id author title date pages extension mime words sentence flesch summary cache txt 0z708w35q8s Sarah G. Pate Characterization of Amine-Functionalized Facilitated Transport Membranes for CO2 Separation 2023 .txt text/plain 372 10 26 To address the fundamental issues of CO2 facilitated transport, we have developed a novel operando transmission FTIR spectroscopic permeation tool to directly observe the formation of CO2 transport intermediates through amine-based FTMs under realistic operating conditions, including dry and humid CO2 gas mixtures, and simultaneously correlate the formation of these intermediate species with the CO2 permeation rates through the same sample. These investigations allow us to clarify the effect of amine structure and the role of water for CO2 transport through amine-functionalized membranes, which ultimately allows us to propose new CO2 transport mechanisms based on the direct observation of intermediate species. cache/0z708w35q8s.txt txt/0z708w35q8s.txt