id sid tid token lemma pos 0z708w35q8s 1 1 amine amine ADJ 0z708w35q8s 1 2 functional functional ADJ 0z708w35q8s 1 3 groups group NOUN 0z708w35q8s 1 4 in in ADP 0z708w35q8s 1 5 polymeric polymeric ADJ 0z708w35q8s 1 6 facilitated facilitated ADJ 0z708w35q8s 1 7 transport transport NOUN 0z708w35q8s 1 8 membranes membrane NOUN 0z708w35q8s 1 9 ( ( PUNCT 0z708w35q8s 1 10 ftms ftms PROPN 0z708w35q8s 1 11 ) ) PUNCT 0z708w35q8s 1 12 selectively selectively ADV 0z708w35q8s 1 13 and and CCONJ 0z708w35q8s 1 14 reversibly reversibly ADV 0z708w35q8s 1 15 facilitate facilitate VERB 0z708w35q8s 1 16 the the DET 0z708w35q8s 1 17 transport transport NOUN 0z708w35q8s 1 18 of of ADP 0z708w35q8s 1 19 co2 co2 NOUN 0z708w35q8s 1 20 over over ADP 0z708w35q8s 1 21 other other ADJ 0z708w35q8s 1 22 gases gas NOUN 0z708w35q8s 1 23 , , PUNCT 0z708w35q8s 1 24 which which PRON 0z708w35q8s 1 25 results result VERB 0z708w35q8s 1 26 in in ADP 0z708w35q8s 1 27 rapid rapid ADJ 0z708w35q8s 1 28 and and CCONJ 0z708w35q8s 1 29 selective selective ADJ 0z708w35q8s 1 30 co2 co2 NOUN 0z708w35q8s 1 31 separation separation NOUN 0z708w35q8s 1 32 from from ADP 0z708w35q8s 1 33 mixed mixed ADJ 0z708w35q8s 1 34 gas gas NOUN 0z708w35q8s 1 35 streams stream NOUN 0z708w35q8s 1 36 , , PUNCT 0z708w35q8s 1 37 such such ADJ 0z708w35q8s 1 38 as as ADP 0z708w35q8s 1 39 co2 co2 PROPN 0z708w35q8s 1 40 / / SYM 0z708w35q8s 1 41 n2 n2 PROPN 0z708w35q8s 1 42 . . PUNCT 0z708w35q8s 2 1 however however ADV 0z708w35q8s 2 2 , , PUNCT 0z708w35q8s 2 3 the the DET 0z708w35q8s 2 4 mechanisms mechanism NOUN 0z708w35q8s 2 5 of of ADP 0z708w35q8s 2 6 co2 co2 NOUN 0z708w35q8s 2 7 transport transport NOUN 0z708w35q8s 2 8 by by ADP 0z708w35q8s 2 9 amine amine ADJ 0z708w35q8s 2 10 functional functional ADJ 0z708w35q8s 2 11 groups group NOUN 0z708w35q8s 2 12 across across ADP 0z708w35q8s 2 13 membranes membrane NOUN 0z708w35q8s 2 14 are be AUX 0z708w35q8s 2 15 not not PART 0z708w35q8s 2 16 well well ADV 0z708w35q8s 2 17 understood understand VERB 0z708w35q8s 2 18 . . PUNCT 0z708w35q8s 3 1 water water NOUN 0z708w35q8s 3 2 vapor vapor NOUN 0z708w35q8s 3 3 is be AUX 0z708w35q8s 3 4 known know VERB 0z708w35q8s 3 5 to to PART 0z708w35q8s 3 6 enhance enhance VERB 0z708w35q8s 3 7 co2 co2 NOUN 0z708w35q8s 3 8 permeation permeation NOUN 0z708w35q8s 3 9 rates rate NOUN 0z708w35q8s 3 10 through through ADP 0z708w35q8s 3 11 amine amine NOUN 0z708w35q8s 3 12 - - PUNCT 0z708w35q8s 3 13 functionalized functionalize VERB 0z708w35q8s 3 14 polymeric polymeric ADJ 0z708w35q8s 3 15 membranes membrane NOUN 0z708w35q8s 3 16 ; ; PUNCT 0z708w35q8s 3 17 however however ADV 0z708w35q8s 3 18 , , PUNCT 0z708w35q8s 3 19 it it PRON 0z708w35q8s 3 20 is be AUX 0z708w35q8s 3 21 unclear unclear ADJ 0z708w35q8s 3 22 how how SCONJ 0z708w35q8s 3 23 exactly exactly ADV 0z708w35q8s 3 24 water water NOUN 0z708w35q8s 3 25 influences influence