id	sid	tid	token	lemma	pos
3j333199s86	1	1	this	this	DET
3j333199s86	1	2	thesis	thesis	NOUN
3j333199s86	1	3	focuses	focus	VERB
3j333199s86	1	4	on	on	ADP
3j333199s86	1	5	understanding	understand	VERB
3j333199s86	1	6	the	the	DET
3j333199s86	1	7	relationship	relationship	NOUN
3j333199s86	1	8	between	between	ADP
3j333199s86	1	9	the	the	DET
3j333199s86	1	10	active	active	ADJ
3j333199s86	1	11	site	site	NOUN
3j333199s86	1	12	structure	structure	NOUN
3j333199s86	1	13	and	and	CCONJ
3j333199s86	1	14	function	function	NOUN
3j333199s86	1	15	in	in	ADP
3j333199s86	1	16	the	the	DET
3j333199s86	1	17	heme	heme	NOUN
3j333199s86	1	18	-	-	PUNCT
3j333199s86	1	19	containing	contain	VERB
3j333199s86	1	20	enzyme	enzyme	NOUN
3j333199s86	1	21	chlorite	chlorite	NOUN
3j333199s86	1	22	dismutase	dismutase	NOUN
3j333199s86	1	23	from	from	ADP
3j333199s86	1	24	dechloromonas	dechloromonas	PROPN
3j333199s86	1	25	aromatica	aromatica	PROPN
3j333199s86	1	26	(	(	PUNCT
3j333199s86	1	27	dacld	dacld	NOUN
3j333199s86	1	28	)	)	PUNCT
3j333199s86	1	29	.	.	PUNCT
3j333199s86	2	1	dacld	dacld	NOUN
3j333199s86	2	2	decomposes	decompose	VERB
3j333199s86	2	3	chlorite	chlorite	PROPN
3j333199s86	2	4	(	(	PUNCT
3j333199s86	2	5	clo2-	clo2-	NOUN
3j333199s86	2	6	)	)	PUNCT
3j333199s86	2	7	into	into	ADP
3j333199s86	2	8	chloride	chloride	PROPN
3j333199s86	2	9	(	(	PUNCT
3j333199s86	2	10	cl-	cl-	NOUN
3j333199s86	2	11	)	)	PUNCT
3j333199s86	2	12	and	and	CCONJ
3j333199s86	2	13	oxygen	oxygen	NOUN
3j333199s86	2	14	(	(	PUNCT
3j333199s86	2	15	o2	o2	NOUN
3j333199s86	2	16	)	)	PUNCT
3j333199s86	2	17	via	via	ADP
3j333199s86	2	18	an	an	DET
3j333199s86	2	19	efficient	efficient	ADJ
3j333199s86	2	20	reaction	reaction	NOUN
3j333199s86	2	21	that	that	PRON
3j333199s86	2	22	is	be	AUX
3j333199s86	2	23	nearly	nearly	ADV
3j333199s86	2	24	diffusion	diffusion	NOUN
3j333199s86	2	25	controlled	control	VERB
3j333199s86	2	26	.	.	PUNCT
3j333199s86	3	1	due	due	ADP
3j333199s86	3	2	to	to	ADP
3j333199s86	3	3	the	the	DET
3j333199s86	3	4	existence	existence	NOUN
3j333199s86	3	5	of	of	ADP
3j333199s86	3	6	advanced	advanced	ADJ
3j333199s86	3	7	structure	structure	NOUN
3j333199s86	3	8	-	-	PUNCT
3j333199s86	3	9	activity	activity	NOUN
3j333199s86	3	10	models	model	NOUN
3j333199s86	3	11	for	for	ADP
3j333199s86	3	12	heme	heme	NOUN
3j333199s86	3	13	peroxidases	peroxidase	NOUN
3j333199s86	3	14	and	and	CCONJ
3j333199s86	3	15	the	the	DET
3j333199s86	3	16	similarity	similarity	NOUN
3j333199s86	3	17	of	of	ADP
3j333199s86	3	18	the	the	DET
3j333199s86	3	19	behavior	behavior	NOUN
3j333199s86	3	20	of	of	ADP
3j333199s86	3	21	peroxide	peroxide	NOUN
3j333199s86	3	22	and	and	CCONJ
3j333199s86	3	23	chlorite	chlorite	NOUN
3j333199s86	3	24	as	as	ADP
3j333199s86	3	25	substrates	substrate	NOUN
3j333199s86	3	26	,	,	PUNCT
3j333199s86	3	27	we	we	PRON
