id	sid	tid	token	lemma	pos
0p096684p4h	1	1	asymmetric	asymmetric	ADJ
0p096684p4h	1	2	synthesis	synthesis	NOUN
0p096684p4h	1	3	is	be	AUX
0p096684p4h	1	4	an	an	DET
0p096684p4h	1	5	important	important	ADJ
0p096684p4h	1	6	area	area	NOUN
0p096684p4h	1	7	of	of	ADP
0p096684p4h	1	8	modern	modern	ADJ
0p096684p4h	1	9	organic	organic	ADJ
0p096684p4h	1	10	chemistry	chemistry	NOUN
0p096684p4h	1	11	as	as	ADV
0p096684p4h	1	12	many	many	ADJ
0p096684p4h	1	13	biologically	biologically	ADV
0p096684p4h	1	14	important	important	ADJ
0p096684p4h	1	15	molecules	molecule	NOUN
0p096684p4h	1	16	contain	contain	VERB
0p096684p4h	1	17	chiral	chiral	ADJ
0p096684p4h	1	18	centers	center	NOUN
0p096684p4h	1	19	,	,	PUNCT
0p096684p4h	1	20	but	but	CCONJ
0p096684p4h	1	21	the	the	DET
0p096684p4h	1	22	choice	choice	NOUN
0p096684p4h	1	23	of	of	ADP
0p096684p4h	1	24	ligand	ligand	NOUN
0p096684p4h	1	25	is	be	AUX
0p096684p4h	1	26	often	often	ADV
0p096684p4h	1	27	based	base	VERB
0p096684p4h	1	28	on	on	ADP
0p096684p4h	1	29	high	high	ADJ
0p096684p4h	1	30	throughput	throughput	NOUN
0p096684p4h	1	31	screening	screening	NOUN
0p096684p4h	1	32	or	or	CCONJ
0p096684p4h	1	33	simply	simply	ADV
0p096684p4h	1	34	trial	trial	NOUN
0p096684p4h	1	35	and	and	CCONJ
0p096684p4h	1	36	error	error	NOUN
0p096684p4h	1	37	.	.	PUNCT
0p096684p4h	2	1	a	a	DET
0p096684p4h	2	2	virtual	virtual	ADJ
0p096684p4h	2	3	screening	screening	NOUN
0p096684p4h	2	4	method	method	NOUN
0p096684p4h	2	5	can	can	AUX
0p096684p4h	2	6	greatly	greatly	ADV
0p096684p4h	2	7	increase	increase	VERB
0p096684p4h	2	8	the	the	DET
0p096684p4h	2	9	speed	speed	NOUN
0p096684p4h	2	10	of	of	ADP
0p096684p4h	2	11	the	the	DET
0p096684p4h	2	12	ligand	ligand	NOUN
0p096684p4h	2	13	screening	screening	NOUN
0p096684p4h	2	14	process	process	NOUN
0p096684p4h	2	15	by	by	ADP
0p096684p4h	2	16	calculating	calculate	VERB
0p096684p4h	2	17	expected	expect	VERB
0p096684p4h	2	18	enantiomeric	enantiomeric	NOUN
0p096684p4h	2	19	excesses	excess	NOUN
0p096684p4h	2	20	.	.	PUNCT
0p096684p4h	3	1	the	the	DET
0p096684p4h	3	2	q2	q2	PROPN
0p096684p4h	3	3	mm	mm	PROPN
0p096684p4h	3	4	method	method	NOUN
0p096684p4h	3	5	was	be	AUX
0p096684p4h	3	6	utilized	utilize	VERB
0p096684p4h	3	7	to	to	PART
0p096684p4h	3	8	develop	develop	VERB
0p096684p4h	3	9	molecular	molecular	ADJ
0p096684p4h	3	10	mechanics	mechanic	NOUN
0p096684p4h	3	11	parameters	parameter	NOUN
0p096684p4h	3	12	for	for	ADP
0p096684p4h	3	13	such	such	DET
0p096684p4h	3	14	a	a	DET
0p096684p4h	3	15	method	method	NOUN
0p096684p4h	3	16	.	.	PUNCT
0p096684p4h	4	1	the	the	DET