VERB 0z708w35q8s 3 26 the the DET 0z708w35q8s 3 27 co2 co2 NOUN 0z708w35q8s 3 28 transport transport NOUN 0z708w35q8s 3 29 . . PUNCT 0z708w35q8s 4 1 to to PART 0z708w35q8s 4 2 address address VERB 0z708w35q8s 4 3 the the DET 0z708w35q8s 4 4 fundamental fundamental ADJ 0z708w35q8s 4 5 issues issue NOUN 0z708w35q8s 4 6 of of ADP 0z708w35q8s 4 7 co2 co2 PROPN 0z708w35q8s 4 8 facilitated facilitated ADJ 0z708w35q8s 4 9 transport transport NOUN 0z708w35q8s 4 10 , , PUNCT 0z708w35q8s 4 11 we we PRON 0z708w35q8s 4 12 have have AUX 0z708w35q8s 4 13 developed develop VERB 0z708w35q8s 4 14 a a DET 0z708w35q8s 4 15 novel novel ADJ 0z708w35q8s 4 16 operando operando NOUN 0z708w35q8s 4 17 transmission transmission NOUN 0z708w35q8s 4 18 ftir ftir PROPN 0z708w35q8s 4 19 spectroscopic spectroscopic PROPN 0z708w35q8s 4 20 permeation permeation NOUN 0z708w35q8s 4 21 tool tool NOUN 0z708w35q8s 4 22 to to PART 0z708w35q8s 4 23 directly directly ADV 0z708w35q8s 4 24 observe observe VERB 0z708w35q8s 4 25 the the DET 0z708w35q8s 4 26 formation formation NOUN 0z708w35q8s 4 27 of of ADP 0z708w35q8s 4 28 co2 co2 NOUN 0z708w35q8s 4 29 transport transport NOUN 0z708w35q8s 4 30 intermediates intermediate VERB 0z708w35q8s 4 31 through through ADP 0z708w35q8s 4 32 amine amine NOUN 0z708w35q8s 4 33 - - PUNCT 0z708w35q8s 4 34 based base VERB 0z708w35q8s 4 35 ftms ftms NOUN 0z708w35q8s 4 36 under under ADP 0z708w35q8s 4 37 realistic realistic ADJ 0z708w35q8s 4 38 operating operating NOUN 0z708w35q8s 4 39 conditions condition NOUN 0z708w35q8s 4 40 , , PUNCT 0z708w35q8s 4 41 including include VERB 0z708w35q8s 4 42 dry dry ADJ 0z708w35q8s 4 43 and and CCONJ 0z708w35q8s 4 44 humid humid ADJ 0z708w35q8s 4 45 co2 co2 NOUN 0z708w35q8s 4 46 gas gas NOUN 0z708w35q8s 4 47 mixtures mixture NOUN 0z708w35q8s 4 48 , , PUNCT 0z708w35q8s 4 49 and and CCONJ 0z708w35q8s 4 50 simultaneously simultaneously ADV 0z708w35q8s 4 51 correlate correlate VERB 0z708w35q8s 4 52 the the DET 0z708w35q8s 4 53 formation formation NOUN 0z708w35q8s 4 54 of of ADP 0z708w35q8s 4 55 these these DET 0z708w35q8s 4 56 intermediate intermediate ADJ 0z708w35q8s 4 57 species specie NOUN 0z708w35q8s 4 58 with with ADP 0z708w35q8s 4 59 the the DET 0z708w35q8s 4 60 co2 co2 NOUN 0z708w35q8s 4 61 permeation permeation NOUN 0z708w35q8s 4 62 rates rate NOUN 0z708w35q8s 4 63 through through ADP 0z708w35q8s 4 64 the the DET 0z708w35q8s 4 65 same same ADJ 0z708w35q8s 4 66 sample sample NOUN 0z708w35q8s 4 67 . . PUNCT 0z708w35q8s 5 1 this this DET 0z708w35q8s 5 2 work work NOUN 0z708w35q8s 5 3 describes describe VERB 0z708w35q8s 5 4 the the DET 0z708w35q8s 5 5 development development NOUN 0z708w35q8s 5 6 of of ADP 0z708w35q8s 5 7 this this DET 0z708w35q8s 5 8 novel novel ADJ 0z708w35q8s 5 9 operando operando PROPN 0z708w35q8s 5 10 transmission transmission NOUN 0z708w35q8s 5 11 ftir ftir PROPN 0z708w35q8s 