id	sid	tid	token	lemma	pos
3197xk83f01	1	1	the	the	DET
3197xk83f01	1	2	synthesis	synthesis	NOUN
3197xk83f01	1	3	and	and	CCONJ
3197xk83f01	1	4	characterization	characterization	NOUN
3197xk83f01	1	5	of	of	ADP
3197xk83f01	1	6	heterobimetallic	heterobimetallic	ADJ
3197xk83f01	1	7	alkaline	alkaline	NOUN
3197xk83f01	1	8	-	-	PUNCT
3197xk83f01	1	9	earth	earth	NOUN
3197xk83f01	1	10	metal	metal	NOUN
3197xk83f01	1	11	amides	amide	NOUN
3197xk83f01	1	12	was	be	AUX
3197xk83f01	1	13	attempted	attempt	VERB
3197xk83f01	1	14	.	.	PUNCT
3197xk83f01	2	1	this	this	PRON
3197xk83f01	2	2	is	be	AUX
3197xk83f01	2	3	an	an	DET
3197xk83f01	2	4	entirely	entirely	ADV
3197xk83f01	2	5	new	new	ADJ
3197xk83f01	2	6	class	class	NOUN
3197xk83f01	2	7	of	of	ADP
3197xk83f01	2	8	compounds	compound	NOUN
3197xk83f01	2	9	and	and	CCONJ
3197xk83f01	2	10	they	they	PRON
3197xk83f01	2	11	were	be	AUX
3197xk83f01	2	12	targeted	target	VERB
3197xk83f01	2	13	with	with	ADP
3197xk83f01	2	14	the	the	DET
3197xk83f01	2	15	purpose	purpose	NOUN
3197xk83f01	2	16	of	of	ADP
3197xk83f01	2	17	evaluating	evaluate	VERB
3197xk83f01	2	18	their	their	PRON
3197xk83f01	2	19	bond	bond	NOUN
3197xk83f01	2	20	character	character	NOUN
3197xk83f01	2	21	aggregation	aggregation	NOUN
3197xk83f01	2	22	behavior	behavior	NOUN
3197xk83f01	2	23	in	in	ADP
3197xk83f01	2	24	solution	solution	NOUN
3197xk83f01	2	25	and	and	CCONJ
3197xk83f01	2	26	in	in	ADP
3197xk83f01	2	27	the	the	DET
3197xk83f01	2	28	solid	solid	ADJ
3197xk83f01	2	29	state	state	NOUN
3197xk83f01	2	30	.	.	PUNCT
3197xk83f01	3	1	the	the	DET
3197xk83f01	3	2	reaction	reaction	NOUN
3197xk83f01	3	3	between	between	ADP
3197xk83f01	3	4	the	the	DET
3197xk83f01	3	5	appropriate	appropriate	ADJ
3197xk83f01	3	6	homometallic	homometallic	NOUN
3197xk83f01	3	7	bis(hexamethyldisilazide	bis(hexamethyldisilazide	ADV
3197xk83f01	3	8	)	)	PUNCT
3197xk83f01	3	9	precursors	precursor	NOUN
3197xk83f01	3	10	in	in	ADP
3197xk83f01	3	11	non	non	ADJ
3197xk83f01	3	12	-	-	ADJ
3197xk83f01	3	13	donating	donating	ADJ
3197xk83f01	3	14	solvents	solvent	NOUN
3197xk83f01	3	15	yielded	yield	VERB
3197xk83f01	3	16	the	the	DET
3197xk83f01	3	17	products	product	NOUN
3197xk83f01	3	18	:	:	PUNCT
3197xk83f01	4	1	[	[	X
3197xk83f01	4	2	camg{n(sime3)2}4	camg{n(sime3)2}4	X
3197xk83f01	4	3	]	]	X
3197xk83f01	4	4	(	(	PUNCT
3197xk83f01	4	5	1	1	NUM
3197xk83f01	4	6	)	)	PUNCT
3197xk83f01	4	7	,	,	PUNCT
3197xk83f01	4	8	[	[	X
3197xk83f01	4	9	srmg{n(sime3)2}4	srmg{n(sime3)2}4	X
3197xk83f01	4	10	]	]	X
3197xk83f01	4	11	(	(	PUNCT
3197xk83f01	4	12	2	2	NUM
3197xk83f01	4	13	)	)	PUNCT
3197xk83f01	4	14	,	,	PUNCT
3197xk83f01	4	15	[	[	X
3197xk83f01	4	16	srca{n(sime3)2}4	srca{n(sime3)2}4	X
3197xk83f01	4	17	]	]	X
3197xk83f01	4	18	(	(	PUNCT
3197xk83f01	4	19	3	3	NUM
3197xk83f01	4	20	)	)	PUNCT
3197xk83f01	4	21	,	,	PUNCT
3197xk83f01	4	22	and	and	CCONJ
3197xk83f01	4	23	[	[	X
