id	sid	tid	token	lemma	pos
3484zg66q03	1	1	the	the	DET
3484zg66q03	1	2	geminal	geminal	ADJ
3484zg66q03	1	3	organodimetallic	organodimetallic	ADJ
3484zg66q03	1	4	complexes	complex	NOUN
3484zg66q03	1	5	[	[	X
3484zg66q03	1	6	{	{	PUNCT
3484zg66q03	1	7	{	{	PUNCT
3484zg66q03	1	8	ph2p(me3si)n}2c}2m4	ph2p(me3si)n}2c}2m4	PROPN
3484zg66q03	1	9	]	]	PUNCT
3484zg66q03	1	10	,	,	PUNCT
3484zg66q03	1	11	l2m4	l2m4	PROPN
3484zg66q03	1	12	,	,	PUNCT
3484zg66q03	1	13	where	where	SCONJ
3484zg66q03	1	14	m4	m4	PRON
3484zg66q03	1	15	=	=	VERB
3484zg66q03	1	16	na4	na4	ADP
3484zg66q03	1	17	;	;	PUNCT
3484zg66q03	1	18	li2na2	li2na2	NOUN
3484zg66q03	1	19	;	;	PUNCT
3484zg66q03	1	20	lina3	lina3	PROPN
3484zg66q03	1	21	;	;	PUNCT
3484zg66q03	1	22	li2k2	li2k2	PROPN
3484zg66q03	1	23	;	;	PUNCT
3484zg66q03	1	24	na2k2	na2k2	PROPN
3484zg66q03	1	25	;	;	PUNCT
3484zg66q03	1	26	na3k	na3k	PROPN
3484zg66q03	1	27	,	,	PUNCT
3484zg66q03	1	28	have	have	AUX
3484zg66q03	1	29	been	be	AUX
3484zg66q03	1	30	prepared	prepare	VERB
3484zg66q03	1	31	through	through	ADP
3484zg66q03	1	32	a	a	DET
3484zg66q03	1	33	variety	variety	NOUN
3484zg66q03	1	34	of	of	ADP
3484zg66q03	1	35	methods	method	NOUN
3484zg66q03	1	36	including	include	VERB
3484zg66q03	1	37	:	:	PUNCT
3484zg66q03	1	38	direct	direct	ADJ
3484zg66q03	1	39	or	or	CCONJ
3484zg66q03	1	40	sequential	sequential	ADJ
3484zg66q03	1	41	deprotonation	deprotonation	NOUN
3484zg66q03	1	42	of	of	ADP
3484zg66q03	1	43	the	the	DET
3484zg66q03	1	44	neutral	neutral	ADJ
3484zg66q03	1	45	ligand	ligand	NOUN
3484zg66q03	1	46	with	with	ADP
3484zg66q03	1	47	strong	strong	ADJ
3484zg66q03	1	48	bases	basis	NOUN
3484zg66q03	1	49	(	(	PUNCT
3484zg66q03	1	50	t	t	PROPN
3484zg66q03	1	51	-	-	PUNCT
3484zg66q03	1	52	buli	buli	PROPN
3484zg66q03	1	53	,	,	PUNCT
3484zg66q03	1	54	n	n	NOUN
3484zg66q03	1	55	-	-	PUNCT
3484zg66q03	1	56	buna	buna	NOUN
3484zg66q03	1	57	,	,	PUNCT
3484zg66q03	1	58	(	(	PUNCT
3484zg66q03	1	59	me3si)2nna	me3si)2nna	SPACE
3484zg66q03	1	60	,	,	PUNCT
3484zg66q03	1	61	phch2k	phch2k	PROPN
3484zg66q03	1	62	or	or	CCONJ
3484zg66q03	1	63	(	(	PUNCT
3484zg66q03	1	64	me3si)2nk	me3si)2nk	SPACE
3484zg66q03	1	65	)	)	PUNCT
3484zg66q03	1	66	,	,	PUNCT
3484zg66q03	1	67	transmetallation	transmetallation	NOUN
3484zg66q03	1	68	of	of	ADP
3484zg66q03	1	69	the	the	DET
3484zg66q03	1	70	homometallic	homometallic	ADJ
3484zg66q03	1	71	derivatives	derivative	NOUN
3484zg66q03	1	72	(	(	PUNCT
3484zg66q03	1	73	m4	m4	PRON
3484zg66q03	1	74	=	=	VERB
3484zg66q03	1	75	li4	li4	VERB
3484zg66q03	1	76	or	or	CCONJ
3484zg66q03	1	77	na4	na4	NOUN
3484zg66q03	1	78	)	)	PUNCT
3484zg66q03	1	79	with	with	ADP
3484zg66q03	1	80	t	t	PROPN
3484zg66q03	1	81	-	-	PUNCT
3484zg66q03	1	82	buona	buona	PROPN
3484zg66q03	1	83	or	or	CCONJ
3484zg66q03	1	84	t	t	PROPN
3484zg66q03	1	85	-	-	PUNCT
3484zg66q03	1	86	buok	buok	PROPN
3484zg66q03	1	87	,	,	PUNCT
3484zg66q03	1	88	and	and	CCONJ
3484zg66q03	1	89	by	by	ADP
3484zg66q03	1	90	cation	cation	NOUN
3484zg66q03	1	91	exchange	exchange	NOUN
3484zg66q03	1	92	upon	upon	SCONJ
3484zg66q03	1	93	mixing	mix	VERB
3484zg66q03	1	94	the	the	DET
3484zg66q03	1	95	homometallic	homometallic	ADJ
3484zg66q03	1	96	complexes	complex	NOUN
3484zg66q03	1	97	in	in	ADP
3484zg66q03	1	98	arene	arene	NOUN
3484zg66q03	1	99	solution	solution	NOUN
3484zg66q03	1	100	.	.	PUNCT
