id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
df65v694x77	Joshua Mitchell Lee	Computational Studies on the Mechanism and Stereochemistry of Lewis Acid-Catalyzed Aldol Condensations and Other Molecular Modeling Studies	2014		.txt	text/plain	468	22	28	By combining insights about the transition state regarding preferred torsion angles, the preferred configuration of the stereocenter at the boron atom, and the preferred coordination geometry of the catalyst relative to the aldehyde, transition state conformational analysis is simplified. A model for diastereoselectivity in the Lewis acid-catalyzed Mukaiyama aldol reaction is presented based on computational scans of the Mukaiyama aldol reaction potential energy surface and optimized transition structures.	cache/df65v694x77.txt	txt/df65v694x77.txt