id	author	title	date	pages	extension	mime	words	sentence	flesch	summary	cache	txt
44558c99g9c	Jing Zhao	Single Molecule Enzyme Dynamics and Spectroelectrochemistry in Gold-Based Zero-Mode Waveguides	2013		.txt	text/plain	433	17	35	In contrast to its behavior in flavoenzymes, where the transitions are coupled to chemical redox events, the research presented here studies single FAD molecules that are chemically immobilized to the Au region of a ZMW array through a pyrroloquinoline quinone (PQQ) linker. In this structure, the Au functions both to confine the optical field in the ZMW and as the working electrode in a potentiostatically controlled 3-elecrode system, thus allowing potential-dependent blinking to be studied in single FAD molecules.	cache/44558c99g9c.txt	txt/44558c99g9c.txt