id sid tid token lemma pos 0z708w34k1v 1 1 the the DET 0z708w34k1v 1 2 work work NOUN 0z708w34k1v 1 3 presented present VERB 0z708w34k1v 1 4 in in ADP 0z708w34k1v 1 5 this this DET 0z708w34k1v 1 6 dissertation dissertation NOUN 0z708w34k1v 1 7 is be AUX 0z708w34k1v 1 8 primarily primarily ADV 0z708w34k1v 1 9 focused focus VERB 0z708w34k1v 1 10 on on ADP 0z708w34k1v 1 11 the the DET 0z708w34k1v 1 12 synthesis synthesis NOUN 0z708w34k1v 1 13 and and CCONJ 0z708w34k1v 1 14 characterization characterization NOUN 0z708w34k1v 1 15 of of ADP 0z708w34k1v 1 16 thorium thorium NOUN 0z708w34k1v 1 17 and and CCONJ 0z708w34k1v 1 18 uranium uranium NOUN 0z708w34k1v 1 19 containing contain VERB 0z708w34k1v 1 20 coordination coordination NOUN 0z708w34k1v 1 21 polymers polymer NOUN 0z708w34k1v 1 22 using use VERB 0z708w34k1v 1 23 benzenediphosphonate benzenediphosphonate NOUN 0z708w34k1v 1 24 and and CCONJ 0z708w34k1v 1 25 carboxyphenylphosphonate carboxyphenylphosphonate VERB 0z708w34k1v 1 26 derivatives derivative NOUN 0z708w34k1v 1 27 as as ADP 0z708w34k1v 1 28 ligands ligand NOUN 0z708w34k1v 1 29 . . PUNCT 0z708w34k1v 2 1 i i PRON 0z708w34k1v 2 2 investigated investigate VERB 0z708w34k1v 2 3 three three NUM 0z708w34k1v 2 4 broad broad ADJ 0z708w34k1v 2 5 areas area NOUN 0z708w34k1v 2 6 of of ADP 0z708w34k1v 2 7 study study NOUN 0z708w34k1v 2 8 that that PRON 0z708w34k1v 2 9 determined determine VERB 0z708w34k1v 2 10 the the DET 0z708w34k1v 2 11 structural structural ADJ 0z708w34k1v 2 12 features feature NOUN 0z708w34k1v 2 13 and and CCONJ 0z708w34k1v 2 14 properties property NOUN 0z708w34k1v 2 15 of of ADP 0z708w34k1v 2 16 these these DET 0z708w34k1v 2 17 materials material NOUN 0z708w34k1v 2 18 as as SCONJ 0z708w34k1v 2 19 they they PRON 0z708w34k1v 2 20 apply apply VERB 0z708w34k1v 2 21 to to ADP 0z708w34k1v 2 22 sequestration sequestration NOUN 0z708w34k1v 2 23 and and CCONJ 0z708w34k1v 2 24 remediation remediation NOUN 0z708w34k1v 2 25 of of ADP 0z708w34k1v 2 26 actinide actinide ADJ 0z708w34k1v 2 27 waste waste NOUN 0z708w34k1v 2 28 and and CCONJ 0z708w34k1v 2 29 their their PRON 0z708w34k1v 2 30 potential potential ADJ 0z708w34k1v 2 31 material material NOUN 0z708w34k1v 2 32 applications application NOUN 0z708w34k1v 2 33 . . PUNCT 0z708w34k1v 3 1 the the DET 0z708w34k1v 3 2 first first ADJ 0z708w34k1v 3 3 area area NOUN 0z708w34k1v 3 4 of of ADP 0z708w34k1v 3 5 investigation investigation NOUN 0z708w34k1v 3 6 is be AUX 0z708w34k1v 3 7 concerned concern VERB 0z708w34k1v 3 8 with with ADP 0z708w34k1v 3 9 the the DET 0z708w34k1v 3 10 use use NOUN 0z708w34k1v 3 11 of of ADP 0z708w34k1v 3 12 structure structure NOUN 0z708w34k1v 3 13 directing direct VERB 0z708w34k1v 3 14 agents agent NOUN 0z708w34k1v 3 15 in in ADP 0z708w34k1v 3 16 the the DET 0z708w34k1v 3 17 