id	sid	tid	token	lemma	pos
2n49t15093d	1	1	the	the	DET
2n49t15093d	1	2	focus	focus	NOUN
2n49t15093d	1	3	for	for	ADP
2n49t15093d	1	4	this	this	DET
2n49t15093d	1	5	dissertation	dissertation	NOUN
2n49t15093d	1	6	involved	involve	VERB
2n49t15093d	1	7	two	two	NUM
2n49t15093d	1	8	main	main	ADJ
2n49t15093d	1	9	projects	project	NOUN
2n49t15093d	1	10	that	that	PRON
2n49t15093d	1	11	complement	complement	VERB
2n49t15093d	1	12	the	the	DET
2n49t15093d	1	13	known	know	VERB
2n49t15093d	1	14	chemistry	chemistry	NOUN
2n49t15093d	1	15	of	of	ADP
2n49t15093d	1	16	acylnitroso	acylnitroso	PROPN
2n49t15093d	1	17	hetero	hetero	NOUN
2n49t15093d	1	18	-	-	PUNCT
2n49t15093d	1	19	diels	diel	NOUN
2n49t15093d	1	20	-	-	PUNCT
2n49t15093d	1	21	alder	alder	NOUN
2n49t15093d	1	22	(	(	PUNCT
2n49t15093d	1	23	hda	hda	NOUN
2n49t15093d	1	24	)	)	PUNCT
2n49t15093d	1	25	reactions	reaction	NOUN
2n49t15093d	1	26	.	.	PUNCT
2n49t15093d	2	1	the	the	DET
2n49t15093d	2	2	first	first	ADJ
2n49t15093d	2	3	project	project	NOUN
2n49t15093d	2	4	involved	involve	VERB
2n49t15093d	2	5	the	the	DET
2n49t15093d	2	6	synthesis	synthesis	NOUN
2n49t15093d	2	7	of	of	ADP
2n49t15093d	2	8	novel	novel	NOUN
2n49t15093d	2	9	mycobactin	mycobactin	PROPN
2n49t15093d	2	10	analogs	analog	NOUN
2n49t15093d	2	11	from	from	ADP
2n49t15093d	2	12	nitroso	nitroso	PROPN
2n49t15093d	2	13	hda	hda	NOUN
2n49t15093d	2	14	cycloadducts	cycloadduct	NOUN
2n49t15093d	2	15	,	,	PUNCT
2n49t15093d	2	16	and	and	CCONJ
2n49t15093d	2	17	also	also	ADV
2n49t15093d	2	18	included	include	VERB
2n49t15093d	2	19	the	the	DET
2n49t15093d	2	20	discovery	discovery	NOUN
2n49t15093d	2	21	and	and	CCONJ
2n49t15093d	2	22	study	study	NOUN
2n49t15093d	2	23	of	of	ADP
2n49t15093d	2	24	a	a	DET
2n49t15093d	2	25	new	new	ADJ
2n49t15093d	2	26	synthesis	synthesis	NOUN
2n49t15093d	2	27	of	of	ADP
2n49t15093d	2	28	imidazoles	imidazole	NOUN
2n49t15093d	2	29	.	.	PUNCT
2n49t15093d	3	1	the	the	DET
2n49t15093d	3	2	second	second	ADJ
2n49t15093d	3	3	main	main	ADJ
2n49t15093d	3	4	project	project	NOUN
2n49t15093d	3	5	involved	involve	VERB
2n49t15093d	3	6	developing	develop	VERB
2n49t15093d	3	7	new	new	ADJ
2n49t15093d	3	8	ways	way	NOUN
2n49t15093d	3	9	to	to	PART
2n49t15093d	3	10	use	use	VERB
2n49t15093d	3	11	acylnitroso	acylnitroso	PROPN
2n49t15093d	3	12	hda	hda	NOUN
2n49t15093d	3	13	cycloadducts	cycloadduct	NOUN
2n49t15093d	3	14	to	to	PART
2n49t15093d	3	15	synthesize	synthesize	VERB
2n49t15093d	3	16	biologically	biologically	ADV
2n49t15093d	3	17	useful	useful	ADJ
2n49t15093d	3	18	heterocyclic	heterocyclic	NOUN
2n49t15093d	3	19	molecules	molecule	NOUN
2n49t15093d	3	20	.	.	PUNCT
2n49t15093d	4	1	in	in	ADP
2n49t15093d	4	2	chapter	chapter	NOUN
2n49t15093d	4	3	2	2	NUM
2n49t15093d	4	4	,	,	PUNCT
2n49t15093d	4	5	the	the	DET
2n49t15093d	4	6	rationale	rationale	NOUN
