id author title date pages extension mime words sentence flesch summary cache txt ws859c71k2r Tanner J. Corrado Development of Iptycene-Containing Polysulfones And Ladder Polymers for Gas Separation Membranes 2022 .txt text/plain 358 12 15 To combat these challenges, molecular level design of polymer membranes to incorporate bulky structures that disrupt chain packing, linkages that rigidify the backbone, and introduction of shape-persistent architectures containing configurational free volume elements is a promising strategy. This tradeoff originates at the molecular level, where undesired free volume architectures (small, indiscriminate microcavities) arising from random chain packing in glassy polymer membranes makes it difficult to simultaneously achieve fast and selective gas transport. cache/ws859c71k2r.txt txt/ws859c71k2r.txt