assembly assembly NOUN 0z708w34k1v 3 18 of of ADP 0z708w34k1v 3 19 uranyl uranyl ADJ 0z708w34k1v 3 20 diphosphonate diphosphonate NOUN 0z708w34k1v 3 21 frameworks framework NOUN 0z708w34k1v 3 22 . . PUNCT 0z708w34k1v 4 1 this this DET 0z708w34k1v 4 2 work work NOUN 0z708w34k1v 4 3 which which PRON 0z708w34k1v 4 4 began begin VERB 0z708w34k1v 4 5 with with ADP 0z708w34k1v 4 6 simple simple ADJ 0z708w34k1v 4 7 templates template NOUN 0z708w34k1v 4 8 such such ADJ 0z708w34k1v 4 9 as as ADP 0z708w34k1v 4 10 organoammonium organoammonium NOUN 0z708w34k1v 4 11 cations cation NOUN 0z708w34k1v 4 12 , , PUNCT 0z708w34k1v 4 13 was be AUX 0z708w34k1v 4 14 later later ADV 0z708w34k1v 4 15 extended extend VERB 0z708w34k1v 4 16 to to ADP 0z708w34k1v 4 17 encapsulated encapsulate VERB 0z708w34k1v 4 18 cations cation NOUN 0z708w34k1v 4 19 , , PUNCT 0z708w34k1v 4 20 hydroniumand hydroniumand PROPN 0z708w34k1v 4 21 alkali alkali PROPN 0z708w34k1v 4 22 metal metal NOUN 0z708w34k1v 4 23 - - PUNCT 0z708w34k1v 4 24 crown crown NOUN 0z708w34k1v 4 25 ether ether NOUN 0z708w34k1v 4 26 inclusion inclusion NOUN 0z708w34k1v 4 27 complexes complex NOUN 0z708w34k1v 4 28 , , PUNCT 0z708w34k1v 4 29 and and CCONJ 0z708w34k1v 4 30 was be AUX 0z708w34k1v 4 31 concluded conclude VERB 0z708w34k1v 4 32 using use VERB 0z708w34k1v 4 33 alkali alkali ADJ 0z708w34k1v 4 34 metal metal NOUN 0z708w34k1v 4 35 ions ion NOUN 0z708w34k1v 4 36 . . PUNCT 0z708w34k1v 5 1 two two NUM 0z708w34k1v 5 2 elliptical elliptical ADJ 0z708w34k1v 5 3 uranyl uranyl NOUN 0z708w34k1v 5 4 nanotubules nanotubule NOUN 0z708w34k1v 5 5 were be AUX 0z708w34k1v 5 6 isolated isolate VERB 0z708w34k1v 5 7 along along ADP 0z708w34k1v 5 8 with with ADP 0z708w34k1v 5 9 other other ADJ 0z708w34k1v 5 10 series series NOUN 0z708w34k1v 5 11 of of ADP 0z708w34k1v 5 12 framework framework NOUN 0z708w34k1v 5 13 materials material NOUN 0z708w34k1v 5 14 with with ADP 0z708w34k1v 5 15 voids void NOUN 0z708w34k1v 5 16 that that PRON 0z708w34k1v 5 17 are be AUX 0z708w34k1v 5 18 filled fill VERB 0z708w34k1v 5 19 with with ADP 0z708w34k1v 5 20 alkali alkali ADJ 0z708w34k1v 5 21 metal metal NOUN 0z708w34k1v 5 22 cations cation NOUN 0z708w34k1v 5 23 and and CCONJ 0z708w34k1v 5 24 organic organic ADJ 0z708w34k1v 5 25 templates template NOUN 0z708w34k1v 5 26 respectively respectively ADV 0z708w34k1v 5 27 . . PUNCT 0z708w34k1v 6 1 i i PRON 0z708w34k1v 6 2 developed develop VERB 0z708w34k1v 6 3 the the DET 0z708w34k1v 6 4 first first ADJ 0z708w34k1v 6 5 highly highly ADV 0z708w34k1v 6 6 stable stable ADJ 0z708w34k1v 6 7 functional functional ADJ 0z708w34k1v 6 8 uranyl uranyl NOUN 0z708w34k1v 6 9 nanotubule nanotubule NOUN 0z708w34k1v 6 10 with with ADP 0z708w34k1v 6 11 exceptional exceptional ADJ 0z708w34k1v 6 12 ion ion NOUN 0z708w34k1v 6 13 - - PUNCT 