3484zg66q03	2	1	the	the	DET
3484zg66q03	2	2	dianionic	dianionic	ADJ
3484zg66q03	2	3	complexes	complex	NOUN
3484zg66q03	2	4	have	have	AUX
3484zg66q03	2	5	been	be	AUX
3484zg66q03	2	6	characterized	characterize	VERB
3484zg66q03	2	7	by	by	ADP
3484zg66q03	2	8	single	single	ADJ
3484zg66q03	2	9	-	-	PUNCT
3484zg66q03	2	10	crystal	crystal	NOUN
3484zg66q03	2	11	x	x	NOUN
3484zg66q03	2	12	-	-	NOUN
3484zg66q03	2	13	ray	ray	NOUN
3484zg66q03	2	14	diffraction	diffraction	NOUN
3484zg66q03	2	15	and	and	CCONJ
3484zg66q03	2	16	found	find	VERB
3484zg66q03	2	17	to	to	PART
3484zg66q03	2	18	form	form	VERB
3484zg66q03	2	19	a	a	DET
3484zg66q03	2	20	homologous	homologous	ADJ
3484zg66q03	2	21	series	series	NOUN
3484zg66q03	2	22	of	of	ADP
3484zg66q03	2	23	dimeric	dimeric	ADJ
3484zg66q03	2	24	structures	structure	NOUN
3484zg66q03	2	25	in	in	ADP
3484zg66q03	2	26	the	the	DET
3484zg66q03	2	27	solid	solid	ADJ
3484zg66q03	2	28	-	-	PUNCT
3484zg66q03	2	29	state	state	NOUN
3484zg66q03	2	30	,	,	PUNCT
3484zg66q03	2	31	in	in	ADP
3484zg66q03	2	32	accord	accord	NOUN
3484zg66q03	2	33	with	with	ADP
3484zg66q03	2	34	the	the	DET
3484zg66q03	2	35	previously	previously	ADV
3484zg66q03	2	36	reported	report	VERB
3484zg66q03	2	37	structure	structure	NOUN
3484zg66q03	2	38	of	of	ADP
3484zg66q03	2	39	l2li4	l2li4	PROPN
3484zg66q03	2	40	.	.	PUNCT
3484zg66q03	3	1	each	each	DET
3484zg66q03	3	2	complex	complex	NOUN
3484zg66q03	3	3	is	be	AUX
3484zg66q03	3	4	composed	compose	VERB
3484zg66q03	3	5	of	of	ADP
3484zg66q03	3	6	an	an	DET
3484zg66q03	3	7	m4	m4	PROPN
3484zg66q03	3	8	plane	plane	NOUN
3484zg66q03	3	9	of	of	ADP
3484zg66q03	3	10	metals	metal	NOUN
3484zg66q03	3	11	,	,	PUNCT
3484zg66q03	3	12	with	with	ADP
3484zg66q03	3	13	the	the	DET
3484zg66q03	3	14	ligands	ligand	NOUN
3484zg66q03	3	15	adopting	adopt	VERB
3484zg66q03	3	16	capping	cap	VERB
3484zg66q03	3	17	positions	position	NOUN
3484zg66q03	3	18	to	to	PART
3484zg66q03	3	19	form	form	VERB
3484zg66q03	3	20	distorted	distorted	ADJ
3484zg66q03	3	21	m4c2	m4c2	DET
3484zg66q03	3	22	octahedral	octahedral	ADJ
3484zg66q03	3	23	cores	core	NOUN
3484zg66q03	3	24	.	.	PUNCT
3484zg66q03	4	1	the	the	DET
3484zg66q03	4	2	metals	metal	NOUN
3484zg66q03	4	3	in	in	ADP
3484zg66q03	4	4	homometallic	homometallic	NOUN
3484zg66q03	4	5	complexes	complex	NOUN
3484zg66q03	4	6	l2li4	l2li4	ADJ
3484zg66q03	4	7	and	and	CCONJ
3484zg66q03	4	8	l2na4	l2na4	ADV
3484zg66q03	4	9	define	define	VERB
3484zg66q03	4	10	an	an	DET
3484zg66q03	4	11	approximate	approximate	ADJ
3484zg66q03	4	12	square	square	NOUN
3484zg66q03	4	13	,	,	PUNCT
3484zg66q03	4	14	whereas	whereas	SCONJ
3484zg66q03	4	15	the	the	DET
3484zg66q03	4	16	heterometallic	heterometallic	ADJ
3484zg66q03	4	17	derivatives	derivative	NOUN
3484zg66q03	4	18	have	have	VERB
3484zg66q03	4	19	distinctly	distinctly	ADV
3484zg66q03	4	20	rhombic	rhombic	ADJ
3484zg66q03	4	21	arrangements	arrangement	NOUN
3484zg66q03	4	22	.	.	PUNCT
3484zg66q03	5	1	the	the	DET
3484zg66q03	5	2	lighter	light	ADJ
3484zg66q03	5	3	metals	metal	NOUN
3484zg66q03	5	4	in	in	ADP
3484zg66q03	5	5	these	these	DET
3484zg66q03	5	6	heterometallic	heterometallic	ADJ
3484zg66q03	5	7	compounds	compound	NOUN
3484zg66q03	5	8	interact	interact	VERB
3484zg66q03	5	9	strongly	strongly	ADV
3484zg66q03	5	10	with	with	ADP
3484zg66q03	5	11	the	the	DET
