id sid tid token lemma pos 2v23vt16t5r 1 1 a a DET 2v23vt16t5r 1 2 three three NUM 2v23vt16t5r 1 3 step step NOUN 2v23vt16t5r 1 4 high high ADJ 2v23vt16t5r 1 5 throughput throughput NOUN 2v23vt16t5r 1 6 catalytic catalytic ADJ 2v23vt16t5r 1 7 screening screening NOUN 2v23vt16t5r 1 8 process process NOUN 2v23vt16t5r 1 9 was be AUX 2v23vt16t5r 1 10 used use VERB 2v23vt16t5r 1 11 to to PART 2v23vt16t5r 1 12 evaluate evaluate VERB 2v23vt16t5r 1 13 the the DET 2v23vt16t5r 1 14 activity activity NOUN 2v23vt16t5r 1 15 and and CCONJ 2v23vt16t5r 1 16 selectivity selectivity NOUN 2v23vt16t5r 1 17 of of ADP 2v23vt16t5r 1 18 copper copper NOUN 2v23vt16t5r 1 19 and and CCONJ 2v23vt16t5r 1 20 zinc zinc NOUN 2v23vt16t5r 1 21 based base VERB 2v23vt16t5r 1 22 methanol methanol NOUN 2v23vt16t5r 1 23 partial partial ADJ 2v23vt16t5r 1 24 oxidation oxidation NOUN 2v23vt16t5r 1 25 catalysts catalyst NOUN 2v23vt16t5r 1 26 . . PUNCT 2v23vt16t5r 2 1 the the DET 2v23vt16t5r 2 2 most most ADV 2v23vt16t5r 2 3 active active ADJ 2v23vt16t5r 2 4 catalyst catalyst NOUN 2v23vt16t5r 2 5 preparations preparation NOUN 2v23vt16t5r 2 6 contained contain VERB 2v23vt16t5r 2 7 both both DET 2v23vt16t5r 2 8 palladium palladium NOUN 2v23vt16t5r 2 9 and and CCONJ 2v23vt16t5r 2 10 zirconium zirconium NOUN 2v23vt16t5r 2 11 promoters promoter NOUN 2v23vt16t5r 2 12 . . PUNCT 2v23vt16t5r 3 1 the the DET 2v23vt16t5r 3 2 high high ADJ 2v23vt16t5r 3 3 activity activity NOUN 2v23vt16t5r 3 4 and and CCONJ 2v23vt16t5r 3 5 selectivity selectivity NOUN 2v23vt16t5r 3 6 obtained obtain VERB 2v23vt16t5r 3 7 from from ADP 2v23vt16t5r 3 8 the the DET 2v23vt16t5r 3 9 doubly doubly ADV 2v23vt16t5r 3 10 promoted promote VERB 2v23vt16t5r 3 11 7cu/3zn/1zr-1pd 7cu/3zn/1zr-1pd NUM 2v23vt16t5r 3 12 composition composition NOUN 2v23vt16t5r 3 13 suggested suggest VERB 2v23vt16t5r 3 14 a a DET 2v23vt16t5r 3 15 synergy synergy NOUN 2v23vt16t5r 3 16 between between ADP 2v23vt16t5r 3 17 palladium palladium NOUN 2v23vt16t5r 3 18 and and CCONJ 2v23vt16t5r 3 19 zirconium zirconium NOUN 2v23vt16t5r 3 20 promoters promoter NOUN 2v23vt16t5r 3 21 . . PUNCT 2v23vt16t5r 4 1 characterization characterization NOUN 2v23vt16t5r 4 2 studies study NOUN 2v23vt16t5r 4 3 showed show VERB 2v23vt16t5r 4 4 that that SCONJ 2v23vt16t5r 4 5 the the DET 2v23vt16t5r 4 6 zirconia zirconia NOUN 2v23vt16t5r 4 7 promoter promoter NOUN 2v23vt16t5r 4 8 significantly significantly ADV 2v23vt16t5r 4 9 enhanced enhance VERB 2v23vt16t5r 4 10 characteristics characteristic NOUN 2v23vt16t5r 4 11 such such ADJ 2v23vt16t5r 