0z708w34k1v 6 14 exchange exchange NOUN 0z708w34k1v 6 15 properties property NOUN 0z708w34k1v 6 16 towards towards ADP 0z708w34k1v 6 17 monovalent monovalent NOUN 0z708w34k1v 6 18 cations cation NOUN 0z708w34k1v 6 19 . . PUNCT 0z708w34k1v 7 1 the the DET 0z708w34k1v 7 2 second second ADJ 0z708w34k1v 7 3 area area NOUN 0z708w34k1v 7 4 of of ADP 0z708w34k1v 7 5 research research NOUN 0z708w34k1v 7 6 explores explore VERB 0z708w34k1v 7 7 the the DET 0z708w34k1v 7 8 structural structural ADJ 0z708w34k1v 7 9 features feature NOUN 0z708w34k1v 7 10 and and CCONJ 0z708w34k1v 7 11 trends trend NOUN 0z708w34k1v 7 12 in in ADP 0z708w34k1v 7 13 actinide actinide ADJ 0z708w34k1v 7 14 diphosphonates diphosphonate NOUN 0z708w34k1v 7 15 and and CCONJ 0z708w34k1v 7 16 carboxyphosphonates carboxyphosphonate NOUN 0z708w34k1v 7 17 as as ADP 0z708w34k1v 7 18 important important ADJ 0z708w34k1v 7 19 tools tool NOUN 0z708w34k1v 7 20 in in ADP 0z708w34k1v 7 21 understanding understand VERB 0z708w34k1v 7 22 how how SCONJ 0z708w34k1v 7 23 actinides actinide NOUN 0z708w34k1v 7 24 behave behave VERB 0z708w34k1v 7 25 in in ADP 0z708w34k1v 7 26 the the DET 0z708w34k1v 7 27 biological biological ADJ 0z708w34k1v 7 28 and and CCONJ 0z708w34k1v 7 29 geological geological ADJ 0z708w34k1v 7 30 environments environment NOUN 0z708w34k1v 7 31 . . PUNCT 0z708w34k1v 8 1 the the DET 0z708w34k1v 8 2 dimensionality dimensionality NOUN 0z708w34k1v 8 3 and and CCONJ 0z708w34k1v 8 4 overall overall ADJ 0z708w34k1v 8 5 topology topology NOUN 0z708w34k1v 8 6 of of ADP 0z708w34k1v 8 7 these these DET 0z708w34k1v 8 8 compounds compound NOUN 0z708w34k1v 8 9 depends depend VERB 0z708w34k1v 8 10 on on ADP 0z708w34k1v 8 11 the the DET 0z708w34k1v 8 12 coordination coordination NOUN 0z708w34k1v 8 13 preferences preference NOUN 0z708w34k1v 8 14 of of ADP 0z708w34k1v 8 15 the the DET 0z708w34k1v 8 16 metals metal NOUN 0z708w34k1v 8 17 as as ADV 0z708w34k1v 8 18 well well ADV 0z708w34k1v 8 19 as as ADP 0z708w34k1v 8 20 the the DET 0z708w34k1v 8 21 functionalized functionalize VERB 0z708w34k1v 8 22 organic organic ADJ 0z708w34k1v 8 23 ligands ligand NOUN 0z708w34k1v 8 24 . . PUNCT 0z708w34k1v 9 1 the the DET 0z708w34k1v 9 2 rigid rigid ADJ 0z708w34k1v 9 3 phenyl phenyl NOUN 0z708w34k1v 9 4 spacer spacer NOUN 0z708w34k1v 9 5 connects connect VERB 0z708w34k1v 9 6 low low ADV 0z708w34k1v 9 7 - - PUNCT 0z708w34k1v 9 8 dimensional dimensional ADJ 0z708w34k1v 9 9 uranyl uranyl ADJ 0z708w34k1v 9 10 chains chain NOUN 0z708w34k1v 9 11 into into ADP 0z708w34k1v 9 12 layered layered ADJ 0z708w34k1v 9 13 three three NUM 0z708w34k1v 9 14 - - PUNCT 0z708w34k1v 9 15 dimensional dimensional ADJ 0z708w34k1v 9 16 pillared pillared ADJ 0z708w34k1v 9 17 structures structure NOUN 0z708w34k1v 9 18 . . PUNCT 0z708w34k1v 10 1 