0p096684p4h	4	2	rhodium	rhodium	NOUN
0p096684p4h	4	3	catalyzed	catalyze	VERB
0p096684p4h	4	4	asymmetric	asymmetric	ADJ
0p096684p4h	4	5	hydrogenation	hydrogenation	NOUN
0p096684p4h	4	6	of	of	ADP
0p096684p4h	4	7	enamides	enamide	NOUN
0p096684p4h	4	8	to	to	PART
0p096684p4h	4	9	generate	generate	VERB
0p096684p4h	4	10	amino	amino	ADJ
0p096684p4h	4	11	acid	acid	NOUN
0p096684p4h	4	12	products	product	NOUN
0p096684p4h	4	13	and	and	CCONJ
0p096684p4h	4	14	derivatives	derivative	NOUN
0p096684p4h	4	15	is	be	AUX
0p096684p4h	4	16	a	a	DET
0p096684p4h	4	17	widely	widely	ADV
0p096684p4h	4	18	used	use	VERB
0p096684p4h	4	19	method	method	NOUN
0p096684p4h	4	20	to	to	PART
0p096684p4h	4	21	generate	generate	VERB
0p096684p4h	4	22	unnatural	unnatural	ADJ
0p096684p4h	4	23	amino	amino	ADJ
0p096684p4h	4	24	acids	acid	NOUN
0p096684p4h	4	25	.	.	PUNCT
0p096684p4h	5	1	the	the	DET
0p096684p4h	5	2	b3lyp	b3lyp	SPACE
0p096684p4h	5	3	/	/	SYM
0p096684p4h	5	4	lacvp	lacvp	NOUN
0p096684p4h	5	5	*	*	NOUN
0p096684p4h	5	6	*	*	ADJ
0p096684p4h	5	7	calculated	calculate	VERB
0p096684p4h	5	8	potential	potential	ADJ
0p096684p4h	5	9	energy	energy	NOUN
0p096684p4h	5	10	surfaces	surface	NOUN
0p096684p4h	5	11	for	for	ADP
0p096684p4h	5	12	the	the	DET
0p096684p4h	5	13	hydrogenations	hydrogenation	NOUN
0p096684p4h	5	14	of	of	ADP
0p096684p4h	5	15	varied	varied	ADJ
0p096684p4h	5	16	substrates	substrate	NOUN
0p096684p4h	5	17	while	while	SCONJ
0p096684p4h	5	18	utilizing	utilize	VERB
0p096684p4h	5	19	a	a	DET
0p096684p4h	5	20	common	common	ADJ
0p096684p4h	5	21	ligand	ligand	NOUN
0p096684p4h	5	22	indicate	indicate	VERB
0p096684p4h	5	23	a	a	DET
0p096684p4h	5	24	mechanistic	mechanistic	ADJ
0p096684p4h	5	25	change	change	NOUN
0p096684p4h	5	26	based	base	VERB
0p096684p4h	5	27	on	on	ADP
0p096684p4h	5	28	substrate	substrate	NOUN
0p096684p4h	5	29	.	.	PUNCT
0p096684p4h	6	1	this	this	PRON
0p096684p4h	6	2	has	have	VERB
0p096684p4h	6	3	a	a	DET
0p096684p4h	6	4	significant	significant	ADJ
0p096684p4h	6	5	impact	impact	NOUN
0p096684p4h	6	6	on	on	ADP
0p096684p4h	6	7	the	the	DET
0p096684p4h	6	8	origins	origin	NOUN
0p096684p4h	6	9	of	of	ADP
0p096684p4h	6	10	enantioselectivity	enantioselectivity	NOUN
0p096684p4h	6	11	as	as	ADP
0p096684p4h	6	12	the	the	DET
0p096684p4h	6	13	first	first	ADJ
0p096684p4h	6	14	hydride	hydride	NOUN
0p096684p4h	6	15	transfer	transfer	NOUN
0p096684p4h	6	16	to	to	ADP
0p096684p4h	6	17	the	the	DET
0p096684p4h	6	18	substrate	substrate	NOUN
0p096684p4h	6	19	is	be	AUX
0p096684p4h	6	20	calculated	calculate	VERB
0p096684p4h	6	21	to	to	PART