4 12 as as ADP 2v23vt16t5r 4 13 surface surface NOUN 2v23vt16t5r 4 14 area area NOUN 2v23vt16t5r 4 15 , , PUNCT 2v23vt16t5r 4 16 dispersion dispersion NOUN 2v23vt16t5r 4 17 , , PUNCT 2v23vt16t5r 4 18 crystallite crystallite ADJ 2v23vt16t5r 4 19 size size NOUN 2v23vt16t5r 4 20 , , PUNCT 2v23vt16t5r 4 21 and and CCONJ 2v23vt16t5r 4 22 deactivation deactivation NOUN 2v23vt16t5r 4 23 resistance resistance NOUN 2v23vt16t5r 4 24 , , PUNCT 2v23vt16t5r 4 25 leading lead VERB 2v23vt16t5r 4 26 to to ADP 2v23vt16t5r 4 27 lowered lower VERB 2v23vt16t5r 4 28 reduction reduction NOUN 2v23vt16t5r 4 29 temperature temperature NOUN 2v23vt16t5r 4 30 . . PUNCT 2v23vt16t5r 5 1 however however ADV 2v23vt16t5r 5 2 the the DET 2v23vt16t5r 5 3 zirconia zirconia NOUN 2v23vt16t5r 5 4 promoter promoter NOUN 2v23vt16t5r 5 5 alone alone ADV 2v23vt16t5r 5 6 only only ADV 2v23vt16t5r 5 7 slightly slightly ADV 2v23vt16t5r 5 8 lowered lower VERB 2v23vt16t5r 5 9 the the DET 2v23vt16t5r 5 10 reaction reaction NOUN 2v23vt16t5r 5 11 light light NOUN 2v23vt16t5r 5 12 off off ADP 2v23vt16t5r 5 13 temperature temperature NOUN 2v23vt16t5r 5 14 . . PUNCT 2v23vt16t5r 6 1 unlike unlike ADP 2v23vt16t5r 6 2 zirconia zirconia PROPN 2v23vt16t5r 6 3 , , PUNCT 2v23vt16t5r 6 4 the the DET 2v23vt16t5r 6 5 palladium palladium NOUN 2v23vt16t5r 6 6 promoter promoter NOUN 2v23vt16t5r 6 7 did do AUX 2v23vt16t5r 6 8 not not PART 2v23vt16t5r 6 9 significantly significantly ADV 2v23vt16t5r 6 10 alter alter VERB 2v23vt16t5r 6 11 microstructural microstructural ADJ 2v23vt16t5r 6 12 characteristics characteristic NOUN 2v23vt16t5r 6 13 of of ADP 2v23vt16t5r 6 14 the the DET 2v23vt16t5r 6 15 catalyst catalyst NOUN 2v23vt16t5r 6 16 . . PUNCT 2v23vt16t5r 7 1 palladium palladium NOUN 2v23vt16t5r 7 2 was be AUX 2v23vt16t5r 7 3 shown show VERB 2v23vt16t5r 7 4 to to PART 2v23vt16t5r 7 5 significantly significantly ADV 2v23vt16t5r 7 6 lower lower VERB 2v23vt16t5r 7 7 the the DET 2v23vt16t5r 7 8 reduction reduction NOUN 2v23vt16t5r 7 9 temperature temperature NOUN 2v23vt16t5r 7 10 regardless regardless ADV 2v23vt16t5r 7 11 of of ADP 2v23vt16t5r 7 12 initial initial ADJ 2v23vt16t5r 7 13 cuo cuo PROPN 2v23vt16t5r 7 14 crystallite crystallite NOUN 2v23vt16t5r 7 15 size size NOUN 2v23vt16t5r 7 16 , , PUNCT 2v23vt16t5r 7 17 which which PRON 2v23vt16t5r 7 18 suggests suggest VERB 2v23vt16t5r 7 19 that that SCONJ 2v23vt16t5r 7 20 palladium palladium NOUN 2v23vt16t5r 7 21 enhances enhance VERB 2v23vt16t5r 7 22 the the DET 2v23vt16t5r 7 23 catalytic catalytic ADJ 2v23vt16t5r 7 24 