3197xk83f01	4	24	ba2{n(sime3)2}3"¢toluene]+[mg{n(sime3)2}3](4	ba2{n(sime3)2}3"¢toluene]+[mg{n(sime3)2}3](4	X
3197xk83f01	4	25	)	)	PUNCT
3197xk83f01	4	26	.	.	PUNCT
3197xk83f01	5	1	the	the	DET
3197xk83f01	5	2	synthesis	synthesis	NOUN
3197xk83f01	5	3	of	of	ADP
3197xk83f01	5	4	crystalline	crystalline	PROPN
3197xk83f01	5	5	ba	ba	PROPN
3197xk83f01	5	6	/	/	SYM
3197xk83f01	5	7	ca	ca	PROPN
3197xk83f01	5	8	and	and	CCONJ
3197xk83f01	5	9	ba	ba	PROPN
3197xk83f01	5	10	/	/	SYM
3197xk83f01	5	11	sr	sr	PROPN
3197xk83f01	5	12	heterobimetallic	heterobimetallic	PROPN
3197xk83f01	5	13	complexes	complex	NOUN
3197xk83f01	5	14	was	be	AUX
3197xk83f01	5	15	attempted	attempt	VERB
3197xk83f01	5	16	however	however	ADV
3197xk83f01	5	17	they	they	PRON
3197xk83f01	5	18	do	do	AUX
3197xk83f01	5	19	not	not	PART
3197xk83f01	5	20	mix	mix	VERB
3197xk83f01	5	21	in	in	ADP
3197xk83f01	5	22	solution	solution	NOUN
3197xk83f01	5	23	.	.	PUNCT
3197xk83f01	6	1	compounds	compound	NOUN
3197xk83f01	6	2	1	1	NUM
3197xk83f01	6	3	-	-	SYM
3197xk83f01	6	4	4	4	NUM
3197xk83f01	6	5	were	be	AUX
3197xk83f01	6	6	successfully	successfully	ADV
3197xk83f01	6	7	characterized	characterize	VERB
3197xk83f01	6	8	by	by	ADP
3197xk83f01	6	9	single	single	ADJ
3197xk83f01	6	10	crystal	crystal	NOUN
3197xk83f01	6	11	x	x	NOUN
3197xk83f01	6	12	-	-	NOUN
3197xk83f01	6	13	ray	ray	NOUN
3197xk83f01	6	14	diffraction	diffraction	NOUN
3197xk83f01	6	15	.	.	PUNCT
3197xk83f01	7	1	structures	structure	NOUN
3197xk83f01	7	2	1	1	NUM
3197xk83f01	7	3	,	,	PUNCT
3197xk83f01	7	4	2	2	NUM
3197xk83f01	7	5	,	,	PUNCT
3197xk83f01	7	6	and	and	CCONJ
3197xk83f01	7	7	3	3	NUM
3197xk83f01	7	8	are	be	AUX
3197xk83f01	7	9	all	all	PRON
3197xk83f01	7	10	heterodimers	heterodimer	NOUN
3197xk83f01	7	11	with	with	ADP
3197xk83f01	7	12	a	a	DET
3197xk83f01	7	13	four	four	NUM
3197xk83f01	7	14	membered	membered	ADJ
3197xk83f01	7	15	ring	ring	NOUN
3197xk83f01	7	16	core	core	NOUN
3197xk83f01	7	17	consisting	consist	VERB
3197xk83f01	7	18	of	of	ADP
3197xk83f01	7	19	both	both	DET
3197xk83f01	7	20	metals	metal	NOUN
3197xk83f01	7	21	connected	connect	VERB
3197xk83f01	7	22	by	by	ADP
3197xk83f01	7	23	bridging	bridge	VERB
3197xk83f01	7	24	amide	amide	PROPN
3197xk83f01	7	25	groups	group	NOUN
3197xk83f01	7	26	.	.	PUNCT
3197xk83f01	8	1	each	each	DET
3197xk83f01	8	2	metal	metal	NOUN
3197xk83f01	8	3	is	be	AUX
3197xk83f01	8	4	bonded	bond	VERB
3197xk83f01	8	5	to	to	ADP
3197xk83f01	8	6	a	a	DET
3197xk83f01	8	7	single	single	ADJ
3197xk83f01	8	8	amide	amide	NOUN
3197xk83f01	8	9	group	group	NOUN
3197xk83f01	8	10	yielding	yield	VERB
3197xk83f01	8	11	a	a	DET
3197xk83f01	8	12	coordination	coordination	NOUN
3197xk83f01	8	13	number	number	NOUN
3197xk83f01	8	14	of	of	ADP
3197xk83f01	8	15	three	three	NUM
3197xk83f01	8	16	.	.	PUNCT
3197xk83f01	9	1	the	the	DET
3197xk83f01	9	2	charge	charge	NOUN
3197xk83f01	9	3	separated	separate	VERB
