id author title date pages extension mime words sentence flesch summary cache txt dz010p1216s Anshumaan Bajpai New Approaches for Describing Non-Ideal Adsorption and Reaction at Transition Metal Surfaces 1904 .txt text/plain 169 7 29 In this work, we explored both the aspects of free energy, the contribution from creation of adsorbate-surface bonds and the estimation of entropic contribution to the free energy. The minimization of free energy is driven by two competing factors: energetic driving force for creating adsorbate-surface bonds and the entropic cost of reducing the degrees of freedom of an adsorbate as it moves from a fluid phase to the surface. cache/dz010p1216s.txt txt/dz010p1216s.txt