2n49t15093d	4	7	behind	behind	ADP
2n49t15093d	4	8	the	the	DET
2n49t15093d	4	9	synthesis	synthesis	NOUN
2n49t15093d	4	10	of	of	ADP
2n49t15093d	4	11	mycobactin	mycobactin	PROPN
2n49t15093d	4	12	analogs	analog	NOUN
2n49t15093d	4	13	was	be	AUX
2n49t15093d	4	14	described	describe	VERB
2n49t15093d	4	15	.	.	PUNCT
2n49t15093d	5	1	in	in	ADP
2n49t15093d	5	2	chapter	chapter	NOUN
2n49t15093d	5	3	3	3	NUM
2n49t15093d	5	4	,	,	PUNCT
2n49t15093d	5	5	the	the	DET
2n49t15093d	5	6	synthesis	synthesis	NOUN
2n49t15093d	5	7	of	of	ADP
2n49t15093d	5	8	mycobactin	mycobactin	PROPN
2n49t15093d	5	9	analog	analog	NOUN
2n49t15093d	5	10	fragments	fragment	NOUN
2n49t15093d	5	11	is	be	AUX
2n49t15093d	5	12	described	describe	VERB
2n49t15093d	5	13	from	from	ADP
2n49t15093d	5	14	amino	amino	ADJ
2n49t15093d	5	15	acids	acid	NOUN
2n49t15093d	5	16	and	and	CCONJ
2n49t15093d	5	17	acylnitroso	acylnitroso	NOUN
2n49t15093d	5	18	hda	hda	NOUN
2n49t15093d	5	19	cycloadducts	cycloadduct	NOUN
2n49t15093d	5	20	.	.	PUNCT
2n49t15093d	6	1	chapter	chapter	NOUN
2n49t15093d	6	2	4	4	NUM
2n49t15093d	6	3	described	describe	VERB
2n49t15093d	6	4	the	the	DET
2n49t15093d	6	5	assembly	assembly	NOUN
2n49t15093d	6	6	of	of	ADP
2n49t15093d	6	7	mycobactin	mycobactin	PROPN
2n49t15093d	6	8	analog	analog	NOUN
2n49t15093d	6	9	fragments	fragment	NOUN
2n49t15093d	6	10	into	into	ADP
2n49t15093d	6	11	fully	fully	ADV
2n49t15093d	6	12	elaborated	elaborate	VERB
2n49t15093d	6	13	and	and	CCONJ
2n49t15093d	6	14	deprotected	deprotecte	VERB
2n49t15093d	6	15	1,2	1,2	NUM
2n49t15093d	6	16	-	-	PUNCT
2n49t15093d	6	17	diol	diol	NOUN
2n49t15093d	6	18	-	-	PUNCT
2n49t15093d	6	19	containing	contain	VERB
2n49t15093d	6	20	mycobactin	mycobactin	PROPN
2n49t15093d	6	21	analogs	analog	NOUN
2n49t15093d	6	22	.	.	PUNCT
2n49t15093d	7	1	general	general	ADJ
2n49t15093d	7	2	strategies	strategy	NOUN
2n49t15093d	7	3	toward	toward	ADP
2n49t15093d	7	4	the	the	DET
2n49t15093d	7	5	synthesis	synthesis	NOUN
2n49t15093d	7	6	of	of	ADP
2n49t15093d	7	7	&	&	CCONJ
2n49t15093d	7	8	#	#	SYM
2n49t15093d	7	9	945;-hydroxy	945;-hydroxy	NUM
2n49t15093d	7	10	carboxylate	carboxylate	NOUN
2n49t15093d	7	11	-	-	PUNCT
2n49t15093d	7	12	containing	contain	VERB
2n49t15093d	7	13	mycobactin	mycobactin	PROPN
2n49t15093d	7	14	analogs	analog	NOUN
2n49t15093d	7	15	were	be	AUX
2n49t15093d	7	16	also	also	ADV
2n49t15093d	7	17	presented	present	VERB
2n49t15093d	7	18	as	as	ADV
2n49t15093d	7	19	well	well	ADV
2n49t15093d	7	20	as	as	ADP
2n49t15093d	7	21	interesting	interesting	ADJ
2n49t15093d	7	22	results	result	NOUN
2n49t15093d	7	23	from	from	ADP
2n49t15093d	7	24	biological	biological	ADJ
2n49t15093d	7	25	assays	assay	NOUN
2n49t15093d	7	26	on	on	ADP
2n49t15093d	7	27	final	final	ADJ
2n49t15093d	7	28	molecules	molecule	NOUN
2n49t15093d	7	29	and	and	CCONJ
2n49t15093d	7	30	intermediates	intermediate	NOUN