5 12 spectroscopic spectroscopic ADJ 0z708w35q8s 5 13 tool tool NOUN 0z708w35q8s 5 14 , , PUNCT 0z708w35q8s 5 15 and and CCONJ 0z708w35q8s 5 16 first first ADV 0z708w35q8s 5 17 demonstrates demonstrate VERB 0z708w35q8s 5 18 its its PRON 0z708w35q8s 5 19 utility utility NOUN 0z708w35q8s 5 20 by by ADP 0z708w35q8s 5 21 probing probe VERB 0z708w35q8s 5 22 the the DET 0z708w35q8s 5 23 mechanism mechanism NOUN 0z708w35q8s 5 24 of of ADP 0z708w35q8s 5 25 water water NOUN 0z708w35q8s 5 26 - - PUNCT 0z708w35q8s 5 27 enhanced enhance VERB 0z708w35q8s 5 28 co2 co2 NOUN 0z708w35q8s 5 29 transport transport NOUN 0z708w35q8s 5 30 through through ADP 0z708w35q8s 5 31 polyvinylamine polyvinylamine ADJ 0z708w35q8s 5 32 ( ( PUNCT 0z708w35q8s 5 33 pvam pvam PROPN 0z708w35q8s 5 34 ) ) PUNCT 0z708w35q8s 5 35 , , PUNCT 0z708w35q8s 5 36 a a DET 0z708w35q8s 5 37 model model NOUN 0z708w35q8s 5 38 primary primary ADJ 0z708w35q8s 5 39 amine amine NOUN 0z708w35q8s 5 40 that that PRON 0z708w35q8s 5 41 it it PRON 0z708w35q8s 5 42 a a DET 0z708w35q8s 5 43 typical typical ADJ 0z708w35q8s 5 44 ftm ftm NOUN 0z708w35q8s 5 45 used use VERB 0z708w35q8s 5 46 for for ADP 0z708w35q8s 5 47 co2 co2 NOUN 0z708w35q8s 5 48 separations separation NOUN 0z708w35q8s 5 49 . . PUNCT 0z708w35q8s 6 1 we we PRON 0z708w35q8s 6 2 show show VERB 0z708w35q8s 6 3 that that SCONJ 0z708w35q8s 6 4 water water NOUN 0z708w35q8s 6 5 enhances enhance VERB 0z708w35q8s 6 6 co2 co2 NOUN 0z708w35q8s 6 7 permeation permeation NOUN 0z708w35q8s 6 8 across across ADP 0z708w35q8s 6 9 pvam pvam ADJ 0z708w35q8s 6 10 by by ADP 0z708w35q8s 6 11 facilitating facilitate VERB 0z708w35q8s 6 12 the the DET 0z708w35q8s 6 13 conversion conversion NOUN 0z708w35q8s 6 14 of of ADP 0z708w35q8s 6 15 co2 co2 NOUN 0z708w35q8s 6 16 to to ADP 0z708w35q8s 6 17 a a DET 0z708w35q8s 6 18 reactive reactive ADJ 0z708w35q8s 6 19 intermediate intermediate NOUN 0z708w35q8s 6 20 , , PUNCT 0z708w35q8s 6 21 which which PRON 0z708w35q8s 6 22 is be AUX 0z708w35q8s 6 23 most most ADV 0z708w35q8s 6 24 consistent consistent ADJ 0z708w35q8s 6 25 with with ADP 0z708w35q8s 6 26 an an DET 0z708w35q8s 6 27 ammonium ammonium NOUN 0z708w35q8s 6 28 carbamate carbamate NOUN 0z708w35q8s 6 29 species specie NOUN 0z708w35q8s 6 30 based base VERB 0z708w35q8s 6 31 on on ADP 0z708w35q8s 6 32 the the DET 0z708w35q8s 6 33 infrared infrared ADJ 0z708w35q8s 6 34 band band NOUN 0z708w35q8s 6 35 positions position NOUN 0z708w35q8s 6 36 . . PUNCT 0z708w35q8s 7 1 to to PART 0z708w35q8s 7 2 further far ADV 0z708w35q8s 7 3 probe probe VERB 0z708w35q8s 7 4 the the DET 0z708w35q8s 7 5 fundamental fundamental ADJ 0z708w35q8s 7 6 issues issue NOUN 0z708w35q8s 7 7 of of ADP 0z708w35q8s 7 8 co2 co2 NOUN 0z708w35q8s 7 9 permeation permeation NOUN 0z708w35q8s 7 10 , , PUNCT 0z708w35q8s 7 11 we we PRON 0z708w35q8s 7 12 will will AUX 0z708w35q8s 7 13 study study VERB 