id	sid	tid	token	lemma	pos
cord-276598-tm0yj2sn	1	1	key	key	NN
cord-276598-tm0yj2sn	1	2	:	:	:
cord-276598-tm0yj2sn	2	1	cord-276598-tm0yj2sn	cord-276598-tm0yj2sn	JJ
cord-276598-tm0yj2sn	2	2	authors	author	NNS
cord-276598-tm0yj2sn	2	3	:	:	:
cord-276598-tm0yj2sn	2	4	Itumoh	Itumoh	NNP
cord-276598-tm0yj2sn	2	5	,	,	,
cord-276598-tm0yj2sn	2	6	Emeka	Emeka	NNP
cord-276598-tm0yj2sn	2	7	J.	J.	NNP
cord-276598-tm0yj2sn	2	8	;	;	:
cord-276598-tm0yj2sn	2	9	Data	Data	NNP
cord-276598-tm0yj2sn	2	10	,	,	,
cord-276598-tm0yj2sn	2	11	Shailja	Shailja	NNP
cord-276598-tm0yj2sn	2	12	;	;	:
cord-276598-tm0yj2sn	2	13	Leitao	Leitao	NNP
cord-276598-tm0yj2sn	2	14	,	,	,
cord-276598-tm0yj2sn	2	15	Erin	Erin	NNP
cord-276598-tm0yj2sn	2	16	M.	M.	NNP
cord-276598-tm0yj2sn	2	17	title	title	NN
cord-276598-tm0yj2sn	2	18	:	:	:
cord-276598-tm0yj2sn	2	19	Opening	open	VBG
cord-276598-tm0yj2sn	2	20	up	up	RP
cord-276598-tm0yj2sn	2	21	the	the	DT
cord-276598-tm0yj2sn	2	22	Toolbox	Toolbox	NNP
cord-276598-tm0yj2sn	2	23	:	:	:
cord-276598-tm0yj2sn	2	24	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	2	25	and	and	CC
cord-276598-tm0yj2sn	2	26	Mechanisms	Mechanisms	NNPS
cord-276598-tm0yj2sn	2	27	of	of	IN
cord-276598-tm0yj2sn	2	28	Phosphoramidates	Phosphoramidates	NNP
cord-276598-tm0yj2sn	2	29	date	date	NN
cord-276598-tm0yj2sn	2	30	:	:	:
cord-276598-tm0yj2sn	2	31	2020	2020	CD
cord-276598-tm0yj2sn	2	32	-	-	HYPH
cord-276598-tm0yj2sn	2	33	08	08	CD
cord-276598-tm0yj2sn	2	34	-	-	SYM
cord-276598-tm0yj2sn	2	35	13	13	CD
cord-276598-tm0yj2sn	2	36	journal	journal	NN
cord-276598-tm0yj2sn	2	37	:	:	:
cord-276598-tm0yj2sn	3	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	3	2	DOI	DOI	NNP
cord-276598-tm0yj2sn	3	3	:	:	:
cord-276598-tm0yj2sn	4	1	10.3390	10.3390	CD
cord-276598-tm0yj2sn	4	2	/	/	SYM
cord-276598-tm0yj2sn	4	3	molecules25163684	molecules25163684	NNP
cord-276598-tm0yj2sn	4	4	sha	sha	NNP
cord-276598-tm0yj2sn	4	5	:	:	:
cord-276598-tm0yj2sn	4	6	d3d24004f408ad6be8dc1817af80e0f40510d212	d3d24004f408ad6be8dc1817af80e0f40510d212	NNP
cord-276598-tm0yj2sn	4	7	doc_id	doc_id	CD
cord-276598-tm0yj2sn	4	8	:	:	:
cord-276598-tm0yj2sn	4	9	276598	276598	CD
cord-276598-tm0yj2sn	4	10	cord_uid	cord_uid	NNS
cord-276598-tm0yj2sn	4	11	:	:	:
cord-276598-tm0yj2sn	5	1	tm0yj2sn	tm0yj2sn	NN
cord-276598-tm0yj2sn	6	1	This	this	DT
cord-276598-tm0yj2sn	6	2	review	review	NN
cord-276598-tm0yj2sn	6	3	covers	cover	VBZ
cord-276598-tm0yj2sn	6	4	the	the	DT
cord-276598-tm0yj2sn	6	5	main	main	JJ
cord-276598-tm0yj2sn	6	6	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	6	7	routes	route	NNS
cord-276598-tm0yj2sn	6	8	to	to	IN
cord-276598-tm0yj2sn	6	9	and	and	CC
cord-276598-tm0yj2sn	6	10	the	the	DT
cord-276598-tm0yj2sn	6	11	corresponding	correspond	VBG
cord-276598-tm0yj2sn	6	12	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	6	13	of	of	IN
cord-276598-tm0yj2sn	6	14	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	6	15	formation	formation	NN
cord-276598-tm0yj2sn	6	16	.	.	.
cord-276598-tm0yj2sn	7	1	The	the	DT
cord-276598-tm0yj2sn	7	2	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	7	3	routes	route	NNS
cord-276598-tm0yj2sn	7	4	can	can	MD
cord-276598-tm0yj2sn	7	5	be	be	VB
cord-276598-tm0yj2sn	7	6	separated	separate	VBN
cord-276598-tm0yj2sn	7	7	into	into	IN
cord-276598-tm0yj2sn	7	8	six	six	CD
cord-276598-tm0yj2sn	7	9	categories	category	NNS
cord-276598-tm0yj2sn	7	10	:	:	:
cord-276598-tm0yj2sn	7	11	salt	salt	NN
cord-276598-tm0yj2sn	7	12	elimination	elimination	NN
cord-276598-tm0yj2sn	7	13	,	,	,
cord-276598-tm0yj2sn	7	14	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	7	15	cross	cross	NN
cord-276598-tm0yj2sn	7	16	-	-	NN
cord-276598-tm0yj2sn	7	17	coupling	coupling	JJ
cord-276598-tm0yj2sn	7	18	,	,	,
cord-276598-tm0yj2sn	7	19	azide	azide	NN
cord-276598-tm0yj2sn	7	20	,	,	,
cord-276598-tm0yj2sn	7	21	reduction	reduction	NN
cord-276598-tm0yj2sn	7	22	,	,	,
cord-276598-tm0yj2sn	7	23	hydrophosphinylation	hydrophosphinylation	NN
cord-276598-tm0yj2sn	7	24	,	,	,
cord-276598-tm0yj2sn	7	25	and	and	CC
cord-276598-tm0yj2sn	7	26	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	7	27	-	-	HYPH
cord-276598-tm0yj2sn	7	28	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	7	29	-	-	HYPH
cord-276598-tm0yj2sn	7	30	dienophile	dienophile	NN
cord-276598-tm0yj2sn	7	31	(	(	-LRB-
cord-276598-tm0yj2sn	7	32	PAD	pad	NN
cord-276598-tm0yj2sn	7	33	)	)	-RRB-
cord-276598-tm0yj2sn	7	34	.	.	.
cord-276598-tm0yj2sn	8	1	Examples	example	NNS
cord-276598-tm0yj2sn	8	2	of	of	IN
cord-276598-tm0yj2sn	8	3	some	some	DT
cord-276598-tm0yj2sn	8	4	important	important	JJ
cord-276598-tm0yj2sn	8	5	compounds	compound	NNS
cord-276598-tm0yj2sn	8	6	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	8	7	through	through	IN
cord-276598-tm0yj2sn	8	8	these	these	DT
cord-276598-tm0yj2sn	8	9	routes	route	NNS
cord-276598-tm0yj2sn	8	10	are	be	VBP
cord-276598-tm0yj2sn	8	11	provided	provide	VBN
cord-276598-tm0yj2sn	8	12	.	.	.
cord-276598-tm0yj2sn	9	1	As	as	IN
cord-276598-tm0yj2sn	9	2	an	an	DT
cord-276598-tm0yj2sn	9	3	important	important	JJ
cord-276598-tm0yj2sn	9	4	class	class	NN
cord-276598-tm0yj2sn	9	5	of	of	IN
cord-276598-tm0yj2sn	9	6	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	9	7	compounds	compound	NNS
cord-276598-tm0yj2sn	9	8	,	,	,
cord-276598-tm0yj2sn	9	9	the	the	DT
cord-276598-tm0yj2sn	9	10	applications	application	NNS
cord-276598-tm0yj2sn	9	11	of	of	IN
cord-276598-tm0yj2sn	9	12	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	9	13	compounds	compound	NNS
cord-276598-tm0yj2sn	9	14	,	,	,
cord-276598-tm0yj2sn	9	15	are	be	VBP
cord-276598-tm0yj2sn	9	16	also	also	RB
cord-276598-tm0yj2sn	9	17	briefly	briefly	RB
cord-276598-tm0yj2sn	9	18	introduced	introduce	VBN
cord-276598-tm0yj2sn	9	19	.	.	.
cord-276598-tm0yj2sn	10	1	Phosphoramidates	Phosphoramidates	NNP
cord-276598-tm0yj2sn	10	2	(	(	-LRB-
cord-276598-tm0yj2sn	10	3	P	P	NNP
cord-276598-tm0yj2sn	10	4	-	-	HYPH
cord-276598-tm0yj2sn	10	5	N	N	NNP
cord-276598-tm0yj2sn	10	6	)	)	-RRB-
cord-276598-tm0yj2sn	10	7	are	be	VBP
cord-276598-tm0yj2sn	10	8	a	a	DT
cord-276598-tm0yj2sn	10	9	class	class	NN
cord-276598-tm0yj2sn	10	10	of	of	IN
cord-276598-tm0yj2sn	10	11	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	10	12	compounds	compound	NNS
cord-276598-tm0yj2sn	10	13	known	know	VBN
cord-276598-tm0yj2sn	10	14	for	for	IN
cord-276598-tm0yj2sn	10	15	the	the	DT
cord-276598-tm0yj2sn	10	16	presence	presence	NN
cord-276598-tm0yj2sn	10	17	of	of	IN
cord-276598-tm0yj2sn	10	18	a	a	DT
cord-276598-tm0yj2sn	10	19	single	single	JJ
cord-276598-tm0yj2sn	10	20	covalent	covalent	JJ
cord-276598-tm0yj2sn	10	21	bond	bond	NN
cord-276598-tm0yj2sn	10	22	between	between	IN
cord-276598-tm0yj2sn	10	23	the	the	DT
cord-276598-tm0yj2sn	10	24	tetracoordinate	tetracoordinate	NN
cord-276598-tm0yj2sn	11	1	P(V	P(V	NNP
cord-276598-tm0yj2sn	11	2	)	)	-RRB-
cord-276598-tm0yj2sn	11	3	atom	atom	NN
cord-276598-tm0yj2sn	11	4	and	and	CC
cord-276598-tm0yj2sn	11	5	N(III	n(iii	CD
cord-276598-tm0yj2sn	11	6	)	)	-RRB-
cord-276598-tm0yj2sn	11	7	atom	atom	NN
cord-276598-tm0yj2sn	11	8	.	.	.
cord-276598-tm0yj2sn	12	1	There	there	EX
cord-276598-tm0yj2sn	12	2	are	be	VBP
cord-276598-tm0yj2sn	12	3	generally	generally	RB
cord-276598-tm0yj2sn	12	4	three	three	CD
cord-276598-tm0yj2sn	12	5	types	type	NNS
cord-276598-tm0yj2sn	12	6	of	of	IN
cord-276598-tm0yj2sn	12	7	phosphoroamidates	phosphoroamidate	NNS
cord-276598-tm0yj2sn	12	8	,	,	,
cord-276598-tm0yj2sn	12	9	which	which	WDT
cord-276598-tm0yj2sn	12	10	are	be	VBP
cord-276598-tm0yj2sn	12	11	distinguished	distinguish	VBN
cord-276598-tm0yj2sn	12	12	according	accord	VBG
cord-276598-tm0yj2sn	12	13	to	to	IN
cord-276598-tm0yj2sn	12	14	the	the	DT
cord-276598-tm0yj2sn	12	15	substitution	substitution	NN
cord-276598-tm0yj2sn	12	16	on	on	IN
cord-276598-tm0yj2sn	12	17	the	the	DT
cord-276598-tm0yj2sn	12	18	P	p	NN
cord-276598-tm0yj2sn	12	19	and	and	CC
cord-276598-tm0yj2sn	12	20	N	n	CD
cord-276598-tm0yj2sn	12	21	atoms	atom	NNS
cord-276598-tm0yj2sn	12	22	(	(	-LRB-
cord-276598-tm0yj2sn	12	23	Figure	figure	NN
cord-276598-tm0yj2sn	12	24	1	1	CD
cord-276598-tm0yj2sn	12	25	)	)	-RRB-
cord-276598-tm0yj2sn	12	26	[	[	-LRB-
cord-276598-tm0yj2sn	12	27	1	1	CD
cord-276598-tm0yj2sn	12	28	]	]	-RRB-
cord-276598-tm0yj2sn	12	29	.	.	.
cord-276598-tm0yj2sn	13	1	Another	another	DT
cord-276598-tm0yj2sn	13	2	feature	feature	NN
cord-276598-tm0yj2sn	13	3	of	of	IN
cord-276598-tm0yj2sn	13	4	these	these	DT
cord-276598-tm0yj2sn	13	5	organophosphorous	organophosphorous	JJ
cord-276598-tm0yj2sn	13	6	compounds	compound	NNS
cord-276598-tm0yj2sn	13	7	,	,	,
cord-276598-tm0yj2sn	13	8	defined	define	VBN
cord-276598-tm0yj2sn	13	9	as	as	IN
cord-276598-tm0yj2sn	13	10	(	(	-LRB-
cord-276598-tm0yj2sn	13	11	RO)2P(O)NR'2	RO)2P(O)NR'2	NNP
cord-276598-tm0yj2sn	13	12	(	(	-LRB-
cord-276598-tm0yj2sn	13	13	R	r	NN
cord-276598-tm0yj2sn	13	14	,	,	,
cord-276598-tm0yj2sn	13	15	R	r	NN
cord-276598-tm0yj2sn	13	16	'	'	''
cord-276598-tm0yj2sn	14	1	=	=	SYM
cord-276598-tm0yj2sn	14	2	H	h	NN
cord-276598-tm0yj2sn	14	3	,	,	,
cord-276598-tm0yj2sn	14	4	alkyl	alkyl	NN
cord-276598-tm0yj2sn	14	5	,	,	,
cord-276598-tm0yj2sn	14	6	aryl	aryl	NN
cord-276598-tm0yj2sn	14	7	,	,	,
cord-276598-tm0yj2sn	14	8	heteroaryl	heteroaryl	NNP
cord-276598-tm0yj2sn	14	9	)	)	-RRB-
cord-276598-tm0yj2sn	14	10	,	,	,
cord-276598-tm0yj2sn	14	11	is	be	VBZ
cord-276598-tm0yj2sn	14	12	a	a	DT
cord-276598-tm0yj2sn	14	13	stable	stable	JJ
cord-276598-tm0yj2sn	14	14	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	14	15	bond	bond	NN
cord-276598-tm0yj2sn	14	16	(	(	-LRB-
cord-276598-tm0yj2sn	14	17	P	p	NN
cord-276598-tm0yj2sn	14	18	=	=	SYM
cord-276598-tm0yj2sn	14	19	O	o	NN
cord-276598-tm0yj2sn	14	20	)	)	-RRB-
cord-276598-tm0yj2sn	14	21	.	.	.
cord-276598-tm0yj2sn	15	1	Both	both	DT
cord-276598-tm0yj2sn	15	2	P	p	NN
cord-276598-tm0yj2sn	15	3	and	and	CC
cord-276598-tm0yj2sn	15	4	N	n	CD
cord-276598-tm0yj2sn	15	5	atoms	atom	NNS
cord-276598-tm0yj2sn	15	6	are	be	VBP
cord-276598-tm0yj2sn	15	7	key	key	JJ
cord-276598-tm0yj2sn	15	8	physiological	physiological	JJ
cord-276598-tm0yj2sn	15	9	elements	element	NNS
cord-276598-tm0yj2sn	15	10	present	present	JJ
cord-276598-tm0yj2sn	15	11	in	in	IN
cord-276598-tm0yj2sn	15	12	genetic	genetic	JJ
cord-276598-tm0yj2sn	15	13	material	material	NN
cord-276598-tm0yj2sn	15	14	,	,	,
cord-276598-tm0yj2sn	15	15	energy	energy	NN
cord-276598-tm0yj2sn	15	16	transfer	transfer	NN
cord-276598-tm0yj2sn	15	17	,	,	,
cord-276598-tm0yj2sn	15	18	enzymes	enzyme	NNS
cord-276598-tm0yj2sn	15	19	,	,	,
cord-276598-tm0yj2sn	15	20	and	and	CC
cord-276598-tm0yj2sn	15	21	other	other	JJ
cord-276598-tm0yj2sn	15	22	biomolecules	biomolecule	NNS
cord-276598-tm0yj2sn	15	23	and	and	CC
cord-276598-tm0yj2sn	15	24	are	be	VBP
cord-276598-tm0yj2sn	15	25	required	require	VBN
cord-276598-tm0yj2sn	15	26	for	for	IN
cord-276598-tm0yj2sn	15	27	various	various	JJ
cord-276598-tm0yj2sn	15	28	life	life	NN
cord-276598-tm0yj2sn	15	29	processes	process	NNS
cord-276598-tm0yj2sn	15	30	.	.	.
cord-276598-tm0yj2sn	16	1	As	as	IN
cord-276598-tm0yj2sn	16	2	such	such	JJ
cord-276598-tm0yj2sn	16	3	,	,	,
cord-276598-tm0yj2sn	16	4	molecules	molecule	NNS
cord-276598-tm0yj2sn	16	5	containing	contain	VBG
cord-276598-tm0yj2sn	16	6	P	P	NNP
cord-276598-tm0yj2sn	16	7	-	-	HYPH
cord-276598-tm0yj2sn	16	8	N	n	CD
cord-276598-tm0yj2sn	16	9	linkages	linkage	NNS
cord-276598-tm0yj2sn	16	10	are	be	VBP
cord-276598-tm0yj2sn	16	11	found	find	VBN
cord-276598-tm0yj2sn	16	12	in	in	IN
cord-276598-tm0yj2sn	16	13	a	a	DT
cord-276598-tm0yj2sn	16	14	large	large	JJ
cord-276598-tm0yj2sn	16	15	array	array	NN
cord-276598-tm0yj2sn	16	16	of	of	IN
cord-276598-tm0yj2sn	16	17	biologically	biologically	RB
cord-276598-tm0yj2sn	16	18	active	active	JJ
cord-276598-tm0yj2sn	16	19	natural	natural	JJ
cord-276598-tm0yj2sn	16	20	products	product	NNS
cord-276598-tm0yj2sn	16	21	(	(	-LRB-
cord-276598-tm0yj2sn	16	22	1	1	CD
cord-276598-tm0yj2sn	16	23	-	-	SYM
cord-276598-tm0yj2sn	16	24	7	7	CD
cord-276598-tm0yj2sn	16	25	)	)	-RRB-
cord-276598-tm0yj2sn	16	26	(	(	-LRB-
cord-276598-tm0yj2sn	16	27	Figure	figure	NN
cord-276598-tm0yj2sn	16	28	2	2	CD
cord-276598-tm0yj2sn	16	29	)	)	-RRB-
cord-276598-tm0yj2sn	16	30	[	[	-LRB-
cord-276598-tm0yj2sn	16	31	2	2	CD
cord-276598-tm0yj2sn	16	32	,	,	,
cord-276598-tm0yj2sn	16	33	3	3	CD
cord-276598-tm0yj2sn	16	34	]	]	-RRB-
cord-276598-tm0yj2sn	16	35	.	.	.
cord-276598-tm0yj2sn	17	1	For	for	IN
cord-276598-tm0yj2sn	17	2	example	example	NN
cord-276598-tm0yj2sn	17	3	,	,	,
cord-276598-tm0yj2sn	17	4	Microcin	Microcin	NNP
cord-276598-tm0yj2sn	17	5	C7	C7	NNP
cord-276598-tm0yj2sn	17	6	(	(	-LRB-
cord-276598-tm0yj2sn	17	7	1	1	CD
cord-276598-tm0yj2sn	17	8	)	)	-RRB-
cord-276598-tm0yj2sn	17	9	(	(	-LRB-
cord-276598-tm0yj2sn	17	10	Figure	figure	NN
cord-276598-tm0yj2sn	17	11	2	2	CD
cord-276598-tm0yj2sn	17	12	)	)	-RRB-
cord-276598-tm0yj2sn	17	13	is	be	VBZ
cord-276598-tm0yj2sn	17	14	an	an	DT
cord-276598-tm0yj2sn	17	15	antibiotic	antibiotic	NN
cord-276598-tm0yj2sn	17	16	produced	produce	VBN
cord-276598-tm0yj2sn	17	17	by	by	IN
cord-276598-tm0yj2sn	17	18	Escherichia	Escherichia	NNP
cord-276598-tm0yj2sn	17	19	coli	coli	NNS
cord-276598-tm0yj2sn	17	20	[	[	-LRB-
cord-276598-tm0yj2sn	17	21	4	4	CD
cord-276598-tm0yj2sn	17	22	]	]	-RRB-
cord-276598-tm0yj2sn	17	23	.	.	.
cord-276598-tm0yj2sn	18	1	Dinogunellin	Dinogunellin	NNP
cord-276598-tm0yj2sn	18	2	(	(	-LRB-
cord-276598-tm0yj2sn	18	3	2	2	LS
cord-276598-tm0yj2sn	18	4	)	)	-RRB-
cord-276598-tm0yj2sn	18	5	(	(	-LRB-
cord-276598-tm0yj2sn	18	6	Figure	figure	NN
cord-276598-tm0yj2sn	18	7	2	2	CD
cord-276598-tm0yj2sn	18	8	)	)	-RRB-
cord-276598-tm0yj2sn	18	9	,	,	,
cord-276598-tm0yj2sn	18	10	which	which	WDT
cord-276598-tm0yj2sn	18	11	is	be	VBZ
cord-276598-tm0yj2sn	18	12	produced	produce	VBN
cord-276598-tm0yj2sn	18	13	in	in	IN
cord-276598-tm0yj2sn	18	14	the	the	DT
cord-276598-tm0yj2sn	18	15	roe	roe	NN
cord-276598-tm0yj2sn	18	16	of	of	IN
cord-276598-tm0yj2sn	18	17	some	some	DT
cord-276598-tm0yj2sn	18	18	fishes	fish	NNS
cord-276598-tm0yj2sn	18	19	,	,	,
cord-276598-tm0yj2sn	18	20	is	be	VBZ
cord-276598-tm0yj2sn	18	21	a	a	DT
cord-276598-tm0yj2sn	18	22	natural	natural	JJ
cord-276598-tm0yj2sn	18	23	toxin	toxin	NN
cord-276598-tm0yj2sn	18	24	[	[	-LRB-
cord-276598-tm0yj2sn	18	25	5	5	CD
cord-276598-tm0yj2sn	18	26	]	]	-RRB-
cord-276598-tm0yj2sn	18	27	.	.	.
cord-276598-tm0yj2sn	19	1	Phosphoarginine	Phosphoarginine	NNP
cord-276598-tm0yj2sn	19	2	and	and	CC
cord-276598-tm0yj2sn	19	3	phosphocreatine	phosphocreatine	NN
cord-276598-tm0yj2sn	19	4	(	(	-LRB-
cord-276598-tm0yj2sn	19	5	3	3	CD
cord-276598-tm0yj2sn	19	6	and	and	CC
cord-276598-tm0yj2sn	19	7	6	6	CD
cord-276598-tm0yj2sn	19	8	)	)	-RRB-
cord-276598-tm0yj2sn	20	1	(	(	-LRB-
cord-276598-tm0yj2sn	20	2	Figure	figure	NN
cord-276598-tm0yj2sn	20	3	2	2	CD
cord-276598-tm0yj2sn	20	4	)	)	-RRB-
cord-276598-tm0yj2sn	20	5	are	be	VBP
cord-276598-tm0yj2sn	20	6	important	important	JJ
cord-276598-tm0yj2sn	20	7	biological	biological	JJ
cord-276598-tm0yj2sn	20	8	molecules	molecule	NNS
cord-276598-tm0yj2sn	20	9	used	use	VBN
cord-276598-tm0yj2sn	20	10	as	as	IN
cord-276598-tm0yj2sn	20	11	sources	source	NNS
cord-276598-tm0yj2sn	20	12	of	of	IN
cord-276598-tm0yj2sn	20	13	stored	store	VBN
cord-276598-tm0yj2sn	20	14	energies	energy	NNS
cord-276598-tm0yj2sn	20	15	in	in	IN
cord-276598-tm0yj2sn	20	16	invertebrates	invertebrate	NNS
cord-276598-tm0yj2sn	20	17	and	and	CC
cord-276598-tm0yj2sn	20	18	vertebrates	vertebrate	NNS
cord-276598-tm0yj2sn	20	19	,	,	,
cord-276598-tm0yj2sn	20	20	respectively	respectively	RB
cord-276598-tm0yj2sn	20	21	[	[	-LRB-
cord-276598-tm0yj2sn	20	22	6	6	CD
cord-276598-tm0yj2sn	20	23	]	]	-RRB-
cord-276598-tm0yj2sn	20	24	.	.	.
cord-276598-tm0yj2sn	21	1	Phosphoramidon	Phosphoramidon	NNP
cord-276598-tm0yj2sn	21	2	(	(	-LRB-
cord-276598-tm0yj2sn	21	3	4	4	LS
cord-276598-tm0yj2sn	21	4	)	)	-RRB-
cord-276598-tm0yj2sn	21	5	(	(	-LRB-
cord-276598-tm0yj2sn	21	6	Figure	figure	NN
cord-276598-tm0yj2sn	21	7	2	2	CD
cord-276598-tm0yj2sn	21	8	)	)	-RRB-
cord-276598-tm0yj2sn	21	9	,	,	,
cord-276598-tm0yj2sn	21	10	derived	derive	VBN
cord-276598-tm0yj2sn	21	11	from	from	IN
cord-276598-tm0yj2sn	21	12	Streptomyces	Streptomyces	NNP
cord-276598-tm0yj2sn	21	13	tanashiensis	tanashiensis	NN
cord-276598-tm0yj2sn	21	14	,	,	,
cord-276598-tm0yj2sn	21	15	inhibits	inhibit	VBZ
cord-276598-tm0yj2sn	21	16	the	the	DT
cord-276598-tm0yj2sn	21	17	thermolysin	thermolysin	NNP
cord-276598-tm0yj2sn	21	18	enzyme	enzyme	NN
cord-276598-tm0yj2sn	21	19	,	,	,
cord-276598-tm0yj2sn	21	20	which	which	WDT
cord-276598-tm0yj2sn	21	21	is	be	VBZ
cord-276598-tm0yj2sn	21	22	a	a	DT
cord-276598-tm0yj2sn	21	23	key	key	JJ
cord-276598-tm0yj2sn	21	24	factor	factor	NN
cord-276598-tm0yj2sn	21	25	in	in	IN
cord-276598-tm0yj2sn	21	26	the	the	DT
cord-276598-tm0yj2sn	21	27	development	development	NN
cord-276598-tm0yj2sn	21	28	of	of	IN
cord-276598-tm0yj2sn	21	29	various	various	JJ
cord-276598-tm0yj2sn	21	30	diseases	disease	NNS
cord-276598-tm0yj2sn	21	31	[	[	-LRB-
cord-276598-tm0yj2sn	21	32	7	7	CD
cord-276598-tm0yj2sn	21	33	,	,	,
cord-276598-tm0yj2sn	21	34	8	8	CD
cord-276598-tm0yj2sn	21	35	]	]	-RRB-
cord-276598-tm0yj2sn	21	36	.	.	.
cord-276598-tm0yj2sn	22	1	Lastly	lastly	RB
cord-276598-tm0yj2sn	22	2	,	,	,
cord-276598-tm0yj2sn	22	3	phosmidosine	phosmidosine	NNP
cord-276598-tm0yj2sn	22	4	and	and	CC
cord-276598-tm0yj2sn	22	5	agrocin	agrocin	NNP
cord-276598-tm0yj2sn	22	6	84	84	CD
cord-276598-tm0yj2sn	22	7	(	(	-LRB-
cord-276598-tm0yj2sn	22	8	5	5	CD
cord-276598-tm0yj2sn	22	9	and	and	CC
cord-276598-tm0yj2sn	22	10	7	7	CD
cord-276598-tm0yj2sn	22	11	)	)	-RRB-
cord-276598-tm0yj2sn	22	12	(	(	-LRB-
cord-276598-tm0yj2sn	22	13	Figure	figure	NN
cord-276598-tm0yj2sn	22	14	2	2	CD
cord-276598-tm0yj2sn	22	15	)	)	-RRB-
cord-276598-tm0yj2sn	22	16	are	be	VBP
cord-276598-tm0yj2sn	22	17	nucleotide	nucleotide	JJ
cord-276598-tm0yj2sn	22	18	antibiotics	antibiotic	NNS
cord-276598-tm0yj2sn	22	19	isolated	isolate	VBN
cord-276598-tm0yj2sn	22	20	from	from	IN
cord-276598-tm0yj2sn	22	21	Streptomyces	Streptomyces	NNP
cord-276598-tm0yj2sn	22	22	durhameusis	durhameusis	NN
cord-276598-tm0yj2sn	22	23	and	and	CC
cord-276598-tm0yj2sn	22	24	Agrobacterium	Agrobacterium	NNP
cord-276598-tm0yj2sn	22	25	radiobacter	radiobacter	NN
cord-276598-tm0yj2sn	22	26	and	and	CC
cord-276598-tm0yj2sn	22	27	are	be	VBP
cord-276598-tm0yj2sn	22	28	used	use	VBN
cord-276598-tm0yj2sn	22	29	to	to	TO
cord-276598-tm0yj2sn	22	30	control	control	VB
cord-276598-tm0yj2sn	22	31	gray	gray	JJ
cord-276598-tm0yj2sn	22	32	mold	mold	NN
cord-276598-tm0yj2sn	22	33	disease	disease	NN
cord-276598-tm0yj2sn	22	34	and	and	CC
cord-276598-tm0yj2sn	22	35	crown	crown	NN
cord-276598-tm0yj2sn	22	36	gall	gall	NN
cord-276598-tm0yj2sn	22	37	disease	disease	NN
cord-276598-tm0yj2sn	22	38	in	in	IN
cord-276598-tm0yj2sn	22	39	plants	plant	NNS
cord-276598-tm0yj2sn	22	40	,	,	,
cord-276598-tm0yj2sn	22	41	respectively	respectively	RB
cord-276598-tm0yj2sn	22	42	[	[	-LRB-
cord-276598-tm0yj2sn	22	43	9	9	CD
cord-276598-tm0yj2sn	22	44	,	,	,
cord-276598-tm0yj2sn	22	45	10	10	CD
cord-276598-tm0yj2sn	22	46	]	]	-RRB-
cord-276598-tm0yj2sn	22	47	.	.	.
cord-276598-tm0yj2sn	23	1	Another	another	DT
cord-276598-tm0yj2sn	23	2	feature	feature	NN
cord-276598-tm0yj2sn	23	3	of	of	IN
cord-276598-tm0yj2sn	23	4	these	these	DT
cord-276598-tm0yj2sn	23	5	organophosphorous	organophosphorous	JJ
cord-276598-tm0yj2sn	23	6	compounds	compound	NNS
cord-276598-tm0yj2sn	23	7	,	,	,
cord-276598-tm0yj2sn	23	8	defined	define	VBN
cord-276598-tm0yj2sn	23	9	as	as	IN
cord-276598-tm0yj2sn	23	10	(	(	-LRB-
cord-276598-tm0yj2sn	23	11	RO	RO	NNP
cord-276598-tm0yj2sn	23	12	)	)	-RRB-
cord-276598-tm0yj2sn	23	13	2	2	CD
cord-276598-tm0yj2sn	23	14	P(O)NR	p(o)nr	NN
cord-276598-tm0yj2sn	23	15	'	'	POS
cord-276598-tm0yj2sn	23	16	2	2	CD
cord-276598-tm0yj2sn	23	17	(	(	-LRB-
cord-276598-tm0yj2sn	23	18	R	r	NN
cord-276598-tm0yj2sn	23	19	,	,	,
cord-276598-tm0yj2sn	23	20	R	r	NN
cord-276598-tm0yj2sn	23	21	'	'	''
cord-276598-tm0yj2sn	23	22	=	=	NN
cord-276598-tm0yj2sn	23	23	H	h	NN
cord-276598-tm0yj2sn	23	24	,	,	,
cord-276598-tm0yj2sn	23	25	alkyl	alkyl	NN
cord-276598-tm0yj2sn	23	26	,	,	,
cord-276598-tm0yj2sn	23	27	aryl	aryl	NN
cord-276598-tm0yj2sn	23	28	,	,	,
cord-276598-tm0yj2sn	23	29	heteroaryl	heteroaryl	NNP
cord-276598-tm0yj2sn	23	30	)	)	-RRB-
cord-276598-tm0yj2sn	23	31	,	,	,
cord-276598-tm0yj2sn	23	32	is	be	VBZ
cord-276598-tm0yj2sn	23	33	a	a	DT
cord-276598-tm0yj2sn	23	34	stable	stable	JJ
cord-276598-tm0yj2sn	23	35	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	23	36	bond	bond	NN
cord-276598-tm0yj2sn	23	37	(	(	-LRB-
cord-276598-tm0yj2sn	23	38	P	p	NN
cord-276598-tm0yj2sn	23	39	=	=	SYM
cord-276598-tm0yj2sn	23	40	O	o	NN
cord-276598-tm0yj2sn	23	41	)	)	-RRB-
cord-276598-tm0yj2sn	23	42	.	.	.
cord-276598-tm0yj2sn	24	1	Both	both	DT
cord-276598-tm0yj2sn	24	2	P	p	NN
cord-276598-tm0yj2sn	24	3	and	and	CC
cord-276598-tm0yj2sn	24	4	N	n	CD
cord-276598-tm0yj2sn	24	5	atoms	atom	NNS
cord-276598-tm0yj2sn	24	6	are	be	VBP
cord-276598-tm0yj2sn	24	7	key	key	JJ
cord-276598-tm0yj2sn	24	8	physiological	physiological	JJ
cord-276598-tm0yj2sn	24	9	elements	element	NNS
cord-276598-tm0yj2sn	24	10	present	present	JJ
cord-276598-tm0yj2sn	24	11	in	in	IN
cord-276598-tm0yj2sn	24	12	genetic	genetic	JJ
cord-276598-tm0yj2sn	24	13	material	material	NN
cord-276598-tm0yj2sn	24	14	,	,	,
cord-276598-tm0yj2sn	24	15	energy	energy	NN
cord-276598-tm0yj2sn	24	16	transfer	transfer	NN
cord-276598-tm0yj2sn	24	17	,	,	,
cord-276598-tm0yj2sn	24	18	enzymes	enzyme	NNS
cord-276598-tm0yj2sn	24	19	,	,	,
cord-276598-tm0yj2sn	24	20	and	and	CC
cord-276598-tm0yj2sn	24	21	other	other	JJ
cord-276598-tm0yj2sn	24	22	biomolecules	biomolecule	NNS
cord-276598-tm0yj2sn	24	23	and	and	CC
cord-276598-tm0yj2sn	24	24	are	be	VBP
cord-276598-tm0yj2sn	24	25	required	require	VBN
cord-276598-tm0yj2sn	24	26	for	for	IN
cord-276598-tm0yj2sn	24	27	various	various	JJ
cord-276598-tm0yj2sn	24	28	life	life	NN
cord-276598-tm0yj2sn	24	29	processes	process	NNS
cord-276598-tm0yj2sn	24	30	.	.	.
cord-276598-tm0yj2sn	25	1	As	as	IN
cord-276598-tm0yj2sn	25	2	such	such	JJ
cord-276598-tm0yj2sn	25	3	,	,	,
cord-276598-tm0yj2sn	25	4	molecules	molecule	NNS
cord-276598-tm0yj2sn	25	5	containing	contain	VBG
cord-276598-tm0yj2sn	25	6	P	P	NNP
cord-276598-tm0yj2sn	25	7	-	-	HYPH
cord-276598-tm0yj2sn	25	8	N	n	CD
cord-276598-tm0yj2sn	25	9	linkages	linkage	NNS
cord-276598-tm0yj2sn	25	10	are	be	VBP
cord-276598-tm0yj2sn	25	11	found	find	VBN
cord-276598-tm0yj2sn	25	12	in	in	IN
cord-276598-tm0yj2sn	25	13	a	a	DT
cord-276598-tm0yj2sn	25	14	large	large	JJ
cord-276598-tm0yj2sn	25	15	array	array	NN
cord-276598-tm0yj2sn	25	16	of	of	IN
cord-276598-tm0yj2sn	25	17	biologically	biologically	RB
cord-276598-tm0yj2sn	25	18	active	active	JJ
cord-276598-tm0yj2sn	25	19	natural	natural	JJ
cord-276598-tm0yj2sn	25	20	products	product	NNS
cord-276598-tm0yj2sn	25	21	(	(	-LRB-
cord-276598-tm0yj2sn	25	22	1	1	CD
cord-276598-tm0yj2sn	25	23	-	-	SYM
cord-276598-tm0yj2sn	25	24	7	7	CD
cord-276598-tm0yj2sn	25	25	)	)	-RRB-
cord-276598-tm0yj2sn	25	26	(	(	-LRB-
cord-276598-tm0yj2sn	25	27	Figure	figure	NN
cord-276598-tm0yj2sn	25	28	2	2	CD
cord-276598-tm0yj2sn	25	29	)	)	-RRB-
cord-276598-tm0yj2sn	25	30	[	[	-LRB-
cord-276598-tm0yj2sn	25	31	2	2	CD
cord-276598-tm0yj2sn	25	32	,	,	,
cord-276598-tm0yj2sn	25	33	3	3	CD
cord-276598-tm0yj2sn	25	34	]	]	-RRB-
cord-276598-tm0yj2sn	25	35	.	.	.
cord-276598-tm0yj2sn	26	1	For	for	IN
cord-276598-tm0yj2sn	26	2	example	example	NN
cord-276598-tm0yj2sn	26	3	,	,	,
cord-276598-tm0yj2sn	26	4	Microcin	Microcin	NNP
cord-276598-tm0yj2sn	26	5	C7	C7	NNP
cord-276598-tm0yj2sn	26	6	(	(	-LRB-
cord-276598-tm0yj2sn	26	7	1	1	CD
cord-276598-tm0yj2sn	26	8	)	)	-RRB-
cord-276598-tm0yj2sn	26	9	(	(	-LRB-
cord-276598-tm0yj2sn	26	10	Figure	figure	NN
cord-276598-tm0yj2sn	26	11	2	2	CD
cord-276598-tm0yj2sn	26	12	)	)	-RRB-
cord-276598-tm0yj2sn	26	13	is	be	VBZ
cord-276598-tm0yj2sn	26	14	an	an	DT
cord-276598-tm0yj2sn	26	15	antibiotic	antibiotic	NN
cord-276598-tm0yj2sn	26	16	produced	produce	VBN
cord-276598-tm0yj2sn	26	17	by	by	IN
cord-276598-tm0yj2sn	26	18	Escherichia	Escherichia	NNP
cord-276598-tm0yj2sn	26	19	coli	coli	NNS
cord-276598-tm0yj2sn	26	20	[	[	-LRB-
cord-276598-tm0yj2sn	26	21	4	4	CD
cord-276598-tm0yj2sn	26	22	]	]	-RRB-
cord-276598-tm0yj2sn	26	23	.	.	.
cord-276598-tm0yj2sn	27	1	Dinogunellin	Dinogunellin	NNP
cord-276598-tm0yj2sn	27	2	(	(	-LRB-
cord-276598-tm0yj2sn	27	3	2	2	LS
cord-276598-tm0yj2sn	27	4	)	)	-RRB-
cord-276598-tm0yj2sn	27	5	(	(	-LRB-
cord-276598-tm0yj2sn	27	6	Figure	figure	NN
cord-276598-tm0yj2sn	27	7	2	2	CD
cord-276598-tm0yj2sn	27	8	)	)	-RRB-
cord-276598-tm0yj2sn	27	9	,	,	,
cord-276598-tm0yj2sn	27	10	which	which	WDT
cord-276598-tm0yj2sn	27	11	is	be	VBZ
cord-276598-tm0yj2sn	27	12	produced	produce	VBN
cord-276598-tm0yj2sn	27	13	in	in	IN
cord-276598-tm0yj2sn	27	14	the	the	DT
cord-276598-tm0yj2sn	27	15	roe	roe	NN
cord-276598-tm0yj2sn	27	16	of	of	IN
cord-276598-tm0yj2sn	27	17	some	some	DT
cord-276598-tm0yj2sn	27	18	fishes	fish	NNS
cord-276598-tm0yj2sn	27	19	,	,	,
cord-276598-tm0yj2sn	27	20	is	be	VBZ
cord-276598-tm0yj2sn	27	21	a	a	DT
cord-276598-tm0yj2sn	27	22	natural	natural	JJ
cord-276598-tm0yj2sn	27	23	toxin	toxin	NN
cord-276598-tm0yj2sn	27	24	[	[	-LRB-
cord-276598-tm0yj2sn	27	25	5	5	CD
cord-276598-tm0yj2sn	27	26	]	]	-RRB-
cord-276598-tm0yj2sn	27	27	.	.	.
cord-276598-tm0yj2sn	28	1	Phosphoarginine	Phosphoarginine	NNP
cord-276598-tm0yj2sn	28	2	and	and	CC
cord-276598-tm0yj2sn	28	3	phosphocreatine	phosphocreatine	NN
cord-276598-tm0yj2sn	28	4	(	(	-LRB-
cord-276598-tm0yj2sn	28	5	3	3	CD
cord-276598-tm0yj2sn	28	6	and	and	CC
cord-276598-tm0yj2sn	28	7	6	6	CD
cord-276598-tm0yj2sn	28	8	)	)	-RRB-
cord-276598-tm0yj2sn	29	1	(	(	-LRB-
cord-276598-tm0yj2sn	29	2	Figure	figure	NN
cord-276598-tm0yj2sn	29	3	2	2	CD
cord-276598-tm0yj2sn	29	4	)	)	-RRB-
cord-276598-tm0yj2sn	29	5	are	be	VBP
cord-276598-tm0yj2sn	29	6	important	important	JJ
cord-276598-tm0yj2sn	29	7	biological	biological	JJ
cord-276598-tm0yj2sn	29	8	molecules	molecule	NNS
cord-276598-tm0yj2sn	29	9	used	use	VBN
cord-276598-tm0yj2sn	29	10	as	as	IN
cord-276598-tm0yj2sn	29	11	sources	source	NNS
cord-276598-tm0yj2sn	29	12	of	of	IN
cord-276598-tm0yj2sn	29	13	stored	store	VBN
cord-276598-tm0yj2sn	29	14	energies	energy	NNS
cord-276598-tm0yj2sn	29	15	in	in	IN
cord-276598-tm0yj2sn	29	16	invertebrates	invertebrate	NNS
cord-276598-tm0yj2sn	29	17	and	and	CC
cord-276598-tm0yj2sn	29	18	vertebrates	vertebrate	NNS
cord-276598-tm0yj2sn	29	19	,	,	,
cord-276598-tm0yj2sn	29	20	respectively	respectively	RB
cord-276598-tm0yj2sn	29	21	[	[	-LRB-
cord-276598-tm0yj2sn	29	22	6	6	CD
cord-276598-tm0yj2sn	29	23	]	]	-RRB-
cord-276598-tm0yj2sn	29	24	.	.	.
cord-276598-tm0yj2sn	30	1	Phosphoramidon	Phosphoramidon	NNP
cord-276598-tm0yj2sn	30	2	(	(	-LRB-
cord-276598-tm0yj2sn	30	3	4	4	LS
cord-276598-tm0yj2sn	30	4	)	)	-RRB-
cord-276598-tm0yj2sn	30	5	(	(	-LRB-
cord-276598-tm0yj2sn	30	6	Figure	figure	NN
cord-276598-tm0yj2sn	30	7	2	2	CD
cord-276598-tm0yj2sn	30	8	)	)	-RRB-
cord-276598-tm0yj2sn	30	9	,	,	,
cord-276598-tm0yj2sn	30	10	derived	derive	VBN
cord-276598-tm0yj2sn	30	11	from	from	IN
cord-276598-tm0yj2sn	30	12	Streptomyces	Streptomyces	NNP
cord-276598-tm0yj2sn	30	13	tanashiensis	tanashiensis	NN
cord-276598-tm0yj2sn	30	14	,	,	,
cord-276598-tm0yj2sn	30	15	inhibits	inhibit	VBZ
cord-276598-tm0yj2sn	30	16	the	the	DT
cord-276598-tm0yj2sn	30	17	thermolysin	thermolysin	NNP
cord-276598-tm0yj2sn	30	18	enzyme	enzyme	NN
cord-276598-tm0yj2sn	30	19	,	,	,
cord-276598-tm0yj2sn	30	20	which	which	WDT
cord-276598-tm0yj2sn	30	21	is	be	VBZ
cord-276598-tm0yj2sn	30	22	a	a	DT
cord-276598-tm0yj2sn	30	23	key	key	JJ
cord-276598-tm0yj2sn	30	24	factor	factor	NN
cord-276598-tm0yj2sn	30	25	in	in	IN
cord-276598-tm0yj2sn	30	26	the	the	DT
cord-276598-tm0yj2sn	30	27	development	development	NN
cord-276598-tm0yj2sn	30	28	of	of	IN
cord-276598-tm0yj2sn	30	29	various	various	JJ
cord-276598-tm0yj2sn	30	30	diseases	disease	NNS
cord-276598-tm0yj2sn	30	31	[	[	-LRB-
cord-276598-tm0yj2sn	30	32	7	7	CD
cord-276598-tm0yj2sn	30	33	,	,	,
cord-276598-tm0yj2sn	30	34	8	8	CD
cord-276598-tm0yj2sn	30	35	]	]	-RRB-
cord-276598-tm0yj2sn	30	36	.	.	.
cord-276598-tm0yj2sn	31	1	Lastly	lastly	RB
cord-276598-tm0yj2sn	31	2	,	,	,
cord-276598-tm0yj2sn	31	3	phosmidosine	phosmidosine	NNP
cord-276598-tm0yj2sn	31	4	and	and	CC
cord-276598-tm0yj2sn	31	5	agrocin	agrocin	NNP
cord-276598-tm0yj2sn	31	6	84	84	CD
cord-276598-tm0yj2sn	31	7	(	(	-LRB-
cord-276598-tm0yj2sn	31	8	5	5	CD
cord-276598-tm0yj2sn	31	9	and	and	CC
cord-276598-tm0yj2sn	31	10	7	7	CD
cord-276598-tm0yj2sn	31	11	)	)	-RRB-
cord-276598-tm0yj2sn	31	12	(	(	-LRB-
cord-276598-tm0yj2sn	31	13	Figure	figure	NN
cord-276598-tm0yj2sn	31	14	2	2	CD
cord-276598-tm0yj2sn	31	15	)	)	-RRB-
cord-276598-tm0yj2sn	31	16	are	be	VBP
cord-276598-tm0yj2sn	31	17	nucleotide	nucleotide	JJ
cord-276598-tm0yj2sn	31	18	antibiotics	antibiotic	NNS
cord-276598-tm0yj2sn	31	19	isolated	isolate	VBN
cord-276598-tm0yj2sn	31	20	from	from	IN
cord-276598-tm0yj2sn	31	21	Streptomyces	Streptomyces	NNP
cord-276598-tm0yj2sn	31	22	Due	due	IN
cord-276598-tm0yj2sn	31	23	to	to	IN
cord-276598-tm0yj2sn	31	24	the	the	DT
cord-276598-tm0yj2sn	31	25	inherent	inherent	JJ
cord-276598-tm0yj2sn	31	26	physiochemical	physiochemical	JJ
cord-276598-tm0yj2sn	31	27	properties	property	NNS
cord-276598-tm0yj2sn	31	28	of	of	IN
cord-276598-tm0yj2sn	31	29	the	the	DT
cord-276598-tm0yj2sn	31	30	phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	31	31	atom	atom	NN
cord-276598-tm0yj2sn	31	32	including	include	VBG
cord-276598-tm0yj2sn	31	33	its	-PRON-	PRP$
cord-276598-tm0yj2sn	31	34	polarizability	polarizability	NN
cord-276598-tm0yj2sn	31	35	,	,	,
cord-276598-tm0yj2sn	31	36	multivalency	multivalency	NN
cord-276598-tm0yj2sn	31	37	,	,	,
cord-276598-tm0yj2sn	31	38	varying	vary	VBG
cord-276598-tm0yj2sn	31	39	oxidation	oxidation	NN
cord-276598-tm0yj2sn	31	40	states	state	NNS
cord-276598-tm0yj2sn	31	41	,	,	,
cord-276598-tm0yj2sn	31	42	and	and	CC
cord-276598-tm0yj2sn	31	43	low	low	JJ
cord-276598-tm0yj2sn	31	44	coordination	coordination	NN
cord-276598-tm0yj2sn	31	45	number	number	NN
cord-276598-tm0yj2sn	31	46	,	,	,
cord-276598-tm0yj2sn	31	47	a	a	DT
cord-276598-tm0yj2sn	31	48	diverse	diverse	JJ
cord-276598-tm0yj2sn	31	49	range	range	NN
cord-276598-tm0yj2sn	31	50	of	of	IN
cord-276598-tm0yj2sn	31	51	compounds	compound	NNS
cord-276598-tm0yj2sn	31	52	containing	contain	VBG
cord-276598-tm0yj2sn	31	53	the	the	DT
cord-276598-tm0yj2sn	31	54	P	P	NNP
cord-276598-tm0yj2sn	31	55	-	-	HYPH
cord-276598-tm0yj2sn	31	56	N	n	CD
cord-276598-tm0yj2sn	31	57	motifs	motif	NNS
cord-276598-tm0yj2sn	31	58	have	have	VBP
cord-276598-tm0yj2sn	31	59	been	be	VBN
cord-276598-tm0yj2sn	31	60	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	31	61	[	[	-LRB-
cord-276598-tm0yj2sn	31	62	11	11	CD
cord-276598-tm0yj2sn	31	63	]	]	-RRB-
cord-276598-tm0yj2sn	31	64	.	.	.
cord-276598-tm0yj2sn	32	1	These	these	DT
cord-276598-tm0yj2sn	32	2	P	P	NNP
cord-276598-tm0yj2sn	32	3	-	-	HYPH
cord-276598-tm0yj2sn	32	4	Ns	Ns	NNP
cord-276598-tm0yj2sn	32	5	are	be	VBP
cord-276598-tm0yj2sn	32	6	widely	widely	RB
cord-276598-tm0yj2sn	32	7	used	use	VBN
cord-276598-tm0yj2sn	32	8	in	in	IN
cord-276598-tm0yj2sn	32	9	medicine	medicine	NN
cord-276598-tm0yj2sn	32	10	for	for	IN
cord-276598-tm0yj2sn	32	11	the	the	DT
cord-276598-tm0yj2sn	32	12	control	control	NN
cord-276598-tm0yj2sn	32	13	and	and	CC
cord-276598-tm0yj2sn	32	14	treatment	treatment	NN
cord-276598-tm0yj2sn	32	15	of	of	IN
cord-276598-tm0yj2sn	32	16	various	various	JJ
cord-276598-tm0yj2sn	32	17	diseases	disease	NNS
cord-276598-tm0yj2sn	32	18	,	,	,
cord-276598-tm0yj2sn	32	19	in	in	IN
cord-276598-tm0yj2sn	32	20	agriculture	agriculture	NN
cord-276598-tm0yj2sn	32	21	as	as	IN
cord-276598-tm0yj2sn	32	22	pesticides	pesticide	NNS
cord-276598-tm0yj2sn	32	23	for	for	IN
cord-276598-tm0yj2sn	32	24	crop	crop	NN
cord-276598-tm0yj2sn	32	25	protection	protection	NN
cord-276598-tm0yj2sn	32	26	,	,	,
cord-276598-tm0yj2sn	32	27	in	in	IN
cord-276598-tm0yj2sn	32	28	industry	industry	NN
cord-276598-tm0yj2sn	32	29	as	as	IN
cord-276598-tm0yj2sn	32	30	novel	novel	JJ
cord-276598-tm0yj2sn	32	31	fire	fire	NN
cord-276598-tm0yj2sn	32	32	-	-	HYPH
cord-276598-tm0yj2sn	32	33	retardant	retardant	NN
cord-276598-tm0yj2sn	32	34	compounds	compound	NNS
cord-276598-tm0yj2sn	32	35	to	to	TO
cord-276598-tm0yj2sn	32	36	delay	delay	VB
cord-276598-tm0yj2sn	32	37	the	the	DT
cord-276598-tm0yj2sn	32	38	flammability	flammability	NN
cord-276598-tm0yj2sn	32	39	of	of	IN
cord-276598-tm0yj2sn	32	40	polymeric	polymeric	JJ
cord-276598-tm0yj2sn	32	41	compounds	compound	NNS
cord-276598-tm0yj2sn	32	42	,	,	,
cord-276598-tm0yj2sn	32	43	and	and	CC
cord-276598-tm0yj2sn	32	44	in	in	IN
cord-276598-tm0yj2sn	32	45	the	the	DT
cord-276598-tm0yj2sn	32	46	fields	field	NNS
cord-276598-tm0yj2sn	32	47	of	of	IN
cord-276598-tm0yj2sn	32	48	analytical	analytical	JJ
cord-276598-tm0yj2sn	32	49	and	and	CC
cord-276598-tm0yj2sn	32	50	coordination	coordination	NN
cord-276598-tm0yj2sn	32	51	chemistry	chemistry	NN
cord-276598-tm0yj2sn	32	52	.	.	.
cord-276598-tm0yj2sn	33	1	Therefore	therefore	RB
cord-276598-tm0yj2sn	33	2	,	,	,
cord-276598-tm0yj2sn	33	3	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	33	4	P	p	NN
cord-276598-tm0yj2sn	33	5	-	-	HYPH
cord-276598-tm0yj2sn	33	6	N	n	CD
cord-276598-tm0yj2sn	33	7	compounds	compound	NNS
cord-276598-tm0yj2sn	33	8	are	be	VBP
cord-276598-tm0yj2sn	33	9	not	not	RB
cord-276598-tm0yj2sn	33	10	only	only	RB
cord-276598-tm0yj2sn	33	11	researched	research	VBN
cord-276598-tm0yj2sn	33	12	out	out	IN
cord-276598-tm0yj2sn	33	13	of	of	IN
cord-276598-tm0yj2sn	33	14	academic	academic	JJ
cord-276598-tm0yj2sn	33	15	interest	interest	NN
cord-276598-tm0yj2sn	33	16	,	,	,
cord-276598-tm0yj2sn	33	17	but	but	CC
cord-276598-tm0yj2sn	33	18	they	-PRON-	PRP
cord-276598-tm0yj2sn	33	19	also	also	RB
cord-276598-tm0yj2sn	33	20	have	have	VBP
cord-276598-tm0yj2sn	33	21	commercial	commercial	JJ
cord-276598-tm0yj2sn	33	22	applications	application	NNS
cord-276598-tm0yj2sn	33	23	.	.	.
cord-276598-tm0yj2sn	34	1	Uses	use	VBZ
cord-276598-tm0yj2sn	34	2	for	for	IN
cord-276598-tm0yj2sn	34	3	P	p	NN
cord-276598-tm0yj2sn	34	4	-	-	HYPH
cord-276598-tm0yj2sn	34	5	Ns	Ns	NNP
cord-276598-tm0yj2sn	34	6	can	can	MD
cord-276598-tm0yj2sn	34	7	be	be	VB
cord-276598-tm0yj2sn	34	8	separated	separate	VBN
cord-276598-tm0yj2sn	34	9	into	into	IN
cord-276598-tm0yj2sn	34	10	5	5	CD
cord-276598-tm0yj2sn	34	11	main	main	JJ
cord-276598-tm0yj2sn	34	12	classes	class	NNS
cord-276598-tm0yj2sn	34	13	:	:	:
cord-276598-tm0yj2sn	34	14	agriculture	agriculture	NN
cord-276598-tm0yj2sn	34	15	,	,	,
cord-276598-tm0yj2sn	34	16	industry	industry	NN
cord-276598-tm0yj2sn	34	17	,	,	,
cord-276598-tm0yj2sn	34	18	analytical	analytical	JJ
cord-276598-tm0yj2sn	34	19	chemistry	chemistry	NN
cord-276598-tm0yj2sn	34	20	,	,	,
cord-276598-tm0yj2sn	34	21	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	34	22	chemistry	chemistry	NN
cord-276598-tm0yj2sn	34	23	,	,	,
cord-276598-tm0yj2sn	34	24	and	and	CC
cord-276598-tm0yj2sn	34	25	medicinal	medicinal	JJ
cord-276598-tm0yj2sn	34	26	chemistry	chemistry	NN
cord-276598-tm0yj2sn	34	27	(	(	-LRB-
cord-276598-tm0yj2sn	34	28	Figure	figure	NN
cord-276598-tm0yj2sn	34	29	3	3	CD
cord-276598-tm0yj2sn	34	30	)	)	-RRB-
cord-276598-tm0yj2sn	34	31	[	[	-LRB-
cord-276598-tm0yj2sn	34	32	12	12	CD
cord-276598-tm0yj2sn	34	33	]	]	-RRB-
cord-276598-tm0yj2sn	34	34	[	[	-LRB-
cord-276598-tm0yj2sn	34	35	13	13	CD
cord-276598-tm0yj2sn	34	36	]	]	-RRB-
cord-276598-tm0yj2sn	34	37	[	[	-LRB-
cord-276598-tm0yj2sn	34	38	14	14	CD
cord-276598-tm0yj2sn	34	39	]	]	-RRB-
cord-276598-tm0yj2sn	34	40	[	[	-LRB-
cord-276598-tm0yj2sn	34	41	15	15	CD
cord-276598-tm0yj2sn	34	42	]	]	-RRB-
cord-276598-tm0yj2sn	34	43	[	[	-LRB-
cord-276598-tm0yj2sn	34	44	16	16	CD
cord-276598-tm0yj2sn	34	45	]	]	-RRB-
cord-276598-tm0yj2sn	34	46	[	[	-LRB-
cord-276598-tm0yj2sn	34	47	17	17	CD
cord-276598-tm0yj2sn	34	48	]	]	-RRB-
cord-276598-tm0yj2sn	34	49	[	[	-LRB-
cord-276598-tm0yj2sn	34	50	18	18	CD
cord-276598-tm0yj2sn	34	51	]	]	-RRB-
cord-276598-tm0yj2sn	34	52	.	.	.
cord-276598-tm0yj2sn	34	53	 	 	_SP
cord-276598-tm0yj2sn	35	1	This	this	DT
cord-276598-tm0yj2sn	35	2	class	class	NN
cord-276598-tm0yj2sn	35	3	of	of	IN
cord-276598-tm0yj2sn	35	4	organophosphates	organophosphate	NNS
cord-276598-tm0yj2sn	35	5	(	(	-LRB-
cord-276598-tm0yj2sn	35	6	with	with	IN
cord-276598-tm0yj2sn	35	7	common	common	JJ
cord-276598-tm0yj2sn	35	8	names	name	NNS
cord-276598-tm0yj2sn	35	9	such	such	JJ
cord-276598-tm0yj2sn	35	10	as	as	IN
cord-276598-tm0yj2sn	35	11	cruformate	cruformate	NNP
cord-276598-tm0yj2sn	35	12	,	,	,
cord-276598-tm0yj2sn	35	13	fenamiphos	fenamiphos	NNP
cord-276598-tm0yj2sn	35	14	,	,	,
cord-276598-tm0yj2sn	35	15	and	and	CC
cord-276598-tm0yj2sn	35	16	fosthietan	fosthietan	NNP
cord-276598-tm0yj2sn	35	17	)	)	-RRB-
cord-276598-tm0yj2sn	35	18	has	have	VBZ
cord-276598-tm0yj2sn	35	19	been	be	VBN
cord-276598-tm0yj2sn	35	20	widely	widely	RB
cord-276598-tm0yj2sn	35	21	used	use	VBN
cord-276598-tm0yj2sn	35	22	in	in	IN
cord-276598-tm0yj2sn	35	23	pest	pest	NN
cord-276598-tm0yj2sn	35	24	management	management	NN
cord-276598-tm0yj2sn	35	25	for	for	IN
cord-276598-tm0yj2sn	35	26	crop	crop	NN
cord-276598-tm0yj2sn	35	27	protection	protection	NN
cord-276598-tm0yj2sn	35	28	(	(	-LRB-
cord-276598-tm0yj2sn	35	29	Figure	figure	NN
cord-276598-tm0yj2sn	35	30	3	3	CD
cord-276598-tm0yj2sn	35	31	)	)	-RRB-
cord-276598-tm0yj2sn	36	1	[	[	-LRB-
cord-276598-tm0yj2sn	36	2	19	19	CD
cord-276598-tm0yj2sn	36	3	]	]	-RRB-
cord-276598-tm0yj2sn	36	4	[	[	-LRB-
cord-276598-tm0yj2sn	36	5	20	20	CD
cord-276598-tm0yj2sn	36	6	]	]	-RRB-
cord-276598-tm0yj2sn	36	7	[	[	-LRB-
cord-276598-tm0yj2sn	36	8	21	21	CD
cord-276598-tm0yj2sn	36	9	]	]	-RRB-
cord-276598-tm0yj2sn	36	10	.	.	.
cord-276598-tm0yj2sn	37	1	P	p	NN
cord-276598-tm0yj2sn	37	2	-	-	HYPH
cord-276598-tm0yj2sn	37	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	37	4	for	for	IN
cord-276598-tm0yj2sn	37	5	pest	pest	NN
cord-276598-tm0yj2sn	37	6	control	control	NN
cord-276598-tm0yj2sn	37	7	affect	affect	VB
cord-276598-tm0yj2sn	37	8	the	the	DT
cord-276598-tm0yj2sn	37	9	nervous	nervous	JJ
cord-276598-tm0yj2sn	37	10	system	system	NN
cord-276598-tm0yj2sn	37	11	of	of	IN
cord-276598-tm0yj2sn	37	12	pests	pest	NNS
cord-276598-tm0yj2sn	37	13	/	/	SYM
cord-276598-tm0yj2sn	37	14	insects	insect	NNS
cord-276598-tm0yj2sn	37	15	by	by	IN
cord-276598-tm0yj2sn	37	16	inhibiting	inhibit	VBG
cord-276598-tm0yj2sn	37	17	acetylcholinesterase	acetylcholinesterase	NN
cord-276598-tm0yj2sn	37	18	(	(	-LRB-
cord-276598-tm0yj2sn	37	19	AChE	ache	NN
cord-276598-tm0yj2sn	37	20	)	)	-RRB-
cord-276598-tm0yj2sn	37	21	,	,	,
cord-276598-tm0yj2sn	37	22	a	a	DT
cord-276598-tm0yj2sn	37	23	major	major	JJ
cord-276598-tm0yj2sn	37	24	neurotransmitter	neurotransmitter	NN
cord-276598-tm0yj2sn	37	25	[	[	-LRB-
cord-276598-tm0yj2sn	37	26	22	22	CD
cord-276598-tm0yj2sn	37	27	]	]	-RRB-
cord-276598-tm0yj2sn	37	28	[	[	-LRB-
cord-276598-tm0yj2sn	37	29	23	23	CD
cord-276598-tm0yj2sn	37	30	]	]	-RRB-
cord-276598-tm0yj2sn	37	31	[	[	-LRB-
cord-276598-tm0yj2sn	37	32	24	24	CD
cord-276598-tm0yj2sn	37	33	]	]	-RRB-
cord-276598-tm0yj2sn	37	34	[	[	-LRB-
cord-276598-tm0yj2sn	37	35	25	25	CD
cord-276598-tm0yj2sn	37	36	]	]	-RRB-
cord-276598-tm0yj2sn	37	37	.	.	.
cord-276598-tm0yj2sn	38	1	In	in	IN
cord-276598-tm0yj2sn	38	2	addition	addition	NN
cord-276598-tm0yj2sn	38	3	,	,	,
cord-276598-tm0yj2sn	38	4	these	these	DT
cord-276598-tm0yj2sn	38	5	P	P	NNP
cord-276598-tm0yj2sn	38	6	-	-	HYPH
cord-276598-tm0yj2sn	38	7	N	N	NNP
cord-276598-tm0yj2sn	38	8	compounds	compound	NNS
cord-276598-tm0yj2sn	38	9	have	have	VBP
cord-276598-tm0yj2sn	38	10	been	be	VBN
cord-276598-tm0yj2sn	38	11	utilized	utilize	VBN
cord-276598-tm0yj2sn	38	12	as	as	IN
cord-276598-tm0yj2sn	38	13	urease	urease	NN
cord-276598-tm0yj2sn	38	14	inhibitors	inhibitor	NNS
cord-276598-tm0yj2sn	38	15	[	[	-LRB-
cord-276598-tm0yj2sn	38	16	26	26	CD
cord-276598-tm0yj2sn	38	17	,	,	,
cord-276598-tm0yj2sn	38	18	27	27	CD
cord-276598-tm0yj2sn	38	19	]	]	-RRB-
cord-276598-tm0yj2sn	38	20	.	.	.
cord-276598-tm0yj2sn	39	1	Urease	Urease	NNP
cord-276598-tm0yj2sn	39	2	is	be	VBZ
cord-276598-tm0yj2sn	39	3	a	a	DT
cord-276598-tm0yj2sn	39	4	nickel	nickel	NN
cord-276598-tm0yj2sn	39	5	-	-	HYPH
cord-276598-tm0yj2sn	39	6	based	base	VBN
cord-276598-tm0yj2sn	39	7	enzyme	enzyme	NN
cord-276598-tm0yj2sn	39	8	that	that	WDT
cord-276598-tm0yj2sn	39	9	catalyzes	catalyze	VBZ
cord-276598-tm0yj2sn	39	10	the	the	DT
cord-276598-tm0yj2sn	39	11	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	39	12	of	of	IN
cord-276598-tm0yj2sn	39	13	urea	urea	NN
cord-276598-tm0yj2sn	39	14	on	on	IN
cord-276598-tm0yj2sn	39	15	soil	soil	NN
cord-276598-tm0yj2sn	39	16	surfaces	surface	NNS
cord-276598-tm0yj2sn	39	17	into	into	IN
cord-276598-tm0yj2sn	39	18	volatile	volatile	JJ
cord-276598-tm0yj2sn	39	19	ammonia	ammonia	NN
cord-276598-tm0yj2sn	39	20	and	and	CC
cord-276598-tm0yj2sn	39	21	carbon	carbon	NN
cord-276598-tm0yj2sn	39	22	dioxide	dioxide	NN
cord-276598-tm0yj2sn	39	23	(	(	-LRB-
cord-276598-tm0yj2sn	39	24	Scheme	scheme	NN
cord-276598-tm0yj2sn	39	25	1	1	CD
cord-276598-tm0yj2sn	39	26	)	)	-RRB-
cord-276598-tm0yj2sn	39	27	[	[	-LRB-
cord-276598-tm0yj2sn	39	28	28	28	CD
cord-276598-tm0yj2sn	39	29	,	,	,
cord-276598-tm0yj2sn	39	30	29	29	CD
cord-276598-tm0yj2sn	39	31	]	]	-RRB-
cord-276598-tm0yj2sn	39	32	.	.	.
cord-276598-tm0yj2sn	40	1	Thus	thus	RB
cord-276598-tm0yj2sn	40	2	,	,	,
cord-276598-tm0yj2sn	40	3	on	on	IN
cord-276598-tm0yj2sn	40	4	inhibiting	inhibit	VBG
cord-276598-tm0yj2sn	40	5	the	the	DT
cord-276598-tm0yj2sn	40	6	activity	activity	NN
cord-276598-tm0yj2sn	40	7	of	of	IN
cord-276598-tm0yj2sn	40	8	this	this	DT
cord-276598-tm0yj2sn	40	9	metalloenzyme	metalloenzyme	NNS
cord-276598-tm0yj2sn	40	10	,	,	,
cord-276598-tm0yj2sn	40	11	the	the	DT
cord-276598-tm0yj2sn	40	12	availability	availability	NN
cord-276598-tm0yj2sn	40	13	and	and	CC
cord-276598-tm0yj2sn	40	14	performance	performance	NN
cord-276598-tm0yj2sn	40	15	of	of	IN
cord-276598-tm0yj2sn	40	16	urea	urea	NN
cord-276598-tm0yj2sn	40	17	is	be	VBZ
cord-276598-tm0yj2sn	40	18	enhanced	enhance	VBN
cord-276598-tm0yj2sn	40	19	,	,	,
cord-276598-tm0yj2sn	40	20	which	which	WDT
cord-276598-tm0yj2sn	40	21	is	be	VBZ
cord-276598-tm0yj2sn	40	22	a	a	DT
cord-276598-tm0yj2sn	40	23	vital	vital	JJ
cord-276598-tm0yj2sn	40	24	nitrogenous	nitrogenous	JJ
cord-276598-tm0yj2sn	40	25	fertilizer	fertilizer	NN
cord-276598-tm0yj2sn	40	26	for	for	IN
cord-276598-tm0yj2sn	40	27	plant	plant	NN
cord-276598-tm0yj2sn	40	28	growth	growth	NN
cord-276598-tm0yj2sn	40	29	.	.	.
cord-276598-tm0yj2sn	40	30	 	 	_SP
cord-276598-tm0yj2sn	41	1	P	p	NN
cord-276598-tm0yj2sn	41	2	-	-	HYPH
cord-276598-tm0yj2sn	41	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	41	4	have	have	VBP
cord-276598-tm0yj2sn	41	5	been	be	VBN
cord-276598-tm0yj2sn	41	6	used	use	VBN
cord-276598-tm0yj2sn	41	7	as	as	IN
cord-276598-tm0yj2sn	41	8	additives	additive	NNS
cord-276598-tm0yj2sn	41	9	in	in	IN
cord-276598-tm0yj2sn	41	10	both	both	DT
cord-276598-tm0yj2sn	41	11	oil	oil	NN
cord-276598-tm0yj2sn	41	12	and	and	CC
cord-276598-tm0yj2sn	41	13	water	water	NN
cord-276598-tm0yj2sn	41	14	-	-	HYPH
cord-276598-tm0yj2sn	41	15	based	base	VBN
cord-276598-tm0yj2sn	41	16	lubricants	lubricant	NNS
cord-276598-tm0yj2sn	41	17	(	(	-LRB-
cord-276598-tm0yj2sn	41	18	Figure	figure	NN
cord-276598-tm0yj2sn	41	19	3	3	CD
cord-276598-tm0yj2sn	41	20	)	)	-RRB-
cord-276598-tm0yj2sn	41	21	.	.	.
cord-276598-tm0yj2sn	42	1	It	-PRON-	PRP
cord-276598-tm0yj2sn	42	2	has	have	VBZ
cord-276598-tm0yj2sn	42	3	been	be	VBN
cord-276598-tm0yj2sn	42	4	proposed	propose	VBN
cord-276598-tm0yj2sn	42	5	that	that	IN
cord-276598-tm0yj2sn	42	6	phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	42	7	acts	act	VBZ
cord-276598-tm0yj2sn	42	8	as	as	IN
cord-276598-tm0yj2sn	42	9	a	a	DT
cord-276598-tm0yj2sn	42	10	key	key	JJ
cord-276598-tm0yj2sn	42	11	element	element	NN
cord-276598-tm0yj2sn	42	12	in	in	IN
cord-276598-tm0yj2sn	42	13	enhancing	enhance	VBG
cord-276598-tm0yj2sn	42	14	the	the	DT
cord-276598-tm0yj2sn	42	15	tribological	tribological	NNP
cord-276598-tm0yj2sn	42	16	properties	property	NNS
cord-276598-tm0yj2sn	42	17	of	of	IN
cord-276598-tm0yj2sn	42	18	water	water	NN
cord-276598-tm0yj2sn	42	19	/	/	SYM
cord-276598-tm0yj2sn	42	20	oil	oil	NN
cord-276598-tm0yj2sn	42	21	-	-	HYPH
cord-276598-tm0yj2sn	42	22	based	base	VBN
cord-276598-tm0yj2sn	42	23	fluids	fluid	NNS
cord-276598-tm0yj2sn	42	24	by	by	IN
cord-276598-tm0yj2sn	42	25	forming	form	VBG
cord-276598-tm0yj2sn	42	26	a	a	DT
cord-276598-tm0yj2sn	42	27	protective	protective	JJ
cord-276598-tm0yj2sn	42	28	layer	layer	NN
cord-276598-tm0yj2sn	42	29	containing	contain	VBG
cord-276598-tm0yj2sn	42	30	phosphates	phosphate	NNS
cord-276598-tm0yj2sn	42	31	and/or	and/or	CC
cord-276598-tm0yj2sn	42	32	polyphosphates	polyphosphate	NNS
cord-276598-tm0yj2sn	42	33	.	.	.
cord-276598-tm0yj2sn	43	1	Thus	thus	RB
cord-276598-tm0yj2sn	43	2	,	,	,
cord-276598-tm0yj2sn	43	3	they	-PRON-	PRP
cord-276598-tm0yj2sn	43	4	possess	possess	VBP
cord-276598-tm0yj2sn	43	5	anti	anti	JJ
cord-276598-tm0yj2sn	43	6	-	-	JJ
cord-276598-tm0yj2sn	43	7	wear	wear	JJ
cord-276598-tm0yj2sn	43	8	and	and	CC
cord-276598-tm0yj2sn	43	9	friction	friction	NN
cord-276598-tm0yj2sn	43	10	-	-	HYPH
cord-276598-tm0yj2sn	43	11	reducing	reduce	VBG
cord-276598-tm0yj2sn	43	12	properties	property	NNS
cord-276598-tm0yj2sn	43	13	[	[	-LRB-
cord-276598-tm0yj2sn	43	14	18	18	CD
cord-276598-tm0yj2sn	43	15	,	,	,
cord-276598-tm0yj2sn	43	16	30	30	CD
cord-276598-tm0yj2sn	43	17	]	]	-RRB-
cord-276598-tm0yj2sn	43	18	.	.	.
cord-276598-tm0yj2sn	44	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	44	2	,	,	,
cord-276598-tm0yj2sn	44	3	these	these	DT
cord-276598-tm0yj2sn	44	4	P	P	NNP
cord-276598-tm0yj2sn	44	5	-	-	HYPH
cord-276598-tm0yj2sn	44	6	Ns	Ns	NNP
cord-276598-tm0yj2sn	44	7	have	have	VBP
cord-276598-tm0yj2sn	44	8	been	be	VBN
cord-276598-tm0yj2sn	44	9	found	find	VBN
cord-276598-tm0yj2sn	44	10	to	to	TO
cord-276598-tm0yj2sn	44	11	be	be	VB
cord-276598-tm0yj2sn	44	12	a	a	DT
cord-276598-tm0yj2sn	44	13	promising	promising	JJ
cord-276598-tm0yj2sn	44	14	alternative	alternative	NN
cord-276598-tm0yj2sn	44	15	to	to	IN
cord-276598-tm0yj2sn	44	16	halogenated	halogenated	JJ
cord-276598-tm0yj2sn	44	17	flame	flame	NN
cord-276598-tm0yj2sn	44	18	retardants	retardant	NNS
cord-276598-tm0yj2sn	44	19	(	(	-LRB-
cord-276598-tm0yj2sn	44	20	FRs	FRs	NNP
cord-276598-tm0yj2sn	44	21	)	)	-RRB-
cord-276598-tm0yj2sn	44	22	,	,	,
cord-276598-tm0yj2sn	44	23	which	which	WDT
cord-276598-tm0yj2sn	44	24	are	be	VBP
cord-276598-tm0yj2sn	44	25	being	be	VBG
cord-276598-tm0yj2sn	44	26	phased	phase	VBN
cord-276598-tm0yj2sn	44	27	out	out	RP
cord-276598-tm0yj2sn	44	28	as	as	IN
cord-276598-tm0yj2sn	44	29	they	-PRON-	PRP
cord-276598-tm0yj2sn	44	30	have	have	VBP
cord-276598-tm0yj2sn	44	31	been	be	VBN
cord-276598-tm0yj2sn	44	32	recognized	recognize	VBN
cord-276598-tm0yj2sn	44	33	as	as	IN
cord-276598-tm0yj2sn	44	34	global	global	JJ
cord-276598-tm0yj2sn	44	35	contaminants	contaminant	NNS
cord-276598-tm0yj2sn	44	36	due	due	IN
cord-276598-tm0yj2sn	44	37	to	to	IN
cord-276598-tm0yj2sn	44	38	their	-PRON-	PRP$
cord-276598-tm0yj2sn	44	39	ill	ill	JJ
cord-276598-tm0yj2sn	44	40	effects	effect	NNS
cord-276598-tm0yj2sn	44	41	on	on	IN
cord-276598-tm0yj2sn	44	42	health	health	NN
cord-276598-tm0yj2sn	44	43	and	and	CC
cord-276598-tm0yj2sn	44	44	the	the	DT
cord-276598-tm0yj2sn	44	45	environment	environment	NN
cord-276598-tm0yj2sn	44	46	[	[	-LRB-
cord-276598-tm0yj2sn	44	47	31	31	CD
cord-276598-tm0yj2sn	44	48	]	]	-RRB-
cord-276598-tm0yj2sn	44	49	.	.	.
cord-276598-tm0yj2sn	45	1	P	p	NN
cord-276598-tm0yj2sn	45	2	-	-	HYPH
cord-276598-tm0yj2sn	45	3	N	n	CD
cord-276598-tm0yj2sn	45	4	fire	fire	NN
cord-276598-tm0yj2sn	45	5	retardants	retardant	NNS
cord-276598-tm0yj2sn	45	6	are	be	VBP
cord-276598-tm0yj2sn	45	7	less	less	RBR
cord-276598-tm0yj2sn	45	8	volatile	volatile	JJ
cord-276598-tm0yj2sn	45	9	and	and	CC
cord-276598-tm0yj2sn	45	10	relatively	relatively	RB
cord-276598-tm0yj2sn	45	11	thermally	thermally	RB
cord-276598-tm0yj2sn	45	12	stable	stable	JJ
cord-276598-tm0yj2sn	45	13	with	with	IN
cord-276598-tm0yj2sn	45	14	 	 	_SP
cord-276598-tm0yj2sn	45	15	This	this	DT
cord-276598-tm0yj2sn	45	16	class	class	NN
cord-276598-tm0yj2sn	45	17	of	of	IN
cord-276598-tm0yj2sn	45	18	organophosphates	organophosphate	NNS
cord-276598-tm0yj2sn	45	19	(	(	-LRB-
cord-276598-tm0yj2sn	45	20	with	with	IN
cord-276598-tm0yj2sn	45	21	common	common	JJ
cord-276598-tm0yj2sn	45	22	names	name	NNS
cord-276598-tm0yj2sn	45	23	such	such	JJ
cord-276598-tm0yj2sn	45	24	as	as	IN
cord-276598-tm0yj2sn	45	25	cruformate	cruformate	NNP
cord-276598-tm0yj2sn	45	26	,	,	,
cord-276598-tm0yj2sn	45	27	fenamiphos	fenamiphos	NNP
cord-276598-tm0yj2sn	45	28	,	,	,
cord-276598-tm0yj2sn	45	29	and	and	CC
cord-276598-tm0yj2sn	45	30	fosthietan	fosthietan	NNP
cord-276598-tm0yj2sn	45	31	)	)	-RRB-
cord-276598-tm0yj2sn	45	32	has	have	VBZ
cord-276598-tm0yj2sn	45	33	been	be	VBN
cord-276598-tm0yj2sn	45	34	widely	widely	RB
cord-276598-tm0yj2sn	45	35	used	use	VBN
cord-276598-tm0yj2sn	45	36	in	in	IN
cord-276598-tm0yj2sn	45	37	pest	pest	NN
cord-276598-tm0yj2sn	45	38	management	management	NN
cord-276598-tm0yj2sn	45	39	for	for	IN
cord-276598-tm0yj2sn	45	40	crop	crop	NN
cord-276598-tm0yj2sn	45	41	protection	protection	NN
cord-276598-tm0yj2sn	45	42	(	(	-LRB-
cord-276598-tm0yj2sn	45	43	Figure	figure	NN
cord-276598-tm0yj2sn	45	44	3	3	CD
cord-276598-tm0yj2sn	45	45	)	)	-RRB-
cord-276598-tm0yj2sn	45	46	[	[	-LRB-
cord-276598-tm0yj2sn	45	47	19	19	CD
cord-276598-tm0yj2sn	45	48	]	]	-RRB-
cord-276598-tm0yj2sn	45	49	[	[	-LRB-
cord-276598-tm0yj2sn	45	50	20	20	CD
cord-276598-tm0yj2sn	45	51	]	]	-RRB-
cord-276598-tm0yj2sn	45	52	[	[	-LRB-
cord-276598-tm0yj2sn	45	53	21	21	CD
cord-276598-tm0yj2sn	45	54	]	]	-RRB-
cord-276598-tm0yj2sn	45	55	.	.	.
cord-276598-tm0yj2sn	46	1	P	p	NN
cord-276598-tm0yj2sn	46	2	-	-	HYPH
cord-276598-tm0yj2sn	46	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	46	4	for	for	IN
cord-276598-tm0yj2sn	46	5	pest	pest	NN
cord-276598-tm0yj2sn	46	6	control	control	NN
cord-276598-tm0yj2sn	46	7	affect	affect	VB
cord-276598-tm0yj2sn	46	8	the	the	DT
cord-276598-tm0yj2sn	46	9	nervous	nervous	JJ
cord-276598-tm0yj2sn	46	10	system	system	NN
cord-276598-tm0yj2sn	46	11	of	of	IN
cord-276598-tm0yj2sn	46	12	pests	pest	NNS
cord-276598-tm0yj2sn	46	13	/	/	SYM
cord-276598-tm0yj2sn	46	14	insects	insect	NNS
cord-276598-tm0yj2sn	46	15	by	by	IN
cord-276598-tm0yj2sn	46	16	inhibiting	inhibit	VBG
cord-276598-tm0yj2sn	46	17	acetylcholinesterase	acetylcholinesterase	NN
cord-276598-tm0yj2sn	46	18	(	(	-LRB-
cord-276598-tm0yj2sn	46	19	AChE	ache	NN
cord-276598-tm0yj2sn	46	20	)	)	-RRB-
cord-276598-tm0yj2sn	46	21	,	,	,
cord-276598-tm0yj2sn	46	22	a	a	DT
cord-276598-tm0yj2sn	46	23	major	major	JJ
cord-276598-tm0yj2sn	46	24	neurotransmitter	neurotransmitter	NN
cord-276598-tm0yj2sn	46	25	[	[	-LRB-
cord-276598-tm0yj2sn	46	26	22	22	CD
cord-276598-tm0yj2sn	46	27	]	]	-RRB-
cord-276598-tm0yj2sn	46	28	[	[	-LRB-
cord-276598-tm0yj2sn	46	29	23	23	CD
cord-276598-tm0yj2sn	46	30	]	]	-RRB-
cord-276598-tm0yj2sn	46	31	[	[	-LRB-
cord-276598-tm0yj2sn	46	32	24	24	CD
cord-276598-tm0yj2sn	46	33	]	]	-RRB-
cord-276598-tm0yj2sn	46	34	[	[	-LRB-
cord-276598-tm0yj2sn	46	35	25	25	CD
cord-276598-tm0yj2sn	46	36	]	]	-RRB-
cord-276598-tm0yj2sn	46	37	.	.	.
cord-276598-tm0yj2sn	47	1	In	in	IN
cord-276598-tm0yj2sn	47	2	addition	addition	NN
cord-276598-tm0yj2sn	47	3	,	,	,
cord-276598-tm0yj2sn	47	4	these	these	DT
cord-276598-tm0yj2sn	47	5	P	P	NNP
cord-276598-tm0yj2sn	47	6	-	-	HYPH
cord-276598-tm0yj2sn	47	7	N	N	NNP
cord-276598-tm0yj2sn	47	8	compounds	compound	NNS
cord-276598-tm0yj2sn	47	9	have	have	VBP
cord-276598-tm0yj2sn	47	10	been	be	VBN
cord-276598-tm0yj2sn	47	11	utilized	utilize	VBN
cord-276598-tm0yj2sn	47	12	as	as	IN
cord-276598-tm0yj2sn	47	13	urease	urease	NN
cord-276598-tm0yj2sn	47	14	inhibitors	inhibitor	NNS
cord-276598-tm0yj2sn	47	15	[	[	-LRB-
cord-276598-tm0yj2sn	47	16	26	26	CD
cord-276598-tm0yj2sn	47	17	,	,	,
cord-276598-tm0yj2sn	47	18	27	27	CD
cord-276598-tm0yj2sn	47	19	]	]	-RRB-
cord-276598-tm0yj2sn	47	20	.	.	.
cord-276598-tm0yj2sn	48	1	Urease	Urease	NNP
cord-276598-tm0yj2sn	48	2	is	be	VBZ
cord-276598-tm0yj2sn	48	3	a	a	DT
cord-276598-tm0yj2sn	48	4	nickel	nickel	NN
cord-276598-tm0yj2sn	48	5	-	-	HYPH
cord-276598-tm0yj2sn	48	6	based	base	VBN
cord-276598-tm0yj2sn	48	7	enzyme	enzyme	NN
cord-276598-tm0yj2sn	48	8	that	that	WDT
cord-276598-tm0yj2sn	48	9	catalyzes	catalyze	VBZ
cord-276598-tm0yj2sn	48	10	the	the	DT
cord-276598-tm0yj2sn	48	11	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	48	12	of	of	IN
cord-276598-tm0yj2sn	48	13	urea	urea	NN
cord-276598-tm0yj2sn	48	14	on	on	IN
cord-276598-tm0yj2sn	48	15	soil	soil	NN
cord-276598-tm0yj2sn	48	16	surfaces	surface	NNS
cord-276598-tm0yj2sn	48	17	into	into	IN
cord-276598-tm0yj2sn	48	18	volatile	volatile	JJ
cord-276598-tm0yj2sn	48	19	ammonia	ammonia	NN
cord-276598-tm0yj2sn	48	20	and	and	CC
cord-276598-tm0yj2sn	48	21	carbon	carbon	NN
cord-276598-tm0yj2sn	48	22	dioxide	dioxide	NN
cord-276598-tm0yj2sn	48	23	(	(	-LRB-
cord-276598-tm0yj2sn	48	24	Scheme	scheme	NN
cord-276598-tm0yj2sn	48	25	1	1	CD
cord-276598-tm0yj2sn	48	26	)	)	-RRB-
cord-276598-tm0yj2sn	48	27	[	[	-LRB-
cord-276598-tm0yj2sn	48	28	28	28	CD
cord-276598-tm0yj2sn	48	29	,	,	,
cord-276598-tm0yj2sn	48	30	29	29	CD
cord-276598-tm0yj2sn	48	31	]	]	-RRB-
cord-276598-tm0yj2sn	48	32	.	.	.
cord-276598-tm0yj2sn	49	1	Thus	thus	RB
cord-276598-tm0yj2sn	49	2	,	,	,
cord-276598-tm0yj2sn	49	3	on	on	IN
cord-276598-tm0yj2sn	49	4	inhibiting	inhibit	VBG
cord-276598-tm0yj2sn	49	5	the	the	DT
cord-276598-tm0yj2sn	49	6	activity	activity	NN
cord-276598-tm0yj2sn	49	7	of	of	IN
cord-276598-tm0yj2sn	49	8	this	this	DT
cord-276598-tm0yj2sn	49	9	metalloenzyme	metalloenzyme	NNS
cord-276598-tm0yj2sn	49	10	,	,	,
cord-276598-tm0yj2sn	49	11	the	the	DT
cord-276598-tm0yj2sn	49	12	availability	availability	NN
cord-276598-tm0yj2sn	49	13	and	and	CC
cord-276598-tm0yj2sn	49	14	performance	performance	NN
cord-276598-tm0yj2sn	49	15	of	of	IN
cord-276598-tm0yj2sn	49	16	urea	urea	NN
cord-276598-tm0yj2sn	49	17	is	be	VBZ
cord-276598-tm0yj2sn	49	18	enhanced	enhance	VBN
cord-276598-tm0yj2sn	49	19	,	,	,
cord-276598-tm0yj2sn	49	20	which	which	WDT
cord-276598-tm0yj2sn	49	21	is	be	VBZ
cord-276598-tm0yj2sn	49	22	a	a	DT
cord-276598-tm0yj2sn	49	23	vital	vital	JJ
cord-276598-tm0yj2sn	49	24	nitrogenous	nitrogenous	JJ
cord-276598-tm0yj2sn	49	25	fertilizer	fertilizer	NN
cord-276598-tm0yj2sn	49	26	for	for	IN
cord-276598-tm0yj2sn	49	27	plant	plant	NN
cord-276598-tm0yj2sn	49	28	growth	growth	NN
cord-276598-tm0yj2sn	49	29	.	.	.
cord-276598-tm0yj2sn	49	30	 	 	_SP
cord-276598-tm0yj2sn	50	1	This	this	DT
cord-276598-tm0yj2sn	50	2	class	class	NN
cord-276598-tm0yj2sn	50	3	of	of	IN
cord-276598-tm0yj2sn	50	4	organophosphates	organophosphate	NNS
cord-276598-tm0yj2sn	50	5	(	(	-LRB-
cord-276598-tm0yj2sn	50	6	with	with	IN
cord-276598-tm0yj2sn	50	7	common	common	JJ
cord-276598-tm0yj2sn	50	8	names	name	NNS
cord-276598-tm0yj2sn	50	9	such	such	JJ
cord-276598-tm0yj2sn	50	10	as	as	IN
cord-276598-tm0yj2sn	50	11	cruformate	cruformate	NNP
cord-276598-tm0yj2sn	50	12	,	,	,
cord-276598-tm0yj2sn	50	13	fenamiphos	fenamiphos	NNP
cord-276598-tm0yj2sn	50	14	,	,	,
cord-276598-tm0yj2sn	50	15	and	and	CC
cord-276598-tm0yj2sn	50	16	fosthietan	fosthietan	NNP
cord-276598-tm0yj2sn	50	17	)	)	-RRB-
cord-276598-tm0yj2sn	50	18	has	have	VBZ
cord-276598-tm0yj2sn	50	19	been	be	VBN
cord-276598-tm0yj2sn	50	20	widely	widely	RB
cord-276598-tm0yj2sn	50	21	used	use	VBN
cord-276598-tm0yj2sn	50	22	in	in	IN
cord-276598-tm0yj2sn	50	23	pest	pest	NN
cord-276598-tm0yj2sn	50	24	management	management	NN
cord-276598-tm0yj2sn	50	25	for	for	IN
cord-276598-tm0yj2sn	50	26	crop	crop	NN
cord-276598-tm0yj2sn	50	27	protection	protection	NN
cord-276598-tm0yj2sn	50	28	(	(	-LRB-
cord-276598-tm0yj2sn	50	29	Figure	figure	NN
cord-276598-tm0yj2sn	50	30	3	3	CD
cord-276598-tm0yj2sn	50	31	)	)	-RRB-
cord-276598-tm0yj2sn	51	1	[	[	-LRB-
cord-276598-tm0yj2sn	51	2	19	19	CD
cord-276598-tm0yj2sn	51	3	]	]	-RRB-
cord-276598-tm0yj2sn	51	4	[	[	-LRB-
cord-276598-tm0yj2sn	51	5	20	20	CD
cord-276598-tm0yj2sn	51	6	]	]	-RRB-
cord-276598-tm0yj2sn	51	7	[	[	-LRB-
cord-276598-tm0yj2sn	51	8	21	21	CD
cord-276598-tm0yj2sn	51	9	]	]	-RRB-
cord-276598-tm0yj2sn	51	10	.	.	.
cord-276598-tm0yj2sn	52	1	P	p	NN
cord-276598-tm0yj2sn	52	2	-	-	HYPH
cord-276598-tm0yj2sn	52	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	52	4	for	for	IN
cord-276598-tm0yj2sn	52	5	pest	pest	NN
cord-276598-tm0yj2sn	52	6	control	control	NN
cord-276598-tm0yj2sn	52	7	affect	affect	VB
cord-276598-tm0yj2sn	52	8	the	the	DT
cord-276598-tm0yj2sn	52	9	nervous	nervous	JJ
cord-276598-tm0yj2sn	52	10	system	system	NN
cord-276598-tm0yj2sn	52	11	of	of	IN
cord-276598-tm0yj2sn	52	12	pests	pest	NNS
cord-276598-tm0yj2sn	52	13	/	/	SYM
cord-276598-tm0yj2sn	52	14	insects	insect	NNS
cord-276598-tm0yj2sn	52	15	by	by	IN
cord-276598-tm0yj2sn	52	16	inhibiting	inhibit	VBG
cord-276598-tm0yj2sn	52	17	acetylcholinesterase	acetylcholinesterase	NN
cord-276598-tm0yj2sn	52	18	(	(	-LRB-
cord-276598-tm0yj2sn	52	19	AChE	ache	NN
cord-276598-tm0yj2sn	52	20	)	)	-RRB-
cord-276598-tm0yj2sn	52	21	,	,	,
cord-276598-tm0yj2sn	52	22	a	a	DT
cord-276598-tm0yj2sn	52	23	major	major	JJ
cord-276598-tm0yj2sn	52	24	neurotransmitter	neurotransmitter	NN
cord-276598-tm0yj2sn	52	25	[	[	-LRB-
cord-276598-tm0yj2sn	52	26	22	22	CD
cord-276598-tm0yj2sn	52	27	]	]	-RRB-
cord-276598-tm0yj2sn	52	28	[	[	-LRB-
cord-276598-tm0yj2sn	52	29	23	23	CD
cord-276598-tm0yj2sn	52	30	]	]	-RRB-
cord-276598-tm0yj2sn	52	31	[	[	-LRB-
cord-276598-tm0yj2sn	52	32	24	24	CD
cord-276598-tm0yj2sn	52	33	]	]	-RRB-
cord-276598-tm0yj2sn	52	34	[	[	-LRB-
cord-276598-tm0yj2sn	52	35	25	25	CD
cord-276598-tm0yj2sn	52	36	]	]	-RRB-
cord-276598-tm0yj2sn	52	37	.	.	.
cord-276598-tm0yj2sn	53	1	In	in	IN
cord-276598-tm0yj2sn	53	2	addition	addition	NN
cord-276598-tm0yj2sn	53	3	,	,	,
cord-276598-tm0yj2sn	53	4	these	these	DT
cord-276598-tm0yj2sn	53	5	P	P	NNP
cord-276598-tm0yj2sn	53	6	-	-	HYPH
cord-276598-tm0yj2sn	53	7	N	N	NNP
cord-276598-tm0yj2sn	53	8	compounds	compound	NNS
cord-276598-tm0yj2sn	53	9	have	have	VBP
cord-276598-tm0yj2sn	53	10	been	be	VBN
cord-276598-tm0yj2sn	53	11	utilized	utilize	VBN
cord-276598-tm0yj2sn	53	12	as	as	IN
cord-276598-tm0yj2sn	53	13	urease	urease	NN
cord-276598-tm0yj2sn	53	14	inhibitors	inhibitor	NNS
cord-276598-tm0yj2sn	53	15	[	[	-LRB-
cord-276598-tm0yj2sn	53	16	26	26	CD
cord-276598-tm0yj2sn	53	17	,	,	,
cord-276598-tm0yj2sn	53	18	27	27	CD
cord-276598-tm0yj2sn	53	19	]	]	-RRB-
cord-276598-tm0yj2sn	53	20	.	.	.
cord-276598-tm0yj2sn	54	1	Urease	Urease	NNP
cord-276598-tm0yj2sn	54	2	is	be	VBZ
cord-276598-tm0yj2sn	54	3	a	a	DT
cord-276598-tm0yj2sn	54	4	nickel	nickel	NN
cord-276598-tm0yj2sn	54	5	-	-	HYPH
cord-276598-tm0yj2sn	54	6	based	base	VBN
cord-276598-tm0yj2sn	54	7	enzyme	enzyme	NN
cord-276598-tm0yj2sn	54	8	that	that	WDT
cord-276598-tm0yj2sn	54	9	catalyzes	catalyze	VBZ
cord-276598-tm0yj2sn	54	10	the	the	DT
cord-276598-tm0yj2sn	54	11	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	54	12	of	of	IN
cord-276598-tm0yj2sn	54	13	urea	urea	NN
cord-276598-tm0yj2sn	54	14	on	on	IN
cord-276598-tm0yj2sn	54	15	soil	soil	NN
cord-276598-tm0yj2sn	54	16	surfaces	surface	NNS
cord-276598-tm0yj2sn	54	17	into	into	IN
cord-276598-tm0yj2sn	54	18	volatile	volatile	JJ
cord-276598-tm0yj2sn	54	19	ammonia	ammonia	NN
cord-276598-tm0yj2sn	54	20	and	and	CC
cord-276598-tm0yj2sn	54	21	carbon	carbon	NN
cord-276598-tm0yj2sn	54	22	dioxide	dioxide	NN
cord-276598-tm0yj2sn	54	23	(	(	-LRB-
cord-276598-tm0yj2sn	54	24	Scheme	scheme	NN
cord-276598-tm0yj2sn	54	25	1	1	CD
cord-276598-tm0yj2sn	54	26	)	)	-RRB-
cord-276598-tm0yj2sn	54	27	[	[	-LRB-
cord-276598-tm0yj2sn	54	28	28	28	CD
cord-276598-tm0yj2sn	54	29	,	,	,
cord-276598-tm0yj2sn	54	30	29	29	CD
cord-276598-tm0yj2sn	54	31	]	]	-RRB-
cord-276598-tm0yj2sn	54	32	.	.	.
cord-276598-tm0yj2sn	55	1	Thus	thus	RB
cord-276598-tm0yj2sn	55	2	,	,	,
cord-276598-tm0yj2sn	55	3	on	on	IN
cord-276598-tm0yj2sn	55	4	inhibiting	inhibit	VBG
cord-276598-tm0yj2sn	55	5	the	the	DT
cord-276598-tm0yj2sn	55	6	activity	activity	NN
cord-276598-tm0yj2sn	55	7	of	of	IN
cord-276598-tm0yj2sn	55	8	this	this	DT
cord-276598-tm0yj2sn	55	9	metalloenzyme	metalloenzyme	NNS
cord-276598-tm0yj2sn	55	10	,	,	,
cord-276598-tm0yj2sn	55	11	the	the	DT
cord-276598-tm0yj2sn	55	12	availability	availability	NN
cord-276598-tm0yj2sn	55	13	and	and	CC
cord-276598-tm0yj2sn	55	14	performance	performance	NN
cord-276598-tm0yj2sn	55	15	of	of	IN
cord-276598-tm0yj2sn	55	16	urea	urea	NN
cord-276598-tm0yj2sn	55	17	is	be	VBZ
cord-276598-tm0yj2sn	55	18	enhanced	enhance	VBN
cord-276598-tm0yj2sn	55	19	,	,	,
cord-276598-tm0yj2sn	55	20	which	which	WDT
cord-276598-tm0yj2sn	55	21	is	be	VBZ
cord-276598-tm0yj2sn	55	22	a	a	DT
cord-276598-tm0yj2sn	55	23	vital	vital	JJ
cord-276598-tm0yj2sn	55	24	nitrogenous	nitrogenous	JJ
cord-276598-tm0yj2sn	55	25	fertilizer	fertilizer	NN
cord-276598-tm0yj2sn	55	26	for	for	IN
cord-276598-tm0yj2sn	55	27	plant	plant	NN
cord-276598-tm0yj2sn	55	28	growth	growth	NN
cord-276598-tm0yj2sn	55	29	.	.	.
cord-276598-tm0yj2sn	55	30	 	 	_SP
cord-276598-tm0yj2sn	56	1	P	p	NN
cord-276598-tm0yj2sn	56	2	-	-	HYPH
cord-276598-tm0yj2sn	56	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	56	4	have	have	VBP
cord-276598-tm0yj2sn	56	5	been	be	VBN
cord-276598-tm0yj2sn	56	6	used	use	VBN
cord-276598-tm0yj2sn	56	7	as	as	IN
cord-276598-tm0yj2sn	56	8	additives	additive	NNS
cord-276598-tm0yj2sn	56	9	in	in	IN
cord-276598-tm0yj2sn	56	10	both	both	DT
cord-276598-tm0yj2sn	56	11	oil	oil	NN
cord-276598-tm0yj2sn	56	12	and	and	CC
cord-276598-tm0yj2sn	56	13	water	water	NN
cord-276598-tm0yj2sn	56	14	-	-	HYPH
cord-276598-tm0yj2sn	56	15	based	base	VBN
cord-276598-tm0yj2sn	56	16	lubricants	lubricant	NNS
cord-276598-tm0yj2sn	56	17	(	(	-LRB-
cord-276598-tm0yj2sn	56	18	Figure	figure	NN
cord-276598-tm0yj2sn	56	19	3	3	CD
cord-276598-tm0yj2sn	56	20	)	)	-RRB-
cord-276598-tm0yj2sn	56	21	.	.	.
cord-276598-tm0yj2sn	57	1	It	-PRON-	PRP
cord-276598-tm0yj2sn	57	2	has	have	VBZ
cord-276598-tm0yj2sn	57	3	been	be	VBN
cord-276598-tm0yj2sn	57	4	proposed	propose	VBN
cord-276598-tm0yj2sn	57	5	that	that	IN
cord-276598-tm0yj2sn	57	6	phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	57	7	acts	act	VBZ
cord-276598-tm0yj2sn	57	8	as	as	IN
cord-276598-tm0yj2sn	57	9	a	a	DT
cord-276598-tm0yj2sn	57	10	key	key	JJ
cord-276598-tm0yj2sn	57	11	element	element	NN
cord-276598-tm0yj2sn	57	12	in	in	IN
cord-276598-tm0yj2sn	57	13	enhancing	enhance	VBG
cord-276598-tm0yj2sn	57	14	the	the	DT
cord-276598-tm0yj2sn	57	15	tribological	tribological	NNP
cord-276598-tm0yj2sn	57	16	properties	property	NNS
cord-276598-tm0yj2sn	57	17	of	of	IN
cord-276598-tm0yj2sn	57	18	water	water	NN
cord-276598-tm0yj2sn	57	19	/	/	SYM
cord-276598-tm0yj2sn	57	20	oil	oil	NN
cord-276598-tm0yj2sn	57	21	-	-	HYPH
cord-276598-tm0yj2sn	57	22	based	base	VBN
cord-276598-tm0yj2sn	57	23	fluids	fluid	NNS
cord-276598-tm0yj2sn	57	24	by	by	IN
cord-276598-tm0yj2sn	57	25	forming	form	VBG
cord-276598-tm0yj2sn	57	26	a	a	DT
cord-276598-tm0yj2sn	57	27	protective	protective	JJ
cord-276598-tm0yj2sn	57	28	layer	layer	NN
cord-276598-tm0yj2sn	57	29	containing	contain	VBG
cord-276598-tm0yj2sn	57	30	phosphates	phosphate	NNS
cord-276598-tm0yj2sn	57	31	and/or	and/or	CC
cord-276598-tm0yj2sn	57	32	polyphosphates	polyphosphate	NNS
cord-276598-tm0yj2sn	57	33	.	.	.
cord-276598-tm0yj2sn	58	1	Thus	thus	RB
cord-276598-tm0yj2sn	58	2	,	,	,
cord-276598-tm0yj2sn	58	3	they	-PRON-	PRP
cord-276598-tm0yj2sn	58	4	possess	possess	VBP
cord-276598-tm0yj2sn	58	5	anti	anti	JJ
cord-276598-tm0yj2sn	58	6	-	-	JJ
cord-276598-tm0yj2sn	58	7	wear	wear	JJ
cord-276598-tm0yj2sn	58	8	and	and	CC
cord-276598-tm0yj2sn	58	9	friction	friction	NN
cord-276598-tm0yj2sn	58	10	-	-	HYPH
cord-276598-tm0yj2sn	58	11	reducing	reduce	VBG
cord-276598-tm0yj2sn	58	12	properties	property	NNS
cord-276598-tm0yj2sn	58	13	[	[	-LRB-
cord-276598-tm0yj2sn	58	14	18	18	CD
cord-276598-tm0yj2sn	58	15	,	,	,
cord-276598-tm0yj2sn	58	16	30	30	CD
cord-276598-tm0yj2sn	58	17	]	]	-RRB-
cord-276598-tm0yj2sn	58	18	.	.	.
cord-276598-tm0yj2sn	59	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	59	2	,	,	,
cord-276598-tm0yj2sn	59	3	these	these	DT
cord-276598-tm0yj2sn	59	4	P	P	NNP
cord-276598-tm0yj2sn	59	5	-	-	HYPH
cord-276598-tm0yj2sn	59	6	Ns	Ns	NNP
cord-276598-tm0yj2sn	59	7	have	have	VBP
cord-276598-tm0yj2sn	59	8	been	be	VBN
cord-276598-tm0yj2sn	59	9	found	find	VBN
cord-276598-tm0yj2sn	59	10	to	to	TO
cord-276598-tm0yj2sn	59	11	be	be	VB
cord-276598-tm0yj2sn	59	12	a	a	DT
cord-276598-tm0yj2sn	59	13	promising	promising	JJ
cord-276598-tm0yj2sn	59	14	alternative	alternative	NN
cord-276598-tm0yj2sn	59	15	to	to	IN
cord-276598-tm0yj2sn	59	16	halogenated	halogenated	JJ
cord-276598-tm0yj2sn	59	17	flame	flame	NN
cord-276598-tm0yj2sn	59	18	retardants	retardant	NNS
cord-276598-tm0yj2sn	59	19	(	(	-LRB-
cord-276598-tm0yj2sn	59	20	FRs	FRs	NNP
cord-276598-tm0yj2sn	59	21	)	)	-RRB-
cord-276598-tm0yj2sn	59	22	,	,	,
cord-276598-tm0yj2sn	59	23	which	which	WDT
cord-276598-tm0yj2sn	59	24	are	be	VBP
cord-276598-tm0yj2sn	59	25	being	be	VBG
cord-276598-tm0yj2sn	59	26	phased	phase	VBN
cord-276598-tm0yj2sn	59	27	out	out	RP
cord-276598-tm0yj2sn	59	28	as	as	IN
cord-276598-tm0yj2sn	59	29	they	-PRON-	PRP
cord-276598-tm0yj2sn	59	30	have	have	VBP
cord-276598-tm0yj2sn	59	31	been	be	VBN
cord-276598-tm0yj2sn	59	32	recognized	recognize	VBN
cord-276598-tm0yj2sn	59	33	as	as	IN
cord-276598-tm0yj2sn	59	34	global	global	JJ
cord-276598-tm0yj2sn	59	35	contaminants	contaminant	NNS
cord-276598-tm0yj2sn	59	36	due	due	IN
cord-276598-tm0yj2sn	59	37	to	to	IN
cord-276598-tm0yj2sn	59	38	their	-PRON-	PRP$
cord-276598-tm0yj2sn	59	39	ill	ill	JJ
cord-276598-tm0yj2sn	59	40	effects	effect	NNS
cord-276598-tm0yj2sn	59	41	on	on	IN
cord-276598-tm0yj2sn	59	42	health	health	NN
cord-276598-tm0yj2sn	59	43	and	and	CC
cord-276598-tm0yj2sn	59	44	the	the	DT
cord-276598-tm0yj2sn	59	45	environment	environment	NN
cord-276598-tm0yj2sn	59	46	[	[	-LRB-
cord-276598-tm0yj2sn	59	47	31	31	CD
cord-276598-tm0yj2sn	59	48	]	]	-RRB-
cord-276598-tm0yj2sn	59	49	.	.	.
cord-276598-tm0yj2sn	60	1	P	p	NN
cord-276598-tm0yj2sn	60	2	-	-	HYPH
cord-276598-tm0yj2sn	60	3	N	n	CD
cord-276598-tm0yj2sn	60	4	fire	fire	NN
cord-276598-tm0yj2sn	60	5	retardants	retardant	NNS
cord-276598-tm0yj2sn	60	6	are	be	VBP
cord-276598-tm0yj2sn	60	7	less	less	RBR
cord-276598-tm0yj2sn	60	8	volatile	volatile	JJ
cord-276598-tm0yj2sn	60	9	and	and	CC
cord-276598-tm0yj2sn	60	10	relatively	relatively	RB
cord-276598-tm0yj2sn	60	11	thermally	thermally	RB
cord-276598-tm0yj2sn	60	12	stable	stable	JJ
cord-276598-tm0yj2sn	60	13	with	with	IN
cord-276598-tm0yj2sn	60	14	Scheme	scheme	NN
cord-276598-tm0yj2sn	60	15	1	1	CD
cord-276598-tm0yj2sn	60	16	.	.	.
cord-276598-tm0yj2sn	61	1	Hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	61	2	of	of	IN
cord-276598-tm0yj2sn	61	3	urea	urea	NN
cord-276598-tm0yj2sn	61	4	on	on	IN
cord-276598-tm0yj2sn	61	5	soil	soil	NN
cord-276598-tm0yj2sn	61	6	in	in	IN
cord-276598-tm0yj2sn	61	7	the	the	DT
cord-276598-tm0yj2sn	61	8	presence	presence	NN
cord-276598-tm0yj2sn	61	9	of	of	IN
cord-276598-tm0yj2sn	61	10	urease	urease	NN
cord-276598-tm0yj2sn	61	11	.	.	.
cord-276598-tm0yj2sn	62	1	P	p	NN
cord-276598-tm0yj2sn	62	2	-	-	HYPH
cord-276598-tm0yj2sn	62	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	62	4	have	have	VBP
cord-276598-tm0yj2sn	62	5	been	be	VBN
cord-276598-tm0yj2sn	62	6	used	use	VBN
cord-276598-tm0yj2sn	62	7	as	as	IN
cord-276598-tm0yj2sn	62	8	additives	additive	NNS
cord-276598-tm0yj2sn	62	9	in	in	IN
cord-276598-tm0yj2sn	62	10	both	both	DT
cord-276598-tm0yj2sn	62	11	oil	oil	NN
cord-276598-tm0yj2sn	62	12	and	and	CC
cord-276598-tm0yj2sn	62	13	water	water	NN
cord-276598-tm0yj2sn	62	14	-	-	HYPH
cord-276598-tm0yj2sn	62	15	based	base	VBN
cord-276598-tm0yj2sn	62	16	lubricants	lubricant	NNS
cord-276598-tm0yj2sn	62	17	(	(	-LRB-
cord-276598-tm0yj2sn	62	18	Figure	figure	NN
cord-276598-tm0yj2sn	62	19	3	3	CD
cord-276598-tm0yj2sn	62	20	)	)	-RRB-
cord-276598-tm0yj2sn	62	21	.	.	.
cord-276598-tm0yj2sn	63	1	It	-PRON-	PRP
cord-276598-tm0yj2sn	63	2	has	have	VBZ
cord-276598-tm0yj2sn	63	3	been	be	VBN
cord-276598-tm0yj2sn	63	4	proposed	propose	VBN
cord-276598-tm0yj2sn	63	5	that	that	IN
cord-276598-tm0yj2sn	63	6	phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	63	7	acts	act	VBZ
cord-276598-tm0yj2sn	63	8	as	as	IN
cord-276598-tm0yj2sn	63	9	a	a	DT
cord-276598-tm0yj2sn	63	10	key	key	JJ
cord-276598-tm0yj2sn	63	11	element	element	NN
cord-276598-tm0yj2sn	63	12	in	in	IN
cord-276598-tm0yj2sn	63	13	enhancing	enhance	VBG
cord-276598-tm0yj2sn	63	14	the	the	DT
cord-276598-tm0yj2sn	63	15	tribological	tribological	NNP
cord-276598-tm0yj2sn	63	16	properties	property	NNS
cord-276598-tm0yj2sn	63	17	of	of	IN
cord-276598-tm0yj2sn	63	18	water	water	NN
cord-276598-tm0yj2sn	63	19	/	/	SYM
cord-276598-tm0yj2sn	63	20	oil	oil	NN
cord-276598-tm0yj2sn	63	21	-	-	HYPH
cord-276598-tm0yj2sn	63	22	based	base	VBN
cord-276598-tm0yj2sn	63	23	fluids	fluid	NNS
cord-276598-tm0yj2sn	63	24	by	by	IN
cord-276598-tm0yj2sn	63	25	forming	form	VBG
cord-276598-tm0yj2sn	63	26	a	a	DT
cord-276598-tm0yj2sn	63	27	protective	protective	JJ
cord-276598-tm0yj2sn	63	28	layer	layer	NN
cord-276598-tm0yj2sn	63	29	containing	contain	VBG
cord-276598-tm0yj2sn	63	30	phosphates	phosphate	NNS
cord-276598-tm0yj2sn	63	31	and/or	and/or	CC
cord-276598-tm0yj2sn	63	32	polyphosphates	polyphosphate	NNS
cord-276598-tm0yj2sn	63	33	.	.	.
cord-276598-tm0yj2sn	64	1	Thus	thus	RB
cord-276598-tm0yj2sn	64	2	,	,	,
cord-276598-tm0yj2sn	64	3	they	-PRON-	PRP
cord-276598-tm0yj2sn	64	4	possess	possess	VBP
cord-276598-tm0yj2sn	64	5	anti	anti	JJ
cord-276598-tm0yj2sn	64	6	-	-	JJ
cord-276598-tm0yj2sn	64	7	wear	wear	JJ
cord-276598-tm0yj2sn	64	8	and	and	CC
cord-276598-tm0yj2sn	64	9	friction	friction	NN
cord-276598-tm0yj2sn	64	10	-	-	HYPH
cord-276598-tm0yj2sn	64	11	reducing	reduce	VBG
cord-276598-tm0yj2sn	64	12	properties	property	NNS
cord-276598-tm0yj2sn	64	13	[	[	-LRB-
cord-276598-tm0yj2sn	64	14	18	18	CD
cord-276598-tm0yj2sn	64	15	,	,	,
cord-276598-tm0yj2sn	64	16	30	30	CD
cord-276598-tm0yj2sn	64	17	]	]	-RRB-
cord-276598-tm0yj2sn	64	18	.	.	.
cord-276598-tm0yj2sn	65	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	65	2	,	,	,
cord-276598-tm0yj2sn	65	3	these	these	DT
cord-276598-tm0yj2sn	65	4	P	P	NNP
cord-276598-tm0yj2sn	65	5	-	-	HYPH
cord-276598-tm0yj2sn	65	6	Ns	Ns	NNP
cord-276598-tm0yj2sn	65	7	have	have	VBP
cord-276598-tm0yj2sn	65	8	been	be	VBN
cord-276598-tm0yj2sn	65	9	found	find	VBN
cord-276598-tm0yj2sn	65	10	to	to	TO
cord-276598-tm0yj2sn	65	11	be	be	VB
cord-276598-tm0yj2sn	65	12	a	a	DT
cord-276598-tm0yj2sn	65	13	promising	promising	JJ
cord-276598-tm0yj2sn	65	14	alternative	alternative	NN
cord-276598-tm0yj2sn	65	15	to	to	IN
cord-276598-tm0yj2sn	65	16	halogenated	halogenated	JJ
cord-276598-tm0yj2sn	65	17	flame	flame	NN
cord-276598-tm0yj2sn	65	18	retardants	retardant	NNS
cord-276598-tm0yj2sn	65	19	(	(	-LRB-
cord-276598-tm0yj2sn	65	20	FRs	FRs	NNP
cord-276598-tm0yj2sn	65	21	)	)	-RRB-
cord-276598-tm0yj2sn	65	22	,	,	,
cord-276598-tm0yj2sn	65	23	which	which	WDT
cord-276598-tm0yj2sn	65	24	are	be	VBP
cord-276598-tm0yj2sn	65	25	being	be	VBG
cord-276598-tm0yj2sn	65	26	phased	phase	VBN
cord-276598-tm0yj2sn	65	27	out	out	RP
cord-276598-tm0yj2sn	65	28	as	as	IN
cord-276598-tm0yj2sn	65	29	they	-PRON-	PRP
cord-276598-tm0yj2sn	65	30	have	have	VBP
cord-276598-tm0yj2sn	65	31	been	be	VBN
cord-276598-tm0yj2sn	65	32	recognized	recognize	VBN
cord-276598-tm0yj2sn	65	33	as	as	IN
cord-276598-tm0yj2sn	65	34	global	global	JJ
cord-276598-tm0yj2sn	65	35	contaminants	contaminant	NNS
cord-276598-tm0yj2sn	65	36	due	due	IN
cord-276598-tm0yj2sn	65	37	to	to	IN
cord-276598-tm0yj2sn	65	38	their	-PRON-	PRP$
cord-276598-tm0yj2sn	65	39	ill	ill	JJ
cord-276598-tm0yj2sn	65	40	effects	effect	NNS
cord-276598-tm0yj2sn	65	41	on	on	IN
cord-276598-tm0yj2sn	65	42	health	health	NN
cord-276598-tm0yj2sn	65	43	and	and	CC
cord-276598-tm0yj2sn	65	44	the	the	DT
cord-276598-tm0yj2sn	65	45	environment	environment	NN
cord-276598-tm0yj2sn	65	46	[	[	-LRB-
cord-276598-tm0yj2sn	65	47	31	31	CD
cord-276598-tm0yj2sn	65	48	]	]	-RRB-
cord-276598-tm0yj2sn	65	49	.	.	.
