id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
4m90dv15v3z	Jung-Jae Lee	Supramolecular Enhancement of the Menshutkin Reaction	2009		.txt	text/plain	290	13	42	This dissertation describes an acceleration of the Menshutkin reaction, a distortion of halide leaving group order, and fluorescence sensing of chloroalkanes. Likely reasons for this selective enhancement effect are: (a) increased transition-state stabilization due to hydrogen bonding in the macrocyclic pocket and (b) reduced entropic penalty in the transition state due to an increased fraction of pre-reaction complexes that are oriented in a near attack conformation.	cache/4m90dv15v3z.txt	txt/4m90dv15v3z.txt