activity activity NOUN 2v23vt16t5r 7 25 by by ADP 2v23vt16t5r 7 26 increasing increase VERB 2v23vt16t5r 7 27 copper copper NOUN 2v23vt16t5r 7 28 reducibility reducibility NOUN 2v23vt16t5r 7 29 . . PUNCT 2v23vt16t5r 8 1 copper copper PROPN 2v23vt16t5r 8 2 k k PROPN 2v23vt16t5r 8 3 edge edge PROPN 2v23vt16t5r 8 4 x x NOUN 2v23vt16t5r 8 5 - - NOUN 2v23vt16t5r 8 6 ray ray NOUN 2v23vt16t5r 8 7 absorption absorption NOUN 2v23vt16t5r 8 8 spectroscopy spectroscopy NOUN 2v23vt16t5r 8 9 confirmed confirm VERB 2v23vt16t5r 8 10 palladium palladium NOUN 2v23vt16t5r 8 11 promoted promote VERB 2v23vt16t5r 8 12 catalysts catalyst NOUN 2v23vt16t5r 8 13 are be AUX 2v23vt16t5r 8 14 more more ADV 2v23vt16t5r 8 15 easily easily ADV 2v23vt16t5r 8 16 reduced reduce VERB 2v23vt16t5r 8 17 to to PART 2v23vt16t5r 8 18 cu0 cu0 VERB 2v23vt16t5r 8 19 under under ADP 2v23vt16t5r 8 20 reaction reaction NOUN 2v23vt16t5r 8 21 conditions condition NOUN 2v23vt16t5r 8 22 . . PUNCT 2v23vt16t5r 9 1 palladium palladium NOUN 2v23vt16t5r 9 2 x x NOUN 2v23vt16t5r 9 3 - - NOUN 2v23vt16t5r 9 4 ray ray NOUN 2v23vt16t5r 9 5 absorption absorption NOUN 2v23vt16t5r 9 6 spectroscopy spectroscopy NOUN 2v23vt16t5r 9 7 was be AUX 2v23vt16t5r 9 8 used use VERB 2v23vt16t5r 9 9 to to PART 2v23vt16t5r 9 10 determine determine VERB 2v23vt16t5r 9 11 that that DET 2v23vt16t5r 9 12 formation formation NOUN 2v23vt16t5r 9 13 of of ADP 2v23vt16t5r 9 14 pd pd PROPN 2v23vt16t5r 9 15 - - PUNCT 2v23vt16t5r 9 16 cu cu PROPN 2v23vt16t5r 9 17 alloys alloy NOUN 2v23vt16t5r 9 18 is be AUX 2v23vt16t5r 9 19 preferred prefer VERB 2v23vt16t5r 9 20 over over ADP 2v23vt16t5r 9 21 pd pd PROPN 2v23vt16t5r 9 22 - - PUNCT 2v23vt16t5r 9 23 zn zn PROPN 2v23vt16t5r 9 24 alloys alloy NOUN 2v23vt16t5r 9 25 . . PUNCT 2v23vt16t5r 10 1 using use VERB 2v23vt16t5r 10 2 a a DET 2v23vt16t5r 10 3 four four NUM 2v23vt16t5r 10 4 step step NOUN 2v23vt16t5r 10 5 model model NOUN 2v23vt16t5r 10 6 reaction reaction NOUN 2v23vt16t5r 10 7 pathway pathway NOUN 2v23vt16t5r 10 8 it it PRON 2v23vt16t5r 10 9 was be AUX 2v23vt16t5r 10 10 found find VERB 2v23vt16t5r 10 11 that that SCONJ 2v23vt16t5r 10 12 the the DET 2v23vt16t5r 10 13 combination combination NOUN 2v23vt16t5r 10 14 of of ADP 2v23vt16t5r 10 15 palladium palladium NOUN 2v23vt16t5r 10 16 and and CCONJ 2v23vt16t5r 10 17 zirconia zirconia NOUN 2v23vt16t5r 10 18 promoters promoter NOUN 2v23vt16t5r 10 19 significantly significantly ADV 2v23vt16t5r 10 20 lowers lower VERB 2v23vt16t5r 10 21 the the DET 2v23vt16t5r 10 22 activation activation NOUN 2v23vt16t5r 