cord-276598-tm0yj2sn	66	1	P	p	NN
cord-276598-tm0yj2sn	66	2	-	-	HYPH
cord-276598-tm0yj2sn	66	3	N	n	CD
cord-276598-tm0yj2sn	66	4	fire	fire	NN
cord-276598-tm0yj2sn	66	5	retardants	retardant	NNS
cord-276598-tm0yj2sn	66	6	are	be	VBP
cord-276598-tm0yj2sn	66	7	less	less	RBR
cord-276598-tm0yj2sn	66	8	volatile	volatile	JJ
cord-276598-tm0yj2sn	66	9	and	and	CC
cord-276598-tm0yj2sn	66	10	relatively	relatively	RB
cord-276598-tm0yj2sn	66	11	thermally	thermally	RB
cord-276598-tm0yj2sn	66	12	stable	stable	JJ
cord-276598-tm0yj2sn	66	13	with	with	IN
cord-276598-tm0yj2sn	66	14	enhanced	enhanced	JJ
cord-276598-tm0yj2sn	66	15	char	char	NN
cord-276598-tm0yj2sn	66	16	formation	formation	NN
cord-276598-tm0yj2sn	66	17	,	,	,
cord-276598-tm0yj2sn	66	18	and	and	CC
cord-276598-tm0yj2sn	66	19	they	-PRON-	PRP
cord-276598-tm0yj2sn	66	20	are	be	VBP
cord-276598-tm0yj2sn	66	21	more	more	RBR
cord-276598-tm0yj2sn	66	22	efficient	efficient	JJ
cord-276598-tm0yj2sn	66	23	and	and	CC
cord-276598-tm0yj2sn	66	24	sustainable	sustainable	JJ
cord-276598-tm0yj2sn	66	25	than	than	IN
cord-276598-tm0yj2sn	66	26	their	-PRON-	PRP$
cord-276598-tm0yj2sn	66	27	halogenated	halogenate	VBN
cord-276598-tm0yj2sn	66	28	Molecules	molecule	NNS
cord-276598-tm0yj2sn	66	29	2020	2020	CD
cord-276598-tm0yj2sn	66	30	,	,	,
cord-276598-tm0yj2sn	66	31	25	25	CD
cord-276598-tm0yj2sn	66	32	,	,	,
cord-276598-tm0yj2sn	66	33	3684	3684	CD
cord-276598-tm0yj2sn	66	34	4	4	CD
cord-276598-tm0yj2sn	66	35	of	of	IN
cord-276598-tm0yj2sn	66	36	37	37	CD
cord-276598-tm0yj2sn	66	37	counterparts	counterpart	NNS
cord-276598-tm0yj2sn	66	38	[	[	-LRB-
cord-276598-tm0yj2sn	66	39	32	32	CD
cord-276598-tm0yj2sn	66	40	,	,	,
cord-276598-tm0yj2sn	66	41	33	33	CD
cord-276598-tm0yj2sn	66	42	]	]	-RRB-
cord-276598-tm0yj2sn	66	43	.	.	.
cord-276598-tm0yj2sn	67	1	Recently	recently	RB
cord-276598-tm0yj2sn	67	2	,	,	,
cord-276598-tm0yj2sn	67	3	compounds	compound	NNS
cord-276598-tm0yj2sn	67	4	containing	contain	VBG
cord-276598-tm0yj2sn	67	5	both	both	CC
cord-276598-tm0yj2sn	67	6	P	P	NNP
cord-276598-tm0yj2sn	67	7	and	and	CC
cord-276598-tm0yj2sn	67	8	N	n	CD
cord-276598-tm0yj2sn	67	9	atoms	atom	NNS
cord-276598-tm0yj2sn	67	10	in	in	IN
cord-276598-tm0yj2sn	67	11	combination	combination	NN
cord-276598-tm0yj2sn	67	12	have	have	VBP
cord-276598-tm0yj2sn	67	13	been	be	VBN
cord-276598-tm0yj2sn	67	14	reported	report	VBN
cord-276598-tm0yj2sn	67	15	to	to	TO
cord-276598-tm0yj2sn	67	16	have	have	VB
cord-276598-tm0yj2sn	67	17	a	a	DT
cord-276598-tm0yj2sn	67	18	synergistic	synergistic	JJ
cord-276598-tm0yj2sn	67	19	effect	effect	NN
cord-276598-tm0yj2sn	67	20	,	,	,
cord-276598-tm0yj2sn	67	21	as	as	IN
cord-276598-tm0yj2sn	67	22	they	-PRON-	PRP
cord-276598-tm0yj2sn	67	23	can	can	MD
cord-276598-tm0yj2sn	67	24	act	act	VB
cord-276598-tm0yj2sn	67	25	in	in	IN
cord-276598-tm0yj2sn	67	26	both	both	DT
cord-276598-tm0yj2sn	67	27	vapor	vapor	NN
cord-276598-tm0yj2sn	67	28	phase	phase	NN
cord-276598-tm0yj2sn	67	29	and	and	CC
cord-276598-tm0yj2sn	67	30	condensed	condensed	JJ
cord-276598-tm0yj2sn	67	31	phase	phase	NN
cord-276598-tm0yj2sn	67	32	,	,	,
cord-276598-tm0yj2sn	67	33	thus	thus	RB
cord-276598-tm0yj2sn	67	34	offering	offer	VBG
cord-276598-tm0yj2sn	67	35	improved	improve	VBN
cord-276598-tm0yj2sn	67	36	flame	flame	NN
cord-276598-tm0yj2sn	67	37	retardancy	retardancy	NN
cord-276598-tm0yj2sn	67	38	on	on	IN
cord-276598-tm0yj2sn	67	39	various	various	JJ
cord-276598-tm0yj2sn	67	40	substrates	substrate	NNS
cord-276598-tm0yj2sn	67	41	such	such	JJ
cord-276598-tm0yj2sn	67	42	as	as	IN
cord-276598-tm0yj2sn	67	43	polyurethane	polyurethane	NN
cord-276598-tm0yj2sn	67	44	foams	foam	NNS
cord-276598-tm0yj2sn	67	45	,	,	,
cord-276598-tm0yj2sn	67	46	cotton	cotton	NN
cord-276598-tm0yj2sn	67	47	,	,	,
cord-276598-tm0yj2sn	67	48	cellulose	cellulose	NN
cord-276598-tm0yj2sn	67	49	,	,	,
cord-276598-tm0yj2sn	67	50	epoxy	epoxy	NN
cord-276598-tm0yj2sn	67	51	resins	resin	NNS
cord-276598-tm0yj2sn	67	52	,	,	,
cord-276598-tm0yj2sn	67	53	textiles	textile	NNS
cord-276598-tm0yj2sn	67	54	,	,	,
cord-276598-tm0yj2sn	67	55	etc	etc	FW
cord-276598-tm0yj2sn	67	56	.	.	.
cord-276598-tm0yj2sn	68	1	[	[	-LRB-
cord-276598-tm0yj2sn	68	2	34	34	CD
cord-276598-tm0yj2sn	68	3	]	]	-RRB-
cord-276598-tm0yj2sn	68	4	[	[	-LRB-
cord-276598-tm0yj2sn	68	5	35	35	CD
cord-276598-tm0yj2sn	68	6	]	]	-RRB-
cord-276598-tm0yj2sn	68	7	[	[	-LRB-
cord-276598-tm0yj2sn	68	8	36	36	CD
cord-276598-tm0yj2sn	68	9	]	]	-RRB-
cord-276598-tm0yj2sn	69	1	[	[	-LRB-
cord-276598-tm0yj2sn	69	2	37	37	CD
cord-276598-tm0yj2sn	69	3	]	]	-RRB-
cord-276598-tm0yj2sn	69	4	[	[	-LRB-
cord-276598-tm0yj2sn	69	5	38	38	CD
cord-276598-tm0yj2sn	69	6	]	]	-RRB-
cord-276598-tm0yj2sn	70	1	[	[	-LRB-
cord-276598-tm0yj2sn	70	2	39	39	CD
cord-276598-tm0yj2sn	70	3	]	]	-RRB-
cord-276598-tm0yj2sn	70	4	[	[	-LRB-
cord-276598-tm0yj2sn	70	5	40	40	CD
cord-276598-tm0yj2sn	70	6	]	]	-RRB-
cord-276598-tm0yj2sn	70	7	.	.	.
cord-276598-tm0yj2sn	71	1	For	for	IN
cord-276598-tm0yj2sn	71	2	example	example	NN
cord-276598-tm0yj2sn	71	3	,	,	,
cord-276598-tm0yj2sn	71	4	novel	novel	NN
cord-276598-tm0yj2sn	71	5	P	p	NN
cord-276598-tm0yj2sn	71	6	-	-	HYPH
cord-276598-tm0yj2sn	71	7	N	n	NN
cord-276598-tm0yj2sn	71	8	-	-	HYPH
cord-276598-tm0yj2sn	71	9	based	base	VBN
cord-276598-tm0yj2sn	71	10	intumescent	intumescent	NN
cord-276598-tm0yj2sn	71	11	flame	flame	NN
cord-276598-tm0yj2sn	71	12	retardants	retardant	NNS
cord-276598-tm0yj2sn	71	13	have	have	VBP
cord-276598-tm0yj2sn	71	14	been	be	VBN
cord-276598-tm0yj2sn	71	15	incorporated	incorporate	VBN
cord-276598-tm0yj2sn	71	16	into	into	IN
cord-276598-tm0yj2sn	71	17	polycarbonates	polycarbonate	NNS
cord-276598-tm0yj2sn	71	18	(	(	-LRB-
cord-276598-tm0yj2sn	71	19	PC	pc	NN
cord-276598-tm0yj2sn	71	20	)	)	-RRB-
cord-276598-tm0yj2sn	71	21	to	to	TO
cord-276598-tm0yj2sn	71	22	impart	impart	VB
cord-276598-tm0yj2sn	71	23	flame	flame	NN
cord-276598-tm0yj2sn	71	24	retardancy	retardancy	NN
cord-276598-tm0yj2sn	71	25	to	to	IN
cord-276598-tm0yj2sn	71	26	the	the	DT
cord-276598-tm0yj2sn	71	27	composite	composite	NN
cord-276598-tm0yj2sn	71	28	by	by	IN
cord-276598-tm0yj2sn	71	29	forming	form	VBG
cord-276598-tm0yj2sn	71	30	an	an	DT
cord-276598-tm0yj2sn	71	31	expandable	expandable	JJ
cord-276598-tm0yj2sn	71	32	protective	protective	JJ
cord-276598-tm0yj2sn	71	33	char	char	NN
cord-276598-tm0yj2sn	71	34	[	[	-LRB-
cord-276598-tm0yj2sn	71	35	41	41	CD
cord-276598-tm0yj2sn	71	36	]	]	-RRB-
cord-276598-tm0yj2sn	71	37	.	.	.
cord-276598-tm0yj2sn	72	1	MALDI	MALDI	NNP
cord-276598-tm0yj2sn	72	2	-	-	HYPH
cord-276598-tm0yj2sn	72	3	TOF	TOF	NNP
cord-276598-tm0yj2sn	72	4	MS	MS	NNP
cord-276598-tm0yj2sn	72	5	is	be	VBZ
cord-276598-tm0yj2sn	72	6	a	a	DT
cord-276598-tm0yj2sn	72	7	prominent	prominent	JJ
cord-276598-tm0yj2sn	72	8	tool	tool	NN
cord-276598-tm0yj2sn	72	9	for	for	IN
cord-276598-tm0yj2sn	72	10	analyzing	analyze	VBG
cord-276598-tm0yj2sn	72	11	biomolecules	biomolecule	NNS
cord-276598-tm0yj2sn	72	12	(	(	-LRB-
cord-276598-tm0yj2sn	72	13	Figure	figure	NN
cord-276598-tm0yj2sn	72	14	3	3	CD
cord-276598-tm0yj2sn	72	15	)	)	-RRB-
cord-276598-tm0yj2sn	73	1	[	[	-LRB-
cord-276598-tm0yj2sn	73	2	42	42	CD
cord-276598-tm0yj2sn	73	3	]	]	-RRB-
cord-276598-tm0yj2sn	73	4	.	.	.
cord-276598-tm0yj2sn	74	1	For	for	IN
cord-276598-tm0yj2sn	74	2	the	the	DT
cord-276598-tm0yj2sn	74	3	detection	detection	NN
cord-276598-tm0yj2sn	74	4	of	of	IN
cord-276598-tm0yj2sn	74	5	low	low	JJ
cord-276598-tm0yj2sn	74	6	molecular	molecular	JJ
cord-276598-tm0yj2sn	74	7	weight	weight	NN
cord-276598-tm0yj2sn	74	8	such	such	JJ
cord-276598-tm0yj2sn	74	9	as	as	IN
cord-276598-tm0yj2sn	74	10	amino	amino	JJ
cord-276598-tm0yj2sn	74	11	acids	acid	NNS
cord-276598-tm0yj2sn	74	12	and	and	CC
cord-276598-tm0yj2sn	74	13	peptides	peptide	NNS
cord-276598-tm0yj2sn	74	14	,	,	,
cord-276598-tm0yj2sn	74	15	conventional	conventional	JJ
cord-276598-tm0yj2sn	74	16	matrices	matrix	NNS
cord-276598-tm0yj2sn	74	17	yield	yield	VBP
cord-276598-tm0yj2sn	74	18	a	a	DT
cord-276598-tm0yj2sn	74	19	lot	lot	NN
cord-276598-tm0yj2sn	74	20	of	of	IN
cord-276598-tm0yj2sn	74	21	matrix	matrix	NN
cord-276598-tm0yj2sn	74	22	-	-	HYPH
cord-276598-tm0yj2sn	74	23	related	relate	VBN
cord-276598-tm0yj2sn	74	24	ions	ion	NNS
cord-276598-tm0yj2sn	74	25	in	in	IN
cord-276598-tm0yj2sn	74	26	the	the	DT
cord-276598-tm0yj2sn	74	27	low	low	JJ
cord-276598-tm0yj2sn	74	28	m	m	NN
cord-276598-tm0yj2sn	74	29	/	/	SYM
cord-276598-tm0yj2sn	74	30	z	z	CD
cord-276598-tm0yj2sn	74	31	range	range	NN
cord-276598-tm0yj2sn	74	32	of	of	IN
cord-276598-tm0yj2sn	74	33	the	the	DT
cord-276598-tm0yj2sn	74	34	spectrum	spectrum	NN
cord-276598-tm0yj2sn	74	35	,	,	,
cord-276598-tm0yj2sn	74	36	thus	thus	RB
cord-276598-tm0yj2sn	74	37	interfering	interfere	VBG
cord-276598-tm0yj2sn	74	38	with	with	IN
cord-276598-tm0yj2sn	74	39	analyte	analyte	NN
cord-276598-tm0yj2sn	74	40	signals	signal	NNS
cord-276598-tm0yj2sn	74	41	.	.	.
cord-276598-tm0yj2sn	75	1	To	to	TO
cord-276598-tm0yj2sn	75	2	tackle	tackle	VB
cord-276598-tm0yj2sn	75	3	this	this	DT
cord-276598-tm0yj2sn	75	4	,	,	,
cord-276598-tm0yj2sn	75	5	various	various	JJ
cord-276598-tm0yj2sn	75	6	approaches	approach	NNS
cord-276598-tm0yj2sn	75	7	such	such	JJ
cord-276598-tm0yj2sn	75	8	as	as	IN
cord-276598-tm0yj2sn	75	9	using	use	VBG
cord-276598-tm0yj2sn	75	10	additives	additive	NNS
cord-276598-tm0yj2sn	75	11	in	in	IN
cord-276598-tm0yj2sn	75	12	the	the	DT
cord-276598-tm0yj2sn	75	13	organic	organic	JJ
cord-276598-tm0yj2sn	75	14	matrix	matrix	NN
cord-276598-tm0yj2sn	75	15	,	,	,
cord-276598-tm0yj2sn	75	16	high	high	JJ
cord-276598-tm0yj2sn	75	17	mass	mass	NN
cord-276598-tm0yj2sn	75	18	matrix	matrix	NN
cord-276598-tm0yj2sn	75	19	molecules	molecule	NNS
cord-276598-tm0yj2sn	75	20	,	,	,
cord-276598-tm0yj2sn	75	21	or	or	CC
cord-276598-tm0yj2sn	75	22	matrices	matrix	NNS
cord-276598-tm0yj2sn	75	23	based	base	VBN
cord-276598-tm0yj2sn	75	24	on	on	IN
cord-276598-tm0yj2sn	75	25	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	75	26	compounds	compound	NNS
cord-276598-tm0yj2sn	75	27	have	have	VBP
cord-276598-tm0yj2sn	75	28	been	be	VBN
cord-276598-tm0yj2sn	75	29	employed	employ	VBN
cord-276598-tm0yj2sn	75	30	[	[	-LRB-
cord-276598-tm0yj2sn	75	31	43	43	CD
cord-276598-tm0yj2sn	75	32	]	]	-RRB-
cord-276598-tm0yj2sn	75	33	.	.	.
cord-276598-tm0yj2sn	76	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	76	2	,	,	,
cord-276598-tm0yj2sn	76	3	to	to	TO
cord-276598-tm0yj2sn	76	4	improve	improve	VB
cord-276598-tm0yj2sn	76	5	analysis	analysis	NN
cord-276598-tm0yj2sn	76	6	,	,	,
cord-276598-tm0yj2sn	76	7	synthesizing	synthesize	VBG
cord-276598-tm0yj2sn	76	8	derivatives	derivative	NNS
cord-276598-tm0yj2sn	76	9	of	of	IN
cord-276598-tm0yj2sn	76	10	small	small	JJ
cord-276598-tm0yj2sn	76	11	analyte	analyte	NN
cord-276598-tm0yj2sn	76	12	molecules	molecule	NNS
cord-276598-tm0yj2sn	76	13	by	by	IN
cord-276598-tm0yj2sn	76	14	N	n	CD
cord-276598-tm0yj2sn	76	15	-	-	HYPH
cord-276598-tm0yj2sn	76	16	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	76	17	labeling	labeling	NN
cord-276598-tm0yj2sn	76	18	has	have	VBZ
cord-276598-tm0yj2sn	76	19	been	be	VBN
cord-276598-tm0yj2sn	76	20	done	do	VBN
cord-276598-tm0yj2sn	76	21	.	.	.
cord-276598-tm0yj2sn	77	1	The	the	DT
cord-276598-tm0yj2sn	77	2	neutral	neutral	JJ
cord-276598-tm0yj2sn	77	3	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	77	4	group	group	NN
cord-276598-tm0yj2sn	77	5	attached	attach	VBN
cord-276598-tm0yj2sn	77	6	at	at	IN
cord-276598-tm0yj2sn	77	7	the	the	DT
cord-276598-tm0yj2sn	77	8	N	n	CD
cord-276598-tm0yj2sn	77	9	-	-	HYPH
cord-276598-tm0yj2sn	77	10	terminal	terminal	NN
cord-276598-tm0yj2sn	77	11	of	of	IN
cord-276598-tm0yj2sn	77	12	amino	amino	JJ
cord-276598-tm0yj2sn	77	13	acids	acid	NNS
cord-276598-tm0yj2sn	77	14	suppresses	suppress	VBZ
cord-276598-tm0yj2sn	77	15	the	the	DT
cord-276598-tm0yj2sn	77	16	matrix	matrix	NN
cord-276598-tm0yj2sn	77	17	signals	signal	NNS
cord-276598-tm0yj2sn	77	18	and	and	CC
cord-276598-tm0yj2sn	77	19	favors	favor	VBZ
cord-276598-tm0yj2sn	77	20	the	the	DT
cord-276598-tm0yj2sn	77	21	transfer	transfer	NN
cord-276598-tm0yj2sn	77	22	of	of	IN
cord-276598-tm0yj2sn	77	23	energy	energy	NN
cord-276598-tm0yj2sn	77	24	from	from	IN
cord-276598-tm0yj2sn	77	25	matrix	matrix	NN
cord-276598-tm0yj2sn	77	26	to	to	IN
cord-276598-tm0yj2sn	77	27	analyte	analyte	NN
cord-276598-tm0yj2sn	77	28	for	for	IN
cord-276598-tm0yj2sn	77	29	ionization	ionization	NN
cord-276598-tm0yj2sn	77	30	by	by	IN
cord-276598-tm0yj2sn	77	31	secondary	secondary	JJ
cord-276598-tm0yj2sn	77	32	ion	ion	NN
cord-276598-tm0yj2sn	77	33	-	-	HYPH
cord-276598-tm0yj2sn	77	34	molecule	molecule	NN
cord-276598-tm0yj2sn	77	35	reactions	reaction	NNS
cord-276598-tm0yj2sn	77	36	.	.	.
cord-276598-tm0yj2sn	78	1	Therefore	therefore	RB
cord-276598-tm0yj2sn	78	2	,	,	,
cord-276598-tm0yj2sn	78	3	P	P	NNP
cord-276598-tm0yj2sn	78	4	-	-	HYPH
cord-276598-tm0yj2sn	78	5	Ns	Ns	NNP
cord-276598-tm0yj2sn	78	6	have	have	VBP
cord-276598-tm0yj2sn	78	7	been	be	VBN
cord-276598-tm0yj2sn	78	8	used	use	VBN
cord-276598-tm0yj2sn	78	9	for	for	IN
cord-276598-tm0yj2sn	78	10	analysis	analysis	NN
cord-276598-tm0yj2sn	78	11	of	of	IN
cord-276598-tm0yj2sn	78	12	biomolecules	biomolecule	NNS
cord-276598-tm0yj2sn	78	13	to	to	TO
cord-276598-tm0yj2sn	78	14	improve	improve	VB
cord-276598-tm0yj2sn	78	15	the	the	DT
cord-276598-tm0yj2sn	78	16	ionization	ionization	NN
cord-276598-tm0yj2sn	78	17	efficiency	efficiency	NN
cord-276598-tm0yj2sn	78	18	and	and	CC
cord-276598-tm0yj2sn	78	19	suppress	suppress	VB
cord-276598-tm0yj2sn	78	20	matrix	matrix	NN
cord-276598-tm0yj2sn	78	21	background	background	NN
cord-276598-tm0yj2sn	78	22	signals	signal	NNS
cord-276598-tm0yj2sn	78	23	[	[	-LRB-
cord-276598-tm0yj2sn	78	24	44	44	CD
cord-276598-tm0yj2sn	78	25	]	]	-RRB-
cord-276598-tm0yj2sn	78	26	.	.	.
cord-276598-tm0yj2sn	79	1	In	in	IN
cord-276598-tm0yj2sn	79	2	addition	addition	NN
cord-276598-tm0yj2sn	79	3	to	to	IN
cord-276598-tm0yj2sn	79	4	this	this	DT
cord-276598-tm0yj2sn	79	5	,	,	,
cord-276598-tm0yj2sn	79	6	P	P	NNP
cord-276598-tm0yj2sn	79	7	-	-	HYPH
cord-276598-tm0yj2sn	79	8	Ns	Ns	NNP
cord-276598-tm0yj2sn	79	9	have	have	VBP
cord-276598-tm0yj2sn	79	10	found	find	VBN
cord-276598-tm0yj2sn	79	11	novel	novel	JJ
cord-276598-tm0yj2sn	79	12	applications	application	NNS
cord-276598-tm0yj2sn	79	13	as	as	IN
cord-276598-tm0yj2sn	79	14	task	task	NN
cord-276598-tm0yj2sn	79	15	-	-	HYPH
cord-276598-tm0yj2sn	79	16	specific	specific	JJ
cord-276598-tm0yj2sn	79	17	ionic	ionic	JJ
cord-276598-tm0yj2sn	79	18	liquids	liquid	NNS
cord-276598-tm0yj2sn	79	19	(	(	-LRB-
cord-276598-tm0yj2sn	79	20	TSILs	TSILs	NNP
cord-276598-tm0yj2sn	79	21	)	)	-RRB-
cord-276598-tm0yj2sn	79	22	,	,	,
cord-276598-tm0yj2sn	79	23	which	which	WDT
cord-276598-tm0yj2sn	79	24	are	be	VBP
cord-276598-tm0yj2sn	79	25	tailored	tailor	VBN
cord-276598-tm0yj2sn	79	26	ionic	ionic	JJ
cord-276598-tm0yj2sn	79	27	liquids	liquid	NNS
cord-276598-tm0yj2sn	79	28	having	have	VBG
cord-276598-tm0yj2sn	79	29	a	a	DT
cord-276598-tm0yj2sn	79	30	specific	specific	JJ
cord-276598-tm0yj2sn	79	31	functionality	functionality	NN
cord-276598-tm0yj2sn	79	32	to	to	IN
cord-276598-tm0yj2sn	79	33	complex	complex	JJ
cord-276598-tm0yj2sn	79	34	metal	metal	NN
cord-276598-tm0yj2sn	79	35	ions	ion	NNS
cord-276598-tm0yj2sn	79	36	.	.	.
cord-276598-tm0yj2sn	80	1	Recently	recently	RB
cord-276598-tm0yj2sn	80	2	,	,	,
cord-276598-tm0yj2sn	80	3	these	these	DT
cord-276598-tm0yj2sn	80	4	TSILs	tsil	NNS
cord-276598-tm0yj2sn	80	5	have	have	VBP
cord-276598-tm0yj2sn	80	6	been	be	VBN
cord-276598-tm0yj2sn	80	7	used	use	VBN
cord-276598-tm0yj2sn	80	8	for	for	IN
cord-276598-tm0yj2sn	80	9	the	the	DT
cord-276598-tm0yj2sn	80	10	efficient	efficient	JJ
cord-276598-tm0yj2sn	80	11	extraction	extraction	NN
cord-276598-tm0yj2sn	80	12	of	of	IN
cord-276598-tm0yj2sn	80	13	uranium	uranium	NN
cord-276598-tm0yj2sn	80	14	metal	metal	NN
cord-276598-tm0yj2sn	80	15	,	,	,
cord-276598-tm0yj2sn	80	16	which	which	WDT
cord-276598-tm0yj2sn	80	17	is	be	VBZ
cord-276598-tm0yj2sn	80	18	an	an	DT
cord-276598-tm0yj2sn	80	19	important	important	JJ
cord-276598-tm0yj2sn	80	20	element	element	NN
cord-276598-tm0yj2sn	80	21	in	in	IN
cord-276598-tm0yj2sn	80	22	nuclear	nuclear	JJ
cord-276598-tm0yj2sn	80	23	fuel	fuel	NN
cord-276598-tm0yj2sn	80	24	,	,	,
cord-276598-tm0yj2sn	80	25	and	and	CC
cord-276598-tm0yj2sn	80	26	the	the	DT
cord-276598-tm0yj2sn	80	27	extraction	extraction	NN
cord-276598-tm0yj2sn	80	28	of	of	IN
cord-276598-tm0yj2sn	80	29	uranium	uranium	NN
cord-276598-tm0yj2sn	80	30	metal	metal	NN
cord-276598-tm0yj2sn	80	31	from	from	IN
cord-276598-tm0yj2sn	80	32	the	the	DT
cord-276598-tm0yj2sn	80	33	spent	spend	VBN
cord-276598-tm0yj2sn	80	34	/	/	SYM
cord-276598-tm0yj2sn	80	35	used	use	VBN
cord-276598-tm0yj2sn	80	36	nuclear	nuclear	JJ
cord-276598-tm0yj2sn	80	37	fuel	fuel	NN
cord-276598-tm0yj2sn	80	38	is	be	VBZ
cord-276598-tm0yj2sn	80	39	vital	vital	JJ
cord-276598-tm0yj2sn	80	40	for	for	IN
cord-276598-tm0yj2sn	80	41	the	the	DT
cord-276598-tm0yj2sn	80	42	sustainable	sustainable	JJ
cord-276598-tm0yj2sn	80	43	economy	economy	NN
cord-276598-tm0yj2sn	80	44	[	[	-LRB-
cord-276598-tm0yj2sn	80	45	45	45	CD
cord-276598-tm0yj2sn	80	46	]	]	-RRB-
cord-276598-tm0yj2sn	80	47	.	.	.
cord-276598-tm0yj2sn	81	1	The	the	DT
cord-276598-tm0yj2sn	81	2	enhanced	enhanced	JJ
cord-276598-tm0yj2sn	81	3	extraction	extraction	NN
cord-276598-tm0yj2sn	81	4	capabilities	capability	NNS
cord-276598-tm0yj2sn	81	5	using	use	VBG
cord-276598-tm0yj2sn	81	6	TSILs	tsil	NNS
cord-276598-tm0yj2sn	81	7	in	in	IN
cord-276598-tm0yj2sn	81	8	contrast	contrast	NN
cord-276598-tm0yj2sn	81	9	to	to	IN
cord-276598-tm0yj2sn	81	10	liquid	liquid	JJ
cord-276598-tm0yj2sn	81	11	-	-	HYPH
cord-276598-tm0yj2sn	81	12	liquid	liquid	NN
cord-276598-tm0yj2sn	81	13	extraction	extraction	NN
cord-276598-tm0yj2sn	81	14	could	could	MD
cord-276598-tm0yj2sn	81	15	be	be	VB
cord-276598-tm0yj2sn	81	16	attributed	attribute	VBN
cord-276598-tm0yj2sn	81	17	to	to	IN
cord-276598-tm0yj2sn	81	18	synergistic	synergistic	JJ
cord-276598-tm0yj2sn	81	19	effects	effect	NNS
cord-276598-tm0yj2sn	81	20	as	as	IN
cord-276598-tm0yj2sn	81	21	a	a	DT
cord-276598-tm0yj2sn	81	22	result	result	NN
cord-276598-tm0yj2sn	81	23	of	of	IN
cord-276598-tm0yj2sn	81	24	complexation	complexation	NN
cord-276598-tm0yj2sn	81	25	and	and	CC
cord-276598-tm0yj2sn	81	26	H	h	NN
cord-276598-tm0yj2sn	81	27	-	-	HYPH
cord-276598-tm0yj2sn	81	28	bonding	bonding	NN
cord-276598-tm0yj2sn	81	29	[	[	-LRB-
cord-276598-tm0yj2sn	81	30	17	17	CD
cord-276598-tm0yj2sn	81	31	]	]	-RRB-
cord-276598-tm0yj2sn	81	32	.	.	.
cord-276598-tm0yj2sn	82	1	To	to	IN
cord-276598-tm0yj2sn	82	2	this	this	DT
cord-276598-tm0yj2sn	82	3	end	end	NN
cord-276598-tm0yj2sn	82	4	,	,	,
cord-276598-tm0yj2sn	82	5	these	these	DT
cord-276598-tm0yj2sn	82	6	tailored	tailor	VBN
cord-276598-tm0yj2sn	82	7	ionic	ionic	JJ
cord-276598-tm0yj2sn	82	8	liquids	liquid	NNS
cord-276598-tm0yj2sn	82	9	have	have	VBP
cord-276598-tm0yj2sn	82	10	been	be	VBN
cord-276598-tm0yj2sn	82	11	found	find	VBN
cord-276598-tm0yj2sn	82	12	to	to	TO
cord-276598-tm0yj2sn	82	13	be	be	VB
cord-276598-tm0yj2sn	82	14	selective	selective	JJ
cord-276598-tm0yj2sn	82	15	for	for	IN
cord-276598-tm0yj2sn	82	16	the	the	DT
cord-276598-tm0yj2sn	82	17	micellar	micellar	JJ
cord-276598-tm0yj2sn	82	18	extraction	extraction	NN
cord-276598-tm0yj2sn	82	19	of	of	IN
cord-276598-tm0yj2sn	82	20	uranium	uranium	NN
cord-276598-tm0yj2sn	82	21	metal	metal	NN
cord-276598-tm0yj2sn	82	22	from	from	IN
cord-276598-tm0yj2sn	82	23	aqueous	aqueous	JJ
cord-276598-tm0yj2sn	82	24	waste	waste	NN
cord-276598-tm0yj2sn	82	25	samples	sample	NNS
cord-276598-tm0yj2sn	82	26	as	as	IN
cord-276598-tm0yj2sn	82	27	even	even	RB
cord-276598-tm0yj2sn	82	28	the	the	DT
cord-276598-tm0yj2sn	82	29	ultra	ultra	JJ
cord-276598-tm0yj2sn	82	30	-	-	JJ
cord-276598-tm0yj2sn	82	31	trace	trace	JJ
cord-276598-tm0yj2sn	82	32	levels	level	NNS
cord-276598-tm0yj2sn	82	33	of	of	IN
cord-276598-tm0yj2sn	82	34	uranium	uranium	NN
cord-276598-tm0yj2sn	82	35	are	be	VBP
cord-276598-tm0yj2sn	82	36	toxic	toxic	JJ
cord-276598-tm0yj2sn	82	37	[	[	-LRB-
cord-276598-tm0yj2sn	82	38	46	46	CD
cord-276598-tm0yj2sn	82	39	]	]	-RRB-
cord-276598-tm0yj2sn	82	40	.	.	.
cord-276598-tm0yj2sn	83	1	P	p	NN
cord-276598-tm0yj2sn	83	2	-	-	HYPH
cord-276598-tm0yj2sn	83	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	83	4	act	act	NN
cord-276598-tm0yj2sn	83	5	as	as	IN
cord-276598-tm0yj2sn	83	6	1,3-N	1,3-n	CD
cord-276598-tm0yj2sn	83	7	,	,	,
cord-276598-tm0yj2sn	83	8	O	o	NN
cord-276598-tm0yj2sn	83	9	-	-	HYPH
cord-276598-tm0yj2sn	83	10	chelating	chelate	VBG
cord-276598-tm0yj2sn	83	11	ligands	ligand	NNS
cord-276598-tm0yj2sn	83	12	(	(	-LRB-
cord-276598-tm0yj2sn	83	13	e.g.	e.g.	RB
cord-276598-tm0yj2sn	83	14	,	,	,
cord-276598-tm0yj2sn	83	15	Figure	figure	NN
cord-276598-tm0yj2sn	83	16	3	3	CD
cord-276598-tm0yj2sn	83	17	,	,	,
cord-276598-tm0yj2sn	83	18	Ligand	Ligand	NNP
cord-276598-tm0yj2sn	83	19	)	)	-RRB-
cord-276598-tm0yj2sn	83	20	and	and	CC
cord-276598-tm0yj2sn	83	21	have	have	VBP
cord-276598-tm0yj2sn	83	22	diverse	diverse	JJ
cord-276598-tm0yj2sn	83	23	applications	application	NNS
cord-276598-tm0yj2sn	83	24	in	in	IN
cord-276598-tm0yj2sn	83	25	the	the	DT
cord-276598-tm0yj2sn	83	26	field	field	NN
cord-276598-tm0yj2sn	83	27	of	of	IN
cord-276598-tm0yj2sn	83	28	coordination	coordination	NN
cord-276598-tm0yj2sn	83	29	chemistry	chemistry	NN
cord-276598-tm0yj2sn	83	30	for	for	IN
cord-276598-tm0yj2sn	83	31	bond	bond	NN
cord-276598-tm0yj2sn	83	32	activation	activation	NN
cord-276598-tm0yj2sn	83	33	,	,	,
cord-276598-tm0yj2sn	83	34	catalysis	catalysis	NN
cord-276598-tm0yj2sn	83	35	,	,	,
cord-276598-tm0yj2sn	83	36	and	and	CC
cord-276598-tm0yj2sn	83	37	metal	metal	NN
cord-276598-tm0yj2sn	83	38	ligand	ligand	NN
cord-276598-tm0yj2sn	83	39	cooperativity	cooperativity	NN
cord-276598-tm0yj2sn	83	40	[	[	-LRB-
cord-276598-tm0yj2sn	83	41	47	47	CD
cord-276598-tm0yj2sn	83	42	]	]	-RRB-
cord-276598-tm0yj2sn	84	1	[	[	-LRB-
cord-276598-tm0yj2sn	84	2	48	48	CD
cord-276598-tm0yj2sn	84	3	]	]	-RRB-
cord-276598-tm0yj2sn	84	4	[	[	-LRB-
cord-276598-tm0yj2sn	84	5	49	49	CD
cord-276598-tm0yj2sn	84	6	]	]	-RRB-
cord-276598-tm0yj2sn	84	7	.	.	.
cord-276598-tm0yj2sn	85	1	For	for	IN
cord-276598-tm0yj2sn	85	2	example	example	NN
cord-276598-tm0yj2sn	85	3	,	,	,
cord-276598-tm0yj2sn	85	4	a	a	DT
cord-276598-tm0yj2sn	85	5	P	P	NNP
cord-276598-tm0yj2sn	85	6	-	-	HYPH
cord-276598-tm0yj2sn	85	7	N	n	NN
cord-276598-tm0yj2sn	85	8	-	-	HYPH
cord-276598-tm0yj2sn	85	9	tantalum	tantalum	NN
cord-276598-tm0yj2sn	85	10	complex	complex	NN
cord-276598-tm0yj2sn	85	11	has	have	VBZ
cord-276598-tm0yj2sn	85	12	been	be	VBN
cord-276598-tm0yj2sn	85	13	developed	develop	VBN
cord-276598-tm0yj2sn	85	14	as	as	IN
cord-276598-tm0yj2sn	85	15	a	a	DT
cord-276598-tm0yj2sn	85	16	pre	pre	NN
cord-276598-tm0yj2sn	85	17	-	-	NN
cord-276598-tm0yj2sn	85	18	catalyst	catalyst	NN
cord-276598-tm0yj2sn	85	19	for	for	IN
cord-276598-tm0yj2sn	85	20	hydroaminoalkylation	hydroaminoalkylation	NN
cord-276598-tm0yj2sn	85	21	reactions	reaction	NNS
cord-276598-tm0yj2sn	85	22	[	[	-LRB-
cord-276598-tm0yj2sn	85	23	50	50	CD
cord-276598-tm0yj2sn	85	24	]	]	-RRB-
cord-276598-tm0yj2sn	85	25	.	.	.
cord-276598-tm0yj2sn	86	1	In	in	IN
cord-276598-tm0yj2sn	86	2	addition	addition	NN
cord-276598-tm0yj2sn	86	3	,	,	,
cord-276598-tm0yj2sn	86	4	the	the	DT
cord-276598-tm0yj2sn	86	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	86	6	of	of	IN
cord-276598-tm0yj2sn	86	7	medium	medium	JJ
cord-276598-tm0yj2sn	86	8	and	and	CC
cord-276598-tm0yj2sn	86	9	large	large	JJ
cord-276598-tm0yj2sn	86	10	N	n	CD
cord-276598-tm0yj2sn	86	11	-	-	HYPH
cord-276598-tm0yj2sn	86	12	based	base	VBN
cord-276598-tm0yj2sn	86	13	heterocycles	heterocycle	NNS
cord-276598-tm0yj2sn	86	14	has	have	VBZ
cord-276598-tm0yj2sn	86	15	been	be	VBN
cord-276598-tm0yj2sn	86	16	achieved	achieve	VBN
cord-276598-tm0yj2sn	86	17	with	with	IN
cord-276598-tm0yj2sn	86	18	the	the	DT
cord-276598-tm0yj2sn	86	19	aid	aid	NN
cord-276598-tm0yj2sn	86	20	of	of	IN
cord-276598-tm0yj2sn	86	21	P	p	NN
cord-276598-tm0yj2sn	86	22	-	-	HYPH
cord-276598-tm0yj2sn	86	23	Ns	Ns	NNP
cord-276598-tm0yj2sn	86	24	,	,	,
cord-276598-tm0yj2sn	86	25	as	as	IN
cord-276598-tm0yj2sn	86	26	the	the	DT
cord-276598-tm0yj2sn	86	27	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	86	28	group	group	NN
cord-276598-tm0yj2sn	86	29	improves	improve	VBZ
cord-276598-tm0yj2sn	86	30	intramolecular	intramolecular	JJ
cord-276598-tm0yj2sn	86	31	cyclization	cyclization	NN
cord-276598-tm0yj2sn	86	32	,	,	,
cord-276598-tm0yj2sn	86	33	and	and	CC
cord-276598-tm0yj2sn	86	34	it	-PRON-	PRP
cord-276598-tm0yj2sn	86	35	can	can	MD
cord-276598-tm0yj2sn	86	36	also	also	RB
cord-276598-tm0yj2sn	86	37	be	be	VB
cord-276598-tm0yj2sn	86	38	easily	easily	RB
cord-276598-tm0yj2sn	86	39	removed	remove	VBN
cord-276598-tm0yj2sn	86	40	afterwards	afterwards	RB
cord-276598-tm0yj2sn	86	41	[	[	-LRB-
cord-276598-tm0yj2sn	86	42	51	51	CD
cord-276598-tm0yj2sn	86	43	]	]	-RRB-
cord-276598-tm0yj2sn	86	44	.	.	.
cord-276598-tm0yj2sn	87	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	87	2	,	,	,
cord-276598-tm0yj2sn	87	3	P	P	NNP
cord-276598-tm0yj2sn	87	4	-	-	HYPH
cord-276598-tm0yj2sn	87	5	Ns	Ns	NNP
cord-276598-tm0yj2sn	87	6	have	have	VBP
cord-276598-tm0yj2sn	87	7	been	be	VBN
cord-276598-tm0yj2sn	87	8	used	use	VBN
cord-276598-tm0yj2sn	87	9	as	as	IN
cord-276598-tm0yj2sn	87	10	directing	direct	VBG
cord-276598-tm0yj2sn	87	11	groups	group	NNS
cord-276598-tm0yj2sn	87	12	for	for	IN
cord-276598-tm0yj2sn	87	13	arylation	arylation	NN
cord-276598-tm0yj2sn	87	14	reactions	reaction	NNS
cord-276598-tm0yj2sn	87	15	,	,	,
cord-276598-tm0yj2sn	87	16	as	as	IN
cord-276598-tm0yj2sn	87	17	they	-PRON-	PRP
cord-276598-tm0yj2sn	87	18	selectively	selectively	RB
cord-276598-tm0yj2sn	87	19	activate	activate	VBP
cord-276598-tm0yj2sn	87	20	C	C	NNP
cord-276598-tm0yj2sn	87	21	-	-	HYPH
cord-276598-tm0yj2sn	87	22	H	H	NNP
cord-276598-tm0yj2sn	87	23	bonds	bond	NNS
cord-276598-tm0yj2sn	87	24	,	,	,
cord-276598-tm0yj2sn	87	25	and	and	CC
cord-276598-tm0yj2sn	87	26	thus	thus	RB
cord-276598-tm0yj2sn	87	27	,	,	,
cord-276598-tm0yj2sn	87	28	desired	desire	VBN
cord-276598-tm0yj2sn	87	29	functionality	functionality	NN
cord-276598-tm0yj2sn	87	30	can	can	MD
cord-276598-tm0yj2sn	87	31	be	be	VB
cord-276598-tm0yj2sn	87	32	achieved	achieve	VBN
cord-276598-tm0yj2sn	87	33	[	[	-LRB-
cord-276598-tm0yj2sn	87	34	52	52	CD
cord-276598-tm0yj2sn	87	35	]	]	-RRB-
cord-276598-tm0yj2sn	87	36	.	.	.
cord-276598-tm0yj2sn	88	1	P	p	NN
cord-276598-tm0yj2sn	88	2	-	-	HYPH
cord-276598-tm0yj2sn	88	3	Ns	Ns	NNP
cord-276598-tm0yj2sn	88	4	have	have	VBP
cord-276598-tm0yj2sn	88	5	garnered	garner	VBN
cord-276598-tm0yj2sn	88	6	considerable	considerable	JJ
cord-276598-tm0yj2sn	88	7	interest	interest	NN
cord-276598-tm0yj2sn	88	8	in	in	IN
cord-276598-tm0yj2sn	88	9	the	the	DT
cord-276598-tm0yj2sn	88	10	field	field	NN
cord-276598-tm0yj2sn	88	11	of	of	IN
cord-276598-tm0yj2sn	88	12	biomedicine	biomedicine	NN
cord-276598-tm0yj2sn	88	13	due	due	IN
cord-276598-tm0yj2sn	88	14	to	to	IN
cord-276598-tm0yj2sn	88	15	their	-PRON-	PRP$
cord-276598-tm0yj2sn	88	16	potential	potential	JJ
cord-276598-tm0yj2sn	88	17	applications	application	NNS
cord-276598-tm0yj2sn	88	18	as	as	IN
cord-276598-tm0yj2sn	88	19	antimicrobial	antimicrobial	JJ
cord-276598-tm0yj2sn	88	20	[	[	-LRB-
cord-276598-tm0yj2sn	88	21	53	53	CD
cord-276598-tm0yj2sn	88	22	]	]	-RRB-
cord-276598-tm0yj2sn	88	23	[	[	-LRB-
cord-276598-tm0yj2sn	88	24	54	54	CD
cord-276598-tm0yj2sn	88	25	]	]	-RRB-
cord-276598-tm0yj2sn	88	26	[	[	-LRB-
cord-276598-tm0yj2sn	88	27	55	55	CD
cord-276598-tm0yj2sn	88	28	]	]	-RRB-
cord-276598-tm0yj2sn	88	29	,	,	,
cord-276598-tm0yj2sn	88	30	antioxidant	antioxidant	JJ
cord-276598-tm0yj2sn	88	31	[	[	-LRB-
cord-276598-tm0yj2sn	88	32	56	56	CD
cord-276598-tm0yj2sn	88	33	]	]	-RRB-
cord-276598-tm0yj2sn	88	34	,	,	,
cord-276598-tm0yj2sn	88	35	anticancer	anticancer	JJ
cord-276598-tm0yj2sn	88	36	[	[	-LRB-
cord-276598-tm0yj2sn	88	37	57	57	CD
cord-276598-tm0yj2sn	88	38	]	]	-RRB-
cord-276598-tm0yj2sn	88	39	,	,	,
cord-276598-tm0yj2sn	88	40	antimalarial	antimalarial	JJ
cord-276598-tm0yj2sn	88	41	[	[	-LRB-
cord-276598-tm0yj2sn	88	42	58	58	CD
cord-276598-tm0yj2sn	88	43	]	]	-RRB-
cord-276598-tm0yj2sn	88	44	,	,	,
cord-276598-tm0yj2sn	88	45	antiviral	antiviral	JJ
cord-276598-tm0yj2sn	88	46	[	[	-LRB-
cord-276598-tm0yj2sn	88	47	59	59	CD
cord-276598-tm0yj2sn	88	48	,	,	,
cord-276598-tm0yj2sn	88	49	60	60	CD
cord-276598-tm0yj2sn	88	50	]	]	-RRB-
cord-276598-tm0yj2sn	88	51	,	,	,
cord-276598-tm0yj2sn	88	52	and	and	CC
cord-276598-tm0yj2sn	88	53	anti	anti	JJ
cord-276598-tm0yj2sn	88	54	-	-	JJ
cord-276598-tm0yj2sn	88	55	HIV	HIV	NNP
cord-276598-tm0yj2sn	88	56	[	[	-LRB-
cord-276598-tm0yj2sn	88	57	61	61	CD
cord-276598-tm0yj2sn	88	58	]	]	-RRB-
cord-276598-tm0yj2sn	88	59	drugs	drug	NNS
cord-276598-tm0yj2sn	88	60	and	and	CC
cord-276598-tm0yj2sn	88	61	prodrugs	prodrug	NNS
cord-276598-tm0yj2sn	88	62	against	against	IN
cord-276598-tm0yj2sn	88	63	various	various	JJ
cord-276598-tm0yj2sn	88	64	ailments	ailment	NNS
cord-276598-tm0yj2sn	88	65	(	(	-LRB-
cord-276598-tm0yj2sn	88	66	Figure	figure	NN
cord-276598-tm0yj2sn	88	67	3	3	CD
cord-276598-tm0yj2sn	88	68	)	)	-RRB-
cord-276598-tm0yj2sn	88	69	.	.	.
cord-276598-tm0yj2sn	89	1	The	the	DT
cord-276598-tm0yj2sn	89	2	ProTide	ProTide	NNP
cord-276598-tm0yj2sn	89	3	approach	approach	NN
cord-276598-tm0yj2sn	89	4	,	,	,
cord-276598-tm0yj2sn	89	5	pioneered	pioneer	VBN
cord-276598-tm0yj2sn	89	6	by	by	IN
cord-276598-tm0yj2sn	89	7	the	the	DT
cord-276598-tm0yj2sn	89	8	McGuigan	McGuigan	NNP
cord-276598-tm0yj2sn	89	9	group	group	NN
cord-276598-tm0yj2sn	89	10	in	in	IN
cord-276598-tm0yj2sn	89	11	1992	1992	CD
cord-276598-tm0yj2sn	89	12	for	for	IN
cord-276598-tm0yj2sn	89	13	drug	drug	NN
cord-276598-tm0yj2sn	89	14	delivery	delivery	NN
cord-276598-tm0yj2sn	89	15	,	,	,
cord-276598-tm0yj2sn	89	16	is	be	VBZ
cord-276598-tm0yj2sn	89	17	a	a	DT
cord-276598-tm0yj2sn	89	18	powerful	powerful	JJ
cord-276598-tm0yj2sn	89	19	tool	tool	NN
cord-276598-tm0yj2sn	89	20	to	to	TO
cord-276598-tm0yj2sn	89	21	enhance	enhance	VB
cord-276598-tm0yj2sn	89	22	the	the	DT
cord-276598-tm0yj2sn	89	23	efficacy	efficacy	NN
cord-276598-tm0yj2sn	89	24	,	,	,
cord-276598-tm0yj2sn	89	25	intracellular	intracellular	JJ
cord-276598-tm0yj2sn	89	26	delivery	delivery	NN
cord-276598-tm0yj2sn	89	27	,	,	,
cord-276598-tm0yj2sn	89	28	and	and	CC
cord-276598-tm0yj2sn	89	29	therapeutic	therapeutic	JJ
cord-276598-tm0yj2sn	89	30	potential	potential	NN
cord-276598-tm0yj2sn	89	31	of	of	IN
cord-276598-tm0yj2sn	89	32	the	the	DT
cord-276598-tm0yj2sn	89	33	parent	parent	NN
cord-276598-tm0yj2sn	89	34	drugs	drug	NNS
cord-276598-tm0yj2sn	89	35	[	[	-LRB-
cord-276598-tm0yj2sn	89	36	62	62	CD
cord-276598-tm0yj2sn	89	37	,	,	,
cord-276598-tm0yj2sn	89	38	63	63	CD
cord-276598-tm0yj2sn	89	39	]	]	-RRB-
cord-276598-tm0yj2sn	89	40	.	.	.
cord-276598-tm0yj2sn	90	1	Recently	recently	RB
cord-276598-tm0yj2sn	90	2	,	,	,
cord-276598-tm0yj2sn	90	3	remdesivir	remdesivir	NNP
cord-276598-tm0yj2sn	90	4	(	(	-LRB-
cord-276598-tm0yj2sn	90	5	Figure	figure	NN
cord-276598-tm0yj2sn	90	6	3	3	CD
cord-276598-tm0yj2sn	90	7	,	,	,
cord-276598-tm0yj2sn	90	8	drug	drug	NN
cord-276598-tm0yj2sn	90	9	candidate	candidate	NN
cord-276598-tm0yj2sn	90	10	)	)	-RRB-
cord-276598-tm0yj2sn	90	11	,	,	,
cord-276598-tm0yj2sn	90	12	which	which	WDT
cord-276598-tm0yj2sn	90	13	has	have	VBZ
cord-276598-tm0yj2sn	90	14	a	a	DT
cord-276598-tm0yj2sn	90	15	P	P	NNP
cord-276598-tm0yj2sn	90	16	-	-	HYPH
cord-276598-tm0yj2sn	90	17	N	N	NNP
cord-276598-tm0yj2sn	90	18	moiety	moiety	NN
cord-276598-tm0yj2sn	90	19	,	,	,
cord-276598-tm0yj2sn	90	20	has	have	VBZ
cord-276598-tm0yj2sn	90	21	been	be	VBN
cord-276598-tm0yj2sn	90	22	evaluated	evaluate	VBN
cord-276598-tm0yj2sn	90	23	as	as	IN
cord-276598-tm0yj2sn	90	24	a	a	DT
cord-276598-tm0yj2sn	90	25	therapeutic	therapeutic	JJ
cord-276598-tm0yj2sn	90	26	option	option	NN
cord-276598-tm0yj2sn	90	27	for	for	IN
cord-276598-tm0yj2sn	90	28	the	the	DT
cord-276598-tm0yj2sn	90	29	treatment	treatment	NN
cord-276598-tm0yj2sn	90	30	of	of	IN
cord-276598-tm0yj2sn	90	31	COVID-19-affected	covid-19-affecte	VBN
cord-276598-tm0yj2sn	90	32	patients	patient	NNS
cord-276598-tm0yj2sn	90	33	and	and	CC
cord-276598-tm0yj2sn	90	34	has	have	VBZ
cord-276598-tm0yj2sn	90	35	attracted	attract	VBN
cord-276598-tm0yj2sn	90	36	a	a	DT
cord-276598-tm0yj2sn	90	37	lot	lot	NN
cord-276598-tm0yj2sn	90	38	of	of	IN
cord-276598-tm0yj2sn	90	39	attention	attention	NN
cord-276598-tm0yj2sn	90	40	in	in	IN
cord-276598-tm0yj2sn	90	41	the	the	DT
cord-276598-tm0yj2sn	90	42	clinical	clinical	JJ
cord-276598-tm0yj2sn	90	43	field	field	NN
cord-276598-tm0yj2sn	90	44	[	[	-LRB-
cord-276598-tm0yj2sn	90	45	64	64	CD
cord-276598-tm0yj2sn	90	46	]	]	-RRB-
cord-276598-tm0yj2sn	90	47	.	.	.
cord-276598-tm0yj2sn	91	1	Additionally	additionally	RB
cord-276598-tm0yj2sn	91	2	,	,	,
cord-276598-tm0yj2sn	91	3	these	these	DT
cord-276598-tm0yj2sn	91	4	P	P	NNP
cord-276598-tm0yj2sn	91	5	-	-	HYPH
cord-276598-tm0yj2sn	91	6	N	N	NNP
cord-276598-tm0yj2sn	91	7	compounds	compound	NNS
cord-276598-tm0yj2sn	91	8	have	have	VBP
cord-276598-tm0yj2sn	91	9	been	be	VBN
cord-276598-tm0yj2sn	91	10	used	use	VBN
cord-276598-tm0yj2sn	91	11	in	in	IN
cord-276598-tm0yj2sn	91	12	gene	gene	NN
cord-276598-tm0yj2sn	91	13	therapy	therapy	NN
cord-276598-tm0yj2sn	91	14	and	and	CC
cord-276598-tm0yj2sn	91	15	nucleoside	nucleoside	NN
cord-276598-tm0yj2sn	91	16	treatment	treatment	NN
cord-276598-tm0yj2sn	91	17	[	[	-LRB-
cord-276598-tm0yj2sn	91	18	65	65	CD
cord-276598-tm0yj2sn	91	19	]	]	-RRB-
cord-276598-tm0yj2sn	92	1	[	[	-LRB-
cord-276598-tm0yj2sn	92	2	66	66	CD
cord-276598-tm0yj2sn	92	3	]	]	-RRB-
cord-276598-tm0yj2sn	92	4	[	[	-LRB-
cord-276598-tm0yj2sn	92	5	67	67	CD
cord-276598-tm0yj2sn	92	6	]	]	-RRB-
cord-276598-tm0yj2sn	92	7	.	.	.
cord-276598-tm0yj2sn	93	1	Moreover	moreover	RB
cord-276598-tm0yj2sn	93	2	,	,	,
cord-276598-tm0yj2sn	93	3	many	many	JJ
cord-276598-tm0yj2sn	93	4	P	p	NN
cord-276598-tm0yj2sn	93	5	-	-	HYPH
cord-276598-tm0yj2sn	93	6	Ns	Ns	NNP
cord-276598-tm0yj2sn	93	7	have	have	VBP
cord-276598-tm0yj2sn	93	8	been	be	VBN
cord-276598-tm0yj2sn	93	9	found	find	VBN
cord-276598-tm0yj2sn	93	10	to	to	TO
cord-276598-tm0yj2sn	93	11	be	be	VB
cord-276598-tm0yj2sn	93	12	hydrolytically	hydrolytically	RB
cord-276598-tm0yj2sn	93	13	degradable	degradable	JJ
cord-276598-tm0yj2sn	93	14	under	under	IN
cord-276598-tm0yj2sn	93	15	acidic	acidic	JJ
cord-276598-tm0yj2sn	93	16	conditions	condition	NNS
cord-276598-tm0yj2sn	93	17	and	and	CC
cord-276598-tm0yj2sn	93	18	are	be	VBP
cord-276598-tm0yj2sn	93	19	comparatively	comparatively	RB
cord-276598-tm0yj2sn	93	20	stable	stable	JJ
cord-276598-tm0yj2sn	93	21	at	at	IN
cord-276598-tm0yj2sn	93	22	neutral	neutral	JJ
cord-276598-tm0yj2sn	93	23	and	and	CC
cord-276598-tm0yj2sn	93	24	higher	high	JJR
cord-276598-tm0yj2sn	93	25	pHs	ph	NNS
cord-276598-tm0yj2sn	93	26	.	.	.
cord-276598-tm0yj2sn	94	1	The	the	DT
cord-276598-tm0yj2sn	94	2	acid	acid	NN
cord-276598-tm0yj2sn	94	3	labile	labile	JJ
cord-276598-tm0yj2sn	94	4	P	p	NN
cord-276598-tm0yj2sn	94	5	-	-	HYPH
cord-276598-tm0yj2sn	94	6	N	n	CD
cord-276598-tm0yj2sn	94	7	bond	bond	NN
cord-276598-tm0yj2sn	94	8	is	be	VBZ
cord-276598-tm0yj2sn	94	9	selectively	selectively	RB
cord-276598-tm0yj2sn	94	10	cleaved	cleave	VBN
cord-276598-tm0yj2sn	94	11	due	due	IN
cord-276598-tm0yj2sn	94	12	to	to	IN
cord-276598-tm0yj2sn	94	13	protonation	protonation	NN
cord-276598-tm0yj2sn	94	14	at	at	IN
cord-276598-tm0yj2sn	94	15	N	n	CD
cord-276598-tm0yj2sn	94	16	,	,	,
cord-276598-tm0yj2sn	94	17	which	which	WDT
cord-276598-tm0yj2sn	94	18	then	then	RB
cord-276598-tm0yj2sn	94	19	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	94	20	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	94	21	attack	attack	NN
cord-276598-tm0yj2sn	94	22	by	by	IN
cord-276598-tm0yj2sn	94	23	a	a	DT
cord-276598-tm0yj2sn	94	24	molecule	molecule	NN
cord-276598-tm0yj2sn	94	25	of	of	IN
cord-276598-tm0yj2sn	94	26	water	water	NN
cord-276598-tm0yj2sn	94	27	to	to	TO
cord-276598-tm0yj2sn	94	28	eliminate	eliminate	VB
cord-276598-tm0yj2sn	94	29	the	the	DT
cord-276598-tm0yj2sn	94	30	corresponding	corresponding	JJ
cord-276598-tm0yj2sn	94	31	phosphates	phosphate	NNS
cord-276598-tm0yj2sn	94	32	and	and	CC
cord-276598-tm0yj2sn	94	33	amines	amine	NNS
cord-276598-tm0yj2sn	94	34	[	[	-LRB-
cord-276598-tm0yj2sn	94	35	68	68	CD
cord-276598-tm0yj2sn	94	36	,	,	,
cord-276598-tm0yj2sn	94	37	69	69	CD
cord-276598-tm0yj2sn	94	38	]	]	-RRB-
cord-276598-tm0yj2sn	94	39	.	.	.
cord-276598-tm0yj2sn	95	1	Thus	thus	RB
cord-276598-tm0yj2sn	95	2	,	,	,
cord-276598-tm0yj2sn	95	3	these	these	DT
cord-276598-tm0yj2sn	95	4	pH	pH	NNP
cord-276598-tm0yj2sn	95	5	responsive	responsive	JJ
cord-276598-tm0yj2sn	95	6	P	P	NNP
cord-276598-tm0yj2sn	95	7	-	-	HYPH
cord-276598-tm0yj2sn	95	8	Ns	Ns	NNP
cord-276598-tm0yj2sn	95	9	have	have	VBP
cord-276598-tm0yj2sn	95	10	notable	notable	JJ
cord-276598-tm0yj2sn	95	11	applications	application	NNS
cord-276598-tm0yj2sn	95	12	in	in	IN
cord-276598-tm0yj2sn	95	13	controlled	control	VBN
cord-276598-tm0yj2sn	95	14	drug	drug	NN
cord-276598-tm0yj2sn	95	15	release	release	NN
cord-276598-tm0yj2sn	95	16	[	[	-LRB-
cord-276598-tm0yj2sn	95	17	70	70	CD
cord-276598-tm0yj2sn	95	18	,	,	,
cord-276598-tm0yj2sn	95	19	71	71	CD
cord-276598-tm0yj2sn	95	20	]	]	-RRB-
cord-276598-tm0yj2sn	95	21	.	.	.
cord-276598-tm0yj2sn	96	1	For	for	IN
cord-276598-tm0yj2sn	96	2	example	example	NN
cord-276598-tm0yj2sn	96	3	,	,	,
cord-276598-tm0yj2sn	96	4	the	the	DT
cord-276598-tm0yj2sn	96	5	P	P	NNP
cord-276598-tm0yj2sn	96	6	-	-	HYPH
cord-276598-tm0yj2sn	96	7	N	N	NNP
cord-276598-tm0yj2sn	96	8	-	-	HYPH
cord-276598-tm0yj2sn	96	9	based	base	VBN
cord-276598-tm0yj2sn	96	10	prodrug	prodrug	NN
cord-276598-tm0yj2sn	96	11	of	of	IN
cord-276598-tm0yj2sn	96	12	l	l	NNP
cord-276598-tm0yj2sn	96	13	-	-	HYPH
cord-276598-tm0yj2sn	96	14	Dopa	Dopa	NNP
cord-276598-tm0yj2sn	96	15	has	have	VBZ
cord-276598-tm0yj2sn	96	16	been	be	VBN
cord-276598-tm0yj2sn	96	17	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	96	18	for	for	IN
cord-276598-tm0yj2sn	96	19	its	-PRON-	PRP$
cord-276598-tm0yj2sn	96	20	controlled	controlled	JJ
cord-276598-tm0yj2sn	96	21	release	release	NN
cord-276598-tm0yj2sn	96	22	for	for	IN
cord-276598-tm0yj2sn	96	23	the	the	DT
cord-276598-tm0yj2sn	96	24	treatment	treatment	NN
cord-276598-tm0yj2sn	96	25	of	of	IN
cord-276598-tm0yj2sn	96	26	Parkinson	Parkinson	NNP
cord-276598-tm0yj2sn	96	27	's	's	POS
cord-276598-tm0yj2sn	96	28	disease	disease	NN
cord-276598-tm0yj2sn	96	29	[	[	-LRB-
cord-276598-tm0yj2sn	96	30	72	72	CD
cord-276598-tm0yj2sn	96	31	]	]	-RRB-
cord-276598-tm0yj2sn	96	32	.	.	.
cord-276598-tm0yj2sn	97	1	Similarly	similarly	RB
cord-276598-tm0yj2sn	97	2	,	,	,
cord-276598-tm0yj2sn	97	3	P	P	NNP
cord-276598-tm0yj2sn	97	4	-	-	HYPH
cord-276598-tm0yj2sn	97	5	N	n	CD
cord-276598-tm0yj2sn	97	6	derivatives	derivative	NNS
cord-276598-tm0yj2sn	97	7	of	of	IN
cord-276598-tm0yj2sn	97	8	the	the	DT
cord-276598-tm0yj2sn	97	9	antiherpetic	antiherpetic	JJ
cord-276598-tm0yj2sn	97	10	drug	drug	NN
cord-276598-tm0yj2sn	97	11	,	,	,
cord-276598-tm0yj2sn	97	12	acyclovir	acyclovir	NNP
cord-276598-tm0yj2sn	97	13	(	(	-LRB-
cord-276598-tm0yj2sn	97	14	ACV	ACV	NNP
cord-276598-tm0yj2sn	97	15	)	)	-RRB-
cord-276598-tm0yj2sn	97	16	,	,	,
cord-276598-tm0yj2sn	97	17	hydrolyses	hydrolyse	VBZ
cord-276598-tm0yj2sn	97	18	at	at	IN
cord-276598-tm0yj2sn	97	19	pH	pH	NNP
cord-276598-tm0yj2sn	97	20	2	2	CD
cord-276598-tm0yj2sn	97	21	into	into	IN
cord-276598-tm0yj2sn	97	22	ACV	acv	NN
cord-276598-tm0yj2sn	97	23	monophosphate	monophosphate	NN
cord-276598-tm0yj2sn	97	24	and	and	CC
cord-276598-tm0yj2sn	97	25	can	can	MD
cord-276598-tm0yj2sn	97	26	be	be	VB
cord-276598-tm0yj2sn	97	27	a	a	DT
cord-276598-tm0yj2sn	97	28	promising	promising	JJ
cord-276598-tm0yj2sn	97	29	antiviral	antiviral	JJ
cord-276598-tm0yj2sn	97	30	drug	drug	NN
cord-276598-tm0yj2sn	97	31	due	due	IN
cord-276598-tm0yj2sn	97	32	to	to	IN
cord-276598-tm0yj2sn	97	33	increased	increase	VBN
cord-276598-tm0yj2sn	97	34	cell	cell	NN
cord-276598-tm0yj2sn	97	35	penetration	penetration	NN
cord-276598-tm0yj2sn	97	36	and	and	CC
cord-276598-tm0yj2sn	97	37	therapeutic	therapeutic	JJ
cord-276598-tm0yj2sn	97	38	potential	potential	JJ
cord-276598-tm0yj2sn	97	39	relative	relative	NN
cord-276598-tm0yj2sn	97	40	to	to	IN
cord-276598-tm0yj2sn	97	41	the	the	DT
cord-276598-tm0yj2sn	97	42	parent	parent	NN
cord-276598-tm0yj2sn	97	43	drug	drug	NN
cord-276598-tm0yj2sn	97	44	[	[	-LRB-
cord-276598-tm0yj2sn	97	45	73	73	CD
cord-276598-tm0yj2sn	97	46	]	]	-RRB-
cord-276598-tm0yj2sn	97	47	.	.	.
cord-276598-tm0yj2sn	98	1	Although	although	IN
cord-276598-tm0yj2sn	98	2	P	P	NNP
cord-276598-tm0yj2sn	98	3	-	-	HYPH
cord-276598-tm0yj2sn	98	4	N	n	NN
cord-276598-tm0yj2sn	98	5	biomolecules	biomolecule	NNS
cord-276598-tm0yj2sn	98	6	such	such	JJ
cord-276598-tm0yj2sn	98	7	as	as	IN
cord-276598-tm0yj2sn	98	8	phosphocreatine	phosphocreatine	NN
cord-276598-tm0yj2sn	98	9	have	have	VBP
cord-276598-tm0yj2sn	98	10	been	be	VBN
cord-276598-tm0yj2sn	98	11	known	know	VBN
cord-276598-tm0yj2sn	98	12	since	since	IN
cord-276598-tm0yj2sn	98	13	the	the	DT
cord-276598-tm0yj2sn	98	14	work	work	NN
cord-276598-tm0yj2sn	98	15	of	of	IN
cord-276598-tm0yj2sn	98	16	Fiske	Fiske	NNP
cord-276598-tm0yj2sn	98	17	and	and	CC
cord-276598-tm0yj2sn	98	18	Subbarow	Subbarow	NNP
cord-276598-tm0yj2sn	98	19	in	in	IN
cord-276598-tm0yj2sn	98	20	1927	1927	CD
cord-276598-tm0yj2sn	98	21	,	,	,
cord-276598-tm0yj2sn	98	22	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	98	23	routes	route	NNS
cord-276598-tm0yj2sn	98	24	to	to	IN
cord-276598-tm0yj2sn	98	25	P	P	NNP
cord-276598-tm0yj2sn	98	26	-	-	HYPH
cord-276598-tm0yj2sn	98	27	N	N	NNP
cord-276598-tm0yj2sn	98	28	compounds	compound	NNS
cord-276598-tm0yj2sn	98	29	prior	prior	RB
cord-276598-tm0yj2sn	98	30	to	to	IN
cord-276598-tm0yj2sn	98	31	1988	1988	CD
cord-276598-tm0yj2sn	98	32	have	have	VBP
cord-276598-tm0yj2sn	98	33	been	be	VBN
cord-276598-tm0yj2sn	98	34	limited	limit	VBN
cord-276598-tm0yj2sn	98	35	[	[	-LRB-
cord-276598-tm0yj2sn	98	36	74	74	CD
cord-276598-tm0yj2sn	98	37	,	,	,
cord-276598-tm0yj2sn	98	38	75	75	CD
cord-276598-tm0yj2sn	98	39	]	]	-RRB-
cord-276598-tm0yj2sn	98	40	.	.	.
cord-276598-tm0yj2sn	99	1	These	these	DT
cord-276598-tm0yj2sn	99	2	early	early	JJ
cord-276598-tm0yj2sn	99	3	routes	route	NNS
cord-276598-tm0yj2sn	99	4	involve	involve	VBP
cord-276598-tm0yj2sn	99	5	the	the	DT
cord-276598-tm0yj2sn	99	6	preparation	preparation	NN
cord-276598-tm0yj2sn	99	7	of	of	IN
cord-276598-tm0yj2sn	99	8	and	and	CC
cord-276598-tm0yj2sn	99	9	use	use	NN
cord-276598-tm0yj2sn	99	10	of	of	IN
cord-276598-tm0yj2sn	99	11	toxic	toxic	JJ
cord-276598-tm0yj2sn	99	12	reagents	reagent	NNS
cord-276598-tm0yj2sn	99	13	over	over	IN
cord-276598-tm0yj2sn	99	14	multiple	multiple	JJ
cord-276598-tm0yj2sn	99	15	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	99	16	steps	step	NNS
cord-276598-tm0yj2sn	99	17	and	and	CC
cord-276598-tm0yj2sn	99	18	often	often	RB
cord-276598-tm0yj2sn	99	19	resulted	result	VBD
cord-276598-tm0yj2sn	99	20	in	in	IN
cord-276598-tm0yj2sn	99	21	the	the	DT
cord-276598-tm0yj2sn	99	22	elimination	elimination	NN
cord-276598-tm0yj2sn	99	23	of	of	IN
cord-276598-tm0yj2sn	99	24	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	99	25	waste	waste	NN
cord-276598-tm0yj2sn	99	26	.	.	.
cord-276598-tm0yj2sn	100	1	However	however	RB
cord-276598-tm0yj2sn	100	2	,	,	,
cord-276598-tm0yj2sn	100	3	with	with	IN
cord-276598-tm0yj2sn	100	4	an	an	DT
cord-276598-tm0yj2sn	100	5	increase	increase	NN
cord-276598-tm0yj2sn	100	6	in	in	IN
cord-276598-tm0yj2sn	100	7	the	the	DT
cord-276598-tm0yj2sn	100	8	number	number	NN
cord-276598-tm0yj2sn	100	9	of	of	IN
cord-276598-tm0yj2sn	100	10	uses	use	NNS
cord-276598-tm0yj2sn	100	11	of	of	IN
cord-276598-tm0yj2sn	100	12	P	P	NNP
cord-276598-tm0yj2sn	100	13	-	-	HYPH
cord-276598-tm0yj2sn	100	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	100	15	,	,	,
cord-276598-tm0yj2sn	100	16	the	the	DT
cord-276598-tm0yj2sn	100	17	need	need	NN
cord-276598-tm0yj2sn	100	18	to	to	TO
cord-276598-tm0yj2sn	100	19	develop	develop	VB
cord-276598-tm0yj2sn	100	20	one	one	CD
cord-276598-tm0yj2sn	100	21	-	-	HYPH
cord-276598-tm0yj2sn	100	22	pot	pot	NN
cord-276598-tm0yj2sn	100	23	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	100	24	routes	route	NNS
cord-276598-tm0yj2sn	100	25	that	that	WDT
cord-276598-tm0yj2sn	100	26	are	be	VBP
cord-276598-tm0yj2sn	100	27	more	more	RBR
cord-276598-tm0yj2sn	100	28	environmentally	environmentally	RB
cord-276598-tm0yj2sn	100	29	benign	benign	JJ
cord-276598-tm0yj2sn	100	30	has	have	VBZ
cord-276598-tm0yj2sn	100	31	driven	drive	VBN
cord-276598-tm0yj2sn	100	32	researchers	researcher	NNS
cord-276598-tm0yj2sn	100	33	to	to	TO
cord-276598-tm0yj2sn	100	34	discover	discover	VB
cord-276598-tm0yj2sn	100	35	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	100	36	strategies	strategy	NNS
cord-276598-tm0yj2sn	100	37	.	.	.
cord-276598-tm0yj2sn	101	1	Accordingly	accordingly	RB
cord-276598-tm0yj2sn	101	2	,	,	,
cord-276598-tm0yj2sn	101	3	all	all	PDT
cord-276598-tm0yj2sn	101	4	the	the	DT
cord-276598-tm0yj2sn	101	5	known	know	VBN
cord-276598-tm0yj2sn	101	6	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	101	7	routes	route	NNS
cord-276598-tm0yj2sn	101	8	to	to	IN
cord-276598-tm0yj2sn	101	9	P	p	NN
cord-276598-tm0yj2sn	101	10	-	-	:
cord-276598-tm0yj2sn	101	11	Ns	Ns	NNP
cord-276598-tm0yj2sn	101	12	can	can	MD
cord-276598-tm0yj2sn	101	13	be	be	VB
cord-276598-tm0yj2sn	101	14	separated	separate	VBN
cord-276598-tm0yj2sn	101	15	into	into	IN
cord-276598-tm0yj2sn	101	16	six	six	CD
cord-276598-tm0yj2sn	101	17	categories	category	NNS
cord-276598-tm0yj2sn	101	18	:	:	:
cord-276598-tm0yj2sn	101	19	salt	salt	NN
cord-276598-tm0yj2sn	101	20	elimination	elimination	NN
cord-276598-tm0yj2sn	101	21	,	,	,
cord-276598-tm0yj2sn	101	22	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	101	23	cross	cross	NN
cord-276598-tm0yj2sn	101	24	-	-	NN
cord-276598-tm0yj2sn	101	25	coupling	coupling	JJ
cord-276598-tm0yj2sn	101	26	,	,	,
cord-276598-tm0yj2sn	101	27	azide	azide	NN
cord-276598-tm0yj2sn	101	28	,	,	,
cord-276598-tm0yj2sn	101	29	reduction	reduction	NN
cord-276598-tm0yj2sn	101	30	,	,	,
cord-276598-tm0yj2sn	101	31	hydrophosphinylation	hydrophosphinylation	NN
cord-276598-tm0yj2sn	101	32	,	,	,
cord-276598-tm0yj2sn	101	33	and	and	CC
cord-276598-tm0yj2sn	101	34	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	101	35	-	-	HYPH
cord-276598-tm0yj2sn	101	36	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	101	37	-	-	HYPH
cord-276598-tm0yj2sn	101	38	dienophile	dienophile	NN
cord-276598-tm0yj2sn	101	39	(	(	-LRB-
cord-276598-tm0yj2sn	101	40	PAD	pad	NN
cord-276598-tm0yj2sn	101	41	)	)	-RRB-
cord-276598-tm0yj2sn	101	42	.	.	.
cord-276598-tm0yj2sn	102	1	Each	each	DT
cord-276598-tm0yj2sn	102	2	of	of	IN
cord-276598-tm0yj2sn	102	3	the	the	DT
cord-276598-tm0yj2sn	102	4	categories	category	NNS
cord-276598-tm0yj2sn	102	5	will	will	MD
cord-276598-tm0yj2sn	102	6	be	be	VB
cord-276598-tm0yj2sn	102	7	discussed	discuss	VBN
cord-276598-tm0yj2sn	102	8	in	in	IN
cord-276598-tm0yj2sn	102	9	detail	detail	NN
cord-276598-tm0yj2sn	102	10	in	in	IN
cord-276598-tm0yj2sn	102	11	the	the	DT
cord-276598-tm0yj2sn	102	12	coming	come	VBG
cord-276598-tm0yj2sn	102	13	sections	section	NNS
cord-276598-tm0yj2sn	102	14	,	,	,
cord-276598-tm0yj2sn	102	15	with	with	IN
cord-276598-tm0yj2sn	102	16	an	an	DT
cord-276598-tm0yj2sn	102	17	emphasis	emphasis	NN
cord-276598-tm0yj2sn	102	18	on	on	IN
cord-276598-tm0yj2sn	102	19	conditions	condition	NNS
cord-276598-tm0yj2sn	102	20	,	,	,
cord-276598-tm0yj2sn	102	21	scope	scope	NN
cord-276598-tm0yj2sn	102	22	,	,	,
cord-276598-tm0yj2sn	102	23	and	and	CC
cord-276598-tm0yj2sn	102	24	mechanism	mechanism	NN
cord-276598-tm0yj2sn	102	25	.	.	.
cord-276598-tm0yj2sn	103	1	This	this	DT
cord-276598-tm0yj2sn	103	2	discussion	discussion	NN
cord-276598-tm0yj2sn	103	3	will	will	MD
cord-276598-tm0yj2sn	103	4	be	be	VB
cord-276598-tm0yj2sn	103	5	preceded	precede	VBN
cord-276598-tm0yj2sn	103	6	by	by	IN
cord-276598-tm0yj2sn	103	7	a	a	DT
cord-276598-tm0yj2sn	103	8	brief	brief	JJ
cord-276598-tm0yj2sn	103	9	introduction	introduction	NN
cord-276598-tm0yj2sn	103	10	to	to	IN
cord-276598-tm0yj2sn	103	11	the	the	DT
cord-276598-tm0yj2sn	103	12	early	early	JJ
cord-276598-tm0yj2sn	103	13	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	103	14	routes	route	NNS
cord-276598-tm0yj2sn	103	15	.	.	.
cord-276598-tm0yj2sn	104	1	Based	base	VBN
cord-276598-tm0yj2sn	104	2	on	on	IN
cord-276598-tm0yj2sn	104	3	the	the	DT
cord-276598-tm0yj2sn	104	4	available	available	JJ
cord-276598-tm0yj2sn	104	5	literature	literature	NN
cord-276598-tm0yj2sn	104	6	,	,	,
cord-276598-tm0yj2sn	104	7	one	one	CD
cord-276598-tm0yj2sn	104	8	of	of	IN
cord-276598-tm0yj2sn	104	9	the	the	DT
cord-276598-tm0yj2sn	104	10	earliest	early	JJS
cord-276598-tm0yj2sn	104	11	syntheses	synthesis	NNS
cord-276598-tm0yj2sn	104	12	of	of	IN
cord-276598-tm0yj2sn	104	13	P	P	NNP
cord-276598-tm0yj2sn	104	14	-	-	HYPH
cord-276598-tm0yj2sn	104	15	Ns	Ns	NNP
cord-276598-tm0yj2sn	104	16	involved	involve	VBD
cord-276598-tm0yj2sn	104	17	the	the	DT
cord-276598-tm0yj2sn	104	18	works	work	NNS
cord-276598-tm0yj2sn	104	19	of	of	IN
cord-276598-tm0yj2sn	104	20	Audrieth	Audrieth	NNP
cord-276598-tm0yj2sn	104	21	and	and	CC
cord-276598-tm0yj2sn	104	22	Toy	Toy	NNP
cord-276598-tm0yj2sn	104	23	[	[	-LRB-
cord-276598-tm0yj2sn	104	24	76	76	CD
cord-276598-tm0yj2sn	104	25	,	,	,
cord-276598-tm0yj2sn	104	26	77	77	CD
cord-276598-tm0yj2sn	104	27	]	]	-RRB-
cord-276598-tm0yj2sn	104	28	.	.	.
cord-276598-tm0yj2sn	105	1	Audrieth	Audrieth	NNP
cord-276598-tm0yj2sn	105	2	and	and	CC
cord-276598-tm0yj2sn	105	3	Toy	Toy	NNP
cord-276598-tm0yj2sn	105	4	treated	treat	VBD
cord-276598-tm0yj2sn	105	5	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	105	6	trichloride	trichloride	VBN
cord-276598-tm0yj2sn	105	7	with	with	IN
cord-276598-tm0yj2sn	105	8	phenol	phenol	NN
cord-276598-tm0yj2sn	105	9	in	in	IN
cord-276598-tm0yj2sn	105	10	the	the	DT
cord-276598-tm0yj2sn	105	11	presence	presence	NN
cord-276598-tm0yj2sn	105	12	of	of	IN
cord-276598-tm0yj2sn	105	13	pyridine	pyridine	NN
cord-276598-tm0yj2sn	105	14	to	to	TO
cord-276598-tm0yj2sn	105	15	obtain	obtain	VB
cord-276598-tm0yj2sn	105	16	a	a	DT
cord-276598-tm0yj2sn	105	17	mixture	mixture	NN
cord-276598-tm0yj2sn	105	18	of	of	IN
cord-276598-tm0yj2sn	105	19	diphenylchlorophosphate	diphenylchlorophosphate	NNP
cord-276598-tm0yj2sn	105	20	(	(	-LRB-
cord-276598-tm0yj2sn	105	21	dPCP	dpcp	JJ
cord-276598-tm0yj2sn	105	22	)	)	-RRB-
cord-276598-tm0yj2sn	105	23	and	and	CC
cord-276598-tm0yj2sn	105	24	phenyl	phenyl	NN
cord-276598-tm0yj2sn	105	25	dichlorophosphate	dichlorophosphate	VBP
cord-276598-tm0yj2sn	105	26	(	(	-LRB-
cord-276598-tm0yj2sn	105	27	PdCP	PdCP	NNP
cord-276598-tm0yj2sn	105	28	)	)	-RRB-
cord-276598-tm0yj2sn	105	29	.	.	.
cord-276598-tm0yj2sn	106	1	Upon	upon	IN
cord-276598-tm0yj2sn	106	2	reacting	react	VBG
cord-276598-tm0yj2sn	106	3	the	the	DT
cord-276598-tm0yj2sn	106	4	mixture	mixture	NN
cord-276598-tm0yj2sn	106	5	with	with	IN
cord-276598-tm0yj2sn	106	6	gaseous	gaseous	JJ
cord-276598-tm0yj2sn	106	7	or	or	CC
cord-276598-tm0yj2sn	106	8	aqueous	aqueous	JJ
cord-276598-tm0yj2sn	106	9	NH	NH	NNP
cord-276598-tm0yj2sn	106	10	3	3	CD
cord-276598-tm0yj2sn	106	11	in	in	IN
cord-276598-tm0yj2sn	106	12	1941	1941	CD
cord-276598-tm0yj2sn	106	13	or	or	CC
cord-276598-tm0yj2sn	106	14	primary	primary	JJ
cord-276598-tm0yj2sn	106	15	amine	amine	NN
cord-276598-tm0yj2sn	106	16	in	in	IN
cord-276598-tm0yj2sn	106	17	1942	1942	CD
cord-276598-tm0yj2sn	106	18	,	,	,
cord-276598-tm0yj2sn	106	19	P	P	NNP
cord-276598-tm0yj2sn	106	20	-	-	HYPH
cord-276598-tm0yj2sn	106	21	N	N	NNP
cord-276598-tm0yj2sn	106	22	and	and	CC
cord-276598-tm0yj2sn	106	23	N	N	NNP
cord-276598-tm0yj2sn	106	24	-	-	HYPH
cord-276598-tm0yj2sn	106	25	P	P	NNP
cord-276598-tm0yj2sn	106	26	-	-	HYPH
cord-276598-tm0yj2sn	106	27	N	N	NNP
cord-276598-tm0yj2sn	106	28	were	be	VBD
cord-276598-tm0yj2sn	106	29	formed	form	VBN
cord-276598-tm0yj2sn	107	1	(	(	-LRB-
cord-276598-tm0yj2sn	107	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	107	3	2	2	CD
cord-276598-tm0yj2sn	107	4	route	route	NN
cord-276598-tm0yj2sn	107	5	A	a	NN
cord-276598-tm0yj2sn	107	6	,	,	,
cord-276598-tm0yj2sn	107	7	R	r	NN
cord-276598-tm0yj2sn	107	8	=	=	NN
cord-276598-tm0yj2sn	107	9	Ph	Ph	NNP
cord-276598-tm0yj2sn	107	10	)	)	-RRB-
cord-276598-tm0yj2sn	107	11	.	.	.
cord-276598-tm0yj2sn	108	1	In	in	IN
cord-276598-tm0yj2sn	108	2	1945	1945	CD
cord-276598-tm0yj2sn	108	3	,	,	,
cord-276598-tm0yj2sn	108	4	P	P	NNP
cord-276598-tm0yj2sn	108	5	-	-	HYPH
cord-276598-tm0yj2sn	108	6	Ns	Ns	NNP
cord-276598-tm0yj2sn	108	7	were	be	VBD
cord-276598-tm0yj2sn	108	8	made	make	VBN
cord-276598-tm0yj2sn	108	9	by	by	IN
cord-276598-tm0yj2sn	108	10	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	108	11	,	,	,
cord-276598-tm0yj2sn	108	12	Openshaw	Openshaw	NNP
cord-276598-tm0yj2sn	108	13	,	,	,
cord-276598-tm0yj2sn	108	14	and	and	CC
cord-276598-tm0yj2sn	108	15	Todd	Todd	NNP
cord-276598-tm0yj2sn	108	16	through	through	IN
cord-276598-tm0yj2sn	108	17	a	a	DT
cord-276598-tm0yj2sn	108	18	salt	salt	NN
cord-276598-tm0yj2sn	108	19	elimination	elimination	NN
cord-276598-tm0yj2sn	108	20	process	process	NN
cord-276598-tm0yj2sn	108	21	using	use	VBG
cord-276598-tm0yj2sn	108	22	disubstituted	disubstitute	VBN
cord-276598-tm0yj2sn	108	23	H	H	NNP
cord-276598-tm0yj2sn	108	24	-	-	HYPH
cord-276598-tm0yj2sn	108	25	phosphonates	phosphonates	NNP
cord-276598-tm0yj2sn	108	26	(	(	-LRB-
cord-276598-tm0yj2sn	108	27	H	h	NN
cord-276598-tm0yj2sn	108	28	-	-	HYPH
cord-276598-tm0yj2sn	108	29	P	P	NNP
cord-276598-tm0yj2sn	108	30	)	)	-RRB-
cord-276598-tm0yj2sn	108	31	,	,	,
cord-276598-tm0yj2sn	108	32	amines	amine	NNS
cord-276598-tm0yj2sn	108	33	,	,	,
cord-276598-tm0yj2sn	108	34	and	and	CC
cord-276598-tm0yj2sn	108	35	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	108	36	agents	agent	NNS
cord-276598-tm0yj2sn	108	37	(	(	-LRB-
cord-276598-tm0yj2sn	108	38	Scheme	scheme	NN
cord-276598-tm0yj2sn	108	39	2	2	CD
cord-276598-tm0yj2sn	108	40	route	route	NN
cord-276598-tm0yj2sn	108	41	B	b	NN
cord-276598-tm0yj2sn	108	42	)	)	-RRB-
cord-276598-tm0yj2sn	108	43	[	[	-LRB-
cord-276598-tm0yj2sn	108	44	78	78	CD
cord-276598-tm0yj2sn	108	45	]	]	-RRB-
cord-276598-tm0yj2sn	108	46	.	.	.
cord-276598-tm0yj2sn	109	1	Subsequently	subsequently	RB
cord-276598-tm0yj2sn	109	2	,	,	,
cord-276598-tm0yj2sn	109	3	the	the	DT
cord-276598-tm0yj2sn	109	4	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	109	5	-	-	HYPH
cord-276598-tm0yj2sn	109	6	Todd	Todd	NNP
cord-276598-tm0yj2sn	109	7	group	group	NN
cord-276598-tm0yj2sn	109	8	synthesized	synthesize	VBD
cord-276598-tm0yj2sn	109	9	P	P	NNP
cord-276598-tm0yj2sn	109	10	-	-	HYPH
cord-276598-tm0yj2sn	109	11	Ns	Ns	NNP
cord-276598-tm0yj2sn	109	12	via	via	IN
cord-276598-tm0yj2sn	109	13	the	the	DT
cord-276598-tm0yj2sn	109	14	same	same	JJ
cord-276598-tm0yj2sn	109	15	method	method	NN
cord-276598-tm0yj2sn	109	16	using	use	VBG
cord-276598-tm0yj2sn	109	17	different	different	JJ
cord-276598-tm0yj2sn	109	18	polyhalogen	polyhalogen	NN
cord-276598-tm0yj2sn	109	19	solvents	solvent	NNS
cord-276598-tm0yj2sn	109	20	in	in	IN
cord-276598-tm0yj2sn	109	21	1947	1947	CD
cord-276598-tm0yj2sn	109	22	[	[	-LRB-
cord-276598-tm0yj2sn	109	23	79	79	CD
cord-276598-tm0yj2sn	109	24	]	]	-RRB-
cord-276598-tm0yj2sn	109	25	and	and	CC
cord-276598-tm0yj2sn	109	26	using	use	VBG
cord-276598-tm0yj2sn	109	27	alternative	alternative	JJ
cord-276598-tm0yj2sn	109	28	phosphorylating	phosphorylate	VBG
cord-276598-tm0yj2sn	109	29	agents	agent	NNS
cord-276598-tm0yj2sn	109	30	in	in	IN
cord-276598-tm0yj2sn	109	31	1948	1948	CD
cord-276598-tm0yj2sn	109	32	[	[	-LRB-
cord-276598-tm0yj2sn	109	33	80	80	CD
cord-276598-tm0yj2sn	109	34	]	]	-RRB-
cord-276598-tm0yj2sn	109	35	.	.	.
cord-276598-tm0yj2sn	110	1	In	in	IN
cord-276598-tm0yj2sn	110	2	1951	1951	CD
cord-276598-tm0yj2sn	110	3	,	,	,
cord-276598-tm0yj2sn	110	4	Wagner	Wagner	NNP
cord-276598-tm0yj2sn	110	5	-	-	HYPH
cord-276598-tm0yj2sn	110	6	Jauregg	Jauregg	NNP
cord-276598-tm0yj2sn	110	7	et	et	FW
cord-276598-tm0yj2sn	110	8	al	al	NNP
cord-276598-tm0yj2sn	110	9	.	.	.
cord-276598-tm0yj2sn	111	1	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	111	2	P	P	NNP
cord-276598-tm0yj2sn	111	3	-	-	HYPH
cord-276598-tm0yj2sn	111	4	N	N	NNP
cord-276598-tm0yj2sn	111	5	compounds	compound	NNS
cord-276598-tm0yj2sn	111	6	from	from	IN
cord-276598-tm0yj2sn	111	7	diisopropylchlorophosphate	diisopropylchlorophosphate	NNP
cord-276598-tm0yj2sn	111	8	(	(	-LRB-
cord-276598-tm0yj2sn	111	9	dPrCP	dPrCP	NNP
cord-276598-tm0yj2sn	111	10	)	)	-RRB-
cord-276598-tm0yj2sn	111	11	or	or	CC
cord-276598-tm0yj2sn	111	12	tetraethylpyrophosphate	tetraethylpyrophosphate	NN
cord-276598-tm0yj2sn	111	13	(	(	-LRB-
cord-276598-tm0yj2sn	111	14	tEPyP	tEPyP	NNP
cord-276598-tm0yj2sn	111	15	)	)	-RRB-
cord-276598-tm0yj2sn	111	16	and	and	CC
cord-276598-tm0yj2sn	111	17	amines	amine	NNS
cord-276598-tm0yj2sn	111	18	(	(	-LRB-
cord-276598-tm0yj2sn	111	19	Scheme	scheme	NN
cord-276598-tm0yj2sn	111	20	2	2	CD
cord-276598-tm0yj2sn	111	21	route	route	NN
cord-276598-tm0yj2sn	111	22	A	a	NN
cord-276598-tm0yj2sn	111	23	,	,	,
cord-276598-tm0yj2sn	111	24	R	r	NN
cord-276598-tm0yj2sn	111	25	=	=	NN
cord-276598-tm0yj2sn	111	26	i	i	NN
cord-276598-tm0yj2sn	111	27	-	-	HYPH
cord-276598-tm0yj2sn	111	28	Pr	pr	NN
cord-276598-tm0yj2sn	111	29	and	and	CC
cord-276598-tm0yj2sn	111	30	route	route	NN
cord-276598-tm0yj2sn	111	31	C	C	NNP
cord-276598-tm0yj2sn	111	32	,	,	,
cord-276598-tm0yj2sn	111	33	respectively	respectively	RB
cord-276598-tm0yj2sn	111	34	)	)	-RRB-
cord-276598-tm0yj2sn	111	35	[	[	-LRB-
cord-276598-tm0yj2sn	111	36	81	81	CD
cord-276598-tm0yj2sn	111	37	]	]	-RRB-
cord-276598-tm0yj2sn	111	38	.	.	.
cord-276598-tm0yj2sn	112	1	Sodium	sodium	NN
cord-276598-tm0yj2sn	112	2	anilide	anilide	NN
cord-276598-tm0yj2sn	112	3	or	or	CC
cord-276598-tm0yj2sn	112	4	sodium	sodium	NN
cord-276598-tm0yj2sn	112	5	diphenylamide	diphenylamide	NNP
cord-276598-tm0yj2sn	112	6	was	be	VBD
cord-276598-tm0yj2sn	112	7	refluxed	refluxe	VBN
cord-276598-tm0yj2sn	112	8	with	with	IN
cord-276598-tm0yj2sn	112	9	triphenylphosphate	triphenylphosphate	NNP
cord-276598-tm0yj2sn	112	10	(	(	-LRB-
cord-276598-tm0yj2sn	112	11	tPPO	tPPO	NNP
cord-276598-tm0yj2sn	112	12	)	)	-RRB-
cord-276598-tm0yj2sn	112	13	to	to	TO
cord-276598-tm0yj2sn	112	14	eliminate	eliminate	VB
cord-276598-tm0yj2sn	112	15	phenol	phenol	NN
cord-276598-tm0yj2sn	112	16	and	and	CC
cord-276598-tm0yj2sn	112	17	give	give	VB
cord-276598-tm0yj2sn	112	18	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	112	19	N	N	NNP
cord-276598-tm0yj2sn	112	20	-	-	HYPH
cord-276598-tm0yj2sn	112	21	phenylphosphoramidate	phenylphosphoramidate	NNP
cord-276598-tm0yj2sn	112	22	or	or	CC
cord-276598-tm0yj2sn	112	23	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	112	24	N	N	NNP
cord-276598-tm0yj2sn	112	25	,	,	,
cord-276598-tm0yj2sn	112	26	N	N	NNP
cord-276598-tm0yj2sn	112	27	-	-	HYPH
cord-276598-tm0yj2sn	112	28	diphenylphosphoramidate	diphenylphosphoramidate	NNP
cord-276598-tm0yj2sn	112	29	in	in	IN
cord-276598-tm0yj2sn	112	30	1964	1964	CD
cord-276598-tm0yj2sn	112	31	(	(	-LRB-
cord-276598-tm0yj2sn	112	32	Scheme	scheme	NN
cord-276598-tm0yj2sn	112	33	2	2	CD
cord-276598-tm0yj2sn	112	34	route	route	NN
cord-276598-tm0yj2sn	112	35	D	d	NN
cord-276598-tm0yj2sn	112	36	)	)	-RRB-
cord-276598-tm0yj2sn	113	1	[	[	-LRB-
cord-276598-tm0yj2sn	113	2	82	82	CD
cord-276598-tm0yj2sn	113	3	]	]	-RRB-
cord-276598-tm0yj2sn	113	4	.	.	.
cord-276598-tm0yj2sn	114	1	In	in	IN
cord-276598-tm0yj2sn	114	2	1965	1965	CD
cord-276598-tm0yj2sn	114	3	,	,	,
cord-276598-tm0yj2sn	114	4	Sundberg	Sundberg	NNP
cord-276598-tm0yj2sn	114	5	reacted	react	VBD
cord-276598-tm0yj2sn	114	6	1-ethyl-2-nitrobenzene	1-ethyl-2-nitrobenzene	CD
cord-276598-tm0yj2sn	114	7	and	and	CC
cord-276598-tm0yj2sn	114	8	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	114	9	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	114	10	to	to	TO
cord-276598-tm0yj2sn	114	11	obtain	obtain	VB
cord-276598-tm0yj2sn	114	12	a	a	DT
cord-276598-tm0yj2sn	114	13	phosphorimidate	phosphorimidate	NN
cord-276598-tm0yj2sn	114	14	-	-	HYPH
cord-276598-tm0yj2sn	114	15	product	product	NN
cord-276598-tm0yj2sn	114	16	(	(	-LRB-
cord-276598-tm0yj2sn	114	17	N	n	NN
cord-276598-tm0yj2sn	114	18	=	=	NN
cord-276598-tm0yj2sn	114	19	P	p	NN
cord-276598-tm0yj2sn	114	20	)	)	-RRB-
cord-276598-tm0yj2sn	114	21	that	that	WDT
cord-276598-tm0yj2sn	114	22	was	be	VBD
cord-276598-tm0yj2sn	114	23	converted	convert	VBN
cord-276598-tm0yj2sn	114	24	to	to	IN
cord-276598-tm0yj2sn	114	25	P	P	NNP
cord-276598-tm0yj2sn	114	26	-	-	HYPH
cord-276598-tm0yj2sn	114	27	N	N	NNP
cord-276598-tm0yj2sn	114	28	on	on	IN
cord-276598-tm0yj2sn	114	29	silica	silica	NN
cord-276598-tm0yj2sn	114	30	or	or	CC
cord-276598-tm0yj2sn	114	31	alumina	alumina	NN
cord-276598-tm0yj2sn	114	32	columns	column	NNS
cord-276598-tm0yj2sn	114	33	[	[	-LRB-
cord-276598-tm0yj2sn	114	34	83	83	CD
cord-276598-tm0yj2sn	114	35	]	]	-RRB-
cord-276598-tm0yj2sn	114	36	.	.	.
cord-276598-tm0yj2sn	115	1	Cadogan	Cadogan	NNP
cord-276598-tm0yj2sn	115	2	and	and	CC
cord-276598-tm0yj2sn	115	3	coworkers	coworker	NNS
cord-276598-tm0yj2sn	115	4	reportedly	reportedly	RB
cord-276598-tm0yj2sn	115	5	synthesized	synthesize	VBD
cord-276598-tm0yj2sn	115	6	and	and	CC
cord-276598-tm0yj2sn	115	7	investigated	investigate	VBD
cord-276598-tm0yj2sn	115	8	the	the	DT
cord-276598-tm0yj2sn	115	9	nucleophilicity	nucleophilicity	NN
cord-276598-tm0yj2sn	115	10	of	of	IN
cord-276598-tm0yj2sn	115	11	various	various	JJ
cord-276598-tm0yj2sn	115	12	P	p	NN
cord-276598-tm0yj2sn	115	13	-	-	HYPH
cord-276598-tm0yj2sn	115	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	115	15	in	in	IN
cord-276598-tm0yj2sn	115	16	1967	1967	CD
cord-276598-tm0yj2sn	115	17	[	[	-LRB-
cord-276598-tm0yj2sn	115	18	84	84	CD
cord-276598-tm0yj2sn	115	19	]	]	-RRB-
cord-276598-tm0yj2sn	115	20	.	.	.
cord-276598-tm0yj2sn	116	1	Two	two	CD
cord-276598-tm0yj2sn	116	2	years	year	NNS
cord-276598-tm0yj2sn	116	3	later	later	RB
cord-276598-tm0yj2sn	116	4	,	,	,
cord-276598-tm0yj2sn	116	5	a	a	DT
cord-276598-tm0yj2sn	116	6	mixture	mixture	NN
cord-276598-tm0yj2sn	116	7	of	of	IN
cord-276598-tm0yj2sn	116	8	N	n	NN
cord-276598-tm0yj2sn	116	9	-	-	HYPH
cord-276598-tm0yj2sn	116	10	arylphosphoramidates	arylphosphoramidates	NNP
cord-276598-tm0yj2sn	116	11	,	,	,
cord-276598-tm0yj2sn	116	12	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	116	13	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	116	14	,	,	,
cord-276598-tm0yj2sn	116	15	and	and	CC
cord-276598-tm0yj2sn	116	16	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	116	17	were	be	VBD
cord-276598-tm0yj2sn	116	18	obtained	obtain	VBN
cord-276598-tm0yj2sn	116	19	when	when	WRB
cord-276598-tm0yj2sn	116	20	nitrosoand	nitrosoand	NNP
cord-276598-tm0yj2sn	116	21	nitro	nitro	NN
cord-276598-tm0yj2sn	116	22	-	-	HYPH
cord-276598-tm0yj2sn	116	23	compounds	compound	NNS
cord-276598-tm0yj2sn	116	24	were	be	VBD
cord-276598-tm0yj2sn	116	25	reduced	reduce	VBN
cord-276598-tm0yj2sn	116	26	in	in	IN
cord-276598-tm0yj2sn	116	27	the	the	DT
cord-276598-tm0yj2sn	116	28	presence	presence	NN
cord-276598-tm0yj2sn	116	29	of	of	IN
cord-276598-tm0yj2sn	116	30	(	(	-LRB-
cord-276598-tm0yj2sn	116	31	RO	ro	NN
cord-276598-tm0yj2sn	116	32	)	)	-RRB-
cord-276598-tm0yj2sn	116	33	3	3	CD
cord-276598-tm0yj2sn	116	34	P	p	NN
cord-276598-tm0yj2sn	116	35	(	(	-LRB-
cord-276598-tm0yj2sn	116	36	R	r	NN
cord-276598-tm0yj2sn	116	37	=	=	NN
cord-276598-tm0yj2sn	116	38	alkyl	alkyl	NN
cord-276598-tm0yj2sn	116	39	)	)	-RRB-
cord-276598-tm0yj2sn	117	1	[	[	-LRB-
cord-276598-tm0yj2sn	117	2	85	85	CD
cord-276598-tm0yj2sn	117	3	]	]	-RRB-
cord-276598-tm0yj2sn	117	4	.	.	.
cord-276598-tm0yj2sn	118	1	In	in	IN
cord-276598-tm0yj2sn	118	2	1975	1975	CD
cord-276598-tm0yj2sn	118	3	,	,	,
cord-276598-tm0yj2sn	118	4	Appel	Appel	NNP
cord-276598-tm0yj2sn	118	5	and	and	CC
cord-276598-tm0yj2sn	118	6	Einig	Einig	NNP
cord-276598-tm0yj2sn	118	7	[	[	-LRB-
cord-276598-tm0yj2sn	118	8	86	86	CD
cord-276598-tm0yj2sn	118	9	]	]	-RRB-
cord-276598-tm0yj2sn	118	10	reported	report	VBD
cord-276598-tm0yj2sn	118	11	a	a	DT
cord-276598-tm0yj2sn	118	12	new	new	JJ
cord-276598-tm0yj2sn	118	13	synthesis	synthesis	NN
cord-276598-tm0yj2sn	118	14	to	to	IN
cord-276598-tm0yj2sn	118	15	P	p	NN
cord-276598-tm0yj2sn	118	16	-	-	HYPH
cord-276598-tm0yj2sn	118	17	Ns	Ns	NNP
cord-276598-tm0yj2sn	118	18	by	by	IN
cord-276598-tm0yj2sn	118	19	reacting	react	VBG
cord-276598-tm0yj2sn	118	20	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	118	21	acid	acid	NN
cord-276598-tm0yj2sn	118	22	and	and	CC
cord-276598-tm0yj2sn	118	23	an	an	DT
cord-276598-tm0yj2sn	118	24	amine	amine	NN
cord-276598-tm0yj2sn	118	25	in	in	IN
cord-276598-tm0yj2sn	118	26	the	the	DT
cord-276598-tm0yj2sn	118	27	presence	presence	NN
cord-276598-tm0yj2sn	118	28	of	of	IN
cord-276598-tm0yj2sn	118	29	triphenylphosphine	triphenylphosphine	NNP
cord-276598-tm0yj2sn	118	30	(	(	-LRB-
cord-276598-tm0yj2sn	118	31	tPP	tPP	NNP
cord-276598-tm0yj2sn	118	32	)	)	-RRB-
cord-276598-tm0yj2sn	118	33	and	and	CC
cord-276598-tm0yj2sn	118	34	CCl	CCl	NNS
cord-276598-tm0yj2sn	118	35	4	4	CD
cord-276598-tm0yj2sn	118	36	.	.	.
cord-276598-tm0yj2sn	119	1	The	the	DT
cord-276598-tm0yj2sn	119	2	same	same	JJ
cord-276598-tm0yj2sn	119	3	year	year	NN
cord-276598-tm0yj2sn	119	4	,	,	,
cord-276598-tm0yj2sn	119	5	phase	phase	NN
cord-276598-tm0yj2sn	119	6	-	-	HYPH
cord-276598-tm0yj2sn	119	7	transfer	transfer	NN
cord-276598-tm0yj2sn	119	8	catalysis	catalysis	NN
cord-276598-tm0yj2sn	119	9	was	be	VBD
cord-276598-tm0yj2sn	119	10	introduced	introduce	VBN
cord-276598-tm0yj2sn	119	11	by	by	IN
cord-276598-tm0yj2sn	119	12	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	119	13	to	to	TO
cord-276598-tm0yj2sn	119	14	synthesize	synthesize	VB
cord-276598-tm0yj2sn	119	15	P	p	NN
cord-276598-tm0yj2sn	119	16	-	-	HYPH
cord-276598-tm0yj2sn	119	17	Ns	ns	NN
cord-276598-tm0yj2sn	119	18	through	through	IN
cord-276598-tm0yj2sn	119	19	the	the	DT
cord-276598-tm0yj2sn	119	20	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	119	21	of	of	IN
cord-276598-tm0yj2sn	119	22	amines	amine	NNS
cord-276598-tm0yj2sn	119	23	[	[	-LRB-
cord-276598-tm0yj2sn	119	24	87	87	CD
cord-276598-tm0yj2sn	119	25	]	]	-RRB-
cord-276598-tm0yj2sn	119	26	.	.	.
cord-276598-tm0yj2sn	120	1	The	the	DT
cord-276598-tm0yj2sn	120	2	selective	selective	JJ
cord-276598-tm0yj2sn	120	3	alkylation	alkylation	NN
cord-276598-tm0yj2sn	120	4	of	of	IN
cord-276598-tm0yj2sn	120	5	(	(	-LRB-
cord-276598-tm0yj2sn	120	6	EtO	EtO	NNP
cord-276598-tm0yj2sn	120	7	)	)	-RRB-
cord-276598-tm0yj2sn	120	8	2	2	CD
cord-276598-tm0yj2sn	120	9	P(O)NH	P(O)NH	NNP
cord-276598-tm0yj2sn	120	10	2	2	CD
cord-276598-tm0yj2sn	120	11	via	via	IN
cord-276598-tm0yj2sn	120	12	silylation	silylation	NN
cord-276598-tm0yj2sn	120	13	was	be	VBD
cord-276598-tm0yj2sn	120	14	achieved	achieve	VBN
cord-276598-tm0yj2sn	120	15	by	by	IN
cord-276598-tm0yj2sn	120	16	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	120	17	in	in	IN
cord-276598-tm0yj2sn	120	18	1982	1982	CD
cord-276598-tm0yj2sn	120	19	using	use	VBG
cord-276598-tm0yj2sn	120	20	[	[	-LRB-
cord-276598-tm0yj2sn	120	21	n	n	NNP
cord-276598-tm0yj2sn	120	22	-	-	HYPH
cord-276598-tm0yj2sn	120	23	Bu	Bu	NNP
cord-276598-tm0yj2sn	120	24	4	4	CD
cord-276598-tm0yj2sn	120	25	N]Br	N]Br	NNP
cord-276598-tm0yj2sn	120	26	catalyst	catalyst	NN
cord-276598-tm0yj2sn	120	27	(	(	-LRB-
cord-276598-tm0yj2sn	120	28	Scheme	scheme	NN
cord-276598-tm0yj2sn	120	29	2	2	CD
cord-276598-tm0yj2sn	120	30	route	route	NN
cord-276598-tm0yj2sn	120	31	E	e	NN
cord-276598-tm0yj2sn	120	32	)	)	-RRB-
cord-276598-tm0yj2sn	121	1	[	[	-LRB-
cord-276598-tm0yj2sn	121	2	88	88	CD
cord-276598-tm0yj2sn	121	3	]	]	-RRB-
cord-276598-tm0yj2sn	121	4	.	.	.
cord-276598-tm0yj2sn	122	1	In	in	IN
cord-276598-tm0yj2sn	122	2	1984	1984	CD
cord-276598-tm0yj2sn	122	3	,	,	,
cord-276598-tm0yj2sn	122	4	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	122	5	and	and	CC
cord-276598-tm0yj2sn	122	6	Osowska	Osowska	NNP
cord-276598-tm0yj2sn	122	7	-	-	HYPH
cord-276598-tm0yj2sn	122	8	Pacewicka	Pacewicka	NNP
cord-276598-tm0yj2sn	122	9	reported	report	VBD
cord-276598-tm0yj2sn	122	10	the	the	DT
cord-276598-tm0yj2sn	122	11	synthesis	synthesis	NN
cord-276598-tm0yj2sn	122	12	of	of	IN
cord-276598-tm0yj2sn	122	13	various	various	JJ
cord-276598-tm0yj2sn	122	14	P	p	NN
cord-276598-tm0yj2sn	122	15	-	-	HYPH
cord-276598-tm0yj2sn	122	16	Ns	Ns	NNP
cord-276598-tm0yj2sn	122	17	via	via	IN
cord-276598-tm0yj2sn	122	18	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	122	19	salt	salt	NN
cord-276598-tm0yj2sn	122	20	elimination	elimination	NN
cord-276598-tm0yj2sn	122	21	[	[	-LRB-
cord-276598-tm0yj2sn	122	22	89	89	CD
cord-276598-tm0yj2sn	122	23	]	]	-RRB-
cord-276598-tm0yj2sn	122	24	and	and	CC
cord-276598-tm0yj2sn	122	25	the	the	DT
cord-276598-tm0yj2sn	122	26	direct	direct	JJ
cord-276598-tm0yj2sn	122	27	conversion	conversion	NN
cord-276598-tm0yj2sn	122	28	of	of	IN
cord-276598-tm0yj2sn	122	29	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	122	30	acid	acid	NN
cord-276598-tm0yj2sn	122	31	[	[	-LRB-
cord-276598-tm0yj2sn	122	32	90	90	CD
cord-276598-tm0yj2sn	122	33	]	]	-RRB-
cord-276598-tm0yj2sn	122	34	.	.	.
cord-276598-tm0yj2sn	123	1	In	in	IN
cord-276598-tm0yj2sn	123	2	1985	1985	CD
cord-276598-tm0yj2sn	123	3	,	,	,
cord-276598-tm0yj2sn	123	4	Riesel	Riesel	NNP
cord-276598-tm0yj2sn	123	5	et	et	NNP
cord-276598-tm0yj2sn	123	6	al	al	NNP
cord-276598-tm0yj2sn	123	7	.	.	NNP
cord-276598-tm0yj2sn	123	8	reacted	react	VBD
cord-276598-tm0yj2sn	123	9	primary	primary	JJ
cord-276598-tm0yj2sn	123	10	amines	amine	NNS
cord-276598-tm0yj2sn	123	11	or	or	CC
cord-276598-tm0yj2sn	123	12	NH	NH	NNP
cord-276598-tm0yj2sn	123	13	3	3	CD
cord-276598-tm0yj2sn	123	14	with	with	IN
cord-276598-tm0yj2sn	123	15	(	(	-LRB-
cord-276598-tm0yj2sn	123	16	RO	ro	NN
cord-276598-tm0yj2sn	123	17	)	)	-RRB-
cord-276598-tm0yj2sn	123	18	3	3	CD
cord-276598-tm0yj2sn	123	19	P	p	NN
cord-276598-tm0yj2sn	123	20	(	(	-LRB-
cord-276598-tm0yj2sn	123	21	R	r	NN
cord-276598-tm0yj2sn	123	22	=	=	NN
cord-276598-tm0yj2sn	123	23	alkyl	alkyl	NN
cord-276598-tm0yj2sn	123	24	)	)	-RRB-
cord-276598-tm0yj2sn	123	25	and	and	CC
cord-276598-tm0yj2sn	123	26	CCl	CCl	NNS
cord-276598-tm0yj2sn	123	27	4	4	CD
cord-276598-tm0yj2sn	123	28	as	as	IN
cord-276598-tm0yj2sn	123	29	an	an	DT
cord-276598-tm0yj2sn	123	30	effective	effective	JJ
cord-276598-tm0yj2sn	123	31	route	route	NN
cord-276598-tm0yj2sn	123	32	to	to	IN
cord-276598-tm0yj2sn	123	33	P	p	NN
cord-276598-tm0yj2sn	123	34	-	-	HYPH
cord-276598-tm0yj2sn	123	35	Ns	Ns	NNP
cord-276598-tm0yj2sn	123	36	[	[	-LRB-
cord-276598-tm0yj2sn	123	37	91	91	CD
cord-276598-tm0yj2sn	123	38	]	]	-RRB-
cord-276598-tm0yj2sn	123	39	.	.	.
cord-276598-tm0yj2sn	124	1	Nielsen	Nielsen	NNP
cord-276598-tm0yj2sn	124	2	and	and	CC
cord-276598-tm0yj2sn	124	3	Caruthers	Caruthers	NNP
cord-276598-tm0yj2sn	124	4	reported	report	VBD
cord-276598-tm0yj2sn	124	5	the	the	DT
cord-276598-tm0yj2sn	124	6	first	first	JJ
cord-276598-tm0yj2sn	124	7	iodine	iodine	NN
cord-276598-tm0yj2sn	124	8	-	-	HYPH
cord-276598-tm0yj2sn	124	9	mediated	mediate	VBN
cord-276598-tm0yj2sn	124	10	reaction	reaction	NN
cord-276598-tm0yj2sn	124	11	of	of	IN
cord-276598-tm0yj2sn	124	12	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	124	13	and	and	CC
cord-276598-tm0yj2sn	124	14	n	n	NNP
cord-276598-tm0yj2sn	124	15	-	-	HYPH
cord-276598-tm0yj2sn	124	16	butylamine	butylamine	NN
cord-276598-tm0yj2sn	124	17	to	to	TO
cord-276598-tm0yj2sn	124	18	synthesize	synthesize	VB
cord-276598-tm0yj2sn	124	19	P	p	NN
cord-276598-tm0yj2sn	124	20	-	-	HYPH
cord-276598-tm0yj2sn	124	21	Ns	Ns	NNP
cord-276598-tm0yj2sn	124	22	in	in	IN
cord-276598-tm0yj2sn	124	23	1988	1988	CD
cord-276598-tm0yj2sn	124	24	(	(	-LRB-
cord-276598-tm0yj2sn	124	25	Scheme	scheme	NN
cord-276598-tm0yj2sn	124	26	2	2	CD
cord-276598-tm0yj2sn	124	27	route	route	NN
cord-276598-tm0yj2sn	124	28	F	F	NNP
cord-276598-tm0yj2sn	124	29	)	)	-RRB-
cord-276598-tm0yj2sn	124	30	[	[	-LRB-
cord-276598-tm0yj2sn	124	31	92	92	CD
cord-276598-tm0yj2sn	124	32	]	]	-RRB-
cord-276598-tm0yj2sn	124	33	.	.	.
cord-276598-tm0yj2sn	125	1	At	at	IN
cord-276598-tm0yj2sn	125	2	about	about	RB
cord-276598-tm0yj2sn	125	3	the	the	DT
cord-276598-tm0yj2sn	125	4	same	same	JJ
cord-276598-tm0yj2sn	125	5	time	time	NN
cord-276598-tm0yj2sn	125	6	,	,	,
cord-276598-tm0yj2sn	125	7	P	P	NNP
cord-276598-tm0yj2sn	125	8	-	-	HYPH
cord-276598-tm0yj2sn	125	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	125	10	were	be	VBD
cord-276598-tm0yj2sn	125	11	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	125	12	from	from	IN
cord-276598-tm0yj2sn	125	13	a	a	DT
cord-276598-tm0yj2sn	125	14	reaction	reaction	NN
cord-276598-tm0yj2sn	125	15	of	of	IN
cord-276598-tm0yj2sn	125	16	azide	azide	NN
cord-276598-tm0yj2sn	125	17	and	and	CC
cord-276598-tm0yj2sn	125	18	(	(	-LRB-
cord-276598-tm0yj2sn	125	19	RO	RO	NNP
cord-276598-tm0yj2sn	125	20	)	)	-RRB-
cord-276598-tm0yj2sn	125	21	3	3	CD
cord-276598-tm0yj2sn	125	22	P	p	NN
cord-276598-tm0yj2sn	125	23	(	(	-LRB-
cord-276598-tm0yj2sn	125	24	R	r	NN
cord-276598-tm0yj2sn	125	25	=	=	NN
cord-276598-tm0yj2sn	125	26	alkyl	alkyl	NN
cord-276598-tm0yj2sn	125	27	)	)	-RRB-
cord-276598-tm0yj2sn	125	28	in	in	IN
cord-276598-tm0yj2sn	125	29	a	a	DT
cord-276598-tm0yj2sn	125	30	one	one	CD
cord-276598-tm0yj2sn	125	31	-	-	HYPH
cord-276598-tm0yj2sn	125	32	pot	pot	NN
cord-276598-tm0yj2sn	125	33	process	process	NN
cord-276598-tm0yj2sn	125	34	[	[	-LRB-
cord-276598-tm0yj2sn	125	35	93	93	CD
cord-276598-tm0yj2sn	125	36	]	]	-RRB-
cord-276598-tm0yj2sn	125	37	.	.	.
