id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
tb09j388f51	Eric Stefan	Novel Access to Methyl Substituted Polyketide Structural Units Through 1,5-Hydride Shift and Ether Transfer: Application to the Syntheses of Diospongins A and B and Towards Lyngbyaloside C	2013		.txt	text/plain	325	11	24	This dissertation comprises three major components that sequentially describe the development of three methodologies for the formation of novel methyl substituted polyketide structural units and their application in complex molecule synthesis. Starting from 1,1-disubstituted alkenes, this transformation enabled us to stereoselectively access tertiary ethers.	cache/tb09j388f51.txt	txt/tb09j388f51.txt