uranyl uranyl ADJ 0z708w34k1v 10 2 cations cation NOUN 0z708w34k1v 10 3 display display VERB 0z708w34k1v 10 4 a a DET 0z708w34k1v 10 5 high high ADJ 0z708w34k1v 10 6 propensity propensity NOUN 0z708w34k1v 10 7 for for ADP 0z708w34k1v 10 8 phosphonates phosphonate NOUN 0z708w34k1v 10 9 over over ADP 0z708w34k1v 10 10 the the DET 0z708w34k1v 10 11 carboxylate carboxylate NOUN 0z708w34k1v 10 12 moieties moiety NOUN 0z708w34k1v 10 13 of of ADP 0z708w34k1v 10 14 the the DET 0z708w34k1v 10 15 bifunctional bifunctional ADJ 0z708w34k1v 10 16 ligands ligand NOUN 0z708w34k1v 10 17 examined examine VERB 0z708w34k1v 10 18 in in ADP 0z708w34k1v 10 19 agreement agreement NOUN 0z708w34k1v 10 20 with with ADP 0z708w34k1v 10 21 the the DET 0z708w34k1v 10 22 hard hard ADV 0z708w34k1v 10 23 - - PUNCT 0z708w34k1v 10 24 soft soft ADJ 0z708w34k1v 10 25 acid acid ADJ 0z708w34k1v 10 26 - - PUNCT 0z708w34k1v 10 27 base base NOUN 0z708w34k1v 10 28 prediction prediction NOUN 0z708w34k1v 10 29 . . PUNCT 0z708w34k1v 11 1 in in ADP 0z708w34k1v 11 2 the the DET 0z708w34k1v 11 3 final final ADJ 0z708w34k1v 11 4 part part NOUN 0z708w34k1v 11 5 of of ADP 0z708w34k1v 11 6 the the DET 0z708w34k1v 11 7 dissertation dissertation NOUN 0z708w34k1v 11 8 i i PRON 0z708w34k1v 11 9 utilized utilize VERB 0z708w34k1v 11 10 the the DET 0z708w34k1v 11 11 hard hard ADV 0z708w34k1v 11 12 - - PUNCT 0z708w34k1v 11 13 soft soft ADJ 0z708w34k1v 11 14 acid acid ADJ 0z708w34k1v 11 15 - - PUNCT 0z708w34k1v 11 16 base base NOUN 0z708w34k1v 11 17 distinctions distinction NOUN 0z708w34k1v 11 18 to to PART 0z708w34k1v 11 19 prepare prepare VERB 0z708w34k1v 11 20 heterometallic heterometallic ADJ 0z708w34k1v 11 21 uranyl uranyl NOUN 0z708w34k1v 11 22 - - PUNCT 0z708w34k1v 11 23 transition transition NOUN 0z708w34k1v 11 24 metal metal NOUN 0z708w34k1v 11 25 coordination coordination NOUN 0z708w34k1v 11 26 polymers polymer NOUN 0z708w34k1v 11 27 using use VERB 0z708w34k1v 11 28 carboxyphenylphosphonate carboxyphenylphosphonate NOUN 0z708w34k1v 11 29 ligands ligand NOUN 0z708w34k1v 11 30 . . PUNCT 0z708w34k1v 12 1 the the DET 0z708w34k1v 12 2 objective objective NOUN 0z708w34k1v 12 3 was be AUX 0z708w34k1v 12 4 to to PART 0z708w34k1v 12 5 develop develop VERB 0z708w34k1v 12 6 actinide actinide ADJ 0z708w34k1v 12 7 materials material NOUN 0z708w34k1v 12 8 for for ADP 0z708w34k1v 12 9 magnetic magnetic ADJ 0z708w34k1v 12 10 or or CCONJ 0z708w34k1v 12 11 other other ADJ 0z708w34k1v 12 12 material material NOUN 0z708w34k1v 12 13 applications application NOUN 0z708w34k1v 12 14 . . PUNCT 0z708w34k1v 13 1 i i PRON 0z708w34k1v 13 2 demonstrated demonstrate VERB 0z708w34k1v 13 3 the the DET 0z708w34k1v 13 4 importance importance NOUN 0z708w34k1v 13 5 of of ADP 0z708w34k1v 13 6 using use VERB 0z708w34k1v 13 7 pliable pliable ADJ 