cord-276598-tm0yj2sn	126	1	A	a	DT
cord-276598-tm0yj2sn	126	2	magnesium	magnesium	NN
cord-276598-tm0yj2sn	126	3	chloride	chloride	NN
cord-276598-tm0yj2sn	126	4	-	-	HYPH
cord-276598-tm0yj2sn	126	5	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	126	6	reaction	reaction	NN
cord-276598-tm0yj2sn	126	7	of	of	IN
cord-276598-tm0yj2sn	126	8	2,6-dimethylphenol	2,6-dimethylphenol	CD
cord-276598-tm0yj2sn	126	9	and	and	CC
cord-276598-tm0yj2sn	126	10	phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	126	11	oxychloride	oxychloride	NN
cord-276598-tm0yj2sn	126	12	was	be	VBD
cord-276598-tm0yj2sn	126	13	used	use	VBN
cord-276598-tm0yj2sn	126	14	to	to	TO
cord-276598-tm0yj2sn	126	15	generate	generate	VB
cord-276598-tm0yj2sn	126	16	phosphorochloridate	phosphorochloridate	NN
cord-276598-tm0yj2sn	126	17	,	,	,
cord-276598-tm0yj2sn	126	18	which	which	WDT
cord-276598-tm0yj2sn	126	19	was	be	VBD
cord-276598-tm0yj2sn	126	20	used	use	VBN
cord-276598-tm0yj2sn	126	21	for	for	IN
cord-276598-tm0yj2sn	126	22	the	the	DT
cord-276598-tm0yj2sn	126	23	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	126	24	of	of	IN
cord-276598-tm0yj2sn	126	25	amines	amine	NNS
cord-276598-tm0yj2sn	126	26	to	to	TO
cord-276598-tm0yj2sn	126	27	synthesize	synthesize	VB
cord-276598-tm0yj2sn	126	28	P	p	NN
cord-276598-tm0yj2sn	126	29	-	-	HYPH
cord-276598-tm0yj2sn	126	30	Ns	Ns	NNP
cord-276598-tm0yj2sn	126	31	[	[	-LRB-
cord-276598-tm0yj2sn	126	32	94	94	CD
cord-276598-tm0yj2sn	126	33	]	]	-RRB-
cord-276598-tm0yj2sn	126	34	.	.	.
cord-276598-tm0yj2sn	127	1	The	the	DT
cord-276598-tm0yj2sn	127	2	aforementioned	aforementioned	JJ
cord-276598-tm0yj2sn	127	3	syntheses	synthesis	NNS
cord-276598-tm0yj2sn	127	4	demonstrate	demonstrate	VBP
cord-276598-tm0yj2sn	127	5	the	the	DT
cord-276598-tm0yj2sn	127	6	diversity	diversity	NN
cord-276598-tm0yj2sn	127	7	of	of	IN
cord-276598-tm0yj2sn	127	8	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	127	9	synthons	synthon	NNS
cord-276598-tm0yj2sn	127	10	available	available	JJ
cord-276598-tm0yj2sn	127	11	for	for	IN
cord-276598-tm0yj2sn	127	12	P	p	NN
cord-276598-tm0yj2sn	127	13	-	-	HYPH
cord-276598-tm0yj2sn	127	14	N	n	CD
cord-276598-tm0yj2sn	127	15	chemistry	chemistry	NN
cord-276598-tm0yj2sn	127	16	up	up	IN
cord-276598-tm0yj2sn	127	17	until	until	IN
cord-276598-tm0yj2sn	127	18	1988	1988	CD
cord-276598-tm0yj2sn	127	19	and	and	CC
cord-276598-tm0yj2sn	127	20	highlight	highlight	VB
cord-276598-tm0yj2sn	127	21	the	the	DT
cord-276598-tm0yj2sn	127	22	main	main	JJ
cord-276598-tm0yj2sn	127	23	pioneers	pioneer	NNS
cord-276598-tm0yj2sn	127	24	in	in	IN
cord-276598-tm0yj2sn	127	25	the	the	DT
cord-276598-tm0yj2sn	127	26	field	field	NN
cord-276598-tm0yj2sn	127	27	(	(	-LRB-
cord-276598-tm0yj2sn	127	28	Figure	figure	NN
cord-276598-tm0yj2sn	127	29	4	4	CD
cord-276598-tm0yj2sn	127	30	)	)	-RRB-
cord-276598-tm0yj2sn	127	31	.	.	.
cord-276598-tm0yj2sn	128	1	The	the	DT
cord-276598-tm0yj2sn	128	2	research	research	NN
cord-276598-tm0yj2sn	128	3	in	in	IN
cord-276598-tm0yj2sn	128	4	these	these	DT
cord-276598-tm0yj2sn	128	5	initial	initial	JJ
cord-276598-tm0yj2sn	128	6	studies	study	NNS
cord-276598-tm0yj2sn	128	7	has	have	VBZ
cord-276598-tm0yj2sn	128	8	focused	focus	VBN
cord-276598-tm0yj2sn	128	9	on	on	IN
cord-276598-tm0yj2sn	128	10	reducing	reduce	VBG
cord-276598-tm0yj2sn	128	11	waste	waste	NN
cord-276598-tm0yj2sn	128	12	,	,	,
cord-276598-tm0yj2sn	128	13	limiting	limit	VBG
cord-276598-tm0yj2sn	128	14	toxic	toxic	JJ
cord-276598-tm0yj2sn	128	15	reagents	reagent	NNS
cord-276598-tm0yj2sn	128	16	,	,	,
cord-276598-tm0yj2sn	128	17	improving	improve	VBG
cord-276598-tm0yj2sn	128	18	selectivity	selectivity	NN
cord-276598-tm0yj2sn	128	19	,	,	,
cord-276598-tm0yj2sn	128	20	expanding	expand	VBG
cord-276598-tm0yj2sn	128	21	scope	scope	NN
cord-276598-tm0yj2sn	128	22	,	,	,
cord-276598-tm0yj2sn	128	23	and	and	CC
cord-276598-tm0yj2sn	128	24	searching	search	VBG
cord-276598-tm0yj2sn	128	25	for	for	IN
cord-276598-tm0yj2sn	128	26	effective	effective	JJ
cord-276598-tm0yj2sn	128	27	and	and	CC
cord-276598-tm0yj2sn	128	28	efficient	efficient	JJ
cord-276598-tm0yj2sn	128	29	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	128	30	P	p	NN
cord-276598-tm0yj2sn	128	31	-	-	HYPH
cord-276598-tm0yj2sn	128	32	N	n	CD
cord-276598-tm0yj2sn	128	33	bond	bond	NN
cord-276598-tm0yj2sn	128	34	-	-	HYPH
cord-276598-tm0yj2sn	128	35	making	make	VBG
cord-276598-tm0yj2sn	128	36	solutions	solution	NNS
cord-276598-tm0yj2sn	128	37	.	.	.
cord-276598-tm0yj2sn	129	1	The	the	DT
cord-276598-tm0yj2sn	129	2	aforementioned	aforementioned	JJ
cord-276598-tm0yj2sn	129	3	syntheses	synthesis	NNS
cord-276598-tm0yj2sn	129	4	demonstrate	demonstrate	VBP
cord-276598-tm0yj2sn	129	5	the	the	DT
cord-276598-tm0yj2sn	129	6	diversity	diversity	NN
cord-276598-tm0yj2sn	129	7	of	of	IN
cord-276598-tm0yj2sn	129	8	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	129	9	synthons	synthon	NNS
cord-276598-tm0yj2sn	129	10	available	available	JJ
cord-276598-tm0yj2sn	129	11	for	for	IN
cord-276598-tm0yj2sn	129	12	P	p	NN
cord-276598-tm0yj2sn	129	13	-	-	HYPH
cord-276598-tm0yj2sn	129	14	N	n	CD
cord-276598-tm0yj2sn	129	15	chemistry	chemistry	NN
cord-276598-tm0yj2sn	129	16	up	up	IN
cord-276598-tm0yj2sn	129	17	until	until	IN
cord-276598-tm0yj2sn	129	18	1988	1988	CD
cord-276598-tm0yj2sn	129	19	and	and	CC
cord-276598-tm0yj2sn	129	20	highlight	highlight	VB
cord-276598-tm0yj2sn	129	21	the	the	DT
cord-276598-tm0yj2sn	129	22	main	main	JJ
cord-276598-tm0yj2sn	129	23	pioneers	pioneer	NNS
cord-276598-tm0yj2sn	129	24	in	in	IN
cord-276598-tm0yj2sn	129	25	the	the	DT
cord-276598-tm0yj2sn	129	26	field	field	NN
cord-276598-tm0yj2sn	129	27	(	(	-LRB-
cord-276598-tm0yj2sn	129	28	Figure	figure	NN
cord-276598-tm0yj2sn	129	29	4	4	CD
cord-276598-tm0yj2sn	129	30	)	)	-RRB-
cord-276598-tm0yj2sn	129	31	.	.	.
cord-276598-tm0yj2sn	130	1	The	the	DT
cord-276598-tm0yj2sn	130	2	research	research	NN
cord-276598-tm0yj2sn	130	3	in	in	IN
cord-276598-tm0yj2sn	130	4	these	these	DT
cord-276598-tm0yj2sn	130	5	initial	initial	JJ
cord-276598-tm0yj2sn	130	6	studies	study	NNS
cord-276598-tm0yj2sn	130	7	has	have	VBZ
cord-276598-tm0yj2sn	130	8	focused	focus	VBN
cord-276598-tm0yj2sn	130	9	on	on	IN
cord-276598-tm0yj2sn	130	10	reducing	reduce	VBG
cord-276598-tm0yj2sn	130	11	waste	waste	NN
cord-276598-tm0yj2sn	130	12	,	,	,
cord-276598-tm0yj2sn	130	13	limiting	limit	VBG
cord-276598-tm0yj2sn	130	14	toxic	toxic	JJ
cord-276598-tm0yj2sn	130	15	reagents	reagent	NNS
cord-276598-tm0yj2sn	130	16	,	,	,
cord-276598-tm0yj2sn	130	17	improving	improve	VBG
cord-276598-tm0yj2sn	130	18	selectivity	selectivity	NN
cord-276598-tm0yj2sn	130	19	,	,	,
cord-276598-tm0yj2sn	130	20	expanding	expand	VBG
cord-276598-tm0yj2sn	130	21	scope	scope	NN
cord-276598-tm0yj2sn	130	22	,	,	,
cord-276598-tm0yj2sn	130	23	and	and	CC
cord-276598-tm0yj2sn	130	24	searching	search	VBG
cord-276598-tm0yj2sn	130	25	for	for	IN
cord-276598-tm0yj2sn	130	26	effective	effective	JJ
cord-276598-tm0yj2sn	130	27	and	and	CC
cord-276598-tm0yj2sn	130	28	efficient	efficient	JJ
cord-276598-tm0yj2sn	130	29	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	130	30	P	p	NN
cord-276598-tm0yj2sn	130	31	-	-	HYPH
cord-276598-tm0yj2sn	130	32	N	n	CD
cord-276598-tm0yj2sn	130	33	bond	bond	NN
cord-276598-tm0yj2sn	130	34	-	-	HYPH
cord-276598-tm0yj2sn	130	35	making	make	VBG
cord-276598-tm0yj2sn	130	36	solutions	solution	NNS
cord-276598-tm0yj2sn	130	37	.	.	.
cord-276598-tm0yj2sn	131	1	The	the	DT
cord-276598-tm0yj2sn	131	2	aforementioned	aforementioned	JJ
cord-276598-tm0yj2sn	131	3	syntheses	synthesis	NNS
cord-276598-tm0yj2sn	131	4	demonstrate	demonstrate	VBP
cord-276598-tm0yj2sn	131	5	the	the	DT
cord-276598-tm0yj2sn	131	6	diversity	diversity	NN
cord-276598-tm0yj2sn	131	7	of	of	IN
cord-276598-tm0yj2sn	131	8	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	131	9	synthons	synthon	NNS
cord-276598-tm0yj2sn	131	10	available	available	JJ
cord-276598-tm0yj2sn	131	11	for	for	IN
cord-276598-tm0yj2sn	131	12	P	p	NN
cord-276598-tm0yj2sn	131	13	-	-	HYPH
cord-276598-tm0yj2sn	131	14	N	n	CD
cord-276598-tm0yj2sn	131	15	chemistry	chemistry	NN
cord-276598-tm0yj2sn	131	16	up	up	IN
cord-276598-tm0yj2sn	131	17	until	until	IN
cord-276598-tm0yj2sn	131	18	1988	1988	CD
cord-276598-tm0yj2sn	131	19	and	and	CC
cord-276598-tm0yj2sn	131	20	highlight	highlight	VB
cord-276598-tm0yj2sn	131	21	the	the	DT
cord-276598-tm0yj2sn	131	22	main	main	JJ
cord-276598-tm0yj2sn	131	23	pioneers	pioneer	NNS
cord-276598-tm0yj2sn	131	24	in	in	IN
cord-276598-tm0yj2sn	131	25	the	the	DT
cord-276598-tm0yj2sn	131	26	field	field	NN
cord-276598-tm0yj2sn	131	27	(	(	-LRB-
cord-276598-tm0yj2sn	131	28	Figure	figure	NN
cord-276598-tm0yj2sn	131	29	4	4	CD
cord-276598-tm0yj2sn	131	30	)	)	-RRB-
cord-276598-tm0yj2sn	131	31	.	.	.
cord-276598-tm0yj2sn	132	1	The	the	DT
cord-276598-tm0yj2sn	132	2	research	research	NN
cord-276598-tm0yj2sn	132	3	in	in	IN
cord-276598-tm0yj2sn	132	4	these	these	DT
cord-276598-tm0yj2sn	132	5	initial	initial	JJ
cord-276598-tm0yj2sn	132	6	studies	study	NNS
cord-276598-tm0yj2sn	132	7	has	have	VBZ
cord-276598-tm0yj2sn	132	8	focused	focus	VBN
cord-276598-tm0yj2sn	132	9	on	on	IN
cord-276598-tm0yj2sn	132	10	reducing	reduce	VBG
cord-276598-tm0yj2sn	132	11	waste	waste	NN
cord-276598-tm0yj2sn	132	12	,	,	,
cord-276598-tm0yj2sn	132	13	limiting	limit	VBG
cord-276598-tm0yj2sn	132	14	toxic	toxic	JJ
cord-276598-tm0yj2sn	132	15	reagents	reagent	NNS
cord-276598-tm0yj2sn	132	16	,	,	,
cord-276598-tm0yj2sn	132	17	improving	improve	VBG
cord-276598-tm0yj2sn	132	18	selectivity	selectivity	NN
cord-276598-tm0yj2sn	132	19	,	,	,
cord-276598-tm0yj2sn	132	20	expanding	expand	VBG
cord-276598-tm0yj2sn	132	21	scope	scope	NN
cord-276598-tm0yj2sn	132	22	,	,	,
cord-276598-tm0yj2sn	132	23	and	and	CC
cord-276598-tm0yj2sn	132	24	searching	search	VBG
cord-276598-tm0yj2sn	132	25	for	for	IN
cord-276598-tm0yj2sn	132	26	effective	effective	JJ
cord-276598-tm0yj2sn	132	27	and	and	CC
cord-276598-tm0yj2sn	132	28	efficient	efficient	JJ
cord-276598-tm0yj2sn	132	29	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	132	30	P	p	NN
cord-276598-tm0yj2sn	132	31	-	-	HYPH
cord-276598-tm0yj2sn	132	32	N	n	CD
cord-276598-tm0yj2sn	132	33	bond	bond	NN
cord-276598-tm0yj2sn	132	34	-	-	HYPH
cord-276598-tm0yj2sn	132	35	making	make	VBG
cord-276598-tm0yj2sn	132	36	solutions	solution	NNS
cord-276598-tm0yj2sn	132	37	.	.	.
cord-276598-tm0yj2sn	132	38	 	 	_SP
cord-276598-tm0yj2sn	133	1	A	a	DT
cord-276598-tm0yj2sn	133	2	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	133	3	P	p	NN
cord-276598-tm0yj2sn	133	4	-	-	HYPH
cord-276598-tm0yj2sn	133	5	N	N	NNP
cord-276598-tm0yj2sn	133	6	was	be	VBD
cord-276598-tm0yj2sn	133	7	fortuitously	fortuitously	RB
cord-276598-tm0yj2sn	133	8	prepared	prepare	VBN
cord-276598-tm0yj2sn	133	9	by	by	IN
cord-276598-tm0yj2sn	133	10	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	133	11	,	,	,
cord-276598-tm0yj2sn	133	12	Openshaw	Openshaw	NNP
cord-276598-tm0yj2sn	133	13	,	,	,
cord-276598-tm0yj2sn	133	14	and	and	CC
cord-276598-tm0yj2sn	133	15	Todd	Todd	NNP
cord-276598-tm0yj2sn	133	16	in	in	IN
cord-276598-tm0yj2sn	133	17	1945	1945	CD
cord-276598-tm0yj2sn	133	18	by	by	IN
cord-276598-tm0yj2sn	133	19	the	the	DT
cord-276598-tm0yj2sn	133	20	salt	salt	NN
cord-276598-tm0yj2sn	133	21	elimination	elimination	NN
cord-276598-tm0yj2sn	133	22	method	method	NN
cord-276598-tm0yj2sn	133	23	using	use	VBG
cord-276598-tm0yj2sn	133	24	H	h	NN
cord-276598-tm0yj2sn	133	25	-	-	HYPH
cord-276598-tm0yj2sn	133	26	phosphonates	phosphonates	FW
cord-276598-tm0yj2sn	133	27	(	(	-LRB-
cord-276598-tm0yj2sn	133	28	H	h	NN
cord-276598-tm0yj2sn	133	29	-	-	HYPH
cord-276598-tm0yj2sn	133	30	P	p	NN
cord-276598-tm0yj2sn	133	31	)	)	-RRB-
cord-276598-tm0yj2sn	133	32	(	(	-LRB-
cord-276598-tm0yj2sn	133	33	(	(	-LRB-
cord-276598-tm0yj2sn	133	34	RO	RO	NNP
cord-276598-tm0yj2sn	133	35	)	)	-RRB-
cord-276598-tm0yj2sn	133	36	2	2	CD
cord-276598-tm0yj2sn	133	37	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	133	38	;	;	:
cord-276598-tm0yj2sn	134	1	R	r	NN
cord-276598-tm0yj2sn	134	2	=	=	FW
cord-276598-tm0yj2sn	134	3	Et	Et	NNP
cord-276598-tm0yj2sn	134	4	,	,	,
cord-276598-tm0yj2sn	134	5	i	i	NN
cord-276598-tm0yj2sn	134	6	-	-	HYPH
cord-276598-tm0yj2sn	134	7	Pr	Pr	NNP
cord-276598-tm0yj2sn	134	8	,	,	,
cord-276598-tm0yj2sn	134	9	Bn	Bn	NNP
cord-276598-tm0yj2sn	134	10	)	)	-RRB-
cord-276598-tm0yj2sn	134	11	and	and	CC
cord-276598-tm0yj2sn	134	12	ammonia	ammonia	NN
cord-276598-tm0yj2sn	134	13	in	in	IN
cord-276598-tm0yj2sn	134	14	the	the	DT
cord-276598-tm0yj2sn	134	15	presence	presence	NN
cord-276598-tm0yj2sn	134	16	of	of	IN
cord-276598-tm0yj2sn	134	17	a	a	DT
cord-276598-tm0yj2sn	134	18	base	base	NN
cord-276598-tm0yj2sn	134	19	(	(	-LRB-
cord-276598-tm0yj2sn	134	20	Scheme	scheme	NN
cord-276598-tm0yj2sn	134	21	2	2	CD
cord-276598-tm0yj2sn	134	22	route	route	NN
cord-276598-tm0yj2sn	134	23	B	b	NN
cord-276598-tm0yj2sn	134	24	)	)	-RRB-
cord-276598-tm0yj2sn	134	25	[	[	-LRB-
cord-276598-tm0yj2sn	134	26	78	78	CD
cord-276598-tm0yj2sn	134	27	]	]	-RRB-
cord-276598-tm0yj2sn	134	28	.	.	.
cord-276598-tm0yj2sn	135	1	The	the	DT
cord-276598-tm0yj2sn	135	2	scope	scope	NN
cord-276598-tm0yj2sn	135	3	of	of	IN
cord-276598-tm0yj2sn	135	4	this	this	DT
cord-276598-tm0yj2sn	135	5	method	method	NN
cord-276598-tm0yj2sn	135	6	was	be	VBD
cord-276598-tm0yj2sn	135	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	135	8	using	use	VBG
cord-276598-tm0yj2sn	135	9	different	different	JJ
cord-276598-tm0yj2sn	135	10	amines	amine	NNS
cord-276598-tm0yj2sn	135	11	(	(	-LRB-
cord-276598-tm0yj2sn	135	12	e.g.	e.g.	RB
cord-276598-tm0yj2sn	135	13	,	,	,
cord-276598-tm0yj2sn	135	14	morpholine	morpholine	NNP
cord-276598-tm0yj2sn	135	15	,	,	,
cord-276598-tm0yj2sn	135	16	cyclohexylamine	cyclohexylamine	NNP
cord-276598-tm0yj2sn	135	17	,	,	,
cord-276598-tm0yj2sn	135	18	1-phenylethan-1-amine	1-phenylethan-1-amine	CD
cord-276598-tm0yj2sn	135	19	and	and	CC
cord-276598-tm0yj2sn	135	20	benzylamine	benzylamine	NN
cord-276598-tm0yj2sn	135	21	,	,	,
cord-276598-tm0yj2sn	135	22	4-methylmorpholine	4-methylmorpholine	CD
cord-276598-tm0yj2sn	135	23	)	)	-RRB-
cord-276598-tm0yj2sn	135	24	or	or	CC
cord-276598-tm0yj2sn	135	25	a	a	DT
cord-276598-tm0yj2sn	135	26	mixture	mixture	NN
cord-276598-tm0yj2sn	135	27	of	of	IN
cord-276598-tm0yj2sn	135	28	aniline	aniline	NN
cord-276598-tm0yj2sn	135	29	and	and	CC
cord-276598-tm0yj2sn	135	30	N	N	NNP
cord-276598-tm0yj2sn	135	31	,	,	,
cord-276598-tm0yj2sn	135	32	N	N	NNP
cord-276598-tm0yj2sn	135	33	-	-	HYPH
cord-276598-tm0yj2sn	135	34	dimethylcyclohexanamine	dimethylcyclohexanamine	NNP
cord-276598-tm0yj2sn	135	35	,	,	,
cord-276598-tm0yj2sn	135	36	as	as	RB
cord-276598-tm0yj2sn	135	37	well	well	RB
cord-276598-tm0yj2sn	135	38	as	as	IN
cord-276598-tm0yj2sn	135	39	different	different	JJ
cord-276598-tm0yj2sn	135	40	solvents	solvent	NNS
cord-276598-tm0yj2sn	135	41	(	(	-LRB-
cord-276598-tm0yj2sn	135	42	e.g.	e.g.	RB
cord-276598-tm0yj2sn	135	43	,	,	,
cord-276598-tm0yj2sn	135	44	CCl	CCl	NNS
cord-276598-tm0yj2sn	135	45	4	4	CD
cord-276598-tm0yj2sn	135	46	,	,	,
cord-276598-tm0yj2sn	135	47	Cl	Cl	NNP
cord-276598-tm0yj2sn	135	48	3	3	CD
cord-276598-tm0yj2sn	135	49	CCCl	CCCl	NNS
cord-276598-tm0yj2sn	135	50	3	3	CD
cord-276598-tm0yj2sn	135	51	,	,	,
cord-276598-tm0yj2sn	135	52	and	and	CC
cord-276598-tm0yj2sn	135	53	HCl	hcl	NN
cord-276598-tm0yj2sn	135	54	2	2	CD
cord-276598-tm0yj2sn	135	55	CCCl	CCCl	NNP
cord-276598-tm0yj2sn	135	56	3	3	CD
cord-276598-tm0yj2sn	135	57	)	)	-RRB-
cord-276598-tm0yj2sn	135	58	.	.	.
cord-276598-tm0yj2sn	136	1	Isolated	isolated	JJ
cord-276598-tm0yj2sn	136	2	yields	yield	NNS
cord-276598-tm0yj2sn	136	3	of	of	IN
cord-276598-tm0yj2sn	136	4	62	62	CD
cord-276598-tm0yj2sn	136	5	-	-	SYM
cord-276598-tm0yj2sn	136	6	92	92	CD
cord-276598-tm0yj2sn	136	7	%	%	NN
cord-276598-tm0yj2sn	136	8	were	be	VBD
cord-276598-tm0yj2sn	136	9	obtained	obtain	VBN
cord-276598-tm0yj2sn	136	10	.	.	.
cord-276598-tm0yj2sn	137	1	The	the	DT
cord-276598-tm0yj2sn	137	2	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	137	3	-	-	HYPH
cord-276598-tm0yj2sn	137	4	Todd	Todd	NNP
cord-276598-tm0yj2sn	137	5	method	method	NN
cord-276598-tm0yj2sn	137	6	was	be	VBD
cord-276598-tm0yj2sn	137	7	prominent	prominent	JJ
cord-276598-tm0yj2sn	137	8	for	for	IN
cord-276598-tm0yj2sn	137	9	its	-PRON-	PRP$
cord-276598-tm0yj2sn	137	10	in	in	IN
cord-276598-tm0yj2sn	137	11	situ	situ	JJ
cord-276598-tm0yj2sn	137	12	generation	generation	NN
cord-276598-tm0yj2sn	137	13	of	of	IN
cord-276598-tm0yj2sn	137	14	(	(	-LRB-
cord-276598-tm0yj2sn	137	15	RO	ro	NN
cord-276598-tm0yj2sn	137	16	)	)	-RRB-
cord-276598-tm0yj2sn	137	17	2	2	CD
cord-276598-tm0yj2sn	138	1	P(O)Cl	P(O)Cl	VBN
cord-276598-tm0yj2sn	139	1	(	(	-LRB-
cord-276598-tm0yj2sn	139	2	dACP	dacp	JJ
cord-276598-tm0yj2sn	139	3	;	;	:
cord-276598-tm0yj2sn	139	4	R	r	NN
cord-276598-tm0yj2sn	139	5	=	=	NN
cord-276598-tm0yj2sn	139	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	139	7	,	,	,
cord-276598-tm0yj2sn	139	8	benzyl	benzyl	NN
cord-276598-tm0yj2sn	139	9	)	)	-RRB-
cord-276598-tm0yj2sn	139	10	,	,	,
cord-276598-tm0yj2sn	139	11	which	which	WDT
cord-276598-tm0yj2sn	139	12	eliminates	eliminate	VBZ
cord-276598-tm0yj2sn	139	13	the	the	DT
cord-276598-tm0yj2sn	139	14	use	use	NN
cord-276598-tm0yj2sn	139	15	of	of	IN
cord-276598-tm0yj2sn	139	16	moisture	moisture	NN
cord-276598-tm0yj2sn	139	17	-	-	HYPH
cord-276598-tm0yj2sn	139	18	and	and	CC
cord-276598-tm0yj2sn	139	19	air	air	NN
cord-276598-tm0yj2sn	139	20	-	-	HYPH
cord-276598-tm0yj2sn	139	21	sensitive	sensitive	JJ
cord-276598-tm0yj2sn	139	22	dACP	dacp	NN
cord-276598-tm0yj2sn	139	23	.	.	.
cord-276598-tm0yj2sn	140	1	However	however	RB
cord-276598-tm0yj2sn	140	2	,	,	,
cord-276598-tm0yj2sn	140	3	the	the	DT
cord-276598-tm0yj2sn	140	4	major	major	JJ
cord-276598-tm0yj2sn	140	5	drawbacks	drawback	NNS
cord-276598-tm0yj2sn	140	6	of	of	IN
cord-276598-tm0yj2sn	140	7	the	the	DT
cord-276598-tm0yj2sn	140	8	method	method	NN
cord-276598-tm0yj2sn	140	9	include	include	VBP
cord-276598-tm0yj2sn	140	10	the	the	DT
cord-276598-tm0yj2sn	140	11	use	use	NN
cord-276598-tm0yj2sn	140	12	of	of	IN
cord-276598-tm0yj2sn	140	13	halogen	halogen	NN
cord-276598-tm0yj2sn	140	14	sources	source	NNS
cord-276598-tm0yj2sn	140	15	such	such	JJ
cord-276598-tm0yj2sn	140	16	as	as	IN
cord-276598-tm0yj2sn	140	17	CCl	CCl	NNS
cord-276598-tm0yj2sn	140	18	4	4	CD
cord-276598-tm0yj2sn	140	19	,	,	,
cord-276598-tm0yj2sn	140	20	Cl	Cl	NNP
cord-276598-tm0yj2sn	140	21	3	3	CD
cord-276598-tm0yj2sn	140	22	CCCl	CCCl	NNS
cord-276598-tm0yj2sn	140	23	3	3	CD
cord-276598-tm0yj2sn	140	24	,	,	,
cord-276598-tm0yj2sn	140	25	and	and	CC
cord-276598-tm0yj2sn	140	26	HCl	hcl	NN
cord-276598-tm0yj2sn	140	27	2	2	CD
cord-276598-tm0yj2sn	140	28	CCCl	CCCl	NNS
cord-276598-tm0yj2sn	140	29	3	3	CD
cord-276598-tm0yj2sn	140	30	and	and	CC
cord-276598-tm0yj2sn	140	31	extensive	extensive	JJ
cord-276598-tm0yj2sn	140	32	work	work	NN
cord-276598-tm0yj2sn	140	33	-	-	HYPH
cord-276598-tm0yj2sn	140	34	up	up	NN
cord-276598-tm0yj2sn	140	35	/	/	SYM
cord-276598-tm0yj2sn	140	36	purification	purification	NN
cord-276598-tm0yj2sn	140	37	of	of	IN
cord-276598-tm0yj2sn	140	38	the	the	DT
cord-276598-tm0yj2sn	140	39	products	product	NNS
cord-276598-tm0yj2sn	140	40	.	.	.
cord-276598-tm0yj2sn	141	1	In	in	IN
cord-276598-tm0yj2sn	141	2	2020	2020	CD
cord-276598-tm0yj2sn	141	3	,	,	,
cord-276598-tm0yj2sn	141	4	Chen	Chen	NNP
cord-276598-tm0yj2sn	141	5	et	et	NNP
cord-276598-tm0yj2sn	141	6	al	al	NNP
cord-276598-tm0yj2sn	141	7	.	.	NNP
cord-276598-tm0yj2sn	141	8	reported	report	VBD
cord-276598-tm0yj2sn	141	9	a	a	DT
cord-276598-tm0yj2sn	141	10	modified	modify	VBN
cord-276598-tm0yj2sn	141	11	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	141	12	-	-	HYPH
cord-276598-tm0yj2sn	141	13	Todd	Todd	NNP
cord-276598-tm0yj2sn	141	14	reaction	reaction	NN
cord-276598-tm0yj2sn	141	15	for	for	IN
cord-276598-tm0yj2sn	141	16	the	the	DT
cord-276598-tm0yj2sn	141	17	synthesis	synthesis	NN
cord-276598-tm0yj2sn	141	18	of	of	IN
cord-276598-tm0yj2sn	141	19	P	P	NNP
cord-276598-tm0yj2sn	141	20	-	-	HYPH
cord-276598-tm0yj2sn	141	21	Ns	Ns	NNP
cord-276598-tm0yj2sn	141	22	using	use	VBG
cord-276598-tm0yj2sn	141	23	air	air	NN
cord-276598-tm0yj2sn	141	24	as	as	IN
cord-276598-tm0yj2sn	141	25	a	a	DT
cord-276598-tm0yj2sn	141	26	radical	radical	JJ
cord-276598-tm0yj2sn	141	27	initiator	initiator	NN
cord-276598-tm0yj2sn	141	28	(	(	-LRB-
cord-276598-tm0yj2sn	141	29	Scheme	scheme	NN
cord-276598-tm0yj2sn	141	30	3	3	CD
cord-276598-tm0yj2sn	141	31	)	)	-RRB-
cord-276598-tm0yj2sn	141	32	[	[	-LRB-
cord-276598-tm0yj2sn	141	33	95	95	CD
cord-276598-tm0yj2sn	141	34	]	]	-RRB-
cord-276598-tm0yj2sn	141	35	.	.	.
cord-276598-tm0yj2sn	142	1	The	the	DT
cord-276598-tm0yj2sn	142	2	modified	modify	VBN
cord-276598-tm0yj2sn	142	3	method	method	NN
cord-276598-tm0yj2sn	142	4	explored	explore	VBN
cord-276598-tm0yj2sn	142	5	P	P	NNP
cord-276598-tm0yj2sn	142	6	-	-	HYPH
cord-276598-tm0yj2sn	142	7	N	n	CD
cord-276598-tm0yj2sn	142	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	142	9	using	use	VBG
cord-276598-tm0yj2sn	142	10	(	(	-LRB-
cord-276598-tm0yj2sn	142	11	H	h	NN
cord-276598-tm0yj2sn	142	12	-	-	HYPH
cord-276598-tm0yj2sn	142	13	P	p	NN
cord-276598-tm0yj2sn	142	14	)	)	-RRB-
cord-276598-tm0yj2sn	142	15	(	(	-LRB-
cord-276598-tm0yj2sn	143	1	(	(	-LRB-
cord-276598-tm0yj2sn	143	2	RO	RO	NNP
cord-276598-tm0yj2sn	143	3	)	)	-RRB-
cord-276598-tm0yj2sn	143	4	2	2	CD
cord-276598-tm0yj2sn	143	5	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	143	6	;	;	:
cord-276598-tm0yj2sn	143	7	R	r	NN
cord-276598-tm0yj2sn	143	8	=	=	FW
cord-276598-tm0yj2sn	143	9	Et	et	NN
cord-276598-tm0yj2sn	143	10	,	,	,
cord-276598-tm0yj2sn	143	11	i	i	NN
cord-276598-tm0yj2sn	143	12	-	-	HYPH
cord-276598-tm0yj2sn	143	13	Pr	Pr	NNP
cord-276598-tm0yj2sn	143	14	,	,	,
cord-276598-tm0yj2sn	143	15	Bu	Bu	NNP
cord-276598-tm0yj2sn	143	16	,	,	,
cord-276598-tm0yj2sn	143	17	i	i	PRP
cord-276598-tm0yj2sn	143	18	-	-	HYPH
cord-276598-tm0yj2sn	143	19	Bu	Bu	NNP
cord-276598-tm0yj2sn	143	20	)	)	-RRB-
cord-276598-tm0yj2sn	143	21	and	and	CC
cord-276598-tm0yj2sn	143	22	benzylamine	benzylamine	JJ
cord-276598-tm0yj2sn	143	23	with	with	IN
cord-276598-tm0yj2sn	143	24	yields	yield	NNS
cord-276598-tm0yj2sn	143	25	in	in	IN
cord-276598-tm0yj2sn	143	26	the	the	DT
cord-276598-tm0yj2sn	143	27	range	range	NN
cord-276598-tm0yj2sn	143	28	of	of	IN
cord-276598-tm0yj2sn	143	29	30	30	CD
cord-276598-tm0yj2sn	143	30	-	-	SYM
cord-276598-tm0yj2sn	143	31	75	75	CD
cord-276598-tm0yj2sn	143	32	%	%	NN
cord-276598-tm0yj2sn	143	33	.	.	.
cord-276598-tm0yj2sn	144	1	Although	although	IN
cord-276598-tm0yj2sn	144	2	this	this	DT
cord-276598-tm0yj2sn	144	3	method	method	NN
cord-276598-tm0yj2sn	144	4	offered	offer	VBD
cord-276598-tm0yj2sn	144	5	advantages	advantage	NNS
cord-276598-tm0yj2sn	144	6	such	such	JJ
cord-276598-tm0yj2sn	144	7	as	as	IN
cord-276598-tm0yj2sn	144	8	using	use	VBG
cord-276598-tm0yj2sn	144	9	air	air	NN
cord-276598-tm0yj2sn	144	10	as	as	IN
cord-276598-tm0yj2sn	144	11	a	a	DT
cord-276598-tm0yj2sn	144	12	radical	radical	JJ
cord-276598-tm0yj2sn	144	13	initiator	initiator	NN
cord-276598-tm0yj2sn	144	14	at	at	IN
cord-276598-tm0yj2sn	144	15	room	room	NN
cord-276598-tm0yj2sn	144	16	temperature	temperature	NN
cord-276598-tm0yj2sn	144	17	,	,	,
cord-276598-tm0yj2sn	144	18	the	the	DT
cord-276598-tm0yj2sn	144	19	use	use	NN
cord-276598-tm0yj2sn	144	20	of	of	IN
cord-276598-tm0yj2sn	144	21	relatively	relatively	RB
cord-276598-tm0yj2sn	144	22	expensive	expensive	JJ
cord-276598-tm0yj2sn	144	23	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	CD
cord-276598-tm0yj2sn	144	24	(	(	-LRB-
cord-276598-tm0yj2sn	144	25	DBU	DBU	NNP
cord-276598-tm0yj2sn	144	26	)	)	-RRB-
cord-276598-tm0yj2sn	144	27	as	as	IN
cord-276598-tm0yj2sn	144	28	a	a	DT
cord-276598-tm0yj2sn	144	29	base	base	NN
cord-276598-tm0yj2sn	144	30	in	in	IN
cord-276598-tm0yj2sn	144	31	the	the	DT
cord-276598-tm0yj2sn	144	32	process	process	NN
cord-276598-tm0yj2sn	144	33	,	,	,
cord-276598-tm0yj2sn	144	34	the	the	DT
cord-276598-tm0yj2sn	144	35	elimination	elimination	NN
cord-276598-tm0yj2sn	144	36	of	of	IN
cord-276598-tm0yj2sn	144	37	large	large	JJ
cord-276598-tm0yj2sn	144	38	amounts	amount	NNS
cord-276598-tm0yj2sn	144	39	of	of	IN
cord-276598-tm0yj2sn	144	40	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	144	41	waste	waste	NN
cord-276598-tm0yj2sn	144	42	,	,	,
cord-276598-tm0yj2sn	144	43	and	and	CC
cord-276598-tm0yj2sn	144	44	comparatively	comparatively	RB
cord-276598-tm0yj2sn	144	45	lower	low	JJR
cord-276598-tm0yj2sn	144	46	yields	yield	NNS
cord-276598-tm0yj2sn	144	47	of	of	IN
cord-276598-tm0yj2sn	144	48	products	product	NNS
cord-276598-tm0yj2sn	144	49	are	be	VBP
cord-276598-tm0yj2sn	144	50	some	some	DT
cord-276598-tm0yj2sn	144	51	of	of	IN
cord-276598-tm0yj2sn	144	52	the	the	DT
cord-276598-tm0yj2sn	144	53	limitations	limitation	NNS
cord-276598-tm0yj2sn	144	54	.	.	.
cord-276598-tm0yj2sn	145	1	[	[	-LRB-
cord-276598-tm0yj2sn	145	2	78	78	CD
cord-276598-tm0yj2sn	145	3	]	]	-RRB-
cord-276598-tm0yj2sn	145	4	.	.	.
cord-276598-tm0yj2sn	146	1	The	the	DT
cord-276598-tm0yj2sn	146	2	scope	scope	NN
cord-276598-tm0yj2sn	146	3	of	of	IN
cord-276598-tm0yj2sn	146	4	this	this	DT
cord-276598-tm0yj2sn	146	5	method	method	NN
cord-276598-tm0yj2sn	146	6	was	be	VBD
cord-276598-tm0yj2sn	146	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	146	8	using	use	VBG
cord-276598-tm0yj2sn	146	9	different	different	JJ
cord-276598-tm0yj2sn	146	10	amines	amine	NNS
cord-276598-tm0yj2sn	146	11	(	(	-LRB-
cord-276598-tm0yj2sn	146	12	e.g.	e.g.	RB
cord-276598-tm0yj2sn	146	13	,	,	,
cord-276598-tm0yj2sn	146	14	morpholine	morpholine	NNP
cord-276598-tm0yj2sn	146	15	,	,	,
cord-276598-tm0yj2sn	146	16	cyclohexylamine	cyclohexylamine	NNP
cord-276598-tm0yj2sn	146	17	,	,	,
cord-276598-tm0yj2sn	146	18	1-phenylethan-1-amine	1-phenylethan-1-amine	CD
cord-276598-tm0yj2sn	146	19	and	and	CC
cord-276598-tm0yj2sn	146	20	benzylamine	benzylamine	NN
cord-276598-tm0yj2sn	146	21	,	,	,
cord-276598-tm0yj2sn	146	22	4-methylmorpholine	4-methylmorpholine	CD
cord-276598-tm0yj2sn	146	23	)	)	-RRB-
cord-276598-tm0yj2sn	146	24	or	or	CC
cord-276598-tm0yj2sn	146	25	a	a	DT
cord-276598-tm0yj2sn	146	26	mixture	mixture	NN
cord-276598-tm0yj2sn	146	27	of	of	IN
cord-276598-tm0yj2sn	146	28	aniline	aniline	NN
cord-276598-tm0yj2sn	146	29	and	and	CC
cord-276598-tm0yj2sn	146	30	N	N	NNP
cord-276598-tm0yj2sn	146	31	,	,	,
cord-276598-tm0yj2sn	146	32	N	N	NNP
cord-276598-tm0yj2sn	146	33	-	-	HYPH
cord-276598-tm0yj2sn	146	34	dimethylcyclohexanamine	dimethylcyclohexanamine	NNP
cord-276598-tm0yj2sn	146	35	,	,	,
cord-276598-tm0yj2sn	146	36	as	as	RB
cord-276598-tm0yj2sn	146	37	well	well	RB
cord-276598-tm0yj2sn	146	38	as	as	IN
cord-276598-tm0yj2sn	146	39	different	different	JJ
cord-276598-tm0yj2sn	146	40	solvents	solvent	NNS
cord-276598-tm0yj2sn	146	41	(	(	-LRB-
cord-276598-tm0yj2sn	146	42	e.g.	e.g.	RB
cord-276598-tm0yj2sn	146	43	,	,	,
cord-276598-tm0yj2sn	146	44	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	146	45	,	,	,
cord-276598-tm0yj2sn	146	46	Cl3CCCl3	Cl3CCCl3	NNP
cord-276598-tm0yj2sn	146	47	,	,	,
cord-276598-tm0yj2sn	146	48	and	and	CC
cord-276598-tm0yj2sn	146	49	HCl2CCCl3	HCl2CCCl3	NNP
cord-276598-tm0yj2sn	146	50	)	)	-RRB-
cord-276598-tm0yj2sn	146	51	.	.	.
cord-276598-tm0yj2sn	147	1	Isolated	isolated	JJ
cord-276598-tm0yj2sn	147	2	yields	yield	NNS
cord-276598-tm0yj2sn	147	3	of	of	IN
cord-276598-tm0yj2sn	147	4	62	62	CD
cord-276598-tm0yj2sn	147	5	-	-	SYM
cord-276598-tm0yj2sn	147	6	92	92	CD
cord-276598-tm0yj2sn	147	7	%	%	NN
cord-276598-tm0yj2sn	147	8	were	be	VBD
cord-276598-tm0yj2sn	147	9	obtained	obtain	VBN
cord-276598-tm0yj2sn	147	10	.	.	.
cord-276598-tm0yj2sn	148	1	The	the	DT
cord-276598-tm0yj2sn	148	2	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	148	3	-	-	HYPH
cord-276598-tm0yj2sn	148	4	Todd	Todd	NNP
cord-276598-tm0yj2sn	148	5	method	method	NN
cord-276598-tm0yj2sn	148	6	was	be	VBD
cord-276598-tm0yj2sn	148	7	prominent	prominent	JJ
cord-276598-tm0yj2sn	148	8	for	for	IN
cord-276598-tm0yj2sn	148	9	its	-PRON-	PRP$
cord-276598-tm0yj2sn	148	10	in	in	IN
cord-276598-tm0yj2sn	148	11	situ	situ	JJ
cord-276598-tm0yj2sn	148	12	generation	generation	NN
cord-276598-tm0yj2sn	148	13	of	of	IN
cord-276598-tm0yj2sn	148	14	(	(	-LRB-
cord-276598-tm0yj2sn	149	1	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	149	2	(	(	-LRB-
cord-276598-tm0yj2sn	149	3	dACP	dacp	NN
cord-276598-tm0yj2sn	149	4	;	;	:
cord-276598-tm0yj2sn	149	5	R	r	NN
cord-276598-tm0yj2sn	149	6	=	=	NN
cord-276598-tm0yj2sn	149	7	alkyl	alkyl	NN
cord-276598-tm0yj2sn	149	8	,	,	,
cord-276598-tm0yj2sn	149	9	benzyl	benzyl	NN
cord-276598-tm0yj2sn	149	10	)	)	-RRB-
cord-276598-tm0yj2sn	149	11	,	,	,
cord-276598-tm0yj2sn	149	12	which	which	WDT
cord-276598-tm0yj2sn	149	13	eliminates	eliminate	VBZ
cord-276598-tm0yj2sn	149	14	the	the	DT
cord-276598-tm0yj2sn	149	15	use	use	NN
cord-276598-tm0yj2sn	149	16	of	of	IN
cord-276598-tm0yj2sn	149	17	moisture	moisture	NN
cord-276598-tm0yj2sn	149	18	-	-	HYPH
cord-276598-tm0yj2sn	149	19	and	and	CC
cord-276598-tm0yj2sn	149	20	air	air	NN
cord-276598-tm0yj2sn	149	21	-	-	HYPH
cord-276598-tm0yj2sn	149	22	sensitive	sensitive	JJ
cord-276598-tm0yj2sn	149	23	dACP	dacp	NN
cord-276598-tm0yj2sn	149	24	.	.	.
cord-276598-tm0yj2sn	150	1	However	however	RB
cord-276598-tm0yj2sn	150	2	,	,	,
cord-276598-tm0yj2sn	150	3	the	the	DT
cord-276598-tm0yj2sn	150	4	major	major	JJ
cord-276598-tm0yj2sn	150	5	drawbacks	drawback	NNS
cord-276598-tm0yj2sn	150	6	of	of	IN
cord-276598-tm0yj2sn	150	7	the	the	DT
cord-276598-tm0yj2sn	150	8	method	method	NN
cord-276598-tm0yj2sn	150	9	include	include	VBP
cord-276598-tm0yj2sn	150	10	the	the	DT
cord-276598-tm0yj2sn	150	11	use	use	NN
cord-276598-tm0yj2sn	150	12	of	of	IN
cord-276598-tm0yj2sn	150	13	halogen	halogen	NN
cord-276598-tm0yj2sn	150	14	sources	source	NNS
cord-276598-tm0yj2sn	150	15	such	such	JJ
cord-276598-tm0yj2sn	150	16	as	as	IN
cord-276598-tm0yj2sn	150	17	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	150	18	,	,	,
cord-276598-tm0yj2sn	150	19	Cl3CCCl3	Cl3CCCl3	NNP
cord-276598-tm0yj2sn	150	20	,	,	,
cord-276598-tm0yj2sn	150	21	and	and	CC
cord-276598-tm0yj2sn	150	22	HCl2CCCl3	HCl2CCCl3	NNP
cord-276598-tm0yj2sn	150	23	and	and	CC
cord-276598-tm0yj2sn	150	24	extensive	extensive	JJ
cord-276598-tm0yj2sn	150	25	work	work	NN
cord-276598-tm0yj2sn	150	26	-	-	HYPH
cord-276598-tm0yj2sn	150	27	up	up	NN
cord-276598-tm0yj2sn	150	28	/	/	SYM
cord-276598-tm0yj2sn	150	29	purification	purification	NN
cord-276598-tm0yj2sn	150	30	of	of	IN
cord-276598-tm0yj2sn	150	31	the	the	DT
cord-276598-tm0yj2sn	150	32	products	product	NNS
cord-276598-tm0yj2sn	150	33	.	.	.
cord-276598-tm0yj2sn	151	1	In	in	IN
cord-276598-tm0yj2sn	151	2	2020	2020	CD
cord-276598-tm0yj2sn	151	3	,	,	,
cord-276598-tm0yj2sn	151	4	Chen	Chen	NNP
cord-276598-tm0yj2sn	151	5	et	et	NNP
cord-276598-tm0yj2sn	151	6	al	al	NNP
cord-276598-tm0yj2sn	151	7	.	.	NNP
cord-276598-tm0yj2sn	151	8	reported	report	VBD
cord-276598-tm0yj2sn	151	9	a	a	DT
cord-276598-tm0yj2sn	151	10	modified	modify	VBN
cord-276598-tm0yj2sn	151	11	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	151	12	-	-	HYPH
cord-276598-tm0yj2sn	151	13	Todd	Todd	NNP
cord-276598-tm0yj2sn	151	14	reaction	reaction	NN
cord-276598-tm0yj2sn	151	15	for	for	IN
cord-276598-tm0yj2sn	151	16	the	the	DT
cord-276598-tm0yj2sn	151	17	synthesis	synthesis	NN
cord-276598-tm0yj2sn	151	18	of	of	IN
cord-276598-tm0yj2sn	151	19	P	P	NNP
cord-276598-tm0yj2sn	151	20	-	-	HYPH
cord-276598-tm0yj2sn	151	21	Ns	Ns	NNP
cord-276598-tm0yj2sn	151	22	using	use	VBG
cord-276598-tm0yj2sn	151	23	air	air	NN
cord-276598-tm0yj2sn	151	24	as	as	IN
cord-276598-tm0yj2sn	151	25	a	a	DT
cord-276598-tm0yj2sn	151	26	radical	radical	JJ
cord-276598-tm0yj2sn	151	27	initiator	initiator	NN
cord-276598-tm0yj2sn	151	28	(	(	-LRB-
cord-276598-tm0yj2sn	151	29	Scheme	scheme	NN
cord-276598-tm0yj2sn	151	30	3	3	CD
cord-276598-tm0yj2sn	151	31	)	)	-RRB-
cord-276598-tm0yj2sn	151	32	[	[	-LRB-
cord-276598-tm0yj2sn	151	33	95	95	CD
cord-276598-tm0yj2sn	151	34	]	]	-RRB-
cord-276598-tm0yj2sn	151	35	.	.	.
cord-276598-tm0yj2sn	152	1	The	the	DT
cord-276598-tm0yj2sn	152	2	modified	modify	VBN
cord-276598-tm0yj2sn	152	3	method	method	NN
cord-276598-tm0yj2sn	152	4	explored	explore	VBN
cord-276598-tm0yj2sn	152	5	P	P	NNP
cord-276598-tm0yj2sn	152	6	-	-	HYPH
cord-276598-tm0yj2sn	152	7	N	n	CD
cord-276598-tm0yj2sn	152	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	152	9	using	use	VBG
cord-276598-tm0yj2sn	152	10	(	(	-LRB-
cord-276598-tm0yj2sn	152	11	H	h	NN
cord-276598-tm0yj2sn	152	12	-	-	HYPH
cord-276598-tm0yj2sn	152	13	P	p	NN
cord-276598-tm0yj2sn	152	14	)	)	-RRB-
cord-276598-tm0yj2sn	152	15	(	(	-LRB-
cord-276598-tm0yj2sn	152	16	(	(	-LRB-
cord-276598-tm0yj2sn	152	17	RO)2P(O)H	ro)2p(o)h	NN
cord-276598-tm0yj2sn	152	18	;	;	.
cord-276598-tm0yj2sn	153	1	R	r	NN
cord-276598-tm0yj2sn	153	2	=	=	FW
cord-276598-tm0yj2sn	153	3	Et	Et	NNP
cord-276598-tm0yj2sn	153	4	,	,	,
cord-276598-tm0yj2sn	153	5	i	i	NN
cord-276598-tm0yj2sn	153	6	-	-	HYPH
cord-276598-tm0yj2sn	153	7	Pr	Pr	NNP
cord-276598-tm0yj2sn	153	8	,	,	,
cord-276598-tm0yj2sn	153	9	Bu	Bu	NNP
cord-276598-tm0yj2sn	153	10	,	,	,
cord-276598-tm0yj2sn	153	11	i	i	PRP
cord-276598-tm0yj2sn	153	12	-	-	HYPH
cord-276598-tm0yj2sn	153	13	Bu	Bu	NNP
cord-276598-tm0yj2sn	153	14	)	)	-RRB-
cord-276598-tm0yj2sn	153	15	and	and	CC
cord-276598-tm0yj2sn	153	16	benzylamine	benzylamine	JJ
cord-276598-tm0yj2sn	153	17	with	with	IN
cord-276598-tm0yj2sn	153	18	yields	yield	NNS
cord-276598-tm0yj2sn	153	19	in	in	IN
cord-276598-tm0yj2sn	153	20	the	the	DT
cord-276598-tm0yj2sn	153	21	range	range	NN
cord-276598-tm0yj2sn	153	22	of	of	IN
cord-276598-tm0yj2sn	153	23	30	30	CD
cord-276598-tm0yj2sn	153	24	-	-	SYM
cord-276598-tm0yj2sn	153	25	75	75	CD
cord-276598-tm0yj2sn	153	26	%	%	NN
cord-276598-tm0yj2sn	153	27	.	.	.
cord-276598-tm0yj2sn	154	1	Although	although	IN
cord-276598-tm0yj2sn	154	2	this	this	DT
cord-276598-tm0yj2sn	154	3	method	method	NN
cord-276598-tm0yj2sn	154	4	offered	offer	VBD
cord-276598-tm0yj2sn	154	5	advantages	advantage	NNS
cord-276598-tm0yj2sn	154	6	such	such	JJ
cord-276598-tm0yj2sn	154	7	as	as	IN
cord-276598-tm0yj2sn	154	8	using	use	VBG
cord-276598-tm0yj2sn	154	9	air	air	NN
cord-276598-tm0yj2sn	154	10	as	as	IN
cord-276598-tm0yj2sn	154	11	a	a	DT
cord-276598-tm0yj2sn	154	12	radical	radical	JJ
cord-276598-tm0yj2sn	154	13	initiator	initiator	NN
cord-276598-tm0yj2sn	154	14	at	at	IN
cord-276598-tm0yj2sn	154	15	room	room	NN
cord-276598-tm0yj2sn	154	16	temperature	temperature	NN
cord-276598-tm0yj2sn	154	17	,	,	,
cord-276598-tm0yj2sn	154	18	the	the	DT
cord-276598-tm0yj2sn	154	19	use	use	NN
cord-276598-tm0yj2sn	154	20	of	of	IN
cord-276598-tm0yj2sn	154	21	relatively	relatively	RB
cord-276598-tm0yj2sn	154	22	expensive	expensive	JJ
cord-276598-tm0yj2sn	154	23	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	CD
cord-276598-tm0yj2sn	154	24	(	(	-LRB-
cord-276598-tm0yj2sn	154	25	DBU	DBU	NNP
cord-276598-tm0yj2sn	154	26	)	)	-RRB-
cord-276598-tm0yj2sn	154	27	as	as	IN
cord-276598-tm0yj2sn	154	28	a	a	DT
cord-276598-tm0yj2sn	154	29	base	base	NN
cord-276598-tm0yj2sn	154	30	in	in	IN
cord-276598-tm0yj2sn	154	31	the	the	DT
cord-276598-tm0yj2sn	154	32	process	process	NN
cord-276598-tm0yj2sn	154	33	,	,	,
cord-276598-tm0yj2sn	154	34	the	the	DT
cord-276598-tm0yj2sn	154	35	elimination	elimination	NN
cord-276598-tm0yj2sn	154	36	of	of	IN
cord-276598-tm0yj2sn	154	37	large	large	JJ
cord-276598-tm0yj2sn	154	38	amounts	amount	NNS
cord-276598-tm0yj2sn	154	39	of	of	IN
cord-276598-tm0yj2sn	154	40	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	154	41	waste	waste	NN
cord-276598-tm0yj2sn	154	42	,	,	,
cord-276598-tm0yj2sn	154	43	and	and	CC
cord-276598-tm0yj2sn	154	44	comparatively	comparatively	RB
cord-276598-tm0yj2sn	154	45	lower	low	JJR
cord-276598-tm0yj2sn	154	46	yields	yield	NNS
cord-276598-tm0yj2sn	154	47	of	of	IN
cord-276598-tm0yj2sn	154	48	products	product	NNS
cord-276598-tm0yj2sn	154	49	are	be	VBP
cord-276598-tm0yj2sn	154	50	some	some	DT
cord-276598-tm0yj2sn	154	51	of	of	IN
cord-276598-tm0yj2sn	154	52	the	the	DT
cord-276598-tm0yj2sn	154	53	limitations	limitation	NNS
cord-276598-tm0yj2sn	154	54	.	.	.
cord-276598-tm0yj2sn	154	55	 	 	_SP
cord-276598-tm0yj2sn	155	1	With	with	IN
cord-276598-tm0yj2sn	155	2	reference	reference	NN
cord-276598-tm0yj2sn	155	3	to	to	IN
cord-276598-tm0yj2sn	155	4	the	the	DT
cord-276598-tm0yj2sn	155	5	limitations	limitation	NNS
cord-276598-tm0yj2sn	155	6	(	(	-LRB-
cord-276598-tm0yj2sn	155	7	such	such	JJ
cord-276598-tm0yj2sn	155	8	as	as	IN
cord-276598-tm0yj2sn	155	9	low	low	JJ
cord-276598-tm0yj2sn	155	10	yield	yield	NN
cord-276598-tm0yj2sn	155	11	and	and	CC
cord-276598-tm0yj2sn	155	12	the	the	DT
cord-276598-tm0yj2sn	155	13	formation	formation	NN
cord-276598-tm0yj2sn	155	14	of	of	IN
cord-276598-tm0yj2sn	155	15	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	155	16	anhydrides	anhydride	NNS
cord-276598-tm0yj2sn	155	17	side	side	NN
cord-276598-tm0yj2sn	155	18	products	product	NNS
cord-276598-tm0yj2sn	155	19	)	)	-RRB-
cord-276598-tm0yj2sn	155	20	in	in	IN
cord-276598-tm0yj2sn	155	21	the	the	DT
cord-276598-tm0yj2sn	155	22	method	method	NN
cord-276598-tm0yj2sn	155	23	reported	report	VBN
cord-276598-tm0yj2sn	155	24	by	by	IN
cord-276598-tm0yj2sn	155	25	Appel	Appel	NNP
cord-276598-tm0yj2sn	155	26	and	and	CC
cord-276598-tm0yj2sn	155	27	Einig	Einig	NNP
cord-276598-tm0yj2sn	155	28	[	[	-LRB-
cord-276598-tm0yj2sn	155	29	86	86	CD
cord-276598-tm0yj2sn	155	30	]	]	-RRB-
cord-276598-tm0yj2sn	155	31	,	,	,
cord-276598-tm0yj2sn	155	32	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	155	33	and	and	CC
cord-276598-tm0yj2sn	155	34	Osowska	Osowska	NNP
cord-276598-tm0yj2sn	155	35	-	-	HYPH
cord-276598-tm0yj2sn	155	36	Pacewicka	Pacewicka	NNP
cord-276598-tm0yj2sn	155	37	[	[	-LRB-
cord-276598-tm0yj2sn	155	38	90	90	CD
cord-276598-tm0yj2sn	155	39	]	]	-RRB-
cord-276598-tm0yj2sn	155	40	proposed	propose	VBD
cord-276598-tm0yj2sn	155	41	an	an	DT
cord-276598-tm0yj2sn	155	42	alternative	alternative	JJ
cord-276598-tm0yj2sn	155	43	method	method	NN
cord-276598-tm0yj2sn	155	44	that	that	WDT
cord-276598-tm0yj2sn	155	45	uses	use	VBZ
cord-276598-tm0yj2sn	155	46	−OH	−oh	CD
cord-276598-tm0yj2sn	155	47	group	group	NN
cord-276598-tm0yj2sn	155	48	activator	activator	NN
cord-276598-tm0yj2sn	155	49	,	,	,
cord-276598-tm0yj2sn	155	50	hexamethyltriaminodibromophosphorane	hexamethyltriaminodibromophosphorane	NNP
cord-276598-tm0yj2sn	155	51	(	(	-LRB-
cord-276598-tm0yj2sn	155	52	(	(	-LRB-
cord-276598-tm0yj2sn	155	53	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	155	54	)	)	-RRB-
cord-276598-tm0yj2sn	155	55	.	.	.
cord-276598-tm0yj2sn	156	1	In	in	IN
cord-276598-tm0yj2sn	156	2	the	the	DT
cord-276598-tm0yj2sn	156	3	reported	report	VBN
cord-276598-tm0yj2sn	156	4	method	method	NN
cord-276598-tm0yj2sn	156	5	,	,	,
cord-276598-tm0yj2sn	156	6	(	(	-LRB-
cord-276598-tm0yj2sn	156	7	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	156	8	was	be	VBD
cord-276598-tm0yj2sn	156	9	prepared	prepare	VBN
cord-276598-tm0yj2sn	156	10	in	in	IN
cord-276598-tm0yj2sn	156	11	situ	situ	NNS
cord-276598-tm0yj2sn	156	12	in	in	IN
cord-276598-tm0yj2sn	156	13	a	a	DT
cord-276598-tm0yj2sn	156	14	one	one	CD
cord-276598-tm0yj2sn	156	15	-	-	HYPH
cord-276598-tm0yj2sn	156	16	pot	pot	NN
cord-276598-tm0yj2sn	156	17	two	two	CD
cord-276598-tm0yj2sn	156	18	-	-	HYPH
cord-276598-tm0yj2sn	156	19	step	step	NN
cord-276598-tm0yj2sn	156	20	synthesis	synthesis	NN
cord-276598-tm0yj2sn	156	21	of	of	IN
cord-276598-tm0yj2sn	156	22	P	p	NN
cord-276598-tm0yj2sn	156	23	-	-	HYPH
cord-276598-tm0yj2sn	156	24	Ns	Ns	NNP
cord-276598-tm0yj2sn	156	25	from	from	IN
cord-276598-tm0yj2sn	156	26	(	(	-LRB-
cord-276598-tm0yj2sn	156	27	EtO)2P(O)OH	eto)2p(o)oh	NN
cord-276598-tm0yj2sn	156	28	and	and	CC
cord-276598-tm0yj2sn	156	29	amines	amine	NNS
cord-276598-tm0yj2sn	156	30	(	(	-LRB-
cord-276598-tm0yj2sn	156	31	Scheme	scheme	NN
cord-276598-tm0yj2sn	156	32	4	4	CD
cord-276598-tm0yj2sn	156	33	)	)	-RRB-
cord-276598-tm0yj2sn	156	34	[	[	-LRB-
cord-276598-tm0yj2sn	156	35	90	90	CD
cord-276598-tm0yj2sn	156	36	]	]	-RRB-
cord-276598-tm0yj2sn	156	37	.	.	.
cord-276598-tm0yj2sn	157	1	The	the	DT
cord-276598-tm0yj2sn	157	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	157	3	was	be	VBD
cord-276598-tm0yj2sn	157	4	explored	explore	VBN
cord-276598-tm0yj2sn	157	5	using	use	VBG
cord-276598-tm0yj2sn	157	6	various	various	JJ
cord-276598-tm0yj2sn	157	7	amines	amine	NNS
cord-276598-tm0yj2sn	157	8	such	such	JJ
cord-276598-tm0yj2sn	157	9	as	as	IN
cord-276598-tm0yj2sn	157	10	aniline	aniline	NN
cord-276598-tm0yj2sn	157	11	,	,	,
cord-276598-tm0yj2sn	157	12	phenylmethanamine	phenylmethanamine	NN
cord-276598-tm0yj2sn	157	13	,	,	,
cord-276598-tm0yj2sn	157	14	dibutylamine	dibutylamine	NNP
cord-276598-tm0yj2sn	157	15	,	,	,
cord-276598-tm0yj2sn	157	16	butan-1-amine	butan-1-amine	NNP
cord-276598-tm0yj2sn	157	17	,	,	,
cord-276598-tm0yj2sn	157	18	dipropylamine	dipropylamine	NN
cord-276598-tm0yj2sn	157	19	,	,	,
cord-276598-tm0yj2sn	157	20	and	and	CC
cord-276598-tm0yj2sn	157	21	hept-1-en-2-amine	hept-1-en-2-amine	NN
cord-276598-tm0yj2sn	157	22	.	.	.
cord-276598-tm0yj2sn	158	1	This	this	DT
cord-276598-tm0yj2sn	158	2	method	method	NN
cord-276598-tm0yj2sn	158	3	was	be	VBD
cord-276598-tm0yj2sn	158	4	favorable	favorable	JJ
cord-276598-tm0yj2sn	158	5	with	with	IN
cord-276598-tm0yj2sn	158	6	improved	improved	JJ
cord-276598-tm0yj2sn	158	7	yields	yield	NNS
cord-276598-tm0yj2sn	158	8	of	of	IN
cord-276598-tm0yj2sn	158	9	P	p	NN
cord-276598-tm0yj2sn	158	10	-	-	HYPH
cord-276598-tm0yj2sn	158	11	N	n	CD
cord-276598-tm0yj2sn	158	12	products	product	NNS
cord-276598-tm0yj2sn	158	13	(	(	-LRB-
cord-276598-tm0yj2sn	158	14	59	59	CD
cord-276598-tm0yj2sn	158	15	-	-	SYM
cord-276598-tm0yj2sn	158	16	91	91	CD
cord-276598-tm0yj2sn	158	17	%	%	NN
cord-276598-tm0yj2sn	158	18	)	)	-RRB-
cord-276598-tm0yj2sn	158	19	after	after	IN
cord-276598-tm0yj2sn	158	20	workup	workup	NN
cord-276598-tm0yj2sn	158	21	and	and	CC
cord-276598-tm0yj2sn	158	22	eliminated	eliminate	VBD
cord-276598-tm0yj2sn	158	23	the	the	DT
cord-276598-tm0yj2sn	158	24	route(s	route(s	NNP
cord-276598-tm0yj2sn	158	25	)	)	-RRB-
cord-276598-tm0yj2sn	158	26	for	for	IN
cord-276598-tm0yj2sn	158	27	anhydride	anhydride	NN
cord-276598-tm0yj2sn	158	28	formation	formation	NN
cord-276598-tm0yj2sn	158	29	.	.	.
cord-276598-tm0yj2sn	159	1	Nevertheless	nevertheless	RB
cord-276598-tm0yj2sn	159	2	,	,	,
cord-276598-tm0yj2sn	159	3	the	the	DT
cord-276598-tm0yj2sn	159	4	method	method	NN
cord-276598-tm0yj2sn	159	5	used	use	VBN
cord-276598-tm0yj2sn	159	6	potentially	potentially	RB
cord-276598-tm0yj2sn	159	7	harmful	harmful	JJ
cord-276598-tm0yj2sn	159	8	bromine	bromine	NN
cord-276598-tm0yj2sn	159	9	in	in	IN
cord-276598-tm0yj2sn	159	10	a	a	DT
cord-276598-tm0yj2sn	159	11	multi	multi	JJ
cord-276598-tm0yj2sn	159	12	-	-	JJ
cord-276598-tm0yj2sn	159	13	step	step	JJ
cord-276598-tm0yj2sn	159	14	tedious	tedious	JJ
cord-276598-tm0yj2sn	159	15	process	process	NN
cord-276598-tm0yj2sn	159	16	with	with	IN
cord-276598-tm0yj2sn	159	17	low	low	JJ
cord-276598-tm0yj2sn	159	18	atom	atom	NN
cord-276598-tm0yj2sn	159	19	economy	economy	NN
cord-276598-tm0yj2sn	159	20	.	.	.
cord-276598-tm0yj2sn	159	21	 	 	_SP
cord-276598-tm0yj2sn	160	1	With	with	IN
cord-276598-tm0yj2sn	160	2	reference	reference	NN
cord-276598-tm0yj2sn	160	3	to	to	IN
cord-276598-tm0yj2sn	160	4	the	the	DT
cord-276598-tm0yj2sn	160	5	limitations	limitation	NNS
cord-276598-tm0yj2sn	160	6	(	(	-LRB-
cord-276598-tm0yj2sn	160	7	such	such	JJ
cord-276598-tm0yj2sn	160	8	as	as	IN
cord-276598-tm0yj2sn	160	9	low	low	JJ
cord-276598-tm0yj2sn	160	10	yield	yield	NN
cord-276598-tm0yj2sn	160	11	and	and	CC
cord-276598-tm0yj2sn	160	12	the	the	DT
cord-276598-tm0yj2sn	160	13	formation	formation	NN
cord-276598-tm0yj2sn	160	14	of	of	IN
cord-276598-tm0yj2sn	160	15	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	160	16	anhydrides	anhydride	NNS
cord-276598-tm0yj2sn	160	17	side	side	NN
cord-276598-tm0yj2sn	160	18	products	product	NNS
cord-276598-tm0yj2sn	160	19	)	)	-RRB-
cord-276598-tm0yj2sn	160	20	in	in	IN
cord-276598-tm0yj2sn	160	21	the	the	DT
cord-276598-tm0yj2sn	160	22	method	method	NN
cord-276598-tm0yj2sn	160	23	reported	report	VBN
cord-276598-tm0yj2sn	160	24	by	by	IN
cord-276598-tm0yj2sn	160	25	Appel	Appel	NNP
cord-276598-tm0yj2sn	160	26	and	and	CC
cord-276598-tm0yj2sn	160	27	Einig	Einig	NNP
cord-276598-tm0yj2sn	160	28	[	[	-LRB-
cord-276598-tm0yj2sn	160	29	86	86	CD
cord-276598-tm0yj2sn	160	30	]	]	-RRB-
cord-276598-tm0yj2sn	160	31	,	,	,
cord-276598-tm0yj2sn	160	32	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	160	33	and	and	CC
cord-276598-tm0yj2sn	160	34	Osowska	Osowska	NNP
cord-276598-tm0yj2sn	160	35	-	-	HYPH
cord-276598-tm0yj2sn	160	36	Pacewicka	Pacewicka	NNP
cord-276598-tm0yj2sn	160	37	[	[	-LRB-
cord-276598-tm0yj2sn	160	38	90	90	CD
cord-276598-tm0yj2sn	160	39	]	]	-RRB-
cord-276598-tm0yj2sn	160	40	proposed	propose	VBD
cord-276598-tm0yj2sn	160	41	an	an	DT
cord-276598-tm0yj2sn	160	42	alternative	alternative	JJ
cord-276598-tm0yj2sn	160	43	method	method	NN
cord-276598-tm0yj2sn	160	44	that	that	WDT
cord-276598-tm0yj2sn	160	45	uses	use	VBZ
cord-276598-tm0yj2sn	160	46	−OH	−oh	CD
cord-276598-tm0yj2sn	160	47	group	group	NN
cord-276598-tm0yj2sn	160	48	activator	activator	NN
cord-276598-tm0yj2sn	160	49	,	,	,
cord-276598-tm0yj2sn	160	50	hexamethyltriaminodibromophosphorane	hexamethyltriaminodibromophosphorane	NNP
cord-276598-tm0yj2sn	160	51	(	(	-LRB-
cord-276598-tm0yj2sn	160	52	(	(	-LRB-
cord-276598-tm0yj2sn	160	53	Me	Me	NNP
cord-276598-tm0yj2sn	160	54	2	2	CD
cord-276598-tm0yj2sn	160	55	N	n	CD
cord-276598-tm0yj2sn	160	56	)	)	-RRB-
cord-276598-tm0yj2sn	160	57	3	3	CD
cord-276598-tm0yj2sn	160	58	PBr	PBr	NNS
cord-276598-tm0yj2sn	160	59	2	2	CD
cord-276598-tm0yj2sn	160	60	)	)	-RRB-
cord-276598-tm0yj2sn	160	61	.	.	.
cord-276598-tm0yj2sn	161	1	In	in	IN
cord-276598-tm0yj2sn	161	2	the	the	DT
cord-276598-tm0yj2sn	161	3	reported	report	VBN
cord-276598-tm0yj2sn	161	4	method	method	NN
cord-276598-tm0yj2sn	161	5	,	,	,
cord-276598-tm0yj2sn	161	6	(	(	-LRB-
cord-276598-tm0yj2sn	161	7	Me	Me	NNP
cord-276598-tm0yj2sn	161	8	2	2	CD
cord-276598-tm0yj2sn	161	9	N	n	CD
cord-276598-tm0yj2sn	161	10	)	)	-RRB-
cord-276598-tm0yj2sn	161	11	3	3	CD
cord-276598-tm0yj2sn	161	12	PBr	PBr	NNS
cord-276598-tm0yj2sn	161	13	2	2	CD
cord-276598-tm0yj2sn	161	14	was	be	VBD
cord-276598-tm0yj2sn	161	15	prepared	prepare	VBN
cord-276598-tm0yj2sn	161	16	in	in	IN
cord-276598-tm0yj2sn	161	17	situ	situ	NNS
cord-276598-tm0yj2sn	161	18	in	in	IN
cord-276598-tm0yj2sn	161	19	a	a	DT
cord-276598-tm0yj2sn	161	20	one	one	CD
cord-276598-tm0yj2sn	161	21	-	-	HYPH
cord-276598-tm0yj2sn	161	22	pot	pot	NN
cord-276598-tm0yj2sn	161	23	two	two	CD
cord-276598-tm0yj2sn	161	24	-	-	HYPH
cord-276598-tm0yj2sn	161	25	step	step	NN
cord-276598-tm0yj2sn	161	26	synthesis	synthesis	NN
cord-276598-tm0yj2sn	161	27	of	of	IN
cord-276598-tm0yj2sn	161	28	P	p	NN
cord-276598-tm0yj2sn	161	29	-	-	HYPH
cord-276598-tm0yj2sn	161	30	Ns	Ns	NNP
cord-276598-tm0yj2sn	161	31	from	from	IN
cord-276598-tm0yj2sn	161	32	(	(	-LRB-
cord-276598-tm0yj2sn	161	33	EtO	EtO	NNP
cord-276598-tm0yj2sn	161	34	)	)	-RRB-
cord-276598-tm0yj2sn	162	1	2	2	CD
cord-276598-tm0yj2sn	162	2	P(O)OH	p(o)oh	NN
cord-276598-tm0yj2sn	162	3	and	and	CC
cord-276598-tm0yj2sn	162	4	amines	amine	NNS
cord-276598-tm0yj2sn	162	5	(	(	-LRB-
cord-276598-tm0yj2sn	162	6	Scheme	scheme	NN
cord-276598-tm0yj2sn	162	7	4	4	CD
cord-276598-tm0yj2sn	162	8	)	)	-RRB-
cord-276598-tm0yj2sn	162	9	[	[	-LRB-
cord-276598-tm0yj2sn	162	10	90	90	CD
cord-276598-tm0yj2sn	162	11	]	]	-RRB-
cord-276598-tm0yj2sn	162	12	.	.	.
cord-276598-tm0yj2sn	163	1	The	the	DT
cord-276598-tm0yj2sn	163	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	163	3	was	be	VBD
cord-276598-tm0yj2sn	163	4	explored	explore	VBN
cord-276598-tm0yj2sn	163	5	using	use	VBG
cord-276598-tm0yj2sn	163	6	various	various	JJ
cord-276598-tm0yj2sn	163	7	amines	amine	NNS
cord-276598-tm0yj2sn	163	8	such	such	JJ
cord-276598-tm0yj2sn	163	9	as	as	IN
cord-276598-tm0yj2sn	163	10	aniline	aniline	NN
cord-276598-tm0yj2sn	163	11	,	,	,
cord-276598-tm0yj2sn	163	12	phenylmethanamine	phenylmethanamine	NN
cord-276598-tm0yj2sn	163	13	,	,	,
cord-276598-tm0yj2sn	163	14	dibutylamine	dibutylamine	NNP
cord-276598-tm0yj2sn	163	15	,	,	,
cord-276598-tm0yj2sn	163	16	butan-1-amine	butan-1-amine	NNP
cord-276598-tm0yj2sn	163	17	,	,	,
cord-276598-tm0yj2sn	163	18	dipropylamine	dipropylamine	NN
cord-276598-tm0yj2sn	163	19	,	,	,
cord-276598-tm0yj2sn	163	20	and	and	CC
cord-276598-tm0yj2sn	163	21	hept-1-en-2-amine	hept-1-en-2-amine	NN
cord-276598-tm0yj2sn	163	22	.	.	.
cord-276598-tm0yj2sn	164	1	This	this	DT
cord-276598-tm0yj2sn	164	2	method	method	NN
cord-276598-tm0yj2sn	164	3	was	be	VBD
cord-276598-tm0yj2sn	164	4	favorable	favorable	JJ
cord-276598-tm0yj2sn	164	5	with	with	IN
cord-276598-tm0yj2sn	164	6	improved	improved	JJ
cord-276598-tm0yj2sn	164	7	yields	yield	NNS
cord-276598-tm0yj2sn	164	8	of	of	IN
cord-276598-tm0yj2sn	164	9	P	p	NN
cord-276598-tm0yj2sn	164	10	-	-	HYPH
cord-276598-tm0yj2sn	164	11	N	n	CD
cord-276598-tm0yj2sn	164	12	products	product	NNS
cord-276598-tm0yj2sn	164	13	(	(	-LRB-
cord-276598-tm0yj2sn	164	14	59	59	CD
cord-276598-tm0yj2sn	164	15	-	-	SYM
cord-276598-tm0yj2sn	164	16	91	91	CD
cord-276598-tm0yj2sn	164	17	%	%	NN
cord-276598-tm0yj2sn	164	18	)	)	-RRB-
cord-276598-tm0yj2sn	164	19	after	after	IN
cord-276598-tm0yj2sn	164	20	workup	workup	NN
cord-276598-tm0yj2sn	164	21	and	and	CC
cord-276598-tm0yj2sn	164	22	eliminated	eliminate	VBD
cord-276598-tm0yj2sn	164	23	the	the	DT
cord-276598-tm0yj2sn	164	24	route(s	route(s	NNP
cord-276598-tm0yj2sn	164	25	)	)	-RRB-
cord-276598-tm0yj2sn	164	26	for	for	IN
cord-276598-tm0yj2sn	164	27	anhydride	anhydride	NN
cord-276598-tm0yj2sn	164	28	formation	formation	NN
cord-276598-tm0yj2sn	164	29	.	.	.
cord-276598-tm0yj2sn	165	1	Nevertheless	nevertheless	RB
cord-276598-tm0yj2sn	165	2	,	,	,
cord-276598-tm0yj2sn	165	3	the	the	DT
cord-276598-tm0yj2sn	165	4	method	method	NN
cord-276598-tm0yj2sn	165	5	used	use	VBN
cord-276598-tm0yj2sn	165	6	potentially	potentially	RB
cord-276598-tm0yj2sn	165	7	harmful	harmful	JJ
cord-276598-tm0yj2sn	165	8	bromine	bromine	NN
cord-276598-tm0yj2sn	165	9	in	in	IN
cord-276598-tm0yj2sn	165	10	a	a	DT
cord-276598-tm0yj2sn	165	11	multi	multi	JJ
cord-276598-tm0yj2sn	165	12	-	-	JJ
cord-276598-tm0yj2sn	165	13	step	step	JJ
cord-276598-tm0yj2sn	165	14	tedious	tedious	JJ
cord-276598-tm0yj2sn	165	15	process	process	NN
cord-276598-tm0yj2sn	165	16	with	with	IN
cord-276598-tm0yj2sn	165	17	low	low	JJ
cord-276598-tm0yj2sn	165	18	atom	atom	NN
cord-276598-tm0yj2sn	165	19	economy	economy	NN
cord-276598-tm0yj2sn	165	20	.	.	.
cord-276598-tm0yj2sn	166	1	[	[	-LRB-
cord-276598-tm0yj2sn	166	2	78	78	CD
cord-276598-tm0yj2sn	166	3	]	]	-RRB-
cord-276598-tm0yj2sn	166	4	.	.	.
cord-276598-tm0yj2sn	167	1	The	the	DT
cord-276598-tm0yj2sn	167	2	scope	scope	NN
cord-276598-tm0yj2sn	167	3	of	of	IN
cord-276598-tm0yj2sn	167	4	this	this	DT
cord-276598-tm0yj2sn	167	5	method	method	NN
cord-276598-tm0yj2sn	167	6	was	be	VBD
cord-276598-tm0yj2sn	167	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	167	8	using	use	VBG
cord-276598-tm0yj2sn	167	9	different	different	JJ
cord-276598-tm0yj2sn	167	10	amines	amine	NNS
cord-276598-tm0yj2sn	167	11	(	(	-LRB-
cord-276598-tm0yj2sn	167	12	e.g.	e.g.	RB
cord-276598-tm0yj2sn	167	13	,	,	,
cord-276598-tm0yj2sn	167	14	morpholine	morpholine	NNP
cord-276598-tm0yj2sn	167	15	,	,	,
cord-276598-tm0yj2sn	167	16	cyclohexylamine	cyclohexylamine	NNP
cord-276598-tm0yj2sn	167	17	,	,	,
cord-276598-tm0yj2sn	167	18	1-phenylethan-1-amine	1-phenylethan-1-amine	CD
cord-276598-tm0yj2sn	167	19	and	and	CC
cord-276598-tm0yj2sn	167	20	benzylamine	benzylamine	NN
cord-276598-tm0yj2sn	167	21	,	,	,
cord-276598-tm0yj2sn	167	22	4-methylmorpholine	4-methylmorpholine	CD
cord-276598-tm0yj2sn	167	23	)	)	-RRB-
cord-276598-tm0yj2sn	167	24	or	or	CC
cord-276598-tm0yj2sn	167	25	a	a	DT
cord-276598-tm0yj2sn	167	26	mixture	mixture	NN
cord-276598-tm0yj2sn	167	27	of	of	IN
cord-276598-tm0yj2sn	167	28	aniline	aniline	NN
cord-276598-tm0yj2sn	167	29	and	and	CC
cord-276598-tm0yj2sn	167	30	N	N	NNP
cord-276598-tm0yj2sn	167	31	,	,	,
cord-276598-tm0yj2sn	167	32	N	N	NNP
cord-276598-tm0yj2sn	167	33	-	-	HYPH
cord-276598-tm0yj2sn	167	34	dimethylcyclohexanamine	dimethylcyclohexanamine	NNP
cord-276598-tm0yj2sn	167	35	,	,	,
cord-276598-tm0yj2sn	167	36	as	as	RB
cord-276598-tm0yj2sn	167	37	well	well	RB
cord-276598-tm0yj2sn	167	38	as	as	IN
cord-276598-tm0yj2sn	167	39	different	different	JJ
cord-276598-tm0yj2sn	167	40	solvents	solvent	NNS
cord-276598-tm0yj2sn	167	41	(	(	-LRB-
cord-276598-tm0yj2sn	167	42	e.g.	e.g.	RB
cord-276598-tm0yj2sn	167	43	,	,	,
cord-276598-tm0yj2sn	167	44	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	167	45	,	,	,
cord-276598-tm0yj2sn	167	46	Cl3CCCl3	Cl3CCCl3	NNP
cord-276598-tm0yj2sn	167	47	,	,	,
cord-276598-tm0yj2sn	167	48	and	and	CC
cord-276598-tm0yj2sn	167	49	HCl2CCCl3	HCl2CCCl3	NNP
cord-276598-tm0yj2sn	167	50	)	)	-RRB-
cord-276598-tm0yj2sn	167	51	.	.	.
cord-276598-tm0yj2sn	168	1	Isolated	isolated	JJ
cord-276598-tm0yj2sn	168	2	yields	yield	NNS
cord-276598-tm0yj2sn	168	3	of	of	IN
cord-276598-tm0yj2sn	168	4	62	62	CD
cord-276598-tm0yj2sn	168	5	-	-	SYM
cord-276598-tm0yj2sn	168	6	92	92	CD
cord-276598-tm0yj2sn	168	7	%	%	NN
cord-276598-tm0yj2sn	168	8	were	be	VBD
cord-276598-tm0yj2sn	168	9	obtained	obtain	VBN
cord-276598-tm0yj2sn	168	10	.	.	.
cord-276598-tm0yj2sn	169	1	The	the	DT
cord-276598-tm0yj2sn	169	2	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	169	3	-	-	HYPH
cord-276598-tm0yj2sn	169	4	Todd	Todd	NNP
cord-276598-tm0yj2sn	169	5	method	method	NN
cord-276598-tm0yj2sn	169	6	was	be	VBD
cord-276598-tm0yj2sn	169	7	prominent	prominent	JJ
cord-276598-tm0yj2sn	169	8	for	for	IN
cord-276598-tm0yj2sn	169	9	its	-PRON-	PRP$
cord-276598-tm0yj2sn	169	10	in	in	IN
cord-276598-tm0yj2sn	169	11	situ	situ	JJ
cord-276598-tm0yj2sn	169	12	generation	generation	NN
cord-276598-tm0yj2sn	169	13	of	of	IN
cord-276598-tm0yj2sn	169	14	(	(	-LRB-
cord-276598-tm0yj2sn	170	1	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	170	2	(	(	-LRB-
cord-276598-tm0yj2sn	170	3	dACP	dacp	NN
cord-276598-tm0yj2sn	170	4	;	;	:
cord-276598-tm0yj2sn	170	5	R	r	NN
cord-276598-tm0yj2sn	170	6	=	=	NN
cord-276598-tm0yj2sn	170	7	alkyl	alkyl	NN
cord-276598-tm0yj2sn	170	8	,	,	,
cord-276598-tm0yj2sn	170	9	benzyl	benzyl	NN
cord-276598-tm0yj2sn	170	10	)	)	-RRB-
cord-276598-tm0yj2sn	170	11	,	,	,
cord-276598-tm0yj2sn	170	12	which	which	WDT
cord-276598-tm0yj2sn	170	13	eliminates	eliminate	VBZ
cord-276598-tm0yj2sn	170	14	the	the	DT
cord-276598-tm0yj2sn	170	15	use	use	NN
cord-276598-tm0yj2sn	170	16	of	of	IN
cord-276598-tm0yj2sn	170	17	moisture	moisture	NN
cord-276598-tm0yj2sn	170	18	-	-	HYPH
cord-276598-tm0yj2sn	170	19	and	and	CC
cord-276598-tm0yj2sn	170	20	air	air	NN
cord-276598-tm0yj2sn	170	21	-	-	HYPH
cord-276598-tm0yj2sn	170	22	sensitive	sensitive	JJ
cord-276598-tm0yj2sn	170	23	dACP	dacp	NN
cord-276598-tm0yj2sn	170	24	.	.	.
cord-276598-tm0yj2sn	171	1	However	however	RB
cord-276598-tm0yj2sn	171	2	,	,	,
cord-276598-tm0yj2sn	171	3	the	the	DT
cord-276598-tm0yj2sn	171	4	major	major	JJ
cord-276598-tm0yj2sn	171	5	drawbacks	drawback	NNS
cord-276598-tm0yj2sn	171	6	of	of	IN
cord-276598-tm0yj2sn	171	7	the	the	DT
cord-276598-tm0yj2sn	171	8	method	method	NN
cord-276598-tm0yj2sn	171	9	include	include	VBP
cord-276598-tm0yj2sn	171	10	the	the	DT
cord-276598-tm0yj2sn	171	11	use	use	NN
cord-276598-tm0yj2sn	171	12	of	of	IN
cord-276598-tm0yj2sn	171	13	halogen	halogen	NN
cord-276598-tm0yj2sn	171	14	sources	source	NNS
cord-276598-tm0yj2sn	171	15	such	such	JJ
cord-276598-tm0yj2sn	171	16	as	as	IN
cord-276598-tm0yj2sn	171	17	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	171	18	,	,	,
cord-276598-tm0yj2sn	171	19	Cl3CCCl3	Cl3CCCl3	NNP
cord-276598-tm0yj2sn	171	20	,	,	,
cord-276598-tm0yj2sn	171	21	and	and	CC
cord-276598-tm0yj2sn	171	22	HCl2CCCl3	HCl2CCCl3	NNP
cord-276598-tm0yj2sn	171	23	and	and	CC
cord-276598-tm0yj2sn	171	24	extensive	extensive	JJ
cord-276598-tm0yj2sn	171	25	work	work	NN
cord-276598-tm0yj2sn	171	26	-	-	HYPH
cord-276598-tm0yj2sn	171	27	up	up	NN
cord-276598-tm0yj2sn	171	28	/	/	SYM
cord-276598-tm0yj2sn	171	29	purification	purification	NN
cord-276598-tm0yj2sn	171	30	of	of	IN
cord-276598-tm0yj2sn	171	31	the	the	DT
cord-276598-tm0yj2sn	171	32	products	product	NNS
cord-276598-tm0yj2sn	171	33	.	.	.
cord-276598-tm0yj2sn	172	1	In	in	IN
cord-276598-tm0yj2sn	172	2	2020	2020	CD
cord-276598-tm0yj2sn	172	3	,	,	,
cord-276598-tm0yj2sn	172	4	Chen	Chen	NNP
cord-276598-tm0yj2sn	172	5	et	et	NNP
cord-276598-tm0yj2sn	172	6	al	al	NNP
cord-276598-tm0yj2sn	172	7	.	.	NNP
cord-276598-tm0yj2sn	172	8	reported	report	VBD
cord-276598-tm0yj2sn	172	9	a	a	DT
cord-276598-tm0yj2sn	172	10	modified	modify	VBN
cord-276598-tm0yj2sn	172	11	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	172	12	-	-	HYPH
cord-276598-tm0yj2sn	172	13	Todd	Todd	NNP
cord-276598-tm0yj2sn	172	14	reaction	reaction	NN
cord-276598-tm0yj2sn	172	15	for	for	IN
cord-276598-tm0yj2sn	172	16	the	the	DT
cord-276598-tm0yj2sn	172	17	synthesis	synthesis	NN
cord-276598-tm0yj2sn	172	18	of	of	IN
cord-276598-tm0yj2sn	172	19	P	P	NNP
cord-276598-tm0yj2sn	172	20	-	-	HYPH
cord-276598-tm0yj2sn	172	21	Ns	Ns	NNP
cord-276598-tm0yj2sn	172	22	using	use	VBG
cord-276598-tm0yj2sn	172	23	air	air	NN
cord-276598-tm0yj2sn	172	24	as	as	IN
cord-276598-tm0yj2sn	172	25	a	a	DT
cord-276598-tm0yj2sn	172	26	radical	radical	JJ
cord-276598-tm0yj2sn	172	27	initiator	initiator	NN
cord-276598-tm0yj2sn	172	28	(	(	-LRB-
cord-276598-tm0yj2sn	172	29	Scheme	scheme	NN
cord-276598-tm0yj2sn	172	30	3	3	CD
cord-276598-tm0yj2sn	172	31	)	)	-RRB-
cord-276598-tm0yj2sn	172	32	[	[	-LRB-
cord-276598-tm0yj2sn	172	33	95	95	CD
cord-276598-tm0yj2sn	172	34	]	]	-RRB-
cord-276598-tm0yj2sn	172	35	.	.	.
cord-276598-tm0yj2sn	173	1	The	the	DT
cord-276598-tm0yj2sn	173	2	modified	modify	VBN
cord-276598-tm0yj2sn	173	3	method	method	NN
cord-276598-tm0yj2sn	173	4	explored	explore	VBN
cord-276598-tm0yj2sn	173	5	P	P	NNP
cord-276598-tm0yj2sn	173	6	-	-	HYPH
cord-276598-tm0yj2sn	173	7	N	n	CD
cord-276598-tm0yj2sn	173	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	173	9	using	use	VBG
cord-276598-tm0yj2sn	173	10	(	(	-LRB-
cord-276598-tm0yj2sn	173	11	H	h	NN
cord-276598-tm0yj2sn	173	12	-	-	HYPH
cord-276598-tm0yj2sn	173	13	P	p	NN
cord-276598-tm0yj2sn	173	14	)	)	-RRB-
cord-276598-tm0yj2sn	173	15	(	(	-LRB-
cord-276598-tm0yj2sn	173	16	(	(	-LRB-
cord-276598-tm0yj2sn	173	17	RO)2P(O)H	ro)2p(o)h	NN
cord-276598-tm0yj2sn	173	18	;	;	.
cord-276598-tm0yj2sn	174	1	R	r	NN
cord-276598-tm0yj2sn	174	2	=	=	FW
cord-276598-tm0yj2sn	174	3	Et	Et	NNP
cord-276598-tm0yj2sn	174	4	,	,	,
cord-276598-tm0yj2sn	174	5	i	i	NN
cord-276598-tm0yj2sn	174	6	-	-	HYPH
cord-276598-tm0yj2sn	174	7	Pr	Pr	NNP
cord-276598-tm0yj2sn	174	8	,	,	,
cord-276598-tm0yj2sn	174	9	Bu	Bu	NNP
cord-276598-tm0yj2sn	174	10	,	,	,
cord-276598-tm0yj2sn	174	11	i	i	PRP
cord-276598-tm0yj2sn	174	12	-	-	HYPH
cord-276598-tm0yj2sn	174	13	Bu	Bu	NNP
cord-276598-tm0yj2sn	174	14	)	)	-RRB-
cord-276598-tm0yj2sn	174	15	and	and	CC
cord-276598-tm0yj2sn	174	16	benzylamine	benzylamine	JJ
cord-276598-tm0yj2sn	174	17	with	with	IN
cord-276598-tm0yj2sn	174	18	yields	yield	NNS
cord-276598-tm0yj2sn	174	19	in	in	IN
cord-276598-tm0yj2sn	174	20	the	the	DT
cord-276598-tm0yj2sn	174	21	range	range	NN
cord-276598-tm0yj2sn	174	22	of	of	IN
cord-276598-tm0yj2sn	174	23	30	30	CD
cord-276598-tm0yj2sn	174	24	-	-	SYM
cord-276598-tm0yj2sn	174	25	75	75	CD
cord-276598-tm0yj2sn	174	26	%	%	NN
cord-276598-tm0yj2sn	174	27	.	.	.
cord-276598-tm0yj2sn	175	1	Although	although	IN
cord-276598-tm0yj2sn	175	2	this	this	DT
cord-276598-tm0yj2sn	175	3	method	method	NN
cord-276598-tm0yj2sn	175	4	offered	offer	VBD
cord-276598-tm0yj2sn	175	5	advantages	advantage	NNS
cord-276598-tm0yj2sn	175	6	such	such	JJ
cord-276598-tm0yj2sn	175	7	as	as	IN
cord-276598-tm0yj2sn	175	8	using	use	VBG
cord-276598-tm0yj2sn	175	9	air	air	NN
cord-276598-tm0yj2sn	175	10	as	as	IN
cord-276598-tm0yj2sn	175	11	a	a	DT
cord-276598-tm0yj2sn	175	12	radical	radical	JJ
cord-276598-tm0yj2sn	175	13	initiator	initiator	NN
cord-276598-tm0yj2sn	175	14	at	at	IN
cord-276598-tm0yj2sn	175	15	room	room	NN
cord-276598-tm0yj2sn	175	16	temperature	temperature	NN
cord-276598-tm0yj2sn	175	17	,	,	,
cord-276598-tm0yj2sn	175	18	the	the	DT
cord-276598-tm0yj2sn	175	19	use	use	NN
cord-276598-tm0yj2sn	175	20	of	of	IN
cord-276598-tm0yj2sn	175	21	relatively	relatively	RB
cord-276598-tm0yj2sn	175	22	expensive	expensive	JJ
cord-276598-tm0yj2sn	175	23	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	CD
cord-276598-tm0yj2sn	175	24	(	(	-LRB-
cord-276598-tm0yj2sn	175	25	DBU	DBU	NNP
cord-276598-tm0yj2sn	175	26	)	)	-RRB-
cord-276598-tm0yj2sn	175	27	as	as	IN
cord-276598-tm0yj2sn	175	28	a	a	DT
cord-276598-tm0yj2sn	175	29	base	base	NN
cord-276598-tm0yj2sn	175	30	in	in	IN
cord-276598-tm0yj2sn	175	31	the	the	DT
cord-276598-tm0yj2sn	175	32	process	process	NN
cord-276598-tm0yj2sn	175	33	,	,	,
cord-276598-tm0yj2sn	175	34	the	the	DT
cord-276598-tm0yj2sn	175	35	elimination	elimination	NN
cord-276598-tm0yj2sn	175	36	of	of	IN
cord-276598-tm0yj2sn	175	37	large	large	JJ
cord-276598-tm0yj2sn	175	38	amounts	amount	NNS
cord-276598-tm0yj2sn	175	39	of	of	IN
cord-276598-tm0yj2sn	175	40	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	175	41	waste	waste	NN
cord-276598-tm0yj2sn	175	42	,	,	,
cord-276598-tm0yj2sn	175	43	and	and	CC
cord-276598-tm0yj2sn	175	44	comparatively	comparatively	RB
cord-276598-tm0yj2sn	175	45	lower	low	JJR
cord-276598-tm0yj2sn	175	46	yields	yield	NNS
cord-276598-tm0yj2sn	175	47	of	of	IN
cord-276598-tm0yj2sn	175	48	products	product	NNS
cord-276598-tm0yj2sn	175	49	are	be	VBP
cord-276598-tm0yj2sn	175	50	some	some	DT
cord-276598-tm0yj2sn	175	51	of	of	IN
cord-276598-tm0yj2sn	175	52	the	the	DT
cord-276598-tm0yj2sn	175	53	limitations	limitation	NNS
cord-276598-tm0yj2sn	175	54	.	.	.
cord-276598-tm0yj2sn	175	55	 	 	_SP
cord-276598-tm0yj2sn	176	1	With	with	IN
cord-276598-tm0yj2sn	176	2	reference	reference	NN
cord-276598-tm0yj2sn	176	3	to	to	IN
cord-276598-tm0yj2sn	176	4	the	the	DT
cord-276598-tm0yj2sn	176	5	limitations	limitation	NNS
cord-276598-tm0yj2sn	176	6	(	(	-LRB-
cord-276598-tm0yj2sn	176	7	such	such	JJ
cord-276598-tm0yj2sn	176	8	as	as	IN
cord-276598-tm0yj2sn	176	9	low	low	JJ
cord-276598-tm0yj2sn	176	10	yield	yield	NN
cord-276598-tm0yj2sn	176	11	and	and	CC
cord-276598-tm0yj2sn	176	12	the	the	DT
cord-276598-tm0yj2sn	176	13	formation	formation	NN
cord-276598-tm0yj2sn	176	14	of	of	IN
cord-276598-tm0yj2sn	176	15	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	176	16	anhydrides	anhydride	NNS
cord-276598-tm0yj2sn	176	17	side	side	NN
cord-276598-tm0yj2sn	176	18	products	product	NNS
cord-276598-tm0yj2sn	176	19	)	)	-RRB-
cord-276598-tm0yj2sn	176	20	in	in	IN
cord-276598-tm0yj2sn	176	21	the	the	DT
cord-276598-tm0yj2sn	176	22	method	method	NN
cord-276598-tm0yj2sn	176	23	reported	report	VBN
cord-276598-tm0yj2sn	176	24	by	by	IN
cord-276598-tm0yj2sn	176	25	Appel	Appel	NNP
cord-276598-tm0yj2sn	176	26	and	and	CC
cord-276598-tm0yj2sn	176	27	Einig	Einig	NNP
cord-276598-tm0yj2sn	176	28	[	[	-LRB-
cord-276598-tm0yj2sn	176	29	86	86	CD
cord-276598-tm0yj2sn	176	30	]	]	-RRB-
cord-276598-tm0yj2sn	176	31	,	,	,
cord-276598-tm0yj2sn	176	32	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	176	33	and	and	CC
cord-276598-tm0yj2sn	176	34	Osowska	Osowska	NNP
cord-276598-tm0yj2sn	176	35	-	-	HYPH
cord-276598-tm0yj2sn	176	36	Pacewicka	Pacewicka	NNP
cord-276598-tm0yj2sn	176	37	[	[	-LRB-
cord-276598-tm0yj2sn	176	38	90	90	CD
cord-276598-tm0yj2sn	176	39	]	]	-RRB-
cord-276598-tm0yj2sn	176	40	proposed	propose	VBD
cord-276598-tm0yj2sn	176	41	an	an	DT
cord-276598-tm0yj2sn	176	42	alternative	alternative	JJ
cord-276598-tm0yj2sn	176	43	method	method	NN
cord-276598-tm0yj2sn	176	44	that	that	WDT
cord-276598-tm0yj2sn	176	45	uses	use	VBZ
cord-276598-tm0yj2sn	176	46	−OH	−oh	CD
cord-276598-tm0yj2sn	176	47	group	group	NN
cord-276598-tm0yj2sn	176	48	activator	activator	NN
cord-276598-tm0yj2sn	176	49	,	,	,
cord-276598-tm0yj2sn	176	50	hexamethyltriaminodibromophosphorane	hexamethyltriaminodibromophosphorane	NNP
cord-276598-tm0yj2sn	176	51	(	(	-LRB-
cord-276598-tm0yj2sn	176	52	(	(	-LRB-
cord-276598-tm0yj2sn	176	53	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	176	54	)	)	-RRB-
cord-276598-tm0yj2sn	176	55	.	.	.
cord-276598-tm0yj2sn	177	1	In	in	IN
cord-276598-tm0yj2sn	177	2	the	the	DT
cord-276598-tm0yj2sn	177	3	reported	report	VBN
cord-276598-tm0yj2sn	177	4	method	method	NN
cord-276598-tm0yj2sn	177	5	,	,	,
cord-276598-tm0yj2sn	177	6	(	(	-LRB-
cord-276598-tm0yj2sn	177	7	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	177	8	was	be	VBD
cord-276598-tm0yj2sn	177	9	prepared	prepare	VBN
cord-276598-tm0yj2sn	177	10	in	in	IN
cord-276598-tm0yj2sn	177	11	situ	situ	NNS
cord-276598-tm0yj2sn	177	12	in	in	IN
cord-276598-tm0yj2sn	177	13	a	a	DT
cord-276598-tm0yj2sn	177	14	one	one	CD
cord-276598-tm0yj2sn	177	15	-	-	HYPH
cord-276598-tm0yj2sn	177	16	pot	pot	NN
cord-276598-tm0yj2sn	177	17	two	two	CD
cord-276598-tm0yj2sn	177	18	-	-	HYPH
cord-276598-tm0yj2sn	177	19	step	step	NN
cord-276598-tm0yj2sn	177	20	synthesis	synthesis	NN
cord-276598-tm0yj2sn	177	21	of	of	IN
cord-276598-tm0yj2sn	177	22	P	p	NN
cord-276598-tm0yj2sn	177	23	-	-	HYPH
cord-276598-tm0yj2sn	177	24	Ns	Ns	NNP
cord-276598-tm0yj2sn	177	25	from	from	IN
cord-276598-tm0yj2sn	177	26	(	(	-LRB-
cord-276598-tm0yj2sn	177	27	EtO)2P(O)OH	eto)2p(o)oh	NN
cord-276598-tm0yj2sn	177	28	and	and	CC
cord-276598-tm0yj2sn	177	29	amines	amine	NNS
cord-276598-tm0yj2sn	177	30	(	(	-LRB-
cord-276598-tm0yj2sn	177	31	Scheme	scheme	NN
cord-276598-tm0yj2sn	177	32	4	4	CD
cord-276598-tm0yj2sn	177	33	)	)	-RRB-
cord-276598-tm0yj2sn	177	34	[	[	-LRB-
cord-276598-tm0yj2sn	177	35	90	90	CD
cord-276598-tm0yj2sn	177	36	]	]	-RRB-
cord-276598-tm0yj2sn	177	37	.	.	.
cord-276598-tm0yj2sn	178	1	The	the	DT
cord-276598-tm0yj2sn	178	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	178	3	was	be	VBD
cord-276598-tm0yj2sn	178	4	explored	explore	VBN
cord-276598-tm0yj2sn	178	5	using	use	VBG
cord-276598-tm0yj2sn	178	6	various	various	JJ
cord-276598-tm0yj2sn	178	7	amines	amine	NNS
cord-276598-tm0yj2sn	178	8	such	such	JJ
cord-276598-tm0yj2sn	178	9	as	as	IN
cord-276598-tm0yj2sn	178	10	aniline	aniline	NN
cord-276598-tm0yj2sn	178	11	,	,	,
cord-276598-tm0yj2sn	178	12	phenylmethanamine	phenylmethanamine	NN
cord-276598-tm0yj2sn	178	13	,	,	,
cord-276598-tm0yj2sn	178	14	dibutylamine	dibutylamine	NNP
cord-276598-tm0yj2sn	178	15	,	,	,
cord-276598-tm0yj2sn	178	16	butan-1-amine	butan-1-amine	NNP
cord-276598-tm0yj2sn	178	17	,	,	,
cord-276598-tm0yj2sn	178	18	dipropylamine	dipropylamine	NN
cord-276598-tm0yj2sn	178	19	,	,	,
cord-276598-tm0yj2sn	178	20	and	and	CC
cord-276598-tm0yj2sn	178	21	hept-1-en-2-amine	hept-1-en-2-amine	NN
cord-276598-tm0yj2sn	178	22	.	.	.
cord-276598-tm0yj2sn	179	1	This	this	DT
cord-276598-tm0yj2sn	179	2	method	method	NN
cord-276598-tm0yj2sn	179	3	was	be	VBD
cord-276598-tm0yj2sn	179	4	favorable	favorable	JJ
cord-276598-tm0yj2sn	179	5	with	with	IN
cord-276598-tm0yj2sn	179	6	improved	improved	JJ
cord-276598-tm0yj2sn	179	7	yields	yield	NNS
cord-276598-tm0yj2sn	179	8	of	of	IN
cord-276598-tm0yj2sn	179	9	P	p	NN
cord-276598-tm0yj2sn	179	10	-	-	HYPH
cord-276598-tm0yj2sn	179	11	N	n	CD
cord-276598-tm0yj2sn	179	12	products	product	NNS
cord-276598-tm0yj2sn	179	13	(	(	-LRB-
cord-276598-tm0yj2sn	179	14	59	59	CD
cord-276598-tm0yj2sn	179	15	-	-	SYM
cord-276598-tm0yj2sn	179	16	91	91	CD
cord-276598-tm0yj2sn	179	17	%	%	NN
cord-276598-tm0yj2sn	179	18	)	)	-RRB-
cord-276598-tm0yj2sn	179	19	after	after	IN
cord-276598-tm0yj2sn	179	20	workup	workup	NN
cord-276598-tm0yj2sn	179	21	and	and	CC
cord-276598-tm0yj2sn	179	22	eliminated	eliminate	VBD
cord-276598-tm0yj2sn	179	23	the	the	DT
cord-276598-tm0yj2sn	179	24	route(s	route(s	NNP
cord-276598-tm0yj2sn	179	25	)	)	-RRB-
cord-276598-tm0yj2sn	179	26	for	for	IN
cord-276598-tm0yj2sn	179	27	anhydride	anhydride	NN
cord-276598-tm0yj2sn	179	28	formation	formation	NN
cord-276598-tm0yj2sn	179	29	.	.	.
cord-276598-tm0yj2sn	180	1	Nevertheless	nevertheless	RB
cord-276598-tm0yj2sn	180	2	,	,	,
cord-276598-tm0yj2sn	180	3	the	the	DT
cord-276598-tm0yj2sn	180	4	method	method	NN
cord-276598-tm0yj2sn	180	5	used	use	VBN
cord-276598-tm0yj2sn	180	6	potentially	potentially	RB
cord-276598-tm0yj2sn	180	7	harmful	harmful	JJ
cord-276598-tm0yj2sn	180	8	bromine	bromine	NN
cord-276598-tm0yj2sn	180	9	in	in	IN
cord-276598-tm0yj2sn	180	10	a	a	DT
cord-276598-tm0yj2sn	180	11	multi	multi	JJ
cord-276598-tm0yj2sn	180	12	-	-	JJ
cord-276598-tm0yj2sn	180	13	step	step	JJ
cord-276598-tm0yj2sn	180	14	tedious	tedious	JJ
cord-276598-tm0yj2sn	180	15	process	process	NN
cord-276598-tm0yj2sn	180	16	with	with	IN
cord-276598-tm0yj2sn	180	17	low	low	JJ
cord-276598-tm0yj2sn	180	18	atom	atom	NN
cord-276598-tm0yj2sn	180	19	economy	economy	NN
cord-276598-tm0yj2sn	180	20	.	.	.
cord-276598-tm0yj2sn	181	1	In	in	IN
cord-276598-tm0yj2sn	181	2	another	another	DT
cord-276598-tm0yj2sn	181	3	salt	salt	NN
cord-276598-tm0yj2sn	181	4	elimination	elimination	NN
cord-276598-tm0yj2sn	181	5	route	route	NN
cord-276598-tm0yj2sn	181	6	,	,	,
cord-276598-tm0yj2sn	181	7	this	this	DT
cord-276598-tm0yj2sn	181	8	time	time	NN
cord-276598-tm0yj2sn	181	9	using	use	VBG
cord-276598-tm0yj2sn	181	10	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	181	11	bases	basis	NNS
cord-276598-tm0yj2sn	181	12	and	and	CC
cord-276598-tm0yj2sn	181	13	[	[	-LRB-
cord-276598-tm0yj2sn	181	14	n	n	NNP
cord-276598-tm0yj2sn	181	15	-	-	HYPH
cord-276598-tm0yj2sn	181	16	Bu	Bu	NNP
cord-276598-tm0yj2sn	181	17	4	4	CD
cord-276598-tm0yj2sn	181	18	N]Br	N]Br	NNP
cord-276598-tm0yj2sn	181	19	as	as	IN
cord-276598-tm0yj2sn	181	20	a	a	DT
cord-276598-tm0yj2sn	181	21	catalyst	catalyst	NN
cord-276598-tm0yj2sn	181	22	,	,	,
cord-276598-tm0yj2sn	181	23	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	181	24	and	and	CC
cord-276598-tm0yj2sn	181	25	Osowska	Osowska	NNP
cord-276598-tm0yj2sn	181	26	-	-	HYPH
cord-276598-tm0yj2sn	181	27	Pacewicka	Pacewicka	NNP
cord-276598-tm0yj2sn	181	28	synthesized	synthesize	VBD
cord-276598-tm0yj2sn	181	29	P	P	NNP
cord-276598-tm0yj2sn	181	30	-	-	HYPH
cord-276598-tm0yj2sn	181	31	Ns	Ns	NNP
cord-276598-tm0yj2sn	181	32	from	from	IN
cord-276598-tm0yj2sn	181	33	(	(	-LRB-
cord-276598-tm0yj2sn	181	34	EtO	EtO	NNP
cord-276598-tm0yj2sn	181	35	)	)	-RRB-
cord-276598-tm0yj2sn	181	36	2	2	CD
cord-276598-tm0yj2sn	181	37	P(O)H	P(O)H	NNP
cord-276598-tm0yj2sn	181	38	(	(	-LRB-
cord-276598-tm0yj2sn	181	39	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	181	40	H	H	NNP
cord-276598-tm0yj2sn	181	41	-	-	HYPH
cord-276598-tm0yj2sn	181	42	P	P	NNP
cord-276598-tm0yj2sn	181	43	)	)	-RRB-
cord-276598-tm0yj2sn	181	44	and	and	CC
cord-276598-tm0yj2sn	181	45	various	various	JJ
cord-276598-tm0yj2sn	181	46	amines	amine	NNS
cord-276598-tm0yj2sn	181	47	(	(	-LRB-
cord-276598-tm0yj2sn	181	48	Scheme	scheme	NN
cord-276598-tm0yj2sn	181	49	5a	5a	CD
cord-276598-tm0yj2sn	181	50	)	)	-RRB-
cord-276598-tm0yj2sn	182	1	[	[	-LRB-
cord-276598-tm0yj2sn	182	2	89	89	CD
cord-276598-tm0yj2sn	182	3	]	]	-RRB-
cord-276598-tm0yj2sn	182	4	.	.	.
cord-276598-tm0yj2sn	183	1	Aromatic	aromatic	JJ
cord-276598-tm0yj2sn	183	2	amines	amine	NNS
cord-276598-tm0yj2sn	183	3	such	such	JJ
cord-276598-tm0yj2sn	183	4	as	as	IN
cord-276598-tm0yj2sn	183	5	aniline	aniline	NN
cord-276598-tm0yj2sn	183	6	and	and	CC
cord-276598-tm0yj2sn	183	7	4-chloroaniline	4-chloroaniline	CD
cord-276598-tm0yj2sn	183	8	,	,	,
cord-276598-tm0yj2sn	183	9	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	183	10	amines	amine	NNS
cord-276598-tm0yj2sn	183	11	such	such	JJ
cord-276598-tm0yj2sn	183	12	as	as	IN
cord-276598-tm0yj2sn	183	13	cyclohexylamine	cyclohexylamine	NNP
cord-276598-tm0yj2sn	183	14	,	,	,
cord-276598-tm0yj2sn	183	15	n	n	JJ
cord-276598-tm0yj2sn	183	16	-	-	HYPH
cord-276598-tm0yj2sn	183	17	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	183	18	,	,	,
cord-276598-tm0yj2sn	183	19	and	and	CC
cord-276598-tm0yj2sn	183	20	ethanamine	ethanamine	NN
cord-276598-tm0yj2sn	183	21	,	,	,
cord-276598-tm0yj2sn	183	22	and	and	CC
cord-276598-tm0yj2sn	183	23	alkanolamines	alkanolamine	NNS
cord-276598-tm0yj2sn	183	24	such	such	JJ
cord-276598-tm0yj2sn	183	25	as	as	IN
cord-276598-tm0yj2sn	183	26	2-aminoethan-1-ol	2-aminoethan-1-ol	CD
cord-276598-tm0yj2sn	183	27	,	,	,
cord-276598-tm0yj2sn	183	28	3-aminopropan-1-ol	3-aminopropan-1-ol	CD
cord-276598-tm0yj2sn	183	29	,	,	,
cord-276598-tm0yj2sn	183	30	and	and	CC
cord-276598-tm0yj2sn	184	1	bis(2-(-ethoxy)ethyl)amine	bis(2-(-ethoxy)ethyl)amine	NNP
cord-276598-tm0yj2sn	184	2	were	be	VBD
cord-276598-tm0yj2sn	184	3	explored	explore	VBN
cord-276598-tm0yj2sn	184	4	to	to	TO
cord-276598-tm0yj2sn	184	5	demonstrate	demonstrate	VB
cord-276598-tm0yj2sn	184	6	the	the	DT
cord-276598-tm0yj2sn	184	7	broad	broad	JJ
cord-276598-tm0yj2sn	184	8	scope	scope	NN
cord-276598-tm0yj2sn	184	9	of	of	IN
cord-276598-tm0yj2sn	184	10	this	this	DT
cord-276598-tm0yj2sn	184	11	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	184	12	transformation	transformation	NN
cord-276598-tm0yj2sn	184	13	.	.	.
cord-276598-tm0yj2sn	185	1	The	the	DT
cord-276598-tm0yj2sn	185	2	P	P	NNP
cord-276598-tm0yj2sn	185	3	-	-	HYPH
cord-276598-tm0yj2sn	185	4	Ns	Ns	NNP
cord-276598-tm0yj2sn	185	5	were	be	VBD
cord-276598-tm0yj2sn	185	6	isolated	isolate	VBN
cord-276598-tm0yj2sn	185	7	in	in	IN
cord-276598-tm0yj2sn	185	8	83	83	CD
cord-276598-tm0yj2sn	185	9	-	-	SYM
cord-276598-tm0yj2sn	185	10	100	100	CD
cord-276598-tm0yj2sn	185	11	%	%	NN
cord-276598-tm0yj2sn	185	12	yield	yield	NN
cord-276598-tm0yj2sn	185	13	after	after	IN
cord-276598-tm0yj2sn	185	14	recrystallization	recrystallization	NN
cord-276598-tm0yj2sn	185	15	.	.	.
cord-276598-tm0yj2sn	186	1	In	in	IN
cord-276598-tm0yj2sn	186	2	a	a	DT
cord-276598-tm0yj2sn	186	3	similar	similar	JJ
cord-276598-tm0yj2sn	186	4	synthesis	synthesis	NN
cord-276598-tm0yj2sn	186	5	,	,	,
cord-276598-tm0yj2sn	186	6	using	use	VBG
cord-276598-tm0yj2sn	186	7	[	[	-LRB-
cord-276598-tm0yj2sn	186	8	BnEt	BnEt	NNP
cord-276598-tm0yj2sn	186	9	3	3	CD
cord-276598-tm0yj2sn	186	10	N]Cl	N]Cl	NNP
cord-276598-tm0yj2sn	186	11	as	as	IN
cord-276598-tm0yj2sn	186	12	the	the	DT
cord-276598-tm0yj2sn	186	13	catalyst	catalyst	NN
cord-276598-tm0yj2sn	186	14	instead	instead	RB
cord-276598-tm0yj2sn	186	15	of	of	IN
cord-276598-tm0yj2sn	186	16	[	[	-LRB-
cord-276598-tm0yj2sn	186	17	n	n	NNP
cord-276598-tm0yj2sn	186	18	-	-	HYPH
cord-276598-tm0yj2sn	186	19	Bu	Bu	NNP
cord-276598-tm0yj2sn	186	20	4	4	CD
cord-276598-tm0yj2sn	186	21	N]Br	N]Br	NNP
cord-276598-tm0yj2sn	186	22	,	,	,
cord-276598-tm0yj2sn	186	23	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	186	24	accomplished	accomplish	VBD
cord-276598-tm0yj2sn	186	25	the	the	DT
cord-276598-tm0yj2sn	186	26	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	186	27	of	of	IN
cord-276598-tm0yj2sn	186	28	amines	amine	NNS
cord-276598-tm0yj2sn	186	29	using	use	VBG
cord-276598-tm0yj2sn	186	30	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	186	31	H	H	NNP
cord-276598-tm0yj2sn	186	32	-	-	HYPH
cord-276598-tm0yj2sn	186	33	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	187	1	(	(	-LRB-
cord-276598-tm0yj2sn	187	2	RO	RO	NNP
cord-276598-tm0yj2sn	187	3	)	)	-RRB-
cord-276598-tm0yj2sn	187	4	2	2	CD
cord-276598-tm0yj2sn	187	5	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	188	1	(	(	-LRB-
cord-276598-tm0yj2sn	188	2	R	r	NN
cord-276598-tm0yj2sn	188	3	=	=	FW
cord-276598-tm0yj2sn	188	4	Et	Et	NNP
cord-276598-tm0yj2sn	188	5	,	,	,
cord-276598-tm0yj2sn	188	6	Bn	Bn	NNP
cord-276598-tm0yj2sn	188	7	,	,	,
cord-276598-tm0yj2sn	188	8	t	t	NN
cord-276598-tm0yj2sn	188	9	-	-	HYPH
cord-276598-tm0yj2sn	188	10	Bu	Bu	NNP
cord-276598-tm0yj2sn	188	11	;	;	:
cord-276598-tm0yj2sn	188	12	Scheme	scheme	NN
cord-276598-tm0yj2sn	188	13	5b	5b	CD
cord-276598-tm0yj2sn	188	14	)	)	-RRB-
cord-276598-tm0yj2sn	189	1	[	[	-LRB-
cord-276598-tm0yj2sn	189	2	87	87	CD
cord-276598-tm0yj2sn	189	3	]	]	-RRB-
cord-276598-tm0yj2sn	189	4	.	.	.
