id sid tid token lemma pos 1831cj84c2c 1 1 this this DET 1831cj84c2c 1 2 thesis thesis NOUN 1831cj84c2c 1 3 describes describe VERB 1831cj84c2c 1 4 studies study NOUN 1831cj84c2c 1 5 of of ADP 1831cj84c2c 1 6 rotaxanes rotaxane NOUN 1831cj84c2c 1 7 which which PRON 1831cj84c2c 1 8 are be AUX 1831cj84c2c 1 9 interlocked interlocked ADJ 1831cj84c2c 1 10 molecules molecule NOUN 1831cj84c2c 1 11 with with ADP 1831cj84c2c 1 12 a a DET 1831cj84c2c 1 13 dumbbell dumbbell NOUN 1831cj84c2c 1 14 shaped shape VERB 1831cj84c2c 1 15 thread thread NOUN 1831cj84c2c 1 16 component component NOUN 1831cj84c2c 1 17 surrounded surround VERB 1831cj84c2c 1 18 by by ADP 1831cj84c2c 1 19 a a DET 1831cj84c2c 1 20 macrocycle macrocycle NOUN 1831cj84c2c 1 21 . . PUNCT 1831cj84c2c 2 1 the the DET 1831cj84c2c 2 2 macrocycle macrocycle NOUN 1831cj84c2c 2 3 pirouetting pirouette VERB 1831cj84c2c 2 4 motion motion NOUN 1831cj84c2c 2 5 in in ADP 1831cj84c2c 2 6 xanthone xanthone PROPN 1831cj84c2c 2 7 rotaxanes rotaxanes PROPN 1831cj84c2c 2 8 was be AUX 1831cj84c2c 2 9 studied study VERB 1831cj84c2c 2 10 using use VERB 1831cj84c2c 2 11 variable variable ADJ 1831cj84c2c 2 12 temperature temperature NOUN 1831cj84c2c 2 13 nmr nmr NOUN 1831cj84c2c 2 14 . . PUNCT 1831cj84c2c 3 1 the the DET 1831cj84c2c 3 2 surrounding surround VERB 1831cj84c2c 3 3 tetralactam tetralactam NOUN 1831cj84c2c 3 4 macrocycle macrocycle NOUN 1831cj84c2c 3 5 contained contain VERB 1831cj84c2c 3 6 either either PRON 1831cj84c2c 3 7 2,6 2,6 NOUN 1831cj84c2c 3 8 - - PUNCT 1831cj84c2c 3 9 pyridine pyridine NOUN 1831cj84c2c 3 10 dicarboxamide dicarboxamide NOUN 1831cj84c2c 3 11 or or CCONJ 1831cj84c2c 3 12 isophthalamide isophthalamide ADP 1831cj84c2c 3 13 bridging bridge VERB 1831cj84c2c 3 14 units unit NOUN 1831cj84c2c 3 15 . . PUNCT 1831cj84c2c 4 1 rotaxanes rotaxane NOUN 1831cj84c2c 4 2 with with ADP 1831cj84c2c 4 3 macrocycle macrocycle NOUN 1831cj84c2c 4 4 containing contain VERB 1831cj84c2c 4 5 2,6 2,6 NUM 1831cj84c2c 4 6 - - PUNCT 1831cj84c2c 4 7 pyridine pyridine ADJ 1831cj84c2c 4 8 dicarboxamide dicarboxamide NOUN 1831cj84c2c 4 9 bridges bridge NOUN 1831cj84c2c 4 10 exhibited exhibit VERB 1831cj84c2c 4 11 higher high ADJ 1831cj84c2c 4 12 rotational rotational ADJ 1831cj84c2c 4 13 barriers barrier NOUN 1831cj84c2c 4 14 due due ADP 1831cj84c2c 4 15 to to ADP 1831cj84c2c 4 16 a a DET 1831cj84c2c 4 17 cavity cavity NOUN 1831cj84c2c 4 18 contraction contraction NOUN 1831cj84c2c 4 19 effect effect NOUN 1831cj84c2c 4 20 which which PRON 1831cj84c2c 4 21 disfavors disfavor NOUN 1831cj84c2c 4 22 macrocycle macrocycle NOUN 1831cj84c2c 4 23 breathing breathing NOUN 1831cj84c2c 4 24 . . PUNCT 1831cj84c2c 5 1 chapter chapter NOUN 1831cj84c2c 5 2 two two NUM 1831cj84c2c 5 3 discusses discuss VERB 1831cj84c2c 5 4 the the DET 1831cj84c2c 5 5 influence influence NOUN 1831cj84c2c 5 6 of of ADP 1831cj84c2c 5 7 metal metal NOUN 1831cj84c2c 5 8 cation cation NOUN 1831cj84c2c 5 9 binding bind VERB 1831cj84c2c 5 10 to to