10 23 energy energy NOUN 2v23vt16t5r 10 24 of of ADP 2v23vt16t5r 10 25 the the DET 2v23vt16t5r 10 26 methanol methanol NOUN 2v23vt16t5r 10 27 combustion combustion NOUN 2v23vt16t5r 10 28 and and CCONJ 2v23vt16t5r 10 29 steam steam NOUN 2v23vt16t5r 10 30 reforming reform VERB 2v23vt16t5r 10 31 reactions reaction NOUN 2v23vt16t5r 10 32 . . PUNCT 2v23vt16t5r 11 1 however however ADV 2v23vt16t5r 11 2 , , PUNCT 2v23vt16t5r 11 3 promoter promoter NOUN 2v23vt16t5r 11 4 materials material NOUN 2v23vt16t5r 11 5 do do AUX 2v23vt16t5r 11 6 not not PART 2v23vt16t5r 11 7 influence influence VERB 2v23vt16t5r 11 8 the the DET 2v23vt16t5r 11 9 methanol methanol NOUN 2v23vt16t5r 11 10 decomposition decomposition NOUN 2v23vt16t5r 11 11 and and CCONJ 2v23vt16t5r 11 12 water water NOUN 2v23vt16t5r 11 13 gas gas NOUN 2v23vt16t5r 11 14 shift shift NOUN 2v23vt16t5r 11 15 activation activation NOUN 2v23vt16t5r 11 16 energies energy NOUN 2v23vt16t5r 11 17 because because SCONJ 2v23vt16t5r 11 18 of of ADP 2v23vt16t5r 11 19 the the DET 2v23vt16t5r 11 20 similarity similarity NOUN 2v23vt16t5r 11 21 of of ADP 2v23vt16t5r 11 22 catalyst catalyst NOUN 2v23vt16t5r 11 23 state state NOUN 2v23vt16t5r 11 24 at at ADP 2v23vt16t5r 11 25 high high ADJ 2v23vt16t5r 11 26 reaction reaction NOUN 2v23vt16t5r 11 27 temperatures temperature NOUN 2v23vt16t5r 11 28 regardless regardless ADV 2v23vt16t5r 11 29 of of ADP 2v23vt16t5r 11 30 promoter promoter NOUN 2v23vt16t5r 11 31 materials material NOUN 2v23vt16t5r 11 32 . . PUNCT 2v23vt16t5r 12 1 in in ADP 2v23vt16t5r 12 2 reformer reformer ADJ 2v23vt16t5r 12 3 simulations simulation NOUN 2v23vt16t5r 12 4 it it PRON 2v23vt16t5r 12 5 was be AUX 2v23vt16t5r 12 6 found find VERB 2v23vt16t5r 12 7 that that SCONJ 2v23vt16t5r 12 8 approximately approximately ADV 2v23vt16t5r 12 9 5 5 NUM 2v23vt16t5r 12 10 grams gram NOUN 2v23vt16t5r 12 11 of of ADP 2v23vt16t5r 12 12 catalyst catalyst NOUN 2v23vt16t5r 12 13 is be AUX 2v23vt16t5r 12 14 needed need VERB 2v23vt16t5r 12 15 to to PART 2v23vt16t5r 12 16 power power VERB 2v23vt16t5r 12 17 a a DET 2v23vt16t5r 12 18 notebook notebook NOUN 2v23vt16t5r 12 19 computer computer NOUN 2v23vt16t5r 12 20 . . PUNCT 2v23vt16t5r 13 1 combustion combustion NOUN 2v23vt16t5r 13 2 synthesized synthesize VERB 2v23vt16t5r 13 3 catalysts catalyst NOUN 2v23vt16t5r 13 4 were be AUX 2v23vt16t5r 13 5 shown show VERB 2v23vt16t5r 13 6 to to PART 2v23vt16t5r 13 7 have have VERB 2v23vt16t5r 13 8 activity activity NOUN 2v23vt16t5r 13 9 similar similar ADJ 2v23vt16t5r 13 10 to to ADP 2v23vt16t5r 