cord-276598-tm0yj2sn	190	1	A	a	DT
cord-276598-tm0yj2sn	190	2	range	range	NN
cord-276598-tm0yj2sn	190	3	of	of	IN
cord-276598-tm0yj2sn	190	4	amines	amine	NNS
cord-276598-tm0yj2sn	190	5	,	,	,
cord-276598-tm0yj2sn	190	6	such	such	JJ
cord-276598-tm0yj2sn	190	7	as	as	IN
cord-276598-tm0yj2sn	190	8	aniline	aniline	NN
cord-276598-tm0yj2sn	190	9	,	,	,
cord-276598-tm0yj2sn	190	10	benzylamine	benzylamine	JJ
cord-276598-tm0yj2sn	190	11	,	,	,
cord-276598-tm0yj2sn	190	12	cyclohexylamine	cyclohexylamine	NNP
cord-276598-tm0yj2sn	190	13	,	,	,
cord-276598-tm0yj2sn	190	14	ethylamine	ethylamine	NNP
cord-276598-tm0yj2sn	190	15	,	,	,
cord-276598-tm0yj2sn	190	16	and	and	CC
cord-276598-tm0yj2sn	190	17	diethylamine	diethylamine	NN
cord-276598-tm0yj2sn	190	18	were	be	VBD
cord-276598-tm0yj2sn	190	19	used	use	VBN
cord-276598-tm0yj2sn	190	20	.	.	.
cord-276598-tm0yj2sn	191	1	The	the	DT
cord-276598-tm0yj2sn	191	2	crude	crude	NN
cord-276598-tm0yj2sn	191	3	P	p	NN
cord-276598-tm0yj2sn	191	4	-	-	HYPH
cord-276598-tm0yj2sn	191	5	Ns	Ns	NNP
cord-276598-tm0yj2sn	191	6	were	be	VBD
cord-276598-tm0yj2sn	191	7	recrystallized	recrystallize	VBN
cord-276598-tm0yj2sn	191	8	to	to	TO
cord-276598-tm0yj2sn	191	9	afford	afford	VB
cord-276598-tm0yj2sn	191	10	pure	pure	JJ
cord-276598-tm0yj2sn	191	11	products	product	NNS
cord-276598-tm0yj2sn	191	12	in	in	IN
cord-276598-tm0yj2sn	191	13	35	35	CD
cord-276598-tm0yj2sn	191	14	-	-	SYM
cord-276598-tm0yj2sn	191	15	93	93	CD
cord-276598-tm0yj2sn	191	16	%	%	NN
cord-276598-tm0yj2sn	191	17	yield	yield	NN
cord-276598-tm0yj2sn	191	18	.	.	.
cord-276598-tm0yj2sn	192	1	Due	due	IN
cord-276598-tm0yj2sn	192	2	to	to	IN
cord-276598-tm0yj2sn	192	3	the	the	DT
cord-276598-tm0yj2sn	192	4	difficulty	difficulty	NN
cord-276598-tm0yj2sn	192	5	encountered	encounter	VBN
cord-276598-tm0yj2sn	192	6	in	in	IN
cord-276598-tm0yj2sn	192	7	phosphorylating	phosphorylate	VBG
cord-276598-tm0yj2sn	192	8	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	192	9	amines	amine	NNS
cord-276598-tm0yj2sn	192	10	,	,	,
cord-276598-tm0yj2sn	192	11	as	as	IN
cord-276598-tm0yj2sn	192	12	mentioned	mention	VBN
cord-276598-tm0yj2sn	192	13	by	by	IN
cord-276598-tm0yj2sn	192	14	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	192	15	[	[	-LRB-
cord-276598-tm0yj2sn	192	16	87	87	CD
cord-276598-tm0yj2sn	192	17	,	,	,
cord-276598-tm0yj2sn	192	18	89	89	CD
cord-276598-tm0yj2sn	192	19	]	]	-RRB-
cord-276598-tm0yj2sn	192	20	,	,	,
cord-276598-tm0yj2sn	192	21	Lukanov	Lukanov	NNP
cord-276598-tm0yj2sn	192	22	et	et	NNP
cord-276598-tm0yj2sn	192	23	al	al	NNP
cord-276598-tm0yj2sn	192	24	.	.	NNP
cord-276598-tm0yj2sn	192	25	proposed	propose	VBD
cord-276598-tm0yj2sn	192	26	a	a	DT
cord-276598-tm0yj2sn	192	27	similar	similar	JJ
cord-276598-tm0yj2sn	192	28	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	192	29	route	route	NN
cord-276598-tm0yj2sn	192	30	using	use	VBG
cord-276598-tm0yj2sn	192	31	N	n	NN
cord-276598-tm0yj2sn	192	32	-	-	HYPH
cord-276598-tm0yj2sn	192	33	phenylformamide	phenylformamide	NN
cord-276598-tm0yj2sn	192	34	or	or	CC
cord-276598-tm0yj2sn	192	35	2-chloro	2-chloro	CD
cord-276598-tm0yj2sn	192	36	-	-	HYPH
cord-276598-tm0yj2sn	192	37	N	n	NN
cord-276598-tm0yj2sn	192	38	-	-	HYPH
cord-276598-tm0yj2sn	192	39	phenylacetamide	phenylacetamide	NN
cord-276598-tm0yj2sn	192	40	as	as	IN
cord-276598-tm0yj2sn	192	41	the	the	DT
cord-276598-tm0yj2sn	192	42	N	n	CD
cord-276598-tm0yj2sn	192	43	-	-	HYPH
cord-276598-tm0yj2sn	192	44	source	source	NN
cord-276598-tm0yj2sn	192	45	,	,	,
cord-276598-tm0yj2sn	192	46	which	which	WDT
cord-276598-tm0yj2sn	192	47	offered	offer	VBD
cord-276598-tm0yj2sn	192	48	less	less	JJR
cord-276598-tm0yj2sn	192	49	steric	steric	JJ
cord-276598-tm0yj2sn	192	50	hindrance	hindrance	NN
cord-276598-tm0yj2sn	192	51	and	and	CC
cord-276598-tm0yj2sn	192	52	better	well	JJR
cord-276598-tm0yj2sn	192	53	N	n	CD
cord-276598-tm0yj2sn	192	54	-	-	HYPH
cord-276598-tm0yj2sn	192	55	H	h	NN
cord-276598-tm0yj2sn	192	56	acidity	acidity	NN
cord-276598-tm0yj2sn	192	57	(	(	-LRB-
cord-276598-tm0yj2sn	192	58	Scheme	scheme	NN
cord-276598-tm0yj2sn	192	59	5c	5c	CD
cord-276598-tm0yj2sn	192	60	)	)	-RRB-
cord-276598-tm0yj2sn	192	61	[	[	-LRB-
cord-276598-tm0yj2sn	192	62	96	96	CD
cord-276598-tm0yj2sn	192	63	]	]	-RRB-
cord-276598-tm0yj2sn	192	64	.	.	.
cord-276598-tm0yj2sn	193	1	Derivatives	derivative	NNS
cord-276598-tm0yj2sn	193	2	of	of	IN
cord-276598-tm0yj2sn	193	3	N	n	NN
cord-276598-tm0yj2sn	193	4	-	-	HYPH
cord-276598-tm0yj2sn	193	5	phenylformamide	phenylformamide	NN
cord-276598-tm0yj2sn	193	6	or	or	CC
cord-276598-tm0yj2sn	193	7	2-chloro	2-chloro	CD
cord-276598-tm0yj2sn	193	8	-	-	HYPH
cord-276598-tm0yj2sn	193	9	N	n	CD
cord-276598-tm0yj2sn	193	10	-	-	HYPH
cord-276598-tm0yj2sn	193	11	phenylacetamide	phenylacetamide	NN
cord-276598-tm0yj2sn	193	12	(	(	-LRB-
cord-276598-tm0yj2sn	193	13	R'R"NC(O)R	R'R"NC(O)R	NNP
cord-276598-tm0yj2sn	193	14	"	"	''
cord-276598-tm0yj2sn	193	15	'	'	''
cord-276598-tm0yj2sn	193	16	)	)	-RRB-
cord-276598-tm0yj2sn	193	17	were	be	VBD
cord-276598-tm0yj2sn	193	18	used	use	VBN
cord-276598-tm0yj2sn	193	19	containing	contain	VBG
cord-276598-tm0yj2sn	193	20	a	a	DT
cord-276598-tm0yj2sn	193	21	wide	wide	JJ
cord-276598-tm0yj2sn	193	22	range	range	NN
cord-276598-tm0yj2sn	193	23	of	of	IN
cord-276598-tm0yj2sn	193	24	aryl	aryl	NN
cord-276598-tm0yj2sn	193	25	-	-	HYPH
cord-276598-tm0yj2sn	193	26	substituents	substituent	NNS
cord-276598-tm0yj2sn	193	27	(	(	-LRB-
cord-276598-tm0yj2sn	193	28	e.g.	e.g.	RB
cord-276598-tm0yj2sn	193	29	,	,	,
cord-276598-tm0yj2sn	193	30	R	r	NN
cord-276598-tm0yj2sn	193	31	"	"	''
cord-276598-tm0yj2sn	193	32	=	=	NFP
cord-276598-tm0yj2sn	194	1	Ph	Ph	NNP
cord-276598-tm0yj2sn	194	2	,	,	,
cord-276598-tm0yj2sn	194	3	4-MeOPh	4-meoph	CD
cord-276598-tm0yj2sn	194	4	,	,	,
cord-276598-tm0yj2sn	194	5	4-ClPh	4-clph	CD
cord-276598-tm0yj2sn	194	6	,	,	,
cord-276598-tm0yj2sn	194	7	2-MeOPh	2-meoph	CD
cord-276598-tm0yj2sn	194	8	,	,	,
cord-276598-tm0yj2sn	194	9	2,3-Cl	2,3-cl	CD
cord-276598-tm0yj2sn	194	10	2	2	CD
cord-276598-tm0yj2sn	194	11	Ph	Ph	NNP
cord-276598-tm0yj2sn	194	12	,	,	,
cord-276598-tm0yj2sn	194	13	2-MePh	2-meph	CD
cord-276598-tm0yj2sn	194	14	,	,	,
cord-276598-tm0yj2sn	194	15	and	and	CC
cord-276598-tm0yj2sn	194	16	2,6-(C	2,6-(c	CD
cord-276598-tm0yj2sn	194	17	2	2	CD
cord-276598-tm0yj2sn	194	18	H	h	NN
cord-276598-tm0yj2sn	194	19	5	5	CD
cord-276598-tm0yj2sn	194	20	)	)	-RRB-
cord-276598-tm0yj2sn	194	21	2	2	CD
cord-276598-tm0yj2sn	194	22	Ph	Ph	NNP
cord-276598-tm0yj2sn	194	23	and	and	CC
cord-276598-tm0yj2sn	194	24	2,6-(CH	2,6-(ch	CD
cord-276598-tm0yj2sn	194	25	3	3	CD
cord-276598-tm0yj2sn	194	26	)	)	-RRB-
cord-276598-tm0yj2sn	194	27	2	2	CD
cord-276598-tm0yj2sn	194	28	Ph	Ph	NNP
cord-276598-tm0yj2sn	194	29	)	)	-RRB-
cord-276598-tm0yj2sn	194	30	.	.	.
cord-276598-tm0yj2sn	195	1	Either	either	CC
cord-276598-tm0yj2sn	195	2	column	column	NN
cord-276598-tm0yj2sn	195	3	chromatography	chromatography	NN
cord-276598-tm0yj2sn	195	4	(	(	-LRB-
cord-276598-tm0yj2sn	195	5	on	on	IN
cord-276598-tm0yj2sn	195	6	silica	silica	NN
cord-276598-tm0yj2sn	195	7	)	)	-RRB-
cord-276598-tm0yj2sn	195	8	or	or	CC
cord-276598-tm0yj2sn	195	9	recrystallization	recrystallization	NN
cord-276598-tm0yj2sn	195	10	were	be	VBD
cord-276598-tm0yj2sn	195	11	used	use	VBN
cord-276598-tm0yj2sn	195	12	to	to	TO
cord-276598-tm0yj2sn	195	13	purify	purify	VB
cord-276598-tm0yj2sn	195	14	the	the	DT
cord-276598-tm0yj2sn	195	15	P	P	NNP
cord-276598-tm0yj2sn	195	16	-	-	HYPH
cord-276598-tm0yj2sn	195	17	Ns	Ns	NNP
cord-276598-tm0yj2sn	195	18	to	to	TO
cord-276598-tm0yj2sn	195	19	obtain	obtain	VB
cord-276598-tm0yj2sn	195	20	isolated	isolated	JJ
cord-276598-tm0yj2sn	195	21	yields	yield	NNS
cord-276598-tm0yj2sn	195	22	in	in	IN
cord-276598-tm0yj2sn	195	23	the	the	DT
cord-276598-tm0yj2sn	195	24	range	range	NN
cord-276598-tm0yj2sn	195	25	of	of	IN
cord-276598-tm0yj2sn	195	26	30	30	CD
cord-276598-tm0yj2sn	195	27	-	-	SYM
cord-276598-tm0yj2sn	195	28	80	80	CD
cord-276598-tm0yj2sn	195	29	%	%	NN
cord-276598-tm0yj2sn	195	30	.	.	.
cord-276598-tm0yj2sn	195	31	 	 	_SP
cord-276598-tm0yj2sn	196	1	In	in	IN
cord-276598-tm0yj2sn	196	2	another	another	DT
cord-276598-tm0yj2sn	196	3	salt	salt	NN
cord-276598-tm0yj2sn	196	4	elimination	elimination	NN
cord-276598-tm0yj2sn	196	5	route	route	NN
cord-276598-tm0yj2sn	196	6	,	,	,
cord-276598-tm0yj2sn	196	7	this	this	DT
cord-276598-tm0yj2sn	196	8	time	time	NN
cord-276598-tm0yj2sn	196	9	using	use	VBG
cord-276598-tm0yj2sn	196	10	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	196	11	bases	basis	NNS
cord-276598-tm0yj2sn	196	12	and	and	CC
cord-276598-tm0yj2sn	196	13	[	[	-LRB-
cord-276598-tm0yj2sn	196	14	n	n	NN
cord-276598-tm0yj2sn	196	15	-	-	HYPH
cord-276598-tm0yj2sn	196	16	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	196	17	as	as	IN
cord-276598-tm0yj2sn	196	18	a	a	DT
cord-276598-tm0yj2sn	196	19	catalyst	catalyst	NN
cord-276598-tm0yj2sn	196	20	,	,	,
cord-276598-tm0yj2sn	196	21	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	196	22	and	and	CC
cord-276598-tm0yj2sn	196	23	Osowska	Osowska	NNP
cord-276598-tm0yj2sn	196	24	-	-	HYPH
cord-276598-tm0yj2sn	196	25	Pacewicka	Pacewicka	NNP
cord-276598-tm0yj2sn	196	26	synthesized	synthesize	VBD
cord-276598-tm0yj2sn	196	27	P	P	NNP
cord-276598-tm0yj2sn	196	28	-	-	HYPH
cord-276598-tm0yj2sn	196	29	Ns	Ns	NNP
cord-276598-tm0yj2sn	196	30	from	from	IN
cord-276598-tm0yj2sn	196	31	(	(	-LRB-
cord-276598-tm0yj2sn	196	32	EtO)2P(O)H	EtO)2P(O)H	NNP
cord-276598-tm0yj2sn	196	33	(	(	-LRB-
cord-276598-tm0yj2sn	196	34	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	196	35	H	H	NNP
cord-276598-tm0yj2sn	196	36	-	-	HYPH
cord-276598-tm0yj2sn	196	37	P	P	NNP
cord-276598-tm0yj2sn	196	38	)	)	-RRB-
cord-276598-tm0yj2sn	196	39	and	and	CC
cord-276598-tm0yj2sn	196	40	various	various	JJ
cord-276598-tm0yj2sn	196	41	amines	amine	NNS
cord-276598-tm0yj2sn	196	42	(	(	-LRB-
cord-276598-tm0yj2sn	196	43	Scheme	scheme	NN
cord-276598-tm0yj2sn	196	44	5a	5a	CD
cord-276598-tm0yj2sn	196	45	)	)	-RRB-
cord-276598-tm0yj2sn	196	46	[	[	-LRB-
cord-276598-tm0yj2sn	196	47	89	89	CD
cord-276598-tm0yj2sn	196	48	]	]	-RRB-
cord-276598-tm0yj2sn	196	49	.	.	.
cord-276598-tm0yj2sn	197	1	Aromatic	aromatic	JJ
cord-276598-tm0yj2sn	197	2	amines	amine	NNS
cord-276598-tm0yj2sn	197	3	such	such	JJ
cord-276598-tm0yj2sn	197	4	as	as	IN
cord-276598-tm0yj2sn	197	5	aniline	aniline	NN
cord-276598-tm0yj2sn	197	6	and	and	CC
cord-276598-tm0yj2sn	197	7	4-chloroaniline	4-chloroaniline	CD
cord-276598-tm0yj2sn	197	8	,	,	,
cord-276598-tm0yj2sn	197	9	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	197	10	amines	amine	NNS
cord-276598-tm0yj2sn	197	11	such	such	JJ
cord-276598-tm0yj2sn	197	12	as	as	IN
cord-276598-tm0yj2sn	197	13	cyclohexylamine	cyclohexylamine	NNP
cord-276598-tm0yj2sn	197	14	,	,	,
cord-276598-tm0yj2sn	197	15	n	n	JJ
cord-276598-tm0yj2sn	197	16	-	-	HYPH
cord-276598-tm0yj2sn	197	17	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	197	18	,	,	,
cord-276598-tm0yj2sn	197	19	and	and	CC
cord-276598-tm0yj2sn	197	20	ethanamine	ethanamine	NN
cord-276598-tm0yj2sn	197	21	,	,	,
cord-276598-tm0yj2sn	197	22	and	and	CC
cord-276598-tm0yj2sn	197	23	alkanolamines	alkanolamine	NNS
cord-276598-tm0yj2sn	197	24	such	such	JJ
cord-276598-tm0yj2sn	197	25	as	as	IN
cord-276598-tm0yj2sn	197	26	2-aminoethan-1-ol	2-aminoethan-1-ol	CD
cord-276598-tm0yj2sn	197	27	,	,	,
cord-276598-tm0yj2sn	197	28	3-aminopropan-1-ol	3-aminopropan-1-ol	CD
cord-276598-tm0yj2sn	197	29	,	,	,
cord-276598-tm0yj2sn	197	30	and	and	CC
cord-276598-tm0yj2sn	198	1	bis(2-(-ethoxy)ethyl)amine	bis(2-(-ethoxy)ethyl)amine	NNP
cord-276598-tm0yj2sn	198	2	were	be	VBD
cord-276598-tm0yj2sn	198	3	explored	explore	VBN
cord-276598-tm0yj2sn	198	4	to	to	TO
cord-276598-tm0yj2sn	198	5	demonstrate	demonstrate	VB
cord-276598-tm0yj2sn	198	6	the	the	DT
cord-276598-tm0yj2sn	198	7	broad	broad	JJ
cord-276598-tm0yj2sn	198	8	scope	scope	NN
cord-276598-tm0yj2sn	198	9	of	of	IN
cord-276598-tm0yj2sn	198	10	this	this	DT
cord-276598-tm0yj2sn	198	11	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	198	12	transformation	transformation	NN
cord-276598-tm0yj2sn	198	13	.	.	.
cord-276598-tm0yj2sn	199	1	The	the	DT
cord-276598-tm0yj2sn	199	2	P	P	NNP
cord-276598-tm0yj2sn	199	3	-	-	HYPH
cord-276598-tm0yj2sn	199	4	Ns	Ns	NNP
cord-276598-tm0yj2sn	199	5	were	be	VBD
cord-276598-tm0yj2sn	199	6	isolated	isolate	VBN
cord-276598-tm0yj2sn	199	7	in	in	IN
cord-276598-tm0yj2sn	199	8	83	83	CD
cord-276598-tm0yj2sn	199	9	-	-	SYM
cord-276598-tm0yj2sn	199	10	100	100	CD
cord-276598-tm0yj2sn	199	11	%	%	NN
cord-276598-tm0yj2sn	199	12	yield	yield	NN
cord-276598-tm0yj2sn	199	13	after	after	IN
cord-276598-tm0yj2sn	199	14	recrystallization	recrystallization	NN
cord-276598-tm0yj2sn	199	15	.	.	.
cord-276598-tm0yj2sn	200	1	In	in	IN
cord-276598-tm0yj2sn	200	2	a	a	DT
cord-276598-tm0yj2sn	200	3	similar	similar	JJ
cord-276598-tm0yj2sn	200	4	synthesis	synthesis	NN
cord-276598-tm0yj2sn	200	5	,	,	,
cord-276598-tm0yj2sn	200	6	using	use	VBG
cord-276598-tm0yj2sn	200	7	[	[	-LRB-
cord-276598-tm0yj2sn	200	8	BnEt3N]Cl	BnEt3N]Cl	NNP
cord-276598-tm0yj2sn	200	9	as	as	IN
cord-276598-tm0yj2sn	200	10	the	the	DT
cord-276598-tm0yj2sn	200	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	200	12	instead	instead	RB
cord-276598-tm0yj2sn	200	13	of	of	IN
cord-276598-tm0yj2sn	200	14	[	[	-LRB-
cord-276598-tm0yj2sn	200	15	n	n	NNP
cord-276598-tm0yj2sn	200	16	-	-	HYPH
cord-276598-tm0yj2sn	200	17	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	200	18	,	,	,
cord-276598-tm0yj2sn	200	19	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	200	20	accomplished	accomplish	VBD
cord-276598-tm0yj2sn	200	21	the	the	DT
cord-276598-tm0yj2sn	200	22	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	200	23	of	of	IN
cord-276598-tm0yj2sn	200	24	amines	amine	NNS
cord-276598-tm0yj2sn	200	25	using	use	VBG
cord-276598-tm0yj2sn	200	26	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	200	27	H	H	NNP
cord-276598-tm0yj2sn	200	28	-	-	HYPH
cord-276598-tm0yj2sn	200	29	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	201	1	(	(	-LRB-
cord-276598-tm0yj2sn	201	2	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	201	3	(	(	-LRB-
cord-276598-tm0yj2sn	201	4	R	r	NN
cord-276598-tm0yj2sn	201	5	=	=	FW
cord-276598-tm0yj2sn	201	6	Et	et	NN
cord-276598-tm0yj2sn	201	7	,	,	,
cord-276598-tm0yj2sn	202	1	Bn	Bn	NNP
cord-276598-tm0yj2sn	202	2	,	,	,
cord-276598-tm0yj2sn	202	3	t	t	NN
cord-276598-tm0yj2sn	202	4	-	-	HYPH
cord-276598-tm0yj2sn	202	5	Bu	Bu	NNP
cord-276598-tm0yj2sn	202	6	;	;	:
cord-276598-tm0yj2sn	202	7	Scheme	scheme	NN
cord-276598-tm0yj2sn	202	8	5b	5b	CD
cord-276598-tm0yj2sn	202	9	)	)	-RRB-
cord-276598-tm0yj2sn	203	1	[	[	-LRB-
cord-276598-tm0yj2sn	203	2	87	87	CD
cord-276598-tm0yj2sn	203	3	]	]	-RRB-
cord-276598-tm0yj2sn	203	4	.	.	.
cord-276598-tm0yj2sn	204	1	A	a	DT
cord-276598-tm0yj2sn	204	2	range	range	NN
cord-276598-tm0yj2sn	204	3	of	of	IN
cord-276598-tm0yj2sn	204	4	amines	amine	NNS
cord-276598-tm0yj2sn	204	5	,	,	,
cord-276598-tm0yj2sn	204	6	such	such	JJ
cord-276598-tm0yj2sn	204	7	as	as	IN
cord-276598-tm0yj2sn	204	8	aniline	aniline	NN
cord-276598-tm0yj2sn	204	9	,	,	,
cord-276598-tm0yj2sn	204	10	benzylamine	benzylamine	JJ
cord-276598-tm0yj2sn	204	11	,	,	,
cord-276598-tm0yj2sn	204	12	cyclohexylamine	cyclohexylamine	NNP
cord-276598-tm0yj2sn	204	13	,	,	,
cord-276598-tm0yj2sn	204	14	ethylamine	ethylamine	NNP
cord-276598-tm0yj2sn	204	15	,	,	,
cord-276598-tm0yj2sn	204	16	and	and	CC
cord-276598-tm0yj2sn	204	17	diethylamine	diethylamine	NN
cord-276598-tm0yj2sn	204	18	were	be	VBD
cord-276598-tm0yj2sn	204	19	used	use	VBN
cord-276598-tm0yj2sn	204	20	.	.	.
cord-276598-tm0yj2sn	205	1	The	the	DT
cord-276598-tm0yj2sn	205	2	crude	crude	NN
cord-276598-tm0yj2sn	205	3	P	p	NN
cord-276598-tm0yj2sn	205	4	-	-	HYPH
cord-276598-tm0yj2sn	205	5	Ns	Ns	NNP
cord-276598-tm0yj2sn	205	6	were	be	VBD
cord-276598-tm0yj2sn	205	7	recrystallized	recrystallize	VBN
cord-276598-tm0yj2sn	205	8	to	to	TO
cord-276598-tm0yj2sn	205	9	afford	afford	VB
cord-276598-tm0yj2sn	205	10	pure	pure	JJ
cord-276598-tm0yj2sn	205	11	products	product	NNS
cord-276598-tm0yj2sn	205	12	in	in	IN
cord-276598-tm0yj2sn	205	13	35	35	CD
cord-276598-tm0yj2sn	205	14	-	-	SYM
cord-276598-tm0yj2sn	205	15	93	93	CD
cord-276598-tm0yj2sn	205	16	%	%	NN
cord-276598-tm0yj2sn	205	17	yield	yield	NN
cord-276598-tm0yj2sn	205	18	.	.	.
cord-276598-tm0yj2sn	206	1	Due	due	IN
cord-276598-tm0yj2sn	206	2	to	to	IN
cord-276598-tm0yj2sn	206	3	the	the	DT
cord-276598-tm0yj2sn	206	4	difficulty	difficulty	NN
cord-276598-tm0yj2sn	206	5	encountered	encounter	VBN
cord-276598-tm0yj2sn	206	6	in	in	IN
cord-276598-tm0yj2sn	206	7	phosphorylating	phosphorylate	VBG
cord-276598-tm0yj2sn	206	8	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	206	9	amines	amine	NNS
cord-276598-tm0yj2sn	206	10	,	,	,
cord-276598-tm0yj2sn	206	11	as	as	IN
cord-276598-tm0yj2sn	206	12	mentioned	mention	VBN
cord-276598-tm0yj2sn	206	13	by	by	IN
cord-276598-tm0yj2sn	206	14	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	206	15	[	[	-LRB-
cord-276598-tm0yj2sn	206	16	87	87	CD
cord-276598-tm0yj2sn	206	17	,	,	,
cord-276598-tm0yj2sn	206	18	89	89	CD
cord-276598-tm0yj2sn	206	19	]	]	-RRB-
cord-276598-tm0yj2sn	206	20	,	,	,
cord-276598-tm0yj2sn	206	21	Lukanov	Lukanov	NNP
cord-276598-tm0yj2sn	206	22	et	et	NNP
cord-276598-tm0yj2sn	206	23	al	al	NNP
cord-276598-tm0yj2sn	206	24	.	.	NNP
cord-276598-tm0yj2sn	206	25	proposed	propose	VBD
cord-276598-tm0yj2sn	206	26	a	a	DT
cord-276598-tm0yj2sn	206	27	similar	similar	JJ
cord-276598-tm0yj2sn	206	28	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	206	29	route	route	NN
cord-276598-tm0yj2sn	206	30	using	use	VBG
cord-276598-tm0yj2sn	206	31	N	n	NN
cord-276598-tm0yj2sn	206	32	-	-	HYPH
cord-276598-tm0yj2sn	206	33	phenylformamide	phenylformamide	NN
cord-276598-tm0yj2sn	206	34	or	or	CC
cord-276598-tm0yj2sn	206	35	2-chloro	2-chloro	CD
cord-276598-tm0yj2sn	206	36	-	-	HYPH
cord-276598-tm0yj2sn	206	37	N	n	NN
cord-276598-tm0yj2sn	206	38	-	-	HYPH
cord-276598-tm0yj2sn	206	39	phenylacetamide	phenylacetamide	NN
cord-276598-tm0yj2sn	206	40	as	as	IN
cord-276598-tm0yj2sn	206	41	the	the	DT
cord-276598-tm0yj2sn	206	42	N	n	CD
cord-276598-tm0yj2sn	206	43	-	-	HYPH
cord-276598-tm0yj2sn	206	44	source	source	NN
cord-276598-tm0yj2sn	206	45	,	,	,
cord-276598-tm0yj2sn	206	46	which	which	WDT
cord-276598-tm0yj2sn	206	47	offered	offer	VBD
cord-276598-tm0yj2sn	206	48	less	less	JJR
cord-276598-tm0yj2sn	206	49	steric	steric	JJ
cord-276598-tm0yj2sn	206	50	hindrance	hindrance	NN
cord-276598-tm0yj2sn	206	51	and	and	CC
cord-276598-tm0yj2sn	206	52	better	well	JJR
cord-276598-tm0yj2sn	206	53	N	n	CD
cord-276598-tm0yj2sn	206	54	-	-	HYPH
cord-276598-tm0yj2sn	206	55	H	h	NN
cord-276598-tm0yj2sn	206	56	acidity	acidity	NN
cord-276598-tm0yj2sn	206	57	(	(	-LRB-
cord-276598-tm0yj2sn	206	58	Scheme	scheme	NN
cord-276598-tm0yj2sn	206	59	5c	5c	CD
cord-276598-tm0yj2sn	206	60	)	)	-RRB-
cord-276598-tm0yj2sn	206	61	[	[	-LRB-
cord-276598-tm0yj2sn	206	62	96	96	CD
cord-276598-tm0yj2sn	206	63	]	]	-RRB-
cord-276598-tm0yj2sn	206	64	.	.	.
cord-276598-tm0yj2sn	207	1	Derivatives	derivative	NNS
cord-276598-tm0yj2sn	207	2	of	of	IN
cord-276598-tm0yj2sn	207	3	N	n	NN
cord-276598-tm0yj2sn	207	4	-	-	HYPH
cord-276598-tm0yj2sn	207	5	phenylformamide	phenylformamide	NN
cord-276598-tm0yj2sn	207	6	or	or	CC
cord-276598-tm0yj2sn	207	7	2-chloro	2-chloro	CD
cord-276598-tm0yj2sn	207	8	-	-	HYPH
cord-276598-tm0yj2sn	207	9	N	n	CD
cord-276598-tm0yj2sn	207	10	-	-	HYPH
cord-276598-tm0yj2sn	207	11	phenylacetamide	phenylacetamide	NN
cord-276598-tm0yj2sn	207	12	(	(	-LRB-
cord-276598-tm0yj2sn	207	13	R'R''NC(O)R	R'R''NC(O)R	NNP
cord-276598-tm0yj2sn	207	14	'	'	''
cord-276598-tm0yj2sn	207	15	'	'	''
cord-276598-tm0yj2sn	207	16	'	'	''
cord-276598-tm0yj2sn	207	17	)	)	-RRB-
cord-276598-tm0yj2sn	207	18	were	be	VBD
cord-276598-tm0yj2sn	207	19	used	use	VBN
cord-276598-tm0yj2sn	207	20	containing	contain	VBG
cord-276598-tm0yj2sn	207	21	a	a	DT
cord-276598-tm0yj2sn	207	22	wide	wide	JJ
cord-276598-tm0yj2sn	207	23	range	range	NN
cord-276598-tm0yj2sn	207	24	of	of	IN
cord-276598-tm0yj2sn	207	25	aryl	aryl	NN
cord-276598-tm0yj2sn	207	26	-	-	HYPH
cord-276598-tm0yj2sn	207	27	substituents	substituent	NNS
cord-276598-tm0yj2sn	207	28	(	(	-LRB-
cord-276598-tm0yj2sn	207	29	e.g.	e.g.	RB
cord-276598-tm0yj2sn	207	30	,	,	,
cord-276598-tm0yj2sn	207	31	R	r	NN
cord-276598-tm0yj2sn	207	32	'	'	''
cord-276598-tm0yj2sn	207	33	'	'	''
cord-276598-tm0yj2sn	207	34	=	=	NFP
cord-276598-tm0yj2sn	208	1	Ph	Ph	NNP
cord-276598-tm0yj2sn	208	2	,	,	,
cord-276598-tm0yj2sn	208	3	4-MeOPh	4-meoph	CD
cord-276598-tm0yj2sn	208	4	,	,	,
cord-276598-tm0yj2sn	208	5	4-ClPh	4-clph	CD
cord-276598-tm0yj2sn	208	6	,	,	,
cord-276598-tm0yj2sn	208	7	2-MeOPh	2-meoph	CD
cord-276598-tm0yj2sn	208	8	,	,	,
cord-276598-tm0yj2sn	208	9	2,3-Cl2Ph	2,3-cl2ph	CD
cord-276598-tm0yj2sn	208	10	,	,	,
cord-276598-tm0yj2sn	208	11	2-MePh	2-meph	CD
cord-276598-tm0yj2sn	208	12	,	,	,
cord-276598-tm0yj2sn	208	13	and	and	CC
cord-276598-tm0yj2sn	208	14	2,6-(C2H5)2Ph	2,6-(c2h5)2ph	CD
cord-276598-tm0yj2sn	208	15	and	and	CC
cord-276598-tm0yj2sn	208	16	2,6-(CH3)2Ph	2,6-(ch3)2ph	CD
cord-276598-tm0yj2sn	208	17	)	)	-RRB-
cord-276598-tm0yj2sn	208	18	.	.	.
cord-276598-tm0yj2sn	209	1	Either	either	CC
cord-276598-tm0yj2sn	209	2	column	column	NN
cord-276598-tm0yj2sn	209	3	chromatography	chromatography	NN
cord-276598-tm0yj2sn	209	4	(	(	-LRB-
cord-276598-tm0yj2sn	209	5	on	on	IN
cord-276598-tm0yj2sn	209	6	silica	silica	NN
cord-276598-tm0yj2sn	209	7	)	)	-RRB-
cord-276598-tm0yj2sn	209	8	or	or	CC
cord-276598-tm0yj2sn	209	9	recrystallization	recrystallization	NN
cord-276598-tm0yj2sn	209	10	were	be	VBD
cord-276598-tm0yj2sn	209	11	used	use	VBN
cord-276598-tm0yj2sn	209	12	to	to	TO
cord-276598-tm0yj2sn	209	13	purify	purify	VB
cord-276598-tm0yj2sn	209	14	the	the	DT
cord-276598-tm0yj2sn	209	15	P	P	NNP
cord-276598-tm0yj2sn	209	16	-	-	HYPH
cord-276598-tm0yj2sn	209	17	Ns	Ns	NNP
cord-276598-tm0yj2sn	209	18	to	to	TO
cord-276598-tm0yj2sn	209	19	obtain	obtain	VB
cord-276598-tm0yj2sn	209	20	isolated	isolated	JJ
cord-276598-tm0yj2sn	209	21	yields	yield	NNS
cord-276598-tm0yj2sn	209	22	in	in	IN
cord-276598-tm0yj2sn	209	23	the	the	DT
cord-276598-tm0yj2sn	209	24	range	range	NN
cord-276598-tm0yj2sn	209	25	of	of	IN
cord-276598-tm0yj2sn	209	26	30	30	CD
cord-276598-tm0yj2sn	209	27	-	-	SYM
cord-276598-tm0yj2sn	209	28	80	80	CD
cord-276598-tm0yj2sn	209	29	%	%	NN
cord-276598-tm0yj2sn	209	30	.	.	.
cord-276598-tm0yj2sn	210	1	Inorganic	inorganic	JJ
cord-276598-tm0yj2sn	210	2	salt	salt	NN
cord-276598-tm0yj2sn	210	3	elimination	elimination	NN
cord-276598-tm0yj2sn	210	4	methods	method	NNS
cord-276598-tm0yj2sn	210	5	stimulated	stimulate	VBD
cord-276598-tm0yj2sn	210	6	an	an	DT
cord-276598-tm0yj2sn	210	7	era	era	NN
cord-276598-tm0yj2sn	210	8	of	of	IN
cord-276598-tm0yj2sn	210	9	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	210	10	transformations	transformation	NNS
cord-276598-tm0yj2sn	210	11	of	of	IN
cord-276598-tm0yj2sn	210	12	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	210	13	H	H	NNP
cord-276598-tm0yj2sn	210	14	-	-	HYPH
cord-276598-tm0yj2sn	210	15	P	p	NN
cord-276598-tm0yj2sn	210	16	(	(	-LRB-
cord-276598-tm0yj2sn	210	17	(	(	-LRB-
cord-276598-tm0yj2sn	210	18	RO	RO	NNP
cord-276598-tm0yj2sn	210	19	)	)	-RRB-
cord-276598-tm0yj2sn	210	20	2	2	CD
cord-276598-tm0yj2sn	210	21	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	210	22	;	;	:
cord-276598-tm0yj2sn	210	23	R	r	NN
cord-276598-tm0yj2sn	210	24	=	=	NN
cord-276598-tm0yj2sn	210	25	alkyl	alkyl	NN
cord-276598-tm0yj2sn	210	26	)	)	-RRB-
cord-276598-tm0yj2sn	210	27	to	to	IN
cord-276598-tm0yj2sn	210	28	(	(	-LRB-
cord-276598-tm0yj2sn	210	29	RO	RO	NNP
cord-276598-tm0yj2sn	210	30	)	)	-RRB-
cord-276598-tm0yj2sn	210	31	2	2	CD
cord-276598-tm0yj2sn	211	1	P(O)Cl	P(O)Cl	VBN
cord-276598-tm0yj2sn	212	1	(	(	-LRB-
cord-276598-tm0yj2sn	212	2	dACP	dacp	JJ
cord-276598-tm0yj2sn	212	3	;	;	:
cord-276598-tm0yj2sn	212	4	R	r	NN
cord-276598-tm0yj2sn	212	5	=	=	NN
cord-276598-tm0yj2sn	212	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	212	7	)	)	-RRB-
cord-276598-tm0yj2sn	212	8	in	in	IN
cord-276598-tm0yj2sn	212	9	the	the	DT
cord-276598-tm0yj2sn	212	10	presence	presence	NN
cord-276598-tm0yj2sn	212	11	of	of	IN
cord-276598-tm0yj2sn	212	12	readily	readily	RB
cord-276598-tm0yj2sn	212	13	available	available	JJ
cord-276598-tm0yj2sn	212	14	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	212	15	bases	basis	NNS
cord-276598-tm0yj2sn	212	16	,	,	,
cord-276598-tm0yj2sn	212	17	thereby	thereby	RB
cord-276598-tm0yj2sn	212	18	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	212	19	the	the	DT
cord-276598-tm0yj2sn	212	20	use	use	NN
cord-276598-tm0yj2sn	212	21	of	of	IN
cord-276598-tm0yj2sn	212	22	Et	Et	NNP
cord-276598-tm0yj2sn	212	23	3	3	CD
cord-276598-tm0yj2sn	212	24	N.	n.	NN
cord-276598-tm0yj2sn	213	1	However	however	RB
cord-276598-tm0yj2sn	213	2	,	,	,
cord-276598-tm0yj2sn	213	3	this	this	DT
cord-276598-tm0yj2sn	213	4	method	method	NN
cord-276598-tm0yj2sn	213	5	has	have	VBZ
cord-276598-tm0yj2sn	213	6	limitations	limitation	NNS
cord-276598-tm0yj2sn	213	7	including	include	VBG
cord-276598-tm0yj2sn	213	8	a	a	DT
cord-276598-tm0yj2sn	213	9	pre	pre	JJ
cord-276598-tm0yj2sn	213	10	-	-	NN
cord-276598-tm0yj2sn	213	11	functionalization	functionalization	JJ
cord-276598-tm0yj2sn	213	12	step	step	NN
cord-276598-tm0yj2sn	213	13	,	,	,
cord-276598-tm0yj2sn	213	14	the	the	DT
cord-276598-tm0yj2sn	213	15	production	production	NN
cord-276598-tm0yj2sn	213	16	of	of	IN
cord-276598-tm0yj2sn	213	17	large	large	JJ
cord-276598-tm0yj2sn	213	18	amounts	amount	NNS
cord-276598-tm0yj2sn	213	19	of	of	IN
cord-276598-tm0yj2sn	213	20	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	213	21	waste	waste	NN
cord-276598-tm0yj2sn	213	22	,	,	,
cord-276598-tm0yj2sn	213	23	and	and	CC
cord-276598-tm0yj2sn	213	24	the	the	DT
cord-276598-tm0yj2sn	213	25	use	use	NN
cord-276598-tm0yj2sn	213	26	of	of	IN
cord-276598-tm0yj2sn	213	27	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	213	28	halogenating	halogenating	NN
cord-276598-tm0yj2sn	213	29	reagents	reagent	NNS
cord-276598-tm0yj2sn	213	30	.	.	.
cord-276598-tm0yj2sn	214	1	A	a	DT
cord-276598-tm0yj2sn	214	2	one	one	CD
cord-276598-tm0yj2sn	214	3	-	-	HYPH
cord-276598-tm0yj2sn	214	4	pot	pot	NN
cord-276598-tm0yj2sn	214	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	214	6	of	of	IN
cord-276598-tm0yj2sn	214	7	P	p	NN
cord-276598-tm0yj2sn	214	8	-	-	HYPH
cord-276598-tm0yj2sn	214	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	214	10	was	be	VBD
cord-276598-tm0yj2sn	214	11	reported	report	VBN
cord-276598-tm0yj2sn	214	12	by	by	IN
cord-276598-tm0yj2sn	214	13	Gupta	Gupta	NNP
cord-276598-tm0yj2sn	214	14	et	et	NNP
cord-276598-tm0yj2sn	214	15	al	al	NNP
cord-276598-tm0yj2sn	214	16	.	.	.
cord-276598-tm0yj2sn	215	1	(	(	-LRB-
cord-276598-tm0yj2sn	215	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	215	3	6a	6a	CD
cord-276598-tm0yj2sn	215	4	)	)	-RRB-
cord-276598-tm0yj2sn	216	1	[	[	-LRB-
cord-276598-tm0yj2sn	216	2	97	97	CD
cord-276598-tm0yj2sn	216	3	]	]	-RRB-
cord-276598-tm0yj2sn	216	4	.	.	.
cord-276598-tm0yj2sn	217	1	According	accord	VBG
cord-276598-tm0yj2sn	217	2	to	to	IN
cord-276598-tm0yj2sn	217	3	the	the	DT
cord-276598-tm0yj2sn	217	4	authors	author	NNS
cord-276598-tm0yj2sn	217	5	,	,	,
cord-276598-tm0yj2sn	217	6	the	the	DT
cord-276598-tm0yj2sn	217	7	chlorination	chlorination	NN
cord-276598-tm0yj2sn	217	8	of	of	IN
cord-276598-tm0yj2sn	217	9	(	(	-LRB-
cord-276598-tm0yj2sn	217	10	RO	ro	NN
cord-276598-tm0yj2sn	217	11	)	)	-RRB-
cord-276598-tm0yj2sn	217	12	2	2	CD
cord-276598-tm0yj2sn	217	13	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	218	1	(	(	-LRB-
cord-276598-tm0yj2sn	218	2	R	r	NN
cord-276598-tm0yj2sn	218	3	=	=	NFP
cord-276598-tm0yj2sn	218	4	Me	-PRON-	PRP
cord-276598-tm0yj2sn	218	5	,	,	,
cord-276598-tm0yj2sn	218	6	Et	Et	NNP
cord-276598-tm0yj2sn	218	7	,	,	,
cord-276598-tm0yj2sn	218	8	Pr	Pr	NNP
cord-276598-tm0yj2sn	218	9	,	,	,
cord-276598-tm0yj2sn	218	10	i	i	NN
cord-276598-tm0yj2sn	218	11	-	-	HYPH
cord-276598-tm0yj2sn	218	12	Pr	pr	NN
cord-276598-tm0yj2sn	218	13	;	;	:
cord-276598-tm0yj2sn	218	14	3	3	CD
cord-276598-tm0yj2sn	218	15	eq	eq	NN
cord-276598-tm0yj2sn	218	16	.	.	.
cord-276598-tm0yj2sn	218	17	)	)	-RRB-
cord-276598-tm0yj2sn	219	1	to	to	TO
cord-276598-tm0yj2sn	219	2	afford	afford	VB
cord-276598-tm0yj2sn	219	3	(	(	-LRB-
cord-276598-tm0yj2sn	219	4	RO	ro	NN
cord-276598-tm0yj2sn	219	5	)	)	-RRB-
cord-276598-tm0yj2sn	219	6	2	2	CD
cord-276598-tm0yj2sn	220	1	P(O)Cl	P(O)Cl	VBN
cord-276598-tm0yj2sn	221	1	(	(	-LRB-
cord-276598-tm0yj2sn	221	2	dACP	dacp	JJ
cord-276598-tm0yj2sn	221	3	;	;	:
cord-276598-tm0yj2sn	221	4	R	r	NN
cord-276598-tm0yj2sn	221	5	=	=	NN
cord-276598-tm0yj2sn	221	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	221	7	)	)	-RRB-
cord-276598-tm0yj2sn	221	8	was	be	VBD
cord-276598-tm0yj2sn	221	9	possible	possible	JJ
cord-276598-tm0yj2sn	221	10	upon	upon	IN
cord-276598-tm0yj2sn	221	11	reacting	react	VBG
cord-276598-tm0yj2sn	221	12	with	with	IN
cord-276598-tm0yj2sn	221	13	trichloroisocyanuric	trichloroisocyanuric	NN
cord-276598-tm0yj2sn	221	14	acid	acid	NN
cord-276598-tm0yj2sn	221	15	(	(	-LRB-
cord-276598-tm0yj2sn	221	16	tCiC	tCiC	NNP
cord-276598-tm0yj2sn	221	17	-	-	HYPH
cord-276598-tm0yj2sn	221	18	A	a	NN
cord-276598-tm0yj2sn	221	19	;	;	:
cord-276598-tm0yj2sn	221	20	1	1	CD
cord-276598-tm0yj2sn	221	21	eq	eq	NN
cord-276598-tm0yj2sn	221	22	.	.	NNP
cord-276598-tm0yj2sn	221	23	)	)	-RRB-
cord-276598-tm0yj2sn	221	24	,	,	,
cord-276598-tm0yj2sn	221	25	which	which	WDT
cord-276598-tm0yj2sn	221	26	was	be	VBD
cord-276598-tm0yj2sn	221	27	then	then	RB
cord-276598-tm0yj2sn	221	28	treated	treat	VBN
cord-276598-tm0yj2sn	221	29	with	with	IN
cord-276598-tm0yj2sn	221	30	an	an	DT
cord-276598-tm0yj2sn	221	31	equal	equal	JJ
cord-276598-tm0yj2sn	221	32	mixture	mixture	NN
cord-276598-tm0yj2sn	221	33	of	of	IN
cord-276598-tm0yj2sn	221	34	amines	amine	NNS
cord-276598-tm0yj2sn	221	35	,	,	,
cord-276598-tm0yj2sn	222	1	R'R"NH	R'R"NH	NNP
cord-276598-tm0yj2sn	223	1	(	(	-LRB-
cord-276598-tm0yj2sn	223	2	R	r	NN
cord-276598-tm0yj2sn	223	3	'	'	''
cord-276598-tm0yj2sn	223	4	=	=	NFP
cord-276598-tm0yj2sn	224	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	224	2	,	,	,
cord-276598-tm0yj2sn	224	3	Et	Et	NNP
cord-276598-tm0yj2sn	224	4	,	,	,
cord-276598-tm0yj2sn	224	5	Pr	Pr	NNP
cord-276598-tm0yj2sn	224	6	;	;	:
cord-276598-tm0yj2sn	224	7	R	r	NN
cord-276598-tm0yj2sn	224	8	"	"	''
cord-276598-tm0yj2sn	224	9	=	=	SYM
cord-276598-tm0yj2sn	224	10	H	h	NN
cord-276598-tm0yj2sn	224	11	)	)	-RRB-
cord-276598-tm0yj2sn	224	12	and	and	CC
cord-276598-tm0yj2sn	224	13	Et	Et	NNP
cord-276598-tm0yj2sn	224	14	3	3	CD
cord-276598-tm0yj2sn	224	15	N	N	NNP
cord-276598-tm0yj2sn	224	16	,	,	,
cord-276598-tm0yj2sn	224	17	to	to	TO
cord-276598-tm0yj2sn	224	18	form	form	VB
cord-276598-tm0yj2sn	224	19	the	the	DT
cord-276598-tm0yj2sn	224	20	P	P	NNP
cord-276598-tm0yj2sn	224	21	-	-	HYPH
cord-276598-tm0yj2sn	224	22	N	n	CD
cord-276598-tm0yj2sn	224	23	in	in	IN
cord-276598-tm0yj2sn	224	24	82	82	CD
cord-276598-tm0yj2sn	224	25	-	-	SYM
cord-276598-tm0yj2sn	224	26	92	92	CD
cord-276598-tm0yj2sn	224	27	%	%	NN
cord-276598-tm0yj2sn	224	28	yield	yield	NN
cord-276598-tm0yj2sn	224	29	,	,	,
cord-276598-tm0yj2sn	224	30	which	which	WDT
cord-276598-tm0yj2sn	224	31	was	be	VBD
cord-276598-tm0yj2sn	224	32	determined	determine	VBN
cord-276598-tm0yj2sn	224	33	as	as	IN
cord-276598-tm0yj2sn	224	34	conversions	conversion	NNS
cord-276598-tm0yj2sn	224	35	by	by	IN
cord-276598-tm0yj2sn	224	36	31	31	CD
cord-276598-tm0yj2sn	224	37	P	p	NN
cord-276598-tm0yj2sn	224	38	NMR	nmr	NN
cord-276598-tm0yj2sn	224	39	spectroscopy	spectroscopy	NN
cord-276598-tm0yj2sn	224	40	.	.	.
cord-276598-tm0yj2sn	225	1	However	however	RB
cord-276598-tm0yj2sn	225	2	,	,	,
cord-276598-tm0yj2sn	225	3	the	the	DT
cord-276598-tm0yj2sn	225	4	isolation	isolation	NN
cord-276598-tm0yj2sn	225	5	of	of	IN
cord-276598-tm0yj2sn	225	6	(	(	-LRB-
cord-276598-tm0yj2sn	225	7	RO	ro	NN
cord-276598-tm0yj2sn	225	8	)	)	-RRB-
cord-276598-tm0yj2sn	225	9	2	2	CD
cord-276598-tm0yj2sn	225	10	P(O)NR'R	P(O)NR'R	NNP
cord-276598-tm0yj2sn	225	11	"	"	''
cord-276598-tm0yj2sn	225	12	(	(	-LRB-
cord-276598-tm0yj2sn	225	13	R	r	NN
cord-276598-tm0yj2sn	225	14	=	=	FW
cord-276598-tm0yj2sn	225	15	Et	et	NN
cord-276598-tm0yj2sn	225	16	,	,	,
cord-276598-tm0yj2sn	225	17	R	R	NNP
cord-276598-tm0yj2sn	225	18	'	'	''
cord-276598-tm0yj2sn	225	19	,	,	,
cord-276598-tm0yj2sn	225	20	R	r	NN
cord-276598-tm0yj2sn	225	21	"	"	''
cord-276598-tm0yj2sn	225	22	=	=	NFP
cord-276598-tm0yj2sn	226	1	Et	Et	NNP
cord-276598-tm0yj2sn	226	2	,	,	,
cord-276598-tm0yj2sn	226	3	Pr	pr	NN
cord-276598-tm0yj2sn	226	4	)	)	-RRB-
cord-276598-tm0yj2sn	226	5	product	product	NN
cord-276598-tm0yj2sn	226	6	gave	give	VBD
cord-276598-tm0yj2sn	226	7	79	79	CD
cord-276598-tm0yj2sn	226	8	%	%	NN
cord-276598-tm0yj2sn	226	9	yield	yield	NN
cord-276598-tm0yj2sn	226	10	.	.	.
cord-276598-tm0yj2sn	227	1	A	a	DT
cord-276598-tm0yj2sn	227	2	similar	similar	JJ
cord-276598-tm0yj2sn	227	3	method	method	NN
cord-276598-tm0yj2sn	227	4	,	,	,
cord-276598-tm0yj2sn	227	5	under	under	IN
cord-276598-tm0yj2sn	227	6	base	base	NN
cord-276598-tm0yj2sn	227	7	-	-	HYPH
cord-276598-tm0yj2sn	227	8	free	free	JJ
cord-276598-tm0yj2sn	227	9	reaction	reaction	NN
cord-276598-tm0yj2sn	227	10	conditions	condition	NNS
cord-276598-tm0yj2sn	227	11	,	,	,
cord-276598-tm0yj2sn	227	12	was	be	VBD
cord-276598-tm0yj2sn	227	13	achieved	achieve	VBN
cord-276598-tm0yj2sn	227	14	by	by	IN
cord-276598-tm0yj2sn	227	15	Kaboudin	Kaboudin	NNP
cord-276598-tm0yj2sn	227	16	et	et	NNP
cord-276598-tm0yj2sn	227	17	al	al	NNP
cord-276598-tm0yj2sn	227	18	.	.	.
cord-276598-tm0yj2sn	228	1	(	(	-LRB-
cord-276598-tm0yj2sn	228	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	228	3	6b	6b	CD
cord-276598-tm0yj2sn	228	4	)	)	-RRB-
cord-276598-tm0yj2sn	228	5	[	[	-LRB-
cord-276598-tm0yj2sn	228	6	98	98	CD
cord-276598-tm0yj2sn	228	7	]	]	-RRB-
cord-276598-tm0yj2sn	228	8	.	.	.
cord-276598-tm0yj2sn	229	1	The	the	DT
cord-276598-tm0yj2sn	229	2	scope	scope	NN
cord-276598-tm0yj2sn	229	3	of	of	IN
cord-276598-tm0yj2sn	229	4	the	the	DT
cord-276598-tm0yj2sn	229	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	229	6	was	be	VBD
cord-276598-tm0yj2sn	229	7	explored	explore	VBN
cord-276598-tm0yj2sn	229	8	with	with	IN
cord-276598-tm0yj2sn	229	9	(	(	-LRB-
cord-276598-tm0yj2sn	229	10	H	h	NN
cord-276598-tm0yj2sn	229	11	-	-	HYPH
cord-276598-tm0yj2sn	229	12	P	p	NN
cord-276598-tm0yj2sn	229	13	)	)	-RRB-
cord-276598-tm0yj2sn	230	1	(	(	-LRB-
cord-276598-tm0yj2sn	230	2	(	(	-LRB-
cord-276598-tm0yj2sn	230	3	RO	RO	NNP
cord-276598-tm0yj2sn	230	4	)	)	-RRB-
cord-276598-tm0yj2sn	230	5	2	2	CD
cord-276598-tm0yj2sn	230	6	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	230	7	;	;	:
cord-276598-tm0yj2sn	230	8	R	r	NN
cord-276598-tm0yj2sn	230	9	=	=	FW
cord-276598-tm0yj2sn	230	10	Et	et	NN
cord-276598-tm0yj2sn	230	11	,	,	,
cord-276598-tm0yj2sn	230	12	i	i	NN
cord-276598-tm0yj2sn	230	13	-	-	HYPH
cord-276598-tm0yj2sn	230	14	Pr	Pr	NNP
cord-276598-tm0yj2sn	230	15	)	)	-RRB-
cord-276598-tm0yj2sn	230	16	and	and	CC
cord-276598-tm0yj2sn	230	17	amine	amine	NN
cord-276598-tm0yj2sn	230	18	(	(	-LRB-
cord-276598-tm0yj2sn	230	19	e.g.	e.g.	RB
cord-276598-tm0yj2sn	230	20	,	,	,
cord-276598-tm0yj2sn	230	21	N	n	NN
cord-276598-tm0yj2sn	230	22	-	-	HYPH
cord-276598-tm0yj2sn	230	23	methylaniline	methylaniline	NNP
cord-276598-tm0yj2sn	230	24	,	,	,
cord-276598-tm0yj2sn	230	25	naphthalen-1-amine	naphthalen-1-amine	NNP
cord-276598-tm0yj2sn	230	26	,	,	,
cord-276598-tm0yj2sn	230	27	2-phenylethan-1-amine	2-phenylethan-1-amine	CD
cord-276598-tm0yj2sn	230	28	,	,	,
cord-276598-tm0yj2sn	230	29	3-chloro-2-methylaniline	3-chloro-2-methylaniline	CD
cord-276598-tm0yj2sn	230	30	,	,	,
cord-276598-tm0yj2sn	230	31	3-nitroaniline	3-nitroaniline	CD
cord-276598-tm0yj2sn	230	32	,	,	,
cord-276598-tm0yj2sn	230	33	benzylamine	benzylamine	JJ
cord-276598-tm0yj2sn	230	34	,	,	,
cord-276598-tm0yj2sn	230	35	or	or	CC
cord-276598-tm0yj2sn	230	36	aniline	aniline	NN
cord-276598-tm0yj2sn	230	37	)	)	-RRB-
cord-276598-tm0yj2sn	230	38	.	.	.
cord-276598-tm0yj2sn	231	1	The	the	DT
cord-276598-tm0yj2sn	231	2	crude	crude	JJ
cord-276598-tm0yj2sn	231	3	product	product	NN
cord-276598-tm0yj2sn	231	4	was	be	VBD
cord-276598-tm0yj2sn	231	5	purified	purify	VBN
cord-276598-tm0yj2sn	231	6	by	by	IN
cord-276598-tm0yj2sn	231	7	column	column	NN
cord-276598-tm0yj2sn	231	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	231	9	(	(	-LRB-
cord-276598-tm0yj2sn	231	10	on	on	IN
cord-276598-tm0yj2sn	231	11	silica	silica	NN
cord-276598-tm0yj2sn	231	12	)	)	-RRB-
cord-276598-tm0yj2sn	231	13	to	to	TO
cord-276598-tm0yj2sn	231	14	yield	yield	VB
cord-276598-tm0yj2sn	231	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	231	16	pure	pure	JJ
cord-276598-tm0yj2sn	231	17	products	product	NNS
cord-276598-tm0yj2sn	231	18	in	in	IN
cord-276598-tm0yj2sn	231	19	the	the	DT
cord-276598-tm0yj2sn	231	20	range	range	NN
cord-276598-tm0yj2sn	231	21	of	of	IN
cord-276598-tm0yj2sn	231	22	22	22	CD
cord-276598-tm0yj2sn	231	23	-	-	SYM
cord-276598-tm0yj2sn	231	24	92	92	CD
cord-276598-tm0yj2sn	231	25	%	%	NN
cord-276598-tm0yj2sn	231	26	.	.	.
cord-276598-tm0yj2sn	232	1	alkyl	alkyl	JJ
cord-276598-tm0yj2sn	232	2	)	)	-RRB-
cord-276598-tm0yj2sn	232	3	was	be	VBD
cord-276598-tm0yj2sn	232	4	possible	possible	JJ
cord-276598-tm0yj2sn	232	5	upon	upon	IN
cord-276598-tm0yj2sn	232	6	reacting	react	VBG
cord-276598-tm0yj2sn	232	7	with	with	IN
cord-276598-tm0yj2sn	232	8	trichloroisocyanuric	trichloroisocyanuric	NN
cord-276598-tm0yj2sn	232	9	acid	acid	NN
cord-276598-tm0yj2sn	232	10	(	(	-LRB-
cord-276598-tm0yj2sn	232	11	tCiC	tCiC	NNP
cord-276598-tm0yj2sn	232	12	-	-	HYPH
cord-276598-tm0yj2sn	232	13	A	a	NN
cord-276598-tm0yj2sn	232	14	;	;	:
cord-276598-tm0yj2sn	232	15	1	1	CD
cord-276598-tm0yj2sn	232	16	eq	eq	NN
cord-276598-tm0yj2sn	232	17	.	.	NNP
cord-276598-tm0yj2sn	232	18	)	)	-RRB-
cord-276598-tm0yj2sn	232	19	,	,	,
cord-276598-tm0yj2sn	232	20	which	which	WDT
cord-276598-tm0yj2sn	232	21	was	be	VBD
cord-276598-tm0yj2sn	232	22	then	then	RB
cord-276598-tm0yj2sn	232	23	treated	treat	VBN
cord-276598-tm0yj2sn	232	24	with	with	IN
cord-276598-tm0yj2sn	232	25	an	an	DT
cord-276598-tm0yj2sn	232	26	equal	equal	JJ
cord-276598-tm0yj2sn	232	27	mixture	mixture	NN
cord-276598-tm0yj2sn	232	28	of	of	IN
cord-276598-tm0yj2sn	232	29	amines	amine	NNS
cord-276598-tm0yj2sn	232	30	,	,	,
cord-276598-tm0yj2sn	232	31	R'R''NH	R'R''NH	NNS
cord-276598-tm0yj2sn	232	32	(	(	-LRB-
cord-276598-tm0yj2sn	232	33	R	r	NN
cord-276598-tm0yj2sn	232	34	'	'	''
cord-276598-tm0yj2sn	232	35	=	=	NFP
cord-276598-tm0yj2sn	233	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	233	2	,	,	,
cord-276598-tm0yj2sn	233	3	Et	Et	NNP
cord-276598-tm0yj2sn	233	4	,	,	,
cord-276598-tm0yj2sn	233	5	Pr	Pr	NNP
cord-276598-tm0yj2sn	233	6	;	;	:
cord-276598-tm0yj2sn	233	7	R	R	NNP
cord-276598-tm0yj2sn	233	8	'	'	''
cord-276598-tm0yj2sn	233	9	'	'	''
cord-276598-tm0yj2sn	233	10	=	=	SYM
cord-276598-tm0yj2sn	233	11	H	h	NN
cord-276598-tm0yj2sn	233	12	)	)	-RRB-
cord-276598-tm0yj2sn	233	13	and	and	CC
cord-276598-tm0yj2sn	233	14	Et3N	Et3N	NNP
cord-276598-tm0yj2sn	233	15	,	,	,
cord-276598-tm0yj2sn	233	16	to	to	TO
cord-276598-tm0yj2sn	233	17	form	form	VB
cord-276598-tm0yj2sn	233	18	the	the	DT
cord-276598-tm0yj2sn	233	19	P	P	NNP
cord-276598-tm0yj2sn	233	20	-	-	HYPH
cord-276598-tm0yj2sn	233	21	N	n	CD
cord-276598-tm0yj2sn	233	22	in	in	IN
cord-276598-tm0yj2sn	233	23	82	82	CD
cord-276598-tm0yj2sn	233	24	-	-	SYM
cord-276598-tm0yj2sn	233	25	92	92	CD
cord-276598-tm0yj2sn	233	26	%	%	NN
cord-276598-tm0yj2sn	233	27	yield	yield	NN
cord-276598-tm0yj2sn	233	28	,	,	,
cord-276598-tm0yj2sn	233	29	which	which	WDT
cord-276598-tm0yj2sn	233	30	was	be	VBD
cord-276598-tm0yj2sn	233	31	determined	determine	VBN
cord-276598-tm0yj2sn	233	32	as	as	IN
cord-276598-tm0yj2sn	233	33	conversions	conversion	NNS
cord-276598-tm0yj2sn	233	34	by	by	IN
cord-276598-tm0yj2sn	233	35	31	31	CD
cord-276598-tm0yj2sn	233	36	P	p	NN
cord-276598-tm0yj2sn	233	37	NMR	nmr	NN
cord-276598-tm0yj2sn	233	38	spectroscopy	spectroscopy	NN
cord-276598-tm0yj2sn	233	39	.	.	.
cord-276598-tm0yj2sn	234	1	However	however	RB
cord-276598-tm0yj2sn	234	2	,	,	,
cord-276598-tm0yj2sn	234	3	the	the	DT
cord-276598-tm0yj2sn	234	4	isolation	isolation	NN
cord-276598-tm0yj2sn	234	5	of	of	IN
cord-276598-tm0yj2sn	234	6	(	(	-LRB-
cord-276598-tm0yj2sn	234	7	RO)2P(O)NR'R	RO)2P(O)NR'R	``
cord-276598-tm0yj2sn	234	8	"	"	''
cord-276598-tm0yj2sn	234	9	(	(	-LRB-
cord-276598-tm0yj2sn	234	10	R	r	NN
cord-276598-tm0yj2sn	234	11	=	=	FW
cord-276598-tm0yj2sn	234	12	Et	et	NN
cord-276598-tm0yj2sn	234	13	,	,	,
cord-276598-tm0yj2sn	234	14	R	R	NNP
cord-276598-tm0yj2sn	234	15	'	'	''
cord-276598-tm0yj2sn	234	16	,	,	,
cord-276598-tm0yj2sn	234	17	R	r	NN
cord-276598-tm0yj2sn	234	18	"	"	''
cord-276598-tm0yj2sn	234	19	=	=	FW
cord-276598-tm0yj2sn	234	20	Et	et	NN
cord-276598-tm0yj2sn	234	21	,	,	,
cord-276598-tm0yj2sn	234	22	Pr	pr	NN
cord-276598-tm0yj2sn	234	23	)	)	-RRB-
cord-276598-tm0yj2sn	234	24	product	product	NN
cord-276598-tm0yj2sn	234	25	gave	give	VBD
cord-276598-tm0yj2sn	234	26	79	79	CD
cord-276598-tm0yj2sn	234	27	%	%	NN
cord-276598-tm0yj2sn	234	28	yield	yield	NN
cord-276598-tm0yj2sn	234	29	.	.	.
cord-276598-tm0yj2sn	235	1	A	a	DT
cord-276598-tm0yj2sn	235	2	similar	similar	JJ
cord-276598-tm0yj2sn	235	3	method	method	NN
cord-276598-tm0yj2sn	235	4	,	,	,
cord-276598-tm0yj2sn	235	5	under	under	IN
cord-276598-tm0yj2sn	235	6	base	base	NN
cord-276598-tm0yj2sn	235	7	-	-	HYPH
cord-276598-tm0yj2sn	235	8	free	free	JJ
cord-276598-tm0yj2sn	235	9	reaction	reaction	NN
cord-276598-tm0yj2sn	235	10	conditions	condition	NNS
cord-276598-tm0yj2sn	235	11	,	,	,
cord-276598-tm0yj2sn	235	12	was	be	VBD
cord-276598-tm0yj2sn	235	13	achieved	achieve	VBN
cord-276598-tm0yj2sn	235	14	by	by	IN
cord-276598-tm0yj2sn	235	15	Kaboudin	Kaboudin	NNP
cord-276598-tm0yj2sn	235	16	et	et	NNP
cord-276598-tm0yj2sn	235	17	al	al	NNP
cord-276598-tm0yj2sn	235	18	.	.	.
cord-276598-tm0yj2sn	236	1	(	(	-LRB-
cord-276598-tm0yj2sn	236	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	236	3	6b	6b	CD
cord-276598-tm0yj2sn	236	4	)	)	-RRB-
cord-276598-tm0yj2sn	236	5	[	[	-LRB-
cord-276598-tm0yj2sn	236	6	98	98	CD
cord-276598-tm0yj2sn	236	7	]	]	-RRB-
cord-276598-tm0yj2sn	236	8	.	.	.
cord-276598-tm0yj2sn	237	1	The	the	DT
cord-276598-tm0yj2sn	237	2	scope	scope	NN
cord-276598-tm0yj2sn	237	3	of	of	IN
cord-276598-tm0yj2sn	237	4	the	the	DT
cord-276598-tm0yj2sn	237	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	237	6	was	be	VBD
cord-276598-tm0yj2sn	237	7	explored	explore	VBN
cord-276598-tm0yj2sn	237	8	with	with	IN
cord-276598-tm0yj2sn	237	9	(	(	-LRB-
cord-276598-tm0yj2sn	237	10	H	h	NN
cord-276598-tm0yj2sn	237	11	-	-	HYPH
cord-276598-tm0yj2sn	237	12	P	p	NN
cord-276598-tm0yj2sn	237	13	)	)	-RRB-
cord-276598-tm0yj2sn	237	14	(	(	-LRB-
cord-276598-tm0yj2sn	237	15	(	(	-LRB-
cord-276598-tm0yj2sn	237	16	RO)2P(O)H	ro)2p(o)h	NN
cord-276598-tm0yj2sn	237	17	;	;	.
cord-276598-tm0yj2sn	238	1	R	r	NN
cord-276598-tm0yj2sn	238	2	=	=	FW
cord-276598-tm0yj2sn	238	3	Et	Et	NNP
cord-276598-tm0yj2sn	238	4	,	,	,
cord-276598-tm0yj2sn	238	5	i	i	NN
cord-276598-tm0yj2sn	238	6	-	-	HYPH
cord-276598-tm0yj2sn	238	7	Pr	Pr	NNP
cord-276598-tm0yj2sn	238	8	)	)	-RRB-
cord-276598-tm0yj2sn	238	9	and	and	CC
cord-276598-tm0yj2sn	238	10	amine	amine	NN
cord-276598-tm0yj2sn	238	11	(	(	-LRB-
cord-276598-tm0yj2sn	238	12	e.g.	e.g.	RB
cord-276598-tm0yj2sn	238	13	,	,	,
cord-276598-tm0yj2sn	238	14	N	n	NN
cord-276598-tm0yj2sn	238	15	-	-	HYPH
cord-276598-tm0yj2sn	238	16	methylaniline	methylaniline	NNP
cord-276598-tm0yj2sn	238	17	,	,	,
cord-276598-tm0yj2sn	238	18	naphthalen-1-amine	naphthalen-1-amine	NNP
cord-276598-tm0yj2sn	238	19	,	,	,
cord-276598-tm0yj2sn	238	20	2-phenylethan-1-amine	2-phenylethan-1-amine	CD
cord-276598-tm0yj2sn	238	21	,	,	,
cord-276598-tm0yj2sn	238	22	3-chloro-2-methylaniline	3-chloro-2-methylaniline	CD
cord-276598-tm0yj2sn	238	23	,	,	,
cord-276598-tm0yj2sn	238	24	3-nitroaniline	3-nitroaniline	CD
cord-276598-tm0yj2sn	238	25	,	,	,
cord-276598-tm0yj2sn	238	26	benzylamine	benzylamine	JJ
cord-276598-tm0yj2sn	238	27	,	,	,
cord-276598-tm0yj2sn	238	28	or	or	CC
cord-276598-tm0yj2sn	238	29	aniline	aniline	NN
cord-276598-tm0yj2sn	238	30	)	)	-RRB-
cord-276598-tm0yj2sn	238	31	.	.	.
cord-276598-tm0yj2sn	239	1	The	the	DT
cord-276598-tm0yj2sn	239	2	crude	crude	JJ
cord-276598-tm0yj2sn	239	3	product	product	NN
cord-276598-tm0yj2sn	239	4	was	be	VBD
cord-276598-tm0yj2sn	239	5	purified	purify	VBN
cord-276598-tm0yj2sn	239	6	by	by	IN
cord-276598-tm0yj2sn	239	7	column	column	NN
cord-276598-tm0yj2sn	239	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	239	9	(	(	-LRB-
cord-276598-tm0yj2sn	239	10	on	on	IN
cord-276598-tm0yj2sn	239	11	silica	silica	NN
cord-276598-tm0yj2sn	239	12	)	)	-RRB-
cord-276598-tm0yj2sn	239	13	to	to	TO
cord-276598-tm0yj2sn	239	14	yield	yield	VB
cord-276598-tm0yj2sn	239	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	239	16	pure	pure	JJ
cord-276598-tm0yj2sn	239	17	products	product	NNS
cord-276598-tm0yj2sn	239	18	in	in	IN
cord-276598-tm0yj2sn	239	19	the	the	DT
cord-276598-tm0yj2sn	239	20	range	range	NN
cord-276598-tm0yj2sn	239	21	of	of	IN
cord-276598-tm0yj2sn	239	22	22	22	CD
cord-276598-tm0yj2sn	239	23	-	-	SYM
cord-276598-tm0yj2sn	239	24	92	92	CD
cord-276598-tm0yj2sn	239	25	%	%	NN
cord-276598-tm0yj2sn	239	26	.	.	.
cord-276598-tm0yj2sn	240	1	Jang	Jang	NNP
cord-276598-tm0yj2sn	240	2	and	and	CC
cord-276598-tm0yj2sn	240	3	coworkers	coworker	NNS
cord-276598-tm0yj2sn	240	4	reported	report	VBD
cord-276598-tm0yj2sn	240	5	a	a	DT
cord-276598-tm0yj2sn	240	6	facile	facile	JJ
cord-276598-tm0yj2sn	240	7	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	240	8	route	route	NN
cord-276598-tm0yj2sn	240	9	to	to	TO
cord-276598-tm0yj2sn	240	10	form	form	VB
cord-276598-tm0yj2sn	240	11	P	p	NN
cord-276598-tm0yj2sn	240	12	-	-	HYPH
cord-276598-tm0yj2sn	240	13	Ns	Ns	NNP
cord-276598-tm0yj2sn	240	14	using	use	VBG
cord-276598-tm0yj2sn	240	15	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	240	16	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	240	17	acid	acid	NN
cord-276598-tm0yj2sn	240	18	(	(	-LRB-
cord-276598-tm0yj2sn	240	19	dPPA	dPPA	NNP
cord-276598-tm0yj2sn	240	20	)	)	-RRB-
cord-276598-tm0yj2sn	240	21	and	and	CC
cord-276598-tm0yj2sn	240	22	an	an	DT
cord-276598-tm0yj2sn	240	23	amine	amine	NN
cord-276598-tm0yj2sn	240	24	in	in	IN
cord-276598-tm0yj2sn	240	25	the	the	DT
cord-276598-tm0yj2sn	240	26	presence	presence	NN
cord-276598-tm0yj2sn	240	27	of	of	IN
cord-276598-tm0yj2sn	240	28	both	both	CC
cord-276598-tm0yj2sn	240	29	a	a	DT
cord-276598-tm0yj2sn	240	30	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	240	31	agent	agent	NN
cord-276598-tm0yj2sn	240	32	(	(	-LRB-
cord-276598-tm0yj2sn	240	33	Cl3CCN	Cl3CCN	NNP
cord-276598-tm0yj2sn	240	34	)	)	-RRB-
cord-276598-tm0yj2sn	240	35	and	and	CC
cord-276598-tm0yj2sn	240	36	a	a	DT
cord-276598-tm0yj2sn	240	37	base	base	NN
cord-276598-tm0yj2sn	240	38	(	(	-LRB-
cord-276598-tm0yj2sn	240	39	Et3N	Et3N	NNP
cord-276598-tm0yj2sn	240	40	)	)	-RRB-
cord-276598-tm0yj2sn	240	41	,	,	,
cord-276598-tm0yj2sn	240	42	which	which	WDT
cord-276598-tm0yj2sn	240	43	was	be	VBD
cord-276598-tm0yj2sn	240	44	added	add	VBN
cord-276598-tm0yj2sn	240	45	to	to	TO
cord-276598-tm0yj2sn	240	46	sequester	sequester	VB
cord-276598-tm0yj2sn	240	47	the	the	DT
cord-276598-tm0yj2sn	240	48	acid	acid	NN
cord-276598-tm0yj2sn	240	49	formed	form	VBN
cord-276598-tm0yj2sn	240	50	during	during	IN
cord-276598-tm0yj2sn	240	51	the	the	DT
cord-276598-tm0yj2sn	240	52	reaction	reaction	NN
cord-276598-tm0yj2sn	240	53	(	(	-LRB-
cord-276598-tm0yj2sn	240	54	Scheme	scheme	NN
cord-276598-tm0yj2sn	240	55	6c	6c	CD
cord-276598-tm0yj2sn	240	56	)	)	-RRB-
cord-276598-tm0yj2sn	240	57	[	[	-LRB-
cord-276598-tm0yj2sn	240	58	99	99	CD
cord-276598-tm0yj2sn	240	59	]	]	-RRB-
cord-276598-tm0yj2sn	240	60	.	.	.
cord-276598-tm0yj2sn	241	1	The	the	DT
cord-276598-tm0yj2sn	241	2	applicability	applicability	NN
cord-276598-tm0yj2sn	241	3	of	of	IN
cord-276598-tm0yj2sn	241	4	the	the	DT
cord-276598-tm0yj2sn	241	5	method	method	NN
cord-276598-tm0yj2sn	241	6	was	be	VBD
cord-276598-tm0yj2sn	241	7	explored	explore	VBN
cord-276598-tm0yj2sn	241	8	using	use	VBG
cord-276598-tm0yj2sn	241	9	prop-2-en-1-amine	prop-2-en-1-amine	NN
cord-276598-tm0yj2sn	241	10	,	,	,
cord-276598-tm0yj2sn	241	11	diethylamine	diethylamine	NNP
cord-276598-tm0yj2sn	241	12	,	,	,
cord-276598-tm0yj2sn	241	13	2-methylpropan-2-amine	2-methylpropan-2-amine	CD
cord-276598-tm0yj2sn	241	14	,	,	,
cord-276598-tm0yj2sn	241	15	cyclohexylamine	cyclohexylamine	NN
cord-276598-tm0yj2sn	241	16	,	,	,
cord-276598-tm0yj2sn	241	17	piperidine	piperidine	NN
cord-276598-tm0yj2sn	241	18	,	,	,
cord-276598-tm0yj2sn	241	19	morpholine	morpholine	NN
cord-276598-tm0yj2sn	241	20	,	,	,
cord-276598-tm0yj2sn	241	21	and	and	CC
cord-276598-tm0yj2sn	241	22	aniline	aniline	NN
cord-276598-tm0yj2sn	241	23	.	.	.
cord-276598-tm0yj2sn	242	1	The	the	DT
cord-276598-tm0yj2sn	242	2	crude	crude	JJ
cord-276598-tm0yj2sn	242	3	product	product	NN
cord-276598-tm0yj2sn	242	4	was	be	VBD
cord-276598-tm0yj2sn	242	5	purified	purify	VBN
cord-276598-tm0yj2sn	242	6	by	by	IN
cord-276598-tm0yj2sn	242	7	column	column	NN
cord-276598-tm0yj2sn	242	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	242	9	(	(	-LRB-
cord-276598-tm0yj2sn	242	10	on	on	IN
cord-276598-tm0yj2sn	242	11	silica	silica	NN
cord-276598-tm0yj2sn	242	12	)	)	-RRB-
cord-276598-tm0yj2sn	242	13	to	to	TO
cord-276598-tm0yj2sn	242	14	obtain	obtain	VB
cord-276598-tm0yj2sn	242	15	isolated	isolated	JJ
cord-276598-tm0yj2sn	242	16	yields	yield	NNS
cord-276598-tm0yj2sn	242	17	of	of	IN
cord-276598-tm0yj2sn	242	18	P	p	NN
cord-276598-tm0yj2sn	242	19	-	-	HYPH
cord-276598-tm0yj2sn	242	20	N	n	CD
cord-276598-tm0yj2sn	242	21	products	product	NNS
cord-276598-tm0yj2sn	242	22	in	in	IN
cord-276598-tm0yj2sn	242	23	the	the	DT
cord-276598-tm0yj2sn	242	24	range	range	NN
cord-276598-tm0yj2sn	242	25	of	of	IN
cord-276598-tm0yj2sn	242	26	53	53	CD
cord-276598-tm0yj2sn	242	27	-	-	SYM
cord-276598-tm0yj2sn	242	28	93	93	CD
cord-276598-tm0yj2sn	242	29	%	%	NN
cord-276598-tm0yj2sn	242	30	.	.	.
cord-276598-tm0yj2sn	243	1	A	a	DT
cord-276598-tm0yj2sn	243	2	similar	similar	JJ
cord-276598-tm0yj2sn	243	3	chlorination	chlorination	NN
cord-276598-tm0yj2sn	243	4	method	method	NN
cord-276598-tm0yj2sn	243	5	reacting	react	VBG
cord-276598-tm0yj2sn	243	6	an	an	DT
cord-276598-tm0yj2sn	243	7	amine	amine	NN
cord-276598-tm0yj2sn	243	8	(	(	-LRB-
cord-276598-tm0yj2sn	243	9	e.g.	e.g.	RB
cord-276598-tm0yj2sn	243	10	,	,	,
cord-276598-tm0yj2sn	243	11	aniline	aniline	NN
cord-276598-tm0yj2sn	243	12	,	,	,
cord-276598-tm0yj2sn	243	13	hexylamine	hexylamine	NNP
cord-276598-tm0yj2sn	243	14	,	,	,
cord-276598-tm0yj2sn	243	15	diethylamine	diethylamine	NNP
cord-276598-tm0yj2sn	243	16	,	,	,
cord-276598-tm0yj2sn	243	17	and	and	CC
cord-276598-tm0yj2sn	243	18	methanamine	methanamine	NN
cord-276598-tm0yj2sn	243	19	)	)	-RRB-
cord-276598-tm0yj2sn	243	20	with	with	IN
cord-276598-tm0yj2sn	243	21	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	243	22	acid	acid	NN
cord-276598-tm0yj2sn	243	23	(	(	-LRB-
cord-276598-tm0yj2sn	243	24	(	(	-LRB-
cord-276598-tm0yj2sn	243	25	R2P(O)OH	r2p(o)oh	NN
cord-276598-tm0yj2sn	243	26	;	;	:
cord-276598-tm0yj2sn	243	27	R	r	NN
cord-276598-tm0yj2sn	243	28	=	=	SYM
cord-276598-tm0yj2sn	243	29	OEt	OEt	NNS
cord-276598-tm0yj2sn	243	30	,	,	,
cord-276598-tm0yj2sn	243	31	OBu	OBu	NNS
cord-276598-tm0yj2sn	243	32	,	,	,
cord-276598-tm0yj2sn	243	33	OBn	OBn	NNS
cord-276598-tm0yj2sn	243	34	)	)	-RRB-
cord-276598-tm0yj2sn	243	35	in	in	IN
cord-276598-tm0yj2sn	243	36	the	the	DT
cord-276598-tm0yj2sn	243	37	presence	presence	NN
cord-276598-tm0yj2sn	243	38	of	of	IN
cord-276598-tm0yj2sn	243	39	triphenylphosphine	triphenylphosphine	NN
cord-276598-tm0yj2sn	243	40	and	and	CC
cord-276598-tm0yj2sn	243	41	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	243	42	was	be	VBD
cord-276598-tm0yj2sn	243	43	also	also	RB
cord-276598-tm0yj2sn	243	44	used	use	VBN
cord-276598-tm0yj2sn	243	45	to	to	TO
cord-276598-tm0yj2sn	243	46	synthesize	synthesize	VB
cord-276598-tm0yj2sn	243	47	P	p	NN
cord-276598-tm0yj2sn	243	48	-	-	HYPH
cord-276598-tm0yj2sn	243	49	Ns	Ns	NNP
cord-276598-tm0yj2sn	243	50	(	(	-LRB-
cord-276598-tm0yj2sn	243	51	Scheme	scheme	NN
cord-276598-tm0yj2sn	243	52	6d	6d	CD
cord-276598-tm0yj2sn	243	53	)	)	-RRB-
cord-276598-tm0yj2sn	243	54	[	[	-LRB-
cord-276598-tm0yj2sn	243	55	86	86	CD
cord-276598-tm0yj2sn	243	56	]	]	-RRB-
cord-276598-tm0yj2sn	243	57	.	.	.
cord-276598-tm0yj2sn	244	1	The	the	DT
cord-276598-tm0yj2sn	244	2	isolated	isolated	JJ
cord-276598-tm0yj2sn	244	3	yields	yield	NNS
cord-276598-tm0yj2sn	244	4	of	of	IN
cord-276598-tm0yj2sn	244	5	the	the	DT
cord-276598-tm0yj2sn	244	6	products	product	NNS
cord-276598-tm0yj2sn	244	7	in	in	IN
cord-276598-tm0yj2sn	244	8	this	this	DT
cord-276598-tm0yj2sn	244	9	case	case	NN
cord-276598-tm0yj2sn	244	10	were	be	VBD
cord-276598-tm0yj2sn	244	11	in	in	IN
cord-276598-tm0yj2sn	244	12	the	the	DT
cord-276598-tm0yj2sn	244	13	range	range	NN
cord-276598-tm0yj2sn	244	14	of	of	IN
cord-276598-tm0yj2sn	244	15	30	30	CD
cord-276598-tm0yj2sn	244	16	-	-	SYM
cord-276598-tm0yj2sn	244	17	75	75	CD
cord-276598-tm0yj2sn	244	18	%	%	NN
cord-276598-tm0yj2sn	244	19	.	.	.
cord-276598-tm0yj2sn	245	1	P	p	NN
cord-276598-tm0yj2sn	245	2	-	-	HYPH
cord-276598-tm0yj2sn	245	3	N	n	CD
cord-276598-tm0yj2sn	245	4	synthesis	synthesis	NN
cord-276598-tm0yj2sn	245	5	via	via	IN
cord-276598-tm0yj2sn	245	6	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	245	7	cross	cross	NN
cord-276598-tm0yj2sn	245	8	-	-	NN
cord-276598-tm0yj2sn	245	9	coupling	coupling	JJ
cord-276598-tm0yj2sn	245	10	using	use	VBG
cord-276598-tm0yj2sn	245	11	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	245	12	agents	agent	NNS
cord-276598-tm0yj2sn	245	13	offers	offer	VBZ
cord-276598-tm0yj2sn	245	14	a	a	DT
cord-276598-tm0yj2sn	245	15	short	short	JJ
cord-276598-tm0yj2sn	245	16	reaction	reaction	NN
cord-276598-tm0yj2sn	245	17	time	time	NN
cord-276598-tm0yj2sn	245	18	,	,	,
cord-276598-tm0yj2sn	245	19	low	low	JJ
cord-276598-tm0yj2sn	245	20	temperature	temperature	NN
cord-276598-tm0yj2sn	245	21	synthesis	synthesis	NN
cord-276598-tm0yj2sn	245	22	,	,	,
cord-276598-tm0yj2sn	245	23	and	and	CC
cord-276598-tm0yj2sn	245	24	a	a	DT
cord-276598-tm0yj2sn	245	25	diverse	diverse	JJ
cord-276598-tm0yj2sn	245	26	choice	choice	NN
cord-276598-tm0yj2sn	245	27	of	of	IN
cord-276598-tm0yj2sn	245	28	phosphorylating	phosphorylate	VBG
cord-276598-tm0yj2sn	245	29	reagents	reagent	NNS
cord-276598-tm0yj2sn	245	30	.	.	.
cord-276598-tm0yj2sn	246	1	Nevertheless	nevertheless	RB
cord-276598-tm0yj2sn	246	2	,	,	,
cord-276598-tm0yj2sn	246	3	the	the	DT
cord-276598-tm0yj2sn	246	4	methods	method	NNS
cord-276598-tm0yj2sn	246	5	use	use	VBP
cord-276598-tm0yj2sn	246	6	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	246	7	chlorinating	chlorinating	NN
cord-276598-tm0yj2sn	246	8	agents	agent	NNS
cord-276598-tm0yj2sn	246	9	such	such	JJ
cord-276598-tm0yj2sn	246	10	as	as	IN
cord-276598-tm0yj2sn	246	11	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	246	12	and	and	CC
cord-276598-tm0yj2sn	246	13	Cl3CCN	Cl3CCN	NNP
cord-276598-tm0yj2sn	246	14	,	,	,
cord-276598-tm0yj2sn	246	15	generate	generate	VBP
cord-276598-tm0yj2sn	246	16	large	large	JJ
cord-276598-tm0yj2sn	246	17	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	246	18	wastes	waste	NNS
cord-276598-tm0yj2sn	246	19	,	,	,
cord-276598-tm0yj2sn	246	20	and	and	CC
cord-276598-tm0yj2sn	246	21	involve	involve	VBP
cord-276598-tm0yj2sn	246	22	a	a	DT
cord-276598-tm0yj2sn	246	23	pre	pre	JJ
cord-276598-tm0yj2sn	246	24	-	-	NN
cord-276598-tm0yj2sn	246	25	functionalization	functionalization	JJ
cord-276598-tm0yj2sn	246	26	step	step	NN
cord-276598-tm0yj2sn	246	27	in	in	IN
cord-276598-tm0yj2sn	246	28	the	the	DT
cord-276598-tm0yj2sn	246	29	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	246	30	process	process	NN
cord-276598-tm0yj2sn	246	31	.	.	.
cord-276598-tm0yj2sn	246	32	 	 	_SP
cord-276598-tm0yj2sn	247	1	The	the	DT
cord-276598-tm0yj2sn	247	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	247	3	of	of	IN
cord-276598-tm0yj2sn	247	4	P	p	NN
cord-276598-tm0yj2sn	247	5	-	-	HYPH
cord-276598-tm0yj2sn	247	6	Ns	Ns	NNP
cord-276598-tm0yj2sn	247	7	from	from	IN
cord-276598-tm0yj2sn	247	8	amines	amine	NNS
cord-276598-tm0yj2sn	247	9	(	(	-LRB-
cord-276598-tm0yj2sn	247	10	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	247	11	and	and	CC
cord-276598-tm0yj2sn	247	12	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	247	13	)	)	-RRB-
cord-276598-tm0yj2sn	247	14	and	and	CC
cord-276598-tm0yj2sn	247	15	symmetrical	symmetrical	JJ
cord-276598-tm0yj2sn	247	16	trialkyl	trialkyl	NN
cord-276598-tm0yj2sn	247	17	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	247	18	(	(	-LRB-
cord-276598-tm0yj2sn	247	19	P(OR)3	p(or)3	CD
cord-276598-tm0yj2sn	247	20	;	;	:
cord-276598-tm0yj2sn	248	1	R=	R=	VBZ
cord-276598-tm0yj2sn	248	2	Me	-PRON-	PRP
cord-276598-tm0yj2sn	248	3	,	,	,
cord-276598-tm0yj2sn	248	4	Et	Et	NNP
cord-276598-tm0yj2sn	248	5	,	,	,
cord-276598-tm0yj2sn	248	6	i	i	NN
cord-276598-tm0yj2sn	248	7	-	-	HYPH
cord-276598-tm0yj2sn	248	8	Pr	Pr	NNP
cord-276598-tm0yj2sn	248	9	)	)	-RRB-
cord-276598-tm0yj2sn	248	10	in	in	IN
cord-276598-tm0yj2sn	248	11	the	the	DT
cord-276598-tm0yj2sn	248	12	presence	presence	NN
cord-276598-tm0yj2sn	248	13	I2	I2	NNP
cord-276598-tm0yj2sn	248	14	was	be	VBD
cord-276598-tm0yj2sn	248	15	reported	report	VBN
cord-276598-tm0yj2sn	248	16	by	by	IN
cord-276598-tm0yj2sn	248	17	Chen	Chen	NNP
cord-276598-tm0yj2sn	248	18	et	et	NNP
cord-276598-tm0yj2sn	248	19	al	al	NNP
cord-276598-tm0yj2sn	248	20	.	.	.
cord-276598-tm0yj2sn	249	1	[	[	-LRB-
cord-276598-tm0yj2sn	249	2	100	100	CD
cord-276598-tm0yj2sn	249	3	]	]	-RRB-
cord-276598-tm0yj2sn	249	4	.	.	.
cord-276598-tm0yj2sn	250	1	Crude	crude	JJ
cord-276598-tm0yj2sn	250	2	products	product	NNS
cord-276598-tm0yj2sn	250	3	were	be	VBD
cord-276598-tm0yj2sn	250	4	purified	purify	VBN
cord-276598-tm0yj2sn	250	5	by	by	IN
cord-276598-tm0yj2sn	250	6	column	column	NN
cord-276598-tm0yj2sn	250	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	250	8	(	(	-LRB-
cord-276598-tm0yj2sn	250	9	on	on	IN
cord-276598-tm0yj2sn	250	10	silica	silica	NN
cord-276598-tm0yj2sn	250	11	)	)	-RRB-
cord-276598-tm0yj2sn	250	12	and	and	CC
cord-276598-tm0yj2sn	250	13	resulted	result	VBD
cord-276598-tm0yj2sn	250	14	in	in	IN
cord-276598-tm0yj2sn	250	15	yields	yield	NNS
cord-276598-tm0yj2sn	250	16	in	in	IN
cord-276598-tm0yj2sn	250	17	the	the	DT
cord-276598-tm0yj2sn	250	18	range	range	NN
cord-276598-tm0yj2sn	250	19	of	of	IN
cord-276598-tm0yj2sn	250	20	0	0	CD
cord-276598-tm0yj2sn	250	21	-	-	SYM
cord-276598-tm0yj2sn	250	22	95	95	CD
cord-276598-tm0yj2sn	250	23	%	%	NN
cord-276598-tm0yj2sn	250	24	.	.	.
cord-276598-tm0yj2sn	251	1	For	for	IN
cord-276598-tm0yj2sn	251	2	the	the	DT
cord-276598-tm0yj2sn	251	3	low	low	JJ
cord-276598-tm0yj2sn	251	4	yielding	yield	VBG
cord-276598-tm0yj2sn	251	5	derivatives	derivative	NNS
cord-276598-tm0yj2sn	251	6	,	,	,
cord-276598-tm0yj2sn	251	7	the	the	DT
cord-276598-tm0yj2sn	251	8	reaction	reaction	NN
cord-276598-tm0yj2sn	251	9	was	be	VBD
cord-276598-tm0yj2sn	251	10	more	more	RBR
cord-276598-tm0yj2sn	251	11	selective	selective	JJ
cord-276598-tm0yj2sn	251	12	to	to	IN
cord-276598-tm0yj2sn	251	13	three	three	CD
cord-276598-tm0yj2sn	251	14	identified	identify	VBN
cord-276598-tm0yj2sn	251	15	by	by	IN
cord-276598-tm0yj2sn	251	16	-	-	HYPH
cord-276598-tm0yj2sn	251	17	products	product	NNS
cord-276598-tm0yj2sn	251	18	,	,	,
cord-276598-tm0yj2sn	251	19	H	H	NNP
cord-276598-tm0yj2sn	251	20	-	-	HYPH
cord-276598-tm0yj2sn	251	21	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	251	22	,	,	,
cord-276598-tm0yj2sn	251	23	trialkyl	trialkyl	JJ
cord-276598-tm0yj2sn	251	24	phosphate	phosphate	NN
cord-276598-tm0yj2sn	251	25	,	,	,
cord-276598-tm0yj2sn	251	26	and	and	CC
cord-276598-tm0yj2sn	251	27	tetraalkyl	tetraalkyl	NN
cord-276598-tm0yj2sn	251	28	diphosphate	diphosphate	NN
cord-276598-tm0yj2sn	251	29	,	,	,
cord-276598-tm0yj2sn	251	30	as	as	RB
cord-276598-tm0yj2sn	251	31	well	well	RB
cord-276598-tm0yj2sn	251	32	as	as	IN
cord-276598-tm0yj2sn	251	33	some	some	DT
cord-276598-tm0yj2sn	251	34	other	other	JJ
cord-276598-tm0yj2sn	251	35	unidentified	unidentified	JJ
cord-276598-tm0yj2sn	251	36	Jang	Jang	NNP
cord-276598-tm0yj2sn	251	37	and	and	CC
cord-276598-tm0yj2sn	251	38	coworkers	coworker	NNS
cord-276598-tm0yj2sn	251	39	reported	report	VBD
cord-276598-tm0yj2sn	251	40	a	a	DT
cord-276598-tm0yj2sn	251	41	facile	facile	JJ
cord-276598-tm0yj2sn	251	42	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	251	43	route	route	NN
cord-276598-tm0yj2sn	251	44	to	to	TO
cord-276598-tm0yj2sn	251	45	form	form	VB
cord-276598-tm0yj2sn	251	46	P	p	NN
cord-276598-tm0yj2sn	251	47	-	-	HYPH
cord-276598-tm0yj2sn	251	48	Ns	Ns	NNP
cord-276598-tm0yj2sn	251	49	using	use	VBG
cord-276598-tm0yj2sn	251	50	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	251	51	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	251	52	acid	acid	NN
cord-276598-tm0yj2sn	251	53	(	(	-LRB-
cord-276598-tm0yj2sn	251	54	dPPA	dPPA	NNP
cord-276598-tm0yj2sn	251	55	)	)	-RRB-
cord-276598-tm0yj2sn	251	56	and	and	CC
cord-276598-tm0yj2sn	251	57	an	an	DT
cord-276598-tm0yj2sn	251	58	amine	amine	NN
cord-276598-tm0yj2sn	251	59	in	in	IN
cord-276598-tm0yj2sn	251	60	the	the	DT
cord-276598-tm0yj2sn	251	61	presence	presence	NN
cord-276598-tm0yj2sn	251	62	of	of	IN
cord-276598-tm0yj2sn	251	63	both	both	CC
cord-276598-tm0yj2sn	251	64	a	a	DT
cord-276598-tm0yj2sn	251	65	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	251	66	agent	agent	NN
cord-276598-tm0yj2sn	251	67	(	(	-LRB-
cord-276598-tm0yj2sn	251	68	Cl	Cl	NNP
cord-276598-tm0yj2sn	251	69	3	3	CD
cord-276598-tm0yj2sn	251	70	CCN	CCN	NNP
cord-276598-tm0yj2sn	251	71	)	)	-RRB-
cord-276598-tm0yj2sn	251	72	and	and	CC
cord-276598-tm0yj2sn	251	73	a	a	DT
cord-276598-tm0yj2sn	251	74	base	base	NN
cord-276598-tm0yj2sn	251	75	(	(	-LRB-
cord-276598-tm0yj2sn	251	76	Et	Et	NNP
cord-276598-tm0yj2sn	251	77	3	3	CD
cord-276598-tm0yj2sn	251	78	N	N	NNP
cord-276598-tm0yj2sn	251	79	)	)	-RRB-
cord-276598-tm0yj2sn	251	80	,	,	,
cord-276598-tm0yj2sn	251	81	which	which	WDT
cord-276598-tm0yj2sn	251	82	was	be	VBD
cord-276598-tm0yj2sn	251	83	added	add	VBN
cord-276598-tm0yj2sn	251	84	to	to	TO
cord-276598-tm0yj2sn	251	85	sequester	sequester	VB
cord-276598-tm0yj2sn	251	86	the	the	DT
cord-276598-tm0yj2sn	251	87	acid	acid	NN
cord-276598-tm0yj2sn	251	88	formed	form	VBN
cord-276598-tm0yj2sn	251	89	during	during	IN
cord-276598-tm0yj2sn	251	90	the	the	DT
cord-276598-tm0yj2sn	251	91	reaction	reaction	NN
cord-276598-tm0yj2sn	251	92	(	(	-LRB-
cord-276598-tm0yj2sn	251	93	Scheme	scheme	NN
cord-276598-tm0yj2sn	251	94	6c	6c	CD
cord-276598-tm0yj2sn	251	95	)	)	-RRB-
cord-276598-tm0yj2sn	251	96	[	[	-LRB-
cord-276598-tm0yj2sn	251	97	99	99	CD
cord-276598-tm0yj2sn	251	98	]	]	-RRB-
cord-276598-tm0yj2sn	251	99	.	.	.
cord-276598-tm0yj2sn	252	1	The	the	DT
cord-276598-tm0yj2sn	252	2	applicability	applicability	NN
cord-276598-tm0yj2sn	252	3	of	of	IN
cord-276598-tm0yj2sn	252	4	the	the	DT
cord-276598-tm0yj2sn	252	5	method	method	NN
cord-276598-tm0yj2sn	252	6	was	be	VBD
cord-276598-tm0yj2sn	252	7	explored	explore	VBN
cord-276598-tm0yj2sn	252	8	using	use	VBG
cord-276598-tm0yj2sn	252	9	prop-2-en-1-amine	prop-2-en-1-amine	NN
cord-276598-tm0yj2sn	252	10	,	,	,
cord-276598-tm0yj2sn	252	11	diethylamine	diethylamine	NNP
cord-276598-tm0yj2sn	252	12	,	,	,
cord-276598-tm0yj2sn	252	13	2-methylpropan-2-amine	2-methylpropan-2-amine	CD
cord-276598-tm0yj2sn	252	14	,	,	,
cord-276598-tm0yj2sn	252	15	cyclohexylamine	cyclohexylamine	NN
cord-276598-tm0yj2sn	252	16	,	,	,
cord-276598-tm0yj2sn	252	17	piperidine	piperidine	NN
cord-276598-tm0yj2sn	252	18	,	,	,
cord-276598-tm0yj2sn	252	19	morpholine	morpholine	NN
cord-276598-tm0yj2sn	252	20	,	,	,
cord-276598-tm0yj2sn	252	21	and	and	CC
cord-276598-tm0yj2sn	252	22	aniline	aniline	NN
cord-276598-tm0yj2sn	252	23	.	.	.
cord-276598-tm0yj2sn	253	1	The	the	DT
cord-276598-tm0yj2sn	253	2	crude	crude	JJ
cord-276598-tm0yj2sn	253	3	product	product	NN
cord-276598-tm0yj2sn	253	4	was	be	VBD
cord-276598-tm0yj2sn	253	5	purified	purify	VBN
cord-276598-tm0yj2sn	253	6	by	by	IN
cord-276598-tm0yj2sn	253	7	column	column	NN
cord-276598-tm0yj2sn	253	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	253	9	(	(	-LRB-
cord-276598-tm0yj2sn	253	10	on	on	IN
cord-276598-tm0yj2sn	253	11	silica	silica	NN
cord-276598-tm0yj2sn	253	12	)	)	-RRB-
cord-276598-tm0yj2sn	253	13	to	to	TO
cord-276598-tm0yj2sn	253	14	obtain	obtain	VB
cord-276598-tm0yj2sn	253	15	isolated	isolated	JJ
cord-276598-tm0yj2sn	253	16	yields	yield	NNS
cord-276598-tm0yj2sn	253	17	of	of	IN
cord-276598-tm0yj2sn	253	18	P	p	NN
cord-276598-tm0yj2sn	253	19	-	-	HYPH
cord-276598-tm0yj2sn	253	20	N	n	CD
cord-276598-tm0yj2sn	253	21	products	product	NNS
cord-276598-tm0yj2sn	253	22	in	in	IN
cord-276598-tm0yj2sn	253	23	the	the	DT
cord-276598-tm0yj2sn	253	24	range	range	NN
cord-276598-tm0yj2sn	253	25	of	of	IN
cord-276598-tm0yj2sn	253	26	53	53	CD
cord-276598-tm0yj2sn	253	27	-	-	SYM
cord-276598-tm0yj2sn	253	28	93	93	CD
cord-276598-tm0yj2sn	253	29	%	%	NN
cord-276598-tm0yj2sn	253	30	.	.	.
cord-276598-tm0yj2sn	254	1	A	a	DT
cord-276598-tm0yj2sn	254	2	similar	similar	JJ
cord-276598-tm0yj2sn	254	3	chlorination	chlorination	NN
cord-276598-tm0yj2sn	254	4	method	method	NN
cord-276598-tm0yj2sn	254	5	reacting	react	VBG
cord-276598-tm0yj2sn	254	6	an	an	DT
cord-276598-tm0yj2sn	254	7	amine	amine	NN
cord-276598-tm0yj2sn	254	8	(	(	-LRB-
cord-276598-tm0yj2sn	254	9	e.g.	e.g.	RB
cord-276598-tm0yj2sn	254	10	,	,	,
cord-276598-tm0yj2sn	254	11	aniline	aniline	NN
cord-276598-tm0yj2sn	254	12	,	,	,
cord-276598-tm0yj2sn	254	13	hexylamine	hexylamine	NNP
cord-276598-tm0yj2sn	254	14	,	,	,
cord-276598-tm0yj2sn	254	15	diethylamine	diethylamine	NNP
cord-276598-tm0yj2sn	254	16	,	,	,
cord-276598-tm0yj2sn	254	17	and	and	CC
cord-276598-tm0yj2sn	254	18	methanamine	methanamine	NN
cord-276598-tm0yj2sn	254	19	)	)	-RRB-
cord-276598-tm0yj2sn	254	20	with	with	IN
cord-276598-tm0yj2sn	254	21	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	254	22	acid	acid	NN
cord-276598-tm0yj2sn	254	23	(	(	-LRB-
cord-276598-tm0yj2sn	254	24	(	(	-LRB-
cord-276598-tm0yj2sn	254	25	R	R	NNP
cord-276598-tm0yj2sn	254	26	2	2	CD
cord-276598-tm0yj2sn	254	27	P(O)OH	p(o)oh	NN
cord-276598-tm0yj2sn	254	28	;	;	:
cord-276598-tm0yj2sn	254	29	R	r	NN
cord-276598-tm0yj2sn	254	30	=	=	SYM
cord-276598-tm0yj2sn	254	31	OEt	OEt	NNS
cord-276598-tm0yj2sn	254	32	,	,	,
cord-276598-tm0yj2sn	254	33	OBu	OBu	NNS
cord-276598-tm0yj2sn	254	34	,	,	,
cord-276598-tm0yj2sn	254	35	OBn	OBn	NNS
cord-276598-tm0yj2sn	254	36	)	)	-RRB-
cord-276598-tm0yj2sn	254	37	in	in	IN
cord-276598-tm0yj2sn	254	38	the	the	DT
cord-276598-tm0yj2sn	254	39	presence	presence	NN
cord-276598-tm0yj2sn	254	40	of	of	IN
cord-276598-tm0yj2sn	254	41	triphenylphosphine	triphenylphosphine	NN
cord-276598-tm0yj2sn	254	42	and	and	CC
cord-276598-tm0yj2sn	254	43	CCl	CCl	NNS
cord-276598-tm0yj2sn	254	44	4	4	CD
cord-276598-tm0yj2sn	254	45	was	be	VBD
cord-276598-tm0yj2sn	254	46	also	also	RB
cord-276598-tm0yj2sn	254	47	used	use	VBN
cord-276598-tm0yj2sn	254	48	to	to	TO
cord-276598-tm0yj2sn	254	49	synthesize	synthesize	VB
cord-276598-tm0yj2sn	254	50	P	p	NN
cord-276598-tm0yj2sn	254	51	-	-	HYPH
cord-276598-tm0yj2sn	254	52	Ns	Ns	NNP
cord-276598-tm0yj2sn	254	53	(	(	-LRB-
cord-276598-tm0yj2sn	254	54	Scheme	scheme	NN
cord-276598-tm0yj2sn	254	55	6d	6d	CD
cord-276598-tm0yj2sn	254	56	)	)	-RRB-
cord-276598-tm0yj2sn	255	1	[	[	-LRB-
cord-276598-tm0yj2sn	255	2	86	86	CD
cord-276598-tm0yj2sn	255	3	]	]	-RRB-
cord-276598-tm0yj2sn	255	4	.	.	.
cord-276598-tm0yj2sn	256	1	The	the	DT
cord-276598-tm0yj2sn	256	2	isolated	isolated	JJ
cord-276598-tm0yj2sn	256	3	yields	yield	NNS
cord-276598-tm0yj2sn	256	4	of	of	IN
cord-276598-tm0yj2sn	256	5	the	the	DT
cord-276598-tm0yj2sn	256	6	products	product	NNS
cord-276598-tm0yj2sn	256	7	in	in	IN
cord-276598-tm0yj2sn	256	8	this	this	DT
cord-276598-tm0yj2sn	256	9	case	case	NN
cord-276598-tm0yj2sn	256	10	were	be	VBD
cord-276598-tm0yj2sn	256	11	in	in	IN
cord-276598-tm0yj2sn	256	12	the	the	DT
cord-276598-tm0yj2sn	256	13	range	range	NN
cord-276598-tm0yj2sn	256	14	of	of	IN
cord-276598-tm0yj2sn	256	15	30	30	CD
cord-276598-tm0yj2sn	256	16	-	-	SYM
cord-276598-tm0yj2sn	256	17	75	75	CD
cord-276598-tm0yj2sn	256	18	%	%	NN
cord-276598-tm0yj2sn	256	19	.	.	.
cord-276598-tm0yj2sn	257	1	P	p	NN
cord-276598-tm0yj2sn	257	2	-	-	HYPH
cord-276598-tm0yj2sn	257	3	N	n	CD
cord-276598-tm0yj2sn	257	4	synthesis	synthesis	NN
cord-276598-tm0yj2sn	257	5	via	via	IN
cord-276598-tm0yj2sn	257	6	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	257	7	cross	cross	NN
cord-276598-tm0yj2sn	257	8	-	-	NN
cord-276598-tm0yj2sn	257	9	coupling	coupling	JJ
cord-276598-tm0yj2sn	257	10	using	use	VBG
cord-276598-tm0yj2sn	257	11	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	257	12	agents	agent	NNS
cord-276598-tm0yj2sn	257	13	offers	offer	VBZ
cord-276598-tm0yj2sn	257	14	a	a	DT
cord-276598-tm0yj2sn	257	15	short	short	JJ
cord-276598-tm0yj2sn	257	16	reaction	reaction	NN
cord-276598-tm0yj2sn	257	17	time	time	NN
cord-276598-tm0yj2sn	257	18	,	,	,
cord-276598-tm0yj2sn	257	19	low	low	JJ
cord-276598-tm0yj2sn	257	20	temperature	temperature	NN
cord-276598-tm0yj2sn	257	21	synthesis	synthesis	NN
cord-276598-tm0yj2sn	257	22	,	,	,
cord-276598-tm0yj2sn	257	23	and	and	CC
cord-276598-tm0yj2sn	257	24	a	a	DT
cord-276598-tm0yj2sn	257	25	diverse	diverse	JJ
cord-276598-tm0yj2sn	257	26	choice	choice	NN
cord-276598-tm0yj2sn	257	27	of	of	IN
cord-276598-tm0yj2sn	257	28	phosphorylating	phosphorylate	VBG
cord-276598-tm0yj2sn	257	29	reagents	reagent	NNS
cord-276598-tm0yj2sn	257	30	.	.	.
cord-276598-tm0yj2sn	258	1	Nevertheless	nevertheless	RB
cord-276598-tm0yj2sn	258	2	,	,	,
cord-276598-tm0yj2sn	258	3	the	the	DT
cord-276598-tm0yj2sn	258	4	methods	method	NNS
cord-276598-tm0yj2sn	258	5	use	use	VBP
cord-276598-tm0yj2sn	258	6	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	258	7	chlorinating	chlorinating	NN
cord-276598-tm0yj2sn	258	8	agents	agent	NNS
cord-276598-tm0yj2sn	258	9	such	such	JJ
cord-276598-tm0yj2sn	258	10	as	as	IN
cord-276598-tm0yj2sn	258	11	CCl	CCl	NNS
cord-276598-tm0yj2sn	258	12	4	4	CD
cord-276598-tm0yj2sn	258	13	and	and	CC
cord-276598-tm0yj2sn	258	14	Cl	Cl	NNP
cord-276598-tm0yj2sn	258	15	3	3	CD
cord-276598-tm0yj2sn	258	16	CCN	CCN	NNP
cord-276598-tm0yj2sn	258	17	,	,	,
cord-276598-tm0yj2sn	258	18	generate	generate	VB
cord-276598-tm0yj2sn	258	19	large	large	JJ
cord-276598-tm0yj2sn	258	20	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	258	21	wastes	waste	NNS
cord-276598-tm0yj2sn	258	22	,	,	,
cord-276598-tm0yj2sn	258	23	and	and	CC
cord-276598-tm0yj2sn	258	24	involve	involve	VBP
cord-276598-tm0yj2sn	258	25	a	a	DT
cord-276598-tm0yj2sn	258	26	pre	pre	JJ
cord-276598-tm0yj2sn	258	27	-	-	NN
cord-276598-tm0yj2sn	258	28	functionalization	functionalization	JJ
cord-276598-tm0yj2sn	258	29	step	step	NN
cord-276598-tm0yj2sn	258	30	in	in	IN
cord-276598-tm0yj2sn	258	31	the	the	DT
cord-276598-tm0yj2sn	258	32	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	258	33	process	process	NN
cord-276598-tm0yj2sn	258	34	.	.	.
cord-276598-tm0yj2sn	259	1	The	the	DT
cord-276598-tm0yj2sn	259	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	259	3	of	of	IN
cord-276598-tm0yj2sn	259	4	P	p	NN
cord-276598-tm0yj2sn	259	5	-	-	HYPH
cord-276598-tm0yj2sn	259	6	Ns	Ns	NNP
cord-276598-tm0yj2sn	259	7	from	from	IN
cord-276598-tm0yj2sn	259	8	amines	amine	NNS
cord-276598-tm0yj2sn	259	9	(	(	-LRB-
cord-276598-tm0yj2sn	259	10	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	259	11	and	and	CC
cord-276598-tm0yj2sn	259	12	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	259	13	)	)	-RRB-
cord-276598-tm0yj2sn	259	14	and	and	CC
cord-276598-tm0yj2sn	259	15	symmetrical	symmetrical	JJ
cord-276598-tm0yj2sn	259	16	trialkyl	trialkyl	NN
cord-276598-tm0yj2sn	259	17	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	259	18	(	(	-LRB-
cord-276598-tm0yj2sn	259	19	P(OR	P(OR	NNP
cord-276598-tm0yj2sn	260	1	)	)	-RRB-
cord-276598-tm0yj2sn	260	2	3	3	LS
cord-276598-tm0yj2sn	260	3	;	;	:
cord-276598-tm0yj2sn	260	4	R=	R=	VBZ
cord-276598-tm0yj2sn	260	5	Me	-PRON-	PRP
cord-276598-tm0yj2sn	260	6	,	,	,
cord-276598-tm0yj2sn	260	7	Et	Et	NNP
cord-276598-tm0yj2sn	260	8	,	,	,
cord-276598-tm0yj2sn	260	9	i	i	NN
cord-276598-tm0yj2sn	260	10	-	-	HYPH
cord-276598-tm0yj2sn	260	11	Pr	Pr	NNP
cord-276598-tm0yj2sn	260	12	)	)	-RRB-
cord-276598-tm0yj2sn	260	13	in	in	IN
cord-276598-tm0yj2sn	260	14	the	the	DT
cord-276598-tm0yj2sn	260	15	presence	presence	NN
cord-276598-tm0yj2sn	260	16	I	-PRON-	PRP
cord-276598-tm0yj2sn	260	17	2	2	CD
cord-276598-tm0yj2sn	260	18	was	be	VBD
cord-276598-tm0yj2sn	260	19	reported	report	VBN
cord-276598-tm0yj2sn	260	20	by	by	IN
cord-276598-tm0yj2sn	260	21	Chen	Chen	NNP
cord-276598-tm0yj2sn	260	22	et	et	NNP
cord-276598-tm0yj2sn	260	23	al	al	NNP
cord-276598-tm0yj2sn	260	24	.	.	.
cord-276598-tm0yj2sn	261	1	[	[	-LRB-
cord-276598-tm0yj2sn	261	2	100	100	CD
cord-276598-tm0yj2sn	261	3	]	]	-RRB-
cord-276598-tm0yj2sn	261	4	.	.	.
cord-276598-tm0yj2sn	262	1	Crude	crude	JJ
cord-276598-tm0yj2sn	262	2	products	product	NNS
cord-276598-tm0yj2sn	262	3	were	be	VBD
cord-276598-tm0yj2sn	262	4	purified	purify	VBN
cord-276598-tm0yj2sn	262	5	by	by	IN
cord-276598-tm0yj2sn	262	6	column	column	NN
cord-276598-tm0yj2sn	262	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	262	8	(	(	-LRB-
cord-276598-tm0yj2sn	262	9	on	on	IN
cord-276598-tm0yj2sn	262	10	silica	silica	NN
cord-276598-tm0yj2sn	262	11	)	)	-RRB-
cord-276598-tm0yj2sn	262	12	and	and	CC
cord-276598-tm0yj2sn	262	13	resulted	result	VBD
cord-276598-tm0yj2sn	262	14	in	in	IN
cord-276598-tm0yj2sn	262	15	yields	yield	NNS
cord-276598-tm0yj2sn	262	16	in	in	IN
cord-276598-tm0yj2sn	262	17	the	the	DT
cord-276598-tm0yj2sn	262	18	range	range	NN
cord-276598-tm0yj2sn	262	19	of	of	IN
cord-276598-tm0yj2sn	262	20	0	0	CD
cord-276598-tm0yj2sn	262	21	-	-	SYM
cord-276598-tm0yj2sn	262	22	95	95	CD
cord-276598-tm0yj2sn	262	23	%	%	NN
cord-276598-tm0yj2sn	262	24	.	.	.