3j333199s86	3	28	initiated	initiate	VERB
3j333199s86	3	29	our	our	PRON
3j333199s86	3	30	structure	structure	NOUN
3j333199s86	3	31	-	-	PUNCT
3j333199s86	3	32	function	function	NOUN
3j333199s86	3	33	studies	study	NOUN
3j333199s86	3	34	in	in	ADP
3j333199s86	3	35	2008	2008	NUM
3j333199s86	3	36	by	by	ADP
3j333199s86	3	37	analogy	analogy	NOUN
3j333199s86	3	38	to	to	ADP
3j333199s86	3	39	these	these	DET
3j333199s86	3	40	enzymes	enzyme	NOUN
3j333199s86	3	41	.	.	PUNCT
3j333199s86	4	1	in	in	ADP
3j333199s86	4	2	2009	2009	NUM
3j333199s86	4	3	,	,	PUNCT
3j333199s86	4	4	the	the	DET
3j333199s86	4	5	crystal	crystal	NOUN
3j333199s86	4	6	structures	structure	NOUN
3j333199s86	4	7	of	of	ADP
3j333199s86	4	8	dacld	dacld	NOUN
3j333199s86	4	9	and	and	CCONJ
3j333199s86	4	10	a	a	DET
3j333199s86	4	11	second	second	ADJ
3j333199s86	4	12	cld	cld	NOUN
3j333199s86	4	13	were	be	AUX
3j333199s86	4	14	solved	solve	VERB
3j333199s86	4	15	for	for	ADP
3j333199s86	4	16	the	the	DET
3j333199s86	4	17	first	first	ADJ
3j333199s86	4	18	time	time	NOUN
3j333199s86	4	19	,	,	PUNCT
3j333199s86	4	20	allowing	allow	VERB
3j333199s86	4	21	us	we	PRON
3j333199s86	4	22	to	to	PART
3j333199s86	4	23	consider	consider	VERB
3j333199s86	4	24	the	the	DET
3j333199s86	4	25	influence	influence	NOUN
3j333199s86	4	26	of	of	ADP
3j333199s86	4	27	structural	structural	ADJ
3j333199s86	4	28	elements	element	NOUN
3j333199s86	4	29	directly	directly	ADV
3j333199s86	4	30	.	.	PUNCT
3j333199s86	5	1	we	we	PRON
3j333199s86	5	2	investigated	investigate	VERB
3j333199s86	5	3	the	the	DET
3j333199s86	5	4	role	role	NOUN
3j333199s86	5	5	of	of	ADP
3j333199s86	5	6	an	an	DET
3j333199s86	5	7	arginine	arginine	NOUN
3j333199s86	5	8	residue	residue	NOUN
3j333199s86	5	9	(	(	PUNCT
3j333199s86	5	10	arg183	arg183	PROPN
3j333199s86	5	11	)	)	PUNCT
3j333199s86	5	12	in	in	ADP
3j333199s86	5	13	the	the	DET
3j333199s86	5	14	pocket	pocket	NOUN
3j333199s86	5	15	above	above	ADP
3j333199s86	5	16	the	the	DET
3j333199s86	5	17	heme	heme	NOUN
3j333199s86	5	18	plane	plane	NOUN
3j333199s86	5	19	in	in	ADP
3j333199s86	5	20	catalysis	catalysis	NOUN
3j333199s86	5	21	using	use	VERB
3j333199s86	5	22	diverse	diverse	ADJ
3j333199s86	5	23	biochemistry	biochemistry	NOUN
3j333199s86	5	24	,	,	PUNCT
3j333199s86	5	25	molecular	molecular	ADJ
3j333199s86	5	26	biology	biology	NOUN
3j333199s86	5	27	and	and	CCONJ
3j333199s86	5	28	spectroscopy	spectroscopy	ADJ
3j333199s86	5	29	techniques	technique	NOUN
3j333199s86	5	30	(	(	PUNCT
3j333199s86	5	31	notably	notably	ADV
3j333199s86	5	32	stopped	stop	VERB
3j333199s86	5	33	-	-	PUNCT
3j333199s86	5	34	flow	flow	NOUN
3j333199s86	5	35	,	,	PUNCT
3j333199s86	5	36	resonance	resonance	NOUN
3j333199s86	5	37	raman	raman	NOUN
3j333199s86	5	38	,	,	PUNCT
3j333199s86	5	39	uv	uv	NOUN
3j333199s86	5	40	/	/	SYM
3j333199s86	5	41	visible	visible	ADJ