ADP 1831cj84c2c 5 11 a a DET 1831cj84c2c 5 12 squaraine squaraine ADJ 1831cj84c2c 5 13 rotaxane rotaxane NOUN 1831cj84c2c 5 14 endoperoxide endoperoxide NOUN 1831cj84c2c 5 15 with with ADP 1831cj84c2c 5 16 a a DET 1831cj84c2c 5 17 2,2'dipicolylamine 2,2'dipicolylamine NUM 1831cj84c2c 5 18 stopper stopper NOUN 1831cj84c2c 5 19 group group NOUN 1831cj84c2c 5 20 . . PUNCT 1831cj84c2c 6 1 metal metal NOUN 1831cj84c2c 6 2 cations cation NOUN 1831cj84c2c 6 3 bind bind VERB 1831cj84c2c 6 4 strongly strongly ADV 1831cj84c2c 6 5 and and CCONJ 1831cj84c2c 6 6 decrease decrease VERB 1831cj84c2c 6 7 the the DET 1831cj84c2c 6 8 rate rate NOUN 1831cj84c2c 6 9 of of ADP 1831cj84c2c 6 10 singlet singlet ADJ 1831cj84c2c 6 11 oxygen oxygen NOUN 1831cj84c2c 6 12 release release NOUN 1831cj84c2c 6 13 due due ADP 1831cj84c2c 6 14 to to ADP 1831cj84c2c 6 15 cycloreversion cycloreversion NOUN 1831cj84c2c 6 16 by by ADP 1831cj84c2c 6 17 about about ADV 1831cj84c2c 6 18 a a DET 1831cj84c2c 6 19 factor factor NOUN 1831cj84c2c 6 20 of of ADP 1831cj84c2c 6 21 two two NUM 1831cj84c2c 6 22 . . PUNCT 1831cj84c2c 7 1 binding bind VERB 1831cj84c2c 7 2 of of ADP 1831cj84c2c 7 3 feå_⁺ feå_⁺ ADJ 1831cj84c2c 7 4 ; ; PUNCT 1831cj84c2c 7 5 induced induce VERB 1831cj84c2c 7 6 fenton fenton NOUN 1831cj84c2c 7 7 - - PUNCT 1831cj84c2c 7 8 type type NOUN 1831cj84c2c 7 9 reaction reaction NOUN 1831cj84c2c 7 10 with with ADP 1831cj84c2c 7 11 endoperoxide endoperoxide NOUN 1831cj84c2c 7 12 , , PUNCT 1831cj84c2c 7 13 causing cause VERB 1831cj84c2c 7 14 the the DET 1831cj84c2c 7 15 macrocycle macrocycle NOUN 1831cj84c2c 7 16 cleavage cleavage NOUN 1831cj84c2c 7 17 and and CCONJ 1831cj84c2c 7 18 desctruction desctruction NOUN 1831cj84c2c 7 19 of of ADP 1831cj84c2c 7 20 the the DET 1831cj84c2c 7 21 rotaxane rotaxane NOUN 1831cj84c2c 7 22 molecule molecule NOUN 1831cj84c2c 7 23 . . PUNCT 1831cj84c2c 8 1 chapter chapter NOUN 1831cj84c2c 8 2 three three NUM 1831cj84c2c 8 3 describes describe VERB 1831cj84c2c 8 4 experiments experiment NOUN 1831cj84c2c 8 5 that that PRON 1831cj84c2c 8 6 help help VERB 1831cj84c2c 8 7 elucidate elucidate VERB 1831cj84c2c 8 8 the the DET 1831cj84c2c 8 9 mechanisms mechanism NOUN 1831cj84c2c 8 10 for for ADP 1831cj84c2c 8 11 the the DET 1831cj84c2c 8 12 chemiluminescence chemiluminescence NOUN 1831cj84c2c 8 13 , , PUNCT 1831cj84c2c 8 14 and and CCONJ 1831cj84c2c 8 15 highlight highlight VERB 1831cj84c2c 8 16 the the DET 1831cj84c2c 8 17 key key ADJ 1831cj84c2c 8 18 role role NOUN 1831cj84c2c 8 19 of of ADP 1831cj84c2c 8 20 singlet singlet ADJ 1831cj84c2c 8 21 oxygen oxygen NOUN 1831cj84c2c 8 22 as as ADP 1831cj84c2c 8 23 a a DET 1831cj84c2c 8 24 mediator mediator NOUN 1831cj84c2c 8 25 of of ADP 1831cj84c2c 8 26 energy energy NOUN 1831cj84c2c 8 27 transfer transfer NOUN 1831cj84c2c 8 28 to to ADP 1831cj84c2c 8 29 the the DET 1831cj84c2c 8 30 encapsulated encapsulate VERB 1831cj84c2c 8 31 squaraine squaraine ADJ 1831cj84c2c 8 32 dye dye NOUN 1831cj84c2c 8 33 . . PUNCT