cord-276598-tm0yj2sn	263	1	For	for	IN
cord-276598-tm0yj2sn	263	2	the	the	DT
cord-276598-tm0yj2sn	263	3	low	low	JJ
cord-276598-tm0yj2sn	263	4	yielding	yield	VBG
cord-276598-tm0yj2sn	263	5	derivatives	derivative	NNS
cord-276598-tm0yj2sn	263	6	,	,	,
cord-276598-tm0yj2sn	263	7	the	the	DT
cord-276598-tm0yj2sn	263	8	reaction	reaction	NN
cord-276598-tm0yj2sn	263	9	was	be	VBD
cord-276598-tm0yj2sn	263	10	more	more	RBR
cord-276598-tm0yj2sn	263	11	selective	selective	JJ
cord-276598-tm0yj2sn	263	12	to	to	IN
cord-276598-tm0yj2sn	263	13	three	three	CD
cord-276598-tm0yj2sn	263	14	identified	identify	VBN
cord-276598-tm0yj2sn	263	15	by	by	IN
cord-276598-tm0yj2sn	263	16	-	-	HYPH
cord-276598-tm0yj2sn	263	17	products	product	NNS
cord-276598-tm0yj2sn	263	18	,	,	,
cord-276598-tm0yj2sn	263	19	H	H	NNP
cord-276598-tm0yj2sn	263	20	-	-	HYPH
cord-276598-tm0yj2sn	263	21	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	263	22	,	,	,
cord-276598-tm0yj2sn	263	23	trialkyl	trialkyl	JJ
cord-276598-tm0yj2sn	263	24	phosphate	phosphate	NN
cord-276598-tm0yj2sn	263	25	,	,	,
cord-276598-tm0yj2sn	263	26	and	and	CC
cord-276598-tm0yj2sn	263	27	tetraalkyl	tetraalkyl	NN
cord-276598-tm0yj2sn	263	28	diphosphate	diphosphate	NN
cord-276598-tm0yj2sn	263	29	,	,	,
cord-276598-tm0yj2sn	263	30	as	as	RB
cord-276598-tm0yj2sn	263	31	well	well	RB
cord-276598-tm0yj2sn	263	32	as	as	IN
cord-276598-tm0yj2sn	263	33	some	some	DT
cord-276598-tm0yj2sn	263	34	other	other	JJ
cord-276598-tm0yj2sn	263	35	unidentified	unidentified	JJ
cord-276598-tm0yj2sn	263	36	by	by	IN
cord-276598-tm0yj2sn	263	37	-	-	HYPH
cord-276598-tm0yj2sn	263	38	products	product	NNS
cord-276598-tm0yj2sn	263	39	.	.	.
cord-276598-tm0yj2sn	264	1	Important	important	JJ
cord-276598-tm0yj2sn	264	2	compounds	compound	NNS
cord-276598-tm0yj2sn	264	3	such	such	JJ
cord-276598-tm0yj2sn	264	4	as	as	IN
cord-276598-tm0yj2sn	264	5	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	264	6	amino	amino	NN
cord-276598-tm0yj2sn	264	7	acid	acid	NN
cord-276598-tm0yj2sn	264	8	esters	ester	NNS
cord-276598-tm0yj2sn	264	9	(	(	-LRB-
cord-276598-tm0yj2sn	264	10	8)	8)	NNP
cord-276598-tm0yj2sn	264	11	(	(	-LRB-
cord-276598-tm0yj2sn	264	12	9	9	CD
cord-276598-tm0yj2sn	264	13	)	)	-RRB-
cord-276598-tm0yj2sn	264	14	(	(	-LRB-
cord-276598-tm0yj2sn	264	15	10	10	CD
cord-276598-tm0yj2sn	264	16	)	)	-RRB-
cord-276598-tm0yj2sn	264	17	(	(	-LRB-
cord-276598-tm0yj2sn	264	18	11	11	CD
cord-276598-tm0yj2sn	264	19	)	)	-RRB-
cord-276598-tm0yj2sn	264	20	were	be	VBD
cord-276598-tm0yj2sn	264	21	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	264	22	using	use	VBG
cord-276598-tm0yj2sn	264	23	the	the	DT
cord-276598-tm0yj2sn	264	24	iodine	iodine	NN
cord-276598-tm0yj2sn	264	25	-	-	HYPH
cord-276598-tm0yj2sn	264	26	mediated	mediate	VBN
cord-276598-tm0yj2sn	264	27	method	method	NN
cord-276598-tm0yj2sn	264	28	(	(	-LRB-
cord-276598-tm0yj2sn	264	29	Figure	figure	NN
cord-276598-tm0yj2sn	264	30	5	5	CD
cord-276598-tm0yj2sn	264	31	)	)	-RRB-
cord-276598-tm0yj2sn	264	32	.	.	.
cord-276598-tm0yj2sn	265	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	265	2	2020	2020	CD
cord-276598-tm0yj2sn	265	3	,	,	,
cord-276598-tm0yj2sn	265	4	25	25	CD
cord-276598-tm0yj2sn	265	5	,	,	,
cord-276598-tm0yj2sn	265	6	x	x	NN
cord-276598-tm0yj2sn	265	7	FOR	for	IN
cord-276598-tm0yj2sn	265	8	PEER	PEER	NNP
cord-276598-tm0yj2sn	265	9	REVIEW	REVIEW	NNP
cord-276598-tm0yj2sn	265	10	10	10	CD
cord-276598-tm0yj2sn	265	11	of	of	IN
cord-276598-tm0yj2sn	265	12	37	37	CD
cord-276598-tm0yj2sn	265	13	by	by	IN
cord-276598-tm0yj2sn	265	14	-	-	HYPH
cord-276598-tm0yj2sn	265	15	products	product	NNS
cord-276598-tm0yj2sn	265	16	.	.	.
cord-276598-tm0yj2sn	266	1	Important	important	JJ
cord-276598-tm0yj2sn	266	2	compounds	compound	NNS
cord-276598-tm0yj2sn	266	3	such	such	JJ
cord-276598-tm0yj2sn	266	4	as	as	IN
cord-276598-tm0yj2sn	266	5	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	266	6	amino	amino	NN
cord-276598-tm0yj2sn	266	7	acid	acid	NN
cord-276598-tm0yj2sn	266	8	esters	ester	NNS
cord-276598-tm0yj2sn	266	9	(	(	-LRB-
cord-276598-tm0yj2sn	266	10	8)	8)	NNP
cord-276598-tm0yj2sn	266	11	(	(	-LRB-
cord-276598-tm0yj2sn	266	12	9	9	CD
cord-276598-tm0yj2sn	266	13	)	)	-RRB-
cord-276598-tm0yj2sn	266	14	(	(	-LRB-
cord-276598-tm0yj2sn	266	15	10	10	CD
cord-276598-tm0yj2sn	266	16	)	)	-RRB-
cord-276598-tm0yj2sn	266	17	(	(	-LRB-
cord-276598-tm0yj2sn	266	18	11	11	CD
cord-276598-tm0yj2sn	266	19	)	)	-RRB-
cord-276598-tm0yj2sn	266	20	were	be	VBD
cord-276598-tm0yj2sn	266	21	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	266	22	using	use	VBG
cord-276598-tm0yj2sn	266	23	the	the	DT
cord-276598-tm0yj2sn	266	24	iodine	iodine	NN
cord-276598-tm0yj2sn	266	25	-	-	HYPH
cord-276598-tm0yj2sn	266	26	mediated	mediate	VBN
cord-276598-tm0yj2sn	266	27	method	method	NN
cord-276598-tm0yj2sn	266	28	(	(	-LRB-
cord-276598-tm0yj2sn	266	29	Figure	figure	NN
cord-276598-tm0yj2sn	266	30	5	5	CD
cord-276598-tm0yj2sn	266	31	)	)	-RRB-
cord-276598-tm0yj2sn	266	32	.	.	.
cord-276598-tm0yj2sn	267	1	Structures	structure	NNS
cord-276598-tm0yj2sn	267	2	(	(	-LRB-
cord-276598-tm0yj2sn	267	3	11	11	CD
cord-276598-tm0yj2sn	267	4	)	)	-RRB-
cord-276598-tm0yj2sn	267	5	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	267	6	by	by	IN
cord-276598-tm0yj2sn	267	7	iodinating	iodinate	VBG
cord-276598-tm0yj2sn	267	8	agents	agent	NNS
cord-276598-tm0yj2sn	267	9	.	.	.
cord-276598-tm0yj2sn	268	1	Iodine	iodine	NN
cord-276598-tm0yj2sn	268	2	(	(	-LRB-
cord-276598-tm0yj2sn	268	3	I2	I2	NNP
cord-276598-tm0yj2sn	268	4	)	)	-RRB-
cord-276598-tm0yj2sn	268	5	has	have	VBZ
cord-276598-tm0yj2sn	268	6	also	also	RB
cord-276598-tm0yj2sn	268	7	been	be	VBN
cord-276598-tm0yj2sn	268	8	used	use	VBN
cord-276598-tm0yj2sn	268	9	as	as	IN
cord-276598-tm0yj2sn	268	10	a	a	DT
cord-276598-tm0yj2sn	268	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	268	12	under	under	IN
cord-276598-tm0yj2sn	268	13	solvent	solvent	NN
cord-276598-tm0yj2sn	268	14	-	-	HYPH
cord-276598-tm0yj2sn	268	15	free	free	JJ
cord-276598-tm0yj2sn	268	16	conditions	condition	NNS
cord-276598-tm0yj2sn	268	17	to	to	IN
cord-276598-tm0yj2sn	268	18	couple	couple	NN
cord-276598-tm0yj2sn	268	19	aryl	aryl	NN
cord-276598-tm0yj2sn	268	20	amines	amine	NNS
cord-276598-tm0yj2sn	268	21	(	(	-LRB-
cord-276598-tm0yj2sn	268	22	PhNH2	phnh2	NN
cord-276598-tm0yj2sn	268	23	and	and	CC
cord-276598-tm0yj2sn	268	24	derivatives	derivative	NNS
cord-276598-tm0yj2sn	268	25	containing	contain	VBG
cord-276598-tm0yj2sn	268	26	OH	oh	UH
cord-276598-tm0yj2sn	268	27	,	,	,
cord-276598-tm0yj2sn	268	28	OEt	OEt	NNS
cord-276598-tm0yj2sn	268	29	,	,	,
cord-276598-tm0yj2sn	268	30	CN	CN	NNP
cord-276598-tm0yj2sn	268	31	,	,	,
cord-276598-tm0yj2sn	268	32	OMe	OMe	NNS
cord-276598-tm0yj2sn	268	33	,	,	,
cord-276598-tm0yj2sn	268	34	NO2	NO2	NNP
cord-276598-tm0yj2sn	268	35	,	,	,
cord-276598-tm0yj2sn	268	36	F	F	NNP
cord-276598-tm0yj2sn	268	37	,	,	,
cord-276598-tm0yj2sn	268	38	Cl	Cl	NNP
cord-276598-tm0yj2sn	268	39	,	,	,
cord-276598-tm0yj2sn	268	40	or	or	CC
cord-276598-tm0yj2sn	268	41	Br	Br	NNP
cord-276598-tm0yj2sn	268	42	substituents	substituent	NNS
cord-276598-tm0yj2sn	268	43	on	on	IN
cord-276598-tm0yj2sn	268	44	Ph	Ph	NNP
cord-276598-tm0yj2sn	268	45	)	)	-RRB-
cord-276598-tm0yj2sn	268	46	with	with	IN
cord-276598-tm0yj2sn	268	47	(	(	-LRB-
cord-276598-tm0yj2sn	268	48	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	268	49	(	(	-LRB-
cord-276598-tm0yj2sn	268	50	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	268	51	H	H	NNP
cord-276598-tm0yj2sn	268	52	-	-	HYPH
cord-276598-tm0yj2sn	268	53	P	p	NN
cord-276598-tm0yj2sn	268	54	;	;	:
cord-276598-tm0yj2sn	268	55	R	r	NN
cord-276598-tm0yj2sn	268	56	=	=	NN
cord-276598-tm0yj2sn	269	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	269	2	,	,	,
cord-276598-tm0yj2sn	269	3	Et	Et	NNP
cord-276598-tm0yj2sn	269	4	)	)	-RRB-
cord-276598-tm0yj2sn	269	5	affording	afford	VBG
cord-276598-tm0yj2sn	269	6	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	269	7	P	P	NNP
cord-276598-tm0yj2sn	269	8	-	-	HYPH
cord-276598-tm0yj2sn	269	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	269	10	(	(	-LRB-
cord-276598-tm0yj2sn	269	11	Scheme	scheme	NN
cord-276598-tm0yj2sn	269	12	7b	7b	CD
cord-276598-tm0yj2sn	269	13	)	)	-RRB-
cord-276598-tm0yj2sn	269	14	[	[	-LRB-
cord-276598-tm0yj2sn	269	15	101	101	CD
cord-276598-tm0yj2sn	269	16	]	]	-RRB-
cord-276598-tm0yj2sn	269	17	.	.	.
cord-276598-tm0yj2sn	270	1	Then	then	RB
cord-276598-tm0yj2sn	270	2	,	,	,
cord-276598-tm0yj2sn	270	3	the	the	DT
cord-276598-tm0yj2sn	270	4	crude	crude	JJ
cord-276598-tm0yj2sn	270	5	products	product	NNS
cord-276598-tm0yj2sn	270	6	were	be	VBD
cord-276598-tm0yj2sn	270	7	purified	purify	VBN
cord-276598-tm0yj2sn	270	8	by	by	IN
cord-276598-tm0yj2sn	270	9	column	column	NN
cord-276598-tm0yj2sn	270	10	chromatography	chromatography	NN
cord-276598-tm0yj2sn	270	11	(	(	-LRB-
cord-276598-tm0yj2sn	270	12	on	on	IN
cord-276598-tm0yj2sn	270	13	silica	silica	NN
cord-276598-tm0yj2sn	270	14	)	)	-RRB-
cord-276598-tm0yj2sn	270	15	to	to	TO
cord-276598-tm0yj2sn	270	16	obtain	obtain	VB
cord-276598-tm0yj2sn	270	17	yields	yield	NNS
cord-276598-tm0yj2sn	270	18	of	of	IN
cord-276598-tm0yj2sn	270	19	product	product	NN
cord-276598-tm0yj2sn	270	20	in	in	IN
cord-276598-tm0yj2sn	270	21	0	0	CD
cord-276598-tm0yj2sn	270	22	-	-	SYM
cord-276598-tm0yj2sn	270	23	88	88	CD
cord-276598-tm0yj2sn	270	24	%	%	NN
cord-276598-tm0yj2sn	270	25	.	.	.
cord-276598-tm0yj2sn	271	1	The	the	DT
cord-276598-tm0yj2sn	271	2	best	good	JJS
cord-276598-tm0yj2sn	271	3	yielding	yielding	JJ
cord-276598-tm0yj2sn	271	4	conditions	condition	NNS
cord-276598-tm0yj2sn	271	5	were	be	VBD
cord-276598-tm0yj2sn	271	6	shorter	short	JJR
cord-276598-tm0yj2sn	271	7	reaction	reaction	NN
cord-276598-tm0yj2sn	271	8	times	time	NNS
cord-276598-tm0yj2sn	271	9	without	without	IN
cord-276598-tm0yj2sn	271	10	solvent	solvent	NN
cord-276598-tm0yj2sn	271	11	.	.	.
cord-276598-tm0yj2sn	272	1	Reactions	reaction	NNS
cord-276598-tm0yj2sn	272	2	performed	perform	VBN
cord-276598-tm0yj2sn	272	3	in	in	IN
cord-276598-tm0yj2sn	272	4	polar	polar	JJ
cord-276598-tm0yj2sn	272	5	non	non	JJ
cord-276598-tm0yj2sn	272	6	-	-	JJ
cord-276598-tm0yj2sn	272	7	protic	protic	JJ
cord-276598-tm0yj2sn	272	8	solvents	solvent	NNS
cord-276598-tm0yj2sn	272	9	(	(	-LRB-
cord-276598-tm0yj2sn	272	10	e.g.	e.g.	RB
cord-276598-tm0yj2sn	272	11	,	,	,
cord-276598-tm0yj2sn	272	12	CH2Cl2	ch2cl2	NN
cord-276598-tm0yj2sn	272	13	)	)	-RRB-
cord-276598-tm0yj2sn	272	14	,	,	,
cord-276598-tm0yj2sn	272	15	non	non	JJ
cord-276598-tm0yj2sn	272	16	-	-	JJ
cord-276598-tm0yj2sn	272	17	polar	polar	JJ
cord-276598-tm0yj2sn	272	18	solvents	solvent	NNS
cord-276598-tm0yj2sn	272	19	(	(	-LRB-
cord-276598-tm0yj2sn	272	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	272	21	,	,	,
cord-276598-tm0yj2sn	272	22	hexane	hexane	NNP
cord-276598-tm0yj2sn	272	23	)	)	-RRB-
cord-276598-tm0yj2sn	272	24	,	,	,
cord-276598-tm0yj2sn	272	25	or	or	CC
cord-276598-tm0yj2sn	272	26	protic	protic	JJ
cord-276598-tm0yj2sn	272	27	solvents	solvent	NNS
cord-276598-tm0yj2sn	272	28	(	(	-LRB-
cord-276598-tm0yj2sn	272	29	e.g.	e.g.	RB
cord-276598-tm0yj2sn	272	30	,	,	,
cord-276598-tm0yj2sn	272	31	MeOH	MeOH	NNP
cord-276598-tm0yj2sn	272	32	)	)	-RRB-
cord-276598-tm0yj2sn	272	33	all	all	DT
cord-276598-tm0yj2sn	272	34	suffered	suffer	VBD
cord-276598-tm0yj2sn	272	35	from	from	IN
cord-276598-tm0yj2sn	272	36	reduced	reduced	JJ
cord-276598-tm0yj2sn	272	37	efficiency	efficiency	NN
cord-276598-tm0yj2sn	272	38	and	and	CC
cord-276598-tm0yj2sn	272	39	selectivity	selectivity	NN
cord-276598-tm0yj2sn	272	40	.	.	.
cord-276598-tm0yj2sn	273	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	273	2	,	,	,
cord-276598-tm0yj2sn	273	3	aniline	aniline	NN
cord-276598-tm0yj2sn	273	4	with	with	IN
cord-276598-tm0yj2sn	273	5	substituents	substituent	NNS
cord-276598-tm0yj2sn	273	6	at	at	IN
cord-276598-tm0yj2sn	273	7	ortho	ortho	NNP
cord-276598-tm0yj2sn	273	8	-	-	HYPH
cord-276598-tm0yj2sn	273	9	and	and	CC
cord-276598-tm0yj2sn	273	10	meta	meta	NNP
cord-276598-tm0yj2sn	273	11	-	-	HYPH
cord-276598-tm0yj2sn	273	12	positions	position	NNS
cord-276598-tm0yj2sn	273	13	were	be	VBD
cord-276598-tm0yj2sn	273	14	observed	observe	VBN
cord-276598-tm0yj2sn	273	15	to	to	TO
cord-276598-tm0yj2sn	273	16	have	have	VB
cord-276598-tm0yj2sn	273	17	reacted	react	VBN
cord-276598-tm0yj2sn	273	18	faster	fast	RBR
cord-276598-tm0yj2sn	273	19	and	and	CC
cord-276598-tm0yj2sn	273	20	were	be	VBD
cord-276598-tm0yj2sn	273	21	higher	high	JJR
cord-276598-tm0yj2sn	273	22	yielding	yield	VBG
cord-276598-tm0yj2sn	273	23	than	than	IN
cord-276598-tm0yj2sn	273	24	aniline	aniline	NN
cord-276598-tm0yj2sn	273	25	containing	contain	VBG
cord-276598-tm0yj2sn	273	26	substituents	substituent	NNS
cord-276598-tm0yj2sn	273	27	at	at	IN
cord-276598-tm0yj2sn	273	28	the	the	DT
cord-276598-tm0yj2sn	273	29	para	para	NNP
cord-276598-tm0yj2sn	273	30	-	-	HYPH
cord-276598-tm0yj2sn	273	31	position	position	NN
cord-276598-tm0yj2sn	273	32	.	.	.
cord-276598-tm0yj2sn	274	1	I2	I2	NNP
cord-276598-tm0yj2sn	274	2	was	be	VBD
cord-276598-tm0yj2sn	274	3	used	use	VBN
cord-276598-tm0yj2sn	274	4	in	in	IN
cord-276598-tm0yj2sn	274	5	the	the	DT
cord-276598-tm0yj2sn	274	6	presence	presence	NN
cord-276598-tm0yj2sn	274	7	of	of	IN
cord-276598-tm0yj2sn	274	8	H2O2	H2O2	NNP
cord-276598-tm0yj2sn	274	9	as	as	IN
cord-276598-tm0yj2sn	274	10	a	a	DT
cord-276598-tm0yj2sn	274	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	274	12	at	at	IN
cord-276598-tm0yj2sn	274	13	20	20	CD
cord-276598-tm0yj2sn	274	14	°	°	NN
cord-276598-tm0yj2sn	274	15	C	c	NN
cord-276598-tm0yj2sn	274	16	for	for	IN
cord-276598-tm0yj2sn	274	17	the	the	DT
cord-276598-tm0yj2sn	274	18	dehydrogenative	dehydrogenative	JJ
cord-276598-tm0yj2sn	274	19	cross	cross	NN
cord-276598-tm0yj2sn	274	20	-	-	NN
cord-276598-tm0yj2sn	274	21	coupling	coupling	NN
cord-276598-tm0yj2sn	274	22	of	of	IN
cord-276598-tm0yj2sn	274	23	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	274	24	H	H	NNP
cord-276598-tm0yj2sn	274	25	-	-	HYPH
cord-276598-tm0yj2sn	274	26	P	p	NN
cord-276598-tm0yj2sn	274	27	and	and	CC
cord-276598-tm0yj2sn	274	28	amine	amine	NN
cord-276598-tm0yj2sn	274	29	or	or	CC
cord-276598-tm0yj2sn	274	30	sulfoximines	sulfoximine	NNS
cord-276598-tm0yj2sn	274	31	to	to	TO
cord-276598-tm0yj2sn	274	32	form	form	VB
cord-276598-tm0yj2sn	274	33	P	p	NN
cord-276598-tm0yj2sn	274	34	-	-	HYPH
cord-276598-tm0yj2sn	274	35	Ns	Ns	NNP
cord-276598-tm0yj2sn	274	36	(	(	-LRB-
cord-276598-tm0yj2sn	274	37	Scheme	scheme	NN
cord-276598-tm0yj2sn	274	38	7c	7c	CD
cord-276598-tm0yj2sn	274	39	)	)	-RRB-
cord-276598-tm0yj2sn	274	40	[	[	-LRB-
cord-276598-tm0yj2sn	274	41	102	102	CD
cord-276598-tm0yj2sn	274	42	]	]	-RRB-
cord-276598-tm0yj2sn	274	43	.	.	.
cord-276598-tm0yj2sn	275	1	Purification	purification	NN
cord-276598-tm0yj2sn	275	2	of	of	IN
cord-276598-tm0yj2sn	275	3	the	the	DT
cord-276598-tm0yj2sn	275	4	products	product	NNS
cord-276598-tm0yj2sn	275	5	by	by	IN
cord-276598-tm0yj2sn	275	6	column	column	NN
cord-276598-tm0yj2sn	275	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	275	8	(	(	-LRB-
cord-276598-tm0yj2sn	275	9	on	on	IN
cord-276598-tm0yj2sn	275	10	silica	silica	NN
cord-276598-tm0yj2sn	275	11	)	)	-RRB-
cord-276598-tm0yj2sn	275	12	afforded	afford	VBN
cord-276598-tm0yj2sn	275	13	P	p	NN
cord-276598-tm0yj2sn	275	14	-	-	HYPH
cord-276598-tm0yj2sn	275	15	Ns	Ns	NNP
cord-276598-tm0yj2sn	275	16	with	with	IN
cord-276598-tm0yj2sn	275	17	isolated	isolated	JJ
cord-276598-tm0yj2sn	275	18	yields	yield	NNS
cord-276598-tm0yj2sn	275	19	of	of	IN
cord-276598-tm0yj2sn	275	20	31	31	CD
cord-276598-tm0yj2sn	275	21	-	-	SYM
cord-276598-tm0yj2sn	275	22	96	96	CD
cord-276598-tm0yj2sn	275	23	%	%	NN
cord-276598-tm0yj2sn	275	24	,	,	,
cord-276598-tm0yj2sn	275	25	with	with	IN
cord-276598-tm0yj2sn	275	26	the	the	DT
cord-276598-tm0yj2sn	275	27	lower	lower	RBR
cord-276598-tm0yj2sn	275	28	yielding	yield	VBG
cord-276598-tm0yj2sn	275	29	products	product	NNS
cord-276598-tm0yj2sn	275	30	reported	report	VBN
cord-276598-tm0yj2sn	275	31	from	from	IN
cord-276598-tm0yj2sn	275	32	sulfoximine	sulfoximine	NNP
cord-276598-tm0yj2sn	275	33	.	.	.
cord-276598-tm0yj2sn	276	1	Both	both	DT
cord-276598-tm0yj2sn	276	2	alkyl	alkyl	NN
cord-276598-tm0yj2sn	276	3	and	and	CC
cord-276598-tm0yj2sn	276	4	aryl	aryl	NN
cord-276598-tm0yj2sn	276	5	H	H	NNP
cord-276598-tm0yj2sn	276	6	-	-	HYPH
cord-276598-tm0yj2sn	276	7	P	p	NN
cord-276598-tm0yj2sn	276	8	(	(	-LRB-
cord-276598-tm0yj2sn	276	9	(	(	-LRB-
cord-276598-tm0yj2sn	276	10	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	276	11	,	,	,
cord-276598-tm0yj2sn	276	12	R	r	NN
cord-276598-tm0yj2sn	276	13	=	=	FW
cord-276598-tm0yj2sn	276	14	Et	et	NN
cord-276598-tm0yj2sn	276	15	,	,	,
cord-276598-tm0yj2sn	276	16	i	i	NN
cord-276598-tm0yj2sn	276	17	-	-	HYPH
cord-276598-tm0yj2sn	276	18	Pr	Pr	NNP
cord-276598-tm0yj2sn	276	19	,	,	,
cord-276598-tm0yj2sn	276	20	Ph	Ph	NNP
cord-276598-tm0yj2sn	276	21	)	)	-RRB-
cord-276598-tm0yj2sn	276	22	were	be	VBD
cord-276598-tm0yj2sn	276	23	used	use	VBN
cord-276598-tm0yj2sn	276	24	as	as	IN
cord-276598-tm0yj2sn	276	25	the	the	DT
cord-276598-tm0yj2sn	276	26	substrate	substrate	NN
cord-276598-tm0yj2sn	276	27	along	along	IN
cord-276598-tm0yj2sn	276	28	with	with	IN
cord-276598-tm0yj2sn	276	29	cyclic	cyclic	JJ
cord-276598-tm0yj2sn	276	30	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	276	31	secondary	secondary	JJ
cord-276598-tm0yj2sn	276	32	amines	amine	NNS
cord-276598-tm0yj2sn	276	33	(	(	-LRB-
cord-276598-tm0yj2sn	276	34	e.g.	e.g.	RB
cord-276598-tm0yj2sn	276	35	,	,	,
cord-276598-tm0yj2sn	276	36	indole	indole	NN
cord-276598-tm0yj2sn	276	37	)	)	-RRB-
cord-276598-tm0yj2sn	276	38	,	,	,
cord-276598-tm0yj2sn	276	39	derivatives	derivative	NNS
cord-276598-tm0yj2sn	276	40	of	of	IN
cord-276598-tm0yj2sn	276	41	heterocyclic	heterocyclic	JJ
cord-276598-tm0yj2sn	276	42	amines	amine	NNS
cord-276598-tm0yj2sn	276	43	(	(	-LRB-
cord-276598-tm0yj2sn	276	44	e.g.	e.g.	RB
cord-276598-tm0yj2sn	276	45	,	,	,
cord-276598-tm0yj2sn	276	46	furfurylamine	furfurylamine	NN
cord-276598-tm0yj2sn	276	47	)	)	-RRB-
cord-276598-tm0yj2sn	276	48	,	,	,
cord-276598-tm0yj2sn	276	49	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	276	50	cyclic	cyclic	JJ
cord-276598-tm0yj2sn	276	51	secondary	secondary	JJ
cord-276598-tm0yj2sn	276	52	amines	amine	NNS
cord-276598-tm0yj2sn	276	53	(	(	-LRB-
cord-276598-tm0yj2sn	276	54	e.g.	e.g.	RB
cord-276598-tm0yj2sn	276	55	,	,	,
cord-276598-tm0yj2sn	276	56	1-benzhydrylpiperazine	1-benzhydrylpiperazine	CD
cord-276598-tm0yj2sn	276	57	)	)	-RRB-
cord-276598-tm0yj2sn	277	1	,	,	,
cord-276598-tm0yj2sn	277	2	tertiary	tertiary	JJ
cord-276598-tm0yj2sn	277	3	amines	amine	NNS
cord-276598-tm0yj2sn	277	4	(	(	-LRB-
cord-276598-tm0yj2sn	277	5	e.g.	e.g.	RB
cord-276598-tm0yj2sn	277	6	,	,	,
cord-276598-tm0yj2sn	277	7	N	N	NNP
cord-276598-tm0yj2sn	277	8	-	-	HYPH
cord-276598-tm0yj2sn	277	9	methylhomopiperazine	methylhomopiperazine	NNP
cord-276598-tm0yj2sn	277	10	)	)	-RRB-
cord-276598-tm0yj2sn	277	11	,	,	,
cord-276598-tm0yj2sn	277	12	or	or	CC
cord-276598-tm0yj2sn	277	13	sulfoximine	sulfoximine	NNP
cord-276598-tm0yj2sn	277	14	.	.	.
cord-276598-tm0yj2sn	278	1	According	accord	VBG
cord-276598-tm0yj2sn	278	2	to	to	IN
cord-276598-tm0yj2sn	278	3	the	the	DT
cord-276598-tm0yj2sn	278	4	article	article	NN
cord-276598-tm0yj2sn	278	5	,	,	,
cord-276598-tm0yj2sn	278	6	using	use	VBG
cord-276598-tm0yj2sn	278	7	other	other	JJ
cord-276598-tm0yj2sn	278	8	sources	source	NNS
cord-276598-tm0yj2sn	278	9	of	of	IN
cord-276598-tm0yj2sn	278	10	I2	I2	NNP
cord-276598-tm0yj2sn	278	11	such	such	JJ
cord-276598-tm0yj2sn	278	12	as	as	IN
cord-276598-tm0yj2sn	278	13	KI	KI	NNP
cord-276598-tm0yj2sn	278	14	or	or	CC
cord-276598-tm0yj2sn	278	15	N	N	NNP
cord-276598-tm0yj2sn	278	16	-	-	HYPH
cord-276598-tm0yj2sn	278	17	bromosuccinimide	bromosuccinimide	NN
cord-276598-tm0yj2sn	278	18	(	(	-LRB-
cord-276598-tm0yj2sn	278	19	NBS	NBS	NNP
cord-276598-tm0yj2sn	278	20	)	)	-RRB-
cord-276598-tm0yj2sn	278	21	for	for	IN
cord-276598-tm0yj2sn	278	22	the	the	DT
cord-276598-tm0yj2sn	278	23	reaction	reaction	NN
cord-276598-tm0yj2sn	278	24	resulted	result	VBD
cord-276598-tm0yj2sn	278	25	in	in	IN
cord-276598-tm0yj2sn	278	26	decreased	decreased	JJ
cord-276598-tm0yj2sn	278	27	yield	yield	NN
cord-276598-tm0yj2sn	278	28	and	and	CC
cord-276598-tm0yj2sn	278	29	trace	trace	NN
cord-276598-tm0yj2sn	278	30	quantities	quantity	NNS
cord-276598-tm0yj2sn	278	31	of	of	IN
cord-276598-tm0yj2sn	278	32	the	the	DT
cord-276598-tm0yj2sn	278	33	desired	desire	VBN
cord-276598-tm0yj2sn	278	34	products	product	NNS
cord-276598-tm0yj2sn	278	35	,	,	,
cord-276598-tm0yj2sn	278	36	respectively	respectively	RB
cord-276598-tm0yj2sn	278	37	.	.	.
cord-276598-tm0yj2sn	279	1	Iodine	iodine	NN
cord-276598-tm0yj2sn	279	2	-	-	HYPH
cord-276598-tm0yj2sn	279	3	mediated	mediate	VBN
cord-276598-tm0yj2sn	279	4	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	279	5	cross	cross	JJ
cord-276598-tm0yj2sn	279	6	-	-	JJ
cord-276598-tm0yj2sn	279	7	coupling	coupling	JJ
cord-276598-tm0yj2sn	279	8	methods	method	NNS
cord-276598-tm0yj2sn	279	9	offer	offer	VBP
cord-276598-tm0yj2sn	279	10	better	well	JJR
cord-276598-tm0yj2sn	279	11	routes	route	NNS
cord-276598-tm0yj2sn	279	12	to	to	IN
cord-276598-tm0yj2sn	279	13	P	P	NNP
cord-276598-tm0yj2sn	279	14	-	-	HYPH
cord-276598-tm0yj2sn	279	15	N	n	CD
cord-276598-tm0yj2sn	279	16	compounds	compound	NNS
cord-276598-tm0yj2sn	279	17	by	by	IN
cord-276598-tm0yj2sn	279	18	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	279	19	toxic	toxic	JJ
cord-276598-tm0yj2sn	279	20	halogenating	halogenating	NN
cord-276598-tm0yj2sn	279	21	agents	agent	NNS
cord-276598-tm0yj2sn	279	22	such	such	JJ
cord-276598-tm0yj2sn	279	23	as	as	IN
cord-276598-tm0yj2sn	279	24	CCl4	ccl4	NN
cord-276598-tm0yj2sn	279	25	in	in	IN
cord-276598-tm0yj2sn	279	26	the	the	DT
cord-276598-tm0yj2sn	279	27	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	279	28	processes	process	NNS
cord-276598-tm0yj2sn	279	29	.	.	.
cord-276598-tm0yj2sn	280	1	The	the	DT
cord-276598-tm0yj2sn	280	2	method	method	NN
cord-276598-tm0yj2sn	280	3	also	also	RB
cord-276598-tm0yj2sn	280	4	uses	use	VBZ
cord-276598-tm0yj2sn	280	5	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	280	6	oxidants	oxidant	NNS
cord-276598-tm0yj2sn	280	7	without	without	IN
cord-276598-tm0yj2sn	280	8	additives	additive	NNS
cord-276598-tm0yj2sn	280	9	and	and	CC
cord-276598-tm0yj2sn	280	10	generates	generate	VBZ
cord-276598-tm0yj2sn	280	11	water	water	NN
cord-276598-tm0yj2sn	280	12	or	or	CC
cord-276598-tm0yj2sn	280	13	alkanol	alkanol	NN
cord-276598-tm0yj2sn	280	14	as	as	IN
cord-276598-tm0yj2sn	280	15	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	280	16	waste	waste	NN
cord-276598-tm0yj2sn	280	17	.	.	.
cord-276598-tm0yj2sn	281	1	However	however	RB
cord-276598-tm0yj2sn	281	2	,	,	,
cord-276598-tm0yj2sn	281	3	the	the	DT
cord-276598-tm0yj2sn	281	4	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	281	5	routes	route	NNS
cord-276598-tm0yj2sn	281	6	are	be	VBP
cord-276598-tm0yj2sn	281	7	prone	prone	JJ
cord-276598-tm0yj2sn	281	8	to	to	IN
cord-276598-tm0yj2sn	281	9	the	the	DT
cord-276598-tm0yj2sn	281	10	formation	formation	NN
cord-276598-tm0yj2sn	281	11	of	of	IN
cord-276598-tm0yj2sn	281	12	many	many	JJ
cord-276598-tm0yj2sn	281	13	undesired	undesired	JJ
cord-276598-tm0yj2sn	281	14	side	side	NN
cord-276598-tm0yj2sn	281	15	products	product	NNS
cord-276598-tm0yj2sn	281	16	,	,	,
cord-276598-tm0yj2sn	281	17	suffer	suffer	VBP
cord-276598-tm0yj2sn	281	18	from	from	IN
cord-276598-tm0yj2sn	281	19	low	low	JJ
cord-276598-tm0yj2sn	281	20	yields	yield	NNS
cord-276598-tm0yj2sn	281	21	,	,	,
cord-276598-tm0yj2sn	281	22	and	and	CC
cord-276598-tm0yj2sn	281	23	sometimes	sometimes	RB
cord-276598-tm0yj2sn	281	24	have	have	VBP
cord-276598-tm0yj2sn	281	25	limited	limit	VBN
cord-276598-tm0yj2sn	281	26	applicability	applicability	NN
cord-276598-tm0yj2sn	281	27	.	.	.
cord-276598-tm0yj2sn	282	1	Iodine	iodine	NN
cord-276598-tm0yj2sn	282	2	(	(	-LRB-
cord-276598-tm0yj2sn	282	3	I	i	NN
cord-276598-tm0yj2sn	282	4	2	2	CD
cord-276598-tm0yj2sn	282	5	)	)	-RRB-
cord-276598-tm0yj2sn	282	6	has	have	VBZ
cord-276598-tm0yj2sn	282	7	also	also	RB
cord-276598-tm0yj2sn	282	8	been	be	VBN
cord-276598-tm0yj2sn	282	9	used	use	VBN
cord-276598-tm0yj2sn	282	10	as	as	IN
cord-276598-tm0yj2sn	282	11	a	a	DT
cord-276598-tm0yj2sn	282	12	catalyst	catalyst	NN
cord-276598-tm0yj2sn	282	13	under	under	IN
cord-276598-tm0yj2sn	282	14	solvent	solvent	NN
cord-276598-tm0yj2sn	282	15	-	-	HYPH
cord-276598-tm0yj2sn	282	16	free	free	JJ
cord-276598-tm0yj2sn	282	17	conditions	condition	NNS
cord-276598-tm0yj2sn	282	18	to	to	IN
cord-276598-tm0yj2sn	282	19	couple	couple	NN
cord-276598-tm0yj2sn	282	20	aryl	aryl	NN
cord-276598-tm0yj2sn	282	21	amines	amine	NNS
cord-276598-tm0yj2sn	282	22	(	(	-LRB-
cord-276598-tm0yj2sn	282	23	PhNH	PhNH	NNP
cord-276598-tm0yj2sn	282	24	2	2	CD
cord-276598-tm0yj2sn	282	25	and	and	CC
cord-276598-tm0yj2sn	282	26	derivatives	derivative	NNS
cord-276598-tm0yj2sn	282	27	containing	contain	VBG
cord-276598-tm0yj2sn	282	28	OH	oh	UH
cord-276598-tm0yj2sn	282	29	,	,	,
cord-276598-tm0yj2sn	282	30	OEt	OEt	NNS
cord-276598-tm0yj2sn	282	31	,	,	,
cord-276598-tm0yj2sn	282	32	CN	CN	NNP
cord-276598-tm0yj2sn	282	33	,	,	,
cord-276598-tm0yj2sn	282	34	OMe	OMe	NNS
cord-276598-tm0yj2sn	282	35	,	,	,
cord-276598-tm0yj2sn	282	36	NO	no	DT
cord-276598-tm0yj2sn	282	37	2	2	CD
cord-276598-tm0yj2sn	282	38	,	,	,
cord-276598-tm0yj2sn	282	39	F	F	NNP
cord-276598-tm0yj2sn	282	40	,	,	,
cord-276598-tm0yj2sn	282	41	Cl	Cl	NNP
cord-276598-tm0yj2sn	282	42	,	,	,
cord-276598-tm0yj2sn	282	43	or	or	CC
cord-276598-tm0yj2sn	282	44	Br	Br	NNP
cord-276598-tm0yj2sn	282	45	substituents	substituent	NNS
cord-276598-tm0yj2sn	282	46	on	on	IN
cord-276598-tm0yj2sn	282	47	Ph	Ph	NNP
cord-276598-tm0yj2sn	282	48	)	)	-RRB-
cord-276598-tm0yj2sn	282	49	with	with	IN
cord-276598-tm0yj2sn	282	50	(	(	-LRB-
cord-276598-tm0yj2sn	282	51	RO	ro	NN
cord-276598-tm0yj2sn	282	52	)	)	-RRB-
cord-276598-tm0yj2sn	282	53	2	2	CD
cord-276598-tm0yj2sn	283	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	284	1	(	(	-LRB-
cord-276598-tm0yj2sn	284	2	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	284	3	H	H	NNP
cord-276598-tm0yj2sn	284	4	-	-	HYPH
cord-276598-tm0yj2sn	284	5	P	p	NN
cord-276598-tm0yj2sn	284	6	;	;	:
cord-276598-tm0yj2sn	285	1	R	r	NN
cord-276598-tm0yj2sn	285	2	=	=	NFP
cord-276598-tm0yj2sn	286	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	286	2	,	,	,
cord-276598-tm0yj2sn	286	3	Et	Et	NNP
cord-276598-tm0yj2sn	286	4	)	)	-RRB-
cord-276598-tm0yj2sn	286	5	affording	afford	VBG
cord-276598-tm0yj2sn	286	6	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	286	7	P	P	NNP
cord-276598-tm0yj2sn	286	8	-	-	HYPH
cord-276598-tm0yj2sn	286	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	286	10	(	(	-LRB-
cord-276598-tm0yj2sn	286	11	Scheme	scheme	NN
cord-276598-tm0yj2sn	286	12	7b	7b	CD
cord-276598-tm0yj2sn	286	13	)	)	-RRB-
cord-276598-tm0yj2sn	286	14	[	[	-LRB-
cord-276598-tm0yj2sn	286	15	101	101	CD
cord-276598-tm0yj2sn	286	16	]	]	-RRB-
cord-276598-tm0yj2sn	286	17	.	.	.
cord-276598-tm0yj2sn	287	1	Then	then	RB
cord-276598-tm0yj2sn	287	2	,	,	,
cord-276598-tm0yj2sn	287	3	the	the	DT
cord-276598-tm0yj2sn	287	4	crude	crude	JJ
cord-276598-tm0yj2sn	287	5	products	product	NNS
cord-276598-tm0yj2sn	287	6	were	be	VBD
cord-276598-tm0yj2sn	287	7	purified	purify	VBN
cord-276598-tm0yj2sn	287	8	by	by	IN
cord-276598-tm0yj2sn	287	9	column	column	NN
cord-276598-tm0yj2sn	287	10	chromatography	chromatography	NN
cord-276598-tm0yj2sn	287	11	(	(	-LRB-
cord-276598-tm0yj2sn	287	12	on	on	IN
cord-276598-tm0yj2sn	287	13	silica	silica	NN
cord-276598-tm0yj2sn	287	14	)	)	-RRB-
cord-276598-tm0yj2sn	287	15	to	to	TO
cord-276598-tm0yj2sn	287	16	obtain	obtain	VB
cord-276598-tm0yj2sn	287	17	yields	yield	NNS
cord-276598-tm0yj2sn	287	18	of	of	IN
cord-276598-tm0yj2sn	287	19	product	product	NN
cord-276598-tm0yj2sn	287	20	in	in	IN
cord-276598-tm0yj2sn	287	21	0	0	CD
cord-276598-tm0yj2sn	287	22	-	-	SYM
cord-276598-tm0yj2sn	287	23	88	88	CD
cord-276598-tm0yj2sn	287	24	%	%	NN
cord-276598-tm0yj2sn	287	25	.	.	.
cord-276598-tm0yj2sn	288	1	The	the	DT
cord-276598-tm0yj2sn	288	2	best	good	JJS
cord-276598-tm0yj2sn	288	3	yielding	yielding	JJ
cord-276598-tm0yj2sn	288	4	conditions	condition	NNS
cord-276598-tm0yj2sn	288	5	were	be	VBD
cord-276598-tm0yj2sn	288	6	shorter	short	JJR
cord-276598-tm0yj2sn	288	7	reaction	reaction	NN
cord-276598-tm0yj2sn	288	8	times	time	NNS
cord-276598-tm0yj2sn	288	9	without	without	IN
cord-276598-tm0yj2sn	288	10	solvent	solvent	NN
cord-276598-tm0yj2sn	288	11	.	.	.
cord-276598-tm0yj2sn	289	1	Reactions	reaction	NNS
cord-276598-tm0yj2sn	289	2	performed	perform	VBN
cord-276598-tm0yj2sn	289	3	in	in	IN
cord-276598-tm0yj2sn	289	4	polar	polar	JJ
cord-276598-tm0yj2sn	289	5	non	non	JJ
cord-276598-tm0yj2sn	289	6	-	-	JJ
cord-276598-tm0yj2sn	289	7	protic	protic	JJ
cord-276598-tm0yj2sn	289	8	solvents	solvent	NNS
cord-276598-tm0yj2sn	289	9	(	(	-LRB-
cord-276598-tm0yj2sn	289	10	e.g.	e.g.	RB
cord-276598-tm0yj2sn	289	11	,	,	,
cord-276598-tm0yj2sn	289	12	CH	CH	NNP
cord-276598-tm0yj2sn	289	13	2	2	CD
cord-276598-tm0yj2sn	289	14	Cl	Cl	NNP
cord-276598-tm0yj2sn	289	15	2	2	CD
cord-276598-tm0yj2sn	289	16	)	)	-RRB-
cord-276598-tm0yj2sn	289	17	,	,	,
cord-276598-tm0yj2sn	289	18	non	non	JJ
cord-276598-tm0yj2sn	289	19	-	-	JJ
cord-276598-tm0yj2sn	289	20	polar	polar	JJ
cord-276598-tm0yj2sn	289	21	solvents	solvent	NNS
cord-276598-tm0yj2sn	289	22	(	(	-LRB-
cord-276598-tm0yj2sn	289	23	e.g.	e.g.	RB
cord-276598-tm0yj2sn	289	24	,	,	,
cord-276598-tm0yj2sn	289	25	hexane	hexane	NNP
cord-276598-tm0yj2sn	289	26	)	)	-RRB-
cord-276598-tm0yj2sn	289	27	,	,	,
cord-276598-tm0yj2sn	289	28	or	or	CC
cord-276598-tm0yj2sn	289	29	protic	protic	JJ
cord-276598-tm0yj2sn	289	30	solvents	solvent	NNS
cord-276598-tm0yj2sn	289	31	(	(	-LRB-
cord-276598-tm0yj2sn	289	32	e.g.	e.g.	RB
cord-276598-tm0yj2sn	289	33	,	,	,
cord-276598-tm0yj2sn	289	34	MeOH	MeOH	NNP
cord-276598-tm0yj2sn	289	35	)	)	-RRB-
cord-276598-tm0yj2sn	289	36	all	all	DT
cord-276598-tm0yj2sn	289	37	suffered	suffer	VBD
cord-276598-tm0yj2sn	289	38	from	from	IN
cord-276598-tm0yj2sn	289	39	reduced	reduced	JJ
cord-276598-tm0yj2sn	289	40	efficiency	efficiency	NN
cord-276598-tm0yj2sn	289	41	and	and	CC
cord-276598-tm0yj2sn	289	42	selectivity	selectivity	NN
cord-276598-tm0yj2sn	289	43	.	.	.
cord-276598-tm0yj2sn	290	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	290	2	,	,	,
cord-276598-tm0yj2sn	290	3	aniline	aniline	NN
cord-276598-tm0yj2sn	290	4	with	with	IN
cord-276598-tm0yj2sn	290	5	substituents	substituent	NNS
cord-276598-tm0yj2sn	290	6	at	at	IN
cord-276598-tm0yj2sn	290	7	orthoand	orthoand	NNP
cord-276598-tm0yj2sn	290	8	meta	meta	NNP
cord-276598-tm0yj2sn	290	9	-	-	HYPH
cord-276598-tm0yj2sn	290	10	positions	position	NNS
cord-276598-tm0yj2sn	290	11	were	be	VBD
cord-276598-tm0yj2sn	290	12	observed	observe	VBN
cord-276598-tm0yj2sn	290	13	to	to	TO
cord-276598-tm0yj2sn	290	14	have	have	VB
cord-276598-tm0yj2sn	290	15	reacted	react	VBN
cord-276598-tm0yj2sn	290	16	faster	fast	RBR
cord-276598-tm0yj2sn	290	17	and	and	CC
cord-276598-tm0yj2sn	290	18	were	be	VBD
cord-276598-tm0yj2sn	290	19	higher	high	JJR
cord-276598-tm0yj2sn	290	20	yielding	yield	VBG
cord-276598-tm0yj2sn	290	21	than	than	IN
cord-276598-tm0yj2sn	290	22	aniline	aniline	NN
cord-276598-tm0yj2sn	290	23	containing	contain	VBG
cord-276598-tm0yj2sn	290	24	substituents	substituent	NNS
cord-276598-tm0yj2sn	290	25	at	at	IN
cord-276598-tm0yj2sn	290	26	the	the	DT
cord-276598-tm0yj2sn	290	27	para	para	NNP
cord-276598-tm0yj2sn	290	28	-	-	HYPH
cord-276598-tm0yj2sn	290	29	position	position	NN
cord-276598-tm0yj2sn	290	30	.	.	.
cord-276598-tm0yj2sn	291	1	Iodine	iodine	NN
cord-276598-tm0yj2sn	291	2	(	(	-LRB-
cord-276598-tm0yj2sn	291	3	I2	I2	NNP
cord-276598-tm0yj2sn	291	4	)	)	-RRB-
cord-276598-tm0yj2sn	291	5	has	have	VBZ
cord-276598-tm0yj2sn	291	6	also	also	RB
cord-276598-tm0yj2sn	291	7	been	be	VBN
cord-276598-tm0yj2sn	291	8	used	use	VBN
cord-276598-tm0yj2sn	291	9	as	as	IN
cord-276598-tm0yj2sn	291	10	a	a	DT
cord-276598-tm0yj2sn	291	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	291	12	under	under	IN
cord-276598-tm0yj2sn	291	13	solvent	solvent	NN
cord-276598-tm0yj2sn	291	14	-	-	HYPH
cord-276598-tm0yj2sn	291	15	free	free	JJ
cord-276598-tm0yj2sn	291	16	conditions	condition	NNS
cord-276598-tm0yj2sn	291	17	to	to	IN
cord-276598-tm0yj2sn	291	18	couple	couple	NN
cord-276598-tm0yj2sn	291	19	aryl	aryl	NN
cord-276598-tm0yj2sn	291	20	amines	amine	NNS
cord-276598-tm0yj2sn	291	21	(	(	-LRB-
cord-276598-tm0yj2sn	291	22	PhNH2	phnh2	NN
cord-276598-tm0yj2sn	291	23	and	and	CC
cord-276598-tm0yj2sn	291	24	derivatives	derivative	NNS
cord-276598-tm0yj2sn	291	25	containing	contain	VBG
cord-276598-tm0yj2sn	291	26	OH	oh	UH
cord-276598-tm0yj2sn	291	27	,	,	,
cord-276598-tm0yj2sn	291	28	OEt	OEt	NNS
cord-276598-tm0yj2sn	291	29	,	,	,
cord-276598-tm0yj2sn	291	30	CN	CN	NNP
cord-276598-tm0yj2sn	291	31	,	,	,
cord-276598-tm0yj2sn	291	32	OMe	OMe	NNS
cord-276598-tm0yj2sn	291	33	,	,	,
cord-276598-tm0yj2sn	291	34	NO2	NO2	NNP
cord-276598-tm0yj2sn	291	35	,	,	,
cord-276598-tm0yj2sn	291	36	F	F	NNP
cord-276598-tm0yj2sn	291	37	,	,	,
cord-276598-tm0yj2sn	291	38	Cl	Cl	NNP
cord-276598-tm0yj2sn	291	39	,	,	,
cord-276598-tm0yj2sn	291	40	or	or	CC
cord-276598-tm0yj2sn	291	41	Br	Br	NNP
cord-276598-tm0yj2sn	291	42	substituents	substituent	NNS
cord-276598-tm0yj2sn	291	43	on	on	IN
cord-276598-tm0yj2sn	291	44	Ph	Ph	NNP
cord-276598-tm0yj2sn	291	45	)	)	-RRB-
cord-276598-tm0yj2sn	291	46	with	with	IN
cord-276598-tm0yj2sn	291	47	(	(	-LRB-
cord-276598-tm0yj2sn	291	48	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	291	49	(	(	-LRB-
cord-276598-tm0yj2sn	291	50	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	291	51	H	H	NNP
cord-276598-tm0yj2sn	291	52	-	-	HYPH
cord-276598-tm0yj2sn	291	53	P	p	NN
cord-276598-tm0yj2sn	291	54	;	;	:
cord-276598-tm0yj2sn	291	55	R	r	NN
cord-276598-tm0yj2sn	291	56	=	=	NN
cord-276598-tm0yj2sn	292	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	292	2	,	,	,
cord-276598-tm0yj2sn	292	3	Et	Et	NNP
cord-276598-tm0yj2sn	292	4	)	)	-RRB-
cord-276598-tm0yj2sn	292	5	affording	afford	VBG
cord-276598-tm0yj2sn	292	6	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	292	7	P	P	NNP
cord-276598-tm0yj2sn	292	8	-	-	HYPH
cord-276598-tm0yj2sn	292	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	292	10	(	(	-LRB-
cord-276598-tm0yj2sn	292	11	Scheme	scheme	NN
cord-276598-tm0yj2sn	292	12	7b	7b	CD
cord-276598-tm0yj2sn	292	13	)	)	-RRB-
cord-276598-tm0yj2sn	292	14	[	[	-LRB-
cord-276598-tm0yj2sn	292	15	101	101	CD
cord-276598-tm0yj2sn	292	16	]	]	-RRB-
cord-276598-tm0yj2sn	292	17	.	.	.
cord-276598-tm0yj2sn	293	1	Then	then	RB
cord-276598-tm0yj2sn	293	2	,	,	,
cord-276598-tm0yj2sn	293	3	the	the	DT
cord-276598-tm0yj2sn	293	4	crude	crude	JJ
cord-276598-tm0yj2sn	293	5	products	product	NNS
cord-276598-tm0yj2sn	293	6	were	be	VBD
cord-276598-tm0yj2sn	293	7	purified	purify	VBN
cord-276598-tm0yj2sn	293	8	by	by	IN
cord-276598-tm0yj2sn	293	9	column	column	NN
cord-276598-tm0yj2sn	293	10	chromatography	chromatography	NN
cord-276598-tm0yj2sn	293	11	(	(	-LRB-
cord-276598-tm0yj2sn	293	12	on	on	IN
cord-276598-tm0yj2sn	293	13	silica	silica	NN
cord-276598-tm0yj2sn	293	14	)	)	-RRB-
cord-276598-tm0yj2sn	293	15	to	to	TO
cord-276598-tm0yj2sn	293	16	obtain	obtain	VB
cord-276598-tm0yj2sn	293	17	yields	yield	NNS
cord-276598-tm0yj2sn	293	18	of	of	IN
cord-276598-tm0yj2sn	293	19	product	product	NN
cord-276598-tm0yj2sn	293	20	in	in	IN
cord-276598-tm0yj2sn	293	21	0	0	CD
cord-276598-tm0yj2sn	293	22	-	-	SYM
cord-276598-tm0yj2sn	293	23	88	88	CD
cord-276598-tm0yj2sn	293	24	%	%	NN
cord-276598-tm0yj2sn	293	25	.	.	.
cord-276598-tm0yj2sn	294	1	The	the	DT
cord-276598-tm0yj2sn	294	2	best	good	JJS
cord-276598-tm0yj2sn	294	3	yielding	yielding	JJ
cord-276598-tm0yj2sn	294	4	conditions	condition	NNS
cord-276598-tm0yj2sn	294	5	were	be	VBD
cord-276598-tm0yj2sn	294	6	shorter	short	JJR
cord-276598-tm0yj2sn	294	7	reaction	reaction	NN
cord-276598-tm0yj2sn	294	8	times	time	NNS
cord-276598-tm0yj2sn	294	9	without	without	IN
cord-276598-tm0yj2sn	294	10	solvent	solvent	NN
cord-276598-tm0yj2sn	294	11	.	.	.
cord-276598-tm0yj2sn	295	1	Reactions	reaction	NNS
cord-276598-tm0yj2sn	295	2	performed	perform	VBN
cord-276598-tm0yj2sn	295	3	in	in	IN
cord-276598-tm0yj2sn	295	4	polar	polar	JJ
cord-276598-tm0yj2sn	295	5	non	non	JJ
cord-276598-tm0yj2sn	295	6	-	-	JJ
cord-276598-tm0yj2sn	295	7	protic	protic	JJ
cord-276598-tm0yj2sn	295	8	solvents	solvent	NNS
cord-276598-tm0yj2sn	295	9	(	(	-LRB-
cord-276598-tm0yj2sn	295	10	e.g.	e.g.	RB
cord-276598-tm0yj2sn	295	11	,	,	,
cord-276598-tm0yj2sn	295	12	CH2Cl2	ch2cl2	NN
cord-276598-tm0yj2sn	295	13	)	)	-RRB-
cord-276598-tm0yj2sn	295	14	,	,	,
cord-276598-tm0yj2sn	295	15	non	non	JJ
cord-276598-tm0yj2sn	295	16	-	-	JJ
cord-276598-tm0yj2sn	295	17	polar	polar	JJ
cord-276598-tm0yj2sn	295	18	solvents	solvent	NNS
cord-276598-tm0yj2sn	295	19	(	(	-LRB-
cord-276598-tm0yj2sn	295	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	295	21	,	,	,
cord-276598-tm0yj2sn	295	22	hexane	hexane	NNP
cord-276598-tm0yj2sn	295	23	)	)	-RRB-
cord-276598-tm0yj2sn	295	24	,	,	,
cord-276598-tm0yj2sn	295	25	or	or	CC
cord-276598-tm0yj2sn	295	26	protic	protic	JJ
cord-276598-tm0yj2sn	295	27	solvents	solvent	NNS
cord-276598-tm0yj2sn	295	28	(	(	-LRB-
cord-276598-tm0yj2sn	295	29	e.g.	e.g.	RB
cord-276598-tm0yj2sn	295	30	,	,	,
cord-276598-tm0yj2sn	295	31	MeOH	MeOH	NNP
cord-276598-tm0yj2sn	295	32	)	)	-RRB-
cord-276598-tm0yj2sn	295	33	all	all	DT
cord-276598-tm0yj2sn	295	34	suffered	suffer	VBD
cord-276598-tm0yj2sn	295	35	from	from	IN
cord-276598-tm0yj2sn	295	36	reduced	reduced	JJ
cord-276598-tm0yj2sn	295	37	efficiency	efficiency	NN
cord-276598-tm0yj2sn	295	38	and	and	CC
cord-276598-tm0yj2sn	295	39	selectivity	selectivity	NN
cord-276598-tm0yj2sn	295	40	.	.	.
cord-276598-tm0yj2sn	296	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	296	2	,	,	,
cord-276598-tm0yj2sn	296	3	aniline	aniline	NN
cord-276598-tm0yj2sn	296	4	with	with	IN
cord-276598-tm0yj2sn	296	5	substituents	substituent	NNS
cord-276598-tm0yj2sn	296	6	at	at	IN
cord-276598-tm0yj2sn	296	7	ortho	ortho	NNP
cord-276598-tm0yj2sn	296	8	-	-	HYPH
cord-276598-tm0yj2sn	296	9	and	and	CC
cord-276598-tm0yj2sn	296	10	meta	meta	NNP
cord-276598-tm0yj2sn	296	11	-	-	HYPH
cord-276598-tm0yj2sn	296	12	positions	position	NNS
cord-276598-tm0yj2sn	296	13	were	be	VBD
cord-276598-tm0yj2sn	296	14	observed	observe	VBN
cord-276598-tm0yj2sn	296	15	to	to	TO
cord-276598-tm0yj2sn	296	16	have	have	VB
cord-276598-tm0yj2sn	296	17	reacted	react	VBN
cord-276598-tm0yj2sn	296	18	faster	fast	RBR
cord-276598-tm0yj2sn	296	19	and	and	CC
cord-276598-tm0yj2sn	296	20	were	be	VBD
cord-276598-tm0yj2sn	296	21	higher	high	JJR
cord-276598-tm0yj2sn	296	22	yielding	yield	VBG
cord-276598-tm0yj2sn	296	23	than	than	IN
cord-276598-tm0yj2sn	296	24	aniline	aniline	NN
cord-276598-tm0yj2sn	296	25	containing	contain	VBG
cord-276598-tm0yj2sn	296	26	substituents	substituent	NNS
cord-276598-tm0yj2sn	296	27	at	at	IN
cord-276598-tm0yj2sn	296	28	the	the	DT
cord-276598-tm0yj2sn	296	29	para	para	NNP
cord-276598-tm0yj2sn	296	30	-	-	HYPH
cord-276598-tm0yj2sn	296	31	position	position	NN
cord-276598-tm0yj2sn	296	32	.	.	.
cord-276598-tm0yj2sn	297	1	I2	I2	NNP
cord-276598-tm0yj2sn	297	2	was	be	VBD
cord-276598-tm0yj2sn	297	3	used	use	VBN
cord-276598-tm0yj2sn	297	4	in	in	IN
cord-276598-tm0yj2sn	297	5	the	the	DT
cord-276598-tm0yj2sn	297	6	presence	presence	NN
cord-276598-tm0yj2sn	297	7	of	of	IN
cord-276598-tm0yj2sn	297	8	H2O2	H2O2	NNP
cord-276598-tm0yj2sn	297	9	as	as	IN
cord-276598-tm0yj2sn	297	10	a	a	DT
cord-276598-tm0yj2sn	297	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	297	12	at	at	IN
cord-276598-tm0yj2sn	297	13	20	20	CD
cord-276598-tm0yj2sn	297	14	°	°	NN
cord-276598-tm0yj2sn	297	15	C	c	NN
cord-276598-tm0yj2sn	297	16	for	for	IN
cord-276598-tm0yj2sn	297	17	the	the	DT
cord-276598-tm0yj2sn	297	18	dehydrogenative	dehydrogenative	JJ
cord-276598-tm0yj2sn	297	19	cross	cross	NN
cord-276598-tm0yj2sn	297	20	-	-	NN
cord-276598-tm0yj2sn	297	21	coupling	coupling	NN
cord-276598-tm0yj2sn	297	22	of	of	IN
cord-276598-tm0yj2sn	297	23	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	297	24	H	H	NNP
cord-276598-tm0yj2sn	297	25	-	-	HYPH
cord-276598-tm0yj2sn	297	26	P	p	NN
cord-276598-tm0yj2sn	297	27	and	and	CC
cord-276598-tm0yj2sn	297	28	amine	amine	NN
cord-276598-tm0yj2sn	297	29	or	or	CC
cord-276598-tm0yj2sn	297	30	sulfoximines	sulfoximine	NNS
cord-276598-tm0yj2sn	297	31	to	to	TO
cord-276598-tm0yj2sn	297	32	form	form	VB
cord-276598-tm0yj2sn	297	33	P	p	NN
cord-276598-tm0yj2sn	297	34	-	-	HYPH
cord-276598-tm0yj2sn	297	35	Ns	Ns	NNP
cord-276598-tm0yj2sn	297	36	(	(	-LRB-
cord-276598-tm0yj2sn	297	37	Scheme	scheme	NN
cord-276598-tm0yj2sn	297	38	7c	7c	CD
cord-276598-tm0yj2sn	297	39	)	)	-RRB-
cord-276598-tm0yj2sn	297	40	[	[	-LRB-
cord-276598-tm0yj2sn	297	41	102	102	CD
cord-276598-tm0yj2sn	297	42	]	]	-RRB-
cord-276598-tm0yj2sn	297	43	.	.	.
cord-276598-tm0yj2sn	298	1	Purification	purification	NN
cord-276598-tm0yj2sn	298	2	of	of	IN
cord-276598-tm0yj2sn	298	3	the	the	DT
cord-276598-tm0yj2sn	298	4	products	product	NNS
cord-276598-tm0yj2sn	298	5	by	by	IN
cord-276598-tm0yj2sn	298	6	column	column	NN
cord-276598-tm0yj2sn	298	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	298	8	(	(	-LRB-
cord-276598-tm0yj2sn	298	9	on	on	IN
cord-276598-tm0yj2sn	298	10	silica	silica	NN
cord-276598-tm0yj2sn	298	11	)	)	-RRB-
cord-276598-tm0yj2sn	298	12	afforded	afford	VBN
cord-276598-tm0yj2sn	298	13	P	p	NN
cord-276598-tm0yj2sn	298	14	-	-	HYPH
cord-276598-tm0yj2sn	298	15	Ns	Ns	NNP
cord-276598-tm0yj2sn	298	16	with	with	IN
cord-276598-tm0yj2sn	298	17	isolated	isolated	JJ
cord-276598-tm0yj2sn	298	18	yields	yield	NNS
cord-276598-tm0yj2sn	298	19	of	of	IN
cord-276598-tm0yj2sn	298	20	31	31	CD
cord-276598-tm0yj2sn	298	21	-	-	SYM
cord-276598-tm0yj2sn	298	22	96	96	CD
cord-276598-tm0yj2sn	298	23	%	%	NN
cord-276598-tm0yj2sn	298	24	,	,	,
cord-276598-tm0yj2sn	298	25	with	with	IN
cord-276598-tm0yj2sn	298	26	the	the	DT
cord-276598-tm0yj2sn	298	27	lower	lower	RBR
cord-276598-tm0yj2sn	298	28	yielding	yield	VBG
cord-276598-tm0yj2sn	298	29	products	product	NNS
cord-276598-tm0yj2sn	298	30	reported	report	VBN
cord-276598-tm0yj2sn	298	31	from	from	IN
cord-276598-tm0yj2sn	298	32	sulfoximine	sulfoximine	NNP
cord-276598-tm0yj2sn	298	33	.	.	.
cord-276598-tm0yj2sn	299	1	Both	both	DT
cord-276598-tm0yj2sn	299	2	alkyl	alkyl	NN
cord-276598-tm0yj2sn	299	3	and	and	CC
cord-276598-tm0yj2sn	299	4	aryl	aryl	NN
cord-276598-tm0yj2sn	299	5	H	H	NNP
cord-276598-tm0yj2sn	299	6	-	-	HYPH
cord-276598-tm0yj2sn	299	7	P	p	NN
cord-276598-tm0yj2sn	299	8	(	(	-LRB-
cord-276598-tm0yj2sn	299	9	(	(	-LRB-
cord-276598-tm0yj2sn	299	10	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	299	11	,	,	,
cord-276598-tm0yj2sn	299	12	R	r	NN
cord-276598-tm0yj2sn	299	13	=	=	FW
cord-276598-tm0yj2sn	299	14	Et	et	NN
cord-276598-tm0yj2sn	299	15	,	,	,
cord-276598-tm0yj2sn	299	16	i	i	NN
cord-276598-tm0yj2sn	299	17	-	-	HYPH
cord-276598-tm0yj2sn	299	18	Pr	Pr	NNP
cord-276598-tm0yj2sn	299	19	,	,	,
cord-276598-tm0yj2sn	299	20	Ph	Ph	NNP
cord-276598-tm0yj2sn	299	21	)	)	-RRB-
cord-276598-tm0yj2sn	299	22	were	be	VBD
cord-276598-tm0yj2sn	299	23	used	use	VBN
cord-276598-tm0yj2sn	299	24	as	as	IN
cord-276598-tm0yj2sn	299	25	the	the	DT
cord-276598-tm0yj2sn	299	26	substrate	substrate	NN
cord-276598-tm0yj2sn	299	27	along	along	IN
cord-276598-tm0yj2sn	299	28	with	with	IN
cord-276598-tm0yj2sn	299	29	cyclic	cyclic	JJ
cord-276598-tm0yj2sn	299	30	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	299	31	secondary	secondary	JJ
cord-276598-tm0yj2sn	299	32	amines	amine	NNS
cord-276598-tm0yj2sn	299	33	(	(	-LRB-
cord-276598-tm0yj2sn	299	34	e.g.	e.g.	RB
cord-276598-tm0yj2sn	299	35	,	,	,
cord-276598-tm0yj2sn	299	36	indole	indole	NN
cord-276598-tm0yj2sn	299	37	)	)	-RRB-
cord-276598-tm0yj2sn	299	38	,	,	,
cord-276598-tm0yj2sn	299	39	derivatives	derivative	NNS
cord-276598-tm0yj2sn	299	40	of	of	IN
cord-276598-tm0yj2sn	299	41	heterocyclic	heterocyclic	JJ
cord-276598-tm0yj2sn	299	42	amines	amine	NNS
cord-276598-tm0yj2sn	299	43	(	(	-LRB-
cord-276598-tm0yj2sn	299	44	e.g.	e.g.	RB
cord-276598-tm0yj2sn	299	45	,	,	,
cord-276598-tm0yj2sn	299	46	furfurylamine	furfurylamine	NN
cord-276598-tm0yj2sn	299	47	)	)	-RRB-
cord-276598-tm0yj2sn	299	48	,	,	,
cord-276598-tm0yj2sn	299	49	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	299	50	cyclic	cyclic	JJ
cord-276598-tm0yj2sn	299	51	secondary	secondary	JJ
cord-276598-tm0yj2sn	299	52	amines	amine	NNS
cord-276598-tm0yj2sn	299	53	(	(	-LRB-
cord-276598-tm0yj2sn	299	54	e.g.	e.g.	RB
cord-276598-tm0yj2sn	299	55	,	,	,
cord-276598-tm0yj2sn	299	56	1-benzhydrylpiperazine	1-benzhydrylpiperazine	CD
cord-276598-tm0yj2sn	299	57	)	)	-RRB-
cord-276598-tm0yj2sn	300	1	,	,	,
cord-276598-tm0yj2sn	300	2	tertiary	tertiary	JJ
cord-276598-tm0yj2sn	300	3	amines	amine	NNS
cord-276598-tm0yj2sn	300	4	(	(	-LRB-
cord-276598-tm0yj2sn	300	5	e.g.	e.g.	RB
cord-276598-tm0yj2sn	300	6	,	,	,
cord-276598-tm0yj2sn	300	7	N	N	NNP
cord-276598-tm0yj2sn	300	8	-	-	HYPH
cord-276598-tm0yj2sn	300	9	methylhomopiperazine	methylhomopiperazine	NNP
cord-276598-tm0yj2sn	300	10	)	)	-RRB-
cord-276598-tm0yj2sn	300	11	,	,	,
cord-276598-tm0yj2sn	300	12	or	or	CC
cord-276598-tm0yj2sn	300	13	sulfoximine	sulfoximine	NNP
cord-276598-tm0yj2sn	300	14	.	.	.
cord-276598-tm0yj2sn	301	1	According	accord	VBG
cord-276598-tm0yj2sn	301	2	to	to	IN
cord-276598-tm0yj2sn	301	3	the	the	DT
cord-276598-tm0yj2sn	301	4	article	article	NN
cord-276598-tm0yj2sn	301	5	,	,	,
cord-276598-tm0yj2sn	301	6	using	use	VBG
cord-276598-tm0yj2sn	301	7	other	other	JJ
cord-276598-tm0yj2sn	301	8	sources	source	NNS
cord-276598-tm0yj2sn	301	9	of	of	IN
cord-276598-tm0yj2sn	301	10	I2	I2	NNP
cord-276598-tm0yj2sn	301	11	such	such	JJ
cord-276598-tm0yj2sn	301	12	as	as	IN
cord-276598-tm0yj2sn	301	13	KI	KI	NNP
cord-276598-tm0yj2sn	301	14	or	or	CC
cord-276598-tm0yj2sn	301	15	N	N	NNP
cord-276598-tm0yj2sn	301	16	-	-	HYPH
cord-276598-tm0yj2sn	301	17	bromosuccinimide	bromosuccinimide	NN
cord-276598-tm0yj2sn	301	18	(	(	-LRB-
cord-276598-tm0yj2sn	301	19	NBS	NBS	NNP
cord-276598-tm0yj2sn	301	20	)	)	-RRB-
cord-276598-tm0yj2sn	301	21	for	for	IN
cord-276598-tm0yj2sn	301	22	the	the	DT
cord-276598-tm0yj2sn	301	23	reaction	reaction	NN
cord-276598-tm0yj2sn	301	24	resulted	result	VBD
cord-276598-tm0yj2sn	301	25	in	in	IN
cord-276598-tm0yj2sn	301	26	decreased	decreased	JJ
cord-276598-tm0yj2sn	301	27	yield	yield	NN
cord-276598-tm0yj2sn	301	28	and	and	CC
cord-276598-tm0yj2sn	301	29	trace	trace	NN
cord-276598-tm0yj2sn	301	30	quantities	quantity	NNS
cord-276598-tm0yj2sn	301	31	of	of	IN
cord-276598-tm0yj2sn	301	32	the	the	DT
cord-276598-tm0yj2sn	301	33	desired	desire	VBN
cord-276598-tm0yj2sn	301	34	products	product	NNS
cord-276598-tm0yj2sn	301	35	,	,	,
cord-276598-tm0yj2sn	301	36	respectively	respectively	RB
cord-276598-tm0yj2sn	301	37	.	.	.
cord-276598-tm0yj2sn	302	1	Iodine	iodine	NN
cord-276598-tm0yj2sn	302	2	-	-	HYPH
cord-276598-tm0yj2sn	302	3	mediated	mediate	VBN
cord-276598-tm0yj2sn	302	4	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	302	5	cross	cross	JJ
cord-276598-tm0yj2sn	302	6	-	-	JJ
cord-276598-tm0yj2sn	302	7	coupling	coupling	JJ
cord-276598-tm0yj2sn	302	8	methods	method	NNS
cord-276598-tm0yj2sn	302	9	offer	offer	VBP
cord-276598-tm0yj2sn	302	10	better	well	JJR
cord-276598-tm0yj2sn	302	11	routes	route	NNS
cord-276598-tm0yj2sn	302	12	to	to	IN
cord-276598-tm0yj2sn	302	13	P	P	NNP
cord-276598-tm0yj2sn	302	14	-	-	HYPH
cord-276598-tm0yj2sn	302	15	N	n	CD
cord-276598-tm0yj2sn	302	16	compounds	compound	NNS
cord-276598-tm0yj2sn	302	17	by	by	IN
cord-276598-tm0yj2sn	302	18	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	302	19	toxic	toxic	JJ
cord-276598-tm0yj2sn	302	20	halogenating	halogenating	NN
cord-276598-tm0yj2sn	302	21	agents	agent	NNS
cord-276598-tm0yj2sn	302	22	such	such	JJ
cord-276598-tm0yj2sn	302	23	as	as	IN
cord-276598-tm0yj2sn	302	24	CCl4	ccl4	NN
cord-276598-tm0yj2sn	302	25	in	in	IN
cord-276598-tm0yj2sn	302	26	the	the	DT
cord-276598-tm0yj2sn	302	27	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	302	28	processes	process	NNS
cord-276598-tm0yj2sn	302	29	.	.	.
cord-276598-tm0yj2sn	303	1	The	the	DT
cord-276598-tm0yj2sn	303	2	method	method	NN
cord-276598-tm0yj2sn	303	3	also	also	RB
cord-276598-tm0yj2sn	303	4	uses	use	VBZ
cord-276598-tm0yj2sn	303	5	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	303	6	oxidants	oxidant	NNS
cord-276598-tm0yj2sn	303	7	without	without	IN
cord-276598-tm0yj2sn	303	8	additives	additive	NNS
cord-276598-tm0yj2sn	303	9	and	and	CC
cord-276598-tm0yj2sn	303	10	generates	generate	VBZ
cord-276598-tm0yj2sn	303	11	water	water	NN
cord-276598-tm0yj2sn	303	12	or	or	CC
cord-276598-tm0yj2sn	303	13	alkanol	alkanol	NN
cord-276598-tm0yj2sn	303	14	as	as	IN
cord-276598-tm0yj2sn	303	15	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	303	16	waste	waste	NN
cord-276598-tm0yj2sn	303	17	.	.	.
cord-276598-tm0yj2sn	304	1	However	however	RB
cord-276598-tm0yj2sn	304	2	,	,	,
cord-276598-tm0yj2sn	304	3	the	the	DT
cord-276598-tm0yj2sn	304	4	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	304	5	routes	route	NNS
cord-276598-tm0yj2sn	304	6	are	be	VBP
cord-276598-tm0yj2sn	304	7	prone	prone	JJ
cord-276598-tm0yj2sn	304	8	to	to	IN
cord-276598-tm0yj2sn	304	9	the	the	DT
cord-276598-tm0yj2sn	304	10	formation	formation	NN
cord-276598-tm0yj2sn	304	11	of	of	IN
cord-276598-tm0yj2sn	304	12	many	many	JJ
cord-276598-tm0yj2sn	304	13	undesired	undesired	JJ
cord-276598-tm0yj2sn	304	14	side	side	NN
cord-276598-tm0yj2sn	304	15	products	product	NNS
cord-276598-tm0yj2sn	304	16	,	,	,
cord-276598-tm0yj2sn	304	17	suffer	suffer	VBP
cord-276598-tm0yj2sn	304	18	from	from	IN
cord-276598-tm0yj2sn	304	19	low	low	JJ
cord-276598-tm0yj2sn	304	20	yields	yield	NNS
cord-276598-tm0yj2sn	304	21	,	,	,
cord-276598-tm0yj2sn	304	22	and	and	CC
cord-276598-tm0yj2sn	304	23	sometimes	sometimes	RB
cord-276598-tm0yj2sn	304	24	have	have	VBP
cord-276598-tm0yj2sn	304	25	limited	limit	VBN
cord-276598-tm0yj2sn	304	26	applicability	applicability	NN
cord-276598-tm0yj2sn	304	27	.	.	.
cord-276598-tm0yj2sn	305	1	I	-PRON-	PRP
cord-276598-tm0yj2sn	305	2	2	2	CD
cord-276598-tm0yj2sn	305	3	was	be	VBD
cord-276598-tm0yj2sn	305	4	used	use	VBN
cord-276598-tm0yj2sn	305	5	in	in	IN
cord-276598-tm0yj2sn	305	6	the	the	DT
cord-276598-tm0yj2sn	305	7	presence	presence	NN
cord-276598-tm0yj2sn	305	8	of	of	IN
cord-276598-tm0yj2sn	305	9	H	h	NN
cord-276598-tm0yj2sn	305	10	2	2	CD
cord-276598-tm0yj2sn	305	11	O	o	NN
cord-276598-tm0yj2sn	305	12	2	2	CD
cord-276598-tm0yj2sn	305	13	as	as	IN
cord-276598-tm0yj2sn	305	14	a	a	DT
cord-276598-tm0yj2sn	305	15	catalyst	catalyst	NN
cord-276598-tm0yj2sn	305	16	at	at	IN
cord-276598-tm0yj2sn	305	17	20	20	CD
cord-276598-tm0yj2sn	305	18	•	•	NN
cord-276598-tm0yj2sn	305	19	C	c	NN
cord-276598-tm0yj2sn	305	20	for	for	IN
cord-276598-tm0yj2sn	305	21	the	the	DT
cord-276598-tm0yj2sn	305	22	dehydrogenative	dehydrogenative	JJ
cord-276598-tm0yj2sn	305	23	cross	cross	NN
cord-276598-tm0yj2sn	305	24	-	-	NN
cord-276598-tm0yj2sn	305	25	coupling	coupling	NN
cord-276598-tm0yj2sn	305	26	of	of	IN
cord-276598-tm0yj2sn	305	27	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	305	28	H	H	NNP
cord-276598-tm0yj2sn	305	29	-	-	HYPH
cord-276598-tm0yj2sn	305	30	P	p	NN
cord-276598-tm0yj2sn	305	31	and	and	CC
cord-276598-tm0yj2sn	305	32	amine	amine	NN
cord-276598-tm0yj2sn	305	33	or	or	CC
cord-276598-tm0yj2sn	305	34	sulfoximines	sulfoximine	NNS
cord-276598-tm0yj2sn	305	35	to	to	TO
cord-276598-tm0yj2sn	305	36	form	form	VB
cord-276598-tm0yj2sn	305	37	P	p	NN
cord-276598-tm0yj2sn	305	38	-	-	HYPH
cord-276598-tm0yj2sn	305	39	Ns	Ns	NNP
cord-276598-tm0yj2sn	305	40	(	(	-LRB-
cord-276598-tm0yj2sn	305	41	Scheme	scheme	NN
cord-276598-tm0yj2sn	305	42	7c	7c	CD
cord-276598-tm0yj2sn	305	43	)	)	-RRB-
cord-276598-tm0yj2sn	305	44	[	[	-LRB-
cord-276598-tm0yj2sn	305	45	102	102	CD
cord-276598-tm0yj2sn	305	46	]	]	-RRB-
cord-276598-tm0yj2sn	305	47	.	.	.
cord-276598-tm0yj2sn	306	1	Purification	purification	NN
cord-276598-tm0yj2sn	306	2	of	of	IN
cord-276598-tm0yj2sn	306	3	the	the	DT
cord-276598-tm0yj2sn	306	4	products	product	NNS
cord-276598-tm0yj2sn	306	5	by	by	IN
cord-276598-tm0yj2sn	306	6	column	column	NN
cord-276598-tm0yj2sn	306	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	306	8	(	(	-LRB-
cord-276598-tm0yj2sn	306	9	on	on	IN
cord-276598-tm0yj2sn	306	10	silica	silica	NN
cord-276598-tm0yj2sn	306	11	)	)	-RRB-
cord-276598-tm0yj2sn	306	12	afforded	afford	VBN
cord-276598-tm0yj2sn	306	13	P	p	NN
cord-276598-tm0yj2sn	306	14	-	-	HYPH
cord-276598-tm0yj2sn	306	15	Ns	Ns	NNP
cord-276598-tm0yj2sn	306	16	with	with	IN
cord-276598-tm0yj2sn	306	17	isolated	isolated	JJ
cord-276598-tm0yj2sn	306	18	yields	yield	NNS
cord-276598-tm0yj2sn	306	19	of	of	IN
cord-276598-tm0yj2sn	306	20	31	31	CD
cord-276598-tm0yj2sn	306	21	-	-	SYM
cord-276598-tm0yj2sn	306	22	96	96	CD
cord-276598-tm0yj2sn	306	23	%	%	NN
cord-276598-tm0yj2sn	306	24	,	,	,
cord-276598-tm0yj2sn	306	25	with	with	IN
cord-276598-tm0yj2sn	306	26	the	the	DT
cord-276598-tm0yj2sn	306	27	lower	lower	RBR
cord-276598-tm0yj2sn	306	28	yielding	yield	VBG
cord-276598-tm0yj2sn	306	29	products	product	NNS
cord-276598-tm0yj2sn	306	30	reported	report	VBN
cord-276598-tm0yj2sn	306	31	from	from	IN
cord-276598-tm0yj2sn	306	32	sulfoximine	sulfoximine	NNP
cord-276598-tm0yj2sn	306	33	.	.	.
cord-276598-tm0yj2sn	307	1	Both	both	DT
cord-276598-tm0yj2sn	307	2	alkyl	alkyl	NN
cord-276598-tm0yj2sn	307	3	and	and	CC
cord-276598-tm0yj2sn	307	4	aryl	aryl	NN
cord-276598-tm0yj2sn	307	5	H	H	NNP
cord-276598-tm0yj2sn	307	6	-	-	HYPH
cord-276598-tm0yj2sn	307	7	P	p	NN
cord-276598-tm0yj2sn	307	8	(	(	-LRB-
cord-276598-tm0yj2sn	307	9	(	(	-LRB-
cord-276598-tm0yj2sn	307	10	RO	RO	NNP
cord-276598-tm0yj2sn	307	11	)	)	-RRB-
cord-276598-tm0yj2sn	307	12	2	2	CD
cord-276598-tm0yj2sn	308	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	309	1	,	,	,
cord-276598-tm0yj2sn	309	2	R	r	NN
cord-276598-tm0yj2sn	309	3	=	=	SYM
cord-276598-tm0yj2sn	309	4	Et	Et	NNP
cord-276598-tm0yj2sn	309	5	,	,	,
cord-276598-tm0yj2sn	309	6	i	i	NN
cord-276598-tm0yj2sn	309	7	-	-	HYPH
cord-276598-tm0yj2sn	309	8	Pr	Pr	NNP
cord-276598-tm0yj2sn	309	9	,	,	,
cord-276598-tm0yj2sn	309	10	Ph	Ph	NNP
cord-276598-tm0yj2sn	309	11	)	)	-RRB-
cord-276598-tm0yj2sn	309	12	were	be	VBD
cord-276598-tm0yj2sn	309	13	used	use	VBN
cord-276598-tm0yj2sn	309	14	as	as	IN
cord-276598-tm0yj2sn	309	15	the	the	DT
cord-276598-tm0yj2sn	309	16	substrate	substrate	NN
cord-276598-tm0yj2sn	309	17	along	along	IN
cord-276598-tm0yj2sn	309	18	with	with	IN
cord-276598-tm0yj2sn	309	19	cyclic	cyclic	JJ
cord-276598-tm0yj2sn	309	20	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	309	21	secondary	secondary	JJ
cord-276598-tm0yj2sn	309	22	amines	amine	NNS
cord-276598-tm0yj2sn	309	23	(	(	-LRB-
cord-276598-tm0yj2sn	309	24	e.g.	e.g.	RB
cord-276598-tm0yj2sn	309	25	,	,	,
cord-276598-tm0yj2sn	309	26	indole	indole	NN
cord-276598-tm0yj2sn	309	27	)	)	-RRB-
cord-276598-tm0yj2sn	309	28	,	,	,
cord-276598-tm0yj2sn	309	29	derivatives	derivative	NNS
cord-276598-tm0yj2sn	309	30	of	of	IN
cord-276598-tm0yj2sn	309	31	heterocyclic	heterocyclic	JJ
cord-276598-tm0yj2sn	309	32	amines	amine	NNS
cord-276598-tm0yj2sn	309	33	(	(	-LRB-
cord-276598-tm0yj2sn	309	34	e.g.	e.g.	RB
cord-276598-tm0yj2sn	309	35	,	,	,
cord-276598-tm0yj2sn	309	36	furfurylamine	furfurylamine	NN
cord-276598-tm0yj2sn	309	37	)	)	-RRB-
cord-276598-tm0yj2sn	309	38	,	,	,
cord-276598-tm0yj2sn	309	39	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	309	40	cyclic	cyclic	JJ
cord-276598-tm0yj2sn	309	41	secondary	secondary	JJ
cord-276598-tm0yj2sn	309	42	amines	amine	NNS
cord-276598-tm0yj2sn	309	43	(	(	-LRB-
cord-276598-tm0yj2sn	309	44	e.g.	e.g.	RB
cord-276598-tm0yj2sn	309	45	,	,	,
cord-276598-tm0yj2sn	309	46	1-benzhydrylpiperazine	1-benzhydrylpiperazine	CD
cord-276598-tm0yj2sn	309	47	)	)	-RRB-
cord-276598-tm0yj2sn	310	1	,	,	,
cord-276598-tm0yj2sn	310	2	tertiary	tertiary	JJ
cord-276598-tm0yj2sn	310	3	amines	amine	NNS
cord-276598-tm0yj2sn	310	4	(	(	-LRB-
cord-276598-tm0yj2sn	310	5	e.g.	e.g.	RB
cord-276598-tm0yj2sn	310	6	,	,	,
cord-276598-tm0yj2sn	310	7	N	N	NNP
cord-276598-tm0yj2sn	310	8	-	-	HYPH
cord-276598-tm0yj2sn	310	9	methylhomopiperazine	methylhomopiperazine	NNP
cord-276598-tm0yj2sn	310	10	)	)	-RRB-
cord-276598-tm0yj2sn	310	11	,	,	,
cord-276598-tm0yj2sn	310	12	or	or	CC
cord-276598-tm0yj2sn	310	13	sulfoximine	sulfoximine	NNP
cord-276598-tm0yj2sn	310	14	.	.	.
cord-276598-tm0yj2sn	311	1	According	accord	VBG
cord-276598-tm0yj2sn	311	2	to	to	IN
cord-276598-tm0yj2sn	311	3	the	the	DT
cord-276598-tm0yj2sn	311	4	article	article	NN
cord-276598-tm0yj2sn	311	5	,	,	,
cord-276598-tm0yj2sn	311	6	using	use	VBG
cord-276598-tm0yj2sn	311	7	other	other	JJ
cord-276598-tm0yj2sn	311	8	sources	source	NNS
cord-276598-tm0yj2sn	311	9	of	of	IN
cord-276598-tm0yj2sn	311	10	I	-PRON-	PRP
cord-276598-tm0yj2sn	311	11	2	2	CD
cord-276598-tm0yj2sn	311	12	such	such	JJ
cord-276598-tm0yj2sn	311	13	as	as	IN
cord-276598-tm0yj2sn	311	14	KI	KI	NNP
cord-276598-tm0yj2sn	311	15	or	or	CC
cord-276598-tm0yj2sn	311	16	N	N	NNP
cord-276598-tm0yj2sn	311	17	-	-	HYPH
cord-276598-tm0yj2sn	311	18	bromosuccinimide	bromosuccinimide	NN
cord-276598-tm0yj2sn	311	19	(	(	-LRB-
cord-276598-tm0yj2sn	311	20	NBS	NBS	NNP
cord-276598-tm0yj2sn	311	21	)	)	-RRB-
cord-276598-tm0yj2sn	311	22	for	for	IN
cord-276598-tm0yj2sn	311	23	the	the	DT
cord-276598-tm0yj2sn	311	24	reaction	reaction	NN
cord-276598-tm0yj2sn	311	25	resulted	result	VBD
cord-276598-tm0yj2sn	311	26	in	in	IN
cord-276598-tm0yj2sn	311	27	decreased	decreased	JJ
cord-276598-tm0yj2sn	311	28	yield	yield	NN
cord-276598-tm0yj2sn	311	29	and	and	CC
cord-276598-tm0yj2sn	311	30	trace	trace	NN
cord-276598-tm0yj2sn	311	31	quantities	quantity	NNS
cord-276598-tm0yj2sn	311	32	of	of	IN
cord-276598-tm0yj2sn	311	33	the	the	DT
cord-276598-tm0yj2sn	311	34	desired	desire	VBN
cord-276598-tm0yj2sn	311	35	products	product	NNS
cord-276598-tm0yj2sn	311	36	,	,	,
cord-276598-tm0yj2sn	311	37	respectively	respectively	RB
cord-276598-tm0yj2sn	311	38	.	.	.
cord-276598-tm0yj2sn	312	1	Iodine	iodine	NN
cord-276598-tm0yj2sn	312	2	-	-	HYPH
cord-276598-tm0yj2sn	312	3	mediated	mediate	VBN
cord-276598-tm0yj2sn	312	4	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	312	5	cross	cross	JJ
cord-276598-tm0yj2sn	312	6	-	-	JJ
cord-276598-tm0yj2sn	312	7	coupling	coupling	JJ
cord-276598-tm0yj2sn	312	8	methods	method	NNS
cord-276598-tm0yj2sn	312	9	offer	offer	VBP
cord-276598-tm0yj2sn	312	10	better	well	JJR
cord-276598-tm0yj2sn	312	11	routes	route	NNS
cord-276598-tm0yj2sn	312	12	to	to	IN
cord-276598-tm0yj2sn	312	13	P	P	NNP
cord-276598-tm0yj2sn	312	14	-	-	HYPH
cord-276598-tm0yj2sn	312	15	N	n	CD
cord-276598-tm0yj2sn	312	16	compounds	compound	NNS
cord-276598-tm0yj2sn	312	17	by	by	IN
cord-276598-tm0yj2sn	312	18	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	312	19	toxic	toxic	JJ
cord-276598-tm0yj2sn	312	20	halogenating	halogenating	NN
cord-276598-tm0yj2sn	312	21	agents	agent	NNS
cord-276598-tm0yj2sn	312	22	such	such	JJ
cord-276598-tm0yj2sn	312	23	as	as	IN
cord-276598-tm0yj2sn	312	24	CCl	CCl	NNS
cord-276598-tm0yj2sn	312	25	4	4	CD
cord-276598-tm0yj2sn	312	26	in	in	IN
cord-276598-tm0yj2sn	312	27	the	the	DT
cord-276598-tm0yj2sn	312	28	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	312	29	processes	process	NNS
cord-276598-tm0yj2sn	312	30	.	.	.
cord-276598-tm0yj2sn	313	1	The	the	DT
cord-276598-tm0yj2sn	313	2	method	method	NN
cord-276598-tm0yj2sn	313	3	also	also	RB
cord-276598-tm0yj2sn	313	4	uses	use	VBZ
cord-276598-tm0yj2sn	313	5	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	313	6	oxidants	oxidant	NNS
cord-276598-tm0yj2sn	313	7	without	without	IN
cord-276598-tm0yj2sn	313	8	additives	additive	NNS
cord-276598-tm0yj2sn	313	9	and	and	CC
cord-276598-tm0yj2sn	313	10	generates	generate	VBZ
cord-276598-tm0yj2sn	313	11	water	water	NN
cord-276598-tm0yj2sn	313	12	or	or	CC
cord-276598-tm0yj2sn	313	13	alkanol	alkanol	NN
cord-276598-tm0yj2sn	313	14	as	as	IN
cord-276598-tm0yj2sn	313	15	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	313	16	waste	waste	NN
cord-276598-tm0yj2sn	313	17	.	.	.
cord-276598-tm0yj2sn	314	1	However	however	RB
cord-276598-tm0yj2sn	314	2	,	,	,
cord-276598-tm0yj2sn	314	3	the	the	DT
cord-276598-tm0yj2sn	314	4	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	314	5	routes	route	NNS
cord-276598-tm0yj2sn	314	6	are	be	VBP
cord-276598-tm0yj2sn	314	7	prone	prone	JJ
cord-276598-tm0yj2sn	314	8	to	to	IN
cord-276598-tm0yj2sn	314	9	the	the	DT
cord-276598-tm0yj2sn	314	10	formation	formation	NN
cord-276598-tm0yj2sn	314	11	of	of	IN
cord-276598-tm0yj2sn	314	12	many	many	JJ
cord-276598-tm0yj2sn	314	13	undesired	undesired	JJ
cord-276598-tm0yj2sn	314	14	side	side	NN
cord-276598-tm0yj2sn	314	15	products	product	NNS
cord-276598-tm0yj2sn	314	16	,	,	,
cord-276598-tm0yj2sn	314	17	suffer	suffer	VBP
cord-276598-tm0yj2sn	314	18	from	from	IN
cord-276598-tm0yj2sn	314	19	low	low	JJ
cord-276598-tm0yj2sn	314	20	yields	yield	NNS
cord-276598-tm0yj2sn	314	21	,	,	,
cord-276598-tm0yj2sn	314	22	and	and	CC
cord-276598-tm0yj2sn	314	23	sometimes	sometimes	RB
cord-276598-tm0yj2sn	314	24	have	have	VBP
cord-276598-tm0yj2sn	314	25	limited	limit	VBN
cord-276598-tm0yj2sn	314	26	applicability	applicability	NN
cord-276598-tm0yj2sn	314	27	.	.	.
cord-276598-tm0yj2sn	315	1	The	the	DT
cord-276598-tm0yj2sn	315	2	aerobic	aerobic	JJ
cord-276598-tm0yj2sn	315	3	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	315	4	coupling	coupling	NN
cord-276598-tm0yj2sn	315	5	of	of	IN
cord-276598-tm0yj2sn	315	6	amines	amine	NNS
cord-276598-tm0yj2sn	315	7	and	and	CC
cord-276598-tm0yj2sn	315	8	disubstituted	disubstituted	JJ
cord-276598-tm0yj2sn	315	9	H	H	NNP
cord-276598-tm0yj2sn	315	10	-	-	HYPH
cord-276598-tm0yj2sn	315	11	phosphonates	phosphonates	NNP
cord-276598-tm0yj2sn	315	12	(	(	-LRB-
cord-276598-tm0yj2sn	315	13	H	h	NN
cord-276598-tm0yj2sn	315	14	-	-	HYPH
cord-276598-tm0yj2sn	315	15	P	p	NN
cord-276598-tm0yj2sn	315	16	)	)	-RRB-
cord-276598-tm0yj2sn	316	1	(	(	-LRB-
cord-276598-tm0yj2sn	316	2	RO	RO	NNP
cord-276598-tm0yj2sn	316	3	)	)	-RRB-
cord-276598-tm0yj2sn	316	4	2	2	CD
cord-276598-tm0yj2sn	317	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	318	1	(	(	-LRB-
cord-276598-tm0yj2sn	318	2	R	r	NN
cord-276598-tm0yj2sn	318	3	=	=	NFP
cord-276598-tm0yj2sn	319	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	319	2	,	,	,
cord-276598-tm0yj2sn	319	3	Et	Et	NNP
cord-276598-tm0yj2sn	319	4	,	,	,
cord-276598-tm0yj2sn	319	5	i	i	NN
cord-276598-tm0yj2sn	319	6	-	-	HYPH
cord-276598-tm0yj2sn	319	7	Pr	pr	NN
cord-276598-tm0yj2sn	319	8	;	;	:
cord-276598-tm0yj2sn	319	9	1	1	CD
cord-276598-tm0yj2sn	319	10	eq	eq	NN
cord-276598-tm0yj2sn	319	11	.	.	.
cord-276598-tm0yj2sn	319	12	)	)	-RRB-
cord-276598-tm0yj2sn	320	1	in	in	IN
cord-276598-tm0yj2sn	320	2	the	the	DT
cord-276598-tm0yj2sn	320	3	presence	presence	NN
cord-276598-tm0yj2sn	320	4	of	of	IN
cord-276598-tm0yj2sn	320	5	copper	copper	NN
cord-276598-tm0yj2sn	320	6	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	320	7	to	to	TO
cord-276598-tm0yj2sn	320	8	synthesize	synthesize	VB
cord-276598-tm0yj2sn	320	9	P	p	NN
cord-276598-tm0yj2sn	320	10	-	-	HYPH
cord-276598-tm0yj2sn	320	11	Ns	Ns	NNP
cord-276598-tm0yj2sn	320	12	was	be	VBD
cord-276598-tm0yj2sn	320	13	reported	report	VBN
cord-276598-tm0yj2sn	320	14	by	by	IN
cord-276598-tm0yj2sn	320	15	Hayes	Hayes	NNP
cord-276598-tm0yj2sn	320	16	and	and	CC
cord-276598-tm0yj2sn	320	17	coworkers	coworker	NNS
cord-276598-tm0yj2sn	320	18	(	(	-LRB-
cord-276598-tm0yj2sn	320	19	Table	table	NN
cord-276598-tm0yj2sn	320	20	1	1	CD
cord-276598-tm0yj2sn	320	21	,	,	,
cord-276598-tm0yj2sn	320	22	route	route	VBP
cord-276598-tm0yj2sn	320	23	a	a	DT
cord-276598-tm0yj2sn	320	24	)	)	-RRB-
cord-276598-tm0yj2sn	320	25	[	[	-LRB-
cord-276598-tm0yj2sn	320	26	103	103	CD
cord-276598-tm0yj2sn	320	27	]	]	-RRB-
cord-276598-tm0yj2sn	320	28	.	.	.
cord-276598-tm0yj2sn	321	1	The	the	DT
cord-276598-tm0yj2sn	321	2	authors	author	NNS
cord-276598-tm0yj2sn	321	3	reported	report	VBD
cord-276598-tm0yj2sn	321	4	that	that	IN
cord-276598-tm0yj2sn	321	5	the	the	DT
cord-276598-tm0yj2sn	321	6	ligands	ligand	NNS
cord-276598-tm0yj2sn	321	7	on	on	IN
cord-276598-tm0yj2sn	321	8	the	the	DT
cord-276598-tm0yj2sn	321	9	copper	copper	NN
cord-276598-tm0yj2sn	321	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	321	11	were	be	VBD
cord-276598-tm0yj2sn	321	12	important	important	JJ
cord-276598-tm0yj2sn	321	13	in	in	IN
cord-276598-tm0yj2sn	321	14	the	the	DT
cord-276598-tm0yj2sn	321	15	reaction	reaction	NN
cord-276598-tm0yj2sn	321	16	,	,	,
cord-276598-tm0yj2sn	321	17	but	but	CC
cord-276598-tm0yj2sn	321	18	not	not	RB
cord-276598-tm0yj2sn	321	19	the	the	DT
cord-276598-tm0yj2sn	321	20	initial	initial	JJ
cord-276598-tm0yj2sn	321	21	oxidation	oxidation	NN
cord-276598-tm0yj2sn	321	22	state	state	NN
cord-276598-tm0yj2sn	321	23	of	of	IN
cord-276598-tm0yj2sn	321	24	copper	copper	NN
cord-276598-tm0yj2sn	321	25	catalyst	catalyst	NN
cord-276598-tm0yj2sn	321	26	,	,	,
cord-276598-tm0yj2sn	321	27	and	and	CC
cord-276598-tm0yj2sn	321	28	that	that	IN
cord-276598-tm0yj2sn	321	29	the	the	DT
cord-276598-tm0yj2sn	321	30	primary	primary	JJ
cord-276598-tm0yj2sn	321	31	amines	amine	NNS
cord-276598-tm0yj2sn	321	32	coupled	couple	VBN
cord-276598-tm0yj2sn	321	33	better	well	RBR
cord-276598-tm0yj2sn	321	34	than	than	IN
cord-276598-tm0yj2sn	321	35	the	the	DT
cord-276598-tm0yj2sn	321	36	secondary	secondary	JJ
cord-276598-tm0yj2sn	321	37	and	and	CC
cord-276598-tm0yj2sn	321	38	tertiary	tertiary	JJ
cord-276598-tm0yj2sn	321	39	amines	amine	NNS
cord-276598-tm0yj2sn	321	40	due	due	IN
cord-276598-tm0yj2sn	321	41	to	to	IN
cord-276598-tm0yj2sn	321	42	the	the	DT
cord-276598-tm0yj2sn	321	43	reduced	reduce	VBN
cord-276598-tm0yj2sn	321	44	steric	steric	JJ
cord-276598-tm0yj2sn	321	45	hindrance	hindrance	NN
cord-276598-tm0yj2sn	321	46	.	.	.
cord-276598-tm0yj2sn	322	1	The	the	DT
cord-276598-tm0yj2sn	322	2	method	method	NN
cord-276598-tm0yj2sn	322	3	was	be	VBD
cord-276598-tm0yj2sn	322	4	slightly	slightly	RB
cord-276598-tm0yj2sn	322	5	modified	modify	VBN
cord-276598-tm0yj2sn	322	6	for	for	IN
cord-276598-tm0yj2sn	322	7	the	the	DT
cord-276598-tm0yj2sn	322	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	322	9	of	of	IN
cord-276598-tm0yj2sn	322	10	some	some	DT
cord-276598-tm0yj2sn	322	11	important	important	JJ
cord-276598-tm0yj2sn	322	12	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	322	13	amino	amino	NN
cord-276598-tm0yj2sn	322	14	compounds	compound	NNS
cord-276598-tm0yj2sn	322	15	such	such	JJ
cord-276598-tm0yj2sn	322	16	as	as	IN
cord-276598-tm0yj2sn	322	17	ethyl	ethyl	NN
cord-276598-tm0yj2sn	322	18	(	(	-LRB-
cord-276598-tm0yj2sn	322	19	diethoxyphosphoryl)glycinate	diethoxyphosphoryl)glycinate	NNP
cord-276598-tm0yj2sn	322	20	,	,	,
cord-276598-tm0yj2sn	322	21	etc	etc	FW
cord-276598-tm0yj2sn	322	22	.	.	.
cord-276598-tm0yj2sn	323	1	(	(	-LRB-
cord-276598-tm0yj2sn	323	2	12	12	CD
cord-276598-tm0yj2sn	323	3	-	-	SYM
cord-276598-tm0yj2sn	323	4	15	15	CD
cord-276598-tm0yj2sn	323	5	)	)	-RRB-
cord-276598-tm0yj2sn	323	6	(	(	-LRB-
cord-276598-tm0yj2sn	323	7	Figure	figure	NN
cord-276598-tm0yj2sn	323	8	6	6	CD
cord-276598-tm0yj2sn	323	9	)	)	-RRB-
cord-276598-tm0yj2sn	323	10	.	.	.
cord-276598-tm0yj2sn	323	11	 	 	_SP
cord-276598-tm0yj2sn	324	1	The	the	DT
cord-276598-tm0yj2sn	324	2	aerobic	aerobic	JJ
cord-276598-tm0yj2sn	324	3	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	324	4	coupling	coupling	NN
cord-276598-tm0yj2sn	324	5	of	of	IN
cord-276598-tm0yj2sn	324	6	amines	amine	NNS
cord-276598-tm0yj2sn	324	7	and	and	CC
cord-276598-tm0yj2sn	324	8	disubstituted	disubstituted	JJ
cord-276598-tm0yj2sn	324	9	H	H	NNP
cord-276598-tm0yj2sn	324	10	-	-	HYPH
cord-276598-tm0yj2sn	324	11	phosphonates	phosphonates	NNP
cord-276598-tm0yj2sn	324	12	(	(	-LRB-
cord-276598-tm0yj2sn	324	13	H	h	NN
cord-276598-tm0yj2sn	324	14	-	-	HYPH
cord-276598-tm0yj2sn	324	15	P	p	NN
cord-276598-tm0yj2sn	324	16	)	)	-RRB-
cord-276598-tm0yj2sn	325	1	(	(	-LRB-
cord-276598-tm0yj2sn	325	2	RO)2P(O)H	ro)2p(o)h	CD
cord-276598-tm0yj2sn	326	1	(	(	-LRB-
cord-276598-tm0yj2sn	326	2	R	r	NN
cord-276598-tm0yj2sn	327	1	=	=	NFP
cord-276598-tm0yj2sn	327	2	Me	-PRON-	PRP
cord-276598-tm0yj2sn	327	3	,	,	,
cord-276598-tm0yj2sn	327	4	Et	Et	NNP
cord-276598-tm0yj2sn	327	5	,	,	,
cord-276598-tm0yj2sn	327	6	i	i	NN
cord-276598-tm0yj2sn	327	7	-	-	HYPH
cord-276598-tm0yj2sn	327	8	Pr	pr	NN
cord-276598-tm0yj2sn	327	9	;	;	:
cord-276598-tm0yj2sn	327	10	1	1	CD
cord-276598-tm0yj2sn	327	11	eq	eq	NN
cord-276598-tm0yj2sn	327	12	.	.	.
cord-276598-tm0yj2sn	327	13	)	)	-RRB-
cord-276598-tm0yj2sn	328	1	in	in	IN
cord-276598-tm0yj2sn	328	2	the	the	DT
cord-276598-tm0yj2sn	328	3	presence	presence	NN
cord-276598-tm0yj2sn	328	4	of	of	IN
cord-276598-tm0yj2sn	328	5	copper	copper	NN
cord-276598-tm0yj2sn	328	6	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	328	7	to	to	TO
cord-276598-tm0yj2sn	328	8	synthesize	synthesize	VB
cord-276598-tm0yj2sn	328	9	P	p	NN
cord-276598-tm0yj2sn	328	10	-	-	HYPH
cord-276598-tm0yj2sn	328	11	Ns	Ns	NNP
cord-276598-tm0yj2sn	328	12	was	be	VBD
cord-276598-tm0yj2sn	328	13	reported	report	VBN
cord-276598-tm0yj2sn	328	14	by	by	IN
cord-276598-tm0yj2sn	328	15	Hayes	Hayes	NNP
cord-276598-tm0yj2sn	328	16	and	and	CC
cord-276598-tm0yj2sn	328	17	coworkers	coworker	NNS
cord-276598-tm0yj2sn	328	18	(	(	-LRB-
cord-276598-tm0yj2sn	328	19	Table	table	NN
cord-276598-tm0yj2sn	328	20	1	1	CD
cord-276598-tm0yj2sn	328	21	,	,	,
cord-276598-tm0yj2sn	328	22	route	route	VBP
cord-276598-tm0yj2sn	328	23	a	a	DT
cord-276598-tm0yj2sn	328	24	)	)	-RRB-
cord-276598-tm0yj2sn	328	25	[	[	-LRB-
cord-276598-tm0yj2sn	328	26	103	103	CD
cord-276598-tm0yj2sn	328	27	]	]	-RRB-
cord-276598-tm0yj2sn	328	28	.	.	.
cord-276598-tm0yj2sn	329	1	The	the	DT
cord-276598-tm0yj2sn	329	2	authors	author	NNS
cord-276598-tm0yj2sn	329	3	reported	report	VBD
cord-276598-tm0yj2sn	329	4	that	that	IN
cord-276598-tm0yj2sn	329	5	the	the	DT
cord-276598-tm0yj2sn	329	6	ligands	ligand	NNS
cord-276598-tm0yj2sn	329	7	on	on	IN
cord-276598-tm0yj2sn	329	8	the	the	DT
cord-276598-tm0yj2sn	329	9	copper	copper	NN
cord-276598-tm0yj2sn	329	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	329	11	were	be	VBD
cord-276598-tm0yj2sn	329	12	important	important	JJ
cord-276598-tm0yj2sn	329	13	in	in	IN
cord-276598-tm0yj2sn	329	14	the	the	DT
cord-276598-tm0yj2sn	329	15	reaction	reaction	NN
cord-276598-tm0yj2sn	329	16	,	,	,
cord-276598-tm0yj2sn	329	17	but	but	CC
cord-276598-tm0yj2sn	329	18	not	not	RB
cord-276598-tm0yj2sn	329	19	the	the	DT
cord-276598-tm0yj2sn	329	20	initial	initial	JJ
cord-276598-tm0yj2sn	329	21	oxidation	oxidation	NN
cord-276598-tm0yj2sn	329	22	state	state	NN
cord-276598-tm0yj2sn	329	23	of	of	IN
cord-276598-tm0yj2sn	329	24	copper	copper	NN
cord-276598-tm0yj2sn	329	25	catalyst	catalyst	NN
cord-276598-tm0yj2sn	329	26	,	,	,
cord-276598-tm0yj2sn	329	27	and	and	CC
cord-276598-tm0yj2sn	329	28	that	that	IN
cord-276598-tm0yj2sn	329	29	the	the	DT
cord-276598-tm0yj2sn	329	30	primary	primary	JJ
cord-276598-tm0yj2sn	329	31	amines	amine	NNS
cord-276598-tm0yj2sn	329	32	coupled	couple	VBN
cord-276598-tm0yj2sn	329	33	better	well	RBR
cord-276598-tm0yj2sn	329	34	than	than	IN
cord-276598-tm0yj2sn	329	35	the	the	DT
cord-276598-tm0yj2sn	329	36	secondary	secondary	JJ
cord-276598-tm0yj2sn	329	37	and	and	CC
cord-276598-tm0yj2sn	329	38	tertiary	tertiary	JJ
cord-276598-tm0yj2sn	329	39	amines	amine	NNS
cord-276598-tm0yj2sn	329	40	due	due	IN
cord-276598-tm0yj2sn	329	41	to	to	IN
cord-276598-tm0yj2sn	329	42	the	the	DT
cord-276598-tm0yj2sn	329	43	reduced	reduce	VBN
cord-276598-tm0yj2sn	329	44	steric	steric	JJ
cord-276598-tm0yj2sn	329	45	hindrance	hindrance	NN
cord-276598-tm0yj2sn	329	46	.	.	.
cord-276598-tm0yj2sn	330	1	The	the	DT
cord-276598-tm0yj2sn	330	2	method	method	NN
cord-276598-tm0yj2sn	330	3	was	be	VBD
cord-276598-tm0yj2sn	330	4	slightly	slightly	RB
cord-276598-tm0yj2sn	330	5	modified	modify	VBN
cord-276598-tm0yj2sn	330	6	for	for	IN
cord-276598-tm0yj2sn	330	7	the	the	DT
cord-276598-tm0yj2sn	330	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	330	9	of	of	IN
cord-276598-tm0yj2sn	330	10	some	some	DT
cord-276598-tm0yj2sn	330	11	important	important	JJ
cord-276598-tm0yj2sn	330	12	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	330	13	amino	amino	NN
cord-276598-tm0yj2sn	330	14	compounds	compound	NNS
cord-276598-tm0yj2sn	330	15	such	such	JJ
cord-276598-tm0yj2sn	330	16	as	as	IN
cord-276598-tm0yj2sn	330	17	ethyl	ethyl	NN
cord-276598-tm0yj2sn	330	18	(	(	-LRB-
cord-276598-tm0yj2sn	330	19	diethoxyphosphoryl)glycinate	diethoxyphosphoryl)glycinate	NNP
cord-276598-tm0yj2sn	330	20	,	,	,
cord-276598-tm0yj2sn	330	21	etc	etc	FW
cord-276598-tm0yj2sn	330	22	.	.	.
cord-276598-tm0yj2sn	331	1	(	(	-LRB-
cord-276598-tm0yj2sn	331	2	12	12	CD
cord-276598-tm0yj2sn	331	3	-	-	SYM
cord-276598-tm0yj2sn	331	4	15	15	CD
cord-276598-tm0yj2sn	331	5	)	)	-RRB-
cord-276598-tm0yj2sn	331	6	(	(	-LRB-
cord-276598-tm0yj2sn	331	7	Figure	figure	NN
cord-276598-tm0yj2sn	331	8	6	6	CD
cord-276598-tm0yj2sn	331	9	)	)	-RRB-
cord-276598-tm0yj2sn	331	10	.	.	.
cord-276598-tm0yj2sn	332	1	(	(	-LRB-
cord-276598-tm0yj2sn	332	2	Table	table	NN
cord-276598-tm0yj2sn	332	3	1	1	CD
cord-276598-tm0yj2sn	332	4	,	,	,
cord-276598-tm0yj2sn	332	5	route	route	NN
cord-276598-tm0yj2sn	332	6	b	b	NN
cord-276598-tm0yj2sn	332	7	)	)	-RRB-
cord-276598-tm0yj2sn	332	8	[	[	-LRB-
cord-276598-tm0yj2sn	332	9	104	104	CD
cord-276598-tm0yj2sn	332	10	]	]	-RRB-
cord-276598-tm0yj2sn	332	11	.	.	.
cord-276598-tm0yj2sn	333	1	Although	although	IN
cord-276598-tm0yj2sn	333	2	paraor	paraor	NNP
cord-276598-tm0yj2sn	333	3	meta	meta	NNP
cord-276598-tm0yj2sn	333	4	-	-	HYPH
cord-276598-tm0yj2sn	333	5	substituted	substitute	VBN
cord-276598-tm0yj2sn	333	6	aryl	aryl	NN
cord-276598-tm0yj2sn	333	7	amines	amine	NNS
cord-276598-tm0yj2sn	333	8	were	be	VBD
cord-276598-tm0yj2sn	333	9	very	very	RB
cord-276598-tm0yj2sn	333	10	effective	effective	JJ
cord-276598-tm0yj2sn	333	11	substrates	substrate	NNS
cord-276598-tm0yj2sn	333	12	in	in	IN
cord-276598-tm0yj2sn	333	13	this	this	DT
cord-276598-tm0yj2sn	333	14	reaction	reaction	NN
cord-276598-tm0yj2sn	333	15	,	,	,
cord-276598-tm0yj2sn	333	16	the	the	DT
cord-276598-tm0yj2sn	333	17	conversions	conversion	NNS
cord-276598-tm0yj2sn	333	18	observed	observe	VBN
cord-276598-tm0yj2sn	333	19	with	with	IN
cord-276598-tm0yj2sn	333	20	ortho	ortho	NNP
cord-276598-tm0yj2sn	333	21	-	-	HYPH
cord-276598-tm0yj2sn	333	22	substituted	substitute	VBN
cord-276598-tm0yj2sn	333	23	aryl	aryl	NN
cord-276598-tm0yj2sn	333	24	amines	amine	NNS
cord-276598-tm0yj2sn	333	25	or	or	CC
cord-276598-tm0yj2sn	333	26	aryl	aryl	NN
cord-276598-tm0yj2sn	334	1	amines	amine	NNS
cord-276598-tm0yj2sn	334	2	with	with	IN
cord-276598-tm0yj2sn	334	3	strong	strong	JJ
cord-276598-tm0yj2sn	334	4	electron	electron	NN
cord-276598-tm0yj2sn	334	5	-	-	HYPH
cord-276598-tm0yj2sn	334	6	withdrawing	withdraw	VBG
cord-276598-tm0yj2sn	334	7	Another	another	DT
cord-276598-tm0yj2sn	334	8	copper	copper	NN
cord-276598-tm0yj2sn	334	9	-	-	HYPH
cord-276598-tm0yj2sn	334	10	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	334	11	aerobic	aerobic	JJ
cord-276598-tm0yj2sn	334	12	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	334	13	cross	cross	JJ
cord-276598-tm0yj2sn	334	14	-	-	JJ
cord-276598-tm0yj2sn	334	15	coupling	coupling	JJ
cord-276598-tm0yj2sn	334	16	reaction	reaction	NN
cord-276598-tm0yj2sn	334	17	reported	report	VBN
cord-276598-tm0yj2sn	334	18	by	by	IN
cord-276598-tm0yj2sn	334	19	Wang	Wang	NNP
cord-276598-tm0yj2sn	334	20	et	et	NNP
cord-276598-tm0yj2sn	334	21	al	al	NNP
cord-276598-tm0yj2sn	334	22	.	.	.
cord-276598-tm0yj2sn	335	1	in	in	IN
cord-276598-tm0yj2sn	335	2	2013	2013	CD
cord-276598-tm0yj2sn	335	3	involved	involve	VBD
cord-276598-tm0yj2sn	335	4	the	the	DT
cord-276598-tm0yj2sn	335	5	coupling	coupling	NN
cord-276598-tm0yj2sn	335	6	of	of	IN
cord-276598-tm0yj2sn	335	7	aryl	aryl	NN
cord-276598-tm0yj2sn	335	8	amines	amine	NNS
cord-276598-tm0yj2sn	335	9	(	(	-LRB-
cord-276598-tm0yj2sn	335	10	1.5	1.5	CD
cord-276598-tm0yj2sn	335	11	eq	eq	NN
cord-276598-tm0yj2sn	335	12	.	.	.