3484zg66q03	5	12	carbanions	carbanion	NOUN
3484zg66q03	5	13	and	and	CCONJ
3484zg66q03	5	14	the	the	DET
3484zg66q03	5	15	heavier	heavy	ADJ
3484zg66q03	5	16	metals	metal	NOUN
3484zg66q03	5	17	are	be	AUX
3484zg66q03	5	18	pushed	push	VERB
3484zg66q03	5	19	towards	towards	ADP
3484zg66q03	5	20	the	the	DET
3484zg66q03	5	21	periphery	periphery	NOUN
3484zg66q03	5	22	of	of	ADP
3484zg66q03	5	23	the	the	DET
3484zg66q03	5	24	structures	structure	NOUN
3484zg66q03	5	25	.	.	PUNCT
3484zg66q03	6	1	1h	1h	NOUN
3484zg66q03	6	2	,	,	PUNCT
3484zg66q03	6	3	13c	13c	NUM
3484zg66q03	6	4	,	,	PUNCT
3484zg66q03	6	5	7li	7li	PROPN
3484zg66q03	6	6	,	,	PUNCT
3484zg66q03	6	7	31p	31p	NOUN
3484zg66q03	6	8	and	and	CCONJ
3484zg66q03	6	9	29si	29si	ADJ
3484zg66q03	6	10	multinuclear	multinuclear	PROPN
3484zg66q03	6	11	nmr	nmr	PROPN
3484zg66q03	6	12	spectroscopic	spectroscopic	ADJ
3484zg66q03	6	13	studies	study	NOUN
3484zg66q03	6	14	,	,	PUNCT
3484zg66q03	6	15	cryoscopic	cryoscopic	NOUN
3484zg66q03	6	16	measurements	measurement	NOUN
3484zg66q03	6	17	,	,	PUNCT
3484zg66q03	6	18	and	and	CCONJ
3484zg66q03	6	19	electrospray	electrospray	ADP
3484zg66q03	6	20	ionization	ionization	NOUN
3484zg66q03	6	21	-	-	PUNCT
3484zg66q03	6	22	mass	mass	NOUN
3484zg66q03	6	23	spectroscopic	spectroscopic	ADJ
3484zg66q03	6	24	studies	study	NOUN
3484zg66q03	6	25	are	be	AUX
3484zg66q03	6	26	consistent	consistent	ADJ
3484zg66q03	6	27	with	with	ADP
3484zg66q03	6	28	the	the	DET
3484zg66q03	6	29	dimers	dimer	NOUN
3484zg66q03	6	30	being	be	AUX
3484zg66q03	6	31	retained	retain	VERB
3484zg66q03	6	32	in	in	ADP
3484zg66q03	6	33	solution	solution	NOUN
3484zg66q03	6	34	.	.	PUNCT
3484zg66q03	7	1	dynamic	dynamic	ADJ
3484zg66q03	7	2	solution	solution	NOUN
3484zg66q03	7	3	behavior	behavior	NOUN
3484zg66q03	7	4	was	be	AUX
3484zg66q03	7	5	discovered	discover	VERB
3484zg66q03	7	6	for	for	ADP
3484zg66q03	7	7	l2li2na2	l2li2na2	PROPN
3484zg66q03	7	8	,	,	PUNCT
3484zg66q03	7	9	where	where	SCONJ
3484zg66q03	7	10	all	all	DET
3484zg66q03	7	11	five	five	NUM
3484zg66q03	7	12	possible	possible	ADJ
3484zg66q03	7	13	tetrametallic	tetrametallic	ADJ
3484zg66q03	7	14	derivatives	derivative	NOUN
3484zg66q03	7	15	l2li4	l2li4	NOUN
3484zg66q03	7	16	,	,	PUNCT
3484zg66q03	7	17	l2li3na	l2li3na	PROPN
3484zg66q03	7	18	,	,	PUNCT
3484zg66q03	7	19	l2li2na2	l2li2na2	PROPN
3484zg66q03	7	20	,	,	PUNCT
3484zg66q03	7	21	l2lina3	l2lina3	NOUN
3484zg66q03	7	22	and	and	CCONJ
3484zg66q03	7	23	l2na4	l2na4	NOUN
3484zg66q03	7	24	coexist	coexist	VERB
3484zg66q03	7	25	.	.	PUNCT
3484zg66q03	8	1	density	density	NOUN
3484zg66q03	8	2	functional	functional	ADJ
3484zg66q03	8	3	theory	theory	NOUN
3484zg66q03	8	4	(	(	PUNCT
3484zg66q03	8	5	dft	dft	NOUN
3484zg66q03	8	6	)	)	PUNCT
3484zg66q03	8	7	and	and	CCONJ
3484zg66q03	8	8	natural	natural	ADJ
3484zg66q03	8	9	bond	bond	NOUN
3484zg66q03	8	10	order	order	NOUN
3484zg66q03	8	11	(	(	PUNCT
3484zg66q03	8	12	nbo	nbo	PROPN
3484zg66q03	8	13	)	)	PUNCT
3484zg66q03	8	14	calculations	calculation	NOUN
3484zg66q03	8	15	in	in	ADP
3484zg66q03	8	16	association	association	NOUN
3484zg66q03	8	17	with	with	ADP
3484zg66q03	8	18	natural	natural	ADJ
3484zg66q03	8	19	population	population	NOUN
3484zg66q03	8	20	analyses	analysis	NOUN
3484zg66q03	8	21	(	(	PUNCT
3484zg66q03	8	22	npa	npa	PROPN
3484zg66q03	8	23	)	)	PUNCT