3j333199s86	5	42	)	)	PUNCT
3j333199s86	5	43	.	.	PUNCT
3j333199s86	6	1	we	we	PRON
3j333199s86	6	2	mutated	mutate	VERB
3j333199s86	6	3	this	this	DET
3j333199s86	6	4	residue	residue	NOUN
3j333199s86	6	5	,	,	PUNCT
3j333199s86	6	6	which	which	PRON
3j333199s86	6	7	has	have	VERB
3j333199s86	6	8	an	an	DET
3j333199s86	6	9	alkylguanidinium	alkylguanidinium	NOUN
3j333199s86	6	10	side	side	NOUN
3j333199s86	6	11	chain	chain	NOUN
3j333199s86	6	12	,	,	PUNCT
3j333199s86	6	13	to	to	ADP
3j333199s86	6	14	lysine	lysine	NOUN
3j333199s86	6	15	(	(	PUNCT
3j333199s86	6	16	primary	primary	ADJ
3j333199s86	6	17	amine	amine	NOUN
3j333199s86	6	18	)	)	PUNCT
3j333199s86	6	19	,	,	PUNCT
3j333199s86	6	20	glutamine	glutamine	NOUN
3j333199s86	6	21	(	(	PUNCT
3j333199s86	6	22	alkylamide	alkylamide	PROPN
3j333199s86	6	23	)	)	PUNCT
3j333199s86	6	24	,	,	PUNCT
3j333199s86	6	25	and	and	CCONJ
3j333199s86	6	26	alanine	alanine	NOUN
3j333199s86	6	27	(	(	PUNCT
3j333199s86	6	28	methyl	methyl	NOUN
3j333199s86	6	29	)	)	PUNCT
3j333199s86	6	30	,	,	PUNCT
3j333199s86	6	31	and	and	CCONJ
3j333199s86	6	32	studied	study	VERB
3j333199s86	6	33	both	both	CCONJ
3j333199s86	6	34	the	the	DET
3j333199s86	6	35	native	native	ADJ
3j333199s86	6	36	(	(	PUNCT
3j333199s86	6	37	wild	wild	ADJ
3j333199s86	6	38	type	type	NOUN
3j333199s86	6	39	,	,	PUNCT
3j333199s86	6	40	wt	wt	PROPN
3j333199s86	6	41	)	)	PUNCT
3j333199s86	6	42	and	and	CCONJ
3j333199s86	6	43	modified	modify	VERB
3j333199s86	6	44	forms	form	NOUN
3j333199s86	6	45	.	.	PUNCT
3j333199s86	7	1	we	we	PRON
3j333199s86	7	2	had	have	AUX
3j333199s86	7	3	found	find	VERB
3j333199s86	7	4	earlier	early	ADV
3j333199s86	7	5	that	that	SCONJ
3j333199s86	7	6	the	the	DET
3j333199s86	7	7	rate	rate	NOUN
3j333199s86	7	8	of	of	ADP
3j333199s86	7	9	catalysis	catalysis	NOUN
3j333199s86	7	10	and	and	CCONJ
3j333199s86	7	11	several	several	ADJ
3j333199s86	7	12	spectroscopic	spectroscopic	ADJ
3j333199s86	7	13	properties	property	NOUN
3j333199s86	7	14	of	of	ADP
3j333199s86	7	15	the	the	DET
3j333199s86	7	16	wt	wt	PROPN
3j333199s86	7	17	protein	protein	NOUN
3j333199s86	7	18	are	be	AUX
3j333199s86	7	19	ph	ph	NOUN
3j333199s86	7	20	-	-	PUNCT
3j333199s86	7	21	dependent	dependent	ADJ
3j333199s86	7	22	.	.	PUNCT
3j333199s86	8	1	we	we	PRON
3j333199s86	8	2	proposed	propose	VERB
3j333199s86	8	3	that	that	SCONJ
3j333199s86	8	4	this	this	PRON
3j333199s86	8	5	was	be	AUX
3j333199s86	8	6	either	either	ADV
3j333199s86	8	7	due	due	ADP
3j333199s86	8	8	to	to	ADP
3j333199s86	8	9	acid	acid	NOUN
3j333199s86	8	10	/	/	SYM
3j333199s86	8	11	base	base	NOUN
3j333199s86	8	12	chemistry	chemistry	NOUN
3j333199s86	8	13	at	at	ADP
3j333199s86	8	14	arg183	arg183	PROPN
3j333199s86	8	15	(	(	PUNCT
3j333199s86	8	16	analogous	analogous	ADJ
3j333199s86	8	17	to	to	ADP
3j333199s86	8	18	an	an	DET
3j333199s86	8	19	active	active	ADJ