cord-276598-tm0yj2sn	335	13	)	)	-RRB-
cord-276598-tm0yj2sn	335	14	and	and	CC
cord-276598-tm0yj2sn	335	15	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	335	16	H	H	NNP
cord-276598-tm0yj2sn	335	17	-	-	HYPH
cord-276598-tm0yj2sn	335	18	phosphonates	phosphonates	NNP
cord-276598-tm0yj2sn	335	19	(	(	-LRB-
cord-276598-tm0yj2sn	335	20	RO	RO	NNP
cord-276598-tm0yj2sn	335	21	)	)	-RRB-
cord-276598-tm0yj2sn	335	22	2	2	CD
cord-276598-tm0yj2sn	336	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	337	1	(	(	-LRB-
cord-276598-tm0yj2sn	337	2	R	r	NN
cord-276598-tm0yj2sn	337	3	=	=	FW
cord-276598-tm0yj2sn	337	4	Et	Et	NNP
cord-276598-tm0yj2sn	337	5	,	,	,
cord-276598-tm0yj2sn	337	6	i	i	NN
cord-276598-tm0yj2sn	337	7	-	-	HYPH
cord-276598-tm0yj2sn	337	8	Pr	Pr	NNP
cord-276598-tm0yj2sn	337	9	,	,	,
cord-276598-tm0yj2sn	337	10	Bu	Bu	NNP
cord-276598-tm0yj2sn	337	11	;	;	:
cord-276598-tm0yj2sn	337	12	1	1	CD
cord-276598-tm0yj2sn	337	13	eq	eq	NN
cord-276598-tm0yj2sn	337	14	.	.	.
cord-276598-tm0yj2sn	337	15	)	)	-RRB-
cord-276598-tm0yj2sn	337	16	in	in	IN
cord-276598-tm0yj2sn	337	17	the	the	DT
cord-276598-tm0yj2sn	337	18	presence	presence	NN
cord-276598-tm0yj2sn	337	19	of	of	IN
cord-276598-tm0yj2sn	337	20	CuBr	CuBr	NNP
cord-276598-tm0yj2sn	337	21	(	(	-LRB-
cord-276598-tm0yj2sn	337	22	5	5	CD
cord-276598-tm0yj2sn	337	23	mol%	mol%	CD
cord-276598-tm0yj2sn	337	24	)	)	-RRB-
cord-276598-tm0yj2sn	337	25	to	to	TO
cord-276598-tm0yj2sn	337	26	give	give	VB
cord-276598-tm0yj2sn	337	27	P	p	NN
cord-276598-tm0yj2sn	337	28	-	-	HYPH
cord-276598-tm0yj2sn	337	29	Ns	Ns	NNP
cord-276598-tm0yj2sn	337	30	(	(	-LRB-
cord-276598-tm0yj2sn	337	31	Table	table	NN
cord-276598-tm0yj2sn	337	32	1	1	CD
cord-276598-tm0yj2sn	337	33	,	,	,
cord-276598-tm0yj2sn	337	34	route	route	NN
cord-276598-tm0yj2sn	337	35	b	b	NN
cord-276598-tm0yj2sn	337	36	)	)	-RRB-
cord-276598-tm0yj2sn	337	37	[	[	-LRB-
cord-276598-tm0yj2sn	337	38	104	104	CD
cord-276598-tm0yj2sn	337	39	]	]	-RRB-
cord-276598-tm0yj2sn	337	40	.	.	.
cord-276598-tm0yj2sn	338	1	Although	although	IN
cord-276598-tm0yj2sn	338	2	paraor	paraor	NNP
cord-276598-tm0yj2sn	338	3	meta	meta	NNP
cord-276598-tm0yj2sn	338	4	-	-	HYPH
cord-276598-tm0yj2sn	338	5	substituted	substitute	VBN
cord-276598-tm0yj2sn	338	6	aryl	aryl	NN
cord-276598-tm0yj2sn	338	7	amines	amine	NNS
cord-276598-tm0yj2sn	338	8	were	be	VBD
cord-276598-tm0yj2sn	338	9	very	very	RB
cord-276598-tm0yj2sn	338	10	effective	effective	JJ
cord-276598-tm0yj2sn	338	11	substrates	substrate	NNS
cord-276598-tm0yj2sn	338	12	in	in	IN
cord-276598-tm0yj2sn	338	13	this	this	DT
cord-276598-tm0yj2sn	338	14	reaction	reaction	NN
cord-276598-tm0yj2sn	338	15	,	,	,
cord-276598-tm0yj2sn	338	16	the	the	DT
cord-276598-tm0yj2sn	338	17	conversions	conversion	NNS
cord-276598-tm0yj2sn	338	18	observed	observe	VBN
cord-276598-tm0yj2sn	338	19	with	with	IN
cord-276598-tm0yj2sn	338	20	ortho	ortho	NNP
cord-276598-tm0yj2sn	338	21	-	-	HYPH
cord-276598-tm0yj2sn	338	22	substituted	substitute	VBN
cord-276598-tm0yj2sn	338	23	aryl	aryl	NN
cord-276598-tm0yj2sn	338	24	amines	amine	NNS
cord-276598-tm0yj2sn	338	25	or	or	CC
cord-276598-tm0yj2sn	338	26	aryl	aryl	NN
cord-276598-tm0yj2sn	339	1	amines	amine	NNS
cord-276598-tm0yj2sn	339	2	with	with	IN
cord-276598-tm0yj2sn	339	3	strong	strong	JJ
cord-276598-tm0yj2sn	339	4	electron	electron	NN
cord-276598-tm0yj2sn	339	5	-	-	HYPH
cord-276598-tm0yj2sn	339	6	withdrawing	withdraw	VBG
cord-276598-tm0yj2sn	339	7	substituents	substituent	NNS
cord-276598-tm0yj2sn	339	8	(	(	-LRB-
cord-276598-tm0yj2sn	339	9	e.g.	e.g.	RB
cord-276598-tm0yj2sn	339	10	,	,	,
cord-276598-tm0yj2sn	339	11	4-nitroaniline	4-nitroaniline	CD
cord-276598-tm0yj2sn	339	12	)	)	-RRB-
cord-276598-tm0yj2sn	339	13	as	as	RB
cord-276598-tm0yj2sn	339	14	well	well	RB
cord-276598-tm0yj2sn	339	15	as	as	IN
cord-276598-tm0yj2sn	339	16	alkylamines	alkylamine	NNS
cord-276598-tm0yj2sn	339	17	were	be	VBD
cord-276598-tm0yj2sn	339	18	very	very	RB
cord-276598-tm0yj2sn	339	19	poor	poor	JJ
cord-276598-tm0yj2sn	339	20	.	.	.
cord-276598-tm0yj2sn	340	1	The	the	DT
cord-276598-tm0yj2sn	340	2	effectiveness	effectiveness	NN
cord-276598-tm0yj2sn	340	3	of	of	IN
cord-276598-tm0yj2sn	340	4	the	the	DT
cord-276598-tm0yj2sn	340	5	reaction	reaction	NN
cord-276598-tm0yj2sn	340	6	with	with	IN
cord-276598-tm0yj2sn	340	7	diaryl	diaryl	NNP
cord-276598-tm0yj2sn	340	8	H	H	NNP
cord-276598-tm0yj2sn	340	9	-	-	HYPH
cord-276598-tm0yj2sn	340	10	phosphonates	phosphonates	NNP
cord-276598-tm0yj2sn	340	11	was	be	VBD
cord-276598-tm0yj2sn	340	12	not	not	RB
cord-276598-tm0yj2sn	340	13	reported	report	VBN
cord-276598-tm0yj2sn	340	14	.	.	.
cord-276598-tm0yj2sn	341	1	In	in	IN
cord-276598-tm0yj2sn	341	2	2015	2015	CD
cord-276598-tm0yj2sn	341	3	,	,	,
cord-276598-tm0yj2sn	341	4	Fe	Fe	NNP
cord-276598-tm0yj2sn	341	5	3	3	CD
cord-276598-tm0yj2sn	341	6	O	o	NN
cord-276598-tm0yj2sn	341	7	4	4	CD
cord-276598-tm0yj2sn	341	8	@MgO	@MgO	NNS
cord-276598-tm0yj2sn	341	9	nanoparticles	nanoparticle	NNS
cord-276598-tm0yj2sn	341	10	were	be	VBD
cord-276598-tm0yj2sn	341	11	used	use	VBN
cord-276598-tm0yj2sn	341	12	as	as	IN
cord-276598-tm0yj2sn	341	13	a	a	DT
cord-276598-tm0yj2sn	341	14	catalyst	catalyst	NN
cord-276598-tm0yj2sn	341	15	to	to	TO
cord-276598-tm0yj2sn	341	16	synthesize	synthesize	VB
cord-276598-tm0yj2sn	341	17	P	P	NNP
cord-276598-tm0yj2sn	341	18	-	-	HYPH
cord-276598-tm0yj2sn	341	19	N	N	NNP
cord-276598-tm0yj2sn	341	20	from	from	IN
cord-276598-tm0yj2sn	341	21	primary	primary	JJ
cord-276598-tm0yj2sn	341	22	amines	amine	NNS
cord-276598-tm0yj2sn	341	23	and	and	CC
cord-276598-tm0yj2sn	341	24	H	h	NN
cord-276598-tm0yj2sn	341	25	-	-	HYPH
cord-276598-tm0yj2sn	341	26	P	p	NN
cord-276598-tm0yj2sn	341	27	via	via	IN
cord-276598-tm0yj2sn	341	28	the	the	DT
cord-276598-tm0yj2sn	341	29	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	341	30	-	-	HYPH
cord-276598-tm0yj2sn	341	31	Todd	Todd	NNP
cord-276598-tm0yj2sn	341	32	coupling	coupling	NN
cord-276598-tm0yj2sn	341	33	reaction	reaction	NN
cord-276598-tm0yj2sn	341	34	with	with	IN
cord-276598-tm0yj2sn	341	35	CCl	CCl	NNS
cord-276598-tm0yj2sn	341	36	4	4	CD
cord-276598-tm0yj2sn	341	37	(	(	-LRB-
cord-276598-tm0yj2sn	341	38	Table	table	NN
cord-276598-tm0yj2sn	341	39	1	1	CD
cord-276598-tm0yj2sn	341	40	,	,	,
cord-276598-tm0yj2sn	341	41	route	route	NN
cord-276598-tm0yj2sn	341	42	c	c	NN
cord-276598-tm0yj2sn	341	43	)	)	-RRB-
cord-276598-tm0yj2sn	341	44	[	[	-LRB-
cord-276598-tm0yj2sn	341	45	105	105	CD
cord-276598-tm0yj2sn	341	46	]	]	-RRB-
cord-276598-tm0yj2sn	341	47	.	.	.
cord-276598-tm0yj2sn	342	1	After	after	IN
cord-276598-tm0yj2sn	342	2	column	column	NN
cord-276598-tm0yj2sn	342	3	chromatography	chromatography	NN
cord-276598-tm0yj2sn	342	4	(	(	-LRB-
cord-276598-tm0yj2sn	342	5	on	on	IN
cord-276598-tm0yj2sn	342	6	silica	silica	NN
cord-276598-tm0yj2sn	342	7	)	)	-RRB-
cord-276598-tm0yj2sn	342	8	,	,	,
cord-276598-tm0yj2sn	342	9	P	P	NNP
cord-276598-tm0yj2sn	342	10	-	-	HYPH
cord-276598-tm0yj2sn	342	11	Ns	Ns	NNP
cord-276598-tm0yj2sn	342	12	were	be	VBD
cord-276598-tm0yj2sn	342	13	isolated	isolate	VBN
cord-276598-tm0yj2sn	342	14	in	in	IN
cord-276598-tm0yj2sn	342	15	52	52	CD
cord-276598-tm0yj2sn	342	16	-	-	SYM
cord-276598-tm0yj2sn	342	17	85	85	CD
cord-276598-tm0yj2sn	342	18	%	%	NN
cord-276598-tm0yj2sn	342	19	yield	yield	NN
cord-276598-tm0yj2sn	342	20	.	.	.
cord-276598-tm0yj2sn	343	1	The	the	DT
cord-276598-tm0yj2sn	343	2	Fe	Fe	NNP
cord-276598-tm0yj2sn	343	3	3	3	CD
cord-276598-tm0yj2sn	343	4	O	o	NN
cord-276598-tm0yj2sn	343	5	4	4	CD
cord-276598-tm0yj2sn	343	6	@MgO	@MgO	NNS
cord-276598-tm0yj2sn	343	7	nanoparticles	nanoparticle	NNS
cord-276598-tm0yj2sn	343	8	were	be	VBD
cord-276598-tm0yj2sn	343	9	recycled	recycle	VBN
cord-276598-tm0yj2sn	343	10	by	by	IN
cord-276598-tm0yj2sn	343	11	washing	wash	VBG
cord-276598-tm0yj2sn	343	12	successively	successively	RB
cord-276598-tm0yj2sn	343	13	with	with	IN
cord-276598-tm0yj2sn	343	14	H	h	NN
cord-276598-tm0yj2sn	343	15	2	2	CD
cord-276598-tm0yj2sn	343	16	O	o	NN
cord-276598-tm0yj2sn	343	17	and	and	CC
cord-276598-tm0yj2sn	343	18	MeOH	MeOH	NNS
cord-276598-tm0yj2sn	343	19	and	and	CC
cord-276598-tm0yj2sn	343	20	drying	dry	VBG
cord-276598-tm0yj2sn	343	21	before	before	IN
cord-276598-tm0yj2sn	343	22	reuse	reuse	NN
cord-276598-tm0yj2sn	343	23	.	.	.
cord-276598-tm0yj2sn	344	1	Although	although	IN
cord-276598-tm0yj2sn	344	2	the	the	DT
cord-276598-tm0yj2sn	344	3	scope	scope	NN
cord-276598-tm0yj2sn	344	4	of	of	IN
cord-276598-tm0yj2sn	344	5	the	the	DT
cord-276598-tm0yj2sn	344	6	transformation	transformation	NN
cord-276598-tm0yj2sn	344	7	was	be	VBD
cord-276598-tm0yj2sn	344	8	not	not	RB
cord-276598-tm0yj2sn	344	9	challenged	challenge	VBN
cord-276598-tm0yj2sn	344	10	by	by	IN
cord-276598-tm0yj2sn	344	11	investigating	investigate	VBG
cord-276598-tm0yj2sn	344	12	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	344	13	H	H	NNP
cord-276598-tm0yj2sn	344	14	-	-	HYPH
cord-276598-tm0yj2sn	344	15	Ps	Ps	NNP
cord-276598-tm0yj2sn	344	16	,	,	,
cord-276598-tm0yj2sn	344	17	this	this	DT
cord-276598-tm0yj2sn	344	18	route	route	NN
cord-276598-tm0yj2sn	344	19	offers	offer	VBZ
cord-276598-tm0yj2sn	344	20	some	some	DT
cord-276598-tm0yj2sn	344	21	advantages	advantage	NNS
cord-276598-tm0yj2sn	344	22	,	,	,
cord-276598-tm0yj2sn	344	23	such	such	JJ
cord-276598-tm0yj2sn	344	24	as	as	IN
cord-276598-tm0yj2sn	344	25	the	the	DT
cord-276598-tm0yj2sn	344	26	use	use	NN
cord-276598-tm0yj2sn	344	27	of	of	IN
cord-276598-tm0yj2sn	344	28	a	a	DT
cord-276598-tm0yj2sn	344	29	low	low	JJ
cord-276598-tm0yj2sn	344	30	-	-	HYPH
cord-276598-tm0yj2sn	344	31	cost	cost	NN
cord-276598-tm0yj2sn	344	32	reusable	reusable	JJ
cord-276598-tm0yj2sn	344	33	catalyst	catalyst	NN
cord-276598-tm0yj2sn	344	34	with	with	IN
cord-276598-tm0yj2sn	344	35	proven	prove	VBN
cord-276598-tm0yj2sn	344	36	activity	activity	NN
cord-276598-tm0yj2sn	344	37	for	for	IN
cord-276598-tm0yj2sn	344	38	up	up	IN
cord-276598-tm0yj2sn	344	39	to	to	TO
cord-276598-tm0yj2sn	344	40	four	four	CD
cord-276598-tm0yj2sn	344	41	consecutive	consecutive	JJ
cord-276598-tm0yj2sn	344	42	reactions	reaction	NNS
cord-276598-tm0yj2sn	344	43	.	.	.
cord-276598-tm0yj2sn	345	1	Purohit	Purohit	NNP
cord-276598-tm0yj2sn	345	2	et	et	NNP
cord-276598-tm0yj2sn	345	3	al	al	NNP
cord-276598-tm0yj2sn	345	4	.	.	NNP
cord-276598-tm0yj2sn	345	5	reported	report	VBD
cord-276598-tm0yj2sn	345	6	a	a	DT
cord-276598-tm0yj2sn	345	7	one	one	CD
cord-276598-tm0yj2sn	345	8	-	-	HYPH
cord-276598-tm0yj2sn	345	9	pot	pot	NN
cord-276598-tm0yj2sn	345	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	345	11	of	of	IN
cord-276598-tm0yj2sn	345	12	P	p	NN
cord-276598-tm0yj2sn	345	13	-	-	HYPH
cord-276598-tm0yj2sn	345	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	345	15	from	from	IN
cord-276598-tm0yj2sn	345	16	(	(	-LRB-
cord-276598-tm0yj2sn	345	17	RO	ro	NN
cord-276598-tm0yj2sn	345	18	)	)	-RRB-
cord-276598-tm0yj2sn	345	19	2	2	CD
cord-276598-tm0yj2sn	346	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	347	1	(	(	-LRB-
cord-276598-tm0yj2sn	347	2	R	r	NN
cord-276598-tm0yj2sn	347	3	=	=	FW
cord-276598-tm0yj2sn	347	4	Et	Et	NNP
cord-276598-tm0yj2sn	347	5	,	,	,
cord-276598-tm0yj2sn	347	6	Pr	Pr	NNP
cord-276598-tm0yj2sn	347	7	,	,	,
cord-276598-tm0yj2sn	347	8	i	i	NN
cord-276598-tm0yj2sn	347	9	-	-	HYPH
cord-276598-tm0yj2sn	347	10	Pr	pr	NN
cord-276598-tm0yj2sn	347	11	;	;	:
cord-276598-tm0yj2sn	347	12	1	1	CD
cord-276598-tm0yj2sn	347	13	eq	eq	NN
cord-276598-tm0yj2sn	347	14	.	.	.
cord-276598-tm0yj2sn	347	15	)	)	-RRB-
cord-276598-tm0yj2sn	347	16	and	and	CC
cord-276598-tm0yj2sn	347	17	amine	amine	NN
cord-276598-tm0yj2sn	347	18	in	in	IN
cord-276598-tm0yj2sn	347	19	the	the	DT
cord-276598-tm0yj2sn	347	20	presence	presence	NN
cord-276598-tm0yj2sn	347	21	of	of	IN
cord-276598-tm0yj2sn	347	22	CuCl	CuCl	NNP
cord-276598-tm0yj2sn	347	23	2	2	CD
cord-276598-tm0yj2sn	347	24	and	and	CC
cord-276598-tm0yj2sn	347	25	Cs	Cs	NNP
cord-276598-tm0yj2sn	347	26	2	2	CD
cord-276598-tm0yj2sn	347	27	CO	CO	NNP
cord-276598-tm0yj2sn	347	28	3	3	CD
cord-276598-tm0yj2sn	347	29	(	(	-LRB-
cord-276598-tm0yj2sn	347	30	Table	table	NN
cord-276598-tm0yj2sn	347	31	1	1	CD
cord-276598-tm0yj2sn	347	32	,	,	,
cord-276598-tm0yj2sn	347	33	route	route	NN
cord-276598-tm0yj2sn	347	34	d	d	NN
cord-276598-tm0yj2sn	347	35	)	)	-RRB-
cord-276598-tm0yj2sn	347	36	[	[	-LRB-
cord-276598-tm0yj2sn	347	37	106	106	CD
cord-276598-tm0yj2sn	347	38	]	]	-RRB-
cord-276598-tm0yj2sn	347	39	.	.	.
cord-276598-tm0yj2sn	348	1	The	the	DT
cord-276598-tm0yj2sn	348	2	reported	report	VBN
cord-276598-tm0yj2sn	348	3	yields	yield	NNS
cord-276598-tm0yj2sn	348	4	for	for	IN
cord-276598-tm0yj2sn	348	5	the	the	DT
cord-276598-tm0yj2sn	348	6	variety	variety	NN
cord-276598-tm0yj2sn	348	7	of	of	IN
cord-276598-tm0yj2sn	348	8	desired	desire	VBN
cord-276598-tm0yj2sn	348	9	products	product	NNS
cord-276598-tm0yj2sn	348	10	were	be	VBD
cord-276598-tm0yj2sn	348	11	in	in	IN
cord-276598-tm0yj2sn	348	12	the	the	DT
cord-276598-tm0yj2sn	348	13	range	range	NN
cord-276598-tm0yj2sn	348	14	of	of	IN
cord-276598-tm0yj2sn	348	15	25	25	CD
cord-276598-tm0yj2sn	348	16	-	-	SYM
cord-276598-tm0yj2sn	348	17	93	93	CD
cord-276598-tm0yj2sn	348	18	%	%	NN
cord-276598-tm0yj2sn	348	19	as	as	IN
cord-276598-tm0yj2sn	348	20	determined	determine	VBN
cord-276598-tm0yj2sn	348	21	by	by	IN
cord-276598-tm0yj2sn	348	22	31	31	CD
cord-276598-tm0yj2sn	348	23	P	p	NN
cord-276598-tm0yj2sn	348	24	NMR	nmr	NN
cord-276598-tm0yj2sn	348	25	spectroscopy	spectroscopy	NN
cord-276598-tm0yj2sn	348	26	.	.	.
cord-276598-tm0yj2sn	349	1	A	a	DT
cord-276598-tm0yj2sn	349	2	Cu(II	cu(ii	NN
cord-276598-tm0yj2sn	349	3	)	)	-RRB-
cord-276598-tm0yj2sn	349	4	catalyst	catalyst	NN
cord-276598-tm0yj2sn	349	5	,	,	,
cord-276598-tm0yj2sn	349	6	a	a	DT
cord-276598-tm0yj2sn	349	7	base	base	NN
cord-276598-tm0yj2sn	349	8	,	,	,
cord-276598-tm0yj2sn	349	9	and	and	CC
cord-276598-tm0yj2sn	349	10	air	air	NN
cord-276598-tm0yj2sn	349	11	as	as	IN
cord-276598-tm0yj2sn	349	12	an	an	DT
cord-276598-tm0yj2sn	349	13	oxidant	oxidant	NN
cord-276598-tm0yj2sn	349	14	were	be	VBD
cord-276598-tm0yj2sn	349	15	used	use	VBN
cord-276598-tm0yj2sn	349	16	to	to	TO
cord-276598-tm0yj2sn	349	17	synthesize	synthesize	VB
cord-276598-tm0yj2sn	349	18	N	N	NNP
cord-276598-tm0yj2sn	349	19	-	-	HYPH
cord-276598-tm0yj2sn	349	20	acylphosphoramidates	acylphosphoramidates	NNP
cord-276598-tm0yj2sn	349	21	(	(	-LRB-
cord-276598-tm0yj2sn	349	22	AcP	AcP	NNP
cord-276598-tm0yj2sn	349	23	-	-	HYPH
cord-276598-tm0yj2sn	349	24	N	N	NNP
cord-276598-tm0yj2sn	349	25	)	)	-RRB-
cord-276598-tm0yj2sn	349	26	from	from	IN
cord-276598-tm0yj2sn	349	27	(	(	-LRB-
cord-276598-tm0yj2sn	349	28	RO	RO	NNP
cord-276598-tm0yj2sn	349	29	)	)	-RRB-
cord-276598-tm0yj2sn	349	30	2	2	CD
cord-276598-tm0yj2sn	350	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	351	1	(	(	-LRB-
cord-276598-tm0yj2sn	351	2	R	r	NN
cord-276598-tm0yj2sn	351	3	=	=	NFP
cord-276598-tm0yj2sn	352	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	352	2	,	,	,
cord-276598-tm0yj2sn	352	3	Et	Et	NNP
cord-276598-tm0yj2sn	352	4	,	,	,
cord-276598-tm0yj2sn	352	5	i	i	NN
cord-276598-tm0yj2sn	352	6	-	-	HYPH
cord-276598-tm0yj2sn	352	7	Pr	Pr	NNP
cord-276598-tm0yj2sn	352	8	,	,	,
cord-276598-tm0yj2sn	352	9	Bu	Bu	NNP
cord-276598-tm0yj2sn	352	10	)	)	-RRB-
cord-276598-tm0yj2sn	352	11	and	and	CC
cord-276598-tm0yj2sn	352	12	an	an	DT
cord-276598-tm0yj2sn	352	13	amide	amide	NN
cord-276598-tm0yj2sn	352	14	via	via	IN
cord-276598-tm0yj2sn	352	15	an	an	DT
cord-276598-tm0yj2sn	352	16	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	352	17	cross	cross	JJ
cord-276598-tm0yj2sn	352	18	-	-	JJ
cord-276598-tm0yj2sn	352	19	coupling	coupling	JJ
cord-276598-tm0yj2sn	352	20	reaction	reaction	NN
cord-276598-tm0yj2sn	352	21	according	accord	VBG
cord-276598-tm0yj2sn	352	22	to	to	IN
cord-276598-tm0yj2sn	352	23	Mizuno	Mizuno	NNP
cord-276598-tm0yj2sn	352	24	et	et	NNP
cord-276598-tm0yj2sn	352	25	al	al	NNP
cord-276598-tm0yj2sn	352	26	.	.	.
cord-276598-tm0yj2sn	353	1	(	(	-LRB-
cord-276598-tm0yj2sn	353	2	Table	table	NN
cord-276598-tm0yj2sn	353	3	1	1	CD
cord-276598-tm0yj2sn	353	4	,	,	,
cord-276598-tm0yj2sn	353	5	route	route	NN
cord-276598-tm0yj2sn	353	6	e	e	NN
cord-276598-tm0yj2sn	353	7	)	)	-RRB-
cord-276598-tm0yj2sn	354	1	[	[	-LRB-
cord-276598-tm0yj2sn	354	2	107	107	CD
cord-276598-tm0yj2sn	354	3	]	]	-RRB-
cord-276598-tm0yj2sn	354	4	.	.	.
cord-276598-tm0yj2sn	355	1	The	the	DT
cord-276598-tm0yj2sn	355	2	scope	scope	NN
cord-276598-tm0yj2sn	355	3	of	of	IN
cord-276598-tm0yj2sn	355	4	the	the	DT
cord-276598-tm0yj2sn	355	5	reaction	reaction	NN
cord-276598-tm0yj2sn	355	6	was	be	VBD
cord-276598-tm0yj2sn	355	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	355	8	by	by	IN
cord-276598-tm0yj2sn	355	9	changing	change	VBG
cord-276598-tm0yj2sn	355	10	the	the	DT
cord-276598-tm0yj2sn	355	11	R	r	NN
cord-276598-tm0yj2sn	355	12	substituent	substituent	NN
cord-276598-tm0yj2sn	355	13	as	as	RB
cord-276598-tm0yj2sn	355	14	well	well	RB
cord-276598-tm0yj2sn	355	15	as	as	IN
cord-276598-tm0yj2sn	355	16	the	the	DT
cord-276598-tm0yj2sn	355	17	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	355	18	nucleophiles	nucleophile	NNS
cord-276598-tm0yj2sn	355	19	(	(	-LRB-
cord-276598-tm0yj2sn	355	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	355	21	,	,	,
cord-276598-tm0yj2sn	355	22	urea	urea	NN
cord-276598-tm0yj2sn	355	23	,	,	,
cord-276598-tm0yj2sn	355	24	oxazolidinone	oxazolidinone	NN
cord-276598-tm0yj2sn	355	25	,	,	,
cord-276598-tm0yj2sn	355	26	indole	indole	NN
cord-276598-tm0yj2sn	355	27	,	,	,
cord-276598-tm0yj2sn	355	28	pyrrolidinone	pyrrolidinone	NN
cord-276598-tm0yj2sn	355	29	,	,	,
cord-276598-tm0yj2sn	355	30	lactam	lactam	NNS
cord-276598-tm0yj2sn	355	31	,	,	,
cord-276598-tm0yj2sn	355	32	and	and	CC
cord-276598-tm0yj2sn	355	33	sulfonamide	sulfonamide	NN
cord-276598-tm0yj2sn	355	34	derivatives	derivative	NNS
cord-276598-tm0yj2sn	355	35	)	)	-RRB-
cord-276598-tm0yj2sn	355	36	.	.	.
cord-276598-tm0yj2sn	356	1	Column	column	NN
cord-276598-tm0yj2sn	356	2	chromatography	chromatography	NN
cord-276598-tm0yj2sn	356	3	(	(	-LRB-
cord-276598-tm0yj2sn	356	4	on	on	IN
cord-276598-tm0yj2sn	356	5	silica	silica	NN
cord-276598-tm0yj2sn	356	6	)	)	-RRB-
cord-276598-tm0yj2sn	356	7	using	use	VBG
cord-276598-tm0yj2sn	356	8	different	different	JJ
cord-276598-tm0yj2sn	356	9	solvent	solvent	NN
cord-276598-tm0yj2sn	356	10	mixtures	mixture	NNS
cord-276598-tm0yj2sn	356	11	was	be	VBD
cord-276598-tm0yj2sn	356	12	used	use	VBN
cord-276598-tm0yj2sn	356	13	to	to	TO
cord-276598-tm0yj2sn	356	14	purify	purify	VB
cord-276598-tm0yj2sn	356	15	the	the	DT
cord-276598-tm0yj2sn	356	16	desired	desire	VBN
cord-276598-tm0yj2sn	356	17	P	P	NNP
cord-276598-tm0yj2sn	356	18	-	-	HYPH
cord-276598-tm0yj2sn	356	19	Ns	Ns	NNP
cord-276598-tm0yj2sn	356	20	in	in	IN
cord-276598-tm0yj2sn	356	21	52	52	CD
cord-276598-tm0yj2sn	356	22	-	-	SYM
cord-276598-tm0yj2sn	356	23	99	99	CD
cord-276598-tm0yj2sn	356	24	%	%	NN
cord-276598-tm0yj2sn	356	25	yield	yield	NN
cord-276598-tm0yj2sn	356	26	.	.	.
cord-276598-tm0yj2sn	357	1	Through	through	IN
cord-276598-tm0yj2sn	357	2	the	the	DT
cord-276598-tm0yj2sn	357	3	reagent	reagent	NN
cord-276598-tm0yj2sn	357	4	screening	screening	NN
cord-276598-tm0yj2sn	357	5	,	,	,
cord-276598-tm0yj2sn	357	6	Mizuno	Mizuno	NNP
cord-276598-tm0yj2sn	357	7	et	et	NNP
cord-276598-tm0yj2sn	357	8	al	al	NNP
cord-276598-tm0yj2sn	357	9	.	.	.
cord-276598-tm0yj2sn	358	1	[	[	-LRB-
cord-276598-tm0yj2sn	358	2	107	107	CD
cord-276598-tm0yj2sn	358	3	]	]	-RRB-
cord-276598-tm0yj2sn	358	4	found	find	VBD
cord-276598-tm0yj2sn	358	5	that	that	IN
cord-276598-tm0yj2sn	358	6	Cu(OTf	cu(otf	NN
cord-276598-tm0yj2sn	358	7	)	)	-RRB-
cord-276598-tm0yj2sn	358	8	2	2	CD
cord-276598-tm0yj2sn	358	9	gave	give	VBD
cord-276598-tm0yj2sn	358	10	similar	similar	JJ
cord-276598-tm0yj2sn	358	11	cross	cross	JJ
cord-276598-tm0yj2sn	358	12	-	-	JJ
cord-276598-tm0yj2sn	358	13	coupling	coupling	JJ
cord-276598-tm0yj2sn	358	14	results	result	NNS
cord-276598-tm0yj2sn	358	15	as	as	IN
cord-276598-tm0yj2sn	358	16	Cu(OAc	Cu(OAc	NNS
cord-276598-tm0yj2sn	358	17	)	)	-RRB-
cord-276598-tm0yj2sn	358	18	2	2	CD
cord-276598-tm0yj2sn	358	19	,	,	,
cord-276598-tm0yj2sn	358	20	while	while	IN
cord-276598-tm0yj2sn	358	21	other	other	JJ
cord-276598-tm0yj2sn	358	22	Cu	Cu	NNP
cord-276598-tm0yj2sn	358	23	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	358	24	such	such	JJ
cord-276598-tm0yj2sn	358	25	as	as	IN
cord-276598-tm0yj2sn	358	26	CuCl	CuCl	NNP
cord-276598-tm0yj2sn	358	27	2	2	CD
cord-276598-tm0yj2sn	358	28	and	and	CC
cord-276598-tm0yj2sn	358	29	CuSO	CuSO	NNP
cord-276598-tm0yj2sn	358	30	4	4	CD
cord-276598-tm0yj2sn	358	31	and	and	CC
cord-276598-tm0yj2sn	358	32	other	other	JJ
cord-276598-tm0yj2sn	358	33	transition	transition	NN
cord-276598-tm0yj2sn	358	34	metal	metal	NN
cord-276598-tm0yj2sn	358	35	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	358	36	(	(	-LRB-
cord-276598-tm0yj2sn	358	37	e.g.	e.g.	RB
cord-276598-tm0yj2sn	358	38	,	,	,
cord-276598-tm0yj2sn	358	39	Co(OAc	Co(OAc	NNS
cord-276598-tm0yj2sn	358	40	)	)	-RRB-
cord-276598-tm0yj2sn	358	41	2	2	CD
cord-276598-tm0yj2sn	358	42	.4H	.4h	SYM
cord-276598-tm0yj2sn	358	43	2	2	CD
cord-276598-tm0yj2sn	358	44	O	o	NN
cord-276598-tm0yj2sn	358	45	,	,	,
cord-276598-tm0yj2sn	358	46	Fe(OAc	Fe(OAc	NNS
cord-276598-tm0yj2sn	358	47	)	)	-RRB-
cord-276598-tm0yj2sn	358	48	2	2	CD
cord-276598-tm0yj2sn	358	49	)	)	-RRB-
cord-276598-tm0yj2sn	358	50	were	be	VBD
cord-276598-tm0yj2sn	358	51	not	not	RB
cord-276598-tm0yj2sn	358	52	selective	selective	JJ
cord-276598-tm0yj2sn	358	53	or	or	CC
cord-276598-tm0yj2sn	358	54	completely	completely	RB
cord-276598-tm0yj2sn	358	55	ineffective	ineffective	JJ
cord-276598-tm0yj2sn	358	56	.	.	.
cord-276598-tm0yj2sn	359	1	Another	another	DT
cord-276598-tm0yj2sn	359	2	copper	copper	NN
cord-276598-tm0yj2sn	359	3	-	-	HYPH
cord-276598-tm0yj2sn	359	4	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	359	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	359	6	of	of	IN
cord-276598-tm0yj2sn	359	7	P	p	NN
cord-276598-tm0yj2sn	359	8	-	-	HYPH
cord-276598-tm0yj2sn	359	9	N	N	NNP
cord-276598-tm0yj2sn	359	10	at	at	IN
cord-276598-tm0yj2sn	359	11	20	20	CD
cord-276598-tm0yj2sn	360	1	•	•	NNP
cord-276598-tm0yj2sn	361	1	C	C	NNP
cord-276598-tm0yj2sn	361	2	in	in	IN
cord-276598-tm0yj2sn	361	3	the	the	DT
cord-276598-tm0yj2sn	361	4	presence	presence	NN
cord-276598-tm0yj2sn	361	5	of	of	IN
cord-276598-tm0yj2sn	361	6	air	air	NN
cord-276598-tm0yj2sn	361	7	,	,	,
cord-276598-tm0yj2sn	361	8	reported	report	VBN
cord-276598-tm0yj2sn	361	9	by	by	IN
cord-276598-tm0yj2sn	361	10	Zhou	Zhou	NNP
cord-276598-tm0yj2sn	361	11	et	et	NNP
cord-276598-tm0yj2sn	361	12	al	al	NNP
cord-276598-tm0yj2sn	361	13	.	.	.
cord-276598-tm0yj2sn	362	1	,	,	,
cord-276598-tm0yj2sn	362	2	involved	involve	VBN
cord-276598-tm0yj2sn	362	3	reacting	react	VBG
cord-276598-tm0yj2sn	362	4	(	(	-LRB-
cord-276598-tm0yj2sn	362	5	RO	RO	NNP
cord-276598-tm0yj2sn	362	6	)	)	-RRB-
cord-276598-tm0yj2sn	362	7	2	2	CD
cord-276598-tm0yj2sn	363	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	364	1	(	(	-LRB-
cord-276598-tm0yj2sn	364	2	R	r	NN
cord-276598-tm0yj2sn	364	3	=	=	NFP
cord-276598-tm0yj2sn	365	1	Me	-PRON-	PRP
cord-276598-tm0yj2sn	365	2	,	,	,
cord-276598-tm0yj2sn	365	3	Et	Et	NNP
cord-276598-tm0yj2sn	365	4	,	,	,
cord-276598-tm0yj2sn	365	5	i	i	NN
cord-276598-tm0yj2sn	365	6	-	-	HYPH
cord-276598-tm0yj2sn	365	7	Pr	Pr	NNP
cord-276598-tm0yj2sn	365	8	,	,	,
cord-276598-tm0yj2sn	365	9	Ph	Ph	NNP
cord-276598-tm0yj2sn	365	10	)	)	-RRB-
cord-276598-tm0yj2sn	365	11	with	with	IN
cord-276598-tm0yj2sn	365	12	primary	primary	JJ
cord-276598-tm0yj2sn	365	13	or	or	CC
cord-276598-tm0yj2sn	365	14	secondary	secondary	JJ
cord-276598-tm0yj2sn	365	15	amines	amine	NNS
cord-276598-tm0yj2sn	365	16	(	(	-LRB-
cord-276598-tm0yj2sn	365	17	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	365	18	,	,	,
cord-276598-tm0yj2sn	365	19	dibutylamine	dibutylamine	NNP
cord-276598-tm0yj2sn	365	20	,	,	,
cord-276598-tm0yj2sn	365	21	hexylamine	hexylamine	NNP
cord-276598-tm0yj2sn	365	22	,	,	,
cord-276598-tm0yj2sn	365	23	cylohexylamine	cylohexylamine	NN
cord-276598-tm0yj2sn	365	24	,	,	,
cord-276598-tm0yj2sn	365	25	and	and	CC
cord-276598-tm0yj2sn	365	26	methyl	methyl	NN
cord-276598-tm0yj2sn	365	27	alaninate	alaninate	NN
cord-276598-tm0yj2sn	365	28	;	;	:
cord-276598-tm0yj2sn	365	29	Table	table	NN
cord-276598-tm0yj2sn	365	30	1	1	CD
cord-276598-tm0yj2sn	365	31	,	,	,
cord-276598-tm0yj2sn	365	32	route	route	NN
cord-276598-tm0yj2sn	365	33	f	f	NNP
cord-276598-tm0yj2sn	365	34	)	)	-RRB-
cord-276598-tm0yj2sn	365	35	[	[	-LRB-
cord-276598-tm0yj2sn	365	36	108	108	CD
cord-276598-tm0yj2sn	365	37	]	]	-RRB-
cord-276598-tm0yj2sn	365	38	.	.	.
cord-276598-tm0yj2sn	366	1	The	the	DT
cord-276598-tm0yj2sn	366	2	crude	crude	NN
cord-276598-tm0yj2sn	366	3	P	p	NN
cord-276598-tm0yj2sn	366	4	-	-	HYPH
cord-276598-tm0yj2sn	366	5	Ns	Ns	NNP
cord-276598-tm0yj2sn	366	6	were	be	VBD
cord-276598-tm0yj2sn	366	7	extracted	extract	VBN
cord-276598-tm0yj2sn	366	8	and	and	CC
cord-276598-tm0yj2sn	366	9	then	then	RB
cord-276598-tm0yj2sn	366	10	concentrated	concentrate	VBN
cord-276598-tm0yj2sn	366	11	under	under	IN
cord-276598-tm0yj2sn	366	12	vacuum	vacuum	NN
cord-276598-tm0yj2sn	366	13	to	to	TO
cord-276598-tm0yj2sn	366	14	obtain	obtain	VB
cord-276598-tm0yj2sn	366	15	pure	pure	JJ
cord-276598-tm0yj2sn	366	16	products	product	NNS
cord-276598-tm0yj2sn	366	17	with	with	IN
cord-276598-tm0yj2sn	366	18	excellent	excellent	JJ
cord-276598-tm0yj2sn	366	19	isolated	isolated	JJ
cord-276598-tm0yj2sn	366	20	yields	yield	NNS
cord-276598-tm0yj2sn	366	21	(	(	-LRB-
cord-276598-tm0yj2sn	366	22	86	86	CD
cord-276598-tm0yj2sn	366	23	-	-	SYM
cord-276598-tm0yj2sn	366	24	96	96	CD
cord-276598-tm0yj2sn	366	25	%	%	NN
cord-276598-tm0yj2sn	366	26	)	)	-RRB-
cord-276598-tm0yj2sn	366	27	.	.	.
cord-276598-tm0yj2sn	367	1	Similar	similar	JJ
cord-276598-tm0yj2sn	367	2	to	to	IN
cord-276598-tm0yj2sn	367	3	other	other	JJ
cord-276598-tm0yj2sn	367	4	copper	copper	NN
cord-276598-tm0yj2sn	367	5	-	-	HYPH
cord-276598-tm0yj2sn	367	6	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	367	7	P	P	NNP
cord-276598-tm0yj2sn	367	8	-	-	HYPH
cord-276598-tm0yj2sn	367	9	N	n	CD
cord-276598-tm0yj2sn	367	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	367	11	,	,	,
cord-276598-tm0yj2sn	367	12	the	the	DT
cord-276598-tm0yj2sn	367	13	authors	author	NNS
cord-276598-tm0yj2sn	367	14	reported	report	VBD
cord-276598-tm0yj2sn	367	15	a	a	DT
cord-276598-tm0yj2sn	367	16	low	low	JJ
cord-276598-tm0yj2sn	367	17	yield	yield	NN
cord-276598-tm0yj2sn	367	18	(	(	-LRB-
cord-276598-tm0yj2sn	367	19	21	21	CD
cord-276598-tm0yj2sn	367	20	%	%	NN
cord-276598-tm0yj2sn	367	21	)	)	-RRB-
cord-276598-tm0yj2sn	367	22	when	when	WRB
cord-276598-tm0yj2sn	367	23	dibutylamine	dibutylamine	NNP
cord-276598-tm0yj2sn	367	24	and	and	CC
cord-276598-tm0yj2sn	367	25	diisopropyl	diisopropyl	NNP
cord-276598-tm0yj2sn	367	26	H	H	NNP
cord-276598-tm0yj2sn	367	27	-	-	HYPH
cord-276598-tm0yj2sn	367	28	P	P	NNP
cord-276598-tm0yj2sn	367	29	were	be	VBD
cord-276598-tm0yj2sn	367	30	used	use	VBN
cord-276598-tm0yj2sn	367	31	as	as	IN
cord-276598-tm0yj2sn	367	32	substrates	substrate	NNS
cord-276598-tm0yj2sn	367	33	,	,	,
cord-276598-tm0yj2sn	367	34	which	which	WDT
cord-276598-tm0yj2sn	367	35	could	could	MD
cord-276598-tm0yj2sn	367	36	be	be	VB
cord-276598-tm0yj2sn	367	37	attributed	attribute	VBN
cord-276598-tm0yj2sn	367	38	to	to	IN
cord-276598-tm0yj2sn	367	39	steric	steric	JJ
cord-276598-tm0yj2sn	367	40	effects	effect	NNS
cord-276598-tm0yj2sn	367	41	.	.	.
cord-276598-tm0yj2sn	368	1	In	in	IN
cord-276598-tm0yj2sn	368	2	addition	addition	NN
cord-276598-tm0yj2sn	368	3	,	,	,
cord-276598-tm0yj2sn	368	4	the	the	DT
cord-276598-tm0yj2sn	368	5	method	method	NN
cord-276598-tm0yj2sn	368	6	was	be	VBD
cord-276598-tm0yj2sn	368	7	not	not	RB
cord-276598-tm0yj2sn	368	8	effective	effective	JJ
cord-276598-tm0yj2sn	368	9	when	when	WRB
cord-276598-tm0yj2sn	368	10	diphenylphosphine	diphenylphosphine	JJ
cord-276598-tm0yj2sn	368	11	oxide	oxide	NN
cord-276598-tm0yj2sn	368	12	(	(	-LRB-
cord-276598-tm0yj2sn	368	13	dPPO	dPPO	NNP
cord-276598-tm0yj2sn	368	14	)	)	-RRB-
cord-276598-tm0yj2sn	368	15	was	be	VBD
cord-276598-tm0yj2sn	368	16	reacted	react	VBN
cord-276598-tm0yj2sn	368	17	with	with	IN
cord-276598-tm0yj2sn	368	18	butylamine	butylamine	NN
cord-276598-tm0yj2sn	368	19	(	(	-LRB-
cord-276598-tm0yj2sn	368	20	13	13	CD
cord-276598-tm0yj2sn	368	21	%	%	NN
cord-276598-tm0yj2sn	368	22	isolated	isolated	JJ
cord-276598-tm0yj2sn	368	23	yield	yield	NN
cord-276598-tm0yj2sn	368	24	)	)	-RRB-
cord-276598-tm0yj2sn	368	25	due	due	IN
cord-276598-tm0yj2sn	368	26	to	to	IN
cord-276598-tm0yj2sn	368	27	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	368	28	conversion	conversion	NN
cord-276598-tm0yj2sn	368	29	to	to	IN
cord-276598-tm0yj2sn	368	30	phosphonic	phosphonic	NNP
cord-276598-tm0yj2sn	368	31	acid	acid	NNP
cord-276598-tm0yj2sn	368	32	(	(	-LRB-
cord-276598-tm0yj2sn	368	33	PP	PP	NNP
cord-276598-tm0yj2sn	368	34	-	-	HYPH
cord-276598-tm0yj2sn	368	35	A	A	NNP
cord-276598-tm0yj2sn	368	36	)	)	-RRB-
cord-276598-tm0yj2sn	368	37	.	.	.
cord-276598-tm0yj2sn	369	1	Using	use	VBG
cord-276598-tm0yj2sn	369	2	this	this	DT
cord-276598-tm0yj2sn	369	3	aerobic	aerobic	JJ
cord-276598-tm0yj2sn	369	4	copper	copper	NN
cord-276598-tm0yj2sn	369	5	-	-	HYPH
cord-276598-tm0yj2sn	369	6	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	369	7	dehydrocoupling	dehydrocoupling	NN
cord-276598-tm0yj2sn	369	8	method	method	NN
cord-276598-tm0yj2sn	369	9	,	,	,
cord-276598-tm0yj2sn	369	10	Zhou	Zhou	NNP
cord-276598-tm0yj2sn	369	11	et	et	NNP
cord-276598-tm0yj2sn	369	12	al	al	NNP
cord-276598-tm0yj2sn	369	13	.	.	NNP
cord-276598-tm0yj2sn	369	14	synthesized	synthesize	VBD
cord-276598-tm0yj2sn	369	15	a	a	DT
cord-276598-tm0yj2sn	369	16	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	369	17	amino	amino	NN
cord-276598-tm0yj2sn	369	18	compound	compound	NN
cord-276598-tm0yj2sn	369	19	(	(	-LRB-
cord-276598-tm0yj2sn	369	20	16	16	CD
cord-276598-tm0yj2sn	369	21	)	)	-RRB-
cord-276598-tm0yj2sn	369	22	(	(	-LRB-
cord-276598-tm0yj2sn	369	23	Figure	figure	NN
cord-276598-tm0yj2sn	369	24	7	7	CD
cord-276598-tm0yj2sn	369	25	)	)	-RRB-
cord-276598-tm0yj2sn	369	26	.	.	.
cord-276598-tm0yj2sn	370	1	(	(	-LRB-
cord-276598-tm0yj2sn	370	2	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	370	3	,	,	,
cord-276598-tm0yj2sn	370	4	dibutylamine	dibutylamine	NNP
cord-276598-tm0yj2sn	370	5	,	,	,
cord-276598-tm0yj2sn	370	6	hexylamine	hexylamine	NNP
cord-276598-tm0yj2sn	370	7	,	,	,
cord-276598-tm0yj2sn	370	8	cylohexylamine	cylohexylamine	NN
cord-276598-tm0yj2sn	370	9	,	,	,
cord-276598-tm0yj2sn	370	10	and	and	CC
cord-276598-tm0yj2sn	370	11	methyl	methyl	NN
cord-276598-tm0yj2sn	370	12	alaninate	alaninate	NN
cord-276598-tm0yj2sn	370	13	;	;	:
cord-276598-tm0yj2sn	370	14	Table	table	NN
cord-276598-tm0yj2sn	370	15	1	1	CD
cord-276598-tm0yj2sn	370	16	,	,	,
cord-276598-tm0yj2sn	370	17	route	route	NN
cord-276598-tm0yj2sn	370	18	f	f	NNP
cord-276598-tm0yj2sn	370	19	)	)	-RRB-
cord-276598-tm0yj2sn	370	20	[	[	-LRB-
cord-276598-tm0yj2sn	370	21	108	108	CD
cord-276598-tm0yj2sn	370	22	]	]	-RRB-
cord-276598-tm0yj2sn	370	23	.	.	.
cord-276598-tm0yj2sn	371	1	The	the	DT
cord-276598-tm0yj2sn	371	2	crude	crude	NN
cord-276598-tm0yj2sn	371	3	P	p	NN
cord-276598-tm0yj2sn	371	4	-	-	HYPH
cord-276598-tm0yj2sn	371	5	Ns	Ns	NNP
cord-276598-tm0yj2sn	371	6	were	be	VBD
cord-276598-tm0yj2sn	371	7	extracted	extract	VBN
cord-276598-tm0yj2sn	371	8	and	and	CC
cord-276598-tm0yj2sn	371	9	then	then	RB
cord-276598-tm0yj2sn	371	10	concentrated	concentrate	VBN
cord-276598-tm0yj2sn	371	11	under	under	IN
cord-276598-tm0yj2sn	371	12	vacuum	vacuum	NN
cord-276598-tm0yj2sn	371	13	to	to	TO
cord-276598-tm0yj2sn	371	14	obtain	obtain	VB
cord-276598-tm0yj2sn	371	15	pure	pure	JJ
cord-276598-tm0yj2sn	371	16	products	product	NNS
cord-276598-tm0yj2sn	371	17	with	with	IN
cord-276598-tm0yj2sn	371	18	excellent	excellent	JJ
cord-276598-tm0yj2sn	371	19	isolated	isolated	JJ
cord-276598-tm0yj2sn	371	20	yields	yield	NNS
cord-276598-tm0yj2sn	371	21	(	(	-LRB-
cord-276598-tm0yj2sn	371	22	86	86	CD
cord-276598-tm0yj2sn	371	23	-	-	SYM
cord-276598-tm0yj2sn	371	24	96	96	CD
cord-276598-tm0yj2sn	371	25	%	%	NN
cord-276598-tm0yj2sn	371	26	)	)	-RRB-
cord-276598-tm0yj2sn	371	27	.	.	.
cord-276598-tm0yj2sn	372	1	Similar	similar	JJ
cord-276598-tm0yj2sn	372	2	to	to	IN
cord-276598-tm0yj2sn	372	3	other	other	JJ
cord-276598-tm0yj2sn	372	4	copper	copper	NN
cord-276598-tm0yj2sn	372	5	-	-	HYPH
cord-276598-tm0yj2sn	372	6	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	372	7	P	P	NNP
cord-276598-tm0yj2sn	372	8	-	-	HYPH
cord-276598-tm0yj2sn	372	9	N	n	CD
cord-276598-tm0yj2sn	372	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	372	11	,	,	,
cord-276598-tm0yj2sn	372	12	the	the	DT
cord-276598-tm0yj2sn	372	13	authors	author	NNS
cord-276598-tm0yj2sn	372	14	reported	report	VBD
cord-276598-tm0yj2sn	372	15	a	a	DT
cord-276598-tm0yj2sn	372	16	low	low	JJ
cord-276598-tm0yj2sn	372	17	yield	yield	NN
cord-276598-tm0yj2sn	372	18	(	(	-LRB-
cord-276598-tm0yj2sn	372	19	21	21	CD
cord-276598-tm0yj2sn	372	20	%	%	NN
cord-276598-tm0yj2sn	372	21	)	)	-RRB-
cord-276598-tm0yj2sn	372	22	when	when	WRB
cord-276598-tm0yj2sn	372	23	dibutylamine	dibutylamine	NNP
cord-276598-tm0yj2sn	372	24	and	and	CC
cord-276598-tm0yj2sn	372	25	diisopropyl	diisopropyl	NNP
cord-276598-tm0yj2sn	372	26	H	H	NNP
cord-276598-tm0yj2sn	372	27	-	-	HYPH
cord-276598-tm0yj2sn	372	28	P	P	NNP
cord-276598-tm0yj2sn	372	29	were	be	VBD
cord-276598-tm0yj2sn	372	30	used	use	VBN
cord-276598-tm0yj2sn	372	31	as	as	IN
cord-276598-tm0yj2sn	372	32	substrates	substrate	NNS
cord-276598-tm0yj2sn	372	33	,	,	,
cord-276598-tm0yj2sn	372	34	which	which	WDT
cord-276598-tm0yj2sn	372	35	could	could	MD
cord-276598-tm0yj2sn	372	36	be	be	VB
cord-276598-tm0yj2sn	372	37	attributed	attribute	VBN
cord-276598-tm0yj2sn	372	38	to	to	IN
cord-276598-tm0yj2sn	372	39	steric	steric	JJ
cord-276598-tm0yj2sn	372	40	effects	effect	NNS
cord-276598-tm0yj2sn	372	41	.	.	.
cord-276598-tm0yj2sn	373	1	In	in	IN
cord-276598-tm0yj2sn	373	2	addition	addition	NN
cord-276598-tm0yj2sn	373	3	,	,	,
cord-276598-tm0yj2sn	373	4	the	the	DT
cord-276598-tm0yj2sn	373	5	method	method	NN
cord-276598-tm0yj2sn	373	6	was	be	VBD
cord-276598-tm0yj2sn	373	7	not	not	RB
cord-276598-tm0yj2sn	373	8	effective	effective	JJ
cord-276598-tm0yj2sn	373	9	when	when	WRB
cord-276598-tm0yj2sn	373	10	diphenylphosphine	diphenylphosphine	JJ
cord-276598-tm0yj2sn	373	11	oxide	oxide	NN
cord-276598-tm0yj2sn	373	12	(	(	-LRB-
cord-276598-tm0yj2sn	373	13	dPPO	dPPO	NNP
cord-276598-tm0yj2sn	373	14	)	)	-RRB-
cord-276598-tm0yj2sn	373	15	was	be	VBD
cord-276598-tm0yj2sn	373	16	reacted	react	VBN
cord-276598-tm0yj2sn	373	17	with	with	IN
cord-276598-tm0yj2sn	373	18	butylamine	butylamine	NN
cord-276598-tm0yj2sn	373	19	(	(	-LRB-
cord-276598-tm0yj2sn	373	20	13	13	CD
cord-276598-tm0yj2sn	373	21	%	%	NN
cord-276598-tm0yj2sn	373	22	isolated	isolated	JJ
cord-276598-tm0yj2sn	373	23	yield	yield	NN
cord-276598-tm0yj2sn	373	24	)	)	-RRB-
cord-276598-tm0yj2sn	373	25	due	due	IN
cord-276598-tm0yj2sn	373	26	to	to	IN
cord-276598-tm0yj2sn	373	27	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	373	28	conversion	conversion	NN
cord-276598-tm0yj2sn	373	29	to	to	IN
cord-276598-tm0yj2sn	373	30	phosphonic	phosphonic	NNP
cord-276598-tm0yj2sn	373	31	acid	acid	NNP
cord-276598-tm0yj2sn	373	32	(	(	-LRB-
cord-276598-tm0yj2sn	373	33	PP	PP	NNP
cord-276598-tm0yj2sn	373	34	-	-	HYPH
cord-276598-tm0yj2sn	373	35	A	A	NNP
cord-276598-tm0yj2sn	373	36	)	)	-RRB-
cord-276598-tm0yj2sn	373	37	.	.	.
cord-276598-tm0yj2sn	374	1	Using	use	VBG
cord-276598-tm0yj2sn	374	2	this	this	DT
cord-276598-tm0yj2sn	374	3	aerobic	aerobic	JJ
cord-276598-tm0yj2sn	374	4	copper	copper	NN
cord-276598-tm0yj2sn	374	5	-	-	HYPH
cord-276598-tm0yj2sn	374	6	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	374	7	dehydrocoupling	dehydrocoupling	NN
cord-276598-tm0yj2sn	374	8	method	method	NN
cord-276598-tm0yj2sn	374	9	,	,	,
cord-276598-tm0yj2sn	374	10	Zhou	Zhou	NNP
cord-276598-tm0yj2sn	374	11	et	et	NNP
cord-276598-tm0yj2sn	374	12	al	al	NNP
cord-276598-tm0yj2sn	374	13	.	.	NNP
cord-276598-tm0yj2sn	374	14	synthesized	synthesize	VBD
cord-276598-tm0yj2sn	374	15	a	a	DT
cord-276598-tm0yj2sn	374	16	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	374	17	amino	amino	NN
cord-276598-tm0yj2sn	374	18	compound	compound	NN
cord-276598-tm0yj2sn	374	19	(	(	-LRB-
cord-276598-tm0yj2sn	374	20	16	16	CD
cord-276598-tm0yj2sn	374	21	)	)	-RRB-
cord-276598-tm0yj2sn	374	22	(	(	-LRB-
cord-276598-tm0yj2sn	374	23	Figure	figure	NN
cord-276598-tm0yj2sn	374	24	7	7	CD
cord-276598-tm0yj2sn	374	25	)	)	-RRB-
cord-276598-tm0yj2sn	374	26	.	.	.
cord-276598-tm0yj2sn	375	1	Phenylboronic	Phenylboronic	NNP
cord-276598-tm0yj2sn	375	2	acid	acid	NN
cord-276598-tm0yj2sn	375	3	or	or	CC
cord-276598-tm0yj2sn	375	4	ester	ester	NN
cord-276598-tm0yj2sn	375	5	-	-	HYPH
cord-276598-tm0yj2sn	375	6	based	base	VBN
cord-276598-tm0yj2sn	375	7	substrates	substrate	NNS
cord-276598-tm0yj2sn	375	8	were	be	VBD
cord-276598-tm0yj2sn	375	9	converted	convert	VBN
cord-276598-tm0yj2sn	375	10	in	in	IN
cord-276598-tm0yj2sn	375	11	situ	situ	NN
cord-276598-tm0yj2sn	375	12	to	to	IN
cord-276598-tm0yj2sn	375	13	an	an	DT
cord-276598-tm0yj2sn	375	14	organic	organic	JJ
cord-276598-tm0yj2sn	375	15	azide	azide	NN
cord-276598-tm0yj2sn	375	16	using	use	VBG
cord-276598-tm0yj2sn	375	17	a	a	DT
cord-276598-tm0yj2sn	375	18	Cu	Cu	NNP
cord-276598-tm0yj2sn	375	19	-	-	HYPH
cord-276598-tm0yj2sn	375	20	based	base	VBN
cord-276598-tm0yj2sn	375	21	catalyst	catalyst	NN
cord-276598-tm0yj2sn	375	22	and	and	CC
cord-276598-tm0yj2sn	375	23	subsequently	subsequently	RB
cord-276598-tm0yj2sn	375	24	used	use	VBN
cord-276598-tm0yj2sn	375	25	for	for	IN
cord-276598-tm0yj2sn	375	26	the	the	DT
cord-276598-tm0yj2sn	375	27	synthesis	synthesis	NN
cord-276598-tm0yj2sn	375	28	of	of	IN
cord-276598-tm0yj2sn	375	29	P	P	NNP
cord-276598-tm0yj2sn	375	30	-	-	HYPH
cord-276598-tm0yj2sn	375	31	Ns	Ns	NNP
cord-276598-tm0yj2sn	375	32	via	via	IN
cord-276598-tm0yj2sn	375	33	a	a	DT
cord-276598-tm0yj2sn	375	34	coupling	coupling	NN
cord-276598-tm0yj2sn	375	35	reaction	reaction	NN
cord-276598-tm0yj2sn	375	36	,	,	,
cord-276598-tm0yj2sn	375	37	according	accord	VBG
cord-276598-tm0yj2sn	375	38	to	to	IN
cord-276598-tm0yj2sn	375	39	Dangroo	Dangroo	NNP
cord-276598-tm0yj2sn	375	40	et	et	FW
cord-276598-tm0yj2sn	375	41	al	al	NNP
cord-276598-tm0yj2sn	375	42	.	.	.
cord-276598-tm0yj2sn	376	1	(	(	-LRB-
cord-276598-tm0yj2sn	376	2	Table	table	NN
cord-276598-tm0yj2sn	376	3	1	1	CD
cord-276598-tm0yj2sn	376	4	,	,	,
cord-276598-tm0yj2sn	376	5	route	route	NN
cord-276598-tm0yj2sn	376	6	g	g	NN
cord-276598-tm0yj2sn	376	7	)	)	-RRB-
cord-276598-tm0yj2sn	377	1	[	[	-LRB-
cord-276598-tm0yj2sn	377	2	109	109	CD
cord-276598-tm0yj2sn	377	3	]	]	-RRB-
cord-276598-tm0yj2sn	377	4	.	.	.
cord-276598-tm0yj2sn	378	1	Triethyl	Triethyl	NNP
cord-276598-tm0yj2sn	378	2	and	and	CC
cord-276598-tm0yj2sn	378	3	trimethyl	trimethyl	NN
cord-276598-tm0yj2sn	378	4	phosphate	phosphate	NN
cord-276598-tm0yj2sn	378	5	were	be	VBD
cord-276598-tm0yj2sn	378	6	used	use	VBN
cord-276598-tm0yj2sn	378	7	as	as	IN
cord-276598-tm0yj2sn	378	8	the	the	DT
cord-276598-tm0yj2sn	378	9	P	p	NN
cord-276598-tm0yj2sn	378	10	-	-	HYPH
cord-276598-tm0yj2sn	378	11	sources	source	NNS
cord-276598-tm0yj2sn	378	12	while	while	IN
cord-276598-tm0yj2sn	378	13	phenylboronic	phenylboronic	JJ
cord-276598-tm0yj2sn	378	14	acids	acid	NNS
cord-276598-tm0yj2sn	378	15	or	or	CC
cord-276598-tm0yj2sn	378	16	esters	ester	NNS
cord-276598-tm0yj2sn	378	17	with	with	IN
cord-276598-tm0yj2sn	378	18	substituents	substituent	NNS
cord-276598-tm0yj2sn	378	19	such	such	JJ
cord-276598-tm0yj2sn	378	20	as	as	IN
cord-276598-tm0yj2sn	378	21	CN	CN	NNP
cord-276598-tm0yj2sn	378	22	,	,	,
cord-276598-tm0yj2sn	378	23	NO2	NO2	NNP
cord-276598-tm0yj2sn	378	24	,	,	,
cord-276598-tm0yj2sn	378	25	OH	oh	UH
cord-276598-tm0yj2sn	378	26	,	,	,
cord-276598-tm0yj2sn	378	27	OMe	OMe	NNS
cord-276598-tm0yj2sn	378	28	and	and	CC
cord-276598-tm0yj2sn	378	29	halides	halide	NNS
cord-276598-tm0yj2sn	378	30	were	be	VBD
cord-276598-tm0yj2sn	378	31	used	use	VBN
cord-276598-tm0yj2sn	378	32	for	for	IN
cord-276598-tm0yj2sn	378	33	azide	azide	NN
cord-276598-tm0yj2sn	378	34	conversion	conversion	NN
cord-276598-tm0yj2sn	378	35	.	.	.
cord-276598-tm0yj2sn	379	1	The	the	DT
cord-276598-tm0yj2sn	379	2	reaction	reaction	NN
cord-276598-tm0yj2sn	379	3	was	be	VBD
cord-276598-tm0yj2sn	379	4	very	very	RB
cord-276598-tm0yj2sn	379	5	tolerant	tolerant	JJ
cord-276598-tm0yj2sn	379	6	to	to	IN
cord-276598-tm0yj2sn	379	7	compounds	compound	NNS
cord-276598-tm0yj2sn	379	8	with	with	IN
cord-276598-tm0yj2sn	379	9	unsaturated	unsaturated	JJ
cord-276598-tm0yj2sn	379	10	boron	boron	NN
cord-276598-tm0yj2sn	379	11	-	-	HYPH
cord-276598-tm0yj2sn	379	12	carbon	carbon	NN
cord-276598-tm0yj2sn	379	13	bonds	bond	NNS
cord-276598-tm0yj2sn	379	14	giving	give	VBG
cord-276598-tm0yj2sn	379	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	379	16	yields	yield	NNS
cord-276598-tm0yj2sn	379	17	of	of	IN
cord-276598-tm0yj2sn	379	18	67	67	CD
cord-276598-tm0yj2sn	379	19	-	-	SYM
cord-276598-tm0yj2sn	379	20	93	93	CD
cord-276598-tm0yj2sn	379	21	%	%	NN
cord-276598-tm0yj2sn	379	22	.	.	.
cord-276598-tm0yj2sn	380	1	However	however	RB
cord-276598-tm0yj2sn	380	2	,	,	,
cord-276598-tm0yj2sn	380	3	this	this	DT
cord-276598-tm0yj2sn	380	4	reaction	reaction	NN
cord-276598-tm0yj2sn	380	5	is	be	VBZ
cord-276598-tm0yj2sn	380	6	not	not	RB
cord-276598-tm0yj2sn	380	7	effective	effective	JJ
cord-276598-tm0yj2sn	380	8	for	for	IN
cord-276598-tm0yj2sn	380	9	compounds	compound	NNS
cord-276598-tm0yj2sn	380	10	containing	contain	VBG
cord-276598-tm0yj2sn	380	11	saturated	saturate	VBN
cord-276598-tm0yj2sn	380	12	boron	boron	NN
cord-276598-tm0yj2sn	380	13	-	-	HYPH
cord-276598-tm0yj2sn	380	14	carbon	carbon	NN
cord-276598-tm0yj2sn	380	15	bonds	bond	NNS
cord-276598-tm0yj2sn	380	16	such	such	JJ
cord-276598-tm0yj2sn	380	17	as	as	IN
cord-276598-tm0yj2sn	380	18	butyl	butyl	NN
cord-276598-tm0yj2sn	380	19	boronic	boronic	NNP
cord-276598-tm0yj2sn	380	20	acid	acid	NNP
cord-276598-tm0yj2sn	380	21	or	or	CC
cord-276598-tm0yj2sn	380	22	cyclopentyl	cyclopentyl	NNP
cord-276598-tm0yj2sn	380	23	boronic	boronic	NNP
cord-276598-tm0yj2sn	380	24	acid	acid	NNP
cord-276598-tm0yj2sn	380	25	.	.	.
cord-276598-tm0yj2sn	381	1	Transition	transition	NN
cord-276598-tm0yj2sn	381	2	metal	metal	NN
cord-276598-tm0yj2sn	381	3	-	-	HYPH
cord-276598-tm0yj2sn	381	4	catalyzed	catalyzed	JJ
cord-276598-tm0yj2sn	381	5	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	381	6	cross	cross	JJ
cord-276598-tm0yj2sn	381	7	-	-	JJ
cord-276598-tm0yj2sn	381	8	coupling	coupling	JJ
cord-276598-tm0yj2sn	381	9	methods	method	NNS
cord-276598-tm0yj2sn	381	10	for	for	IN
cord-276598-tm0yj2sn	381	11	P	p	NN
cord-276598-tm0yj2sn	381	12	-	-	HYPH
cord-276598-tm0yj2sn	381	13	N	n	CD
cord-276598-tm0yj2sn	381	14	synthesis	synthesis	NN
cord-276598-tm0yj2sn	381	15	have	have	VBP
cord-276598-tm0yj2sn	381	16	become	become	VBN
cord-276598-tm0yj2sn	381	17	Phenylboronic	Phenylboronic	NNP
cord-276598-tm0yj2sn	381	18	acid	acid	NN
cord-276598-tm0yj2sn	381	19	or	or	CC
cord-276598-tm0yj2sn	381	20	ester	ester	NN
cord-276598-tm0yj2sn	381	21	-	-	HYPH
cord-276598-tm0yj2sn	381	22	based	base	VBN
cord-276598-tm0yj2sn	381	23	substrates	substrate	NNS
cord-276598-tm0yj2sn	381	24	were	be	VBD
cord-276598-tm0yj2sn	381	25	converted	convert	VBN
cord-276598-tm0yj2sn	381	26	in	in	IN
cord-276598-tm0yj2sn	381	27	situ	situ	NN
cord-276598-tm0yj2sn	381	28	to	to	IN
cord-276598-tm0yj2sn	381	29	an	an	DT
cord-276598-tm0yj2sn	381	30	organic	organic	JJ
cord-276598-tm0yj2sn	381	31	azide	azide	NN
cord-276598-tm0yj2sn	381	32	using	use	VBG
cord-276598-tm0yj2sn	381	33	a	a	DT
cord-276598-tm0yj2sn	381	34	Cu	Cu	NNP
cord-276598-tm0yj2sn	381	35	-	-	HYPH
cord-276598-tm0yj2sn	381	36	based	base	VBN
cord-276598-tm0yj2sn	381	37	catalyst	catalyst	NN
cord-276598-tm0yj2sn	381	38	and	and	CC
cord-276598-tm0yj2sn	381	39	subsequently	subsequently	RB
cord-276598-tm0yj2sn	381	40	used	use	VBN
cord-276598-tm0yj2sn	381	41	for	for	IN
cord-276598-tm0yj2sn	381	42	the	the	DT
cord-276598-tm0yj2sn	381	43	synthesis	synthesis	NN
cord-276598-tm0yj2sn	381	44	of	of	IN
cord-276598-tm0yj2sn	381	45	P	P	NNP
cord-276598-tm0yj2sn	381	46	-	-	HYPH
cord-276598-tm0yj2sn	381	47	Ns	Ns	NNP
cord-276598-tm0yj2sn	381	48	via	via	IN
cord-276598-tm0yj2sn	381	49	a	a	DT
cord-276598-tm0yj2sn	381	50	coupling	coupling	NN
cord-276598-tm0yj2sn	381	51	reaction	reaction	NN
cord-276598-tm0yj2sn	381	52	,	,	,
cord-276598-tm0yj2sn	381	53	according	accord	VBG
cord-276598-tm0yj2sn	381	54	to	to	IN
cord-276598-tm0yj2sn	381	55	Dangroo	Dangroo	NNP
cord-276598-tm0yj2sn	381	56	et	et	FW
cord-276598-tm0yj2sn	381	57	al	al	NNP
cord-276598-tm0yj2sn	381	58	.	.	.
cord-276598-tm0yj2sn	382	1	(	(	-LRB-
cord-276598-tm0yj2sn	382	2	Table	table	NN
cord-276598-tm0yj2sn	382	3	1	1	CD
cord-276598-tm0yj2sn	382	4	,	,	,
cord-276598-tm0yj2sn	382	5	route	route	NN
cord-276598-tm0yj2sn	382	6	g	g	NN
cord-276598-tm0yj2sn	382	7	)	)	-RRB-
cord-276598-tm0yj2sn	383	1	[	[	-LRB-
cord-276598-tm0yj2sn	383	2	109	109	CD
cord-276598-tm0yj2sn	383	3	]	]	-RRB-
cord-276598-tm0yj2sn	383	4	.	.	.
cord-276598-tm0yj2sn	384	1	Triethyl	Triethyl	NNP
cord-276598-tm0yj2sn	384	2	and	and	CC
cord-276598-tm0yj2sn	384	3	trimethyl	trimethyl	NN
cord-276598-tm0yj2sn	384	4	phosphate	phosphate	NN
cord-276598-tm0yj2sn	384	5	were	be	VBD
cord-276598-tm0yj2sn	384	6	used	use	VBN
cord-276598-tm0yj2sn	384	7	as	as	IN
cord-276598-tm0yj2sn	384	8	the	the	DT
cord-276598-tm0yj2sn	384	9	P	p	NN
cord-276598-tm0yj2sn	384	10	-	-	HYPH
cord-276598-tm0yj2sn	384	11	sources	source	NNS
cord-276598-tm0yj2sn	384	12	while	while	IN
cord-276598-tm0yj2sn	384	13	phenylboronic	phenylboronic	JJ
cord-276598-tm0yj2sn	384	14	acids	acid	NNS
cord-276598-tm0yj2sn	384	15	or	or	CC
cord-276598-tm0yj2sn	384	16	esters	ester	NNS
cord-276598-tm0yj2sn	384	17	with	with	IN
cord-276598-tm0yj2sn	384	18	substituents	substituent	NNS
cord-276598-tm0yj2sn	384	19	such	such	JJ
cord-276598-tm0yj2sn	384	20	as	as	IN
cord-276598-tm0yj2sn	384	21	CN	CN	NNP
cord-276598-tm0yj2sn	384	22	,	,	,
cord-276598-tm0yj2sn	384	23	NO	no	DT
cord-276598-tm0yj2sn	384	24	2	2	CD
cord-276598-tm0yj2sn	384	25	,	,	,
cord-276598-tm0yj2sn	384	26	OH	oh	UH
cord-276598-tm0yj2sn	384	27	,	,	,
cord-276598-tm0yj2sn	384	28	OMe	OMe	NNS
cord-276598-tm0yj2sn	384	29	and	and	CC
cord-276598-tm0yj2sn	384	30	halides	halide	NNS
cord-276598-tm0yj2sn	384	31	were	be	VBD
cord-276598-tm0yj2sn	384	32	used	use	VBN
cord-276598-tm0yj2sn	384	33	for	for	IN
cord-276598-tm0yj2sn	384	34	azide	azide	NN
cord-276598-tm0yj2sn	384	35	conversion	conversion	NN
cord-276598-tm0yj2sn	384	36	.	.	.
cord-276598-tm0yj2sn	385	1	The	the	DT
cord-276598-tm0yj2sn	385	2	reaction	reaction	NN
cord-276598-tm0yj2sn	385	3	was	be	VBD
cord-276598-tm0yj2sn	385	4	very	very	RB
cord-276598-tm0yj2sn	385	5	tolerant	tolerant	JJ
cord-276598-tm0yj2sn	385	6	to	to	IN
cord-276598-tm0yj2sn	385	7	compounds	compound	NNS
cord-276598-tm0yj2sn	385	8	with	with	IN
cord-276598-tm0yj2sn	385	9	unsaturated	unsaturated	JJ
cord-276598-tm0yj2sn	385	10	boron	boron	NN
cord-276598-tm0yj2sn	385	11	-	-	HYPH
cord-276598-tm0yj2sn	385	12	carbon	carbon	NN
cord-276598-tm0yj2sn	385	13	bonds	bond	NNS
cord-276598-tm0yj2sn	385	14	giving	give	VBG
cord-276598-tm0yj2sn	385	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	385	16	yields	yield	NNS
cord-276598-tm0yj2sn	385	17	of	of	IN
cord-276598-tm0yj2sn	385	18	67	67	CD
cord-276598-tm0yj2sn	385	19	-	-	SYM
cord-276598-tm0yj2sn	385	20	93	93	CD
cord-276598-tm0yj2sn	385	21	%	%	NN
cord-276598-tm0yj2sn	385	22	.	.	.
cord-276598-tm0yj2sn	386	1	However	however	RB
cord-276598-tm0yj2sn	386	2	,	,	,
cord-276598-tm0yj2sn	386	3	this	this	DT
cord-276598-tm0yj2sn	386	4	reaction	reaction	NN
cord-276598-tm0yj2sn	386	5	is	be	VBZ
cord-276598-tm0yj2sn	386	6	not	not	RB
cord-276598-tm0yj2sn	386	7	effective	effective	JJ
cord-276598-tm0yj2sn	386	8	for	for	IN
cord-276598-tm0yj2sn	386	9	compounds	compound	NNS
cord-276598-tm0yj2sn	386	10	containing	contain	VBG
cord-276598-tm0yj2sn	386	11	saturated	saturate	VBN
cord-276598-tm0yj2sn	386	12	boron	boron	NN
cord-276598-tm0yj2sn	386	13	-	-	HYPH
cord-276598-tm0yj2sn	386	14	carbon	carbon	NN
cord-276598-tm0yj2sn	386	15	bonds	bond	NNS
cord-276598-tm0yj2sn	386	16	such	such	JJ
cord-276598-tm0yj2sn	386	17	as	as	IN
cord-276598-tm0yj2sn	386	18	butyl	butyl	NN
cord-276598-tm0yj2sn	386	19	boronic	boronic	NNP
cord-276598-tm0yj2sn	386	20	acid	acid	NNP
cord-276598-tm0yj2sn	386	21	or	or	CC
cord-276598-tm0yj2sn	386	22	cyclopentyl	cyclopentyl	NNP
cord-276598-tm0yj2sn	386	23	boronic	boronic	NNP
cord-276598-tm0yj2sn	386	24	acid	acid	NNP
cord-276598-tm0yj2sn	386	25	.	.	.
cord-276598-tm0yj2sn	387	1	Transition	transition	NN
cord-276598-tm0yj2sn	387	2	metal	metal	NN
cord-276598-tm0yj2sn	387	3	-	-	HYPH
cord-276598-tm0yj2sn	387	4	catalyzed	catalyzed	JJ
cord-276598-tm0yj2sn	387	5	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	387	6	cross	cross	JJ
cord-276598-tm0yj2sn	387	7	-	-	JJ
cord-276598-tm0yj2sn	387	8	coupling	coupling	JJ
cord-276598-tm0yj2sn	387	9	methods	method	NNS
cord-276598-tm0yj2sn	387	10	for	for	IN
cord-276598-tm0yj2sn	387	11	P	p	NN
cord-276598-tm0yj2sn	387	12	-	-	HYPH
cord-276598-tm0yj2sn	387	13	N	n	CD
cord-276598-tm0yj2sn	387	14	synthesis	synthesis	NN
cord-276598-tm0yj2sn	387	15	have	have	VBP
cord-276598-tm0yj2sn	387	16	become	become	VBN
cord-276598-tm0yj2sn	387	17	attractive	attractive	JJ
cord-276598-tm0yj2sn	387	18	in	in	IN
cord-276598-tm0yj2sn	387	19	recent	recent	JJ
cord-276598-tm0yj2sn	387	20	years	year	NNS
cord-276598-tm0yj2sn	387	21	because	because	IN
cord-276598-tm0yj2sn	387	22	of	of	IN
cord-276598-tm0yj2sn	387	23	the	the	DT
cord-276598-tm0yj2sn	387	24	advantages	advantage	NNS
cord-276598-tm0yj2sn	387	25	of	of	IN
cord-276598-tm0yj2sn	387	26	using	use	VBG
cord-276598-tm0yj2sn	387	27	readily	readily	RB
cord-276598-tm0yj2sn	387	28	available	available	JJ
cord-276598-tm0yj2sn	387	29	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	387	30	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	387	31	,	,	,
cord-276598-tm0yj2sn	387	32	for	for	IN
cord-276598-tm0yj2sn	387	33	example	example	NN
cord-276598-tm0yj2sn	387	34	CuX	CuX	NNP
cord-276598-tm0yj2sn	387	35	n	n	NNP
cord-276598-tm0yj2sn	388	1	(	(	-LRB-
cord-276598-tm0yj2sn	388	2	X	x	NN
cord-276598-tm0yj2sn	388	3	=	=	SYM
cord-276598-tm0yj2sn	388	4	Cl	Cl	NNP
cord-276598-tm0yj2sn	388	5	,	,	,
cord-276598-tm0yj2sn	388	6	Br	Br	NNP
cord-276598-tm0yj2sn	388	7	,	,	,
cord-276598-tm0yj2sn	388	8	(	(	-LRB-
cord-276598-tm0yj2sn	388	9	OAc	OAc	NNS
cord-276598-tm0yj2sn	388	10	)	)	-RRB-
cord-276598-tm0yj2sn	388	11	,	,	,
cord-276598-tm0yj2sn	388	12	etc	etc	FW
cord-276598-tm0yj2sn	388	13	.	.	.
cord-276598-tm0yj2sn	389	1	,	,	,
cord-276598-tm0yj2sn	389	2	n	n	NN
cord-276598-tm0yj2sn	389	3	=	=	SYM
cord-276598-tm0yj2sn	389	4	1	1	CD
cord-276598-tm0yj2sn	389	5	,	,	,
cord-276598-tm0yj2sn	389	6	2	2	CD
cord-276598-tm0yj2sn	389	7	)	)	-RRB-
cord-276598-tm0yj2sn	389	8	,	,	,
cord-276598-tm0yj2sn	389	9	and	and	CC
cord-276598-tm0yj2sn	389	10	air	air	NN
cord-276598-tm0yj2sn	389	11	as	as	IN
cord-276598-tm0yj2sn	389	12	an	an	DT
cord-276598-tm0yj2sn	389	13	oxidant	oxidant	NN
cord-276598-tm0yj2sn	389	14	.	.	.
cord-276598-tm0yj2sn	390	1	In	in	IN
cord-276598-tm0yj2sn	390	2	addition	addition	NN
cord-276598-tm0yj2sn	390	3	,	,	,
cord-276598-tm0yj2sn	390	4	this	this	DT
cord-276598-tm0yj2sn	390	5	route	route	NN
cord-276598-tm0yj2sn	390	6	uses	use	VBZ
cord-276598-tm0yj2sn	390	7	environmentally	environmentally	RB
cord-276598-tm0yj2sn	390	8	friendly	friendly	JJ
cord-276598-tm0yj2sn	390	9	H	h	NN
cord-276598-tm0yj2sn	390	10	-	-	HYPH
cord-276598-tm0yj2sn	390	11	P	p	NN
cord-276598-tm0yj2sn	390	12	(	(	-LRB-
cord-276598-tm0yj2sn	390	13	RO	RO	NNP
cord-276598-tm0yj2sn	390	14	)	)	-RRB-
cord-276598-tm0yj2sn	390	15	2	2	CD
cord-276598-tm0yj2sn	391	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	392	1	(	(	-LRB-
cord-276598-tm0yj2sn	392	2	R	r	NN
cord-276598-tm0yj2sn	392	3	=	=	NN
cord-276598-tm0yj2sn	392	4	alkyl	alkyl	NN
cord-276598-tm0yj2sn	392	5	,	,	,
cord-276598-tm0yj2sn	392	6	Ph	Ph	NNP
cord-276598-tm0yj2sn	392	7	)	)	-RRB-
cord-276598-tm0yj2sn	392	8	and	and	CC
cord-276598-tm0yj2sn	392	9	amines	amine	NNS
cord-276598-tm0yj2sn	392	10	as	as	IN
cord-276598-tm0yj2sn	392	11	starting	start	VBG
cord-276598-tm0yj2sn	392	12	materials	material	NNS
cord-276598-tm0yj2sn	392	13	in	in	IN
cord-276598-tm0yj2sn	392	14	a	a	DT
cord-276598-tm0yj2sn	392	15	one	one	CD
cord-276598-tm0yj2sn	392	16	-	-	HYPH
cord-276598-tm0yj2sn	392	17	pot	pot	NN
cord-276598-tm0yj2sn	392	18	single	single	JJ
cord-276598-tm0yj2sn	392	19	-	-	HYPH
cord-276598-tm0yj2sn	392	20	step	step	NN
cord-276598-tm0yj2sn	392	21	process	process	NN
cord-276598-tm0yj2sn	392	22	without	without	IN
cord-276598-tm0yj2sn	392	23	any	any	DT
cord-276598-tm0yj2sn	392	24	need	need	NN
cord-276598-tm0yj2sn	392	25	for	for	IN
cord-276598-tm0yj2sn	392	26	purification	purification	NN
cord-276598-tm0yj2sn	392	27	of	of	IN
cord-276598-tm0yj2sn	392	28	the	the	DT
cord-276598-tm0yj2sn	392	29	starting	starting	NN
cord-276598-tm0yj2sn	392	30	material	material	NN
cord-276598-tm0yj2sn	392	31	,	,	,
cord-276598-tm0yj2sn	392	32	thereby	thereby	RB
cord-276598-tm0yj2sn	392	33	making	make	VBG
cord-276598-tm0yj2sn	393	1	the	the	DT
cord-276598-tm0yj2sn	393	2	process	process	NN
cord-276598-tm0yj2sn	393	3	cost	cost	NN
cord-276598-tm0yj2sn	393	4	-	-	HYPH
cord-276598-tm0yj2sn	393	5	and	and	CC
cord-276598-tm0yj2sn	393	6	time	time	NN
cord-276598-tm0yj2sn	393	7	-	-	HYPH
cord-276598-tm0yj2sn	393	8	effective	effective	JJ
cord-276598-tm0yj2sn	393	9	.	.	.
cord-276598-tm0yj2sn	394	1	Apart	apart	RB
cord-276598-tm0yj2sn	394	2	from	from	IN
cord-276598-tm0yj2sn	394	3	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	394	4	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	394	5	starting	starting	NN
cord-276598-tm0yj2sn	394	6	materials	material	NNS
cord-276598-tm0yj2sn	394	7	,	,	,
cord-276598-tm0yj2sn	394	8	the	the	DT
cord-276598-tm0yj2sn	394	9	method	method	NN
cord-276598-tm0yj2sn	394	10	uses	use	VBZ
cord-276598-tm0yj2sn	394	11	fewer	few	JJR
cord-276598-tm0yj2sn	394	12	chemical	chemical	NN
cord-276598-tm0yj2sn	394	13	additives	additive	NNS
cord-276598-tm0yj2sn	394	14	and	and	CC
cord-276598-tm0yj2sn	394	15	generates	generate	VBZ
cord-276598-tm0yj2sn	394	16	mainly	mainly	RB
cord-276598-tm0yj2sn	394	17	water	water	NN
cord-276598-tm0yj2sn	394	18	as	as	IN
cord-276598-tm0yj2sn	394	19	a	a	DT
cord-276598-tm0yj2sn	394	20	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	394	21	waste	waste	NN
cord-276598-tm0yj2sn	394	22	.	.	.
cord-276598-tm0yj2sn	395	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	395	2	,	,	,
cord-276598-tm0yj2sn	395	3	the	the	DT
cord-276598-tm0yj2sn	395	4	methods	method	NNS
cord-276598-tm0yj2sn	395	5	offer	offer	VBP
cord-276598-tm0yj2sn	395	6	a	a	DT
cord-276598-tm0yj2sn	395	7	possibility	possibility	NN
cord-276598-tm0yj2sn	395	8	of	of	IN
cord-276598-tm0yj2sn	395	9	catalyst	catalyst	NN
cord-276598-tm0yj2sn	395	10	recycling	recycling	NN
cord-276598-tm0yj2sn	395	11	,	,	,
cord-276598-tm0yj2sn	395	12	which	which	WDT
cord-276598-tm0yj2sn	395	13	is	be	VBZ
cord-276598-tm0yj2sn	395	14	an	an	DT
cord-276598-tm0yj2sn	395	15	important	important	JJ
cord-276598-tm0yj2sn	395	16	attribute	attribute	NN
cord-276598-tm0yj2sn	395	17	for	for	IN
cord-276598-tm0yj2sn	395	18	any	any	DT
cord-276598-tm0yj2sn	395	19	green	green	JJ
cord-276598-tm0yj2sn	395	20	chemical	chemical	NN
cord-276598-tm0yj2sn	395	21	process	process	NN
cord-276598-tm0yj2sn	395	22	in	in	IN
cord-276598-tm0yj2sn	395	23	terms	term	NNS
cord-276598-tm0yj2sn	395	24	of	of	IN
cord-276598-tm0yj2sn	395	25	mass	mass	NN
cord-276598-tm0yj2sn	395	26	production	production	NN
cord-276598-tm0yj2sn	395	27	.	.	.
cord-276598-tm0yj2sn	396	1	However	however	RB
cord-276598-tm0yj2sn	396	2	,	,	,
cord-276598-tm0yj2sn	396	3	a	a	DT
cord-276598-tm0yj2sn	396	4	notable	notable	JJ
cord-276598-tm0yj2sn	396	5	limitation	limitation	NN
cord-276598-tm0yj2sn	396	6	of	of	IN
cord-276598-tm0yj2sn	396	7	the	the	DT
cord-276598-tm0yj2sn	396	8	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	396	9	route	route	NN
cord-276598-tm0yj2sn	396	10	is	be	VBZ
cord-276598-tm0yj2sn	396	11	the	the	DT
cord-276598-tm0yj2sn	396	12	formation	formation	NN
cord-276598-tm0yj2sn	396	13	of	of	IN
cord-276598-tm0yj2sn	396	14	various	various	JJ
cord-276598-tm0yj2sn	396	15	undesired	undesired	JJ
cord-276598-tm0yj2sn	396	16	by	by	IN
cord-276598-tm0yj2sn	396	17	-	-	HYPH
cord-276598-tm0yj2sn	396	18	products	product	NNS
cord-276598-tm0yj2sn	396	19	from	from	IN
cord-276598-tm0yj2sn	396	20	the	the	DT
cord-276598-tm0yj2sn	396	21	reactivities	reactivity	NNS
cord-276598-tm0yj2sn	396	22	of	of	IN
cord-276598-tm0yj2sn	396	23	H	H	NNP
cord-276598-tm0yj2sn	396	24	-	-	HYPH
cord-276598-tm0yj2sn	396	25	P	p	NN
cord-276598-tm0yj2sn	396	26	and	and	CC
cord-276598-tm0yj2sn	396	27	amine	amine	NN
cord-276598-tm0yj2sn	396	28	with	with	IN
cord-276598-tm0yj2sn	396	29	the	the	DT
cord-276598-tm0yj2sn	396	30	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	396	31	under	under	IN
cord-276598-tm0yj2sn	396	32	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	396	33	conditions	condition	NNS
cord-276598-tm0yj2sn	396	34	[	[	-LRB-
cord-276598-tm0yj2sn	396	35	103	103	CD
cord-276598-tm0yj2sn	396	36	]	]	-RRB-
cord-276598-tm0yj2sn	396	37	.	.	.
cord-276598-tm0yj2sn	397	1	Guo	Guo	NNP
cord-276598-tm0yj2sn	397	2	et	et	FW
cord-276598-tm0yj2sn	397	3	al	al	NNP
cord-276598-tm0yj2sn	397	4	.	.	.
cord-276598-tm0yj2sn	397	5	used	use	VBD
cord-276598-tm0yj2sn	397	6	visible	visible	JJ
cord-276598-tm0yj2sn	397	7	light	light	NN
cord-276598-tm0yj2sn	397	8	and	and	CC
cord-276598-tm0yj2sn	397	9	organic	organic	JJ
cord-276598-tm0yj2sn	397	10	dyes	dye	NNS
cord-276598-tm0yj2sn	397	11	as	as	IN
cord-276598-tm0yj2sn	397	12	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	397	13	for	for	IN
cord-276598-tm0yj2sn	397	14	the	the	DT
cord-276598-tm0yj2sn	397	15	dehydrogenative	dehydrogenative	JJ
cord-276598-tm0yj2sn	397	16	cross	cross	JJ
cord-276598-tm0yj2sn	397	17	-	-	JJ
cord-276598-tm0yj2sn	397	18	coupling	coupling	JJ
cord-276598-tm0yj2sn	397	19	reaction	reaction	NN
cord-276598-tm0yj2sn	397	20	of	of	IN
cord-276598-tm0yj2sn	397	21	(	(	-LRB-
cord-276598-tm0yj2sn	397	22	EtO	EtO	NNP
cord-276598-tm0yj2sn	397	23	)	)	-RRB-
cord-276598-tm0yj2sn	397	24	2	2	CD
cord-276598-tm0yj2sn	398	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	399	1	(	(	-LRB-
cord-276598-tm0yj2sn	399	2	H	h	NN
cord-276598-tm0yj2sn	399	3	-	-	HYPH
cord-276598-tm0yj2sn	399	4	P	p	NN
cord-276598-tm0yj2sn	399	5	)	)	-RRB-
cord-276598-tm0yj2sn	399	6	and	and	CC
cord-276598-tm0yj2sn	399	7	amines	amine	NNS
cord-276598-tm0yj2sn	399	8	(	(	-LRB-
cord-276598-tm0yj2sn	399	9	aniline	aniline	NN
cord-276598-tm0yj2sn	399	10	,	,	,
cord-276598-tm0yj2sn	399	11	aniline	aniline	NN
cord-276598-tm0yj2sn	399	12	derivatives	derivative	NNS
cord-276598-tm0yj2sn	399	13	with	with	IN
cord-276598-tm0yj2sn	399	14	CN	CN	NNP
cord-276598-tm0yj2sn	399	15	,	,	,
cord-276598-tm0yj2sn	399	16	X	X	NNP
cord-276598-tm0yj2sn	399	17	,	,	,
cord-276598-tm0yj2sn	399	18	Me	-PRON-	PRP
cord-276598-tm0yj2sn	399	19	,	,	,
cord-276598-tm0yj2sn	399	20	OMe	OMe	NNS
cord-276598-tm0yj2sn	399	21	and	and	CC
cord-276598-tm0yj2sn	399	22	1-naphthylamine	1-naphthylamine	CD
cord-276598-tm0yj2sn	399	23	)	)	-RRB-
cord-276598-tm0yj2sn	399	24	to	to	TO
cord-276598-tm0yj2sn	399	25	form	form	VB
cord-276598-tm0yj2sn	399	26	the	the	DT
cord-276598-tm0yj2sn	399	27	corresponding	correspond	VBG
cord-276598-tm0yj2sn	399	28	P	P	NNP
cord-276598-tm0yj2sn	399	29	-	-	HYPH
cord-276598-tm0yj2sn	399	30	Ns	Ns	NNP
cord-276598-tm0yj2sn	399	31	(	(	-LRB-
cord-276598-tm0yj2sn	399	32	Scheme	scheme	NN
cord-276598-tm0yj2sn	399	33	8)	8)	.
cord-276598-tm0yj2sn	399	34	[	[	-LRB-
cord-276598-tm0yj2sn	399	35	110	110	CD
cord-276598-tm0yj2sn	399	36	]	]	-RRB-
cord-276598-tm0yj2sn	399	37	.	.	.
cord-276598-tm0yj2sn	400	1	After	after	IN
cord-276598-tm0yj2sn	400	2	an	an	DT
cord-276598-tm0yj2sn	400	3	extraction	extraction	NN
cord-276598-tm0yj2sn	400	4	,	,	,
cord-276598-tm0yj2sn	400	5	the	the	DT
cord-276598-tm0yj2sn	400	6	pure	pure	JJ
cord-276598-tm0yj2sn	400	7	product	product	NN
cord-276598-tm0yj2sn	400	8	was	be	VBD
cord-276598-tm0yj2sn	400	9	formed	form	VBN
cord-276598-tm0yj2sn	400	10	with	with	IN
cord-276598-tm0yj2sn	400	11	isolated	isolated	JJ
cord-276598-tm0yj2sn	400	12	yield	yield	NN
cord-276598-tm0yj2sn	400	13	in	in	IN
cord-276598-tm0yj2sn	400	14	the	the	DT
cord-276598-tm0yj2sn	400	15	range	range	NN
cord-276598-tm0yj2sn	400	16	of	of	IN
cord-276598-tm0yj2sn	400	17	0	0	CD
cord-276598-tm0yj2sn	400	18	-	-	SYM
cord-276598-tm0yj2sn	400	19	99	99	CD
cord-276598-tm0yj2sn	400	20	%	%	NN
cord-276598-tm0yj2sn	400	21	.	.	.
cord-276598-tm0yj2sn	401	1	It	-PRON-	PRP
cord-276598-tm0yj2sn	401	2	is	be	VBZ
cord-276598-tm0yj2sn	401	3	noteworthy	noteworthy	JJ
cord-276598-tm0yj2sn	401	4	that	that	IN
cord-276598-tm0yj2sn	401	5	the	the	DT
cord-276598-tm0yj2sn	401	6	method	method	NN
cord-276598-tm0yj2sn	401	7	was	be	VBD
cord-276598-tm0yj2sn	401	8	not	not	RB
cord-276598-tm0yj2sn	401	9	effective	effective	JJ
cord-276598-tm0yj2sn	401	10	when	when	WRB
cord-276598-tm0yj2sn	401	11	vinylaniline	vinylaniline	NN
cord-276598-tm0yj2sn	401	12	and	and	CC
cord-276598-tm0yj2sn	401	13	2-aminothiazole	2-aminothiazole	CD
cord-276598-tm0yj2sn	401	14	were	be	VBD
cord-276598-tm0yj2sn	401	15	used	use	VBN
cord-276598-tm0yj2sn	401	16	because	because	IN
cord-276598-tm0yj2sn	401	17	of	of	IN
cord-276598-tm0yj2sn	401	18	their	-PRON-	PRP$
cord-276598-tm0yj2sn	401	19	radical	radical	JJ
cord-276598-tm0yj2sn	401	20	sensitivity	sensitivity	NN
cord-276598-tm0yj2sn	401	21	making	make	VBG
cord-276598-tm0yj2sn	401	22	them	-PRON-	PRP
cord-276598-tm0yj2sn	401	23	prone	prone	JJ
cord-276598-tm0yj2sn	401	24	to	to	IN
cord-276598-tm0yj2sn	401	25	either	either	CC
cord-276598-tm0yj2sn	401	26	polymerization	polymerization	NN
cord-276598-tm0yj2sn	401	27	or	or	CC
cord-276598-tm0yj2sn	401	28	decomposition	decomposition	NN
cord-276598-tm0yj2sn	401	29	in	in	IN
cord-276598-tm0yj2sn	401	30	the	the	DT
cord-276598-tm0yj2sn	401	31	reaction	reaction	NN
cord-276598-tm0yj2sn	401	32	media	medium	NNS
cord-276598-tm0yj2sn	401	33	,	,	,
cord-276598-tm0yj2sn	401	34	respectively	respectively	RB
cord-276598-tm0yj2sn	401	35	.	.	.
cord-276598-tm0yj2sn	402	1	Although	although	IN
cord-276598-tm0yj2sn	402	2	no	no	DT
cord-276598-tm0yj2sn	402	3	product	product	NN
cord-276598-tm0yj2sn	402	4	was	be	VBD
cord-276598-tm0yj2sn	402	5	formed	form	VBN
cord-276598-tm0yj2sn	402	6	when	when	WRB
cord-276598-tm0yj2sn	402	7	secondary	secondary	JJ
cord-276598-tm0yj2sn	402	8	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	402	9	amines	amine	NNS
cord-276598-tm0yj2sn	402	10	were	be	VBD
cord-276598-tm0yj2sn	402	11	used	use	VBN
cord-276598-tm0yj2sn	402	12	,	,	,
cord-276598-tm0yj2sn	402	13	moderate	moderate	JJ
cord-276598-tm0yj2sn	402	14	yields	yield	NNS
cord-276598-tm0yj2sn	402	15	of	of	IN
cord-276598-tm0yj2sn	402	16	up	up	IN
cord-276598-tm0yj2sn	402	17	to	to	TO
cord-276598-tm0yj2sn	402	18	59	59	CD
cord-276598-tm0yj2sn	402	19	%	%	NN
cord-276598-tm0yj2sn	402	20	were	be	VBD
cord-276598-tm0yj2sn	402	21	obtained	obtain	VBN
cord-276598-tm0yj2sn	402	22	from	from	IN
cord-276598-tm0yj2sn	402	23	primary	primary	JJ
cord-276598-tm0yj2sn	402	24	or	or	CC
cord-276598-tm0yj2sn	402	25	tertiary	tertiary	JJ
cord-276598-tm0yj2sn	402	26	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	402	27	amines	amine	NNS
cord-276598-tm0yj2sn	402	28	,	,	,
cord-276598-tm0yj2sn	402	29	while	while	IN
cord-276598-tm0yj2sn	402	30	a	a	DT
cord-276598-tm0yj2sn	402	31	complex	complex	JJ
cord-276598-tm0yj2sn	402	32	mixture	mixture	NN
cord-276598-tm0yj2sn	402	33	of	of	IN
cord-276598-tm0yj2sn	402	34	products	product	NNS
cord-276598-tm0yj2sn	402	35	was	be	VBD
cord-276598-tm0yj2sn	402	36	formed	form	VBN
cord-276598-tm0yj2sn	402	37	when	when	WRB
cord-276598-tm0yj2sn	402	38	an	an	DT
cord-276598-tm0yj2sn	402	39	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	402	40	H	h	NN
cord-276598-tm0yj2sn	402	41	-	-	HYPH
cord-276598-tm0yj2sn	402	42	P	P	NNP
cord-276598-tm0yj2sn	402	43	was	be	VBD
cord-276598-tm0yj2sn	402	44	used	use	VBN
cord-276598-tm0yj2sn	402	45	.	.	.
cord-276598-tm0yj2sn	403	1	[	[	-LRB-
cord-276598-tm0yj2sn	403	2	111	111	CD
cord-276598-tm0yj2sn	403	3	]	]	-RRB-
cord-276598-tm0yj2sn	403	4	.	.	.
cord-276598-tm0yj2sn	404	1	The	the	DT
cord-276598-tm0yj2sn	404	2	crude	crude	JJ
cord-276598-tm0yj2sn	404	3	products	product	NNS
cord-276598-tm0yj2sn	404	4	were	be	VBD
cord-276598-tm0yj2sn	404	5	purified	purify	VBN
cord-276598-tm0yj2sn	404	6	by	by	IN
cord-276598-tm0yj2sn	404	7	column	column	NN
cord-276598-tm0yj2sn	404	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	404	9	(	(	-LRB-
cord-276598-tm0yj2sn	404	10	on	on	IN
cord-276598-tm0yj2sn	404	11	silica	silica	NN
cord-276598-tm0yj2sn	404	12	)	)	-RRB-
cord-276598-tm0yj2sn	404	13	with	with	IN
cord-276598-tm0yj2sn	404	14	isolated	isolated	JJ
cord-276598-tm0yj2sn	404	15	yields	yield	NNS
cord-276598-tm0yj2sn	404	16	of	of	IN
cord-276598-tm0yj2sn	404	17	65	65	CD
cord-276598-tm0yj2sn	404	18	%	%	NN
cord-276598-tm0yj2sn	404	19	and	and	CC
cord-276598-tm0yj2sn	404	20	31	31	CD
cord-276598-tm0yj2sn	404	21	%	%	NN
cord-276598-tm0yj2sn	404	22	for	for	IN
cord-276598-tm0yj2sn	404	23	the	the	DT
cord-276598-tm0yj2sn	404	24	use	use	NN
cord-276598-tm0yj2sn	404	25	of	of	IN
cord-276598-tm0yj2sn	404	26	benzylamine	benzylamine	NN
cord-276598-tm0yj2sn	404	27	and	and	CC
cord-276598-tm0yj2sn	404	28	4-chloroaniline	4-chloroaniline	CD
cord-276598-tm0yj2sn	404	29	,	,	,
cord-276598-tm0yj2sn	404	30	respectively	respectively	RB
cord-276598-tm0yj2sn	404	31	.	.	.
cord-276598-tm0yj2sn	405	1	Other	other	JJ
cord-276598-tm0yj2sn	405	2	amines	amine	NNS
cord-276598-tm0yj2sn	405	3	were	be	VBD
cord-276598-tm0yj2sn	405	4	not	not	RB
cord-276598-tm0yj2sn	405	5	investigated	investigate	VBN
cord-276598-tm0yj2sn	405	6	.	.	.
cord-276598-tm0yj2sn	406	1	Although	although	IN
cord-276598-tm0yj2sn	406	2	the	the	DT
cord-276598-tm0yj2sn	406	3	method	method	NN
cord-276598-tm0yj2sn	406	4	uses	use	VBZ
cord-276598-tm0yj2sn	406	5	an	an	DT
cord-276598-tm0yj2sn	406	6	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	406	7	catalyst	catalyst	NN
cord-276598-tm0yj2sn	406	8	and	and	CC
cord-276598-tm0yj2sn	406	9	oxidant	oxidant	NN
cord-276598-tm0yj2sn	406	10	,	,	,
cord-276598-tm0yj2sn	406	11	the	the	DT
cord-276598-tm0yj2sn	406	12	applicability	applicability	NN
cord-276598-tm0yj2sn	406	13	of	of	IN
cord-276598-tm0yj2sn	406	14	the	the	DT
cord-276598-tm0yj2sn	406	15	process	process	NN
cord-276598-tm0yj2sn	406	16	was	be	VBD
cord-276598-tm0yj2sn	406	17	not	not	RB
cord-276598-tm0yj2sn	406	18	explored	explore	VBN
cord-276598-tm0yj2sn	406	19	using	use	VBG
cord-276598-tm0yj2sn	406	20	diverse	diverse	JJ
cord-276598-tm0yj2sn	406	21	H	h	NN
cord-276598-tm0yj2sn	406	22	-	-	HYPH
cord-276598-tm0yj2sn	406	23	P	p	NN
cord-276598-tm0yj2sn	406	24	and	and	CC
cord-276598-tm0yj2sn	406	25	amines	amine	NNS
cord-276598-tm0yj2sn	406	26	.	.	.
cord-276598-tm0yj2sn	407	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	407	2	9	9	CD
cord-276598-tm0yj2sn	407	3	.	.	.
cord-276598-tm0yj2sn	408	1	Oxidative	oxidative	JJ
cord-276598-tm0yj2sn	408	2	cross	cross	JJ
cord-276598-tm0yj2sn	408	3	-	-	JJ
cord-276598-tm0yj2sn	408	4	coupling	coupling	JJ
cord-276598-tm0yj2sn	408	5	reaction	reaction	NN
cord-276598-tm0yj2sn	408	6	of	of	IN
cord-276598-tm0yj2sn	408	7	amines	amine	NNS
cord-276598-tm0yj2sn	408	8	and	and	CC
cord-276598-tm0yj2sn	408	9	H	h	NN
cord-276598-tm0yj2sn	408	10	-	-	HYPH
cord-276598-tm0yj2sn	408	11	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	408	12	to	to	TO
cord-276598-tm0yj2sn	408	13	form	form	VB
cord-276598-tm0yj2sn	408	14	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	408	15	in	in	IN
cord-276598-tm0yj2sn	408	16	the	the	DT
cord-276598-tm0yj2sn	408	17	presence	presence	NN
cord-276598-tm0yj2sn	408	18	of	of	IN
cord-276598-tm0yj2sn	408	19	LiI	lii	NN
cord-276598-tm0yj2sn	408	20	/	/	SYM
cord-276598-tm0yj2sn	408	21	TBHP	TBHP	NNP
cord-276598-tm0yj2sn	408	22	.	.	.
cord-276598-tm0yj2sn	409	1	[	[	-LRB-
cord-276598-tm0yj2sn	409	2	111	111	CD
cord-276598-tm0yj2sn	409	3	]	]	-RRB-
cord-276598-tm0yj2sn	409	4	.	.	.
cord-276598-tm0yj2sn	410	1	The	the	DT
cord-276598-tm0yj2sn	410	2	crude	crude	JJ
cord-276598-tm0yj2sn	410	3	products	product	NNS
cord-276598-tm0yj2sn	410	4	were	be	VBD
cord-276598-tm0yj2sn	410	5	purified	purify	VBN
cord-276598-tm0yj2sn	410	6	by	by	IN
cord-276598-tm0yj2sn	410	7	column	column	NN
cord-276598-tm0yj2sn	410	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	410	9	(	(	-LRB-
cord-276598-tm0yj2sn	410	10	on	on	IN
cord-276598-tm0yj2sn	410	11	silica	silica	NN
cord-276598-tm0yj2sn	410	12	)	)	-RRB-
cord-276598-tm0yj2sn	410	13	with	with	IN
cord-276598-tm0yj2sn	410	14	isolated	isolated	JJ
cord-276598-tm0yj2sn	410	15	yields	yield	NNS
cord-276598-tm0yj2sn	410	16	of	of	IN
cord-276598-tm0yj2sn	410	17	65	65	CD
cord-276598-tm0yj2sn	410	18	%	%	NN
cord-276598-tm0yj2sn	410	19	and	and	CC
cord-276598-tm0yj2sn	410	20	31	31	CD
cord-276598-tm0yj2sn	410	21	%	%	NN
cord-276598-tm0yj2sn	410	22	for	for	IN
cord-276598-tm0yj2sn	410	23	the	the	DT
cord-276598-tm0yj2sn	410	24	use	use	NN
cord-276598-tm0yj2sn	410	25	of	of	IN
cord-276598-tm0yj2sn	410	26	benzylamine	benzylamine	NN
cord-276598-tm0yj2sn	410	27	and	and	CC
cord-276598-tm0yj2sn	410	28	4-chloroaniline	4-chloroaniline	CD
cord-276598-tm0yj2sn	410	29	,	,	,
cord-276598-tm0yj2sn	410	30	respectively	respectively	RB
cord-276598-tm0yj2sn	410	31	.	.	.
cord-276598-tm0yj2sn	411	1	Other	other	JJ
cord-276598-tm0yj2sn	411	2	amines	amine	NNS
cord-276598-tm0yj2sn	411	3	were	be	VBD
cord-276598-tm0yj2sn	411	4	not	not	RB
cord-276598-tm0yj2sn	411	5	investigated	investigate	VBN
cord-276598-tm0yj2sn	411	6	.	.	.
cord-276598-tm0yj2sn	412	1	Although	although	IN
cord-276598-tm0yj2sn	412	2	the	the	DT
cord-276598-tm0yj2sn	412	3	method	method	NN
cord-276598-tm0yj2sn	412	4	uses	use	VBZ
cord-276598-tm0yj2sn	412	5	an	an	DT
cord-276598-tm0yj2sn	412	6	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	412	7	catalyst	catalyst	NN
cord-276598-tm0yj2sn	412	8	and	and	CC
cord-276598-tm0yj2sn	412	9	oxidant	oxidant	NN
cord-276598-tm0yj2sn	412	10	,	,	,
cord-276598-tm0yj2sn	412	11	the	the	DT
cord-276598-tm0yj2sn	412	12	applicability	applicability	NN
cord-276598-tm0yj2sn	412	13	of	of	IN
cord-276598-tm0yj2sn	412	14	the	the	DT
cord-276598-tm0yj2sn	412	15	process	process	NN
cord-276598-tm0yj2sn	412	16	was	be	VBD
cord-276598-tm0yj2sn	412	17	not	not	RB
cord-276598-tm0yj2sn	412	18	explored	explore	VBN
cord-276598-tm0yj2sn	412	19	using	use	VBG
cord-276598-tm0yj2sn	412	20	diverse	diverse	JJ
cord-276598-tm0yj2sn	412	21	H	h	NN
cord-276598-tm0yj2sn	412	22	-	-	HYPH
cord-276598-tm0yj2sn	412	23	P	p	NN
cord-276598-tm0yj2sn	412	24	and	and	CC
cord-276598-tm0yj2sn	412	25	amines	amine	NNS
cord-276598-tm0yj2sn	412	26	.	.	.
cord-276598-tm0yj2sn	413	1	lithium	lithium	NN
cord-276598-tm0yj2sn	413	2	iodide	iodide	NN
cord-276598-tm0yj2sn	413	3	-	-	HYPH
cord-276598-tm0yj2sn	413	4	tert	tert	NN
cord-276598-tm0yj2sn	413	5	-	-	HYPH
cord-276598-tm0yj2sn	413	6	butyl	butyl	NN
cord-276598-tm0yj2sn	413	7	hydroperoxide	hydroperoxide	NN
cord-276598-tm0yj2sn	414	1	(	(	-LRB-
cord-276598-tm0yj2sn	414	2	LiI	lii	NN
cord-276598-tm0yj2sn	414	3	/	/	SYM
cord-276598-tm0yj2sn	414	4	TBHP	TBHP	NNP
cord-276598-tm0yj2sn	414	5	)	)	-RRB-
cord-276598-tm0yj2sn	414	6	was	be	VBD
cord-276598-tm0yj2sn	414	7	used	use	VBN
cord-276598-tm0yj2sn	414	8	for	for	IN
cord-276598-tm0yj2sn	414	9	the	the	DT
cord-276598-tm0yj2sn	414	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	414	11	of	of	IN
cord-276598-tm0yj2sn	414	12	P	P	NNP
cord-276598-tm0yj2sn	414	13	-	-	HYPH
cord-276598-tm0yj2sn	414	14	N	N	NNP
cord-276598-tm0yj2sn	414	15	and	and	CC
cord-276598-tm0yj2sn	414	16	other	other	JJ
cord-276598-tm0yj2sn	414	17	compounds	compound	NNS
cord-276598-tm0yj2sn	414	18	by	by	IN
cord-276598-tm0yj2sn	414	19	Reddy	Reddy	NNP
cord-276598-tm0yj2sn	414	20	et	et	NNP
cord-276598-tm0yj2sn	414	21	al	al	NNP
cord-276598-tm0yj2sn	414	22	.	.	.
cord-276598-tm0yj2sn	415	1	(	(	-LRB-
cord-276598-tm0yj2sn	415	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	415	3	9	9	CD
cord-276598-tm0yj2sn	415	4	)	)	-RRB-
cord-276598-tm0yj2sn	415	5	[	[	-LRB-
cord-276598-tm0yj2sn	415	6	111	111	CD
cord-276598-tm0yj2sn	415	7	]	]	-RRB-
cord-276598-tm0yj2sn	415	8	.	.	.
cord-276598-tm0yj2sn	416	1	The	the	DT
cord-276598-tm0yj2sn	416	2	crude	crude	JJ
cord-276598-tm0yj2sn	416	3	products	product	NNS
cord-276598-tm0yj2sn	416	4	were	be	VBD
cord-276598-tm0yj2sn	416	5	purified	purify	VBN
cord-276598-tm0yj2sn	416	6	by	by	IN
cord-276598-tm0yj2sn	416	7	column	column	NN
cord-276598-tm0yj2sn	416	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	416	9	(	(	-LRB-
cord-276598-tm0yj2sn	416	10	on	on	IN
cord-276598-tm0yj2sn	416	11	silica	silica	NN
cord-276598-tm0yj2sn	416	12	)	)	-RRB-
cord-276598-tm0yj2sn	416	13	with	with	IN
cord-276598-tm0yj2sn	416	14	isolated	isolated	JJ
cord-276598-tm0yj2sn	416	15	yields	yield	NNS
cord-276598-tm0yj2sn	416	16	of	of	IN
cord-276598-tm0yj2sn	416	17	65	65	CD
cord-276598-tm0yj2sn	416	18	%	%	NN
cord-276598-tm0yj2sn	416	19	and	and	CC
cord-276598-tm0yj2sn	416	20	31	31	CD
cord-276598-tm0yj2sn	416	21	%	%	NN
cord-276598-tm0yj2sn	416	22	for	for	IN
cord-276598-tm0yj2sn	416	23	the	the	DT
cord-276598-tm0yj2sn	416	24	use	use	NN
cord-276598-tm0yj2sn	416	25	of	of	IN
cord-276598-tm0yj2sn	416	26	benzylamine	benzylamine	NN
cord-276598-tm0yj2sn	416	27	and	and	CC
cord-276598-tm0yj2sn	416	28	4-chloroaniline	4-chloroaniline	CD
cord-276598-tm0yj2sn	416	29	,	,	,
cord-276598-tm0yj2sn	416	30	respectively	respectively	RB
cord-276598-tm0yj2sn	416	31	.	.	.
cord-276598-tm0yj2sn	417	1	Other	other	JJ
cord-276598-tm0yj2sn	417	2	amines	amine	NNS
cord-276598-tm0yj2sn	417	3	were	be	VBD
cord-276598-tm0yj2sn	417	4	not	not	RB
cord-276598-tm0yj2sn	417	5	investigated	investigate	VBN
cord-276598-tm0yj2sn	417	6	.	.	.
cord-276598-tm0yj2sn	418	1	Although	although	IN
cord-276598-tm0yj2sn	418	2	the	the	DT
cord-276598-tm0yj2sn	418	3	method	method	NN
cord-276598-tm0yj2sn	418	4	uses	use	VBZ
cord-276598-tm0yj2sn	418	5	an	an	DT
cord-276598-tm0yj2sn	418	6	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	418	7	catalyst	catalyst	NN
cord-276598-tm0yj2sn	418	8	and	and	CC
cord-276598-tm0yj2sn	418	9	oxidant	oxidant	NN
cord-276598-tm0yj2sn	418	10	,	,	,
cord-276598-tm0yj2sn	418	11	the	the	DT
cord-276598-tm0yj2sn	418	12	applicability	applicability	NN
cord-276598-tm0yj2sn	418	13	of	of	IN
cord-276598-tm0yj2sn	418	14	the	the	DT
cord-276598-tm0yj2sn	418	15	process	process	NN
cord-276598-tm0yj2sn	418	16	was	be	VBD
cord-276598-tm0yj2sn	418	17	not	not	RB
cord-276598-tm0yj2sn	418	18	explored	explore	VBN
cord-276598-tm0yj2sn	418	19	using	use	VBG
cord-276598-tm0yj2sn	418	20	diverse	diverse	JJ
cord-276598-tm0yj2sn	418	21	H	h	NN
cord-276598-tm0yj2sn	418	22	-	-	HYPH
cord-276598-tm0yj2sn	418	23	P	p	NN
cord-276598-tm0yj2sn	418	24	and	and	CC
cord-276598-tm0yj2sn	418	25	amines	amine	NNS
cord-276598-tm0yj2sn	418	26	.	.	.