3197xk83f01	9	4	complex	complex	ADJ
3197xk83f01	9	5	4	4	NUM
3197xk83f01	9	6	consists	consist	NOUN
3197xk83f01	9	7	of	of	ADP
3197xk83f01	9	8	a	a	DET
3197xk83f01	9	9	magnesium	magnesium	NOUN
3197xk83f01	9	10	trisamide	trisamide	NOUN
3197xk83f01	9	11	anion	anion	NOUN
3197xk83f01	9	12	and	and	CCONJ
3197xk83f01	9	13	a	a	DET
3197xk83f01	9	14	dimeric	dimeric	ADJ
3197xk83f01	9	15	barium	barium	NOUN
3197xk83f01	9	16	cation	cation	NOUN
3197xk83f01	9	17	with	with	ADP
3197xk83f01	9	18	one	one	NUM
3197xk83f01	9	19	metal	metal	NOUN
3197xk83f01	9	20	site	site	NOUN
3197xk83f01	9	21	solvated	solvate	VERB
3197xk83f01	9	22	by	by	ADP
3197xk83f01	9	23	a	a	PRON
3197xk83f01	9	24	&	&	CCONJ
3197xk83f01	9	25	#	#	SYM
3197xk83f01	9	26	960;-bound	960;-bound	NUM
3197xk83f01	9	27	toluene	toluene	NOUN
3197xk83f01	9	28	molecule	molecule	NOUN
3197xk83f01	9	29	.	.	PUNCT
3197xk83f01	10	1	analysis	analysis	NOUN
3197xk83f01	10	2	of	of	ADP
3197xk83f01	10	3	the	the	DET
3197xk83f01	10	4	metrical	metrical	ADJ
3197xk83f01	10	5	parameters	parameter	NOUN
3197xk83f01	10	6	in	in	ADP
3197xk83f01	10	7	1	1	NUM
3197xk83f01	10	8	-	-	SYM
3197xk83f01	10	9	3	3	NUM
3197xk83f01	10	10	indicates	indicate	VERB
3197xk83f01	10	11	that	that	SCONJ
3197xk83f01	10	12	the	the	DET
3197xk83f01	10	13	more	more	ADV
3197xk83f01	10	14	lewis	lewis	NOUN
3197xk83f01	10	15	acidic	acidic	ADJ
3197xk83f01	10	16	metal	metal	NOUN
3197xk83f01	10	17	pulls	pull	VERB
3197xk83f01	10	18	the	the	DET
3197xk83f01	10	19	electron	electron	NOUN
3197xk83f01	10	20	density	density	NOUN
3197xk83f01	10	21	of	of	ADP
3197xk83f01	10	22	the	the	DET
3197xk83f01	10	23	bridging	bridge	VERB
3197xk83f01	10	24	amide	amide	PROPN
3197xk83f01	10	25	ligands	ligand	NOUN
3197xk83f01	10	26	towards	towards	ADP
3197xk83f01	10	27	it	it	PRON
3197xk83f01	10	28	,	,	PUNCT
3197xk83f01	10	29	causing	cause	VERB
3197xk83f01	10	30	a	a	DET
3197xk83f01	10	31	lauren	lauren	PROPN
3197xk83f01	10	32	t.	t.	PROPN
3197xk83f01	10	33	wendell	wendell	PROPN
3197xk83f01	10	34	change	change	PROPN
3197xk83f01	10	35	in	in	ADP
3197xk83f01	10	36	the	the	DET
3197xk83f01	10	37	bonding	bonding	NOUN
3197xk83f01	10	38	when	when	SCONJ
3197xk83f01	10	39	compared	compare	VERB
3197xk83f01	10	40	to	to	ADP
3197xk83f01	10	41	the	the	DET
3197xk83f01	10	42	homodimer	homodimer	NOUN
3197xk83f01	10	43	structures	structure	NOUN
3197xk83f01	10	44	.	.	PUNCT
3197xk83f01	11	1	this	this	DET
3197xk83f01	11	2	change	change	NOUN
3197xk83f01	11	3	in	in	ADP
3197xk83f01	11	4	the	the	DET
3197xk83f01	11	5	bonding	bonding	NOUN
3197xk83f01	11	6	causes	cause	VERB
3197xk83f01	11	7	interesting	interesting	ADJ
3197xk83f01	11	8	solution	solution	NOUN
3197xk83f01	11	9	behavior	behavior	NOUN
3197xk83f01	11	10	,	,	PUNCT
3197xk83f01	11	11	where	where	SCONJ
3197xk83f01	11	12	charge	charge	NOUN
3197xk83f01	11	13	separated	separate	VERB
3197xk83f01	11	14	species	specie	NOUN