3484zg66q03	8	24	reveal	reveal	VERB
3484zg66q03	8	25	significant	significant	ADJ
3484zg66q03	8	26	differences	difference	NOUN
3484zg66q03	8	27	in	in	ADP
3484zg66q03	8	28	the	the	DET
3484zg66q03	8	29	electronic	electronic	ADJ
3484zg66q03	8	30	structures	structure	NOUN
3484zg66q03	8	31	of	of	ADP
3484zg66q03	8	32	the	the	DET
3484zg66q03	8	33	variously	variously	ADV
3484zg66q03	8	34	metallated	metallate	VERB
3484zg66q03	8	35	dianions	dianion	NOUN
3484zg66q03	8	36	.	.	PUNCT
3484zg66q03	9	1	the	the	DET
3484zg66q03	9	2	smaller	small	ADJ
3484zg66q03	9	3	cations	cation	NOUN
3484zg66q03	9	4	are	be	AUX
3484zg66q03	9	5	more	more	ADV
3484zg66q03	9	6	effective	effective	ADJ
3484zg66q03	9	7	in	in	ADP
3484zg66q03	9	8	localizing	localize	VERB
3484zg66q03	9	9	the	the	DET
3484zg66q03	9	10	double	double	ADJ
3484zg66q03	9	11	negative	negative	ADJ
3484zg66q03	9	12	charge	charge	NOUN
3484zg66q03	9	13	on	on	ADP
3484zg66q03	9	14	the	the	DET
3484zg66q03	9	15	carbanion	carbanion	NOUN
3484zg66q03	9	16	(	(	PUNCT
3484zg66q03	9	17	in	in	ADP
3484zg66q03	9	18	the	the	DET
3484zg66q03	9	19	form	form	NOUN
3484zg66q03	9	20	of	of	ADP
3484zg66q03	9	21	two	two	NUM
3484zg66q03	9	22	lone	lone	ADJ
3484zg66q03	9	23	pairs	pair	NOUN
3484zg66q03	9	24	)	)	PUNCT
3484zg66q03	9	25	,	,	PUNCT
3484zg66q03	9	26	leading	lead	VERB
3484zg66q03	9	27	to	to	ADP
3484zg66q03	9	28	differences	difference	NOUN
3484zg66q03	9	29	in	in	ADP
3484zg66q03	9	30	the	the	DET
3484zg66q03	9	31	distribution	distribution	NOUN
3484zg66q03	9	32	of	of	ADP
3484zg66q03	9	33	the	the	DET
3484zg66q03	9	34	electron	electron	NOUN
3484zg66q03	9	35	density	density	NOUN
3484zg66q03	9	36	within	within	ADP
3484zg66q03	9	37	the	the	DET
3484zg66q03	9	38	ligand	ligand	NOUN
3484zg66q03	9	39	backbones	backbone	NOUN
3484zg66q03	9	40	.	.	PUNCT
3484zg66q03	10	1	in	in	ADP
3484zg66q03	10	2	turn	turn	NOUN
3484zg66q03	10	3	,	,	PUNCT
3484zg66q03	10	4	a	a	DET
3484zg66q03	10	5	complex	complex	ADJ
3484zg66q03	10	6	interplay	interplay	NOUN
3484zg66q03	10	7	of	of	ADP
3484zg66q03	10	8	hyperconjugation	hyperconjugation	NOUN
3484zg66q03	10	9	,	,	PUNCT
3484zg66q03	10	10	electrostatics	electrostatic	NOUN
3484zg66q03	10	11	and	and	CCONJ
3484zg66q03	10	12	metal	metal	NOUN
3484zg66q03	10	13	-	-	PUNCT
3484zg66q03	10	14	ligand	ligand	NOUN
3484zg66q03	10	15	interactions	interaction	NOUN
3484zg66q03	10	16	is	be	AUX
3484zg66q03	10	17	found	find	VERB
3484zg66q03	10	18	to	to	PART
3484zg66q03	10	19	control	control	VERB
3484zg66q03	10	20	the	the	DET
3484zg66q03	10	21	resulting	result	VERB
3484zg66q03	10	22	electronic	electronic	ADJ
3484zg66q03	10	23	structures	structure	NOUN
3484zg66q03	10	24	of	of	ADP
3484zg66q03	10	25	the	the	DET
3484zg66q03	10	26	geminal	geminal	ADJ
3484zg66q03	10	27	organodimetallic	organodimetallic	ADJ
3484zg66q03	10	28	complexes	complex	NOUN
3484zg66q03	10	29	.	.	PUNCT
3484zg66q03	11	1	the	the	DET
3484zg66q03	11	2	lithium	lithium	NOUN
3484zg66q03	11	3	-	-	PUNCT
3484zg66q03	11	4	based	base	VERB
3484zg66q03	11	5	geminal	geminal	ADJ
3484zg66q03	11	6	organodimetallic	organodimetallic	NOUN
3484zg66q03	11	7	[	[	X
3484zg66q03	11	8	{	{	PUNCT
3484zg66q03	11	9	{	{	PUNCT
3484zg66q03	11	10	ph2p(me3si)n}2cli2}2	ph2p(me3si)n}2cli2}2	NOUN
3484zg66q03	11	11	]	]	PUNCT
3484zg66q03	11	12	,	,	PUNCT