0p096684p4h	6	22	be	be	AUX
0p096684p4h	6	23	irreversible	irreversible	ADJ
0p096684p4h	6	24	for	for	ADP
0p096684p4h	6	25	all	all	DET
0p096684p4h	6	26	substrates	substrate	NOUN
0p096684p4h	6	27	,	,	PUNCT
0p096684p4h	6	28	independent	independent	ADJ
0p096684p4h	6	29	of	of	ADP
0p096684p4h	6	30	whether	whether	SCONJ
0p096684p4h	6	31	it	it	PRON
0p096684p4h	6	32	occurs	occur	VERB
0p096684p4h	6	33	at	at	ADP
0p096684p4h	6	34	the	the	DET
0p096684p4h	6	35	ì_å±	ì_å±	NOUN
0p096684p4h	6	36	or	or	CCONJ
0p096684p4h	6	37	ì_å	ì_å	SPACE
0p096684p4h	6	38	_	_	PROPN
0p096684p4h	6	39	carbon	carbon	NOUN
0p096684p4h	6	40	of	of	ADP
0p096684p4h	6	41	the	the	DET
0p096684p4h	6	42	olefin	olefin	NOUN
0p096684p4h	6	43	.	.	PUNCT
0p096684p4h	7	1	utilizing	utilize	VERB
0p096684p4h	7	2	the	the	DET
0p096684p4h	7	3	q2	q2	PROPN
0p096684p4h	7	4	mm	mm	PROPN
0p096684p4h	7	5	method	method	NOUN
0p096684p4h	7	6	,	,	PUNCT
0p096684p4h	7	7	new	new	ADJ
0p096684p4h	7	8	molecular	molecular	ADJ
0p096684p4h	7	9	mechanics	mechanic	NOUN
0p096684p4h	7	10	parameters	parameter	NOUN
0p096684p4h	7	11	are	be	AUX
0p096684p4h	7	12	derived	derive	VERB
0p096684p4h	7	13	to	to	PART
0p096684p4h	7	14	model	model	VERB
0p096684p4h	7	15	two	two	NUM
0p096684p4h	7	16	important	important	ADJ
0p096684p4h	7	17	transition	transition	NOUN
0p096684p4h	7	18	structures	structure	NOUN
0p096684p4h	7	19	and	and	CCONJ
0p096684p4h	7	20	an	an	DET
0p096684p4h	7	21	intermediate	intermediate	ADJ
0p096684p4h	7	22	ground	ground	NOUN
0p096684p4h	7	23	state	state	NOUN
0p096684p4h	7	24	structure	structure	NOUN
0p096684p4h	7	25	in	in	ADP
0p096684p4h	7	26	the	the	DET
0p096684p4h	7	27	hydrogenation	hydrogenation	NOUN
0p096684p4h	7	28	of	of	ADP
0p096684p4h	7	29	dehydro	dehydro	PROPN
0p096684p4h	7	30	-	-	PUNCT
0p096684p4h	7	31	ì_å±-amino	ì_å±-amino	NUM
0p096684p4h	7	32	acids	acid	NOUN
0p096684p4h	7	33	and	and	CCONJ
0p096684p4h	7	34	corresponding	correspond	VERB
0p096684p4h	7	35	derivatives	derivative	NOUN
0p096684p4h	7	36	.	.	PUNCT
0p096684p4h	8	1	the	the	DET
0p096684p4h	8	2	new	new	ADJ
0p096684p4h	8	3	parameters	parameter	NOUN
0p096684p4h	8	4	are	be	AUX
0p096684p4h	8	5	based	base	VERB
0p096684p4h	8	6	on	on	ADP
0p096684p4h	8	7	structures	structure	NOUN
0p096684p4h	8	8	calculated	calculate	VERB
0p096684p4h	8	9	at	at	ADP
0p096684p4h	8	10	the	the	DET
0p096684p4h	8	11	b3lyp	b3lyp	SPACE
0p096684p4h	8	12	/	/	SYM
0p096684p4h	8	13	lacvp	lacvp	NOUN
0p096684p4h	8	14	*	*	NOUN
0p096684p4h	8	15	*	*	NOUN
0p096684p4h	8	16	level	level	NOUN
0p096684p4h	8	17	of	of	ADP