0z708w35q8s 7 14 the the DET 0z708w35q8s 7 15 effect effect NOUN 0z708w35q8s 7 16 of of ADP 0z708w35q8s 7 17 water water NOUN 0z708w35q8s 7 18 - - PUNCT 0z708w35q8s 7 19 enhanced enhance VERB 0z708w35q8s 7 20 co2 co2 NOUN 0z708w35q8s 7 21 permeation permeation NOUN 0z708w35q8s 7 22 on on ADP 0z708w35q8s 7 23 poly(n poly(n PROPN 0z708w35q8s 7 24 - - PUNCT 0z708w35q8s 7 25 methyl methyl NOUN 0z708w35q8s 7 26 - - PUNCT 0z708w35q8s 7 27 n n NOUN 0z708w35q8s 7 28 - - PUNCT 0z708w35q8s 7 29 vinylamine vinylamine NOUN 0z708w35q8s 7 30 ) ) PUNCT 0z708w35q8s 7 31 ( ( PUNCT 0z708w35q8s 7 32 pmvam pmvam NOUN 0z708w35q8s 7 33 ) ) PUNCT 0z708w35q8s 7 34 , , PUNCT 0z708w35q8s 7 35 poly(n poly(n PROPN 0z708w35q8s 7 36 , , PUNCT 0z708w35q8s 7 37 n n NOUN 0z708w35q8s 7 38 - - PUNCT 0z708w35q8s 7 39 dimethyl dimethyl NOUN 0z708w35q8s 7 40 - - PUNCT 0z708w35q8s 7 41 n n NOUN 0z708w35q8s 7 42 - - PUNCT 0z708w35q8s 7 43 vinylamine vinylamine NOUN 0z708w35q8s 7 44 ) ) PUNCT 0z708w35q8s 7 45 ( ( PUNCT 0z708w35q8s 7 46 pdvam pdvam PROPN 0z708w35q8s 7 47 ) ) PUNCT 0z708w35q8s 7 48 , , PUNCT 0z708w35q8s 7 49 polyvinylpyridine polyvinylpyridine NOUN 0z708w35q8s 7 50 , , PUNCT 0z708w35q8s 7 51 and and CCONJ 0z708w35q8s 7 52 quaternized quaternize VERB 0z708w35q8s 7 53 polyvinylpyridine polyvinylpyridine NOUN 0z708w35q8s 7 54 materials material NOUN 0z708w35q8s 7 55 to to PART 0z708w35q8s 7 56 investigate investigate VERB 0z708w35q8s 7 57 the the DET 0z708w35q8s 7 58 effect effect NOUN 0z708w35q8s 7 59 of of ADP 0z708w35q8s 7 60 amine amine NOUN 0z708w35q8s 7 61 structure structure NOUN 0z708w35q8s 7 62 on on ADP 0z708w35q8s 7 63 co2 co2 NOUN 0z708w35q8s 7 64 transport transport NOUN 0z708w35q8s 7 65 through through ADP 0z708w35q8s 7 66 membranes membrane NOUN 0z708w35q8s 7 67 . . PUNCT 0z708w35q8s 8 1 next next ADV 0z708w35q8s 8 2 , , PUNCT 0z708w35q8s 8 3 we we PRON 0z708w35q8s 8 4 will will AUX 0z708w35q8s 8 5 further far ADV 0z708w35q8s 8 6 investigate investigate VERB 0z708w35q8s 8 7 how how SCONJ 0z708w35q8s 8 8 the the DET 0z708w35q8s 8 9 presence presence NOUN 0z708w35q8s 8 10 or or CCONJ 0z708w35q8s 8 11 absence absence NOUN 0z708w35q8s 8 12 of of ADP 0z708w35q8s 8 13 water water NOUN 0z708w35q8s 8 14 influences influence VERB 0z708w35q8s 8 15 co2 co2 NOUN 0z708w35q8s 8 16 transport transport NOUN 0z708w35q8s 8 17 through through ADP 0z708w35q8s 8 18 these these DET 0z708w35q8s 8 19 same same ADJ 0z708w35q8s 8 20 materials material NOUN 0z708w35q8s 8 21 through through ADP 0z708w35q8s 8 22 exposure exposure NOUN 0z708w35q8s 8 23 to to ADP 0z708w35q8s 8 24 dry dry VERB 0z708w35q8s 8 25 co2 co2 NOUN 0z708w35q8s 8 26 / / SYM 0z708w35q8s 8 27 n2 n2 PROPN 0z708w35q8s 8 28 and and CCONJ 0z708w35q8s 8 29 humid humid PROPN 0z708w35q8s 8 30 n2 n2 PROPN 0z708w35q8s 8 31 . . PUNCT 0z708w35q8s 9 1 these these DET 0z708w35q8s 9 2 investigations investigation