3484zg66q03	11	13	l2li4	l2li4	PROPN
3484zg66q03	11	14	,	,	PUNCT
3484zg66q03	11	15	undergoes	undergo	VERB
3484zg66q03	11	16	major	major	ADJ
3484zg66q03	11	17	structural	structural	ADJ
3484zg66q03	11	18	changes	change	NOUN
3484zg66q03	11	19	in	in	ADP
3484zg66q03	11	20	polar	polar	ADJ
3484zg66q03	11	21	media	medium	NOUN
3484zg66q03	11	22	.	.	PUNCT
3484zg66q03	12	1	upon	upon	SCONJ
3484zg66q03	12	2	dissolution	dissolution	NOUN
3484zg66q03	12	3	of	of	ADP
3484zg66q03	12	4	l2li4	l2li4	PROPN
3484zg66q03	12	5	in	in	ADP
3484zg66q03	12	6	thf	thf	PROPN
3484zg66q03	12	7	,	,	PUNCT
3484zg66q03	12	8	a	a	DET
3484zg66q03	12	9	new	new	ADJ
3484zg66q03	12	10	charge	charge	NOUN
3484zg66q03	12	11	-	-	PUNCT
3484zg66q03	12	12	separated	separate	VERB
3484zg66q03	12	13	species	specie	NOUN
3484zg66q03	12	14	[	[	X
3484zg66q03	12	15	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	NOUN
3484zg66q03	12	16	is	be	AUX
3484zg66q03	12	17	immediately	immediately	ADV
3484zg66q03	12	18	formed	form	VERB
3484zg66q03	12	19	.	.	PUNCT
3484zg66q03	13	1	in	in	ADP
3484zg66q03	13	2	turn	turn	NOUN
3484zg66q03	13	3	,	,	PUNCT
3484zg66q03	13	4	the	the	DET
3484zg66q03	13	5	ion	ion	NOUN
3484zg66q03	13	6	pair	pair	NOUN
3484zg66q03	13	7	slowly	slowly	ADV
3484zg66q03	13	8	(	(	PUNCT
3484zg66q03	13	9	hours	hour	NOUN
3484zg66q03	13	10	)	)	PUNCT
3484zg66q03	13	11	undergoes	undergo	VERB
3484zg66q03	13	12	dismutation	dismutation	NOUN
3484zg66q03	13	13	to	to	PART
3484zg66q03	13	14	form	form	VERB
3484zg66q03	13	15	a	a	DET
3484zg66q03	13	16	neutral	neutral	ADJ
3484zg66q03	13	17	monomer	monomer	NOUN
3484zg66q03	13	18	lli2(thf)n	lli2(thf)n	PROPN
3484zg66q03	13	19	.	.	PUNCT
3484zg66q03	14	1	the	the	DET
3484zg66q03	14	2	identities	identity	NOUN
3484zg66q03	14	3	of	of	ADP
3484zg66q03	14	4	these	these	DET
3484zg66q03	14	5	two	two	NUM
3484zg66q03	14	6	solution	solution	NOUN
3484zg66q03	14	7	complexes	complex	NOUN
3484zg66q03	14	8	were	be	AUX
3484zg66q03	14	9	confirmed	confirm	VERB
3484zg66q03	14	10	through	through	ADP
3484zg66q03	14	11	a	a	DET
3484zg66q03	14	12	series	series	NOUN
3484zg66q03	14	13	of	of	ADP
3484zg66q03	14	14	experiments	experiment	NOUN
3484zg66q03	14	15	including	include	VERB
3484zg66q03	14	16	variable	variable	ADJ
3484zg66q03	14	17	concentration	concentration	NOUN
3484zg66q03	14	18	keq	keq	PROPN
3484zg66q03	14	19	measurements	measurement	NOUN
3484zg66q03	14	20	,	,	PUNCT
3484zg66q03	14	21	7li	7li	PROPN
3484zg66q03	14	22	nmr	nmr	NOUN
3484zg66q03	14	23	,	,	PUNCT
3484zg66q03	14	24	and	and	CCONJ
3484zg66q03	14	25	diffusion	diffusion	NOUN
3484zg66q03	14	26	-	-	PUNCT
3484zg66q03	14	27	ordered	order	VERB
3484zg66q03	14	28	nmr	nmr	NOUN
3484zg66q03	14	29	.	.	PUNCT
3484zg66q03	15	1	the	the	DET
3484zg66q03	15	2	ion	ion	NOUN
3484zg66q03	15	3	pair	pair	NOUN
3484zg66q03	15	4	[	[	X
3484zg66q03	15	5	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	PROPN
3484zg66q03	15	6	was	be	AUX
3484zg66q03	15	7	also	also	ADV
3484zg66q03	15	8	crystallized	crystallize	VERB
3484zg66q03	15	9	from	from	ADP
3484zg66q03	15	10	thf	thf	NOUN
3484zg66q03	15	11	solution	solution	NOUN
3484zg66q03	15	12	,	,	PUNCT
3484zg66q03	15	13	and	and	CCONJ
3484zg66q03	15	14	the	the	DET
3484zg66q03	15	15	structure	structure	NOUN
3484zg66q03	15	16	was	be	AUX
3484zg66q03	15	17	elucidated	elucidate	VERB
