id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
x346d221071	Philip Alan Smith Jr.	Design, Synthesis, and Characterization of Uranyl and Neptunyl Coordination Complexes	1904		.txt	text/plain	319	9	12	This dissertation focuses on exploring the fundamental chemistry of solid-state uranyl and neptunyl coordination complexes to better understand actinyl crystal chemistry and probe the nature of structure directing factors leading to their formation. Several classes of ionic liquids were employed to develop coordination compounds and hybrid materials that expand on the topological diversity of solid-state uranyl structures and systematically investigate, through judicious selection of incorporated moieties, the importance and role of various structure directing factors (i.e. steric affects, hydrogen bonding, pH, temperature, etc.)A second area of research investigates transuranic cyanometallates, and demonstrates marked differences between pentavalent neptunium and hexavalent uranium chemistry.	cache/x346d221071.txt	txt/x346d221071.txt