id author title date pages extension mime words sentence flesch summary cache txt 9s161546d9g Sukesh Shekar Part 1: Molybdenum Amidophenolates and Catecholates for Nonclassical Oxygen Activation and Atom Transfer Reactions / Part 2: Silicon-Carbon Bond Activation in Aryloxy-Iminoquinones and Enhanced Reactivity Over Tin Analogues 2014 .txt text/plain 418 16 33 These amidophenolate ligands enable oxygen atom abstraction by the molybdenum(VI) in a ?nonclassical? fashion, as the required reducing equivalents for oxygen reduction are drawn from ligand oxidation and not the molybdenum center. The doubly deprotonated cis-dioxo complex (tBuClipH2)MoO2 readily loses water to form a series of monooxo complexes (tBuClip)MoO(L) in the presence of donor ligands. cache/9s161546d9g.txt txt/9s161546d9g.txt