2n49t15093d	7	31	.	.	PUNCT
2n49t15093d	8	1	in	in	ADP
2n49t15093d	8	2	chapter	chapter	NOUN
2n49t15093d	8	3	5	5	NUM
2n49t15093d	8	4	,	,	PUNCT
2n49t15093d	8	5	the	the	DET
2n49t15093d	8	6	discovery	discovery	NOUN
2n49t15093d	8	7	of	of	ADP
2n49t15093d	8	8	a	a	DET
2n49t15093d	8	9	new	new	ADJ
2n49t15093d	8	10	method	method	NOUN
2n49t15093d	8	11	for	for	ADP
2n49t15093d	8	12	synthesizing	synthesize	VERB
2n49t15093d	8	13	imidazole	imidazole	NOUN
2n49t15093d	8	14	analogs	analog	NOUN
2n49t15093d	8	15	of	of	ADP
2n49t15093d	8	16	mycobactin	mycobactin	PROPN
2n49t15093d	8	17	fragments	fragment	NOUN
2n49t15093d	8	18	from	from	ADP
2n49t15093d	8	19	azides	azide	NOUN
2n49t15093d	8	20	and	and	CCONJ
2n49t15093d	8	21	2	2	NUM
2n49t15093d	8	22	-	-	PUNCT
2n49t15093d	8	23	amidoacrylates	amidoacrylate	NOUN
2n49t15093d	8	24	was	be	AUX
2n49t15093d	8	25	described	describe	VERB
2n49t15093d	8	26	.	.	PUNCT
2n49t15093d	9	1	the	the	DET
2n49t15093d	9	2	initial	initial	ADJ
2n49t15093d	9	3	reaction	reaction	NOUN
2n49t15093d	9	4	,	,	PUNCT
2n49t15093d	9	5	optimization	optimization	NOUN
2n49t15093d	9	6	of	of	ADP
2n49t15093d	9	7	reaction	reaction	NOUN
2n49t15093d	9	8	conditions	condition	NOUN
2n49t15093d	9	9	,	,	PUNCT
2n49t15093d	9	10	and	and	CCONJ
2n49t15093d	9	11	a	a	DET
2n49t15093d	9	12	limited	limited	ADJ
2n49t15093d	9	13	study	study	NOUN
2n49t15093d	9	14	of	of	ADP
2n49t15093d	9	15	reaction	reaction	NOUN
2n49t15093d	9	16	scope	scope	NOUN
2n49t15093d	9	17	was	be	AUX
2n49t15093d	9	18	presented	present	VERB
2n49t15093d	9	19	as	as	ADV
2n49t15093d	9	20	well	well	ADV
2n49t15093d	9	21	as	as	ADP
2n49t15093d	9	22	the	the	DET
2n49t15093d	9	23	results	result	NOUN
2n49t15093d	9	24	of	of	ADP
2n49t15093d	9	25	biological	biological	ADJ
2n49t15093d	9	26	assays	assay	NOUN
2n49t15093d	9	27	performed	perform	VERB
2n49t15093d	9	28	on	on	ADP
2n49t15093d	9	29	selected	select	VERB
2n49t15093d	9	30	intermediates	intermediate	NOUN
2n49t15093d	9	31	.	.	PUNCT
2n49t15093d	10	1	this	this	DET
2n49t15093d	10	2	discovery	discovery	NOUN
2n49t15093d	10	3	provided	provide	VERB
2n49t15093d	10	4	a	a	DET
2n49t15093d	10	5	new	new	ADJ
2n49t15093d	10	6	method	method	NOUN
2n49t15093d	10	7	for	for	ADP
2n49t15093d	10	8	synthesizing	synthesize	VERB
2n49t15093d	10	9	imidazole	imidazole	NOUN
2n49t15093d	10	10	-	-	PUNCT
2n49t15093d	10	11	containing	contain	VERB
2n49t15093d	10	12	mycobactin	mycobactin	PROPN
2n49t15093d	10	13	analogs	analog	NOUN
2n49t15093d	10	14	as	as	ADV
2n49t15093d	10	15	well	well	ADV
2n49t15093d	10	16	as	as	ADP
2n49t15093d	10	17	a	a	DET
2n49t15093d	10	18	general	general	ADJ
2n49t15093d	10	19	method	method	NOUN
2n49t15093d	10	20	for	for	ADP
2n49t15093d	10	21	preparing	prepare	VERB
2n49t15093d	10	22	1	1	NUM
2n49t15093d	10	23	-	-	PUNCT
2n49t15093d	10	24	substitutedand	substitutedand	PROPN