3197xk83f01	11	15	are	be	AUX
3197xk83f01	11	16	often	often	ADV
3197xk83f01	11	17	seen	see	VERB
3197xk83f01	11	18	in	in	ADP
3197xk83f01	11	19	donating	donate	VERB
3197xk83f01	11	20	solvents	solvent	NOUN
3197xk83f01	11	21	.	.	PUNCT
3197xk83f01	12	1	the	the	DET
3197xk83f01	12	2	most	most	ADV
3197xk83f01	12	3	extreme	extreme	ADJ
3197xk83f01	12	4	case	case	NOUN
3197xk83f01	12	5	is	be	AUX
3197xk83f01	12	6	complex	complex	ADJ
3197xk83f01	12	7	4	4	NUM
3197xk83f01	12	8	where	where	SCONJ
3197xk83f01	12	9	charge	charge	NOUN
3197xk83f01	12	10	separation	separation	NOUN
3197xk83f01	12	11	is	be	AUX
3197xk83f01	12	12	also	also	ADV
3197xk83f01	12	13	observed	observe	VERB
3197xk83f01	12	14	in	in	ADP
3197xk83f01	12	15	the	the	DET
3197xk83f01	12	16	solid	solid	ADJ
3197xk83f01	12	17	state	state	NOUN
3197xk83f01	12	18	.	.	PUNCT
3197xk83f01	13	1	complexes	complex	NOUN
3197xk83f01	13	2	1	1	NUM
3197xk83f01	13	3	,	,	PUNCT
3197xk83f01	13	4	2	2	NUM
3197xk83f01	13	5	,	,	PUNCT
3197xk83f01	13	6	and	and	CCONJ
3197xk83f01	13	7	3	3	NUM
3197xk83f01	13	8	all	all	PRON
3197xk83f01	13	9	undergo	undergo	VERB
3197xk83f01	13	10	a	a	DET
3197xk83f01	13	11	dynamic	dynamic	ADJ
3197xk83f01	13	12	equilibrium	equilibrium	NOUN
3197xk83f01	13	13	between	between	ADP
3197xk83f01	13	14	the	the	DET
3197xk83f01	13	15	heterobimetallic	heterobimetallic	ADJ
3197xk83f01	13	16	structures	structure	NOUN
3197xk83f01	13	17	and	and	CCONJ
3197xk83f01	13	18	the	the	DET
3197xk83f01	13	19	homometallic	homometallic	NOUN
3197xk83f01	13	20	precursors	precursor	NOUN
3197xk83f01	13	21	in	in	ADP
3197xk83f01	13	22	arene	arene	NOUN
3197xk83f01	13	23	solvents	solvent	NOUN
3197xk83f01	13	24	.	.	PUNCT
3197xk83f01	14	1	in	in	ADP
3197xk83f01	14	2	contrast	contrast	NOUN
3197xk83f01	14	3	,	,	PUNCT
3197xk83f01	14	4	complex	complex	ADJ
3197xk83f01	14	5	4	4	NUM
3197xk83f01	14	6	maintains	maintain	VERB
3197xk83f01	14	7	charge	charge	NOUN
3197xk83f01	14	8	separation	separation	NOUN
3197xk83f01	14	9	.	.	PUNCT
3197xk83f01	15	1	the	the	DET
3197xk83f01	15	2	change	change	NOUN
3197xk83f01	15	3	in	in	ADP
3197xk83f01	15	4	the	the	DET
3197xk83f01	15	5	bonding	bonding	NOUN
3197xk83f01	15	6	and	and	CCONJ
3197xk83f01	15	7	solution	solution	NOUN
3197xk83f01	15	8	behavior	behavior	NOUN
3197xk83f01	15	9	compared	compare	VERB
3197xk83f01	15	10	to	to	ADP
3197xk83f01	15	11	the	the	DET
3197xk83f01	15	12	homodimers	homodimer	NOUN
3197xk83f01	15	13	suggests	suggest	VERB
3197xk83f01	15	14	that	that	SCONJ
3197xk83f01	15	15	these	these	DET
3197xk83f01	15	16	compounds	compound	NOUN
3197xk83f01	15	17	will	will	AUX
3197xk83f01	15	18	have	have	VERB
3197xk83f01	15	19	interesting	interesting	ADJ
3197xk83f01	15	20	reactivity	reactivity	NOUN
3197xk83f01	15	21	with	with	ADP
3197xk83f01	15	22	organic	organic	ADJ
3197xk83f01	15	23	substrates	substrate	NOUN
3197xk83f01	15	24	.	.	PUNCT