0p096684p4h	8	18	theory	theory	NOUN
0p096684p4h	8	19	and	and	CCONJ
0p096684p4h	8	20	added	add	VERB
0p096684p4h	8	21	to	to	ADP
0p096684p4h	8	22	the	the	DET
0p096684p4h	8	23	mm3	mm3	PROPN
0p096684p4h	8	24	*	*	NOUN
0p096684p4h	8	25	force	force	NOUN
0p096684p4h	8	26	field	field	NOUN
0p096684p4h	8	27	.	.	PUNCT
0p096684p4h	9	1	the	the	DET
0p096684p4h	9	2	new	new	ADJ
0p096684p4h	9	3	parameters	parameter	NOUN
0p096684p4h	9	4	were	be	AUX
0p096684p4h	9	5	tested	test	VERB
0p096684p4h	9	6	against	against	ADP
0p096684p4h	9	7	a	a	DET
0p096684p4h	9	8	test	test	NOUN
0p096684p4h	9	9	set	set	NOUN
0p096684p4h	9	10	of	of	ADP
0p096684p4h	9	11	47	47	NUM
0p096684p4h	9	12	points	point	NOUN
0p096684p4h	9	13	of	of	ADP
0p096684p4h	9	14	experimental	experimental	ADJ
0p096684p4h	9	15	data	datum	NOUN
0p096684p4h	9	16	utilizing	utilize	VERB
0p096684p4h	9	17	a	a	DET
0p096684p4h	9	18	wide	wide	ADJ
0p096684p4h	9	19	range	range	NOUN
0p096684p4h	9	20	of	of	ADP
0p096684p4h	9	21	bis	bis	ADJ
0p096684p4h	9	22	-	-	PUNCT
0p096684p4h	9	23	phosphine	phosphine	ADJ
0p096684p4h	9	24	ligands	ligand	NOUN
0p096684p4h	9	25	,	,	PUNCT
0p096684p4h	9	26	with	with	ADP
0p096684p4h	9	27	good	good	ADJ
0p096684p4h	9	28	agreement	agreement	NOUN
0p096684p4h	9	29	between	between	ADP
0p096684p4h	9	30	theory	theory	NOUN
0p096684p4h	9	31	and	and	CCONJ
0p096684p4h	9	32	experiment	experiment	NOUN
0p096684p4h	9	33	.	.	PUNCT
0p096684p4h	10	1	data	data	NOUN
0p096684p4h	10	2	points	point	NOUN
0p096684p4h	10	3	with	with	ADP
0p096684p4h	10	4	large	large	ADJ
0p096684p4h	10	5	quantitative	quantitative	ADJ
0p096684p4h	10	6	errors	error	NOUN
0p096684p4h	10	7	still	still	ADV
0p096684p4h	10	8	give	give	VERB
0p096684p4h	10	9	good	good	ADJ
0p096684p4h	10	10	qualitative	qualitative	ADJ
0p096684p4h	10	11	results	result	NOUN
0p096684p4h	10	12	,	,	PUNCT
0p096684p4h	10	13	and	and	CCONJ
0p096684p4h	10	14	reasons	reason	NOUN
0p096684p4h	10	15	for	for	ADP
0p096684p4h	10	16	these	these	DET
0p096684p4h	10	17	errors	error	NOUN
0p096684p4h	10	18	are	be	AUX
0p096684p4h	10	19	discussed	discuss	VERB
0p096684p4h	10	20	.	.	PUNCT
0p096684p4h	11	1	a	a	DET
0p096684p4h	11	2	second	second	ADJ
0p096684p4h	11	3	reaction	reaction	NOUN
0p096684p4h	11	4	studied	study	VERB
0p096684p4h	11	5	was	be	AUX
0p096684p4h	11	6	the	the	DET
0p096684p4h	11	7	silver	silver	ADJ
0p096684p4h	11	8	catalyzed	catalyze	VERB
0p096684p4h	11	9	intramolecular	intramolecular	ADJ
0p096684p4h	11	10	hydroamination	hydroamination	NOUN
0p096684p4h	11	11	of	of	ADP
0p096684p4h	11	12	alkynes	alkyne	NOUN
0p096684p4h	11	13	,	,	PUNCT