2n49t15093d	10	25	1,2	1,2	PROPN
2n49t15093d	10	26	-	-	PUNCT
2n49t15093d	10	27	disubstituted	disubstitute	VERB
2n49t15093d	10	28	-	-	PUNCT
2n49t15093d	10	29	imidazole-4	imidazole-4	NOUN
2n49t15093d	10	30	-	-	PUNCT
2n49t15093d	10	31	carboxylates	carboxylate	NOUN
2n49t15093d	10	32	in	in	ADP
2n49t15093d	10	33	three	three	NUM
2n49t15093d	10	34	steps	step	NOUN
2n49t15093d	10	35	from	from	ADP
2n49t15093d	10	36	serine	serine	NOUN
2n49t15093d	10	37	,	,	PUNCT
2n49t15093d	10	38	carboxylic	carboxylic	ADJ
2n49t15093d	10	39	acids	acid	NOUN
2n49t15093d	10	40	,	,	PUNCT
2n49t15093d	10	41	and	and	CCONJ
2n49t15093d	10	42	azides	azide	NOUN
2n49t15093d	10	43	.	.	PUNCT
2n49t15093d	11	1	chapter	chapter	NOUN
2n49t15093d	11	2	6	6	NUM
2n49t15093d	11	3	described	describe	VERB
2n49t15093d	11	4	the	the	DET
2n49t15093d	11	5	development	development	NOUN
2n49t15093d	11	6	of	of	ADP
2n49t15093d	11	7	the	the	DET
2n49t15093d	11	8	addition	addition	NOUN
2n49t15093d	11	9	of	of	ADP
2n49t15093d	11	10	azides	azide	NOUN
2n49t15093d	11	11	to	to	PART
2n49t15093d	11	12	acylnitroso	acylnitroso	PROPN
2n49t15093d	11	13	hda	hda	NOUN
2n49t15093d	11	14	cycloadducts	cycloadduct	NOUN
2n49t15093d	11	15	and	and	CCONJ
2n49t15093d	11	16	the	the	DET
2n49t15093d	11	17	effect	effect	NOUN
2n49t15093d	11	18	of	of	ADP
2n49t15093d	11	19	alkene	alkene	NOUN
2n49t15093d	11	20	strain	strain	NOUN
2n49t15093d	11	21	on	on	ADP
2n49t15093d	11	22	reactivity	reactivity	NOUN
2n49t15093d	11	23	.	.	PUNCT
2n49t15093d	12	1	the	the	DET
2n49t15093d	12	2	scope	scope	NOUN
2n49t15093d	12	3	of	of	ADP
2n49t15093d	12	4	the	the	DET
2n49t15093d	12	5	reaction	reaction	NOUN
2n49t15093d	12	6	was	be	AUX
2n49t15093d	12	7	investigated	investigate	VERB
2n49t15093d	12	8	as	as	ADV
2n49t15093d	12	9	well	well	ADV
2n49t15093d	12	10	as	as	ADP
2n49t15093d	12	11	conversion	conversion	NOUN
2n49t15093d	12	12	of	of	ADP
2n49t15093d	12	13	the	the	DET
2n49t15093d	12	14	triazoline	triazoline	ADJ
2n49t15093d	12	15	products	product	NOUN
2n49t15093d	12	16	to	to	ADP
2n49t15093d	12	17	aziridines	aziridine	NOUN
2n49t15093d	12	18	.	.	PUNCT
2n49t15093d	13	1	the	the	DET
2n49t15093d	13	2	significance	significance	NOUN
2n49t15093d	13	3	of	of	ADP
2n49t15093d	13	4	this	this	DET
2n49t15093d	13	5	research	research	NOUN
2n49t15093d	13	6	as	as	SCONJ
2n49t15093d	13	7	it	it	PRON
2n49t15093d	13	8	related	relate	VERB
2n49t15093d	13	9	to	to	ADP
2n49t15093d	13	10	the	the	DET
2n49t15093d	13	11	synthesis	synthesis	NOUN
2n49t15093d	13	12	of	of	ADP
2n49t15093d	13	13	aziridineand	aziridineand	NOUN
2n49t15093d	13	14	triazoline	triazoline	NOUN
2n49t15093d	13	15	-	-	PUNCT
2n49t15093d	13	16	containing	contain	VERB
2n49t15093d	13	17	5'-norcarbocyclic	5'-norcarbocyclic	NUM
2n49t15093d	13	18	nucleosides	nucleoside	NOUN
2n49t15093d	13	19	and	and	CCONJ