cord-276598-tm0yj2sn	419	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	419	2	9	9	CD
cord-276598-tm0yj2sn	419	3	.	.	.
cord-276598-tm0yj2sn	420	1	Oxidative	oxidative	JJ
cord-276598-tm0yj2sn	420	2	cross	cross	JJ
cord-276598-tm0yj2sn	420	3	-	-	JJ
cord-276598-tm0yj2sn	420	4	coupling	coupling	JJ
cord-276598-tm0yj2sn	420	5	reaction	reaction	NN
cord-276598-tm0yj2sn	420	6	of	of	IN
cord-276598-tm0yj2sn	420	7	amines	amine	NNS
cord-276598-tm0yj2sn	420	8	and	and	CC
cord-276598-tm0yj2sn	420	9	H	h	NN
cord-276598-tm0yj2sn	420	10	-	-	HYPH
cord-276598-tm0yj2sn	420	11	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	420	12	to	to	TO
cord-276598-tm0yj2sn	420	13	form	form	VB
cord-276598-tm0yj2sn	420	14	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	420	15	in	in	IN
cord-276598-tm0yj2sn	420	16	the	the	DT
cord-276598-tm0yj2sn	420	17	presence	presence	NN
cord-276598-tm0yj2sn	420	18	of	of	IN
cord-276598-tm0yj2sn	420	19	LiI	lii	NN
cord-276598-tm0yj2sn	420	20	/	/	SYM
cord-276598-tm0yj2sn	420	21	TBHP	TBHP	NNP
cord-276598-tm0yj2sn	420	22	.	.	.
cord-276598-tm0yj2sn	421	1	Many	many	JJ
cord-276598-tm0yj2sn	421	2	conventional	conventional	JJ
cord-276598-tm0yj2sn	421	3	routes	route	NNS
cord-276598-tm0yj2sn	421	4	to	to	IN
cord-276598-tm0yj2sn	421	5	P	P	NNP
cord-276598-tm0yj2sn	421	6	-	-	HYPH
cord-276598-tm0yj2sn	421	7	N	n	CD
cord-276598-tm0yj2sn	421	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	421	9	as	as	IN
cord-276598-tm0yj2sn	421	10	discussed	discuss	VBN
cord-276598-tm0yj2sn	421	11	above	above	RB
cord-276598-tm0yj2sn	421	12	have	have	VBP
cord-276598-tm0yj2sn	421	13	used	use	VBN
cord-276598-tm0yj2sn	421	14	H	h	NN
cord-276598-tm0yj2sn	421	15	-	-	HYPH
cord-276598-tm0yj2sn	421	16	P	p	NN
cord-276598-tm0yj2sn	421	17	(	(	-LRB-
cord-276598-tm0yj2sn	421	18	RO)2P(O)H	ro)2p(o)h	CD
cord-276598-tm0yj2sn	422	1	(	(	-LRB-
cord-276598-tm0yj2sn	422	2	R	r	NN
cord-276598-tm0yj2sn	422	3	=	=	NN
cord-276598-tm0yj2sn	422	4	alkyl	alkyl	NN
cord-276598-tm0yj2sn	422	5	,	,	,
cord-276598-tm0yj2sn	423	1	Bn	Bn	NNP
cord-276598-tm0yj2sn	423	2	,	,	,
cord-276598-tm0yj2sn	423	3	Ph	Ph	NNP
cord-276598-tm0yj2sn	423	4	)	)	-RRB-
cord-276598-tm0yj2sn	423	5	or	or	CC
cord-276598-tm0yj2sn	424	1	(	(	-LRB-
cord-276598-tm0yj2sn	424	2	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	424	3	(	(	-LRB-
cord-276598-tm0yj2sn	424	4	dACP	dacp	NN
cord-276598-tm0yj2sn	424	5	;	;	:
cord-276598-tm0yj2sn	424	6	R	r	NN
cord-276598-tm0yj2sn	424	7	=	=	NN
cord-276598-tm0yj2sn	424	8	alkyl	alkyl	NN
cord-276598-tm0yj2sn	424	9	,	,	,
cord-276598-tm0yj2sn	424	10	Bn	Bn	NNP
cord-276598-tm0yj2sn	424	11	,	,	,
cord-276598-tm0yj2sn	424	12	Ph	Ph	NNP
cord-276598-tm0yj2sn	424	13	)	)	-RRB-
cord-276598-tm0yj2sn	424	14	and	and	CC
cord-276598-tm0yj2sn	424	15	amine	amine	NN
cord-276598-tm0yj2sn	424	16	as	as	IN
cord-276598-tm0yj2sn	424	17	the	the	DT
cord-276598-tm0yj2sn	424	18	P	P	NNP
cord-276598-tm0yj2sn	424	19	-	-	,
cord-276598-tm0yj2sn	424	20	and	and	CC
cord-276598-tm0yj2sn	424	21	N	n	CD
cord-276598-tm0yj2sn	424	22	-	-	HYPH
cord-276598-tm0yj2sn	424	23	sources	source	NNS
cord-276598-tm0yj2sn	424	24	,	,	,
cord-276598-tm0yj2sn	424	25	respectively	respectively	RB
cord-276598-tm0yj2sn	424	26	.	.	.
cord-276598-tm0yj2sn	425	1	As	as	IN
cord-276598-tm0yj2sn	425	2	a	a	DT
cord-276598-tm0yj2sn	425	3	result	result	NN
cord-276598-tm0yj2sn	425	4	,	,	,
cord-276598-tm0yj2sn	425	5	derivatives	derivative	NNS
cord-276598-tm0yj2sn	425	6	of	of	IN
cord-276598-tm0yj2sn	425	7	P	P	NNP
cord-276598-tm0yj2sn	425	8	-	-	HYPH
cord-276598-tm0yj2sn	425	9	N	N	NNP
cord-276598-tm0yj2sn	425	10	compounds	compound	NNS
cord-276598-tm0yj2sn	425	11	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	425	12	through	through	IN
cord-276598-tm0yj2sn	425	13	these	these	DT
cord-276598-tm0yj2sn	425	14	routes	route	NNS
cord-276598-tm0yj2sn	425	15	are	be	VBP
cord-276598-tm0yj2sn	425	16	limited	limit	VBN
cord-276598-tm0yj2sn	425	17	mainly	mainly	RB
cord-276598-tm0yj2sn	425	18	to	to	IN
cord-276598-tm0yj2sn	425	19	substituents	substituent	NNS
cord-276598-tm0yj2sn	425	20	on	on	IN
cord-276598-tm0yj2sn	425	21	the	the	DT
cord-276598-tm0yj2sn	425	22	amine	amine	NN
cord-276598-tm0yj2sn	425	23	starting	start	VBG
cord-276598-tm0yj2sn	425	24	materials	material	NNS
cord-276598-tm0yj2sn	425	25	.	.	.
cord-276598-tm0yj2sn	426	1	Due	due	IN
cord-276598-tm0yj2sn	426	2	to	to	IN
cord-276598-tm0yj2sn	426	3	increased	increase	VBN
cord-276598-tm0yj2sn	426	4	applicability	applicability	NN
cord-276598-tm0yj2sn	426	5	,	,	,
cord-276598-tm0yj2sn	426	6	it	-PRON-	PRP
cord-276598-tm0yj2sn	426	7	has	have	VBZ
cord-276598-tm0yj2sn	426	8	become	become	VBN
cord-276598-tm0yj2sn	426	9	necessary	necessary	JJ
cord-276598-tm0yj2sn	426	10	to	to	TO
cord-276598-tm0yj2sn	426	11	synthesize	synthesize	VB
cord-276598-tm0yj2sn	426	12	P	P	NNP
cord-276598-tm0yj2sn	426	13	-	-	HYPH
cord-276598-tm0yj2sn	426	14	N	n	CD
cord-276598-tm0yj2sn	426	15	compounds	compound	NNS
cord-276598-tm0yj2sn	426	16	with	with	IN
cord-276598-tm0yj2sn	426	17	diverse	diverse	JJ
cord-276598-tm0yj2sn	426	18	functionalities	functionality	NNS
cord-276598-tm0yj2sn	426	19	.	.	.
cord-276598-tm0yj2sn	427	1	In	in	IN
cord-276598-tm0yj2sn	427	2	order	order	NN
cord-276598-tm0yj2sn	427	3	to	to	TO
cord-276598-tm0yj2sn	427	4	achieve	achieve	VB
cord-276598-tm0yj2sn	427	5	this	this	DT
cord-276598-tm0yj2sn	427	6	,	,	,
cord-276598-tm0yj2sn	427	7	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	427	8	insertion	insertion	NN
cord-276598-tm0yj2sn	427	9	from	from	IN
cord-276598-tm0yj2sn	427	10	organic	organic	JJ
cord-276598-tm0yj2sn	427	11	azides	azide	NNS
cord-276598-tm0yj2sn	427	12	is	be	VBZ
cord-276598-tm0yj2sn	427	13	becoming	become	VBG
cord-276598-tm0yj2sn	427	14	a	a	DT
cord-276598-tm0yj2sn	427	15	popular	popular	JJ
cord-276598-tm0yj2sn	427	16	one	one	NN
cord-276598-tm0yj2sn	427	17	because	because	IN
cord-276598-tm0yj2sn	427	18	the	the	DT
cord-276598-tm0yj2sn	427	19	route	route	NN
cord-276598-tm0yj2sn	427	20	uses	use	VBZ
cord-276598-tm0yj2sn	427	21	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	427	22	azide	azide	NN
cord-276598-tm0yj2sn	427	23	,	,	,
cord-276598-tm0yj2sn	427	24	which	which	WDT
cord-276598-tm0yj2sn	427	25	acts	act	VBZ
cord-276598-tm0yj2sn	427	26	a	a	DT
cord-276598-tm0yj2sn	427	27	dual	dual	JJ
cord-276598-tm0yj2sn	427	28	source	source	NN
cord-276598-tm0yj2sn	427	29	of	of	IN
cord-276598-tm0yj2sn	427	30	P	p	NN
cord-276598-tm0yj2sn	427	31	and	and	CC
cord-276598-tm0yj2sn	427	32	N.	n.	NN
cord-276598-tm0yj2sn	428	1	In	in	IN
cord-276598-tm0yj2sn	428	2	this	this	DT
cord-276598-tm0yj2sn	428	3	case	case	NN
cord-276598-tm0yj2sn	428	4	,	,	,
cord-276598-tm0yj2sn	428	5	it	-PRON-	PRP
cord-276598-tm0yj2sn	428	6	is	be	VBZ
cord-276598-tm0yj2sn	428	7	possible	possible	JJ
cord-276598-tm0yj2sn	428	8	to	to	TO
cord-276598-tm0yj2sn	428	9	add	add	VB
cord-276598-tm0yj2sn	428	10	(	(	-LRB-
cord-276598-tm0yj2sn	428	11	or	or	CC
cord-276598-tm0yj2sn	428	12	insert	insert	VB
cord-276598-tm0yj2sn	428	13	)	)	-RRB-
cord-276598-tm0yj2sn	428	14	diverse	diverse	JJ
cord-276598-tm0yj2sn	428	15	molecules	molecule	NNS
cord-276598-tm0yj2sn	428	16	on	on	IN
cord-276598-tm0yj2sn	428	17	the	the	DT
cord-276598-tm0yj2sn	428	18	P	P	NNP
cord-276598-tm0yj2sn	428	19	-	-	HYPH
cord-276598-tm0yj2sn	428	20	N	N	NNP
cord-276598-tm0yj2sn	428	21	moiety	moiety	NN
cord-276598-tm0yj2sn	428	22	through	through	IN
cord-276598-tm0yj2sn	428	23	C	C	NNP
cord-276598-tm0yj2sn	428	24	-	-	HYPH
cord-276598-tm0yj2sn	428	25	N	N	NNP
cord-276598-tm0yj2sn	428	26	bond	bond	NN
cord-276598-tm0yj2sn	428	27	formation	formation	NN
cord-276598-tm0yj2sn	428	28	.	.	.
cord-276598-tm0yj2sn	429	1	A	a	DT
cord-276598-tm0yj2sn	429	2	route	route	NN
cord-276598-tm0yj2sn	429	3	to	to	IN
cord-276598-tm0yj2sn	429	4	P	p	NN
cord-276598-tm0yj2sn	429	5	-	-	HYPH
cord-276598-tm0yj2sn	429	6	N	n	CD
cord-276598-tm0yj2sn	429	7	formation	formation	NN
cord-276598-tm0yj2sn	429	8	through	through	IN
cord-276598-tm0yj2sn	429	9	C	C	NNP
cord-276598-tm0yj2sn	429	10	-	-	HYPH
cord-276598-tm0yj2sn	429	11	N	N	NNP
cord-276598-tm0yj2sn	429	12	bond	bond	NN
cord-276598-tm0yj2sn	429	13	formation	formation	NN
cord-276598-tm0yj2sn	429	14	was	be	VBD
cord-276598-tm0yj2sn	429	15	explored	explore	VBN
cord-276598-tm0yj2sn	429	16	by	by	IN
cord-276598-tm0yj2sn	429	17	Chang	Chang	NNP
cord-276598-tm0yj2sn	429	18	,	,	,
cord-276598-tm0yj2sn	429	19	Kim	Kim	NNP
cord-276598-tm0yj2sn	429	20	,	,	,
cord-276598-tm0yj2sn	429	21	and	and	CC
cord-276598-tm0yj2sn	429	22	coworkers	coworker	NNS
cord-276598-tm0yj2sn	429	23	(	(	-LRB-
cord-276598-tm0yj2sn	429	24	Scheme	scheme	NN
cord-276598-tm0yj2sn	429	25	10a	10a	CD
cord-276598-tm0yj2sn	429	26	)	)	-RRB-
cord-276598-tm0yj2sn	429	27	[	[	-LRB-
cord-276598-tm0yj2sn	429	28	112	112	CD
cord-276598-tm0yj2sn	429	29	]	]	-RRB-
cord-276598-tm0yj2sn	429	30	.	.	.
cord-276598-tm0yj2sn	430	1	The	the	DT
cord-276598-tm0yj2sn	430	2	P	P	NNP
cord-276598-tm0yj2sn	430	3	-	-	HYPH
cord-276598-tm0yj2sn	430	4	N	N	NNP
cord-276598-tm0yj2sn	430	5	was	be	VBD
cord-276598-tm0yj2sn	430	6	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	430	7	in	in	IN
cord-276598-tm0yj2sn	430	8	the	the	DT
cord-276598-tm0yj2sn	430	9	presence	presence	NN
cord-276598-tm0yj2sn	430	10	of	of	IN
cord-276598-tm0yj2sn	430	11	an	an	DT
cord-276598-tm0yj2sn	430	12	Ir(III)-based	ir(iii)-based	JJ
cord-276598-tm0yj2sn	430	13	catalyst	catalyst	NN
cord-276598-tm0yj2sn	430	14	using	use	VBG
cord-276598-tm0yj2sn	430	15	an	an	DT
cord-276598-tm0yj2sn	430	16	amide	amide	NN
cord-276598-tm0yj2sn	430	17	or	or	CC
cord-276598-tm0yj2sn	430	18	a	a	DT
cord-276598-tm0yj2sn	430	19	ketone	ketone	NN
cord-276598-tm0yj2sn	430	20	and	and	CC
cord-276598-tm0yj2sn	430	21	a	a	DT
cord-276598-tm0yj2sn	430	22	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	430	23	azide	azide	NN
cord-276598-tm0yj2sn	430	24	.	.	.
cord-276598-tm0yj2sn	431	1	The	the	DT
cord-276598-tm0yj2sn	431	2	product	product	NN
cord-276598-tm0yj2sn	431	3	was	be	VBD
cord-276598-tm0yj2sn	431	4	purified	purify	VBN
cord-276598-tm0yj2sn	431	5	by	by	IN
cord-276598-tm0yj2sn	431	6	column	column	NN
cord-276598-tm0yj2sn	431	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	431	8	(	(	-LRB-
cord-276598-tm0yj2sn	431	9	on	on	IN
cord-276598-tm0yj2sn	431	10	silica	silica	NN
cord-276598-tm0yj2sn	431	11	)	)	-RRB-
cord-276598-tm0yj2sn	431	12	with	with	IN
cord-276598-tm0yj2sn	431	13	isolated	isolate	VBN
cord-276598-tm0yj2sn	431	14	yields	yield	NNS
cord-276598-tm0yj2sn	431	15	in	in	IN
cord-276598-tm0yj2sn	431	16	the	the	DT
cord-276598-tm0yj2sn	431	17	range	range	NN
cord-276598-tm0yj2sn	431	18	41	41	CD
cord-276598-tm0yj2sn	431	19	-	-	SYM
cord-276598-tm0yj2sn	431	20	99	99	CD
cord-276598-tm0yj2sn	431	21	%	%	NN
cord-276598-tm0yj2sn	431	22	.	.	.
cord-276598-tm0yj2sn	432	1	The	the	DT
cord-276598-tm0yj2sn	432	2	scope	scope	NN
cord-276598-tm0yj2sn	432	3	of	of	IN
cord-276598-tm0yj2sn	432	4	the	the	DT
cord-276598-tm0yj2sn	432	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	432	6	was	be	VBD
cord-276598-tm0yj2sn	432	7	explored	explore	VBN
cord-276598-tm0yj2sn	432	8	using	use	VBG
cord-276598-tm0yj2sn	432	9	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	432	10	azide	azide	NN
cord-276598-tm0yj2sn	432	11	substituted	substitute	VBN
cord-276598-tm0yj2sn	432	12	with	with	IN
cord-276598-tm0yj2sn	432	13	binaphthyl	binaphthyl	NN
cord-276598-tm0yj2sn	432	14	,	,	,
cord-276598-tm0yj2sn	432	15	aryl	aryl	NN
cord-276598-tm0yj2sn	432	16	,	,	,
cord-276598-tm0yj2sn	432	17	and	and	CC
cord-276598-tm0yj2sn	432	18	alkyl	alkyl	JJ
cord-276598-tm0yj2sn	432	19	groups	group	NNS
cord-276598-tm0yj2sn	432	20	,	,	,
cord-276598-tm0yj2sn	432	21	while	while	IN
cord-276598-tm0yj2sn	432	22	the	the	DT
cord-276598-tm0yj2sn	432	23	phenone	phenone	NN
cord-276598-tm0yj2sn	432	24	had	have	VBD
cord-276598-tm0yj2sn	432	25	substituents	substituent	NNS
cord-276598-tm0yj2sn	432	26	such	such	JJ
cord-276598-tm0yj2sn	432	27	as	as	IN
cord-276598-tm0yj2sn	432	28	phenyl	phenyl	NN
cord-276598-tm0yj2sn	432	29	,	,	,
cord-276598-tm0yj2sn	432	30	methyl	methyl	NN
cord-276598-tm0yj2sn	432	31	,	,	,
cord-276598-tm0yj2sn	432	32	and	and	CC
cord-276598-tm0yj2sn	432	33	isobutane	isobutane	NN
cord-276598-tm0yj2sn	432	34	groups	group	NNS
cord-276598-tm0yj2sn	432	35	.	.	.
cord-276598-tm0yj2sn	433	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	433	2	,	,	,
cord-276598-tm0yj2sn	433	3	4-methoxy	4-methoxy	CD
cord-276598-tm0yj2sn	433	4	,	,	,
cord-276598-tm0yj2sn	433	5	4-CF3	4-cf3	CD
cord-276598-tm0yj2sn	433	6	,	,	,
cord-276598-tm0yj2sn	433	7	and	and	CC
cord-276598-tm0yj2sn	433	8	tert	tert	NN
cord-276598-tm0yj2sn	433	9	-	-	HYPH
cord-276598-tm0yj2sn	433	10	butyl	butyl	NN
cord-276598-tm0yj2sn	433	11	were	be	VBD
cord-276598-tm0yj2sn	433	12	some	some	DT
cord-276598-tm0yj2sn	433	13	of	of	IN
cord-276598-tm0yj2sn	433	14	the	the	DT
cord-276598-tm0yj2sn	433	15	substituents	substituent	NNS
cord-276598-tm0yj2sn	433	16	on	on	IN
cord-276598-tm0yj2sn	433	17	the	the	DT
cord-276598-tm0yj2sn	433	18	benzamide	benzamide	NN
cord-276598-tm0yj2sn	433	19	.	.	.
cord-276598-tm0yj2sn	434	1	Biologically	biologically	RB
cord-276598-tm0yj2sn	434	2	active	active	JJ
cord-276598-tm0yj2sn	434	3	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	434	4	(	(	-LRB-
cord-276598-tm0yj2sn	434	5	17	17	CD
cord-276598-tm0yj2sn	434	6	and	and	CC
cord-276598-tm0yj2sn	434	7	18	18	CD
cord-276598-tm0yj2sn	434	8	)	)	-RRB-
cord-276598-tm0yj2sn	434	9	were	be	VBD
cord-276598-tm0yj2sn	434	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	434	11	through	through	IN
cord-276598-tm0yj2sn	434	12	this	this	DT
cord-276598-tm0yj2sn	434	13	method	method	NN
cord-276598-tm0yj2sn	434	14	(	(	-LRB-
cord-276598-tm0yj2sn	434	15	Figure	Figure	NNP
cord-276598-tm0yj2sn	434	16	8	8	CD
cord-276598-tm0yj2sn	434	17	)	)	-RRB-
cord-276598-tm0yj2sn	434	18	.	.	.
cord-276598-tm0yj2sn	435	1	Oxidative	oxidative	JJ
cord-276598-tm0yj2sn	435	2	cross	cross	JJ
cord-276598-tm0yj2sn	435	3	-	-	JJ
cord-276598-tm0yj2sn	435	4	coupling	coupling	JJ
cord-276598-tm0yj2sn	435	5	reaction	reaction	NN
cord-276598-tm0yj2sn	435	6	of	of	IN
cord-276598-tm0yj2sn	435	7	amines	amine	NNS
cord-276598-tm0yj2sn	435	8	and	and	CC
cord-276598-tm0yj2sn	435	9	H	h	NN
cord-276598-tm0yj2sn	435	10	-	-	HYPH
cord-276598-tm0yj2sn	435	11	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	435	12	to	to	TO
cord-276598-tm0yj2sn	435	13	form	form	VB
cord-276598-tm0yj2sn	435	14	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	435	15	in	in	IN
cord-276598-tm0yj2sn	435	16	the	the	DT
cord-276598-tm0yj2sn	435	17	presence	presence	NN
cord-276598-tm0yj2sn	435	18	of	of	IN
cord-276598-tm0yj2sn	435	19	LiI	lii	NN
cord-276598-tm0yj2sn	435	20	/	/	SYM
cord-276598-tm0yj2sn	435	21	TBHP	TBHP	NNP
cord-276598-tm0yj2sn	435	22	.	.	.
cord-276598-tm0yj2sn	436	1	Many	many	JJ
cord-276598-tm0yj2sn	436	2	conventional	conventional	JJ
cord-276598-tm0yj2sn	436	3	routes	route	NNS
cord-276598-tm0yj2sn	436	4	to	to	IN
cord-276598-tm0yj2sn	436	5	P	P	NNP
cord-276598-tm0yj2sn	436	6	-	-	HYPH
cord-276598-tm0yj2sn	436	7	N	n	CD
cord-276598-tm0yj2sn	436	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	436	9	as	as	IN
cord-276598-tm0yj2sn	436	10	discussed	discuss	VBN
cord-276598-tm0yj2sn	436	11	above	above	RB
cord-276598-tm0yj2sn	436	12	have	have	VBP
cord-276598-tm0yj2sn	436	13	used	use	VBN
cord-276598-tm0yj2sn	436	14	H	h	NN
cord-276598-tm0yj2sn	436	15	-	-	HYPH
cord-276598-tm0yj2sn	436	16	P	p	NN
cord-276598-tm0yj2sn	436	17	(	(	-LRB-
cord-276598-tm0yj2sn	436	18	RO	RO	NNP
cord-276598-tm0yj2sn	436	19	)	)	-RRB-
cord-276598-tm0yj2sn	436	20	2	2	CD
cord-276598-tm0yj2sn	437	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	438	1	(	(	-LRB-
cord-276598-tm0yj2sn	438	2	R	r	NN
cord-276598-tm0yj2sn	438	3	=	=	NN
cord-276598-tm0yj2sn	438	4	alkyl	alkyl	NN
cord-276598-tm0yj2sn	438	5	,	,	,
cord-276598-tm0yj2sn	439	1	Bn	Bn	NNP
cord-276598-tm0yj2sn	439	2	,	,	,
cord-276598-tm0yj2sn	439	3	Ph	Ph	NNP
cord-276598-tm0yj2sn	439	4	)	)	-RRB-
cord-276598-tm0yj2sn	439	5	or	or	CC
cord-276598-tm0yj2sn	439	6	(	(	-LRB-
cord-276598-tm0yj2sn	439	7	RO	RO	NNP
cord-276598-tm0yj2sn	439	8	)	)	-RRB-
cord-276598-tm0yj2sn	439	9	2	2	CD
cord-276598-tm0yj2sn	440	1	P(O)Cl	P(O)Cl	VBN
cord-276598-tm0yj2sn	441	1	(	(	-LRB-
cord-276598-tm0yj2sn	441	2	dACP	dacp	JJ
cord-276598-tm0yj2sn	441	3	;	;	:
cord-276598-tm0yj2sn	441	4	R	r	NN
cord-276598-tm0yj2sn	441	5	=	=	NN
cord-276598-tm0yj2sn	441	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	441	7	,	,	,
cord-276598-tm0yj2sn	441	8	Bn	Bn	NNP
cord-276598-tm0yj2sn	441	9	,	,	,
cord-276598-tm0yj2sn	441	10	Ph	Ph	NNP
cord-276598-tm0yj2sn	441	11	)	)	-RRB-
cord-276598-tm0yj2sn	441	12	and	and	CC
cord-276598-tm0yj2sn	441	13	amine	amine	NN
cord-276598-tm0yj2sn	441	14	as	as	IN
cord-276598-tm0yj2sn	441	15	the	the	DT
cord-276598-tm0yj2sn	441	16	P	P	NNP
cord-276598-tm0yj2sn	441	17	-	-	,
cord-276598-tm0yj2sn	441	18	and	and	CC
cord-276598-tm0yj2sn	441	19	N	n	CD
cord-276598-tm0yj2sn	441	20	-	-	HYPH
cord-276598-tm0yj2sn	441	21	sources	source	NNS
cord-276598-tm0yj2sn	441	22	,	,	,
cord-276598-tm0yj2sn	441	23	respectively	respectively	RB
cord-276598-tm0yj2sn	441	24	.	.	.
cord-276598-tm0yj2sn	442	1	As	as	IN
cord-276598-tm0yj2sn	442	2	a	a	DT
cord-276598-tm0yj2sn	442	3	result	result	NN
cord-276598-tm0yj2sn	442	4	,	,	,
cord-276598-tm0yj2sn	442	5	derivatives	derivative	NNS
cord-276598-tm0yj2sn	442	6	of	of	IN
cord-276598-tm0yj2sn	442	7	P	P	NNP
cord-276598-tm0yj2sn	442	8	-	-	HYPH
cord-276598-tm0yj2sn	442	9	N	N	NNP
cord-276598-tm0yj2sn	442	10	compounds	compound	NNS
cord-276598-tm0yj2sn	442	11	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	442	12	through	through	IN
cord-276598-tm0yj2sn	442	13	these	these	DT
cord-276598-tm0yj2sn	442	14	routes	route	NNS
cord-276598-tm0yj2sn	442	15	are	be	VBP
cord-276598-tm0yj2sn	442	16	limited	limit	VBN
cord-276598-tm0yj2sn	442	17	mainly	mainly	RB
cord-276598-tm0yj2sn	442	18	to	to	IN
cord-276598-tm0yj2sn	442	19	substituents	substituent	NNS
cord-276598-tm0yj2sn	442	20	on	on	IN
cord-276598-tm0yj2sn	442	21	the	the	DT
cord-276598-tm0yj2sn	442	22	amine	amine	NN
cord-276598-tm0yj2sn	442	23	starting	start	VBG
cord-276598-tm0yj2sn	442	24	materials	material	NNS
cord-276598-tm0yj2sn	442	25	.	.	.
cord-276598-tm0yj2sn	443	1	Due	due	IN
cord-276598-tm0yj2sn	443	2	to	to	IN
cord-276598-tm0yj2sn	443	3	increased	increase	VBN
cord-276598-tm0yj2sn	443	4	applicability	applicability	NN
cord-276598-tm0yj2sn	443	5	,	,	,
cord-276598-tm0yj2sn	443	6	it	-PRON-	PRP
cord-276598-tm0yj2sn	443	7	has	have	VBZ
cord-276598-tm0yj2sn	443	8	become	become	VBN
cord-276598-tm0yj2sn	443	9	necessary	necessary	JJ
cord-276598-tm0yj2sn	443	10	to	to	TO
cord-276598-tm0yj2sn	443	11	synthesize	synthesize	VB
cord-276598-tm0yj2sn	443	12	P	P	NNP
cord-276598-tm0yj2sn	443	13	-	-	HYPH
cord-276598-tm0yj2sn	443	14	N	n	CD
cord-276598-tm0yj2sn	443	15	compounds	compound	NNS
cord-276598-tm0yj2sn	443	16	with	with	IN
cord-276598-tm0yj2sn	443	17	diverse	diverse	JJ
cord-276598-tm0yj2sn	443	18	functionalities	functionality	NNS
cord-276598-tm0yj2sn	443	19	.	.	.
cord-276598-tm0yj2sn	444	1	In	in	IN
cord-276598-tm0yj2sn	444	2	order	order	NN
cord-276598-tm0yj2sn	444	3	to	to	TO
cord-276598-tm0yj2sn	444	4	achieve	achieve	VB
cord-276598-tm0yj2sn	444	5	this	this	DT
cord-276598-tm0yj2sn	444	6	,	,	,
cord-276598-tm0yj2sn	444	7	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	444	8	insertion	insertion	NN
cord-276598-tm0yj2sn	444	9	from	from	IN
cord-276598-tm0yj2sn	444	10	organic	organic	JJ
cord-276598-tm0yj2sn	444	11	azides	azide	NNS
cord-276598-tm0yj2sn	444	12	is	be	VBZ
cord-276598-tm0yj2sn	444	13	becoming	become	VBG
cord-276598-tm0yj2sn	444	14	a	a	DT
cord-276598-tm0yj2sn	444	15	popular	popular	JJ
cord-276598-tm0yj2sn	444	16	one	one	NN
cord-276598-tm0yj2sn	444	17	because	because	IN
cord-276598-tm0yj2sn	444	18	the	the	DT
cord-276598-tm0yj2sn	444	19	route	route	NN
cord-276598-tm0yj2sn	444	20	uses	use	VBZ
cord-276598-tm0yj2sn	444	21	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	444	22	azide	azide	NN
cord-276598-tm0yj2sn	444	23	,	,	,
cord-276598-tm0yj2sn	444	24	which	which	WDT
cord-276598-tm0yj2sn	444	25	acts	act	VBZ
cord-276598-tm0yj2sn	444	26	a	a	DT
cord-276598-tm0yj2sn	444	27	dual	dual	JJ
cord-276598-tm0yj2sn	444	28	source	source	NN
cord-276598-tm0yj2sn	444	29	of	of	IN
cord-276598-tm0yj2sn	444	30	P	p	NN
cord-276598-tm0yj2sn	444	31	and	and	CC
cord-276598-tm0yj2sn	444	32	N.	n.	NN
cord-276598-tm0yj2sn	445	1	In	in	IN
cord-276598-tm0yj2sn	445	2	this	this	DT
cord-276598-tm0yj2sn	445	3	case	case	NN
cord-276598-tm0yj2sn	445	4	,	,	,
cord-276598-tm0yj2sn	445	5	it	-PRON-	PRP
cord-276598-tm0yj2sn	445	6	is	be	VBZ
cord-276598-tm0yj2sn	445	7	possible	possible	JJ
cord-276598-tm0yj2sn	445	8	to	to	TO
cord-276598-tm0yj2sn	445	9	add	add	VB
cord-276598-tm0yj2sn	445	10	(	(	-LRB-
cord-276598-tm0yj2sn	445	11	or	or	CC
cord-276598-tm0yj2sn	445	12	insert	insert	VB
cord-276598-tm0yj2sn	445	13	)	)	-RRB-
cord-276598-tm0yj2sn	445	14	diverse	diverse	JJ
cord-276598-tm0yj2sn	445	15	molecules	molecule	NNS
cord-276598-tm0yj2sn	445	16	on	on	IN
cord-276598-tm0yj2sn	445	17	the	the	DT
cord-276598-tm0yj2sn	445	18	P	P	NNP
cord-276598-tm0yj2sn	445	19	-	-	HYPH
cord-276598-tm0yj2sn	445	20	N	N	NNP
cord-276598-tm0yj2sn	445	21	moiety	moiety	NN
cord-276598-tm0yj2sn	445	22	through	through	IN
cord-276598-tm0yj2sn	445	23	C	C	NNP
cord-276598-tm0yj2sn	445	24	-	-	HYPH
cord-276598-tm0yj2sn	445	25	N	N	NNP
cord-276598-tm0yj2sn	445	26	bond	bond	NN
cord-276598-tm0yj2sn	445	27	formation	formation	NN
cord-276598-tm0yj2sn	445	28	.	.	.
cord-276598-tm0yj2sn	446	1	A	a	DT
cord-276598-tm0yj2sn	446	2	route	route	NN
cord-276598-tm0yj2sn	446	3	to	to	IN
cord-276598-tm0yj2sn	446	4	P	p	NN
cord-276598-tm0yj2sn	446	5	-	-	HYPH
cord-276598-tm0yj2sn	446	6	N	n	CD
cord-276598-tm0yj2sn	446	7	formation	formation	NN
cord-276598-tm0yj2sn	446	8	through	through	IN
cord-276598-tm0yj2sn	446	9	C	C	NNP
cord-276598-tm0yj2sn	446	10	-	-	HYPH
cord-276598-tm0yj2sn	446	11	N	N	NNP
cord-276598-tm0yj2sn	446	12	bond	bond	NN
cord-276598-tm0yj2sn	446	13	formation	formation	NN
cord-276598-tm0yj2sn	446	14	was	be	VBD
cord-276598-tm0yj2sn	446	15	explored	explore	VBN
cord-276598-tm0yj2sn	446	16	by	by	IN
cord-276598-tm0yj2sn	446	17	Chang	Chang	NNP
cord-276598-tm0yj2sn	446	18	,	,	,
cord-276598-tm0yj2sn	446	19	Kim	Kim	NNP
cord-276598-tm0yj2sn	446	20	,	,	,
cord-276598-tm0yj2sn	446	21	and	and	CC
cord-276598-tm0yj2sn	446	22	coworkers	coworker	NNS
cord-276598-tm0yj2sn	446	23	(	(	-LRB-
cord-276598-tm0yj2sn	446	24	Scheme	scheme	NN
cord-276598-tm0yj2sn	446	25	10a	10a	CD
cord-276598-tm0yj2sn	446	26	)	)	-RRB-
cord-276598-tm0yj2sn	446	27	[	[	-LRB-
cord-276598-tm0yj2sn	446	28	112	112	CD
cord-276598-tm0yj2sn	446	29	]	]	-RRB-
cord-276598-tm0yj2sn	446	30	.	.	.
cord-276598-tm0yj2sn	447	1	The	the	DT
cord-276598-tm0yj2sn	447	2	P	P	NNP
cord-276598-tm0yj2sn	447	3	-	-	HYPH
cord-276598-tm0yj2sn	447	4	N	N	NNP
cord-276598-tm0yj2sn	447	5	was	be	VBD
cord-276598-tm0yj2sn	447	6	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	447	7	in	in	IN
cord-276598-tm0yj2sn	447	8	the	the	DT
cord-276598-tm0yj2sn	447	9	presence	presence	NN
cord-276598-tm0yj2sn	447	10	of	of	IN
cord-276598-tm0yj2sn	447	11	an	an	DT
cord-276598-tm0yj2sn	447	12	Ir(III)-based	ir(iii)-based	JJ
cord-276598-tm0yj2sn	447	13	catalyst	catalyst	NN
cord-276598-tm0yj2sn	447	14	using	use	VBG
cord-276598-tm0yj2sn	447	15	an	an	DT
cord-276598-tm0yj2sn	447	16	amide	amide	NN
cord-276598-tm0yj2sn	447	17	or	or	CC
cord-276598-tm0yj2sn	447	18	a	a	DT
cord-276598-tm0yj2sn	447	19	ketone	ketone	NN
cord-276598-tm0yj2sn	447	20	and	and	CC
cord-276598-tm0yj2sn	447	21	a	a	DT
cord-276598-tm0yj2sn	447	22	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	447	23	azide	azide	NN
cord-276598-tm0yj2sn	447	24	.	.	.
cord-276598-tm0yj2sn	448	1	The	the	DT
cord-276598-tm0yj2sn	448	2	product	product	NN
cord-276598-tm0yj2sn	448	3	was	be	VBD
cord-276598-tm0yj2sn	448	4	purified	purify	VBN
cord-276598-tm0yj2sn	448	5	by	by	IN
cord-276598-tm0yj2sn	448	6	column	column	NN
cord-276598-tm0yj2sn	448	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	448	8	(	(	-LRB-
cord-276598-tm0yj2sn	448	9	on	on	IN
cord-276598-tm0yj2sn	448	10	silica	silica	NN
cord-276598-tm0yj2sn	448	11	)	)	-RRB-
cord-276598-tm0yj2sn	448	12	with	with	IN
cord-276598-tm0yj2sn	448	13	isolated	isolate	VBN
cord-276598-tm0yj2sn	448	14	yields	yield	NNS
cord-276598-tm0yj2sn	448	15	in	in	IN
cord-276598-tm0yj2sn	448	16	the	the	DT
cord-276598-tm0yj2sn	448	17	range	range	NN
cord-276598-tm0yj2sn	448	18	41	41	CD
cord-276598-tm0yj2sn	448	19	-	-	SYM
cord-276598-tm0yj2sn	448	20	99	99	CD
cord-276598-tm0yj2sn	448	21	%	%	NN
cord-276598-tm0yj2sn	448	22	.	.	.
cord-276598-tm0yj2sn	449	1	The	the	DT
cord-276598-tm0yj2sn	449	2	scope	scope	NN
cord-276598-tm0yj2sn	449	3	of	of	IN
cord-276598-tm0yj2sn	449	4	the	the	DT
cord-276598-tm0yj2sn	449	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	449	6	was	be	VBD
cord-276598-tm0yj2sn	449	7	explored	explore	VBN
cord-276598-tm0yj2sn	449	8	using	use	VBG
cord-276598-tm0yj2sn	449	9	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	449	10	azide	azide	NN
cord-276598-tm0yj2sn	449	11	substituted	substitute	VBN
cord-276598-tm0yj2sn	449	12	with	with	IN
cord-276598-tm0yj2sn	449	13	binaphthyl	binaphthyl	NN
cord-276598-tm0yj2sn	449	14	,	,	,
cord-276598-tm0yj2sn	449	15	aryl	aryl	NN
cord-276598-tm0yj2sn	449	16	,	,	,
cord-276598-tm0yj2sn	449	17	and	and	CC
cord-276598-tm0yj2sn	449	18	alkyl	alkyl	JJ
cord-276598-tm0yj2sn	449	19	groups	group	NNS
cord-276598-tm0yj2sn	449	20	,	,	,
cord-276598-tm0yj2sn	449	21	while	while	IN
cord-276598-tm0yj2sn	449	22	the	the	DT
cord-276598-tm0yj2sn	449	23	phenone	phenone	NN
cord-276598-tm0yj2sn	449	24	had	have	VBD
cord-276598-tm0yj2sn	449	25	substituents	substituent	NNS
cord-276598-tm0yj2sn	449	26	such	such	JJ
cord-276598-tm0yj2sn	449	27	as	as	IN
cord-276598-tm0yj2sn	449	28	phenyl	phenyl	NN
cord-276598-tm0yj2sn	449	29	,	,	,
cord-276598-tm0yj2sn	449	30	methyl	methyl	NN
cord-276598-tm0yj2sn	449	31	,	,	,
cord-276598-tm0yj2sn	449	32	and	and	CC
cord-276598-tm0yj2sn	449	33	isobutane	isobutane	NN
cord-276598-tm0yj2sn	449	34	groups	group	NNS
cord-276598-tm0yj2sn	449	35	.	.	.
cord-276598-tm0yj2sn	450	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	450	2	,	,	,
cord-276598-tm0yj2sn	450	3	4-methoxy	4-methoxy	CD
cord-276598-tm0yj2sn	450	4	,	,	,
cord-276598-tm0yj2sn	450	5	4-CF	4-cf	CD
cord-276598-tm0yj2sn	450	6	3	3	CD
cord-276598-tm0yj2sn	450	7	,	,	,
cord-276598-tm0yj2sn	450	8	and	and	CC
cord-276598-tm0yj2sn	450	9	tert	tert	NN
cord-276598-tm0yj2sn	450	10	-	-	HYPH
cord-276598-tm0yj2sn	450	11	butyl	butyl	NN
cord-276598-tm0yj2sn	450	12	were	be	VBD
cord-276598-tm0yj2sn	450	13	some	some	DT
cord-276598-tm0yj2sn	450	14	of	of	IN
cord-276598-tm0yj2sn	450	15	the	the	DT
cord-276598-tm0yj2sn	450	16	substituents	substituent	NNS
cord-276598-tm0yj2sn	450	17	on	on	IN
cord-276598-tm0yj2sn	450	18	the	the	DT
cord-276598-tm0yj2sn	450	19	benzamide	benzamide	NN
cord-276598-tm0yj2sn	450	20	.	.	.
cord-276598-tm0yj2sn	451	1	Biologically	biologically	RB
cord-276598-tm0yj2sn	451	2	active	active	JJ
cord-276598-tm0yj2sn	451	3	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	451	4	(	(	-LRB-
cord-276598-tm0yj2sn	451	5	17	17	CD
cord-276598-tm0yj2sn	451	6	and	and	CC
cord-276598-tm0yj2sn	451	7	18	18	CD
cord-276598-tm0yj2sn	451	8	)	)	-RRB-
cord-276598-tm0yj2sn	451	9	were	be	VBD
cord-276598-tm0yj2sn	451	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	451	11	through	through	IN
cord-276598-tm0yj2sn	451	12	this	this	DT
cord-276598-tm0yj2sn	451	13	method	method	NN
cord-276598-tm0yj2sn	451	14	(	(	-LRB-
cord-276598-tm0yj2sn	451	15	Figure	Figure	NNP
cord-276598-tm0yj2sn	451	16	8	8	CD
cord-276598-tm0yj2sn	451	17	)	)	-RRB-
cord-276598-tm0yj2sn	451	18	.	.	.
cord-276598-tm0yj2sn	452	1	Che	Che	NNP
cord-276598-tm0yj2sn	452	2	and	and	CC
cord-276598-tm0yj2sn	452	3	coworkers	coworker	NNS
cord-276598-tm0yj2sn	452	4	later	later	RB
cord-276598-tm0yj2sn	452	5	introduced	introduce	VBD
cord-276598-tm0yj2sn	452	6	a	a	DT
cord-276598-tm0yj2sn	452	7	Ru	Ru	NNP
cord-276598-tm0yj2sn	452	8	IV	IV	NNP
cord-276598-tm0yj2sn	452	9	-porphyrin	-porphyrin	NN
cord-276598-tm0yj2sn	452	10	-	-	HYPH
cord-276598-tm0yj2sn	452	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	452	12	to	to	TO
cord-276598-tm0yj2sn	452	13	synthesize	synthesize	VB
cord-276598-tm0yj2sn	452	14	N	N	NNP
cord-276598-tm0yj2sn	452	15	-	-	HYPH
cord-276598-tm0yj2sn	452	16	acylphosphoramidates	acylphosphoramidates	NNP
cord-276598-tm0yj2sn	452	17	(	(	-LRB-
cord-276598-tm0yj2sn	452	18	AcP	AcP	NNP
cord-276598-tm0yj2sn	452	19	-	-	HYPH
cord-276598-tm0yj2sn	452	20	N	N	NNP
cord-276598-tm0yj2sn	452	21	)	)	-RRB-
cord-276598-tm0yj2sn	452	22	from	from	IN
cord-276598-tm0yj2sn	452	23	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	452	24	and	and	CC
cord-276598-tm0yj2sn	452	25	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	452	26	azide	azide	NN
cord-276598-tm0yj2sn	452	27	through	through	IN
cord-276598-tm0yj2sn	452	28	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	452	29	insertion	insertion	NN
cord-276598-tm0yj2sn	452	30	(	(	-LRB-
cord-276598-tm0yj2sn	452	31	Scheme	scheme	NN
cord-276598-tm0yj2sn	452	32	10b	10b	CD
cord-276598-tm0yj2sn	452	33	)	)	-RRB-
cord-276598-tm0yj2sn	452	34	[	[	-LRB-
cord-276598-tm0yj2sn	452	35	113	113	CD
cord-276598-tm0yj2sn	452	36	]	]	-RRB-
cord-276598-tm0yj2sn	452	37	.	.	.
cord-276598-tm0yj2sn	453	1	The	the	DT
cord-276598-tm0yj2sn	453	2	product	product	NN
cord-276598-tm0yj2sn	453	3	was	be	VBD
cord-276598-tm0yj2sn	453	4	isolated	isolate	VBN
cord-276598-tm0yj2sn	453	5	by	by	IN
cord-276598-tm0yj2sn	453	6	column	column	NN
cord-276598-tm0yj2sn	453	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	453	8	(	(	-LRB-
cord-276598-tm0yj2sn	453	9	on	on	IN
cord-276598-tm0yj2sn	453	10	silica	silica	NN
cord-276598-tm0yj2sn	453	11	)	)	-RRB-
cord-276598-tm0yj2sn	453	12	.	.	.
cord-276598-tm0yj2sn	454	1	The	the	DT
cord-276598-tm0yj2sn	454	2	observed	observed	JJ
cord-276598-tm0yj2sn	454	3	product	product	NN
cord-276598-tm0yj2sn	454	4	conversions	conversion	NNS
cord-276598-tm0yj2sn	454	5	were	be	VBD
cord-276598-tm0yj2sn	454	6	in	in	IN
cord-276598-tm0yj2sn	454	7	the	the	DT
cord-276598-tm0yj2sn	454	8	range	range	NN
cord-276598-tm0yj2sn	454	9	56	56	CD
cord-276598-tm0yj2sn	454	10	-	-	SYM
cord-276598-tm0yj2sn	454	11	99	99	CD
cord-276598-tm0yj2sn	454	12	%	%	NN
cord-276598-tm0yj2sn	454	13	.	.	.
cord-276598-tm0yj2sn	455	1	Aromatic	aromatic	JJ
cord-276598-tm0yj2sn	455	2	and	and	CC
cord-276598-tm0yj2sn	455	3	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	455	4	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	455	5	such	such	JJ
cord-276598-tm0yj2sn	455	6	as	as	IN
cord-276598-tm0yj2sn	455	7	2-naphthaldehyde	2-naphthaldehyde	CD
cord-276598-tm0yj2sn	455	8	,	,	,
cord-276598-tm0yj2sn	455	9	benzo[d	benzo[d	NNP
cord-276598-tm0yj2sn	455	10	]	]	-RRB-
cord-276598-tm0yj2sn	456	1	[	[	-LRB-
cord-276598-tm0yj2sn	456	2	1	1	CD
cord-276598-tm0yj2sn	456	3	,	,	,
cord-276598-tm0yj2sn	456	4	3	3	CD
cord-276598-tm0yj2sn	456	5	]	]	-RRB-
cord-276598-tm0yj2sn	456	6	dioxole-5-carbaldehyde	dioxole-5-carbaldehyde	NNP
cord-276598-tm0yj2sn	456	7	,	,	,
cord-276598-tm0yj2sn	456	8	5,6-dihydro-2H	5,6-dihydro-2h	CD
cord-276598-tm0yj2sn	456	9	-	-	:
cord-276598-tm0yj2sn	456	10	pyran-3-carbaldehyde	pyran-3-carbaldehyde	NNP
cord-276598-tm0yj2sn	456	11	and	and	CC
cord-276598-tm0yj2sn	456	12	3-methylbut-2-enal	3-methylbut-2-enal	CD
cord-276598-tm0yj2sn	456	13	were	be	VBD
cord-276598-tm0yj2sn	456	14	used	use	VBN
cord-276598-tm0yj2sn	456	15	in	in	IN
cord-276598-tm0yj2sn	456	16	the	the	DT
cord-276598-tm0yj2sn	456	17	reaction	reaction	NN
cord-276598-tm0yj2sn	456	18	along	along	IN
cord-276598-tm0yj2sn	456	19	with	with	IN
cord-276598-tm0yj2sn	456	20	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	456	21	and	and	CC
cord-276598-tm0yj2sn	456	22	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	456	23	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	456	24	azide	azide	NN
cord-276598-tm0yj2sn	456	25	such	such	JJ
cord-276598-tm0yj2sn	456	26	as	as	IN
cord-276598-tm0yj2sn	456	27	3-nitrophenyl	3-nitrophenyl	CD
cord-276598-tm0yj2sn	457	1	(	(	-LRB-
cord-276598-tm0yj2sn	457	2	4-nitrophenyl	4-nitrophenyl	CD
cord-276598-tm0yj2sn	457	3	)	)	-RRB-
cord-276598-tm0yj2sn	457	4	phosphorazidate	phosphorazidate	NNP
cord-276598-tm0yj2sn	457	5	,	,	,
cord-276598-tm0yj2sn	457	6	bis(2,2,2-trichloroethyl	bis(2,2,2-trichloroethyl	NNP
cord-276598-tm0yj2sn	457	7	)	)	-RRB-
cord-276598-tm0yj2sn	457	8	phosphorazidate	phosphorazidate	NNP
cord-276598-tm0yj2sn	457	9	,	,	,
cord-276598-tm0yj2sn	457	10	and	and	CC
cord-276598-tm0yj2sn	457	11	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	457	12	phosphorazidate	phosphorazidate	NNP
cord-276598-tm0yj2sn	457	13	.	.	.
cord-276598-tm0yj2sn	458	1	However	however	RB
cord-276598-tm0yj2sn	458	2	,	,	,
cord-276598-tm0yj2sn	458	3	lower	low	JJR
cord-276598-tm0yj2sn	458	4	yields	yield	NNS
cord-276598-tm0yj2sn	458	5	were	be	VBD
cord-276598-tm0yj2sn	458	6	obtained	obtain	VBN
cord-276598-tm0yj2sn	458	7	from	from	IN
cord-276598-tm0yj2sn	458	8	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	458	9	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	458	10	when	when	WRB
cord-276598-tm0yj2sn	458	11	compared	compare	VBN
cord-276598-tm0yj2sn	458	12	with	with	IN
cord-276598-tm0yj2sn	458	13	the	the	DT
cord-276598-tm0yj2sn	458	14	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	458	15	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	458	16	,	,	,
cord-276598-tm0yj2sn	458	17	suggesting	suggest	VBG
cord-276598-tm0yj2sn	458	18	that	that	IN
cord-276598-tm0yj2sn	458	19	the	the	DT
cord-276598-tm0yj2sn	458	20	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	458	21	procedure	procedure	NN
cord-276598-tm0yj2sn	458	22	favors	favor	VBZ
cord-276598-tm0yj2sn	458	23	electron	electron	NN
cord-276598-tm0yj2sn	458	24	-	-	HYPH
cord-276598-tm0yj2sn	458	25	rich	rich	JJ
cord-276598-tm0yj2sn	458	26	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	458	27	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	458	28	.	.	.
cord-276598-tm0yj2sn	459	1	Che	Che	NNP
cord-276598-tm0yj2sn	459	2	and	and	CC
cord-276598-tm0yj2sn	459	3	coworkers	coworker	NNS
cord-276598-tm0yj2sn	459	4	later	later	RB
cord-276598-tm0yj2sn	459	5	introduced	introduce	VBD
cord-276598-tm0yj2sn	459	6	a	a	DT
cord-276598-tm0yj2sn	459	7	Ru	Ru	NNP
cord-276598-tm0yj2sn	459	8	IV	IV	NNP
cord-276598-tm0yj2sn	459	9	-porphyrin	-porphyrin	NN
cord-276598-tm0yj2sn	459	10	-	-	HYPH
cord-276598-tm0yj2sn	459	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	459	12	to	to	TO
cord-276598-tm0yj2sn	459	13	synthesize	synthesize	VB
cord-276598-tm0yj2sn	459	14	N	N	NNP
cord-276598-tm0yj2sn	459	15	-	-	HYPH
cord-276598-tm0yj2sn	459	16	acylphosphoramidates	acylphosphoramidates	NNP
cord-276598-tm0yj2sn	459	17	(	(	-LRB-
cord-276598-tm0yj2sn	459	18	AcP	AcP	NNP
cord-276598-tm0yj2sn	459	19	-	-	HYPH
cord-276598-tm0yj2sn	459	20	N	N	NNP
cord-276598-tm0yj2sn	459	21	)	)	-RRB-
cord-276598-tm0yj2sn	459	22	from	from	IN
cord-276598-tm0yj2sn	459	23	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	459	24	and	and	CC
cord-276598-tm0yj2sn	459	25	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	459	26	azide	azide	NN
cord-276598-tm0yj2sn	459	27	through	through	IN
cord-276598-tm0yj2sn	459	28	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	459	29	insertion	insertion	NN
cord-276598-tm0yj2sn	459	30	(	(	-LRB-
cord-276598-tm0yj2sn	459	31	Scheme	scheme	NN
cord-276598-tm0yj2sn	459	32	10b	10b	CD
cord-276598-tm0yj2sn	459	33	)	)	-RRB-
cord-276598-tm0yj2sn	459	34	[	[	-LRB-
cord-276598-tm0yj2sn	459	35	113	113	CD
cord-276598-tm0yj2sn	459	36	]	]	-RRB-
cord-276598-tm0yj2sn	459	37	.	.	.
cord-276598-tm0yj2sn	460	1	The	the	DT
cord-276598-tm0yj2sn	460	2	product	product	NN
cord-276598-tm0yj2sn	460	3	was	be	VBD
cord-276598-tm0yj2sn	460	4	isolated	isolate	VBN
cord-276598-tm0yj2sn	460	5	by	by	IN
cord-276598-tm0yj2sn	460	6	column	column	NN
cord-276598-tm0yj2sn	460	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	460	8	(	(	-LRB-
cord-276598-tm0yj2sn	460	9	on	on	IN
cord-276598-tm0yj2sn	460	10	silica	silica	NN
cord-276598-tm0yj2sn	460	11	)	)	-RRB-
cord-276598-tm0yj2sn	460	12	.	.	.
cord-276598-tm0yj2sn	461	1	The	the	DT
cord-276598-tm0yj2sn	461	2	observed	observed	JJ
cord-276598-tm0yj2sn	461	3	product	product	NN
cord-276598-tm0yj2sn	461	4	conversions	conversion	NNS
cord-276598-tm0yj2sn	461	5	were	be	VBD
cord-276598-tm0yj2sn	461	6	in	in	IN
cord-276598-tm0yj2sn	461	7	the	the	DT
cord-276598-tm0yj2sn	461	8	range	range	NN
cord-276598-tm0yj2sn	461	9	56	56	CD
cord-276598-tm0yj2sn	461	10	-	-	SYM
cord-276598-tm0yj2sn	461	11	99	99	CD
cord-276598-tm0yj2sn	461	12	%	%	NN
cord-276598-tm0yj2sn	461	13	.	.	.
cord-276598-tm0yj2sn	462	1	Aromatic	aromatic	JJ
cord-276598-tm0yj2sn	462	2	and	and	CC
cord-276598-tm0yj2sn	462	3	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	462	4	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	462	5	such	such	JJ
cord-276598-tm0yj2sn	462	6	as	as	IN
cord-276598-tm0yj2sn	462	7	2-naphthaldehyde	2-naphthaldehyde	CD
cord-276598-tm0yj2sn	462	8	,	,	,
cord-276598-tm0yj2sn	462	9	benzo[d	benzo[d	NNP
cord-276598-tm0yj2sn	462	10	]	]	-RRB-
cord-276598-tm0yj2sn	463	1	[	[	-LRB-
cord-276598-tm0yj2sn	463	2	1	1	CD
cord-276598-tm0yj2sn	463	3	,	,	,
cord-276598-tm0yj2sn	463	4	3	3	CD
cord-276598-tm0yj2sn	463	5	]	]	-RRB-
cord-276598-tm0yj2sn	463	6	dioxole-5-carbaldehyde	dioxole-5-carbaldehyde	NNP
cord-276598-tm0yj2sn	463	7	,	,	,
cord-276598-tm0yj2sn	463	8	5,6-dihydro-2H	5,6-dihydro-2h	CD
cord-276598-tm0yj2sn	463	9	-	-	:
cord-276598-tm0yj2sn	463	10	pyran-3-carbaldehyde	pyran-3-carbaldehyde	NNP
cord-276598-tm0yj2sn	463	11	and	and	CC
cord-276598-tm0yj2sn	463	12	3-methylbut-2-enal	3-methylbut-2-enal	CD
cord-276598-tm0yj2sn	463	13	were	be	VBD
cord-276598-tm0yj2sn	463	14	used	use	VBN
cord-276598-tm0yj2sn	463	15	in	in	IN
cord-276598-tm0yj2sn	463	16	the	the	DT
cord-276598-tm0yj2sn	463	17	reaction	reaction	NN
cord-276598-tm0yj2sn	463	18	along	along	IN
cord-276598-tm0yj2sn	463	19	with	with	IN
cord-276598-tm0yj2sn	463	20	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	463	21	and	and	CC
cord-276598-tm0yj2sn	463	22	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	463	23	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	463	24	azide	azide	NN
cord-276598-tm0yj2sn	463	25	such	such	JJ
cord-276598-tm0yj2sn	463	26	as	as	IN
cord-276598-tm0yj2sn	463	27	3-nitrophenyl	3-nitrophenyl	CD
cord-276598-tm0yj2sn	464	1	(	(	-LRB-
cord-276598-tm0yj2sn	464	2	4-nitrophenyl	4-nitrophenyl	CD
cord-276598-tm0yj2sn	464	3	)	)	-RRB-
cord-276598-tm0yj2sn	464	4	phosphorazidate	phosphorazidate	NNP
cord-276598-tm0yj2sn	464	5	,	,	,
cord-276598-tm0yj2sn	464	6	bis(2,2,2-trichloroethyl	bis(2,2,2-trichloroethyl	NNP
cord-276598-tm0yj2sn	464	7	)	)	-RRB-
cord-276598-tm0yj2sn	464	8	phosphorazidate	phosphorazidate	NNP
cord-276598-tm0yj2sn	464	9	,	,	,
cord-276598-tm0yj2sn	464	10	and	and	CC
cord-276598-tm0yj2sn	464	11	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	464	12	phosphorazidate	phosphorazidate	NNP
cord-276598-tm0yj2sn	464	13	.	.	.
cord-276598-tm0yj2sn	465	1	However	however	RB
cord-276598-tm0yj2sn	465	2	,	,	,
cord-276598-tm0yj2sn	465	3	lower	low	JJR
cord-276598-tm0yj2sn	465	4	yields	yield	NNS
cord-276598-tm0yj2sn	465	5	were	be	VBD
cord-276598-tm0yj2sn	465	6	obtained	obtain	VBN
cord-276598-tm0yj2sn	465	7	from	from	IN
cord-276598-tm0yj2sn	465	8	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	465	9	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	465	10	when	when	WRB
cord-276598-tm0yj2sn	465	11	compared	compare	VBN
cord-276598-tm0yj2sn	465	12	with	with	IN
cord-276598-tm0yj2sn	465	13	the	the	DT
cord-276598-tm0yj2sn	465	14	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	465	15	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	465	16	,	,	,
cord-276598-tm0yj2sn	465	17	suggesting	suggest	VBG
cord-276598-tm0yj2sn	465	18	that	that	IN
cord-276598-tm0yj2sn	465	19	the	the	DT
cord-276598-tm0yj2sn	465	20	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	465	21	procedure	procedure	NN
cord-276598-tm0yj2sn	465	22	favors	favor	VBZ
cord-276598-tm0yj2sn	465	23	electron	electron	NN
cord-276598-tm0yj2sn	465	24	-	-	HYPH
cord-276598-tm0yj2sn	465	25	rich	rich	JJ
cord-276598-tm0yj2sn	465	26	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	465	27	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	465	28	.	.	.
cord-276598-tm0yj2sn	466	1	A	a	DT
cord-276598-tm0yj2sn	466	2	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	466	3	insertion	insertion	NN
cord-276598-tm0yj2sn	466	4	route	route	NN
cord-276598-tm0yj2sn	466	5	in	in	IN
cord-276598-tm0yj2sn	466	6	the	the	DT
cord-276598-tm0yj2sn	466	7	presence	presence	NN
cord-276598-tm0yj2sn	466	8	of	of	IN
cord-276598-tm0yj2sn	466	9	Ir(III)-based	Ir(III)-based	NNP
cord-276598-tm0yj2sn	466	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	466	11	was	be	VBD
cord-276598-tm0yj2sn	466	12	also	also	RB
cord-276598-tm0yj2sn	466	13	used	use	VBN
cord-276598-tm0yj2sn	466	14	to	to	TO
cord-276598-tm0yj2sn	466	15	synthesize	synthesize	VB
cord-276598-tm0yj2sn	466	16	P	p	NN
cord-276598-tm0yj2sn	466	17	-	-	HYPH
cord-276598-tm0yj2sn	466	18	Ns	Ns	NNP
cord-276598-tm0yj2sn	466	19	by	by	IN
cord-276598-tm0yj2sn	466	20	Zhu	Zhu	NNP
cord-276598-tm0yj2sn	466	21	et	et	FW
cord-276598-tm0yj2sn	466	22	al	al	NNP
cord-276598-tm0yj2sn	466	23	.	.	.
cord-276598-tm0yj2sn	467	1	(	(	-LRB-
cord-276598-tm0yj2sn	467	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	467	3	10c	10c	CD
cord-276598-tm0yj2sn	467	4	)	)	-RRB-
cord-276598-tm0yj2sn	468	1	[	[	-LRB-
cord-276598-tm0yj2sn	468	2	114	114	CD
cord-276598-tm0yj2sn	468	3	]	]	-RRB-
cord-276598-tm0yj2sn	468	4	.	.	.
cord-276598-tm0yj2sn	469	1	The	the	DT
cord-276598-tm0yj2sn	469	2	P	P	NNP
cord-276598-tm0yj2sn	469	3	-	-	HYPH
cord-276598-tm0yj2sn	469	4	Ns	Ns	NNP
cord-276598-tm0yj2sn	469	5	were	be	VBD
cord-276598-tm0yj2sn	469	6	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	469	7	under	under	IN
cord-276598-tm0yj2sn	469	8	an	an	DT
cord-276598-tm0yj2sn	469	9	inert	inert	JJ
cord-276598-tm0yj2sn	469	10	environment	environment	NN
cord-276598-tm0yj2sn	469	11	and	and	CC
cord-276598-tm0yj2sn	469	12	the	the	DT
cord-276598-tm0yj2sn	469	13	isolated	isolated	JJ
cord-276598-tm0yj2sn	469	14	yield	yield	NN
cord-276598-tm0yj2sn	469	15	of	of	IN
cord-276598-tm0yj2sn	469	16	the	the	DT
cord-276598-tm0yj2sn	469	17	products	product	NNS
cord-276598-tm0yj2sn	469	18	was	be	VBD
cord-276598-tm0yj2sn	469	19	in	in	IN
cord-276598-tm0yj2sn	469	20	the	the	DT
cord-276598-tm0yj2sn	469	21	range	range	NN
cord-276598-tm0yj2sn	469	22	of	of	IN
cord-276598-tm0yj2sn	469	23	52	52	CD
cord-276598-tm0yj2sn	469	24	-	-	SYM
cord-276598-tm0yj2sn	469	25	77	77	CD
cord-276598-tm0yj2sn	469	26	%	%	NN
cord-276598-tm0yj2sn	469	27	.	.	.
cord-276598-tm0yj2sn	470	1	The	the	DT
cord-276598-tm0yj2sn	470	2	scope	scope	NN
cord-276598-tm0yj2sn	470	3	of	of	IN
cord-276598-tm0yj2sn	470	4	the	the	DT
cord-276598-tm0yj2sn	470	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	470	6	was	be	VBD
cord-276598-tm0yj2sn	470	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	470	8	using	use	VBG
cord-276598-tm0yj2sn	470	9	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	470	10	phosphorazidate	phosphorazidate	NN
cord-276598-tm0yj2sn	470	11	and	and	CC
cord-276598-tm0yj2sn	470	12	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	470	13	phosphorazidate	phosphorazidate	VB
cord-276598-tm0yj2sn	470	14	along	along	IN
cord-276598-tm0yj2sn	470	15	with	with	IN
cord-276598-tm0yj2sn	470	16	2-phenylpyridine	2-phenylpyridine	CD
cord-276598-tm0yj2sn	470	17	or	or	CC
cord-276598-tm0yj2sn	470	18	pyrazole	pyrazole	NN
cord-276598-tm0yj2sn	470	19	derivatives	derivative	NNS
cord-276598-tm0yj2sn	470	20	with	with	IN
cord-276598-tm0yj2sn	470	21	substituents	substituent	NNS
cord-276598-tm0yj2sn	470	22	such	such	JJ
cord-276598-tm0yj2sn	470	23	as	as	IN
cord-276598-tm0yj2sn	470	24	Me	-PRON-	PRP
cord-276598-tm0yj2sn	470	25	,	,	,
cord-276598-tm0yj2sn	470	26	OMe	OMe	NNS
cord-276598-tm0yj2sn	470	27	,	,	,
cord-276598-tm0yj2sn	470	28	CF	CF	NNP
cord-276598-tm0yj2sn	470	29	3	3	CD
cord-276598-tm0yj2sn	470	30	,	,	,
cord-276598-tm0yj2sn	470	31	Cl	Cl	NNP
cord-276598-tm0yj2sn	470	32	,	,	,
cord-276598-tm0yj2sn	470	33	F	F	NNP
cord-276598-tm0yj2sn	470	34	,	,	,
cord-276598-tm0yj2sn	470	35	Ph	Ph	NNP
cord-276598-tm0yj2sn	470	36	,	,	,
cord-276598-tm0yj2sn	470	37	and	and	CC
cord-276598-tm0yj2sn	470	38	COOMe	COOMe	NNPS
cord-276598-tm0yj2sn	470	39	at	at	IN
cord-276598-tm0yj2sn	470	40	ortho-	ortho-	NN
cord-276598-tm0yj2sn	470	41	,	,	,
cord-276598-tm0yj2sn	470	42	meta-	meta-	NN
cord-276598-tm0yj2sn	470	43	,	,	,
cord-276598-tm0yj2sn	470	44	and	and	CC
cord-276598-tm0yj2sn	470	45	para	para	NN
cord-276598-tm0yj2sn	470	46	-	-	HYPH
cord-276598-tm0yj2sn	470	47	positions	position	NNS
cord-276598-tm0yj2sn	470	48	as	as	RB
cord-276598-tm0yj2sn	470	49	well	well	RB
cord-276598-tm0yj2sn	470	50	as	as	IN
cord-276598-tm0yj2sn	470	51	benzo[h]quinoline	benzo[h]quinoline	NNP
cord-276598-tm0yj2sn	470	52	.	.	.
cord-276598-tm0yj2sn	471	1	Although	although	IN
cord-276598-tm0yj2sn	471	2	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	471	3	insertion	insertion	NN
cord-276598-tm0yj2sn	471	4	provides	provide	VBZ
cord-276598-tm0yj2sn	471	5	a	a	DT
cord-276598-tm0yj2sn	471	6	viable	viable	JJ
cord-276598-tm0yj2sn	471	7	route	route	NN
cord-276598-tm0yj2sn	471	8	to	to	IN
cord-276598-tm0yj2sn	471	9	P	p	NN
cord-276598-tm0yj2sn	471	10	-	-	HYPH
cord-276598-tm0yj2sn	471	11	N	n	CD
cord-276598-tm0yj2sn	471	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	471	13	and	and	CC
cord-276598-tm0yj2sn	471	14	generates	generate	VBZ
cord-276598-tm0yj2sn	471	15	N	n	CD
cord-276598-tm0yj2sn	471	16	2	2	CD
cord-276598-tm0yj2sn	471	17	gas	gas	NN
cord-276598-tm0yj2sn	471	18	as	as	IN
cord-276598-tm0yj2sn	471	19	the	the	DT
cord-276598-tm0yj2sn	471	20	only	only	JJ
cord-276598-tm0yj2sn	471	21	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	471	22	by	by	IN
cord-276598-tm0yj2sn	471	23	-	-	HYPH
cord-276598-tm0yj2sn	471	24	product	product	NN
cord-276598-tm0yj2sn	471	25	,	,	,
cord-276598-tm0yj2sn	471	26	the	the	DT
cord-276598-tm0yj2sn	471	27	process	process	NN
cord-276598-tm0yj2sn	471	28	uses	use	VBZ
cord-276598-tm0yj2sn	471	29	expensive	expensive	JJ
cord-276598-tm0yj2sn	471	30	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	471	31	in	in	IN
cord-276598-tm0yj2sn	471	32	addition	addition	NN
cord-276598-tm0yj2sn	471	33	to	to	IN
cord-276598-tm0yj2sn	471	34	many	many	JJ
cord-276598-tm0yj2sn	471	35	chemical	chemical	JJ
cord-276598-tm0yj2sn	471	36	additives	additive	NNS
cord-276598-tm0yj2sn	471	37	.	.	.
cord-276598-tm0yj2sn	472	1	Moreover	moreover	RB
cord-276598-tm0yj2sn	472	2	,	,	,
cord-276598-tm0yj2sn	472	3	apart	apart	RB
cord-276598-tm0yj2sn	472	4	from	from	IN
cord-276598-tm0yj2sn	472	5	the	the	DT
cord-276598-tm0yj2sn	472	6	hazards	hazard	NNS
cord-276598-tm0yj2sn	472	7	associated	associate	VBN
cord-276598-tm0yj2sn	472	8	with	with	IN
cord-276598-tm0yj2sn	472	9	the	the	DT
cord-276598-tm0yj2sn	472	10	handling	handling	NN
cord-276598-tm0yj2sn	472	11	of	of	IN
cord-276598-tm0yj2sn	472	12	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	472	13	azide	azide	NN
cord-276598-tm0yj2sn	472	14	,	,	,
cord-276598-tm0yj2sn	472	15	the	the	DT
cord-276598-tm0yj2sn	472	16	route	route	NN
cord-276598-tm0yj2sn	472	17	requires	require	VBZ
cord-276598-tm0yj2sn	472	18	a	a	DT
cord-276598-tm0yj2sn	472	19	long	long	JJ
cord-276598-tm0yj2sn	472	20	reaction	reaction	NN
cord-276598-tm0yj2sn	472	21	time	time	NN
cord-276598-tm0yj2sn	472	22	,	,	,
cord-276598-tm0yj2sn	472	23	high	high	JJ
cord-276598-tm0yj2sn	472	24	temperature	temperature	NN
cord-276598-tm0yj2sn	472	25	,	,	,
cord-276598-tm0yj2sn	472	26	and	and	CC
cord-276598-tm0yj2sn	472	27	does	do	VBZ
cord-276598-tm0yj2sn	472	28	not	not	RB
cord-276598-tm0yj2sn	472	29	favor	favor	VB
cord-276598-tm0yj2sn	472	30	electron	electron	NN
cord-276598-tm0yj2sn	472	31	-	-	HYPH
cord-276598-tm0yj2sn	472	32	deficient	deficient	JJ
cord-276598-tm0yj2sn	472	33	starting	starting	NN
cord-276598-tm0yj2sn	472	34	materials	material	NNS
cord-276598-tm0yj2sn	472	35	.	.	.
cord-276598-tm0yj2sn	473	1	An	an	DT
cord-276598-tm0yj2sn	473	2	organic	organic	JJ
cord-276598-tm0yj2sn	473	3	azide	azide	NN
cord-276598-tm0yj2sn	473	4	was	be	VBD
cord-276598-tm0yj2sn	473	5	generated	generate	VBN
cord-276598-tm0yj2sn	473	6	in	in	IN
cord-276598-tm0yj2sn	473	7	situ	situ	NN
cord-276598-tm0yj2sn	473	8	from	from	IN
cord-276598-tm0yj2sn	473	9	organic	organic	JJ
cord-276598-tm0yj2sn	473	10	halides	halide	NNS
cord-276598-tm0yj2sn	473	11	and	and	CC
cord-276598-tm0yj2sn	473	12	was	be	VBD
cord-276598-tm0yj2sn	473	13	coupled	couple	VBN
cord-276598-tm0yj2sn	473	14	with	with	IN
cord-276598-tm0yj2sn	473	15	(	(	-LRB-
cord-276598-tm0yj2sn	473	16	RO	ro	NN
cord-276598-tm0yj2sn	473	17	)	)	-RRB-
cord-276598-tm0yj2sn	473	18	3	3	CD
cord-276598-tm0yj2sn	473	19	P	p	NN
cord-276598-tm0yj2sn	473	20	(	(	-LRB-
cord-276598-tm0yj2sn	473	21	R	r	NN
cord-276598-tm0yj2sn	473	22	=	=	NN
cord-276598-tm0yj2sn	473	23	alkyl	alkyl	NN
cord-276598-tm0yj2sn	473	24	)	)	-RRB-
cord-276598-tm0yj2sn	473	25	for	for	IN
cord-276598-tm0yj2sn	473	26	the	the	DT
cord-276598-tm0yj2sn	473	27	synthesis	synthesis	NN
cord-276598-tm0yj2sn	473	28	of	of	IN
cord-276598-tm0yj2sn	473	29	P	P	NNP
cord-276598-tm0yj2sn	473	30	-	-	HYPH
cord-276598-tm0yj2sn	473	31	N	N	NNP
cord-276598-tm0yj2sn	473	32	by	by	IN
cord-276598-tm0yj2sn	473	33	Sangwan	Sangwan	NNP
cord-276598-tm0yj2sn	473	34	et	et	NNP
cord-276598-tm0yj2sn	473	35	al	al	NNP
cord-276598-tm0yj2sn	473	36	.	.	.
cord-276598-tm0yj2sn	474	1	(	(	-LRB-
cord-276598-tm0yj2sn	474	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	474	3	11	11	CD
cord-276598-tm0yj2sn	474	4	)	)	-RRB-
cord-276598-tm0yj2sn	475	1	The	the	DT
cord-276598-tm0yj2sn	475	2	crude	crude	JJ
cord-276598-tm0yj2sn	475	3	product	product	NN
cord-276598-tm0yj2sn	475	4	was	be	VBD
cord-276598-tm0yj2sn	475	5	purified	purify	VBN
cord-276598-tm0yj2sn	475	6	by	by	IN
cord-276598-tm0yj2sn	475	7	column	column	NN
cord-276598-tm0yj2sn	475	8	chromatography	chromatography	NN
cord-276598-tm0yj2sn	475	9	(	(	-LRB-
cord-276598-tm0yj2sn	475	10	on	on	IN
cord-276598-tm0yj2sn	475	11	silica	silica	NN
cord-276598-tm0yj2sn	475	12	)	)	-RRB-
cord-276598-tm0yj2sn	475	13	to	to	TO
cord-276598-tm0yj2sn	475	14	afford	afford	VB
cord-276598-tm0yj2sn	475	15	isolated	isolated	JJ
cord-276598-tm0yj2sn	475	16	products	product	NNS
cord-276598-tm0yj2sn	475	17	in	in	IN
cord-276598-tm0yj2sn	475	18	the	the	DT
cord-276598-tm0yj2sn	475	19	range	range	NN
cord-276598-tm0yj2sn	475	20	of	of	IN
cord-276598-tm0yj2sn	475	21	52	52	CD
cord-276598-tm0yj2sn	475	22	-	-	SYM
cord-276598-tm0yj2sn	475	23	96	96	CD
cord-276598-tm0yj2sn	475	24	%	%	NN
cord-276598-tm0yj2sn	475	25	yield	yield	NN
cord-276598-tm0yj2sn	475	26	.	.	.
cord-276598-tm0yj2sn	476	1	A	a	DT
cord-276598-tm0yj2sn	476	2	broad	broad	JJ
cord-276598-tm0yj2sn	476	3	scope	scope	NN
cord-276598-tm0yj2sn	476	4	of	of	IN
cord-276598-tm0yj2sn	476	5	the	the	DT
cord-276598-tm0yj2sn	476	6	reaction	reaction	NN
cord-276598-tm0yj2sn	476	7	was	be	VBD
cord-276598-tm0yj2sn	476	8	tested	test	VBN
cord-276598-tm0yj2sn	476	9	;	;	:
cord-276598-tm0yj2sn	476	10	3-bromoprop-1-yne	3-bromoprop-1-yne	NN
cord-276598-tm0yj2sn	476	11	,	,	,
cord-276598-tm0yj2sn	476	12	3-bromoprop-1-ene	3-bromoprop-1-ene	CD
cord-276598-tm0yj2sn	476	13	,	,	,
cord-276598-tm0yj2sn	476	14	1-bromopropane	1-bromopropane	CD
cord-276598-tm0yj2sn	476	15	alkyl	alkyl	NN
cord-276598-tm0yj2sn	476	16	or	or	CC
cord-276598-tm0yj2sn	476	17	(	(	-LRB-
cord-276598-tm0yj2sn	476	18	un)substituted	un)substitute	VBN
cord-276598-tm0yj2sn	476	19	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	476	20	halide	halide	NN
cord-276598-tm0yj2sn	476	21	such	such	JJ
cord-276598-tm0yj2sn	476	22	as	as	IN
cord-276598-tm0yj2sn	476	23	(	(	-LRB-
cord-276598-tm0yj2sn	476	24	bromomethyl)benzene	bromomethyl)benzene	NNP
cord-276598-tm0yj2sn	476	25	,	,	,
cord-276598-tm0yj2sn	476	26	1-(bromomethyl)-2-nitrobenzene	1-(bromomethyl)-2-nitrobenzene	CD
cord-276598-tm0yj2sn	476	27	,	,	,
cord-276598-tm0yj2sn	476	28	1-(chloromethyl)-4-nitrobenzene	1-(chloromethyl)-4-nitrobenzene	CD
cord-276598-tm0yj2sn	476	29	,	,	,
cord-276598-tm0yj2sn	476	30	(	(	-LRB-
cord-276598-tm0yj2sn	476	31	chloromethyl)benzene	chloromethyl)benzene	NNP
cord-276598-tm0yj2sn	476	32	,	,	,
cord-276598-tm0yj2sn	476	33	1-(bromomethyl)-3,5-dimethoxybenzene	1-(bromomethyl)-3,5-dimethoxybenzene	CD
cord-276598-tm0yj2sn	476	34	,	,	,
cord-276598-tm0yj2sn	476	35	or	or	CC
cord-276598-tm0yj2sn	476	36	3-(4-(bromomethyl)-1H-1,2,3-triazol-1-yl)benzyl	3-(4-(bromomethyl)-1h-1,2,3-triazol-1-yl)benzyl	CD
cord-276598-tm0yj2sn	476	37	acetate	acetate	NN
cord-276598-tm0yj2sn	476	38	were	be	VBD
cord-276598-tm0yj2sn	476	39	reacted	react	VBN
cord-276598-tm0yj2sn	476	40	with	with	IN
cord-276598-tm0yj2sn	476	41	dimethyl	dimethyl	NN
cord-276598-tm0yj2sn	476	42	or	or	CC
cord-276598-tm0yj2sn	476	43	diethyl	diethyl	NN
cord-276598-tm0yj2sn	476	44	H	H	NNP
cord-276598-tm0yj2sn	476	45	-	-	HYPH
cord-276598-tm0yj2sn	476	46	P.	P.	NNP
cord-276598-tm0yj2sn	476	47	1-(chloromethyl)-4-nitrobenzene	1-(chloromethyl)-4-nitrobenzene	CD
cord-276598-tm0yj2sn	476	48	,	,	,
cord-276598-tm0yj2sn	476	49	(	(	-LRB-
cord-276598-tm0yj2sn	476	50	chloromethyl)benzene	chloromethyl)benzene	NNP
cord-276598-tm0yj2sn	476	51	,	,	,
cord-276598-tm0yj2sn	476	52	1-(bromomethyl)-3,5-dimethoxybenzene	1-(bromomethyl)-3,5-dimethoxybenzene	CD
cord-276598-tm0yj2sn	476	53	,	,	,
cord-276598-tm0yj2sn	476	54	or	or	CC
cord-276598-tm0yj2sn	476	55	3-(4-(bromomethyl)-1H-1,2,3-triazol-1-yl)benzyl	3-(4-(bromomethyl)-1h-1,2,3-triazol-1-yl)benzyl	CD
cord-276598-tm0yj2sn	476	56	acetate	acetate	NN
cord-276598-tm0yj2sn	476	57	were	be	VBD
cord-276598-tm0yj2sn	476	58	reacted	react	VBN
cord-276598-tm0yj2sn	476	59	with	with	IN
cord-276598-tm0yj2sn	476	60	dimethyl	dimethyl	NN
cord-276598-tm0yj2sn	476	61	or	or	CC
cord-276598-tm0yj2sn	476	62	diethyl	diethyl	NN
cord-276598-tm0yj2sn	476	63	H	h	NN
cord-276598-tm0yj2sn	477	1	-P.	-P.	:
cord-276598-tm0yj2sn	477	2	A	a	DT
cord-276598-tm0yj2sn	477	3	similar	similar	JJ
cord-276598-tm0yj2sn	477	4	method	method	NN
cord-276598-tm0yj2sn	477	5	of	of	IN
cord-276598-tm0yj2sn	477	6	P	p	NN
cord-276598-tm0yj2sn	477	7	-	-	HYPH
cord-276598-tm0yj2sn	477	8	N	n	CD
cord-276598-tm0yj2sn	477	9	synthesis	synthesis	NN
cord-276598-tm0yj2sn	477	10	via	via	IN
cord-276598-tm0yj2sn	477	11	in	in	IN
cord-276598-tm0yj2sn	477	12	situ	situ	NN
cord-276598-tm0yj2sn	477	13	azide	azide	NN
cord-276598-tm0yj2sn	477	14	generation	generation	NN
cord-276598-tm0yj2sn	477	15	from	from	IN
cord-276598-tm0yj2sn	477	16	organic	organic	JJ
cord-276598-tm0yj2sn	477	17	halides	halide	NNS
cord-276598-tm0yj2sn	477	18	was	be	VBD
cord-276598-tm0yj2sn	477	19	reported	report	VBN
cord-276598-tm0yj2sn	477	20	by	by	IN
cord-276598-tm0yj2sn	477	21	Dar	Dar	NNP
cord-276598-tm0yj2sn	477	22	[	[	-LRB-
cord-276598-tm0yj2sn	477	23	115	115	CD
cord-276598-tm0yj2sn	477	24	]	]	-RRB-
cord-276598-tm0yj2sn	477	25	,	,	,
cord-276598-tm0yj2sn	477	26	following	follow	VBG
cord-276598-tm0yj2sn	477	27	the	the	DT
cord-276598-tm0yj2sn	477	28	procedure	procedure	NN
cord-276598-tm0yj2sn	477	29	previously	previously	RB
cord-276598-tm0yj2sn	477	30	reported	report	VBN
cord-276598-tm0yj2sn	477	31	by	by	IN
cord-276598-tm0yj2sn	477	32	Sangwan	Sangwan	NNP
cord-276598-tm0yj2sn	477	33	et	et	NNP
cord-276598-tm0yj2sn	477	34	al	al	NNP
cord-276598-tm0yj2sn	477	35	.	.	.
cord-276598-tm0yj2sn	478	1	(	(	-LRB-
cord-276598-tm0yj2sn	478	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	478	3	11	11	CD
cord-276598-tm0yj2sn	478	4	)	)	-RRB-
cord-276598-tm0yj2sn	478	5	[	[	-LRB-
cord-276598-tm0yj2sn	478	6	116	116	CD
cord-276598-tm0yj2sn	478	7	]	]	-RRB-
cord-276598-tm0yj2sn	478	8	.	.	.
cord-276598-tm0yj2sn	479	1	The	the	DT
cord-276598-tm0yj2sn	479	2	yield	yield	NN
cord-276598-tm0yj2sn	479	3	range	range	NN
cord-276598-tm0yj2sn	479	4	of	of	IN
cord-276598-tm0yj2sn	479	5	the	the	DT
cord-276598-tm0yj2sn	479	6	isolated	isolate	VBN
cord-276598-tm0yj2sn	479	7	P	p	NN
cord-276598-tm0yj2sn	479	8	-	-	HYPH
cord-276598-tm0yj2sn	479	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	479	10	,	,	,
cord-276598-tm0yj2sn	479	11	in	in	IN
cord-276598-tm0yj2sn	479	12	this	this	DT
cord-276598-tm0yj2sn	479	13	case	case	NN
cord-276598-tm0yj2sn	479	14	,	,	,
cord-276598-tm0yj2sn	479	15	was	be	VBD
cord-276598-tm0yj2sn	479	16	60	60	CD
cord-276598-tm0yj2sn	479	17	-	-	SYM
cord-276598-tm0yj2sn	479	18	96	96	CD
cord-276598-tm0yj2sn	479	19	%	%	NN
cord-276598-tm0yj2sn	479	20	.	.	.
cord-276598-tm0yj2sn	480	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	480	2	-	-	HYPH
cord-276598-tm0yj2sn	480	3	derived	derive	VBN
cord-276598-tm0yj2sn	480	4	bioactive	bioactive	JJ
cord-276598-tm0yj2sn	480	5	compound	compound	NN
cord-276598-tm0yj2sn	480	6	(	(	-LRB-
cord-276598-tm0yj2sn	480	7	19	19	CD
cord-276598-tm0yj2sn	480	8	)	)	-RRB-
cord-276598-tm0yj2sn	480	9	was	be	VBD
cord-276598-tm0yj2sn	480	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	480	11	using	use	VBG
cord-276598-tm0yj2sn	480	12	the	the	DT
cord-276598-tm0yj2sn	480	13	proposed	propose	VBN
cord-276598-tm0yj2sn	480	14	method	method	NN
cord-276598-tm0yj2sn	480	15	(	(	-LRB-
cord-276598-tm0yj2sn	480	16	Figure	figure	NN
cord-276598-tm0yj2sn	480	17	9	9	CD
cord-276598-tm0yj2sn	480	18	)	)	-RRB-
cord-276598-tm0yj2sn	480	19	.	.	.
cord-276598-tm0yj2sn	481	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	481	2	11	11	CD
cord-276598-tm0yj2sn	481	3	.	.	.
cord-276598-tm0yj2sn	482	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	482	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	482	3	from	from	IN
cord-276598-tm0yj2sn	482	4	organic	organic	JJ
cord-276598-tm0yj2sn	482	5	azide	azide	NN
cord-276598-tm0yj2sn	482	6	and	and	CC
cord-276598-tm0yj2sn	482	7	(	(	-LRB-
cord-276598-tm0yj2sn	482	8	RO)3P.	ro)3p.	IN
cord-276598-tm0yj2sn	482	9	Figure	figure	NN
cord-276598-tm0yj2sn	482	10	9	9	CD
cord-276598-tm0yj2sn	482	11	.	.	.
cord-276598-tm0yj2sn	483	1	Structure	structure	NN
cord-276598-tm0yj2sn	483	2	of	of	IN
cord-276598-tm0yj2sn	483	3	(	(	-LRB-
cord-276598-tm0yj2sn	483	4	1R,2S,5R)-2-isopropyl-5-methylcyclohexyl	1r,2s,5r)-2-isopropyl-5-methylcyclohexyl	CD
cord-276598-tm0yj2sn	483	5	(	(	-LRB-
cord-276598-tm0yj2sn	483	6	dimethoxyphosphoryl)glycinate	dimethoxyphosphoryl)glycinate	NNP
cord-276598-tm0yj2sn	483	7	(	(	-LRB-
cord-276598-tm0yj2sn	483	8	19	19	CD
cord-276598-tm0yj2sn	483	9	)	)	-RRB-
cord-276598-tm0yj2sn	483	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	483	11	via	via	IN
cord-276598-tm0yj2sn	483	12	in	in	IN
cord-276598-tm0yj2sn	483	13	situ	situ	NN
cord-276598-tm0yj2sn	483	14	azide	azide	NN
cord-276598-tm0yj2sn	483	15	generation	generation	NN
cord-276598-tm0yj2sn	483	16	.	.	.
cord-276598-tm0yj2sn	484	1	In	in	IN
cord-276598-tm0yj2sn	484	2	1988	1988	CD
cord-276598-tm0yj2sn	484	3	,	,	,
cord-276598-tm0yj2sn	484	4	Koziara	Koziara	NNP
cord-276598-tm0yj2sn	484	5	reported	report	VBD
cord-276598-tm0yj2sn	484	6	a	a	DT
cord-276598-tm0yj2sn	484	7	two	two	CD
cord-276598-tm0yj2sn	484	8	-	-	HYPH
cord-276598-tm0yj2sn	484	9	step	step	NN
cord-276598-tm0yj2sn	484	10	P	p	NN
cord-276598-tm0yj2sn	484	11	-	-	HYPH
cord-276598-tm0yj2sn	484	12	N	n	CD
cord-276598-tm0yj2sn	484	13	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	484	14	route	route	NN
cord-276598-tm0yj2sn	484	15	via	via	IN
cord-276598-tm0yj2sn	484	16	organic	organic	JJ
cord-276598-tm0yj2sn	484	17	azide	azide	NN
cord-276598-tm0yj2sn	484	18	generation	generation	NN
cord-276598-tm0yj2sn	484	19	using	use	VBG
cord-276598-tm0yj2sn	484	20	a	a	DT
cord-276598-tm0yj2sn	484	21	[	[	-LRB-
cord-276598-tm0yj2sn	484	22	n	n	NNP
cord-276598-tm0yj2sn	484	23	-	-	HYPH
cord-276598-tm0yj2sn	484	24	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	484	25	catalyst	catalyst	NN
cord-276598-tm0yj2sn	484	26	(	(	-LRB-
cord-276598-tm0yj2sn	484	27	Scheme	scheme	NN
cord-276598-tm0yj2sn	484	28	12	12	CD
cord-276598-tm0yj2sn	484	29	)	)	-RRB-
cord-276598-tm0yj2sn	484	30	[	[	-LRB-
cord-276598-tm0yj2sn	484	31	93	93	CD
cord-276598-tm0yj2sn	484	32	]	]	-RRB-
cord-276598-tm0yj2sn	484	33	.	.	.
cord-276598-tm0yj2sn	485	1	The	the	DT
cord-276598-tm0yj2sn	485	2	crude	crude	JJ
cord-276598-tm0yj2sn	485	3	product	product	NN
cord-276598-tm0yj2sn	485	4	was	be	VBD
cord-276598-tm0yj2sn	485	5	purified	purify	VBN
cord-276598-tm0yj2sn	485	6	by	by	IN
cord-276598-tm0yj2sn	485	7	crystallization	crystallization	NN
cord-276598-tm0yj2sn	485	8	or	or	CC
cord-276598-tm0yj2sn	485	9	vacuum	vacuum	NN
cord-276598-tm0yj2sn	485	10	distillation	distillation	NN
cord-276598-tm0yj2sn	485	11	with	with	IN
cord-276598-tm0yj2sn	485	12	50	50	CD
cord-276598-tm0yj2sn	485	13	-	-	SYM
cord-276598-tm0yj2sn	485	14	93	93	CD
cord-276598-tm0yj2sn	485	15	%	%	NN
cord-276598-tm0yj2sn	485	16	isolated	isolated	JJ
cord-276598-tm0yj2sn	485	17	yield	yield	NN
cord-276598-tm0yj2sn	485	18	.	.	.
cord-276598-tm0yj2sn	486	1	The	the	DT
cord-276598-tm0yj2sn	486	2	organic	organic	JJ
cord-276598-tm0yj2sn	486	3	halides	halide	NNS
cord-276598-tm0yj2sn	486	4	used	use	VBN
cord-276598-tm0yj2sn	486	5	were	be	VBD
cord-276598-tm0yj2sn	486	6	(	(	-LRB-
cord-276598-tm0yj2sn	486	7	3-bromopropyl)benzene	3-bromopropyl)benzene	CD
cord-276598-tm0yj2sn	486	8	,	,	,
cord-276598-tm0yj2sn	486	9	(	(	-LRB-
cord-276598-tm0yj2sn	486	10	2-bromoethyl)benzene	2-bromoethyl)benzene	CD
cord-276598-tm0yj2sn	486	11	,	,	,
cord-276598-tm0yj2sn	486	12	1-bromohexane	1-bromohexane	CD
cord-276598-tm0yj2sn	486	13	,	,	,
cord-276598-tm0yj2sn	486	14	bromocyclohexane	bromocyclohexane	NNP
cord-276598-tm0yj2sn	486	15	,	,	,
cord-276598-tm0yj2sn	486	16	1-bromobutane	1-bromobutane	CD
cord-276598-tm0yj2sn	486	17	,	,	,
cord-276598-tm0yj2sn	486	18	or	or	CC
cord-276598-tm0yj2sn	486	19	bromocyclopentane	bromocyclopentane	NNP
cord-276598-tm0yj2sn	486	20	.	.	.
cord-276598-tm0yj2sn	487	1	Routes	route	NNS
cord-276598-tm0yj2sn	487	2	via	via	IN
cord-276598-tm0yj2sn	487	3	organic	organic	JJ
cord-276598-tm0yj2sn	487	4	azide	azide	NN
cord-276598-tm0yj2sn	487	5	generation	generation	NN
cord-276598-tm0yj2sn	487	6	use	use	NN
cord-276598-tm0yj2sn	487	7	readily	readily	RB
cord-276598-tm0yj2sn	487	8	available	available	JJ
cord-276598-tm0yj2sn	487	9	,	,	,
cord-276598-tm0yj2sn	487	10	less	less	RBR
cord-276598-tm0yj2sn	487	11	toxic	toxic	JJ
cord-276598-tm0yj2sn	487	12	organic	organic	JJ
cord-276598-tm0yj2sn	487	13	halides	halide	NNS
cord-276598-tm0yj2sn	488	1	and	and	CC
cord-276598-tm0yj2sn	488	2	(	(	-LRB-
cord-276598-tm0yj2sn	488	3	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	488	4	(	(	-LRB-
cord-276598-tm0yj2sn	488	5	R	r	NN
cord-276598-tm0yj2sn	488	6	=	=	NN
cord-276598-tm0yj2sn	488	7	alkyl	alkyl	NN
cord-276598-tm0yj2sn	488	8	)	)	-RRB-
cord-276598-tm0yj2sn	488	9	relative	relative	JJ
cord-276598-tm0yj2sn	488	10	to	to	IN
cord-276598-tm0yj2sn	488	11	other	other	JJ
cord-276598-tm0yj2sn	488	12	routes	route	NNS
cord-276598-tm0yj2sn	488	13	and	and	CC
cord-276598-tm0yj2sn	488	14	generate	generate	VB
cord-276598-tm0yj2sn	488	15	N2	n2	NN
cord-276598-tm0yj2sn	488	16	as	as	IN
cord-276598-tm0yj2sn	488	17	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	488	18	waste	waste	NN
cord-276598-tm0yj2sn	488	19	.	.	.
cord-276598-tm0yj2sn	489	1	However	however	RB
cord-276598-tm0yj2sn	489	2	,	,	,
cord-276598-tm0yj2sn	489	3	the	the	DT
cord-276598-tm0yj2sn	489	4	method	method	NN
cord-276598-tm0yj2sn	489	5	Scheme	scheme	NN
cord-276598-tm0yj2sn	489	6	11	11	CD
cord-276598-tm0yj2sn	489	7	.	.	.
cord-276598-tm0yj2sn	490	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	490	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	490	3	from	from	IN
cord-276598-tm0yj2sn	490	4	organic	organic	JJ
cord-276598-tm0yj2sn	490	5	azide	azide	NN
cord-276598-tm0yj2sn	490	6	and	and	CC
cord-276598-tm0yj2sn	490	7	(	(	-LRB-
cord-276598-tm0yj2sn	490	8	RO	ro	NN
cord-276598-tm0yj2sn	490	9	)	)	-RRB-
cord-276598-tm0yj2sn	491	1	3	3	CD
cord-276598-tm0yj2sn	491	2	P.	P.	NNP
cord-276598-tm0yj2sn	491	3	A	a	DT
cord-276598-tm0yj2sn	491	4	similar	similar	JJ
cord-276598-tm0yj2sn	491	5	method	method	NN
cord-276598-tm0yj2sn	491	6	of	of	IN
cord-276598-tm0yj2sn	491	7	P	p	NN
cord-276598-tm0yj2sn	491	8	-	-	HYPH
cord-276598-tm0yj2sn	491	9	N	n	CD
cord-276598-tm0yj2sn	491	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	491	11	via	via	IN
cord-276598-tm0yj2sn	491	12	in	in	IN
cord-276598-tm0yj2sn	491	13	situ	situ	NN
cord-276598-tm0yj2sn	491	14	azide	azide	NN
cord-276598-tm0yj2sn	491	15	generation	generation	NN
cord-276598-tm0yj2sn	491	16	from	from	IN
cord-276598-tm0yj2sn	491	17	organic	organic	JJ
cord-276598-tm0yj2sn	491	18	halides	halide	NNS
cord-276598-tm0yj2sn	491	19	was	be	VBD
cord-276598-tm0yj2sn	491	20	reported	report	VBN
cord-276598-tm0yj2sn	491	21	by	by	IN
cord-276598-tm0yj2sn	491	22	Dar	Dar	NNP
cord-276598-tm0yj2sn	491	23	[	[	-LRB-
cord-276598-tm0yj2sn	491	24	115	115	CD
cord-276598-tm0yj2sn	491	25	]	]	-RRB-
cord-276598-tm0yj2sn	491	26	,	,	,
cord-276598-tm0yj2sn	491	27	following	follow	VBG
cord-276598-tm0yj2sn	491	28	the	the	DT
cord-276598-tm0yj2sn	491	29	procedure	procedure	NN
cord-276598-tm0yj2sn	491	30	previously	previously	RB
cord-276598-tm0yj2sn	491	31	reported	report	VBN
cord-276598-tm0yj2sn	491	32	by	by	IN
cord-276598-tm0yj2sn	491	33	Sangwan	Sangwan	NNP
cord-276598-tm0yj2sn	491	34	et	et	NNP
cord-276598-tm0yj2sn	491	35	al	al	NNP
cord-276598-tm0yj2sn	491	36	.	.	.
cord-276598-tm0yj2sn	492	1	(	(	-LRB-
cord-276598-tm0yj2sn	492	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	492	3	11	11	CD
cord-276598-tm0yj2sn	492	4	)	)	-RRB-
cord-276598-tm0yj2sn	492	5	[	[	-LRB-
cord-276598-tm0yj2sn	492	6	116	116	CD
cord-276598-tm0yj2sn	492	7	]	]	-RRB-
cord-276598-tm0yj2sn	492	8	.	.	.
cord-276598-tm0yj2sn	493	1	The	the	DT
cord-276598-tm0yj2sn	493	2	yield	yield	NN
cord-276598-tm0yj2sn	493	3	range	range	NN
cord-276598-tm0yj2sn	493	4	of	of	IN
cord-276598-tm0yj2sn	493	5	the	the	DT
cord-276598-tm0yj2sn	493	6	isolated	isolate	VBN
cord-276598-tm0yj2sn	493	7	P	p	NN
cord-276598-tm0yj2sn	493	8	-	-	HYPH
cord-276598-tm0yj2sn	493	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	493	10	,	,	,
cord-276598-tm0yj2sn	493	11	in	in	IN
cord-276598-tm0yj2sn	493	12	this	this	DT
cord-276598-tm0yj2sn	493	13	case	case	NN
cord-276598-tm0yj2sn	493	14	,	,	,
cord-276598-tm0yj2sn	493	15	was	be	VBD
cord-276598-tm0yj2sn	493	16	60	60	CD
cord-276598-tm0yj2sn	493	17	-	-	SYM
cord-276598-tm0yj2sn	493	18	96	96	CD
cord-276598-tm0yj2sn	493	19	%	%	NN
cord-276598-tm0yj2sn	493	20	.	.	.
cord-276598-tm0yj2sn	494	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	494	2	-	-	HYPH
cord-276598-tm0yj2sn	494	3	derived	derive	VBN
cord-276598-tm0yj2sn	494	4	bioactive	bioactive	JJ
cord-276598-tm0yj2sn	494	5	compound	compound	NN
cord-276598-tm0yj2sn	494	6	(	(	-LRB-
cord-276598-tm0yj2sn	494	7	19	19	CD
cord-276598-tm0yj2sn	494	8	)	)	-RRB-
cord-276598-tm0yj2sn	494	9	was	be	VBD
cord-276598-tm0yj2sn	494	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	494	11	using	use	VBG
cord-276598-tm0yj2sn	494	12	the	the	DT
cord-276598-tm0yj2sn	494	13	proposed	propose	VBN
cord-276598-tm0yj2sn	494	14	method	method	NN
cord-276598-tm0yj2sn	494	15	(	(	-LRB-
cord-276598-tm0yj2sn	494	16	Figure	figure	NN
cord-276598-tm0yj2sn	494	17	9	9	CD
cord-276598-tm0yj2sn	494	18	)	)	-RRB-
cord-276598-tm0yj2sn	494	19	.	.	.
cord-276598-tm0yj2sn	495	1	column	column	NN
cord-276598-tm0yj2sn	495	2	chromatography	chromatography	NN
cord-276598-tm0yj2sn	495	3	(	(	-LRB-
cord-276598-tm0yj2sn	495	4	on	on	IN
cord-276598-tm0yj2sn	495	5	silica	silica	NN
cord-276598-tm0yj2sn	495	6	)	)	-RRB-
cord-276598-tm0yj2sn	495	7	to	to	TO
cord-276598-tm0yj2sn	495	8	afford	afford	VB
cord-276598-tm0yj2sn	495	9	isolated	isolated	JJ
cord-276598-tm0yj2sn	495	10	products	product	NNS
cord-276598-tm0yj2sn	495	11	in	in	IN
cord-276598-tm0yj2sn	495	12	the	the	DT
cord-276598-tm0yj2sn	495	13	range	range	NN
cord-276598-tm0yj2sn	495	14	of	of	IN
cord-276598-tm0yj2sn	495	15	52	52	CD
cord-276598-tm0yj2sn	495	16	-	-	SYM
cord-276598-tm0yj2sn	495	17	96	96	CD
cord-276598-tm0yj2sn	495	18	%	%	NN
cord-276598-tm0yj2sn	495	19	yield	yield	NN
cord-276598-tm0yj2sn	495	20	.	.	.
cord-276598-tm0yj2sn	496	1	A	a	DT
cord-276598-tm0yj2sn	496	2	broad	broad	JJ
cord-276598-tm0yj2sn	496	3	scope	scope	NN
cord-276598-tm0yj2sn	496	4	of	of	IN
cord-276598-tm0yj2sn	496	5	the	the	DT
cord-276598-tm0yj2sn	496	6	reaction	reaction	NN
cord-276598-tm0yj2sn	496	7	was	be	VBD
cord-276598-tm0yj2sn	496	8	tested	test	VBN
cord-276598-tm0yj2sn	496	9	;	;	:
cord-276598-tm0yj2sn	496	10	3-bromoprop-1-yne	3-bromoprop-1-yne	NN
cord-276598-tm0yj2sn	496	11	,	,	,
cord-276598-tm0yj2sn	496	12	3-bromoprop-1-ene	3-bromoprop-1-ene	CD
cord-276598-tm0yj2sn	496	13	,	,	,
cord-276598-tm0yj2sn	496	14	1-bromopropane	1-bromopropane	CD
cord-276598-tm0yj2sn	496	15	alkyl	alkyl	NN
cord-276598-tm0yj2sn	496	16	or	or	CC
cord-276598-tm0yj2sn	496	17	(	(	-LRB-
cord-276598-tm0yj2sn	496	18	un)substituted	un)substitute	VBN
cord-276598-tm0yj2sn	496	19	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	496	20	halide	halide	NN
cord-276598-tm0yj2sn	496	21	such	such	JJ
cord-276598-tm0yj2sn	496	22	as	as	IN
cord-276598-tm0yj2sn	496	23	(	(	-LRB-
cord-276598-tm0yj2sn	496	24	bromomethyl)benzene	bromomethyl)benzene	NNP
cord-276598-tm0yj2sn	496	25	,	,	,
cord-276598-tm0yj2sn	496	26	1-(bromomethyl)-2-nitrobenzene	1-(bromomethyl)-2-nitrobenzene	CD
cord-276598-tm0yj2sn	496	27	,	,	,
cord-276598-tm0yj2sn	496	28	1-(chloromethyl)-4-nitrobenzene	1-(chloromethyl)-4-nitrobenzene	CD
cord-276598-tm0yj2sn	496	29	,	,	,
cord-276598-tm0yj2sn	496	30	(	(	-LRB-
cord-276598-tm0yj2sn	496	31	chloromethyl)benzene	chloromethyl)benzene	NNP
cord-276598-tm0yj2sn	496	32	,	,	,
cord-276598-tm0yj2sn	496	33	1-(bromomethyl)-3,5-dimethoxybenzene	1-(bromomethyl)-3,5-dimethoxybenzene	CD
cord-276598-tm0yj2sn	496	34	,	,	,
cord-276598-tm0yj2sn	496	35	or	or	CC
cord-276598-tm0yj2sn	496	36	3-(4-(bromomethyl)-1H-1,2,3-triazol-1-yl)benzyl	3-(4-(bromomethyl)-1h-1,2,3-triazol-1-yl)benzyl	CD
cord-276598-tm0yj2sn	496	37	acetate	acetate	NN
cord-276598-tm0yj2sn	496	38	were	be	VBD
cord-276598-tm0yj2sn	496	39	reacted	react	VBN
cord-276598-tm0yj2sn	496	40	with	with	IN
cord-276598-tm0yj2sn	496	41	dimethyl	dimethyl	NN
cord-276598-tm0yj2sn	496	42	or	or	CC
cord-276598-tm0yj2sn	496	43	diethyl	diethyl	NN
cord-276598-tm0yj2sn	496	44	H	h	NN
cord-276598-tm0yj2sn	497	1	-P.	-P.	:
cord-276598-tm0yj2sn	497	2	A	a	DT
cord-276598-tm0yj2sn	497	3	similar	similar	JJ
cord-276598-tm0yj2sn	497	4	method	method	NN
cord-276598-tm0yj2sn	497	5	of	of	IN
cord-276598-tm0yj2sn	497	6	P	p	NN
cord-276598-tm0yj2sn	497	7	-	-	HYPH
cord-276598-tm0yj2sn	497	8	N	n	CD
cord-276598-tm0yj2sn	497	9	synthesis	synthesis	NN
cord-276598-tm0yj2sn	497	10	via	via	IN
cord-276598-tm0yj2sn	497	11	in	in	IN
cord-276598-tm0yj2sn	497	12	situ	situ	NN
cord-276598-tm0yj2sn	497	13	azide	azide	NN
cord-276598-tm0yj2sn	497	14	generation	generation	NN
cord-276598-tm0yj2sn	497	15	from	from	IN
cord-276598-tm0yj2sn	497	16	organic	organic	JJ
cord-276598-tm0yj2sn	497	17	halides	halide	NNS
cord-276598-tm0yj2sn	497	18	was	be	VBD
cord-276598-tm0yj2sn	497	19	reported	report	VBN
cord-276598-tm0yj2sn	497	20	by	by	IN
cord-276598-tm0yj2sn	497	21	Dar	Dar	NNP
cord-276598-tm0yj2sn	497	22	[	[	-LRB-
cord-276598-tm0yj2sn	497	23	115	115	CD
cord-276598-tm0yj2sn	497	24	]	]	-RRB-
cord-276598-tm0yj2sn	497	25	,	,	,
cord-276598-tm0yj2sn	497	26	following	follow	VBG
cord-276598-tm0yj2sn	497	27	the	the	DT
cord-276598-tm0yj2sn	497	28	procedure	procedure	NN
cord-276598-tm0yj2sn	497	29	previously	previously	RB
cord-276598-tm0yj2sn	497	30	reported	report	VBN
cord-276598-tm0yj2sn	497	31	by	by	IN
cord-276598-tm0yj2sn	497	32	Sangwan	Sangwan	NNP
cord-276598-tm0yj2sn	497	33	et	et	NNP
cord-276598-tm0yj2sn	497	34	al	al	NNP
cord-276598-tm0yj2sn	497	35	.	.	.
cord-276598-tm0yj2sn	498	1	(	(	-LRB-
cord-276598-tm0yj2sn	498	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	498	3	11	11	CD
cord-276598-tm0yj2sn	498	4	)	)	-RRB-
cord-276598-tm0yj2sn	498	5	[	[	-LRB-
cord-276598-tm0yj2sn	498	6	116	116	CD
cord-276598-tm0yj2sn	498	7	]	]	-RRB-
cord-276598-tm0yj2sn	498	8	.	.	.
cord-276598-tm0yj2sn	499	1	The	the	DT
cord-276598-tm0yj2sn	499	2	yield	yield	NN
cord-276598-tm0yj2sn	499	3	range	range	NN
cord-276598-tm0yj2sn	499	4	of	of	IN
cord-276598-tm0yj2sn	499	5	the	the	DT
cord-276598-tm0yj2sn	499	6	isolated	isolate	VBN
cord-276598-tm0yj2sn	499	7	P	p	NN
cord-276598-tm0yj2sn	499	8	-	-	HYPH
cord-276598-tm0yj2sn	499	9	Ns	Ns	NNP
cord-276598-tm0yj2sn	499	10	,	,	,
cord-276598-tm0yj2sn	499	11	in	in	IN
cord-276598-tm0yj2sn	499	12	this	this	DT
cord-276598-tm0yj2sn	499	13	case	case	NN
cord-276598-tm0yj2sn	499	14	,	,	,
cord-276598-tm0yj2sn	499	15	was	be	VBD
cord-276598-tm0yj2sn	499	16	60	60	CD
cord-276598-tm0yj2sn	499	17	-	-	SYM
cord-276598-tm0yj2sn	499	18	96	96	CD
cord-276598-tm0yj2sn	499	19	%	%	NN
cord-276598-tm0yj2sn	499	20	.	.	.
cord-276598-tm0yj2sn	500	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	500	2	-	-	HYPH
cord-276598-tm0yj2sn	500	3	derived	derive	VBN
cord-276598-tm0yj2sn	500	4	bioactive	bioactive	JJ
cord-276598-tm0yj2sn	500	5	compound	compound	NN
cord-276598-tm0yj2sn	500	6	(	(	-LRB-
cord-276598-tm0yj2sn	500	7	19	19	CD
cord-276598-tm0yj2sn	500	8	)	)	-RRB-
cord-276598-tm0yj2sn	500	9	was	be	VBD
cord-276598-tm0yj2sn	500	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	500	11	using	use	VBG
cord-276598-tm0yj2sn	500	12	the	the	DT
cord-276598-tm0yj2sn	500	13	proposed	propose	VBN
cord-276598-tm0yj2sn	500	14	method	method	NN
cord-276598-tm0yj2sn	500	15	(	(	-LRB-
cord-276598-tm0yj2sn	500	16	Figure	figure	NN
cord-276598-tm0yj2sn	500	17	9	9	CD
cord-276598-tm0yj2sn	500	18	)	)	-RRB-
cord-276598-tm0yj2sn	500	19	.	.	.
cord-276598-tm0yj2sn	501	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	501	2	11	11	CD
cord-276598-tm0yj2sn	501	3	.	.	.
cord-276598-tm0yj2sn	502	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	502	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	502	3	from	from	IN
cord-276598-tm0yj2sn	502	4	organic	organic	JJ
cord-276598-tm0yj2sn	502	5	azide	azide	NN
cord-276598-tm0yj2sn	502	6	and	and	CC
cord-276598-tm0yj2sn	502	7	(	(	-LRB-
cord-276598-tm0yj2sn	502	8	RO)3P.	ro)3p.	IN
cord-276598-tm0yj2sn	502	9	Figure	figure	NN
cord-276598-tm0yj2sn	502	10	9	9	CD
cord-276598-tm0yj2sn	502	11	.	.	.
cord-276598-tm0yj2sn	503	1	Structure	structure	NN
cord-276598-tm0yj2sn	503	2	of	of	IN
cord-276598-tm0yj2sn	503	3	(	(	-LRB-
cord-276598-tm0yj2sn	503	4	1R,2S,5R)-2-isopropyl-5-methylcyclohexyl	1r,2s,5r)-2-isopropyl-5-methylcyclohexyl	CD
cord-276598-tm0yj2sn	503	5	(	(	-LRB-
cord-276598-tm0yj2sn	503	6	dimethoxyphosphoryl)glycinate	dimethoxyphosphoryl)glycinate	NNP
cord-276598-tm0yj2sn	503	7	(	(	-LRB-
cord-276598-tm0yj2sn	503	8	19	19	CD
cord-276598-tm0yj2sn	503	9	)	)	-RRB-
cord-276598-tm0yj2sn	503	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	503	11	via	via	IN
cord-276598-tm0yj2sn	503	12	in	in	IN
cord-276598-tm0yj2sn	503	13	situ	situ	NN
cord-276598-tm0yj2sn	503	14	azide	azide	NN
cord-276598-tm0yj2sn	503	15	generation	generation	NN
cord-276598-tm0yj2sn	503	16	.	.	.
cord-276598-tm0yj2sn	504	1	In	in	IN
cord-276598-tm0yj2sn	504	2	1988	1988	CD
cord-276598-tm0yj2sn	504	3	,	,	,
cord-276598-tm0yj2sn	504	4	Koziara	Koziara	NNP
cord-276598-tm0yj2sn	504	5	reported	report	VBD
cord-276598-tm0yj2sn	504	6	a	a	DT
cord-276598-tm0yj2sn	504	7	two	two	CD
cord-276598-tm0yj2sn	504	8	-	-	HYPH
cord-276598-tm0yj2sn	504	9	step	step	NN
cord-276598-tm0yj2sn	504	10	P	p	NN
cord-276598-tm0yj2sn	504	11	-	-	HYPH
cord-276598-tm0yj2sn	504	12	N	n	CD
cord-276598-tm0yj2sn	504	13	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	504	14	route	route	NN
cord-276598-tm0yj2sn	504	15	via	via	IN
cord-276598-tm0yj2sn	504	16	organic	organic	JJ
cord-276598-tm0yj2sn	504	17	azide	azide	NN
cord-276598-tm0yj2sn	504	18	generation	generation	NN
cord-276598-tm0yj2sn	504	19	using	use	VBG
cord-276598-tm0yj2sn	504	20	a	a	DT
cord-276598-tm0yj2sn	504	21	[	[	-LRB-
cord-276598-tm0yj2sn	504	22	n	n	NNP
cord-276598-tm0yj2sn	504	23	-	-	HYPH
cord-276598-tm0yj2sn	504	24	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	504	25	catalyst	catalyst	NN
cord-276598-tm0yj2sn	504	26	(	(	-LRB-
cord-276598-tm0yj2sn	504	27	Scheme	scheme	NN
cord-276598-tm0yj2sn	504	28	12	12	CD
cord-276598-tm0yj2sn	504	29	)	)	-RRB-
cord-276598-tm0yj2sn	504	30	[	[	-LRB-
cord-276598-tm0yj2sn	504	31	93	93	CD
cord-276598-tm0yj2sn	504	32	]	]	-RRB-
cord-276598-tm0yj2sn	504	33	.	.	.
cord-276598-tm0yj2sn	505	1	The	the	DT
cord-276598-tm0yj2sn	505	2	crude	crude	JJ
cord-276598-tm0yj2sn	505	3	product	product	NN
cord-276598-tm0yj2sn	505	4	was	be	VBD
cord-276598-tm0yj2sn	505	5	purified	purify	VBN
cord-276598-tm0yj2sn	505	6	by	by	IN
cord-276598-tm0yj2sn	505	7	crystallization	crystallization	NN
cord-276598-tm0yj2sn	505	8	or	or	CC
cord-276598-tm0yj2sn	505	9	vacuum	vacuum	NN
cord-276598-tm0yj2sn	505	10	distillation	distillation	NN
cord-276598-tm0yj2sn	505	11	with	with	IN
cord-276598-tm0yj2sn	505	12	50	50	CD
cord-276598-tm0yj2sn	505	13	-	-	SYM
cord-276598-tm0yj2sn	505	14	93	93	CD
cord-276598-tm0yj2sn	505	15	%	%	NN
cord-276598-tm0yj2sn	505	16	isolated	isolated	JJ
cord-276598-tm0yj2sn	505	17	yield	yield	NN
cord-276598-tm0yj2sn	505	18	.	.	.
