c99f92	8	6	is	be	AUX
44558c99f92	8	7	used	use	VERB
44558c99f92	8	8	extensively	extensively	ADV
44558c99f92	8	9	to	to	PART
44558c99f92	8	10	reveal	reveal	VERB
44558c99f92	8	11	the	the	DET
44558c99f92	8	12	fe	fe	PROPN
44558c99f92	8	13	vibrational	vibrational	ADJ
44558c99f92	8	14	dynamics	dynamic	NOUN
44558c99f92	8	15	of	of	ADP
44558c99f92	8	16	heme	heme	NOUN
44558c99f92	8	17	coordinated	coordinate	VERB
44558c99f92	8	18	by	by	ADP
44558c99f92	8	19	diatomic	diatomic	ADJ
44558c99f92	8	20	molecules	molecule	NOUN
44558c99f92	8	21	.	.	PUNCT
44558c99f92	9	1	these	these	DET
44558c99f92	9	2	studies	study	NOUN
44558c99f92	9	3	reveal	reveal	VERB
44558c99f92	9	4	several	several	ADJ
44558c99f92	9	5	reactive	reactive	ADJ
44558c99f92	9	6	vibrational	vibrational	ADJ
44558c99f92	9	7	modes	mode	NOUN
44558c99f92	9	8	associated	associate	VERB
44558c99f92	9	9	with	with	ADP
44558c99f92	9	10	ligand	ligand	NOUN
44558c99f92	9	11	ejection	ejection	NOUN
44558c99f92	9	12	and	and	CCONJ
44558c99f92	9	13	activation	activation	NOUN
44558c99f92	9	14	which	which	PRON
44558c99f92	9	15	have	have	AUX
44558c99f92	9	16	not	not	PART
44558c99f92	9	17	previously	previously	ADV
44558c99f92	9	18	been	be	AUX
44558c99f92	9	19	described	describe	VERB
44558c99f92	9	20	.	.	PUNCT