3484zg66q03	15	18	in	in	ADP
3484zg66q03	15	19	the	the	DET
3484zg66q03	15	20	solid	solid	ADJ
3484zg66q03	15	21	state	state	NOUN
3484zg66q03	15	22	.	.	PUNCT
3484zg66q03	16	1	attempts	attempt	NOUN
3484zg66q03	16	2	to	to	PART
3484zg66q03	16	3	further	far	ADV
3484zg66q03	16	4	charge	charge	VERB
3484zg66q03	16	5	separate	separate	VERB
3484zg66q03	16	6	the	the	DET
3484zg66q03	16	7	lithium	lithium	NOUN
3484zg66q03	16	8	cations	cation	NOUN
3484zg66q03	16	9	from	from	ADP
3484zg66q03	16	10	the	the	DET
3484zg66q03	16	11	ligand	ligand	NOUN
3484zg66q03	16	12	backbone	backbone	NOUN
3484zg66q03	16	13	with	with	ADP
3484zg66q03	16	14	additives	additive	NOUN
3484zg66q03	16	15	such	such	ADJ
3484zg66q03	16	16	as	as	ADP
3484zg66q03	16	17	12	12	NUM
3484zg66q03	16	18	-	-	PUNCT
3484zg66q03	16	19	crown-4	crown-4	PROPN
3484zg66q03	16	20	or	or	CCONJ
3484zg66q03	16	21	hmpa	hmpa	PROPN
3484zg66q03	16	22	generally	generally	ADV
3484zg66q03	16	23	resulted	result	VERB
3484zg66q03	16	24	in	in	ADP
3484zg66q03	16	25	decomposition	decomposition	NOUN
3484zg66q03	16	26	of	of	ADP
3484zg66q03	16	27	the	the	DET
3484zg66q03	16	28	dianion	dianion	NOUN
3484zg66q03	16	29	system	system	NOUN
3484zg66q03	16	30	.	.	PUNCT
3484zg66q03	17	1	density	density	NOUN
3484zg66q03	17	2	functional	functional	ADJ
3484zg66q03	17	3	theory	theory	NOUN
3484zg66q03	17	4	calculations	calculation	NOUN
3484zg66q03	17	5	of	of	ADP
3484zg66q03	17	6	l2li4	l2li4	PROPN
3484zg66q03	17	7	,	,	PUNCT
3484zg66q03	17	8	[	[	X
3484zg66q03	17	9	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	NOUN
3484zg66q03	17	10	,	,	PUNCT
3484zg66q03	17	11	and	and	CCONJ
3484zg66q03	17	12	lli2(thf)n	lli2(thf)n	PROPN
3484zg66q03	17	13	were	be	AUX
3484zg66q03	17	14	also	also	ADV
3484zg66q03	17	15	performed	perform	VERB
3484zg66q03	17	16	.	.	PUNCT
3484zg66q03	18	1	two	two	NUM
3484zg66q03	18	2	possible	possible	ADJ
3484zg66q03	18	3	structures	structure	NOUN
3484zg66q03	18	4	for	for	ADP
3484zg66q03	18	5	the	the	DET
3484zg66q03	18	6	monomer	monomer	NOUN
3484zg66q03	18	7	,	,	PUNCT
3484zg66q03	18	8	lli2(thf)3	lli2(thf)3	PROPN
3484zg66q03	18	9	and	and	CCONJ
3484zg66q03	18	10	lli2(thf)4	lli2(thf)4	PROPN
3484zg66q03	18	11	,	,	PUNCT
3484zg66q03	18	12	were	be	AUX
3484zg66q03	18	13	found	find	VERB
3484zg66q03	18	14	and	and	CCONJ
3484zg66q03	18	15	are	be	AUX
3484zg66q03	18	16	different	different	ADJ
3484zg66q03	18	17	in	in	ADP
3484zg66q03	18	18	energy	energy	NOUN
3484zg66q03	18	19	by	by	ADP
3484zg66q03	18	20	only	only	ADV
3484zg66q03	18	21	1.41	1.41	NUM
3484zg66q03	18	22	kcal	kcal	PROPN
3484zg66q03	18	23	/	/	SYM
3484zg66q03	18	24	mol	mol	PROPN
3484zg66q03	18	25	.	.	PROPN
3484zg66q03	18	26	1h	1h	PROPN
3484zg66q03	18	27	nmr	nmr	PROPN
3484zg66q03	18	28	rate	rate	NOUN
3484zg66q03	18	29	studies	study	NOUN
3484zg66q03	18	30	of	of	ADP
3484zg66q03	18	31	the	the	DET
3484zg66q03	18	32	[	[	X
3484zg66q03	18	33	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	NOUN
3484zg66q03	18	34	to	to	PART
3484zg66q03	18	35	lli2(thf)n	lli2(thf)n	PROPN
3484zg66q03	18	36	equilibration	equilibration	NOUN
3484zg66q03	18	37	process	process	NOUN
3484zg66q03	18	38	were	be	AUX
3484zg66q03	18	39	performed	perform	VERB
3484zg66q03	18	40	(	(	PUNCT
3484zg66q03	18	41	dhì¢	dhì¢	NOUN
3484zg66q03	18	42	ââåá	ââåá	NOUN
3484zg66q03	18	43	=	=	VERB