3j333199s86	8	20	-	-	PUNCT
3j333199s86	8	21	site	site	NOUN
3j333199s86	8	22	his	his	PRON
3j333199s86	8	23	in	in	ADP
3j333199s86	8	24	peroxidase	peroxidase	NOUN
3j333199s86	8	25	)	)	PUNCT
3j333199s86	8	26	,	,	PUNCT
3j333199s86	8	27	or	or	CCONJ
3j333199s86	8	28	to	to	ADP
3j333199s86	8	29	the	the	DET
3j333199s86	8	30	mobility	mobility	NOUN
3j333199s86	8	31	of	of	ADP
3j333199s86	8	32	its	its	PRON
3j333199s86	8	33	side	side	NOUN
3j333199s86	8	34	chain	chain	NOUN
3j333199s86	8	35	due	due	ADP
3j333199s86	8	36	to	to	ADP
3j333199s86	8	37	ph	ph	ADJ
3j333199s86	8	38	-	-	PUNCT
3j333199s86	8	39	dependent	dependent	ADJ
3j333199s86	8	40	hydrogen	hydrogen	NOUN
3j333199s86	8	41	bond	bond	NOUN
3j333199s86	8	42	formation	formation	NOUN
3j333199s86	8	43	/	/	SYM
3j333199s86	8	44	cleavage	cleavage	NOUN
3j333199s86	8	45	.	.	PUNCT
3j333199s86	9	1	the	the	DET
3j333199s86	9	2	latter	latter	ADJ
3j333199s86	9	3	model	model	NOUN
3j333199s86	9	4	was	be	AUX
3j333199s86	9	5	most	most	ADV
3j333199s86	9	6	consistent	consistent	ADJ
3j333199s86	9	7	with	with	ADP
3j333199s86	9	8	the	the	DET
3j333199s86	9	9	available	available	ADJ
3j333199s86	9	10	data	datum	NOUN
3j333199s86	9	11	;	;	PUNCT
3j333199s86	9	12	particularly	particularly	ADV
3j333199s86	9	13	resonance	resonance	VERB
3j333199s86	9	14	raman	raman	NOUN
3j333199s86	9	15	(	(	PUNCT
3j333199s86	9	16	rr	rr	PROPN
3j333199s86	9	17	)	)	PUNCT
3j333199s86	9	18	data	datum	NOUN
3j333199s86	9	19	for	for	ADP
3j333199s86	9	20	the	the	DET
3j333199s86	9	21	ferrous	ferrous	ADJ
3j333199s86	9	22	carbonyl	carbonyl	NOUN
3j333199s86	9	23	form	form	NOUN
3j333199s86	9	24	of	of	ADP
3j333199s86	9	25	wt	wt	PROPN
3j333199s86	9	26	and	and	CCONJ
3j333199s86	9	27	mutant	mutant	ADJ
3j333199s86	9	28	proteins	protein	NOUN
3j333199s86	9	29	.	.	PUNCT
3j333199s86	10	1	by	by	ADP
3j333199s86	10	2	reacting	react	VERB
3j333199s86	10	3	the	the	DET
3j333199s86	10	4	protein	protein	NOUN
3j333199s86	10	5	with	with	ADP
3j333199s86	10	6	peracids	peracid	NOUN
3j333199s86	10	7	,	,	PUNCT
3j333199s86	10	8	we	we	PRON
3j333199s86	10	9	were	be	AUX
3j333199s86	10	10	able	able	ADJ
3j333199s86	10	11	to	to	PART
3j333199s86	10	12	characterize	characterize	VERB
3j333199s86	10	13	compound	compound	NOUN
3j333199s86	11	1	i	i	PRON
3j333199s86	11	2	(	(	PUNCT
3j333199s86	11	3	oxoferryl	oxoferryl	PROPN
3j333199s86	11	4	porphyrin	porphyrin	PROPN
3j333199s86	11	5	radical	radical	PROPN
3j333199s86	11	6	)	)	PUNCT
3j333199s86	11	7	which	which	PRON
3j333199s86	11	8	decays	decay	VERB
3j333199s86	11	9	to	to	ADP
3j333199s86	11	10	a	a	DET
3j333199s86	11	11	compound	compound	PROPN
3j333199s86	11	12	es	es	NOUN
3j333199s86	11	13	-	-	PUNCT
3j333199s86	11	14	like	like	ADJ
3j333199s86	11	15	species	specie	NOUN
3j333199s86	11	16	where	where	SCONJ
3j333199s86	11	17	the	the	DET