0p096684p4h	11	14	which	which	PRON
0p096684p4h	11	15	is	be	AUX
0p096684p4h	11	16	an	an	DET
0p096684p4h	11	17	effective	effective	ADJ
0p096684p4h	11	18	method	method	NOUN
0p096684p4h	11	19	for	for	ADP
0p096684p4h	11	20	the	the	DET
0p096684p4h	11	21	rapid	rapid	ADJ
0p096684p4h	11	22	construction	construction	NOUN
0p096684p4h	11	23	of	of	ADP
0p096684p4h	11	24	nitrogen	nitrogen	NOUN
0p096684p4h	11	25	heterocycles	heterocycle	NOUN
0p096684p4h	11	26	.	.	PUNCT
0p096684p4h	12	1	the	the	DET
0p096684p4h	12	2	chiral	chiral	ADJ
0p096684p4h	12	3	ligands	ligand	NOUN
0p096684p4h	12	4	in	in	ADP
0p096684p4h	12	5	the	the	DET
0p096684p4h	12	6	library	library	NOUN
0p096684p4h	12	7	are	be	AUX
0p096684p4h	12	8	derived	derive	VERB
0p096684p4h	12	9	from	from	ADP
0p096684p4h	12	10	a	a	DET
0p096684p4h	12	11	phenanthroline	phenanthroline	NOUN
0p096684p4h	12	12	scaffold	scaffold	NOUN
0p096684p4h	12	13	.	.	PUNCT
0p096684p4h	13	1	as	as	ADP
0p096684p4h	13	2	before	before	ADV
0p096684p4h	13	3	,	,	PUNCT
0p096684p4h	13	4	new	new	ADJ
0p096684p4h	13	5	mm3	mm3	NOUN
0p096684p4h	13	6	*	*	NOUN
0p096684p4h	13	7	parameters	parameter	NOUN
0p096684p4h	13	8	were	be	AUX
0p096684p4h	13	9	developed	develop	VERB
0p096684p4h	13	10	to	to	PART
0p096684p4h	13	11	describe	describe	VERB
0p096684p4h	13	12	the	the	DET
0p096684p4h	13	13	transition	transition	NOUN
0p096684p4h	13	14	state	state	NOUN
0p096684p4h	13	15	and	and	CCONJ
0p096684p4h	13	16	subsequent	subsequent	ADJ
0p096684p4h	13	17	screening	screening	NOUN
0p096684p4h	13	18	of	of	ADP
0p096684p4h	13	19	a	a	DET
0p096684p4h	13	20	selection	selection	NOUN
0p096684p4h	13	21	of	of	ADP
0p096684p4h	13	22	chiral	chiral	ADJ
0p096684p4h	13	23	ligands	ligand	NOUN
0p096684p4h	13	24	against	against	ADP
0p096684p4h	13	25	a	a	DET
0p096684p4h	13	26	common	common	ADJ
0p096684p4h	13	27	,	,	PUNCT
0p096684p4h	13	28	symmetric	symmetric	ADJ
0p096684p4h	13	29	aminodiyne	aminodiyne	PROPN
0p096684p4h	13	30	.	.	PUNCT
0p096684p4h	14	1	preliminary	preliminary	ADJ
0p096684p4h	14	2	synthesis	synthesis	NOUN
0p096684p4h	14	3	of	of	ADP
0p096684p4h	14	4	an	an	DET
0p096684p4h	14	5	aminodiyne	aminodiyne	PROPN
0p096684p4h	14	6	substrate	substrate	NOUN
0p096684p4h	14	7	was	be	AUX
0p096684p4h	14	8	also	also	ADV
0p096684p4h	14	9	performed	perform	VERB
0p096684p4h	14	10	for	for	ADP
0p096684p4h	14	11	experimental	experimental	ADJ
0p096684p4h	14	12	verification	verification	NOUN
0p096684p4h	14	13	of	of	ADP
0p096684p4h	14	14	the	the	DET
0p096684p4h	14	15	predictions	prediction	NOUN
0p096684p4h	14	16	.	.	PUNCT