2n49t15093d	13	20	bioconjugation	bioconjugation	NOUN
2n49t15093d	13	21	chemistry	chemistry	NOUN
2n49t15093d	13	22	was	be	AUX
2n49t15093d	13	23	also	also	ADV
2n49t15093d	13	24	described	describe	VERB
2n49t15093d	13	25	.	.	PUNCT
2n49t15093d	14	1	in	in	ADP
2n49t15093d	14	2	chapter	chapter	NOUN
2n49t15093d	14	3	7	7	NUM
2n49t15093d	14	4	,	,	PUNCT
2n49t15093d	14	5	other	other	ADJ
2n49t15093d	14	6	ways	way	NOUN
2n49t15093d	14	7	of	of	ADP
2n49t15093d	14	8	utilizing	utilize	VERB
2n49t15093d	14	9	the	the	DET
2n49t15093d	14	10	acylnitroso	acylnitroso	NOUN
2n49t15093d	14	11	hda	hda	NOUN
2n49t15093d	14	12	reaction	reaction	NOUN
2n49t15093d	14	13	were	be	AUX
2n49t15093d	14	14	investigated	investigate	VERB
2n49t15093d	14	15	.	.	PUNCT
2n49t15093d	15	1	preliminary	preliminary	ADJ
2n49t15093d	15	2	results	result	NOUN
2n49t15093d	15	3	on	on	ADP
2n49t15093d	15	4	addition	addition	NOUN
2n49t15093d	15	5	of	of	ADP
2n49t15093d	15	6	diazoalkanes	diazoalkane	NOUN
2n49t15093d	15	7	to	to	ADP
2n49t15093d	15	8	cycloadducts	cycloadduct	NOUN
2n49t15093d	15	9	,	,	PUNCT
2n49t15093d	15	10	brønsted	brønste	VERB
2n49t15093d	15	11	acid	acid	NOUN
2n49t15093d	15	12	-	-	PUNCT
2n49t15093d	15	13	catalyzed	catalyze	VERB
2n49t15093d	15	14	opening	opening	NOUN
2n49t15093d	15	15	of	of	ADP
2n49t15093d	15	16	cycloadducts	cycloadduct	NOUN
2n49t15093d	15	17	,	,	PUNCT
2n49t15093d	15	18	acylnitroso	acylnitroso	PROPN
2n49t15093d	16	1	[	[	X
2n49t15093d	16	2	2	2	NUM
2n49t15093d	16	3	+	+	NUM
2n49t15093d	16	4	2	2	NUM
2n49t15093d	16	5	+	+	NUM
2n49t15093d	16	6	2	2	NUM
2n49t15093d	16	7	]	]	PUNCT
2n49t15093d	16	8	homo	homo	ADJ
2n49t15093d	16	9	-	-	PUNCT
2n49t15093d	16	10	diels	diel	NOUN
2n49t15093d	16	11	-	-	PUNCT
2n49t15093d	16	12	alder	alder	NOUN
2n49t15093d	16	13	reactions	reaction	NOUN
2n49t15093d	16	14	,	,	PUNCT
2n49t15093d	16	15	and	and	CCONJ
2n49t15093d	16	16	acylnitroso	acylnitroso	NOUN
2n49t15093d	16	17	cycloadditions	cycloaddition	NOUN
2n49t15093d	16	18	to	to	PART
2n49t15093d	16	19	indole	indole	VERB
2n49t15093d	16	20	ortho	ortho	PROPN
2n49t15093d	16	21	-	-	PUNCT
2n49t15093d	16	22	quinodimethanes	quinodimethane	NOUN
2n49t15093d	16	23	were	be	AUX
2n49t15093d	16	24	presented	present	VERB
2n49t15093d	16	25	.	.	PUNCT
2n49t15093d	17	1	a	a	DET
2n49t15093d	17	2	discussion	discussion	NOUN
2n49t15093d	17	3	of	of	ADP
2n49t15093d	17	4	their	their	PRON
2n49t15093d	17	5	significance	significance	NOUN
2n49t15093d	17	6	toward	toward	ADP
2n49t15093d	17	7	the	the	DET
2n49t15093d	17	8	synthesis	synthesis	NOUN
2n49t15093d	17	9	of	of	ADP
2n49t15093d	17	10	biologically	biologically	ADV
2n49t15093d	17	11	useful	useful	ADJ
2n49t15093d	17	12	molecules	molecule	NOUN
2n49t15093d	17	13	was	be	AUX
2n49t15093d	17	14	also	also	ADV
2n49t15093d	17	15	included	include	VERB
2n49t15093d	17	16	.	.	PUNCT