3j333199s86	11	18	porphyrin	porphyrin	NOUN
3j333199s86	11	19	radical	radical	ADJ
3j333199s86	11	20	migrates	migrate	VERB
3j333199s86	11	21	to	to	ADP
3j333199s86	11	22	a	a	DET
3j333199s86	11	23	nearby	nearby	ADJ
3j333199s86	11	24	tryptophan	tryptophan	NOUN
3j333199s86	11	25	residue	residue	NOUN
3j333199s86	11	26	.	.	PUNCT
3j333199s86	12	1	we	we	PRON
3j333199s86	12	2	mutated	mutate	VERB
3j333199s86	12	3	three	three	NUM
3j333199s86	12	4	conserved	conserve	VERB
3j333199s86	12	5	tryptophan	tryptophan	NOUN
3j333199s86	12	6	residues	residue	NOUN
3j333199s86	12	7	in	in	ADP
3j333199s86	12	8	dacld	dacld	NOUN
3j333199s86	12	9	's	's	PART
3j333199s86	12	10	active	active	ADJ
3j333199s86	12	11	site	site	NOUN
3j333199s86	12	12	in	in	ADP
3j333199s86	12	13	order	order	NOUN
3j333199s86	12	14	to	to	PART
3j333199s86	12	15	attempt	attempt	VERB
3j333199s86	12	16	to	to	PART
3j333199s86	12	17	block	block	VERB
3j333199s86	12	18	off	off	ADP
3j333199s86	12	19	radical	radical	ADJ
3j333199s86	12	20	migration	migration	NOUN
3j333199s86	12	21	and	and	CCONJ
3j333199s86	12	22	stabilize	stabilize	VERB
3j333199s86	12	23	compound	compound	PROPN
3j333199s86	12	24	i.	i.	PROPN
3j333199s86	12	25	the	the	DET
3j333199s86	12	26	ability	ability	NOUN
3j333199s86	12	27	of	of	ADP
3j333199s86	12	28	dacld	dacld	NOUN
3j333199s86	12	29	to	to	PART
3j333199s86	12	30	produce	produce	VERB
3j333199s86	12	31	such	such	DET
3j333199s86	12	32	a	a	DET
3j333199s86	12	33	great	great	ADJ
3j333199s86	12	34	amount	amount	NOUN
3j333199s86	12	35	of	of	ADP
3j333199s86	12	36	oxygen	oxygen	NOUN
3j333199s86	12	37	can	can	AUX
3j333199s86	12	38	be	be	AUX
3j333199s86	12	39	used	use	VERB
3j333199s86	12	40	for	for	ADP
3j333199s86	12	41	other	other	ADJ
3j333199s86	12	42	needs	need	NOUN
3j333199s86	12	43	,	,	PUNCT
3j333199s86	12	44	for	for	ADP
3j333199s86	12	45	example	example	NOUN
3j333199s86	12	46	in	in	ADP
3j333199s86	12	47	the	the	DET
3j333199s86	12	48	prevention	prevention	NOUN
3j333199s86	12	49	of	of	ADP
3j333199s86	12	50	tissue	tissue	NOUN
3j333199s86	12	51	necrosis	necrosis	NOUN
3j333199s86	12	52	.	.	PUNCT
3j333199s86	13	1	dacld	dacld	NOUN
3j333199s86	13	2	offers	offer	VERB
3j333199s86	13	3	the	the	DET
3j333199s86	13	4	possibility	possibility	NOUN
3j333199s86	13	5	of	of	ADP
3j333199s86	13	6	production	production	NOUN
3j333199s86	13	7	of	of	ADP
3j333199s86	13	8	o2	o2	PROPN
3j333199s86	13	9	in	in	ADP
3j333199s86	13	10	situ	situ	NOUN
3j333199s86	13	11	in	in	ADP
3j333199s86	13	12	a	a	DET
3j333199s86	13	13	regulated	regulated	ADJ
3j333199s86	13	14	fashion	fashion	NOUN
3j333199s86	13	15	and	and	CCONJ
3j333199s86	13	16	without	without	ADP
3j333199s86	13	17	generation	generation	NOUN
3j333199s86	13	18	of	of	ADP
3j333199s86	13	19	toxic	toxic	ADJ
3j333199s86	13	20	byproducts	byproduct	NOUN
3j333199s86	13	21	.	.	PUNCT