13 11 bulk bulk ADJ 2v23vt16t5r 13 12 prepared prepared ADJ 2v23vt16t5r 13 13 catalysts catalyst NOUN 2v23vt16t5r 13 14 , , PUNCT 2v23vt16t5r 13 15 despite despite SCONJ 2v23vt16t5r 13 16 lower low ADJ 2v23vt16t5r 13 17 copper copper NOUN 2v23vt16t5r 13 18 area area NOUN 2v23vt16t5r 13 19 , , PUNCT 2v23vt16t5r 13 20 suggesting suggest VERB 2v23vt16t5r 13 21 higher high ADJ 2v23vt16t5r 13 22 turn turn NOUN 2v23vt16t5r 13 23 over over ADP 2v23vt16t5r 13 24 rate rate NOUN 2v23vt16t5r 13 25 . . PUNCT 2v23vt16t5r 14 1 it it PRON 2v23vt16t5r 14 2 was be AUX 2v23vt16t5r 14 3 found find VERB 2v23vt16t5r 14 4 that that SCONJ 2v23vt16t5r 14 5 changing change VERB 2v23vt16t5r 14 6 the the DET 2v23vt16t5r 14 7 palladium palladium NOUN 2v23vt16t5r 14 8 loading loading NOUN 2v23vt16t5r 14 9 to to ADP 2v23vt16t5r 14 10 the the DET 2v23vt16t5r 14 11 surface surface NOUN 2v23vt16t5r 14 12 from from ADP 2v23vt16t5r 14 13 the the DET 2v23vt16t5r 14 14 bulk bulk NOUN 2v23vt16t5r 14 15 did do AUX 2v23vt16t5r 14 16 not not PART 2v23vt16t5r 14 17 significantly significantly ADV 2v23vt16t5r 14 18 affect affect VERB 2v23vt16t5r 14 19 catalytic catalytic ADJ 2v23vt16t5r 14 20 activity activity NOUN 2v23vt16t5r 14 21 , , PUNCT 2v23vt16t5r 14 22 most most ADV 2v23vt16t5r 14 23 likely likely ADV 2v23vt16t5r 14 24 due due ADJ 2v23vt16t5r 14 25 to to ADP 2v23vt16t5r 14 26 encapsulation encapsulation NOUN 2v23vt16t5r 14 27 of of ADP 2v23vt16t5r 14 28 pd pd PROPN 2v23vt16t5r 14 29 by by ADP 2v23vt16t5r 14 30 alloying alloy VERB 2v23vt16t5r 14 31 with with ADP 2v23vt16t5r 14 32 copper copper NOUN 2v23vt16t5r 14 33 . . PUNCT 2v23vt16t5r 15 1 an an DET 2v23vt16t5r 15 2 exploration exploration NOUN 2v23vt16t5r 15 3 of of ADP 2v23vt16t5r 15 4 preparing prepare VERB 2v23vt16t5r 15 5 structured structured ADJ 2v23vt16t5r 15 6 catalysts catalyst NOUN 2v23vt16t5r 15 7 by by ADP 2v23vt16t5r 15 8 hydrothermal hydrothermal ADJ 2v23vt16t5r 15 9 synthesis synthesis NOUN 2v23vt16t5r 15 10 methods method NOUN 2v23vt16t5r 15 11 showed show VERB 2v23vt16t5r 15 12 that that SCONJ 2v23vt16t5r 15 13 intimate intimate ADJ 2v23vt16t5r 15 14 contact contact NOUN 2v23vt16t5r 15 15 of of ADP 2v23vt16t5r 15 16 copper copper NOUN 2v23vt16t5r 15 17 with with ADP 2v23vt16t5r 15 18 certain certain ADJ 2v23vt16t5r 15 19 oxide oxide NOUN 2v23vt16t5r 15 20 phases phase NOUN 2v23vt16t5r 15 21 is be AUX 2v23vt16t5r 15 22 required require VERB 2v23vt16t5r 15 23 for for ADP 2v23vt16t5r 15 24 high high ADJ 2v23vt16t5r 15 25 activity activity NOUN 2v23vt16t5r 15 26 . . PUNCT