3484zg66q03	18	44	12.6	12.6	NUM
3484zg66q03	18	45	ìâå±	ìâå±	NUM
3484zg66q03	18	46	0.5	0.5	NUM
3484zg66q03	18	47	kcal	kcal	PROPN
3484zg66q03	18	48	/	/	SYM
3484zg66q03	18	49	mol	mol	PROPN
3484zg66q03	18	50	,	,	PUNCT
3484zg66q03	18	51	dsì¢	dsì¢	PROPN
3484zg66q03	18	52	ââåá	ââåá	NOUN
3484zg66q03	18	53	=	=	PUNCT
3484zg66q03	18	54	-33.6	-33.6	X
3484zg66q03	18	55	ìâå±	ìâå±	NOUN
3484zg66q03	18	56	1.8	1.8	NUM
3484zg66q03	18	57	kcal	kcal	ADJ
3484zg66q03	18	58	/	/	SYM
3484zg66q03	18	59	molì¢è	molì¢è	NOUN
3484zg66q03	18	60	  	  	SPACE
3484zg66q03	18	61	ã¢k	ã¢k	SPACE
3484zg66q03	18	62	)	)	PUNCT
3484zg66q03	18	63	.	.	PUNCT
3484zg66q03	19	1	we	we	PRON
3484zg66q03	19	2	furthermore	furthermore	ADV
3484zg66q03	19	3	explored	explore	VERB
3484zg66q03	19	4	the	the	DET
3484zg66q03	19	5	reactivities	reactivity	NOUN
3484zg66q03	19	6	of	of	ADP
3484zg66q03	19	7	[	[	X
3484zg66q03	19	8	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	PROPN
3484zg66q03	19	9	and	and	CCONJ
3484zg66q03	19	10	lli2(thf)n	lli2(thf)n	PROPN
3484zg66q03	19	11	.	.	PUNCT
3484zg66q03	20	1	addition	addition	NOUN
3484zg66q03	20	2	of	of	ADP
3484zg66q03	20	3	the	the	DET
3484zg66q03	20	4	protic	protic	ADJ
3484zg66q03	20	5	amine	amine	NOUN
3484zg66q03	20	6	(	(	PUNCT
3484zg66q03	20	7	me3si)2nh	me3si)2nh	NUM
3484zg66q03	20	8	to	to	PART
3484zg66q03	20	9	an	an	DET
3484zg66q03	20	10	equilibrium	equilibrium	NOUN
3484zg66q03	20	11	mixture	mixture	NOUN
3484zg66q03	20	12	of	of	ADP
3484zg66q03	20	13	the	the	DET
3484zg66q03	20	14	two	two	NUM
3484zg66q03	20	15	complexes	complex	NOUN
3484zg66q03	20	16	at	at	ADP
3484zg66q03	20	17	room	room	NOUN
3484zg66q03	20	18	temperature	temperature	NOUN
3484zg66q03	20	19	showed	show	VERB
3484zg66q03	20	20	immediate	immediate	ADJ
3484zg66q03	20	21	consumption	consumption	NOUN
3484zg66q03	20	22	of	of	ADP
3484zg66q03	20	23	lli2(thf)4	lli2(thf)4	NOUN
3484zg66q03	20	24	(	(	PUNCT
3484zg66q03	20	25	forming	form	VERB
3484zg66q03	20	26	lin(sime3)2(thf)n	lin(sime3)2(thf)n	PROPN
3484zg66q03	20	27	and	and	CCONJ
3484zg66q03	20	28	l(h)li(thf)n	l(h)li(thf)n	PROPN
3484zg66q03	20	29	)	)	PUNCT
3484zg66q03	20	30	followed	follow	VERB
3484zg66q03	20	31	by	by	ADP
3484zg66q03	20	32	the	the	DET
3484zg66q03	20	33	slow	slow	ADJ
3484zg66q03	20	34	disappearance	disappearance	NOUN
3484zg66q03	20	35	of	of	ADP
3484zg66q03	20	36	[	[	X
3484zg66q03	20	37	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	PROPN
3484zg66q03	20	38	.	.	PUNCT
3484zg66q03	20	39	room	room	NOUN
3484zg66q03	20	40	-	-	PUNCT
3484zg66q03	20	41	temperature	temperature	NOUN
3484zg66q03	20	42	rate	rate	NOUN
3484zg66q03	20	43	studies	study	NOUN
3484zg66q03	20	44	using	use	VERB
3484zg66q03	20	45	1h	1h	NOUN
3484zg66q03	20	46	nmr	nmr	PROPN
3484zg66q03	20	47	spectroscopy	spectroscopy	NOUN
3484zg66q03	20	48	reveal	reveal	VERB
3484zg66q03	20	49	first	first	ADJ
3484zg66q03	20	50	-	-	PUNCT
3484zg66q03	20	51	order	order	NOUN
3484zg66q03	20	52	decay	decay	NOUN
3484zg66q03	20	53	of	of	ADP
3484zg66q03	20	54	[	[	X
3484zg66q03	20	55	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	NOUN
3484zg66q03	20	56	with	with	ADP
3484zg66q03	20	57	rate	rate	NOUN
3484zg66q03	20	58	constants	constant	NOUN
3484zg66q03	20	59	independent	independent	ADJ
3484zg66q03	20	60	of	of	ADP
3484zg66q03	20	61	the	the	DET