NOUN 0z708w35q8s 9 3 allow allow VERB 0z708w35q8s 9 4 us we PRON 0z708w35q8s 9 5 to to PART 0z708w35q8s 9 6 clarify clarify VERB 0z708w35q8s 9 7 the the DET 0z708w35q8s 9 8 effect effect NOUN 0z708w35q8s 9 9 of of ADP 0z708w35q8s 9 10 amine amine ADJ 0z708w35q8s 9 11 structure structure NOUN 0z708w35q8s 9 12 and and CCONJ 0z708w35q8s 9 13 the the DET 0z708w35q8s 9 14 role role NOUN 0z708w35q8s 9 15 of of ADP 0z708w35q8s 9 16 water water NOUN 0z708w35q8s 9 17 for for ADP 0z708w35q8s 9 18 co2 co2 NOUN 0z708w35q8s 9 19 transport transport NOUN 0z708w35q8s 9 20 through through ADP 0z708w35q8s 9 21 amine amine NOUN 0z708w35q8s 9 22 - - PUNCT 0z708w35q8s 9 23 functionalized functionalize VERB 0z708w35q8s 9 24 membranes membrane NOUN 0z708w35q8s 9 25 , , PUNCT 0z708w35q8s 9 26 which which PRON 0z708w35q8s 9 27 ultimately ultimately ADV 0z708w35q8s 9 28 allows allow VERB 0z708w35q8s 9 29 us we PRON 0z708w35q8s 9 30 to to PART 0z708w35q8s 9 31 propose propose VERB 0z708w35q8s 9 32 new new ADJ 0z708w35q8s 9 33 co2 co2 NOUN 0z708w35q8s 9 34 transport transport NOUN 0z708w35q8s 9 35 mechanisms mechanism NOUN 0z708w35q8s 9 36 based base VERB 0z708w35q8s 9 37 on on ADP 0z708w35q8s 9 38 the the DET 0z708w35q8s 9 39 direct direct ADJ 0z708w35q8s 9 40 observation observation NOUN 0z708w35q8s 9 41 of of ADP 0z708w35q8s 9 42 intermediate intermediate ADJ 0z708w35q8s 9 43 species specie NOUN 0z708w35q8s 9 44 . . PUNCT 0z708w35q8s 10 1 this this DET 0z708w35q8s 10 2 work work NOUN 0z708w35q8s 10 3 establishes establish VERB 0z708w35q8s 10 4 a a DET 0z708w35q8s 10 5 novel novel ADJ 0z708w35q8s 10 6 operando operando NOUN 0z708w35q8s 10 7 spectroscopy spectroscopy NOUN 0z708w35q8s 10 8 tool tool NOUN 0z708w35q8s 10 9 that that PRON 0z708w35q8s 10 10 can can AUX 0z708w35q8s 10 11 be be AUX 0z708w35q8s 10 12 used use VERB 0z708w35q8s 10 13 to to PART 0z708w35q8s 10 14 further far ADV 0z708w35q8s 10 15 study study VERB 0z708w35q8s 10 16 a a DET 0z708w35q8s 10 17 wide wide ADJ 0z708w35q8s 10 18 range range NOUN 0z708w35q8s 10 19 of of ADP 0z708w35q8s 10 20 membrane membrane NOUN 0z708w35q8s 10 21 systems system NOUN 0z708w35q8s 10 22 to to PART 0z708w35q8s 10 23 probe probe VERB 0z708w35q8s 10 24 transport transport NOUN 0z708w35q8s 10 25 mechanisms mechanism NOUN 0z708w35q8s 10 26 , , PUNCT 0z708w35q8s 10 27 fouling foul VERB 0z708w35q8s 10 28 mechanisms mechanism NOUN 0z708w35q8s 10 29 , , PUNCT 0z708w35q8s 10 30 and and CCONJ 0z708w35q8s 10 31 correlate correlate VERB 0z708w35q8s 10 32 any any DET 0z708w35q8s 10 33 changes change NOUN 0z708w35q8s 10 34 in in ADP 0z708w35q8s 10 35 membrane membrane NOUN 0z708w35q8s 10 36 structure structure NOUN 0z708w35q8s 10 37 to to ADP 0z708w35q8s 10 38 its its PRON 0z708w35q8s 10 39 performance performance NOUN 0z708w35q8s 10 40 over over ADP 0z708w35q8s 10 41 time time NOUN 0z708w35q8s 10 42 . . PUNCT