id	author	title	date	pages	extension	mime	words	sentences	flesch	summary	cache	txt
cord-213136-euv6pqh5	Singh, Kulveer	Sequence Effects on Internal Structure of Droplets of Associative Polymers	2020-05-17		.txt	text/plain	4329	184	56	We study the evolution of internal structure of large droplets (morphology of clusters of stickers) and the kinetics of interconversion between intramolecular and intermolecular associations, for different sequences of our model polymers. Since at t = 0 we begin with a dilute solution of associating polymers in poor solvent in which most of the chains contain intramolecular bonds between their stickers, the observation of a second peak that corresponds to intermolecular bridges means that major molecular rearrangement takes place inside droplets formed by polymers with s8s, 1s6s1 and 2s4s2 sequences. For three of the sequences (s8s, 1s6s1 and 2s4s2) we found that the average spatial distance R ss between the two stickers of a polymer inside the condensed droplet has a bimodal distribution, such that one of the peaks corresponds to intramolecular bonds and the other to intermolecular bridges between clusters (or between different parts of a long fiber of stickers).	./cache/cord-213136-euv6pqh5.txt	./txt/cord-213136-euv6pqh5.txt