3484zg66q03	20	62	concentration	concentration	NOUN
3484zg66q03	20	63	of	of	ADP
3484zg66q03	20	64	(	(	PUNCT
3484zg66q03	20	65	me3si)2nh	me3si)2nh	PROPN
3484zg66q03	20	66	.	.	PUNCT
3484zg66q03	21	1	this	this	DET
3484zg66q03	21	2	decay	decay	NOUN
3484zg66q03	21	3	of	of	ADP
3484zg66q03	21	4	[	[	X
3484zg66q03	21	5	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	PROPN
3484zg66q03	21	6	primarily	primarily	ADV
3484zg66q03	21	7	occurs	occur	VERB
3484zg66q03	21	8	through	through	ADP
3484zg66q03	21	9	dismutation	dismutation	NOUN
3484zg66q03	21	10	to	to	ADP
3484zg66q03	21	11	lli2(thf)n	lli2(thf)n	PROPN
3484zg66q03	21	12	(	(	PUNCT
3484zg66q03	21	13	which	which	PRON
3484zg66q03	21	14	in	in	ADP
3484zg66q03	21	15	turn	turn	NOUN
3484zg66q03	21	16	reacts	react	VERB
3484zg66q03	21	17	with	with	ADP
3484zg66q03	21	18	(	(	PUNCT
3484zg66q03	21	19	me3si)2nh	me3si)2nh	NUM
3484zg66q03	21	20	)	)	PUNCT
3484zg66q03	21	21	.	.	PUNCT
3484zg66q03	22	1	1h	1h	NOUN
3484zg66q03	22	2	nmr	nmr	PROPN
3484zg66q03	22	3	rate	rate	NOUN
3484zg66q03	22	4	studies	study	NOUN
3484zg66q03	22	5	could	could	AUX
3484zg66q03	22	6	be	be	AUX
3484zg66q03	22	7	directly	directly	ADV
3484zg66q03	22	8	performed	perform	VERB
3484zg66q03	22	9	on	on	ADP
3484zg66q03	22	10	the	the	DET
3484zg66q03	22	11	reaction	reaction	NOUN
3484zg66q03	22	12	between	between	ADP
3484zg66q03	22	13	lli2(thf)n	lli2(thf)n	PROPN
3484zg66q03	22	14	and	and	CCONJ
3484zg66q03	22	15	(	(	PUNCT
3484zg66q03	22	16	me3si)2nh	me3si)2nh	NUM
3484zg66q03	22	17	by	by	ADP
3484zg66q03	22	18	performing	perform	VERB
3484zg66q03	22	19	experiments	experiment	NOUN
3484zg66q03	22	20	in	in	ADP
3484zg66q03	22	21	the	the	DET
3484zg66q03	22	22	temperature	temperature	NOUN
3484zg66q03	22	23	range	range	NOUN
3484zg66q03	22	24	of	of	ADP
3484zg66q03	22	25	-75	-75	NUM
3484zg66q03	22	26	to	to	ADP
3484zg66q03	22	27	-45	-45	NUM
3484zg66q03	22	28	ìâå¼c	ìâå¼c	SPACE
3484zg66q03	22	29	.	.	PUNCT
3484zg66q03	23	1	the	the	DET
3484zg66q03	23	2	observed	observed	ADJ
3484zg66q03	23	3	rates	rate	NOUN
3484zg66q03	23	4	for	for	ADP
3484zg66q03	23	5	lli2(thf)n	lli2(thf)n	NOUN
3484zg66q03	23	6	from	from	ADP
3484zg66q03	23	7	measurements	measurement	NOUN
3484zg66q03	23	8	between	between	ADP
3484zg66q03	23	9	-75	-75	NUM
3484zg66q03	23	10	and	and	CCONJ
3484zg66q03	23	11	-45	-45	NUM
3484zg66q03	23	12	ìâå¼c	ìâå¼c	PUNCT
3484zg66q03	23	13	were	be	AUX
3484zg66q03	23	14	extrapolated	extrapolate	VERB
3484zg66q03	23	15	to	to	ADP
3484zg66q03	23	16	25	25	NUM
3484zg66q03	23	17	ìâå¼c	ìâå¼c	SPACE
3484zg66q03	23	18	.	.	PUNCT
3484zg66q03	23	19	comparison	comparison	NOUN
3484zg66q03	23	20	of	of	ADP
3484zg66q03	23	21	the	the	DET
3484zg66q03	23	22	reaction	reaction	NOUN
3484zg66q03	23	23	rates	rate	NOUN
3484zg66q03	23	24	of	of	ADP
3484zg66q03	23	25	lli2(thf)n	lli2(thf)n	PROPN
3484zg66q03	23	26	and	and	CCONJ
3484zg66q03	23	27	[	[	X
3484zg66q03	23	28	l2li3]-[li(thf)4]+	l2li3]-[li(thf)4]+	NOUN
3484zg66q03	23	29	provide	provide	VERB
3484zg66q03	23	30	a	a	DET
3484zg66q03	23	31	reactivity	reactivity	NOUN
3484zg66q03	23	32	ratio	ratio	NOUN
3484zg66q03	23	33	on	on	ADP
3484zg66q03	23	34	the	the	DET
3484zg66q03	23	35	order	order	NOUN
3484zg66q03	23	36	of	of	ADP
3484zg66q03	23	37	8x105	8x105	NUM
3484zg66q03	23	38	!	!	PUNCT
3484zg66q03	23	39	!	!	PUNCT
3484zg66q03	23	40	!	!	PUNCT