0z708w34k1v 13 8 1,2 1,2 NUM 0z708w34k1v 13 9 - - PUNCT 0z708w34k1v 13 10 carboxyphenylphosphonate carboxyphenylphosphonate NOUN 0z708w34k1v 13 11 ligand ligand NOUN 0z708w34k1v 13 12 in in ADP 0z708w34k1v 13 13 stabilizing stabilize VERB 0z708w34k1v 13 14 high high ADJ 0z708w34k1v 13 15 nuclearity nuclearity NOUN 0z708w34k1v 13 16 uranyl uranyl NOUN 0z708w34k1v 13 17 heteropolyoxometalate heteropolyoxometalate NOUN 0z708w34k1v 13 18 cage cage NOUN 0z708w34k1v 13 19 clusters cluster NOUN 0z708w34k1v 13 20 under under ADP 0z708w34k1v 13 21 mild mild ADJ 0z708w34k1v 13 22 hydrothermal hydrothermal ADJ 0z708w34k1v 13 23 condition condition NOUN 0z708w34k1v 13 24 . . PUNCT 0z708w34k1v 14 1 this this DET 0z708w34k1v 14 2 work work NOUN 0z708w34k1v 14 3 suggests suggest VERB 0z708w34k1v 14 4 that that SCONJ 0z708w34k1v 14 5 metal metal NOUN 0z708w34k1v 14 6 linkers linker NOUN 0z708w34k1v 14 7 are be AUX 0z708w34k1v 14 8 needed need VERB 0z708w34k1v 14 9 to to PART 0z708w34k1v 14 10 complete complete VERB 0z708w34k1v 14 11 the the DET 0z708w34k1v 14 12 sphere sphere NOUN 0z708w34k1v 14 13 . . PUNCT 0z708w34k1v 15 1 in in ADP 0z708w34k1v 15 2 addition addition NOUN 0z708w34k1v 15 3 , , PUNCT 0z708w34k1v 15 4 this this DET 0z708w34k1v 15 5 result result NOUN 0z708w34k1v 15 6 opens open VERB 0z708w34k1v 15 7 up up ADP 0z708w34k1v 15 8 this this DET 0z708w34k1v 15 9 field field NOUN 0z708w34k1v 15 10 for for ADP 0z708w34k1v 15 11 exploration exploration NOUN 0z708w34k1v 15 12 as as ADP 0z708w34k1v 15 13 this this DET 0z708w34k1v 15 14 material material NOUN 0z708w34k1v 15 15 represents represent VERB 0z708w34k1v 15 16 an an DET 0z708w34k1v 15 17 excellent excellent ADJ 0z708w34k1v 15 18 model model NOUN 0z708w34k1v 15 19 system system NOUN 0z708w34k1v 15 20 with with ADP 0z708w34k1v 15 21 which which PRON 0z708w34k1v 15 22 to to PART 0z708w34k1v 15 23 design design VERB 0z708w34k1v 15 24 and and CCONJ 0z708w34k1v 15 25 study study VERB 0z708w34k1v 15 26 uranyl uranyl NOUN 0z708w34k1v 15 27 nanoclusters nanocluster NOUN 0z708w34k1v 15 28 . . PUNCT 0z708w34k1v 16 1 moreover moreover ADV 0z708w34k1v 16 2 , , PUNCT 0z708w34k1v 16 3 this this DET 0z708w34k1v 16 4 research research NOUN 0z708w34k1v 16 5 will will AUX 0z708w34k1v 16 6 undoubtedly undoubtedly ADV 0z708w34k1v 16 7 stimulate stimulate VERB 0z708w34k1v 16 8 much much ADV 0z708w34k1v 16 9 more more ADJ 0z708w34k1v 16 10 activity activity NOUN 0z708w34k1v 16 11 in in ADP 0z708w34k1v 16 12 this this DET 0z708w34k1v 16 13 important important ADJ 0z708w34k1v 16 14 area area NOUN 0z708w34k1v 16 15 of of ADP 0z708w34k1v 16 16 actinide actinide ADJ 0z708w34k1v 16 17 chemistry chemistry NOUN 0z708w34k1v 16 18 in in ADP 0z708w34k1v 16 19 the the DET 0z708w34k1v 16 20 future future NOUN 0z708w34k1v 16 21 . . PUNCT