cord-276598-tm0yj2sn	506	1	The	the	DT
cord-276598-tm0yj2sn	506	2	organic	organic	JJ
cord-276598-tm0yj2sn	506	3	halides	halide	NNS
cord-276598-tm0yj2sn	506	4	used	use	VBN
cord-276598-tm0yj2sn	506	5	were	be	VBD
cord-276598-tm0yj2sn	506	6	(	(	-LRB-
cord-276598-tm0yj2sn	506	7	3-bromopropyl)benzene	3-bromopropyl)benzene	CD
cord-276598-tm0yj2sn	506	8	,	,	,
cord-276598-tm0yj2sn	506	9	(	(	-LRB-
cord-276598-tm0yj2sn	506	10	2-bromoethyl)benzene	2-bromoethyl)benzene	CD
cord-276598-tm0yj2sn	506	11	,	,	,
cord-276598-tm0yj2sn	506	12	1-bromohexane	1-bromohexane	CD
cord-276598-tm0yj2sn	506	13	,	,	,
cord-276598-tm0yj2sn	506	14	bromocyclohexane	bromocyclohexane	NNP
cord-276598-tm0yj2sn	506	15	,	,	,
cord-276598-tm0yj2sn	506	16	1-bromobutane	1-bromobutane	CD
cord-276598-tm0yj2sn	506	17	,	,	,
cord-276598-tm0yj2sn	506	18	or	or	CC
cord-276598-tm0yj2sn	506	19	bromocyclopentane	bromocyclopentane	NNP
cord-276598-tm0yj2sn	506	20	.	.	.
cord-276598-tm0yj2sn	507	1	Routes	route	NNS
cord-276598-tm0yj2sn	507	2	via	via	IN
cord-276598-tm0yj2sn	507	3	organic	organic	JJ
cord-276598-tm0yj2sn	507	4	azide	azide	NN
cord-276598-tm0yj2sn	507	5	generation	generation	NN
cord-276598-tm0yj2sn	507	6	use	use	NN
cord-276598-tm0yj2sn	507	7	readily	readily	RB
cord-276598-tm0yj2sn	507	8	available	available	JJ
cord-276598-tm0yj2sn	507	9	,	,	,
cord-276598-tm0yj2sn	507	10	less	less	RBR
cord-276598-tm0yj2sn	507	11	toxic	toxic	JJ
cord-276598-tm0yj2sn	507	12	organic	organic	JJ
cord-276598-tm0yj2sn	507	13	halides	halide	NNS
cord-276598-tm0yj2sn	508	1	and	and	CC
cord-276598-tm0yj2sn	508	2	(	(	-LRB-
cord-276598-tm0yj2sn	508	3	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	508	4	(	(	-LRB-
cord-276598-tm0yj2sn	508	5	R	r	NN
cord-276598-tm0yj2sn	508	6	=	=	NN
cord-276598-tm0yj2sn	508	7	alkyl	alkyl	NN
cord-276598-tm0yj2sn	508	8	)	)	-RRB-
cord-276598-tm0yj2sn	508	9	relative	relative	JJ
cord-276598-tm0yj2sn	508	10	to	to	IN
cord-276598-tm0yj2sn	508	11	other	other	JJ
cord-276598-tm0yj2sn	508	12	routes	route	NNS
cord-276598-tm0yj2sn	508	13	and	and	CC
cord-276598-tm0yj2sn	508	14	generate	generate	VB
cord-276598-tm0yj2sn	508	15	N2	n2	NN
cord-276598-tm0yj2sn	508	16	as	as	IN
cord-276598-tm0yj2sn	508	17	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	508	18	waste	waste	NN
cord-276598-tm0yj2sn	508	19	.	.	.
cord-276598-tm0yj2sn	509	1	However	however	RB
cord-276598-tm0yj2sn	509	2	,	,	,
cord-276598-tm0yj2sn	509	3	the	the	DT
cord-276598-tm0yj2sn	509	4	method	method	NN
cord-276598-tm0yj2sn	509	5	Figure	figure	NN
cord-276598-tm0yj2sn	509	6	9	9	CD
cord-276598-tm0yj2sn	509	7	.	.	.
cord-276598-tm0yj2sn	510	1	Structure	structure	NN
cord-276598-tm0yj2sn	510	2	of	of	IN
cord-276598-tm0yj2sn	510	3	(	(	-LRB-
cord-276598-tm0yj2sn	510	4	1R,2S,5R)-2-isopropyl-5-methylcyclohexyl	1r,2s,5r)-2-isopropyl-5-methylcyclohexyl	CD
cord-276598-tm0yj2sn	510	5	(	(	-LRB-
cord-276598-tm0yj2sn	510	6	dimethoxyphosphoryl)glycinate	dimethoxyphosphoryl)glycinate	NNP
cord-276598-tm0yj2sn	510	7	(	(	-LRB-
cord-276598-tm0yj2sn	510	8	19	19	CD
cord-276598-tm0yj2sn	510	9	)	)	-RRB-
cord-276598-tm0yj2sn	510	10	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	510	11	via	via	IN
cord-276598-tm0yj2sn	510	12	in	in	IN
cord-276598-tm0yj2sn	510	13	situ	situ	NN
cord-276598-tm0yj2sn	510	14	azide	azide	NN
cord-276598-tm0yj2sn	510	15	generation	generation	NN
cord-276598-tm0yj2sn	510	16	.	.	.
cord-276598-tm0yj2sn	511	1	In	in	IN
cord-276598-tm0yj2sn	511	2	1988	1988	CD
cord-276598-tm0yj2sn	511	3	,	,	,
cord-276598-tm0yj2sn	511	4	Koziara	Koziara	NNP
cord-276598-tm0yj2sn	511	5	reported	report	VBD
cord-276598-tm0yj2sn	511	6	a	a	DT
cord-276598-tm0yj2sn	511	7	two	two	CD
cord-276598-tm0yj2sn	511	8	-	-	HYPH
cord-276598-tm0yj2sn	511	9	step	step	NN
cord-276598-tm0yj2sn	511	10	P	p	NN
cord-276598-tm0yj2sn	511	11	-	-	HYPH
cord-276598-tm0yj2sn	511	12	N	n	CD
cord-276598-tm0yj2sn	511	13	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	511	14	route	route	NN
cord-276598-tm0yj2sn	511	15	via	via	IN
cord-276598-tm0yj2sn	511	16	organic	organic	JJ
cord-276598-tm0yj2sn	511	17	azide	azide	NN
cord-276598-tm0yj2sn	511	18	generation	generation	NN
cord-276598-tm0yj2sn	511	19	using	use	VBG
cord-276598-tm0yj2sn	511	20	a	a	DT
cord-276598-tm0yj2sn	511	21	[	[	-LRB-
cord-276598-tm0yj2sn	511	22	n	n	NNP
cord-276598-tm0yj2sn	511	23	-	-	HYPH
cord-276598-tm0yj2sn	511	24	Bu	Bu	NNP
cord-276598-tm0yj2sn	511	25	4	4	CD
cord-276598-tm0yj2sn	511	26	N]Br	N]Br	NNP
cord-276598-tm0yj2sn	511	27	catalyst	catalyst	NN
cord-276598-tm0yj2sn	511	28	(	(	-LRB-
cord-276598-tm0yj2sn	511	29	Scheme	scheme	NN
cord-276598-tm0yj2sn	511	30	12	12	CD
cord-276598-tm0yj2sn	511	31	)	)	-RRB-
cord-276598-tm0yj2sn	512	1	[	[	-LRB-
cord-276598-tm0yj2sn	512	2	93	93	CD
cord-276598-tm0yj2sn	512	3	]	]	-RRB-
cord-276598-tm0yj2sn	512	4	.	.	.
cord-276598-tm0yj2sn	513	1	The	the	DT
cord-276598-tm0yj2sn	513	2	crude	crude	JJ
cord-276598-tm0yj2sn	513	3	product	product	NN
cord-276598-tm0yj2sn	513	4	was	be	VBD
cord-276598-tm0yj2sn	513	5	purified	purify	VBN
cord-276598-tm0yj2sn	513	6	by	by	IN
cord-276598-tm0yj2sn	513	7	crystallization	crystallization	NN
cord-276598-tm0yj2sn	513	8	or	or	CC
cord-276598-tm0yj2sn	513	9	vacuum	vacuum	NN
cord-276598-tm0yj2sn	513	10	distillation	distillation	NN
cord-276598-tm0yj2sn	513	11	with	with	IN
cord-276598-tm0yj2sn	513	12	50	50	CD
cord-276598-tm0yj2sn	513	13	-	-	SYM
cord-276598-tm0yj2sn	513	14	93	93	CD
cord-276598-tm0yj2sn	513	15	%	%	NN
cord-276598-tm0yj2sn	513	16	isolated	isolated	JJ
cord-276598-tm0yj2sn	513	17	yield	yield	NN
cord-276598-tm0yj2sn	513	18	.	.	.
cord-276598-tm0yj2sn	514	1	The	the	DT
cord-276598-tm0yj2sn	514	2	organic	organic	JJ
cord-276598-tm0yj2sn	514	3	halides	halide	NNS
cord-276598-tm0yj2sn	514	4	used	use	VBN
cord-276598-tm0yj2sn	514	5	were	be	VBD
cord-276598-tm0yj2sn	514	6	(	(	-LRB-
cord-276598-tm0yj2sn	514	7	3-bromopropyl)benzene	3-bromopropyl)benzene	CD
cord-276598-tm0yj2sn	514	8	,	,	,
cord-276598-tm0yj2sn	514	9	(	(	-LRB-
cord-276598-tm0yj2sn	514	10	2-bromoethyl)benzene	2-bromoethyl)benzene	CD
cord-276598-tm0yj2sn	514	11	,	,	,
cord-276598-tm0yj2sn	514	12	1-bromohexane	1-bromohexane	CD
cord-276598-tm0yj2sn	514	13	,	,	,
cord-276598-tm0yj2sn	514	14	bromocyclohexane	bromocyclohexane	NNP
cord-276598-tm0yj2sn	514	15	,	,	,
cord-276598-tm0yj2sn	514	16	1-bromobutane	1-bromobutane	CD
cord-276598-tm0yj2sn	514	17	,	,	,
cord-276598-tm0yj2sn	514	18	or	or	CC
cord-276598-tm0yj2sn	514	19	bromocyclopentane	bromocyclopentane	NNP
cord-276598-tm0yj2sn	514	20	.	.	.
cord-276598-tm0yj2sn	515	1	relies	rely	VBZ
cord-276598-tm0yj2sn	515	2	on	on	IN
cord-276598-tm0yj2sn	515	3	the	the	DT
cord-276598-tm0yj2sn	515	4	pre	pre	JJ
cord-276598-tm0yj2sn	515	5	-	-	NN
cord-276598-tm0yj2sn	515	6	functionalization	functionalization	NN
cord-276598-tm0yj2sn	515	7	and	and	CC
cord-276598-tm0yj2sn	515	8	preparation	preparation	NN
cord-276598-tm0yj2sn	515	9	of	of	IN
cord-276598-tm0yj2sn	515	10	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	515	11	azide	azide	NN
cord-276598-tm0yj2sn	515	12	precursors	precursor	NNS
cord-276598-tm0yj2sn	515	13	in	in	IN
cord-276598-tm0yj2sn	515	14	multi	multi	JJ
cord-276598-tm0yj2sn	515	15	-	-	JJ
cord-276598-tm0yj2sn	515	16	step	step	JJ
cord-276598-tm0yj2sn	515	17	processes	process	NNS
cord-276598-tm0yj2sn	515	18	.	.	.
cord-276598-tm0yj2sn	516	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	516	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	516	3	via	via	IN
cord-276598-tm0yj2sn	516	4	two	two	CD
cord-276598-tm0yj2sn	516	5	-	-	HYPH
cord-276598-tm0yj2sn	516	6	step	step	NN
cord-276598-tm0yj2sn	516	7	organic	organic	JJ
cord-276598-tm0yj2sn	516	8	azide	azide	NN
cord-276598-tm0yj2sn	516	9	generation	generation	NN
cord-276598-tm0yj2sn	516	10	.	.	.
cord-276598-tm0yj2sn	517	1	Transition	transition	NN
cord-276598-tm0yj2sn	517	2	metal	metal	NN
cord-276598-tm0yj2sn	517	3	-	-	HYPH
cord-276598-tm0yj2sn	517	4	free	free	JJ
cord-276598-tm0yj2sn	517	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	517	6	of	of	IN
cord-276598-tm0yj2sn	517	7	P	P	NNP
cord-276598-tm0yj2sn	517	8	-	-	HYPH
cord-276598-tm0yj2sn	517	9	N	N	NNP
cord-276598-tm0yj2sn	517	10	from	from	IN
cord-276598-tm0yj2sn	517	11	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	517	12	azide	azide	NN
cord-276598-tm0yj2sn	517	13	and	and	CC
cord-276598-tm0yj2sn	517	14	amines	amine	NNS
cord-276598-tm0yj2sn	517	15	was	be	VBD
cord-276598-tm0yj2sn	517	16	accomplished	accomplish	VBN
cord-276598-tm0yj2sn	517	17	by	by	IN
cord-276598-tm0yj2sn	517	18	Chen	Chen	NNP
cord-276598-tm0yj2sn	517	19	et	et	NNP
cord-276598-tm0yj2sn	517	20	al	al	NNP
cord-276598-tm0yj2sn	517	21	.	.	.
cord-276598-tm0yj2sn	518	1	[	[	-LRB-
cord-276598-tm0yj2sn	518	2	117	117	CD
cord-276598-tm0yj2sn	518	3	]	]	-RRB-
cord-276598-tm0yj2sn	518	4	.	.	.
cord-276598-tm0yj2sn	519	1	The	the	DT
cord-276598-tm0yj2sn	519	2	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	519	3	process	process	NN
cord-276598-tm0yj2sn	519	4	uses	use	VBZ
cord-276598-tm0yj2sn	519	5	the	the	DT
cord-276598-tm0yj2sn	519	6	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	519	7	atom	atom	NN
cord-276598-tm0yj2sn	519	8	available	available	JJ
cord-276598-tm0yj2sn	519	9	from	from	IN
cord-276598-tm0yj2sn	519	10	the	the	DT
cord-276598-tm0yj2sn	519	11	amine	amine	NN
cord-276598-tm0yj2sn	519	12	rather	rather	RB
cord-276598-tm0yj2sn	519	13	than	than	IN
cord-276598-tm0yj2sn	519	14	from	from	IN
cord-276598-tm0yj2sn	519	15	the	the	DT
cord-276598-tm0yj2sn	519	16	azide	azide	NN
cord-276598-tm0yj2sn	519	17	(	(	-LRB-
cord-276598-tm0yj2sn	519	18	Scheme	scheme	NN
cord-276598-tm0yj2sn	519	19	13	13	CD
cord-276598-tm0yj2sn	519	20	)	)	-RRB-
cord-276598-tm0yj2sn	519	21	.	.	.
cord-276598-tm0yj2sn	520	1	The	the	DT
cord-276598-tm0yj2sn	520	2	residue	residue	NN
cord-276598-tm0yj2sn	520	3	was	be	VBD
cord-276598-tm0yj2sn	520	4	purified	purify	VBN
cord-276598-tm0yj2sn	520	5	by	by	IN
cord-276598-tm0yj2sn	520	6	column	column	NN
cord-276598-tm0yj2sn	520	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	520	8	(	(	-LRB-
cord-276598-tm0yj2sn	520	9	on	on	IN
cord-276598-tm0yj2sn	520	10	silica	silica	NN
cord-276598-tm0yj2sn	520	11	)	)	-RRB-
cord-276598-tm0yj2sn	520	12	to	to	TO
cord-276598-tm0yj2sn	520	13	afford	afford	VB
cord-276598-tm0yj2sn	520	14	the	the	DT
cord-276598-tm0yj2sn	520	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	520	16	product	product	NN
cord-276598-tm0yj2sn	520	17	in	in	IN
cord-276598-tm0yj2sn	520	18	52	52	CD
cord-276598-tm0yj2sn	520	19	-	-	SYM
cord-276598-tm0yj2sn	520	20	92	92	CD
cord-276598-tm0yj2sn	520	21	%	%	NN
cord-276598-tm0yj2sn	520	22	yield	yield	NN
cord-276598-tm0yj2sn	520	23	.	.	.
cord-276598-tm0yj2sn	521	1	The	the	DT
cord-276598-tm0yj2sn	521	2	scope	scope	NN
cord-276598-tm0yj2sn	521	3	of	of	IN
cord-276598-tm0yj2sn	521	4	the	the	DT
cord-276598-tm0yj2sn	521	5	reaction	reaction	NN
cord-276598-tm0yj2sn	521	6	was	be	VBD
cord-276598-tm0yj2sn	521	7	examined	examine	VBN
cord-276598-tm0yj2sn	521	8	by	by	IN
cord-276598-tm0yj2sn	521	9	using	use	VBG
cord-276598-tm0yj2sn	521	10	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	521	11	and	and	CC
cord-276598-tm0yj2sn	521	12	diisopropyl	diisopropyl	NNP
cord-276598-tm0yj2sn	521	13	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	521	14	azide	azide	NN
cord-276598-tm0yj2sn	521	15	along	along	IN
cord-276598-tm0yj2sn	521	16	with	with	IN
cord-276598-tm0yj2sn	521	17	primary	primary	JJ
cord-276598-tm0yj2sn	521	18	amines	amine	NNS
cord-276598-tm0yj2sn	521	19	(	(	-LRB-
cord-276598-tm0yj2sn	521	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	521	21	,	,	,
cord-276598-tm0yj2sn	521	22	isopropylamine	isopropylamine	NN
cord-276598-tm0yj2sn	521	23	and	and	CC
cord-276598-tm0yj2sn	521	24	t	t	NN
cord-276598-tm0yj2sn	521	25	-	-	HYPH
cord-276598-tm0yj2sn	521	26	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	521	27	)	)	-RRB-
cord-276598-tm0yj2sn	521	28	,	,	,
cord-276598-tm0yj2sn	521	29	substituted	substitute	VBN
cord-276598-tm0yj2sn	521	30	primary	primary	JJ
cord-276598-tm0yj2sn	521	31	amines	amine	NNS
cord-276598-tm0yj2sn	521	32	(	(	-LRB-
cord-276598-tm0yj2sn	521	33	e.g.	e.g.	RB
cord-276598-tm0yj2sn	521	34	,	,	,
cord-276598-tm0yj2sn	521	35	thiophen-2-ylmethylamine	thiophen-2-ylmethylamine	NNP
cord-276598-tm0yj2sn	521	36	and	and	CC
cord-276598-tm0yj2sn	521	37	4-chlorobenzylamine	4-chlorobenzylamine	CD
cord-276598-tm0yj2sn	521	38	)	)	-RRB-
cord-276598-tm0yj2sn	521	39	,	,	,
cord-276598-tm0yj2sn	521	40	and	and	CC
cord-276598-tm0yj2sn	521	41	heterocyclic	heterocyclic	JJ
cord-276598-tm0yj2sn	521	42	amines	amine	NNS
cord-276598-tm0yj2sn	521	43	(	(	-LRB-
cord-276598-tm0yj2sn	521	44	e.g.	e.g.	RB
cord-276598-tm0yj2sn	521	45	,	,	,
cord-276598-tm0yj2sn	521	46	pyrrolidine	pyrrolidine	JJ
cord-276598-tm0yj2sn	521	47	and	and	CC
cord-276598-tm0yj2sn	521	48	morpholine	morpholine	NNP
cord-276598-tm0yj2sn	521	49	)	)	-RRB-
cord-276598-tm0yj2sn	521	50	.	.	.
cord-276598-tm0yj2sn	522	1	Although	although	IN
cord-276598-tm0yj2sn	522	2	the	the	DT
cord-276598-tm0yj2sn	522	3	method	method	NN
cord-276598-tm0yj2sn	522	4	circumvents	circumvent	VBZ
cord-276598-tm0yj2sn	522	5	the	the	DT
cord-276598-tm0yj2sn	522	6	use	use	NN
cord-276598-tm0yj2sn	522	7	of	of	IN
cord-276598-tm0yj2sn	522	8	metal	metal	NN
cord-276598-tm0yj2sn	522	9	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	522	10	in	in	IN
cord-276598-tm0yj2sn	522	11	the	the	DT
cord-276598-tm0yj2sn	522	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	522	13	,	,	,
cord-276598-tm0yj2sn	522	14	the	the	DT
cord-276598-tm0yj2sn	522	15	use	use	NN
cord-276598-tm0yj2sn	522	16	of	of	IN
cord-276598-tm0yj2sn	522	17	a	a	DT
cord-276598-tm0yj2sn	522	18	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	522	19	azide	azide	NN
cord-276598-tm0yj2sn	522	20	and	and	CC
cord-276598-tm0yj2sn	522	21	high	high	JJ
cord-276598-tm0yj2sn	522	22	temperature	temperature	NN
cord-276598-tm0yj2sn	522	23	are	be	VBP
cord-276598-tm0yj2sn	522	24	its	-PRON-	PRP$
cord-276598-tm0yj2sn	522	25	limitations	limitation	NNS
cord-276598-tm0yj2sn	522	26	.	.	.
cord-276598-tm0yj2sn	523	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	523	2	13	13	CD
cord-276598-tm0yj2sn	523	3	.	.	.
cord-276598-tm0yj2sn	524	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	524	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	524	3	from	from	IN
cord-276598-tm0yj2sn	524	4	organic	organic	JJ
cord-276598-tm0yj2sn	524	5	azide	azide	NN
cord-276598-tm0yj2sn	524	6	and	and	CC
cord-276598-tm0yj2sn	524	7	amine	amine	NN
cord-276598-tm0yj2sn	524	8	.	.	.
cord-276598-tm0yj2sn	525	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	525	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	525	3	via	via	IN
cord-276598-tm0yj2sn	525	4	two	two	CD
cord-276598-tm0yj2sn	525	5	-	-	HYPH
cord-276598-tm0yj2sn	525	6	step	step	NN
cord-276598-tm0yj2sn	525	7	organic	organic	JJ
cord-276598-tm0yj2sn	525	8	azide	azide	NN
cord-276598-tm0yj2sn	525	9	generation	generation	NN
cord-276598-tm0yj2sn	525	10	.	.	.
cord-276598-tm0yj2sn	526	1	Routes	route	NNS
cord-276598-tm0yj2sn	526	2	via	via	IN
cord-276598-tm0yj2sn	526	3	organic	organic	JJ
cord-276598-tm0yj2sn	526	4	azide	azide	NN
cord-276598-tm0yj2sn	526	5	generation	generation	NN
cord-276598-tm0yj2sn	526	6	use	use	NN
cord-276598-tm0yj2sn	526	7	readily	readily	RB
cord-276598-tm0yj2sn	526	8	available	available	JJ
cord-276598-tm0yj2sn	526	9	,	,	,
cord-276598-tm0yj2sn	526	10	less	less	RBR
cord-276598-tm0yj2sn	526	11	toxic	toxic	JJ
cord-276598-tm0yj2sn	526	12	organic	organic	JJ
cord-276598-tm0yj2sn	526	13	halides	halide	NNS
cord-276598-tm0yj2sn	527	1	and	and	CC
cord-276598-tm0yj2sn	527	2	(	(	-LRB-
cord-276598-tm0yj2sn	527	3	RO	RO	NNP
cord-276598-tm0yj2sn	527	4	)	)	-RRB-
cord-276598-tm0yj2sn	527	5	3	3	CD
cord-276598-tm0yj2sn	527	6	P	p	NN
cord-276598-tm0yj2sn	527	7	(	(	-LRB-
cord-276598-tm0yj2sn	527	8	R	r	NN
cord-276598-tm0yj2sn	527	9	=	=	NN
cord-276598-tm0yj2sn	527	10	alkyl	alkyl	NN
cord-276598-tm0yj2sn	527	11	)	)	-RRB-
cord-276598-tm0yj2sn	527	12	relative	relative	JJ
cord-276598-tm0yj2sn	527	13	to	to	IN
cord-276598-tm0yj2sn	527	14	other	other	JJ
cord-276598-tm0yj2sn	527	15	routes	route	NNS
cord-276598-tm0yj2sn	527	16	and	and	CC
cord-276598-tm0yj2sn	527	17	generate	generate	VB
cord-276598-tm0yj2sn	527	18	N	n	CD
cord-276598-tm0yj2sn	527	19	2	2	CD
cord-276598-tm0yj2sn	527	20	as	as	IN
cord-276598-tm0yj2sn	527	21	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	527	22	waste	waste	NN
cord-276598-tm0yj2sn	527	23	.	.	.
cord-276598-tm0yj2sn	528	1	However	however	RB
cord-276598-tm0yj2sn	528	2	,	,	,
cord-276598-tm0yj2sn	528	3	the	the	DT
cord-276598-tm0yj2sn	528	4	method	method	NN
cord-276598-tm0yj2sn	528	5	relies	rely	VBZ
cord-276598-tm0yj2sn	528	6	on	on	IN
cord-276598-tm0yj2sn	528	7	the	the	DT
cord-276598-tm0yj2sn	528	8	pre	pre	JJ
cord-276598-tm0yj2sn	528	9	-	-	NN
cord-276598-tm0yj2sn	528	10	functionalization	functionalization	NN
cord-276598-tm0yj2sn	528	11	and	and	CC
cord-276598-tm0yj2sn	528	12	preparation	preparation	NN
cord-276598-tm0yj2sn	528	13	of	of	IN
cord-276598-tm0yj2sn	528	14	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	528	15	azide	azide	NN
cord-276598-tm0yj2sn	528	16	precursors	precursor	NNS
cord-276598-tm0yj2sn	528	17	in	in	IN
cord-276598-tm0yj2sn	528	18	multi	multi	JJ
cord-276598-tm0yj2sn	528	19	-	-	JJ
cord-276598-tm0yj2sn	528	20	step	step	JJ
cord-276598-tm0yj2sn	528	21	processes	process	NNS
cord-276598-tm0yj2sn	528	22	.	.	.
cord-276598-tm0yj2sn	529	1	Transition	transition	NN
cord-276598-tm0yj2sn	529	2	metal	metal	NN
cord-276598-tm0yj2sn	529	3	-	-	HYPH
cord-276598-tm0yj2sn	529	4	free	free	JJ
cord-276598-tm0yj2sn	529	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	529	6	of	of	IN
cord-276598-tm0yj2sn	529	7	P	P	NNP
cord-276598-tm0yj2sn	529	8	-	-	HYPH
cord-276598-tm0yj2sn	529	9	N	N	NNP
cord-276598-tm0yj2sn	529	10	from	from	IN
cord-276598-tm0yj2sn	529	11	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	529	12	azide	azide	NN
cord-276598-tm0yj2sn	529	13	and	and	CC
cord-276598-tm0yj2sn	529	14	amines	amine	NNS
cord-276598-tm0yj2sn	529	15	was	be	VBD
cord-276598-tm0yj2sn	529	16	accomplished	accomplish	VBN
cord-276598-tm0yj2sn	529	17	by	by	IN
cord-276598-tm0yj2sn	529	18	Chen	Chen	NNP
cord-276598-tm0yj2sn	529	19	et	et	NNP
cord-276598-tm0yj2sn	529	20	al	al	NNP
cord-276598-tm0yj2sn	529	21	.	.	.
cord-276598-tm0yj2sn	530	1	[	[	-LRB-
cord-276598-tm0yj2sn	530	2	117	117	CD
cord-276598-tm0yj2sn	530	3	]	]	-RRB-
cord-276598-tm0yj2sn	530	4	.	.	.
cord-276598-tm0yj2sn	531	1	The	the	DT
cord-276598-tm0yj2sn	531	2	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	531	3	process	process	NN
cord-276598-tm0yj2sn	531	4	uses	use	VBZ
cord-276598-tm0yj2sn	531	5	the	the	DT
cord-276598-tm0yj2sn	531	6	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	531	7	atom	atom	NN
cord-276598-tm0yj2sn	531	8	available	available	JJ
cord-276598-tm0yj2sn	531	9	from	from	IN
cord-276598-tm0yj2sn	531	10	the	the	DT
cord-276598-tm0yj2sn	531	11	amine	amine	NN
cord-276598-tm0yj2sn	531	12	rather	rather	RB
cord-276598-tm0yj2sn	531	13	than	than	IN
cord-276598-tm0yj2sn	531	14	from	from	IN
cord-276598-tm0yj2sn	531	15	the	the	DT
cord-276598-tm0yj2sn	531	16	azide	azide	NN
cord-276598-tm0yj2sn	531	17	(	(	-LRB-
cord-276598-tm0yj2sn	531	18	Scheme	scheme	NN
cord-276598-tm0yj2sn	531	19	13	13	CD
cord-276598-tm0yj2sn	531	20	)	)	-RRB-
cord-276598-tm0yj2sn	531	21	.	.	.
cord-276598-tm0yj2sn	532	1	The	the	DT
cord-276598-tm0yj2sn	532	2	residue	residue	NN
cord-276598-tm0yj2sn	532	3	was	be	VBD
cord-276598-tm0yj2sn	532	4	purified	purify	VBN
cord-276598-tm0yj2sn	532	5	by	by	IN
cord-276598-tm0yj2sn	532	6	column	column	NN
cord-276598-tm0yj2sn	532	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	532	8	(	(	-LRB-
cord-276598-tm0yj2sn	532	9	on	on	IN
cord-276598-tm0yj2sn	532	10	silica	silica	NN
cord-276598-tm0yj2sn	532	11	)	)	-RRB-
cord-276598-tm0yj2sn	532	12	to	to	TO
cord-276598-tm0yj2sn	532	13	afford	afford	VB
cord-276598-tm0yj2sn	532	14	the	the	DT
cord-276598-tm0yj2sn	532	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	532	16	product	product	NN
cord-276598-tm0yj2sn	532	17	in	in	IN
cord-276598-tm0yj2sn	532	18	52	52	CD
cord-276598-tm0yj2sn	532	19	-	-	SYM
cord-276598-tm0yj2sn	532	20	92	92	CD
cord-276598-tm0yj2sn	532	21	%	%	NN
cord-276598-tm0yj2sn	532	22	yield	yield	NN
cord-276598-tm0yj2sn	532	23	.	.	.
cord-276598-tm0yj2sn	533	1	The	the	DT
cord-276598-tm0yj2sn	533	2	scope	scope	NN
cord-276598-tm0yj2sn	533	3	of	of	IN
cord-276598-tm0yj2sn	533	4	the	the	DT
cord-276598-tm0yj2sn	533	5	reaction	reaction	NN
cord-276598-tm0yj2sn	533	6	was	be	VBD
cord-276598-tm0yj2sn	533	7	examined	examine	VBN
cord-276598-tm0yj2sn	533	8	by	by	IN
cord-276598-tm0yj2sn	533	9	using	use	VBG
cord-276598-tm0yj2sn	533	10	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	533	11	and	and	CC
cord-276598-tm0yj2sn	533	12	diisopropyl	diisopropyl	NNP
cord-276598-tm0yj2sn	533	13	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	533	14	azide	azide	NN
cord-276598-tm0yj2sn	533	15	along	along	IN
cord-276598-tm0yj2sn	533	16	with	with	IN
cord-276598-tm0yj2sn	533	17	primary	primary	JJ
cord-276598-tm0yj2sn	533	18	amines	amine	NNS
cord-276598-tm0yj2sn	533	19	(	(	-LRB-
cord-276598-tm0yj2sn	533	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	533	21	,	,	,
cord-276598-tm0yj2sn	533	22	isopropylamine	isopropylamine	NN
cord-276598-tm0yj2sn	533	23	and	and	CC
cord-276598-tm0yj2sn	533	24	t	t	NN
cord-276598-tm0yj2sn	533	25	-	-	HYPH
cord-276598-tm0yj2sn	533	26	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	533	27	)	)	-RRB-
cord-276598-tm0yj2sn	533	28	,	,	,
cord-276598-tm0yj2sn	533	29	substituted	substitute	VBN
cord-276598-tm0yj2sn	533	30	primary	primary	JJ
cord-276598-tm0yj2sn	533	31	amines	amine	NNS
cord-276598-tm0yj2sn	533	32	(	(	-LRB-
cord-276598-tm0yj2sn	533	33	e.g.	e.g.	RB
cord-276598-tm0yj2sn	533	34	,	,	,
cord-276598-tm0yj2sn	533	35	thiophen-2-ylmethylamine	thiophen-2-ylmethylamine	NNP
cord-276598-tm0yj2sn	533	36	and	and	CC
cord-276598-tm0yj2sn	533	37	4-chlorobenzylamine	4-chlorobenzylamine	CD
cord-276598-tm0yj2sn	533	38	)	)	-RRB-
cord-276598-tm0yj2sn	533	39	,	,	,
cord-276598-tm0yj2sn	533	40	and	and	CC
cord-276598-tm0yj2sn	533	41	heterocyclic	heterocyclic	JJ
cord-276598-tm0yj2sn	533	42	amines	amine	NNS
cord-276598-tm0yj2sn	533	43	(	(	-LRB-
cord-276598-tm0yj2sn	533	44	e.g.	e.g.	RB
cord-276598-tm0yj2sn	533	45	,	,	,
cord-276598-tm0yj2sn	533	46	pyrrolidine	pyrrolidine	JJ
cord-276598-tm0yj2sn	533	47	and	and	CC
cord-276598-tm0yj2sn	533	48	morpholine	morpholine	NNP
cord-276598-tm0yj2sn	533	49	)	)	-RRB-
cord-276598-tm0yj2sn	533	50	.	.	.
cord-276598-tm0yj2sn	534	1	Although	although	IN
cord-276598-tm0yj2sn	534	2	the	the	DT
cord-276598-tm0yj2sn	534	3	method	method	NN
cord-276598-tm0yj2sn	534	4	circumvents	circumvent	VBZ
cord-276598-tm0yj2sn	534	5	the	the	DT
cord-276598-tm0yj2sn	534	6	use	use	NN
cord-276598-tm0yj2sn	534	7	of	of	IN
cord-276598-tm0yj2sn	534	8	metal	metal	NN
cord-276598-tm0yj2sn	534	9	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	534	10	in	in	IN
cord-276598-tm0yj2sn	534	11	the	the	DT
cord-276598-tm0yj2sn	534	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	534	13	,	,	,
cord-276598-tm0yj2sn	534	14	the	the	DT
cord-276598-tm0yj2sn	534	15	use	use	NN
cord-276598-tm0yj2sn	534	16	of	of	IN
cord-276598-tm0yj2sn	534	17	a	a	DT
cord-276598-tm0yj2sn	534	18	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	534	19	azide	azide	NN
cord-276598-tm0yj2sn	534	20	and	and	CC
cord-276598-tm0yj2sn	534	21	high	high	JJ
cord-276598-tm0yj2sn	534	22	temperature	temperature	NN
cord-276598-tm0yj2sn	534	23	are	be	VBP
cord-276598-tm0yj2sn	534	24	its	-PRON-	PRP$
cord-276598-tm0yj2sn	534	25	limitations	limitation	NNS
cord-276598-tm0yj2sn	534	26	.	.	.
cord-276598-tm0yj2sn	535	1	from	from	IN
cord-276598-tm0yj2sn	535	2	the	the	DT
cord-276598-tm0yj2sn	535	3	azide	azide	NN
cord-276598-tm0yj2sn	535	4	(	(	-LRB-
cord-276598-tm0yj2sn	535	5	Scheme	scheme	NN
cord-276598-tm0yj2sn	535	6	13	13	CD
cord-276598-tm0yj2sn	535	7	)	)	-RRB-
cord-276598-tm0yj2sn	535	8	.	.	.
cord-276598-tm0yj2sn	536	1	The	the	DT
cord-276598-tm0yj2sn	536	2	residue	residue	NN
cord-276598-tm0yj2sn	536	3	was	be	VBD
cord-276598-tm0yj2sn	536	4	purified	purify	VBN
cord-276598-tm0yj2sn	536	5	by	by	IN
cord-276598-tm0yj2sn	536	6	column	column	NN
cord-276598-tm0yj2sn	536	7	chromatography	chromatography	NN
cord-276598-tm0yj2sn	536	8	(	(	-LRB-
cord-276598-tm0yj2sn	536	9	on	on	IN
cord-276598-tm0yj2sn	536	10	silica	silica	NN
cord-276598-tm0yj2sn	536	11	)	)	-RRB-
cord-276598-tm0yj2sn	536	12	to	to	TO
cord-276598-tm0yj2sn	536	13	afford	afford	VB
cord-276598-tm0yj2sn	536	14	the	the	DT
cord-276598-tm0yj2sn	536	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	536	16	product	product	NN
cord-276598-tm0yj2sn	536	17	in	in	IN
cord-276598-tm0yj2sn	536	18	52	52	CD
cord-276598-tm0yj2sn	536	19	-	-	SYM
cord-276598-tm0yj2sn	536	20	92	92	CD
cord-276598-tm0yj2sn	536	21	%	%	NN
cord-276598-tm0yj2sn	536	22	yield	yield	NN
cord-276598-tm0yj2sn	536	23	.	.	.
cord-276598-tm0yj2sn	537	1	The	the	DT
cord-276598-tm0yj2sn	537	2	scope	scope	NN
cord-276598-tm0yj2sn	537	3	of	of	IN
cord-276598-tm0yj2sn	537	4	the	the	DT
cord-276598-tm0yj2sn	537	5	reaction	reaction	NN
cord-276598-tm0yj2sn	537	6	was	be	VBD
cord-276598-tm0yj2sn	537	7	examined	examine	VBN
cord-276598-tm0yj2sn	537	8	by	by	IN
cord-276598-tm0yj2sn	537	9	using	use	VBG
cord-276598-tm0yj2sn	537	10	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	537	11	and	and	CC
cord-276598-tm0yj2sn	537	12	diisopropyl	diisopropyl	NNP
cord-276598-tm0yj2sn	537	13	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	537	14	azide	azide	NN
cord-276598-tm0yj2sn	537	15	along	along	IN
cord-276598-tm0yj2sn	537	16	with	with	IN
cord-276598-tm0yj2sn	537	17	primary	primary	JJ
cord-276598-tm0yj2sn	537	18	amines	amine	NNS
cord-276598-tm0yj2sn	537	19	(	(	-LRB-
cord-276598-tm0yj2sn	537	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	537	21	,	,	,
cord-276598-tm0yj2sn	537	22	isopropylamine	isopropylamine	NN
cord-276598-tm0yj2sn	537	23	and	and	CC
cord-276598-tm0yj2sn	537	24	t	t	NN
cord-276598-tm0yj2sn	537	25	-	-	HYPH
cord-276598-tm0yj2sn	537	26	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	537	27	)	)	-RRB-
cord-276598-tm0yj2sn	537	28	,	,	,
cord-276598-tm0yj2sn	537	29	substituted	substitute	VBN
cord-276598-tm0yj2sn	537	30	primary	primary	JJ
cord-276598-tm0yj2sn	537	31	amines	amine	NNS
cord-276598-tm0yj2sn	537	32	(	(	-LRB-
cord-276598-tm0yj2sn	537	33	e.g.	e.g.	RB
cord-276598-tm0yj2sn	537	34	,	,	,
cord-276598-tm0yj2sn	537	35	thiophen-2-ylmethylamine	thiophen-2-ylmethylamine	NNP
cord-276598-tm0yj2sn	537	36	and	and	CC
cord-276598-tm0yj2sn	537	37	4-chlorobenzylamine	4-chlorobenzylamine	CD
cord-276598-tm0yj2sn	537	38	)	)	-RRB-
cord-276598-tm0yj2sn	537	39	,	,	,
cord-276598-tm0yj2sn	537	40	and	and	CC
cord-276598-tm0yj2sn	537	41	heterocyclic	heterocyclic	JJ
cord-276598-tm0yj2sn	537	42	amines	amine	NNS
cord-276598-tm0yj2sn	537	43	(	(	-LRB-
cord-276598-tm0yj2sn	537	44	e.g.	e.g.	RB
cord-276598-tm0yj2sn	537	45	,	,	,
cord-276598-tm0yj2sn	537	46	pyrrolidine	pyrrolidine	JJ
cord-276598-tm0yj2sn	537	47	and	and	CC
cord-276598-tm0yj2sn	537	48	morpholine	morpholine	NNP
cord-276598-tm0yj2sn	537	49	)	)	-RRB-
cord-276598-tm0yj2sn	537	50	.	.	.
cord-276598-tm0yj2sn	538	1	Although	although	IN
cord-276598-tm0yj2sn	538	2	the	the	DT
cord-276598-tm0yj2sn	538	3	method	method	NN
cord-276598-tm0yj2sn	538	4	circumvents	circumvent	VBZ
cord-276598-tm0yj2sn	538	5	the	the	DT
cord-276598-tm0yj2sn	538	6	use	use	NN
cord-276598-tm0yj2sn	538	7	of	of	IN
cord-276598-tm0yj2sn	538	8	metal	metal	NN
cord-276598-tm0yj2sn	538	9	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	538	10	in	in	IN
cord-276598-tm0yj2sn	538	11	the	the	DT
cord-276598-tm0yj2sn	538	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	538	13	,	,	,
cord-276598-tm0yj2sn	538	14	the	the	DT
cord-276598-tm0yj2sn	538	15	use	use	NN
cord-276598-tm0yj2sn	538	16	of	of	IN
cord-276598-tm0yj2sn	538	17	a	a	DT
cord-276598-tm0yj2sn	538	18	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	538	19	azide	azide	NN
cord-276598-tm0yj2sn	538	20	and	and	CC
cord-276598-tm0yj2sn	538	21	high	high	JJ
cord-276598-tm0yj2sn	538	22	temperature	temperature	NN
cord-276598-tm0yj2sn	538	23	are	be	VBP
cord-276598-tm0yj2sn	538	24	its	-PRON-	PRP$
cord-276598-tm0yj2sn	538	25	limitations	limitation	NNS
cord-276598-tm0yj2sn	538	26	.	.	.
cord-276598-tm0yj2sn	539	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	539	2	13	13	CD
cord-276598-tm0yj2sn	539	3	.	.	.
cord-276598-tm0yj2sn	540	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	540	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	540	3	from	from	IN
cord-276598-tm0yj2sn	540	4	organic	organic	JJ
cord-276598-tm0yj2sn	540	5	azide	azide	NN
cord-276598-tm0yj2sn	540	6	and	and	CC
cord-276598-tm0yj2sn	540	7	amine	amine	NN
cord-276598-tm0yj2sn	540	8	.	.	.
cord-276598-tm0yj2sn	541	1	Beifuss	Beifuss	NNP
cord-276598-tm0yj2sn	541	2	et	et	NNP
cord-276598-tm0yj2sn	541	3	al	al	NNP
cord-276598-tm0yj2sn	541	4	.	.	NNP
cord-276598-tm0yj2sn	541	5	reported	report	VBD
cord-276598-tm0yj2sn	541	6	a	a	DT
cord-276598-tm0yj2sn	541	7	microwave	microwave	NN
cord-276598-tm0yj2sn	541	8	-	-	HYPH
cord-276598-tm0yj2sn	541	9	assisted	assist	VBN
cord-276598-tm0yj2sn	541	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	541	11	of	of	IN
cord-276598-tm0yj2sn	541	12	N	n	NN
cord-276598-tm0yj2sn	541	13	-	-	HYPH
cord-276598-tm0yj2sn	541	14	arylphosphoramidates	arylphosphoramidate	NNS
cord-276598-tm0yj2sn	541	15	from	from	IN
cord-276598-tm0yj2sn	541	16	nitrobenzene	nitrobenzene	NN
cord-276598-tm0yj2sn	541	17	and	and	CC
cord-276598-tm0yj2sn	541	18	(	(	-LRB-
cord-276598-tm0yj2sn	541	19	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	541	20	(	(	-LRB-
cord-276598-tm0yj2sn	541	21	R	r	NN
cord-276598-tm0yj2sn	541	22	=	=	NN
cord-276598-tm0yj2sn	541	23	alkyl	alkyl	NN
cord-276598-tm0yj2sn	541	24	)	)	-RRB-
cord-276598-tm0yj2sn	542	1	(	(	-LRB-
cord-276598-tm0yj2sn	542	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	542	3	14	14	CD
cord-276598-tm0yj2sn	542	4	)	)	-RRB-
cord-276598-tm0yj2sn	542	5	[	[	-LRB-
cord-276598-tm0yj2sn	542	6	118	118	CD
cord-276598-tm0yj2sn	542	7	]	]	-RRB-
cord-276598-tm0yj2sn	542	8	.	.	.
cord-276598-tm0yj2sn	543	1	The	the	DT
cord-276598-tm0yj2sn	543	2	crude	crude	JJ
cord-276598-tm0yj2sn	543	3	residue	residue	NN
cord-276598-tm0yj2sn	543	4	product	product	NN
cord-276598-tm0yj2sn	543	5	was	be	VBD
cord-276598-tm0yj2sn	543	6	purified	purify	VBN
cord-276598-tm0yj2sn	543	7	by	by	IN
cord-276598-tm0yj2sn	543	8	column	column	NN
cord-276598-tm0yj2sn	543	9	chromatography	chromatography	NN
cord-276598-tm0yj2sn	543	10	(	(	-LRB-
cord-276598-tm0yj2sn	543	11	on	on	IN
cord-276598-tm0yj2sn	543	12	silica	silica	NN
cord-276598-tm0yj2sn	543	13	)	)	-RRB-
cord-276598-tm0yj2sn	543	14	resulting	result	VBG
cord-276598-tm0yj2sn	543	15	in	in	IN
cord-276598-tm0yj2sn	543	16	pure	pure	JJ
cord-276598-tm0yj2sn	543	17	P	p	NN
cord-276598-tm0yj2sn	543	18	-	-	HYPH
cord-276598-tm0yj2sn	543	19	Ns	Ns	NNP
cord-276598-tm0yj2sn	543	20	with	with	IN
cord-276598-tm0yj2sn	543	21	52	52	CD
cord-276598-tm0yj2sn	543	22	-	-	SYM
cord-276598-tm0yj2sn	543	23	79	79	CD
cord-276598-tm0yj2sn	543	24	%	%	NN
cord-276598-tm0yj2sn	543	25	isolated	isolated	JJ
cord-276598-tm0yj2sn	543	26	yield	yield	NN
cord-276598-tm0yj2sn	543	27	.	.	.
cord-276598-tm0yj2sn	544	1	The	the	DT
cord-276598-tm0yj2sn	544	2	scope	scope	NN
cord-276598-tm0yj2sn	544	3	of	of	IN
cord-276598-tm0yj2sn	544	4	the	the	DT
cord-276598-tm0yj2sn	544	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	544	6	was	be	VBD
cord-276598-tm0yj2sn	544	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	544	8	using	use	VBG
cord-276598-tm0yj2sn	544	9	trimethyl	trimethyl	NNP
cord-276598-tm0yj2sn	544	10	or	or	CC
cord-276598-tm0yj2sn	544	11	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	544	12	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	544	13	along	along	IN
cord-276598-tm0yj2sn	544	14	with	with	IN
cord-276598-tm0yj2sn	544	15	nitrobenzene	nitrobenzene	NNP
cord-276598-tm0yj2sn	544	16	,	,	,
cord-276598-tm0yj2sn	544	17	and	and	CC
cord-276598-tm0yj2sn	544	18	mono	mono	NN
cord-276598-tm0yj2sn	544	19	-	-	:
cord-276598-tm0yj2sn	544	20	or	or	CC
cord-276598-tm0yj2sn	544	21	di	di	NN
cord-276598-tm0yj2sn	544	22	-	-	HYPH
cord-276598-tm0yj2sn	544	23	substituted	substitute	VBN
cord-276598-tm0yj2sn	544	24	nitrobenzenes	nitrobenzene	NNS
cord-276598-tm0yj2sn	544	25	with	with	IN
cord-276598-tm0yj2sn	544	26	substitution	substitution	NN
cord-276598-tm0yj2sn	544	27	such	such	JJ
cord-276598-tm0yj2sn	544	28	as	as	IN
cord-276598-tm0yj2sn	544	29	Me	-PRON-	PRP
cord-276598-tm0yj2sn	544	30	,	,	,
cord-276598-tm0yj2sn	544	31	OMe	OMe	NNS
cord-276598-tm0yj2sn	544	32	,	,	,
cord-276598-tm0yj2sn	544	33	Cl	Cl	NNP
cord-276598-tm0yj2sn	544	34	,	,	,
cord-276598-tm0yj2sn	544	35	Br	Br	NNP
cord-276598-tm0yj2sn	544	36	,	,	,
cord-276598-tm0yj2sn	544	37	or	or	CC
cord-276598-tm0yj2sn	544	38	CN	CN	NNP
cord-276598-tm0yj2sn	544	39	groups	group	NNS
cord-276598-tm0yj2sn	544	40	.	.	.
cord-276598-tm0yj2sn	545	1	This	this	DT
cord-276598-tm0yj2sn	545	2	method	method	NN
cord-276598-tm0yj2sn	545	3	is	be	VBZ
cord-276598-tm0yj2sn	545	4	attractive	attractive	JJ
cord-276598-tm0yj2sn	545	5	because	because	IN
cord-276598-tm0yj2sn	545	6	it	-PRON-	PRP
cord-276598-tm0yj2sn	545	7	provides	provide	VBZ
cord-276598-tm0yj2sn	545	8	a	a	DT
cord-276598-tm0yj2sn	545	9	different	different	JJ
cord-276598-tm0yj2sn	545	10	route	route	NN
cord-276598-tm0yj2sn	545	11	to	to	IN
cord-276598-tm0yj2sn	545	12	P	p	NN
cord-276598-tm0yj2sn	545	13	-	-	HYPH
cord-276598-tm0yj2sn	545	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	545	15	using	use	VBG
cord-276598-tm0yj2sn	545	16	nitro	nitro	NN
cord-276598-tm0yj2sn	545	17	compounds	compound	NNS
cord-276598-tm0yj2sn	545	18	instead	instead	RB
cord-276598-tm0yj2sn	545	19	of	of	IN
cord-276598-tm0yj2sn	545	20	the	the	DT
cord-276598-tm0yj2sn	545	21	conventional	conventional	JJ
cord-276598-tm0yj2sn	545	22	amines	amine	NNS
cord-276598-tm0yj2sn	545	23	.	.	.
cord-276598-tm0yj2sn	546	1	Nonetheless	nonetheless	RB
cord-276598-tm0yj2sn	546	2	,	,	,
cord-276598-tm0yj2sn	546	3	the	the	DT
cord-276598-tm0yj2sn	546	4	high	high	JJ
cord-276598-tm0yj2sn	546	5	temperature	temperature	NN
cord-276598-tm0yj2sn	546	6	and	and	CC
cord-276598-tm0yj2sn	546	7	amount	amount	NN
cord-276598-tm0yj2sn	546	8	of	of	IN
cord-276598-tm0yj2sn	546	9	energy	energy	NN
cord-276598-tm0yj2sn	546	10	required	require	VBN
cord-276598-tm0yj2sn	546	11	during	during	IN
cord-276598-tm0yj2sn	546	12	the	the	DT
cord-276598-tm0yj2sn	546	13	synthesis	synthesis	NN
cord-276598-tm0yj2sn	546	14	are	be	VBP
cord-276598-tm0yj2sn	546	15	the	the	DT
cord-276598-tm0yj2sn	546	16	obvious	obvious	JJ
cord-276598-tm0yj2sn	546	17	limitations	limitation	NNS
cord-276598-tm0yj2sn	546	18	.	.	.
cord-276598-tm0yj2sn	546	19	 	 	_SP
cord-276598-tm0yj2sn	547	1	Beifuss	Beifuss	NNP
cord-276598-tm0yj2sn	547	2	et	et	NNP
cord-276598-tm0yj2sn	547	3	al	al	NNP
cord-276598-tm0yj2sn	547	4	.	.	NNP
cord-276598-tm0yj2sn	547	5	reported	report	VBD
cord-276598-tm0yj2sn	547	6	a	a	DT
cord-276598-tm0yj2sn	547	7	microwave	microwave	NN
cord-276598-tm0yj2sn	547	8	-	-	HYPH
cord-276598-tm0yj2sn	547	9	assisted	assist	VBN
cord-276598-tm0yj2sn	547	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	547	11	of	of	IN
cord-276598-tm0yj2sn	547	12	N	n	NN
cord-276598-tm0yj2sn	547	13	-	-	HYPH
cord-276598-tm0yj2sn	547	14	arylphosphoramidates	arylphosphoramidate	NNS
cord-276598-tm0yj2sn	547	15	from	from	IN
cord-276598-tm0yj2sn	547	16	nitrobenzene	nitrobenzene	NN
cord-276598-tm0yj2sn	547	17	and	and	CC
cord-276598-tm0yj2sn	547	18	(	(	-LRB-
cord-276598-tm0yj2sn	547	19	RO	RO	NNP
cord-276598-tm0yj2sn	547	20	)	)	-RRB-
cord-276598-tm0yj2sn	547	21	3	3	CD
cord-276598-tm0yj2sn	547	22	P	p	NN
cord-276598-tm0yj2sn	547	23	(	(	-LRB-
cord-276598-tm0yj2sn	547	24	R	r	NN
cord-276598-tm0yj2sn	547	25	=	=	NN
cord-276598-tm0yj2sn	547	26	alkyl	alkyl	NN
cord-276598-tm0yj2sn	547	27	)	)	-RRB-
cord-276598-tm0yj2sn	548	1	(	(	-LRB-
cord-276598-tm0yj2sn	548	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	548	3	14	14	CD
cord-276598-tm0yj2sn	548	4	)	)	-RRB-
cord-276598-tm0yj2sn	548	5	[	[	-LRB-
cord-276598-tm0yj2sn	548	6	118	118	CD
cord-276598-tm0yj2sn	548	7	]	]	-RRB-
cord-276598-tm0yj2sn	548	8	.	.	.
cord-276598-tm0yj2sn	549	1	The	the	DT
cord-276598-tm0yj2sn	549	2	crude	crude	JJ
cord-276598-tm0yj2sn	549	3	residue	residue	NN
cord-276598-tm0yj2sn	549	4	product	product	NN
cord-276598-tm0yj2sn	549	5	was	be	VBD
cord-276598-tm0yj2sn	549	6	purified	purify	VBN
cord-276598-tm0yj2sn	549	7	by	by	IN
cord-276598-tm0yj2sn	549	8	column	column	NN
cord-276598-tm0yj2sn	549	9	chromatography	chromatography	NN
cord-276598-tm0yj2sn	549	10	(	(	-LRB-
cord-276598-tm0yj2sn	549	11	on	on	IN
cord-276598-tm0yj2sn	549	12	silica	silica	NN
cord-276598-tm0yj2sn	549	13	)	)	-RRB-
cord-276598-tm0yj2sn	549	14	resulting	result	VBG
cord-276598-tm0yj2sn	549	15	in	in	IN
cord-276598-tm0yj2sn	549	16	pure	pure	JJ
cord-276598-tm0yj2sn	549	17	P	p	NN
cord-276598-tm0yj2sn	549	18	-	-	HYPH
cord-276598-tm0yj2sn	549	19	Ns	Ns	NNP
cord-276598-tm0yj2sn	549	20	with	with	IN
cord-276598-tm0yj2sn	549	21	52	52	CD
cord-276598-tm0yj2sn	549	22	-	-	SYM
cord-276598-tm0yj2sn	549	23	79	79	CD
cord-276598-tm0yj2sn	549	24	%	%	NN
cord-276598-tm0yj2sn	549	25	isolated	isolated	JJ
cord-276598-tm0yj2sn	549	26	yield	yield	NN
cord-276598-tm0yj2sn	549	27	.	.	.
cord-276598-tm0yj2sn	550	1	The	the	DT
cord-276598-tm0yj2sn	550	2	scope	scope	NN
cord-276598-tm0yj2sn	550	3	of	of	IN
cord-276598-tm0yj2sn	550	4	the	the	DT
cord-276598-tm0yj2sn	550	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	550	6	was	be	VBD
cord-276598-tm0yj2sn	550	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	550	8	using	use	VBG
cord-276598-tm0yj2sn	550	9	trimethyl	trimethyl	NNP
cord-276598-tm0yj2sn	550	10	or	or	CC
cord-276598-tm0yj2sn	550	11	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	550	12	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	550	13	along	along	IN
cord-276598-tm0yj2sn	550	14	with	with	IN
cord-276598-tm0yj2sn	550	15	nitrobenzene	nitrobenzene	NNP
cord-276598-tm0yj2sn	550	16	,	,	,
cord-276598-tm0yj2sn	550	17	and	and	CC
cord-276598-tm0yj2sn	550	18	mono	mono	NN
cord-276598-tm0yj2sn	550	19	-	-	:
cord-276598-tm0yj2sn	550	20	or	or	CC
cord-276598-tm0yj2sn	550	21	di	di	NN
cord-276598-tm0yj2sn	550	22	-	-	HYPH
cord-276598-tm0yj2sn	550	23	substituted	substitute	VBN
cord-276598-tm0yj2sn	550	24	nitrobenzenes	nitrobenzene	NNS
cord-276598-tm0yj2sn	550	25	with	with	IN
cord-276598-tm0yj2sn	550	26	substitution	substitution	NN
cord-276598-tm0yj2sn	550	27	such	such	JJ
cord-276598-tm0yj2sn	550	28	as	as	IN
cord-276598-tm0yj2sn	550	29	Me	-PRON-	PRP
cord-276598-tm0yj2sn	550	30	,	,	,
cord-276598-tm0yj2sn	550	31	OMe	OMe	NNS
cord-276598-tm0yj2sn	550	32	,	,	,
cord-276598-tm0yj2sn	550	33	Cl	Cl	NNP
cord-276598-tm0yj2sn	550	34	,	,	,
cord-276598-tm0yj2sn	550	35	Br	Br	NNP
cord-276598-tm0yj2sn	550	36	,	,	,
cord-276598-tm0yj2sn	550	37	or	or	CC
cord-276598-tm0yj2sn	550	38	CN	CN	NNP
cord-276598-tm0yj2sn	550	39	groups	group	NNS
cord-276598-tm0yj2sn	550	40	.	.	.
cord-276598-tm0yj2sn	551	1	This	this	DT
cord-276598-tm0yj2sn	551	2	method	method	NN
cord-276598-tm0yj2sn	551	3	is	be	VBZ
cord-276598-tm0yj2sn	551	4	attractive	attractive	JJ
cord-276598-tm0yj2sn	551	5	because	because	IN
cord-276598-tm0yj2sn	551	6	it	-PRON-	PRP
cord-276598-tm0yj2sn	551	7	provides	provide	VBZ
cord-276598-tm0yj2sn	551	8	a	a	DT
cord-276598-tm0yj2sn	551	9	different	different	JJ
cord-276598-tm0yj2sn	551	10	route	route	NN
cord-276598-tm0yj2sn	551	11	to	to	IN
cord-276598-tm0yj2sn	551	12	P	p	NN
cord-276598-tm0yj2sn	551	13	-	-	HYPH
cord-276598-tm0yj2sn	551	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	551	15	using	use	VBG
cord-276598-tm0yj2sn	551	16	nitro	nitro	NN
cord-276598-tm0yj2sn	551	17	compounds	compound	NNS
cord-276598-tm0yj2sn	551	18	instead	instead	RB
cord-276598-tm0yj2sn	551	19	of	of	IN
cord-276598-tm0yj2sn	551	20	the	the	DT
cord-276598-tm0yj2sn	551	21	conventional	conventional	JJ
cord-276598-tm0yj2sn	551	22	amines	amine	NNS
cord-276598-tm0yj2sn	551	23	.	.	.
cord-276598-tm0yj2sn	552	1	Nonetheless	nonetheless	RB
cord-276598-tm0yj2sn	552	2	,	,	,
cord-276598-tm0yj2sn	552	3	the	the	DT
cord-276598-tm0yj2sn	552	4	high	high	JJ
cord-276598-tm0yj2sn	552	5	temperature	temperature	NN
cord-276598-tm0yj2sn	552	6	and	and	CC
cord-276598-tm0yj2sn	552	7	amount	amount	NN
cord-276598-tm0yj2sn	552	8	of	of	IN
cord-276598-tm0yj2sn	552	9	energy	energy	NN
cord-276598-tm0yj2sn	552	10	required	require	VBN
cord-276598-tm0yj2sn	552	11	during	during	IN
cord-276598-tm0yj2sn	552	12	the	the	DT
cord-276598-tm0yj2sn	552	13	synthesis	synthesis	NN
cord-276598-tm0yj2sn	552	14	are	be	VBP
cord-276598-tm0yj2sn	552	15	the	the	DT
cord-276598-tm0yj2sn	552	16	obvious	obvious	JJ
cord-276598-tm0yj2sn	552	17	limitations	limitation	NNS
cord-276598-tm0yj2sn	552	18	.	.	.
cord-276598-tm0yj2sn	553	1	afford	afford	VB
cord-276598-tm0yj2sn	553	2	the	the	DT
cord-276598-tm0yj2sn	553	3	isolated	isolate	VBN
cord-276598-tm0yj2sn	553	4	product	product	NN
cord-276598-tm0yj2sn	553	5	in	in	IN
cord-276598-tm0yj2sn	553	6	52	52	CD
cord-276598-tm0yj2sn	553	7	-	-	SYM
cord-276598-tm0yj2sn	553	8	92	92	CD
cord-276598-tm0yj2sn	553	9	%	%	NN
cord-276598-tm0yj2sn	553	10	yield	yield	NN
cord-276598-tm0yj2sn	553	11	.	.	.
cord-276598-tm0yj2sn	554	1	The	the	DT
cord-276598-tm0yj2sn	554	2	scope	scope	NN
cord-276598-tm0yj2sn	554	3	of	of	IN
cord-276598-tm0yj2sn	554	4	the	the	DT
cord-276598-tm0yj2sn	554	5	reaction	reaction	NN
cord-276598-tm0yj2sn	554	6	was	be	VBD
cord-276598-tm0yj2sn	554	7	examined	examine	VBN
cord-276598-tm0yj2sn	554	8	by	by	IN
cord-276598-tm0yj2sn	554	9	using	use	VBG
cord-276598-tm0yj2sn	554	10	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	554	11	and	and	CC
cord-276598-tm0yj2sn	554	12	diisopropyl	diisopropyl	NNP
cord-276598-tm0yj2sn	554	13	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	554	14	azide	azide	NN
cord-276598-tm0yj2sn	554	15	along	along	IN
cord-276598-tm0yj2sn	554	16	with	with	IN
cord-276598-tm0yj2sn	554	17	primary	primary	JJ
cord-276598-tm0yj2sn	554	18	amines	amine	NNS
cord-276598-tm0yj2sn	554	19	(	(	-LRB-
cord-276598-tm0yj2sn	554	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	554	21	,	,	,
cord-276598-tm0yj2sn	554	22	isopropylamine	isopropylamine	NN
cord-276598-tm0yj2sn	554	23	and	and	CC
cord-276598-tm0yj2sn	554	24	t	t	NN
cord-276598-tm0yj2sn	554	25	-	-	HYPH
cord-276598-tm0yj2sn	554	26	butylamine	butylamine	NNP
cord-276598-tm0yj2sn	554	27	)	)	-RRB-
cord-276598-tm0yj2sn	554	28	,	,	,
cord-276598-tm0yj2sn	554	29	substituted	substitute	VBN
cord-276598-tm0yj2sn	554	30	primary	primary	JJ
cord-276598-tm0yj2sn	554	31	amines	amine	NNS
cord-276598-tm0yj2sn	554	32	(	(	-LRB-
cord-276598-tm0yj2sn	554	33	e.g.	e.g.	RB
cord-276598-tm0yj2sn	554	34	,	,	,
cord-276598-tm0yj2sn	554	35	thiophen-2-ylmethylamine	thiophen-2-ylmethylamine	NNP
cord-276598-tm0yj2sn	554	36	and	and	CC
cord-276598-tm0yj2sn	554	37	4-chlorobenzylamine	4-chlorobenzylamine	CD
cord-276598-tm0yj2sn	554	38	)	)	-RRB-
cord-276598-tm0yj2sn	554	39	,	,	,
cord-276598-tm0yj2sn	554	40	and	and	CC
cord-276598-tm0yj2sn	554	41	heterocyclic	heterocyclic	JJ
cord-276598-tm0yj2sn	554	42	amines	amine	NNS
cord-276598-tm0yj2sn	554	43	(	(	-LRB-
cord-276598-tm0yj2sn	554	44	e.g.	e.g.	RB
cord-276598-tm0yj2sn	554	45	,	,	,
cord-276598-tm0yj2sn	554	46	pyrrolidine	pyrrolidine	JJ
cord-276598-tm0yj2sn	554	47	and	and	CC
cord-276598-tm0yj2sn	554	48	morpholine	morpholine	NNP
cord-276598-tm0yj2sn	554	49	)	)	-RRB-
cord-276598-tm0yj2sn	554	50	.	.	.
cord-276598-tm0yj2sn	555	1	Although	although	IN
cord-276598-tm0yj2sn	555	2	the	the	DT
cord-276598-tm0yj2sn	555	3	method	method	NN
cord-276598-tm0yj2sn	555	4	circumvents	circumvent	VBZ
cord-276598-tm0yj2sn	555	5	the	the	DT
cord-276598-tm0yj2sn	555	6	use	use	NN
cord-276598-tm0yj2sn	555	7	of	of	IN
cord-276598-tm0yj2sn	555	8	metal	metal	NN
cord-276598-tm0yj2sn	555	9	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	555	10	in	in	IN
cord-276598-tm0yj2sn	555	11	the	the	DT
cord-276598-tm0yj2sn	555	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	555	13	,	,	,
cord-276598-tm0yj2sn	555	14	the	the	DT
cord-276598-tm0yj2sn	555	15	use	use	NN
cord-276598-tm0yj2sn	555	16	of	of	IN
cord-276598-tm0yj2sn	555	17	a	a	DT
cord-276598-tm0yj2sn	555	18	hazardous	hazardous	JJ
cord-276598-tm0yj2sn	555	19	azide	azide	NN
cord-276598-tm0yj2sn	555	20	and	and	CC
cord-276598-tm0yj2sn	555	21	high	high	JJ
cord-276598-tm0yj2sn	555	22	temperature	temperature	NN
cord-276598-tm0yj2sn	555	23	are	be	VBP
cord-276598-tm0yj2sn	555	24	its	-PRON-	PRP$
cord-276598-tm0yj2sn	555	25	limitations	limitation	NNS
cord-276598-tm0yj2sn	555	26	.	.	.
cord-276598-tm0yj2sn	556	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	556	2	13	13	CD
cord-276598-tm0yj2sn	556	3	.	.	.
cord-276598-tm0yj2sn	557	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	557	2	synthesis	synthesis	NN
cord-276598-tm0yj2sn	557	3	from	from	IN
cord-276598-tm0yj2sn	557	4	organic	organic	JJ
cord-276598-tm0yj2sn	557	5	azide	azide	NN
cord-276598-tm0yj2sn	557	6	and	and	CC
cord-276598-tm0yj2sn	557	7	amine	amine	NN
cord-276598-tm0yj2sn	557	8	.	.	.
cord-276598-tm0yj2sn	558	1	Beifuss	Beifuss	NNP
cord-276598-tm0yj2sn	558	2	et	et	NNP
cord-276598-tm0yj2sn	558	3	al	al	NNP
cord-276598-tm0yj2sn	558	4	.	.	NNP
cord-276598-tm0yj2sn	558	5	reported	report	VBD
cord-276598-tm0yj2sn	558	6	a	a	DT
cord-276598-tm0yj2sn	558	7	microwave	microwave	NN
cord-276598-tm0yj2sn	558	8	-	-	HYPH
cord-276598-tm0yj2sn	558	9	assisted	assist	VBN
cord-276598-tm0yj2sn	558	10	synthesis	synthesis	NN
cord-276598-tm0yj2sn	558	11	of	of	IN
cord-276598-tm0yj2sn	558	12	N	n	NN
cord-276598-tm0yj2sn	558	13	-	-	HYPH
cord-276598-tm0yj2sn	558	14	arylphosphoramidates	arylphosphoramidate	NNS
cord-276598-tm0yj2sn	558	15	from	from	IN
cord-276598-tm0yj2sn	558	16	nitrobenzene	nitrobenzene	NN
cord-276598-tm0yj2sn	558	17	and	and	CC
cord-276598-tm0yj2sn	558	18	(	(	-LRB-
cord-276598-tm0yj2sn	558	19	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	558	20	(	(	-LRB-
cord-276598-tm0yj2sn	558	21	R	r	NN
cord-276598-tm0yj2sn	558	22	=	=	NN
cord-276598-tm0yj2sn	558	23	alkyl	alkyl	NN
cord-276598-tm0yj2sn	558	24	)	)	-RRB-
cord-276598-tm0yj2sn	559	1	(	(	-LRB-
cord-276598-tm0yj2sn	559	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	559	3	14	14	CD
cord-276598-tm0yj2sn	559	4	)	)	-RRB-
cord-276598-tm0yj2sn	559	5	[	[	-LRB-
cord-276598-tm0yj2sn	559	6	118	118	CD
cord-276598-tm0yj2sn	559	7	]	]	-RRB-
cord-276598-tm0yj2sn	559	8	.	.	.
cord-276598-tm0yj2sn	560	1	The	the	DT
cord-276598-tm0yj2sn	560	2	crude	crude	JJ
cord-276598-tm0yj2sn	560	3	residue	residue	NN
cord-276598-tm0yj2sn	560	4	product	product	NN
cord-276598-tm0yj2sn	560	5	was	be	VBD
cord-276598-tm0yj2sn	560	6	purified	purify	VBN
cord-276598-tm0yj2sn	560	7	by	by	IN
cord-276598-tm0yj2sn	560	8	column	column	NN
cord-276598-tm0yj2sn	560	9	chromatography	chromatography	NN
cord-276598-tm0yj2sn	560	10	(	(	-LRB-
cord-276598-tm0yj2sn	560	11	on	on	IN
cord-276598-tm0yj2sn	560	12	silica	silica	NN
cord-276598-tm0yj2sn	560	13	)	)	-RRB-
cord-276598-tm0yj2sn	560	14	resulting	result	VBG
cord-276598-tm0yj2sn	560	15	in	in	IN
cord-276598-tm0yj2sn	560	16	pure	pure	JJ
cord-276598-tm0yj2sn	560	17	P	p	NN
cord-276598-tm0yj2sn	560	18	-	-	HYPH
cord-276598-tm0yj2sn	560	19	Ns	Ns	NNP
cord-276598-tm0yj2sn	560	20	with	with	IN
cord-276598-tm0yj2sn	560	21	52	52	CD
cord-276598-tm0yj2sn	560	22	-	-	SYM
cord-276598-tm0yj2sn	560	23	79	79	CD
cord-276598-tm0yj2sn	560	24	%	%	NN
cord-276598-tm0yj2sn	560	25	isolated	isolated	JJ
cord-276598-tm0yj2sn	560	26	yield	yield	NN
cord-276598-tm0yj2sn	560	27	.	.	.
cord-276598-tm0yj2sn	561	1	The	the	DT
cord-276598-tm0yj2sn	561	2	scope	scope	NN
cord-276598-tm0yj2sn	561	3	of	of	IN
cord-276598-tm0yj2sn	561	4	the	the	DT
cord-276598-tm0yj2sn	561	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	561	6	was	be	VBD
cord-276598-tm0yj2sn	561	7	investigated	investigate	VBN
cord-276598-tm0yj2sn	561	8	using	use	VBG
cord-276598-tm0yj2sn	561	9	trimethyl	trimethyl	NNP
cord-276598-tm0yj2sn	561	10	or	or	CC
cord-276598-tm0yj2sn	561	11	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	561	12	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	561	13	along	along	IN
cord-276598-tm0yj2sn	561	14	with	with	IN
cord-276598-tm0yj2sn	561	15	nitrobenzene	nitrobenzene	NNP
cord-276598-tm0yj2sn	561	16	,	,	,
cord-276598-tm0yj2sn	561	17	and	and	CC
cord-276598-tm0yj2sn	561	18	mono	mono	NN
cord-276598-tm0yj2sn	561	19	-	-	:
cord-276598-tm0yj2sn	561	20	or	or	CC
cord-276598-tm0yj2sn	561	21	di	di	NN
cord-276598-tm0yj2sn	561	22	-	-	HYPH
cord-276598-tm0yj2sn	561	23	substituted	substitute	VBN
cord-276598-tm0yj2sn	561	24	nitrobenzenes	nitrobenzene	NNS
cord-276598-tm0yj2sn	561	25	with	with	IN
cord-276598-tm0yj2sn	561	26	substitution	substitution	NN
cord-276598-tm0yj2sn	561	27	such	such	JJ
cord-276598-tm0yj2sn	561	28	as	as	IN
cord-276598-tm0yj2sn	561	29	Me	-PRON-	PRP
cord-276598-tm0yj2sn	561	30	,	,	,
cord-276598-tm0yj2sn	561	31	OMe	OMe	NNS
cord-276598-tm0yj2sn	561	32	,	,	,
cord-276598-tm0yj2sn	561	33	Cl	Cl	NNP
cord-276598-tm0yj2sn	561	34	,	,	,
cord-276598-tm0yj2sn	561	35	Br	Br	NNP
cord-276598-tm0yj2sn	561	36	,	,	,
cord-276598-tm0yj2sn	561	37	or	or	CC
cord-276598-tm0yj2sn	561	38	CN	CN	NNP
cord-276598-tm0yj2sn	561	39	groups	group	NNS
cord-276598-tm0yj2sn	561	40	.	.	.
cord-276598-tm0yj2sn	562	1	This	this	DT
cord-276598-tm0yj2sn	562	2	method	method	NN
cord-276598-tm0yj2sn	562	3	is	be	VBZ
cord-276598-tm0yj2sn	562	4	attractive	attractive	JJ
cord-276598-tm0yj2sn	562	5	because	because	IN
cord-276598-tm0yj2sn	562	6	it	-PRON-	PRP
cord-276598-tm0yj2sn	562	7	provides	provide	VBZ
cord-276598-tm0yj2sn	562	8	a	a	DT
cord-276598-tm0yj2sn	562	9	different	different	JJ
cord-276598-tm0yj2sn	562	10	route	route	NN
cord-276598-tm0yj2sn	562	11	to	to	IN
cord-276598-tm0yj2sn	562	12	P	p	NN
cord-276598-tm0yj2sn	562	13	-	-	HYPH
cord-276598-tm0yj2sn	562	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	562	15	using	use	VBG
cord-276598-tm0yj2sn	562	16	nitro	nitro	NN
cord-276598-tm0yj2sn	562	17	compounds	compound	NNS
cord-276598-tm0yj2sn	562	18	instead	instead	RB
cord-276598-tm0yj2sn	562	19	of	of	IN
cord-276598-tm0yj2sn	562	20	the	the	DT
cord-276598-tm0yj2sn	562	21	conventional	conventional	JJ
cord-276598-tm0yj2sn	562	22	amines	amine	NNS
cord-276598-tm0yj2sn	562	23	.	.	.
cord-276598-tm0yj2sn	563	1	Nonetheless	nonetheless	RB
cord-276598-tm0yj2sn	563	2	,	,	,
cord-276598-tm0yj2sn	563	3	the	the	DT
cord-276598-tm0yj2sn	563	4	high	high	JJ
cord-276598-tm0yj2sn	563	5	temperature	temperature	NN
cord-276598-tm0yj2sn	563	6	and	and	CC
cord-276598-tm0yj2sn	563	7	amount	amount	NN
cord-276598-tm0yj2sn	563	8	of	of	IN
cord-276598-tm0yj2sn	563	9	energy	energy	NN
cord-276598-tm0yj2sn	563	10	required	require	VBN
cord-276598-tm0yj2sn	563	11	during	during	IN
cord-276598-tm0yj2sn	563	12	the	the	DT
cord-276598-tm0yj2sn	563	13	synthesis	synthesis	NN
cord-276598-tm0yj2sn	563	14	are	be	VBP
cord-276598-tm0yj2sn	563	15	the	the	DT
cord-276598-tm0yj2sn	563	16	obvious	obvious	JJ
cord-276598-tm0yj2sn	563	17	limitations	limitation	NNS
cord-276598-tm0yj2sn	563	18	.	.	.
cord-276598-tm0yj2sn	563	19	 	 	_SP
cord-276598-tm0yj2sn	564	1	Hackenberger	Hackenberger	NNP
cord-276598-tm0yj2sn	564	2	et	et	NNP
cord-276598-tm0yj2sn	564	3	al	al	NNP
cord-276598-tm0yj2sn	564	4	.	.	.
cord-276598-tm0yj2sn	565	1	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	565	2	P	P	NNP
cord-276598-tm0yj2sn	565	3	-	-	HYPH
cord-276598-tm0yj2sn	565	4	N	n	CD
cord-276598-tm0yj2sn	565	5	compounds	compound	NNS
cord-276598-tm0yj2sn	565	6	from	from	IN
cord-276598-tm0yj2sn	565	7	organic	organic	JJ
cord-276598-tm0yj2sn	565	8	azide	azide	NN
cord-276598-tm0yj2sn	565	9	derivatives	derivative	NNS
cord-276598-tm0yj2sn	565	10	and	and	CC
cord-276598-tm0yj2sn	565	11	(	(	-LRB-
cord-276598-tm0yj2sn	565	12	RO	RO	NNP
cord-276598-tm0yj2sn	565	13	)	)	-RRB-
cord-276598-tm0yj2sn	565	14	3	3	CD
cord-276598-tm0yj2sn	565	15	P	p	NN
cord-276598-tm0yj2sn	565	16	(	(	-LRB-
cord-276598-tm0yj2sn	565	17	R	r	NN
cord-276598-tm0yj2sn	565	18	=	=	NN
cord-276598-tm0yj2sn	565	19	alkyl	alkyl	NN
cord-276598-tm0yj2sn	565	20	)	)	-RRB-
cord-276598-tm0yj2sn	566	1	after	after	IN
cord-276598-tm0yj2sn	566	2	Lewis	Lewis	NNP
cord-276598-tm0yj2sn	566	3	acid	acid	NN
cord-276598-tm0yj2sn	566	4	-	-	HYPH
cord-276598-tm0yj2sn	566	5	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	566	6	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	566	7	(	(	-LRB-
cord-276598-tm0yj2sn	566	8	Scheme	scheme	NN
cord-276598-tm0yj2sn	566	9	15	15	CD
cord-276598-tm0yj2sn	566	10	)	)	-RRB-
cord-276598-tm0yj2sn	566	11	[	[	-LRB-
cord-276598-tm0yj2sn	566	12	119	119	CD
cord-276598-tm0yj2sn	566	13	]	]	-RRB-
cord-276598-tm0yj2sn	566	14	.	.	.
cord-276598-tm0yj2sn	567	1	The	the	DT
cord-276598-tm0yj2sn	567	2	crude	crude	JJ
cord-276598-tm0yj2sn	567	3	product	product	NN
cord-276598-tm0yj2sn	567	4	was	be	VBD
cord-276598-tm0yj2sn	567	5	concentrated	concentrate	VBN
cord-276598-tm0yj2sn	567	6	under	under	IN
cord-276598-tm0yj2sn	567	7	reduced	reduce	VBN
cord-276598-tm0yj2sn	567	8	pressure	pressure	NN
cord-276598-tm0yj2sn	567	9	,	,	,
cord-276598-tm0yj2sn	567	10	and	and	CC
cord-276598-tm0yj2sn	567	11	the	the	DT
cord-276598-tm0yj2sn	567	12	desired	desire	VBN
cord-276598-tm0yj2sn	567	13	product	product	NN
cord-276598-tm0yj2sn	567	14	was	be	VBD
cord-276598-tm0yj2sn	567	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	567	16	(	(	-LRB-
cord-276598-tm0yj2sn	567	17	63	63	CD
cord-276598-tm0yj2sn	567	18	-	-	SYM
cord-276598-tm0yj2sn	567	19	98	98	CD
cord-276598-tm0yj2sn	567	20	%	%	NN
cord-276598-tm0yj2sn	567	21	yield	yield	NN
cord-276598-tm0yj2sn	567	22	)	)	-RRB-
cord-276598-tm0yj2sn	567	23	through	through	IN
cord-276598-tm0yj2sn	567	24	column	column	NN
cord-276598-tm0yj2sn	567	25	chromatography	chromatography	NN
cord-276598-tm0yj2sn	567	26	(	(	-LRB-
cord-276598-tm0yj2sn	567	27	on	on	IN
cord-276598-tm0yj2sn	567	28	silica	silica	NN
cord-276598-tm0yj2sn	567	29	)	)	-RRB-
cord-276598-tm0yj2sn	567	30	.	.	.
cord-276598-tm0yj2sn	568	1	Triethyl	Triethyl	NNP
cord-276598-tm0yj2sn	568	2	or	or	CC
cord-276598-tm0yj2sn	568	3	trimethyl	trimethyl	NNP
cord-276598-tm0yj2sn	568	4	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	568	5	were	be	VBD
cord-276598-tm0yj2sn	568	6	used	use	VBN
cord-276598-tm0yj2sn	568	7	as	as	IN
cord-276598-tm0yj2sn	568	8	the	the	DT
cord-276598-tm0yj2sn	568	9	P	p	NN
cord-276598-tm0yj2sn	568	10	-	-	HYPH
cord-276598-tm0yj2sn	568	11	source	source	NN
cord-276598-tm0yj2sn	568	12	along	along	IN
cord-276598-tm0yj2sn	568	13	with	with	IN
cord-276598-tm0yj2sn	568	14	organic	organic	JJ
cord-276598-tm0yj2sn	568	15	azide	azide	NN
cord-276598-tm0yj2sn	568	16	derivatives	derivative	NNS
cord-276598-tm0yj2sn	568	17	such	such	JJ
cord-276598-tm0yj2sn	568	18	as	as	IN
cord-276598-tm0yj2sn	568	19	(	(	-LRB-
cord-276598-tm0yj2sn	568	20	azidomethyl)benzene	azidomethyl)benzene	NNP
cord-276598-tm0yj2sn	568	21	,	,	,
cord-276598-tm0yj2sn	568	22	azidocyclohexane	azidocyclohexane	NNP
cord-276598-tm0yj2sn	568	23	,	,	,
cord-276598-tm0yj2sn	568	24	(	(	-LRB-
cord-276598-tm0yj2sn	568	25	2-azidopropan-2-yl)benzene	2-azidopropan-2-yl)benzene	CD
cord-276598-tm0yj2sn	568	26	,	,	,
cord-276598-tm0yj2sn	568	27	azidobenzene	azidobenzene	NN
cord-276598-tm0yj2sn	568	28	,	,	,
cord-276598-tm0yj2sn	568	29	ethyl	ethyl	NNP
cord-276598-tm0yj2sn	568	30	2-azidoacetate	2-azidoacetate	CD
cord-276598-tm0yj2sn	568	31	,	,	,
cord-276598-tm0yj2sn	568	32	1-azidodecane	1-azidodecane	CD
cord-276598-tm0yj2sn	568	33	,	,	,
cord-276598-tm0yj2sn	568	34	(	(	-LRB-
cord-276598-tm0yj2sn	568	35	azidomethylene)dibenzene	azidomethylene)dibenzene	NNP
cord-276598-tm0yj2sn	568	36	,	,	,
cord-276598-tm0yj2sn	568	37	and	and	CC
cord-276598-tm0yj2sn	568	38	(	(	-LRB-
cord-276598-tm0yj2sn	568	39	3-azidoprop-1-en-1-yl)benzene	3-azidoprop-1-en-1-yl)benzene	CD
cord-276598-tm0yj2sn	568	40	.	.	.
cord-276598-tm0yj2sn	569	1	[	[	-LRB-
cord-276598-tm0yj2sn	569	2	119	119	CD
cord-276598-tm0yj2sn	569	3	]	]	-RRB-
cord-276598-tm0yj2sn	569	4	.	.	.
cord-276598-tm0yj2sn	570	1	The	the	DT
cord-276598-tm0yj2sn	570	2	crude	crude	JJ
cord-276598-tm0yj2sn	570	3	product	product	NN
cord-276598-tm0yj2sn	570	4	was	be	VBD
cord-276598-tm0yj2sn	570	5	concentrated	concentrate	VBN
cord-276598-tm0yj2sn	570	6	under	under	IN
cord-276598-tm0yj2sn	570	7	reduced	reduce	VBN
cord-276598-tm0yj2sn	570	8	pressure	pressure	NN
cord-276598-tm0yj2sn	570	9	,	,	,
cord-276598-tm0yj2sn	570	10	and	and	CC
cord-276598-tm0yj2sn	570	11	the	the	DT
cord-276598-tm0yj2sn	570	12	desired	desire	VBN
cord-276598-tm0yj2sn	570	13	product	product	NN
cord-276598-tm0yj2sn	570	14	was	be	VBD
cord-276598-tm0yj2sn	570	15	isolated	isolate	VBN
cord-276598-tm0yj2sn	570	16	(	(	-LRB-
cord-276598-tm0yj2sn	570	17	63	63	CD
cord-276598-tm0yj2sn	570	18	-	-	SYM
cord-276598-tm0yj2sn	570	19	98	98	CD
cord-276598-tm0yj2sn	570	20	%	%	NN
cord-276598-tm0yj2sn	570	21	yield	yield	NN
cord-276598-tm0yj2sn	570	22	)	)	-RRB-
cord-276598-tm0yj2sn	570	23	through	through	IN
cord-276598-tm0yj2sn	570	24	column	column	NN
cord-276598-tm0yj2sn	570	25	chromatography	chromatography	NN
cord-276598-tm0yj2sn	570	26	(	(	-LRB-
cord-276598-tm0yj2sn	570	27	on	on	IN
cord-276598-tm0yj2sn	570	28	silica	silica	NN
cord-276598-tm0yj2sn	570	29	)	)	-RRB-
cord-276598-tm0yj2sn	570	30	.	.	.
cord-276598-tm0yj2sn	571	1	Triethyl	Triethyl	NNP
cord-276598-tm0yj2sn	571	2	or	or	CC
cord-276598-tm0yj2sn	571	3	trimethyl	trimethyl	NNP
cord-276598-tm0yj2sn	571	4	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	571	5	were	be	VBD
cord-276598-tm0yj2sn	571	6	used	use	VBN
cord-276598-tm0yj2sn	571	7	as	as	IN
cord-276598-tm0yj2sn	571	8	the	the	DT
cord-276598-tm0yj2sn	571	9	P	p	NN
cord-276598-tm0yj2sn	571	10	-	-	HYPH
cord-276598-tm0yj2sn	571	11	source	source	NN
cord-276598-tm0yj2sn	571	12	along	along	IN
cord-276598-tm0yj2sn	571	13	with	with	IN
cord-276598-tm0yj2sn	571	14	organic	organic	JJ
cord-276598-tm0yj2sn	571	15	azide	azide	NN
cord-276598-tm0yj2sn	571	16	derivatives	derivative	NNS
cord-276598-tm0yj2sn	571	17	such	such	JJ
cord-276598-tm0yj2sn	571	18	as	as	IN
cord-276598-tm0yj2sn	571	19	(	(	-LRB-
cord-276598-tm0yj2sn	571	20	azidomethyl)benzene	azidomethyl)benzene	NNP
cord-276598-tm0yj2sn	571	21	,	,	,
cord-276598-tm0yj2sn	571	22	azidocyclohexane	azidocyclohexane	NNP
cord-276598-tm0yj2sn	571	23	,	,	,
cord-276598-tm0yj2sn	571	24	(	(	-LRB-
cord-276598-tm0yj2sn	571	25	2-azidopropan-2-yl)benzene	2-azidopropan-2-yl)benzene	CD
cord-276598-tm0yj2sn	571	26	,	,	,
cord-276598-tm0yj2sn	571	27	azidobenzene	azidobenzene	NN
cord-276598-tm0yj2sn	571	28	,	,	,
cord-276598-tm0yj2sn	571	29	ethyl	ethyl	NNP
cord-276598-tm0yj2sn	571	30	2-azidoacetate	2-azidoacetate	CD
cord-276598-tm0yj2sn	571	31	,	,	,
cord-276598-tm0yj2sn	571	32	1-azidodecane	1-azidodecane	CD
cord-276598-tm0yj2sn	571	33	,	,	,
cord-276598-tm0yj2sn	571	34	(	(	-LRB-
cord-276598-tm0yj2sn	571	35	azidomethylene)dibenzene	azidomethylene)dibenzene	NNP
cord-276598-tm0yj2sn	571	36	,	,	,
cord-276598-tm0yj2sn	571	37	and	and	CC
cord-276598-tm0yj2sn	571	38	(	(	-LRB-
cord-276598-tm0yj2sn	571	39	3-azidoprop-1-en-1-yl)benzene	3-azidoprop-1-en-1-yl)benzene	CD
cord-276598-tm0yj2sn	571	40	.	.	.
cord-276598-tm0yj2sn	571	41	 	 	_SP
cord-276598-tm0yj2sn	572	1	Zimin	Zimin	NNP
cord-276598-tm0yj2sn	572	2	et	et	NNP
cord-276598-tm0yj2sn	572	3	al	al	NNP
cord-276598-tm0yj2sn	572	4	.	.	NNP
cord-276598-tm0yj2sn	572	5	reported	report	VBD
cord-276598-tm0yj2sn	572	6	the	the	DT
cord-276598-tm0yj2sn	572	7	1,2-hydrophosphinylation	1,2-hydrophosphinylation	CD
cord-276598-tm0yj2sn	572	8	of	of	IN
cord-276598-tm0yj2sn	572	9	alkyl	alkyl	NN
cord-276598-tm0yj2sn	572	10	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	572	11	(	(	-LRB-
cord-276598-tm0yj2sn	572	12	R'-CN	R'-CN	NNS
cord-276598-tm0yj2sn	572	13	,	,	,
cord-276598-tm0yj2sn	572	14	R	r	NN
cord-276598-tm0yj2sn	572	15	'	'	''
cord-276598-tm0yj2sn	573	1	=	=	NFP
cord-276598-tm0yj2sn	573	2	alkyl	alkyl	NN
cord-276598-tm0yj2sn	573	3	,	,	,
cord-276598-tm0yj2sn	573	4	Ph	Ph	NNP
cord-276598-tm0yj2sn	573	5	,	,	,
cord-276598-tm0yj2sn	573	6	Bn	Bn	NNP
cord-276598-tm0yj2sn	573	7	)	)	-RRB-
cord-276598-tm0yj2sn	573	8	using	use	VBG
cord-276598-tm0yj2sn	573	9	sodium	sodium	NN
cord-276598-tm0yj2sn	573	10	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	573	11	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	573	12	(	(	-LRB-
cord-276598-tm0yj2sn	573	13	(	(	-LRB-
cord-276598-tm0yj2sn	573	14	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	573	15	,	,	,
cord-276598-tm0yj2sn	573	16	R	r	NN
cord-276598-tm0yj2sn	573	17	=	=	FW
cord-276598-tm0yj2sn	573	18	Et	et	NN
cord-276598-tm0yj2sn	573	19	,	,	,
cord-276598-tm0yj2sn	573	20	Pr	Pr	NNP
cord-276598-tm0yj2sn	573	21	)	)	-RRB-
cord-276598-tm0yj2sn	573	22	to	to	TO
cord-276598-tm0yj2sn	573	23	achieve	achieve	VB
cord-276598-tm0yj2sn	573	24	the	the	DT
cord-276598-tm0yj2sn	573	25	formation	formation	NN
cord-276598-tm0yj2sn	573	26	of	of	IN
cord-276598-tm0yj2sn	573	27	a	a	DT
cord-276598-tm0yj2sn	573	28	P	P	NNP
cord-276598-tm0yj2sn	573	29	-	-	HYPH
cord-276598-tm0yj2sn	573	30	N	n	NN
cord-276598-tm0yj2sn	573	31	featuring	feature	VBG
cord-276598-tm0yj2sn	573	32	a	a	DT
cord-276598-tm0yj2sn	573	33	P	P	NNP
cord-276598-tm0yj2sn	573	34	-	-	HYPH
cord-276598-tm0yj2sn	573	35	C	C	NNP
cord-276598-tm0yj2sn	573	36	-	-	HYPH
cord-276598-tm0yj2sn	573	37	N	N	NNP
cord-276598-tm0yj2sn	573	38	-	-	HYPH
cord-276598-tm0yj2sn	573	39	P	p	NN
cord-276598-tm0yj2sn	573	40	linkage	linkage	NN
cord-276598-tm0yj2sn	573	41	in	in	IN
cord-276598-tm0yj2sn	573	42	which	which	WDT
cord-276598-tm0yj2sn	573	43	the	the	DT
cord-276598-tm0yj2sn	573	44	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	573	45	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	573	46	group	group	NNP
cord-276598-tm0yj2sn	573	47	of	of	IN
cord-276598-tm0yj2sn	573	48	(	(	-LRB-
cord-276598-tm0yj2sn	573	49	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	573	50	was	be	VBD
cord-276598-tm0yj2sn	573	51	added	add	VBN
cord-276598-tm0yj2sn	573	52	to	to	IN
cord-276598-tm0yj2sn	573	53	the	the	DT
cord-276598-tm0yj2sn	573	54	carbon	carbon	NN
cord-276598-tm0yj2sn	573	55	and	and	CC
cord-276598-tm0yj2sn	573	56	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	573	57	atoms	atom	NNS
cord-276598-tm0yj2sn	573	58	of	of	IN
cord-276598-tm0yj2sn	573	59	the	the	DT
cord-276598-tm0yj2sn	573	60	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	573	61	(	(	-LRB-
cord-276598-tm0yj2sn	573	62	Scheme	scheme	NN
cord-276598-tm0yj2sn	573	63	16	16	CD
cord-276598-tm0yj2sn	573	64	)	)	-RRB-
cord-276598-tm0yj2sn	573	65	[	[	-LRB-
cord-276598-tm0yj2sn	573	66	120	120	CD
cord-276598-tm0yj2sn	573	67	]	]	-RRB-
cord-276598-tm0yj2sn	573	68	.	.	.
cord-276598-tm0yj2sn	573	69	 	 	_SP
cord-276598-tm0yj2sn	574	1	Zimin	Zimin	NNP
cord-276598-tm0yj2sn	574	2	et	et	NNP
cord-276598-tm0yj2sn	574	3	al	al	NNP
cord-276598-tm0yj2sn	574	4	.	.	NNP
cord-276598-tm0yj2sn	574	5	reported	report	VBD
cord-276598-tm0yj2sn	574	6	the	the	DT
cord-276598-tm0yj2sn	574	7	1,2-hydrophosphinylation	1,2-hydrophosphinylation	CD
cord-276598-tm0yj2sn	574	8	of	of	IN
cord-276598-tm0yj2sn	574	9	alkyl	alkyl	NN
cord-276598-tm0yj2sn	574	10	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	574	11	(	(	-LRB-
cord-276598-tm0yj2sn	574	12	R'-CN	R'-CN	NNS
cord-276598-tm0yj2sn	574	13	,	,	,
cord-276598-tm0yj2sn	574	14	R	r	NN
cord-276598-tm0yj2sn	574	15	'	'	''
cord-276598-tm0yj2sn	575	1	=	=	NFP
cord-276598-tm0yj2sn	575	2	alkyl	alkyl	NN
cord-276598-tm0yj2sn	575	3	,	,	,
cord-276598-tm0yj2sn	575	4	Ph	Ph	NNP
cord-276598-tm0yj2sn	575	5	,	,	,
cord-276598-tm0yj2sn	575	6	Bn	Bn	NNP
cord-276598-tm0yj2sn	575	7	)	)	-RRB-
cord-276598-tm0yj2sn	575	8	using	use	VBG
cord-276598-tm0yj2sn	575	9	sodium	sodium	NN
cord-276598-tm0yj2sn	575	10	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	575	11	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	575	12	(	(	-LRB-
cord-276598-tm0yj2sn	575	13	(	(	-LRB-
cord-276598-tm0yj2sn	575	14	RO	RO	NNP
cord-276598-tm0yj2sn	575	15	)	)	-RRB-
cord-276598-tm0yj2sn	576	1	2	2	CD
cord-276598-tm0yj2sn	576	2	PONa	PONa	NNS
cord-276598-tm0yj2sn	576	3	,	,	,
cord-276598-tm0yj2sn	576	4	R	r	NN
cord-276598-tm0yj2sn	576	5	=	=	FW
cord-276598-tm0yj2sn	576	6	Et	et	NN
cord-276598-tm0yj2sn	576	7	,	,	,
cord-276598-tm0yj2sn	576	8	Pr	Pr	NNP
cord-276598-tm0yj2sn	576	9	)	)	-RRB-
cord-276598-tm0yj2sn	577	1	to	to	TO
cord-276598-tm0yj2sn	577	2	achieve	achieve	VB
cord-276598-tm0yj2sn	577	3	the	the	DT
cord-276598-tm0yj2sn	577	4	formation	formation	NN
cord-276598-tm0yj2sn	577	5	of	of	IN
cord-276598-tm0yj2sn	577	6	a	a	DT
cord-276598-tm0yj2sn	577	7	P	P	NNP
cord-276598-tm0yj2sn	577	8	-	-	HYPH
cord-276598-tm0yj2sn	577	9	N	n	NN
cord-276598-tm0yj2sn	577	10	featuring	feature	VBG
cord-276598-tm0yj2sn	577	11	a	a	DT
cord-276598-tm0yj2sn	577	12	P	P	NNP
cord-276598-tm0yj2sn	577	13	-	-	HYPH
cord-276598-tm0yj2sn	577	14	C	C	NNP
cord-276598-tm0yj2sn	577	15	-	-	HYPH
cord-276598-tm0yj2sn	577	16	N	N	NNP
cord-276598-tm0yj2sn	577	17	-	-	HYPH
cord-276598-tm0yj2sn	577	18	P	p	NN
cord-276598-tm0yj2sn	577	19	linkage	linkage	NN
cord-276598-tm0yj2sn	577	20	in	in	IN
cord-276598-tm0yj2sn	577	21	which	which	WDT
cord-276598-tm0yj2sn	577	22	the	the	DT
cord-276598-tm0yj2sn	577	23	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	577	24	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	577	25	group	group	NNP
cord-276598-tm0yj2sn	577	26	of	of	IN
cord-276598-tm0yj2sn	577	27	(	(	-LRB-
cord-276598-tm0yj2sn	577	28	RO	RO	NNP
cord-276598-tm0yj2sn	577	29	)	)	-RRB-
cord-276598-tm0yj2sn	577	30	2	2	CD
cord-276598-tm0yj2sn	577	31	PONa	PONa	NNS
cord-276598-tm0yj2sn	577	32	was	be	VBD
cord-276598-tm0yj2sn	577	33	added	add	VBN
cord-276598-tm0yj2sn	577	34	to	to	IN
cord-276598-tm0yj2sn	577	35	the	the	DT
cord-276598-tm0yj2sn	577	36	carbon	carbon	NN
cord-276598-tm0yj2sn	577	37	and	and	CC
cord-276598-tm0yj2sn	577	38	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	577	39	atoms	atom	NNS
cord-276598-tm0yj2sn	577	40	of	of	IN
cord-276598-tm0yj2sn	577	41	the	the	DT
cord-276598-tm0yj2sn	577	42	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	577	43	(	(	-LRB-
cord-276598-tm0yj2sn	577	44	Scheme	scheme	NN
cord-276598-tm0yj2sn	577	45	16	16	CD
cord-276598-tm0yj2sn	577	46	)	)	-RRB-
cord-276598-tm0yj2sn	577	47	[	[	-LRB-
cord-276598-tm0yj2sn	577	48	120	120	CD
cord-276598-tm0yj2sn	577	49	]	]	-RRB-
cord-276598-tm0yj2sn	577	50	.	.	.
cord-276598-tm0yj2sn	578	1	Zimin	Zimin	NNP
cord-276598-tm0yj2sn	578	2	et	et	NNP
cord-276598-tm0yj2sn	578	3	al	al	NNP
cord-276598-tm0yj2sn	578	4	.	.	NNP
cord-276598-tm0yj2sn	578	5	reported	report	VBD
cord-276598-tm0yj2sn	578	6	the	the	DT
cord-276598-tm0yj2sn	578	7	1,2-hydrophosphinylation	1,2-hydrophosphinylation	CD
cord-276598-tm0yj2sn	578	8	of	of	IN
cord-276598-tm0yj2sn	578	9	alkyl	alkyl	NN
cord-276598-tm0yj2sn	578	10	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	578	11	(	(	-LRB-
cord-276598-tm0yj2sn	578	12	R'-CN	R'-CN	NNS
cord-276598-tm0yj2sn	578	13	,	,	,
cord-276598-tm0yj2sn	578	14	R	r	NN
cord-276598-tm0yj2sn	578	15	'	'	''
cord-276598-tm0yj2sn	579	1	=	=	NFP
cord-276598-tm0yj2sn	579	2	alkyl	alkyl	NN
cord-276598-tm0yj2sn	579	3	,	,	,
cord-276598-tm0yj2sn	579	4	Ph	Ph	NNP
cord-276598-tm0yj2sn	579	5	,	,	,
cord-276598-tm0yj2sn	579	6	Bn	Bn	NNP
cord-276598-tm0yj2sn	579	7	)	)	-RRB-
cord-276598-tm0yj2sn	579	8	using	use	VBG
cord-276598-tm0yj2sn	579	9	sodium	sodium	NN
cord-276598-tm0yj2sn	579	10	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	579	11	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	579	12	(	(	-LRB-
cord-276598-tm0yj2sn	579	13	(	(	-LRB-
cord-276598-tm0yj2sn	579	14	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	579	15	,	,	,
cord-276598-tm0yj2sn	579	16	R	r	NN
cord-276598-tm0yj2sn	579	17	=	=	FW
cord-276598-tm0yj2sn	579	18	Et	et	NN
cord-276598-tm0yj2sn	579	19	,	,	,
cord-276598-tm0yj2sn	579	20	Pr	Pr	NNP
cord-276598-tm0yj2sn	579	21	)	)	-RRB-
cord-276598-tm0yj2sn	579	22	to	to	TO
cord-276598-tm0yj2sn	579	23	achieve	achieve	VB
cord-276598-tm0yj2sn	579	24	the	the	DT
cord-276598-tm0yj2sn	579	25	formation	formation	NN
cord-276598-tm0yj2sn	579	26	of	of	IN
cord-276598-tm0yj2sn	579	27	a	a	DT
cord-276598-tm0yj2sn	579	28	P	P	NNP
cord-276598-tm0yj2sn	579	29	-	-	HYPH
cord-276598-tm0yj2sn	579	30	N	n	NN
cord-276598-tm0yj2sn	579	31	featuring	feature	VBG
cord-276598-tm0yj2sn	579	32	a	a	DT
cord-276598-tm0yj2sn	579	33	P	P	NNP
cord-276598-tm0yj2sn	579	34	-	-	HYPH
cord-276598-tm0yj2sn	579	35	C	C	NNP
cord-276598-tm0yj2sn	579	36	-	-	HYPH
cord-276598-tm0yj2sn	579	37	N	N	NNP
cord-276598-tm0yj2sn	579	38	-	-	HYPH
cord-276598-tm0yj2sn	579	39	P	p	NN
cord-276598-tm0yj2sn	579	40	linkage	linkage	NN
cord-276598-tm0yj2sn	579	41	in	in	IN
cord-276598-tm0yj2sn	579	42	which	which	WDT
cord-276598-tm0yj2sn	579	43	the	the	DT
cord-276598-tm0yj2sn	579	44	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	579	45	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	579	46	group	group	NNP
cord-276598-tm0yj2sn	579	47	of	of	IN
cord-276598-tm0yj2sn	579	48	(	(	-LRB-
cord-276598-tm0yj2sn	579	49	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	579	50	was	be	VBD
cord-276598-tm0yj2sn	579	51	added	add	VBN
cord-276598-tm0yj2sn	579	52	to	to	IN
cord-276598-tm0yj2sn	579	53	the	the	DT
cord-276598-tm0yj2sn	579	54	carbon	carbon	NN
cord-276598-tm0yj2sn	579	55	and	and	CC
cord-276598-tm0yj2sn	579	56	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	579	57	atoms	atom	NNS
cord-276598-tm0yj2sn	579	58	of	of	IN
cord-276598-tm0yj2sn	579	59	the	the	DT
cord-276598-tm0yj2sn	579	60	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	579	61	(	(	-LRB-
cord-276598-tm0yj2sn	579	62	Scheme	scheme	NN
cord-276598-tm0yj2sn	579	63	16	16	CD
cord-276598-tm0yj2sn	579	64	)	)	-RRB-
cord-276598-tm0yj2sn	579	65	[	[	-LRB-
cord-276598-tm0yj2sn	579	66	120	120	CD
cord-276598-tm0yj2sn	579	67	]	]	-RRB-
cord-276598-tm0yj2sn	579	68	.	.	.
cord-276598-tm0yj2sn	580	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	580	2	16	16	CD
cord-276598-tm0yj2sn	580	3	.	.	.
cord-276598-tm0yj2sn	581	1	A	a	DT
cord-276598-tm0yj2sn	581	2	1,2-hydrophosphinylation	1,2-hydrophosphinylation	CD
cord-276598-tm0yj2sn	581	3	of	of	IN
cord-276598-tm0yj2sn	581	4	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	581	5	to	to	TO
cord-276598-tm0yj2sn	581	6	form	form	VB
cord-276598-tm0yj2sn	581	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	581	8	.	.	.
cord-276598-tm0yj2sn	582	1	Chabour	Chabour	NNP
cord-276598-tm0yj2sn	582	2	et	et	FW
cord-276598-tm0yj2sn	582	3	al	al	NNP
cord-276598-tm0yj2sn	582	4	.	.	NNP
cord-276598-tm0yj2sn	582	5	reported	report	VBD
cord-276598-tm0yj2sn	582	6	a	a	DT
cord-276598-tm0yj2sn	582	7	diastereoselective	diastereoselective	NN
cord-276598-tm0yj2sn	582	8	P	P	NNP
cord-276598-tm0yj2sn	582	9	-	-	HYPH
cord-276598-tm0yj2sn	582	10	N	n	CD
cord-276598-tm0yj2sn	582	11	synthesis	synthesis	NN
cord-276598-tm0yj2sn	582	12	via	via	IN
cord-276598-tm0yj2sn	582	13	the	the	DT
cord-276598-tm0yj2sn	582	14	PAD	pad	NN
cord-276598-tm0yj2sn	582	15	process	process	NN
cord-276598-tm0yj2sn	582	16	using	use	VBG
cord-276598-tm0yj2sn	582	17	a	a	DT
cord-276598-tm0yj2sn	582	18	TsOH	TsOH	NNP
cord-276598-tm0yj2sn	582	19	acid	acid	NN
cord-276598-tm0yj2sn	582	20	catalyst	catalyst	NN
cord-276598-tm0yj2sn	582	21	and	and	CC
cord-276598-tm0yj2sn	582	22	a	a	DT
cord-276598-tm0yj2sn	582	23	dienophile	dienophile	NN
cord-276598-tm0yj2sn	582	24	,	,	,
cord-276598-tm0yj2sn	582	25	maleimide	maleimide	NNP
cord-276598-tm0yj2sn	582	26	(	(	-LRB-
cord-276598-tm0yj2sn	582	27	Scheme	scheme	NN
cord-276598-tm0yj2sn	582	28	17	17	CD
cord-276598-tm0yj2sn	582	29	)	)	-RRB-
cord-276598-tm0yj2sn	582	30	[	[	-LRB-
cord-276598-tm0yj2sn	582	31	1	1	CD
cord-276598-tm0yj2sn	582	32	]	]	-RRB-
cord-276598-tm0yj2sn	582	33	.	.	.
cord-276598-tm0yj2sn	583	1	Flash	flash	NN
cord-276598-tm0yj2sn	583	2	chromatography	chromatography	NN
cord-276598-tm0yj2sn	583	3	was	be	VBD
cord-276598-tm0yj2sn	583	4	used	use	VBN
cord-276598-tm0yj2sn	583	5	to	to	TO
cord-276598-tm0yj2sn	583	6	isolate	isolate	VB
cord-276598-tm0yj2sn	583	7	the	the	DT
cord-276598-tm0yj2sn	583	8	desired	desire	VBN
cord-276598-tm0yj2sn	583	9	product	product	NN
cord-276598-tm0yj2sn	583	10	in	in	IN
cord-276598-tm0yj2sn	583	11	40	40	CD
cord-276598-tm0yj2sn	583	12	-	-	SYM
cord-276598-tm0yj2sn	583	13	88	88	CD
cord-276598-tm0yj2sn	583	14	%	%	NN
cord-276598-tm0yj2sn	583	15	yield	yield	NN
cord-276598-tm0yj2sn	583	16	.	.	.
cord-276598-tm0yj2sn	584	1	The	the	DT
cord-276598-tm0yj2sn	584	2	scope	scope	NN
cord-276598-tm0yj2sn	584	3	of	of	IN
cord-276598-tm0yj2sn	584	4	the	the	DT
cord-276598-tm0yj2sn	584	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	584	6	was	be	VBD
cord-276598-tm0yj2sn	584	7	explored	explore	VBN
cord-276598-tm0yj2sn	584	8	with	with	IN
cord-276598-tm0yj2sn	584	9	maleimide	maleimide	NNP
cord-276598-tm0yj2sn	584	10	derivatives	derivative	NNS
cord-276598-tm0yj2sn	584	11	with	with	IN
cord-276598-tm0yj2sn	584	12	substituents	substituent	NNS
cord-276598-tm0yj2sn	584	13	such	such	JJ
cord-276598-tm0yj2sn	584	14	as	as	IN
cord-276598-tm0yj2sn	584	15	4-FC6H4CH2	4-fc6h4ch2	CD
cord-276598-tm0yj2sn	584	16	,	,	,
cord-276598-tm0yj2sn	584	17	C6H4CH2	c6h4ch2	CD
cord-276598-tm0yj2sn	584	18	,	,	,
cord-276598-tm0yj2sn	584	19	C6H4COCH3	C6H4COCH3	NNP
cord-276598-tm0yj2sn	584	20	,	,	,
cord-276598-tm0yj2sn	584	21	4-BrC6H4	4-brc6h4	CD
cord-276598-tm0yj2sn	584	22	,	,	,
cord-276598-tm0yj2sn	584	23	phenyl	phenyl	CD
cord-276598-tm0yj2sn	584	24	,	,	,
cord-276598-tm0yj2sn	584	25	and	and	CC
cord-276598-tm0yj2sn	584	26	methyl	methyl	NN
cord-276598-tm0yj2sn	584	27	.	.	.
cord-276598-tm0yj2sn	585	1	The	the	DT
cord-276598-tm0yj2sn	585	2	unsaturated	unsaturated	JJ
cord-276598-tm0yj2sn	585	3	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	585	4	derivatives	derivative	NNS
cord-276598-tm0yj2sn	585	5	that	that	WDT
cord-276598-tm0yj2sn	585	6	were	be	VBD
cord-276598-tm0yj2sn	585	7	used	use	VBN
cord-276598-tm0yj2sn	585	8	were	be	VBD
cord-276598-tm0yj2sn	585	9	3,7-dimethylocta-2,6-dienal	3,7-dimethylocta-2,6-dienal	JJ
cord-276598-tm0yj2sn	585	10	,	,	,
cord-276598-tm0yj2sn	585	11	3-methylbut-2-enal	3-methylbut-2-enal	CD
cord-276598-tm0yj2sn	585	12	,	,	,
cord-276598-tm0yj2sn	585	13	pent-2-enal	pent-2-enal	NNP
cord-276598-tm0yj2sn	585	14	,	,	,
cord-276598-tm0yj2sn	585	15	and	and	CC
cord-276598-tm0yj2sn	585	16	hex-2-enal	hex-2-enal	JJ
cord-276598-tm0yj2sn	585	17	.	.	.
cord-276598-tm0yj2sn	586	1	This	this	DT
cord-276598-tm0yj2sn	586	2	newest	new	JJS
cord-276598-tm0yj2sn	586	3	route	route	NN
cord-276598-tm0yj2sn	586	4	for	for	IN
cord-276598-tm0yj2sn	586	5	P	p	NN
cord-276598-tm0yj2sn	586	6	-	-	HYPH
cord-276598-tm0yj2sn	586	7	N	n	CD
cord-276598-tm0yj2sn	586	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	586	9	uses	use	VBZ
cord-276598-tm0yj2sn	586	10	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	586	11	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	586	12	,	,	,
cord-276598-tm0yj2sn	586	13	generates	generate	VBZ
cord-276598-tm0yj2sn	586	14	only	only	RB
cord-276598-tm0yj2sn	586	15	H2O	h2o	NN
cord-276598-tm0yj2sn	586	16	as	as	IN
cord-276598-tm0yj2sn	586	17	a	a	DT
cord-276598-tm0yj2sn	586	18	by	by	IN
cord-276598-tm0yj2sn	586	19	-	-	HYPH
cord-276598-tm0yj2sn	586	20	product	product	NN
cord-276598-tm0yj2sn	586	21	in	in	IN
cord-276598-tm0yj2sn	586	22	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	586	23	amounts	amount	NNS
cord-276598-tm0yj2sn	586	24	,	,	,
cord-276598-tm0yj2sn	586	25	and	and	CC
cord-276598-tm0yj2sn	586	26	demonstrates	demonstrate	VBZ
cord-276598-tm0yj2sn	586	27	an	an	DT
cord-276598-tm0yj2sn	586	28	important	important	JJ
cord-276598-tm0yj2sn	586	29	route	route	NN
cord-276598-tm0yj2sn	586	30	to	to	IN
cord-276598-tm0yj2sn	586	31	the	the	DT
cord-276598-tm0yj2sn	586	32	synthesis	synthesis	NN
cord-276598-tm0yj2sn	586	33	of	of	IN
cord-276598-tm0yj2sn	586	34	polyfunctionalized	polyfunctionalized	NNP
cord-276598-tm0yj2sn	586	35	P	P	NNP
cord-276598-tm0yj2sn	586	36	-	-	HYPH
cord-276598-tm0yj2sn	586	37	N	N	NNP
cord-276598-tm0yj2sn	586	38	compounds	compound	NNS
cord-276598-tm0yj2sn	586	39	.	.	.
cord-276598-tm0yj2sn	586	40	 	 	_SP
cord-276598-tm0yj2sn	587	1	Chabour	Chabour	NNP
cord-276598-tm0yj2sn	587	2	et	et	FW
cord-276598-tm0yj2sn	587	3	al	al	NNP
cord-276598-tm0yj2sn	587	4	.	.	NNP
cord-276598-tm0yj2sn	587	5	reported	report	VBD
cord-276598-tm0yj2sn	587	6	a	a	DT
cord-276598-tm0yj2sn	587	7	diastereoselective	diastereoselective	NN
cord-276598-tm0yj2sn	587	8	P	P	NNP
cord-276598-tm0yj2sn	587	9	-	-	HYPH
cord-276598-tm0yj2sn	587	10	N	n	CD
cord-276598-tm0yj2sn	587	11	synthesis	synthesis	NN
cord-276598-tm0yj2sn	587	12	via	via	IN
cord-276598-tm0yj2sn	587	13	the	the	DT
cord-276598-tm0yj2sn	587	14	PAD	pad	NN
cord-276598-tm0yj2sn	587	15	process	process	NN
cord-276598-tm0yj2sn	587	16	using	use	VBG
cord-276598-tm0yj2sn	587	17	a	a	DT
cord-276598-tm0yj2sn	587	18	TsOH	TsOH	NNP
cord-276598-tm0yj2sn	587	19	acid	acid	NN
cord-276598-tm0yj2sn	587	20	catalyst	catalyst	NN
cord-276598-tm0yj2sn	587	21	and	and	CC
cord-276598-tm0yj2sn	587	22	a	a	DT
cord-276598-tm0yj2sn	587	23	dienophile	dienophile	NN
cord-276598-tm0yj2sn	587	24	,	,	,
cord-276598-tm0yj2sn	587	25	maleimide	maleimide	NNP
cord-276598-tm0yj2sn	587	26	(	(	-LRB-
cord-276598-tm0yj2sn	587	27	Scheme	scheme	NN
cord-276598-tm0yj2sn	587	28	17	17	CD
cord-276598-tm0yj2sn	587	29	)	)	-RRB-
cord-276598-tm0yj2sn	587	30	[	[	-LRB-
cord-276598-tm0yj2sn	587	31	1	1	CD
cord-276598-tm0yj2sn	587	32	]	]	-RRB-
cord-276598-tm0yj2sn	587	33	.	.	.
cord-276598-tm0yj2sn	588	1	Flash	flash	NN
cord-276598-tm0yj2sn	588	2	chromatography	chromatography	NN
cord-276598-tm0yj2sn	588	3	was	be	VBD
cord-276598-tm0yj2sn	588	4	used	use	VBN
cord-276598-tm0yj2sn	588	5	to	to	TO
cord-276598-tm0yj2sn	588	6	isolate	isolate	VB
cord-276598-tm0yj2sn	588	7	the	the	DT
cord-276598-tm0yj2sn	588	8	desired	desire	VBN
cord-276598-tm0yj2sn	588	9	product	product	NN
cord-276598-tm0yj2sn	588	10	in	in	IN
cord-276598-tm0yj2sn	588	11	40	40	CD
cord-276598-tm0yj2sn	588	12	-	-	SYM
cord-276598-tm0yj2sn	588	13	88	88	CD
cord-276598-tm0yj2sn	588	14	%	%	NN
cord-276598-tm0yj2sn	588	15	yield	yield	NN
cord-276598-tm0yj2sn	588	16	.	.	.
cord-276598-tm0yj2sn	589	1	The	the	DT
cord-276598-tm0yj2sn	589	2	scope	scope	NN
cord-276598-tm0yj2sn	589	3	of	of	IN
cord-276598-tm0yj2sn	589	4	the	the	DT
cord-276598-tm0yj2sn	589	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	589	6	was	be	VBD
cord-276598-tm0yj2sn	589	7	explored	explore	VBN
cord-276598-tm0yj2sn	589	8	with	with	IN
cord-276598-tm0yj2sn	589	9	maleimide	maleimide	NNP
cord-276598-tm0yj2sn	589	10	derivatives	derivative	NNS
cord-276598-tm0yj2sn	589	11	with	with	IN
cord-276598-tm0yj2sn	589	12	substituents	substituent	NNS
cord-276598-tm0yj2sn	589	13	such	such	JJ
cord-276598-tm0yj2sn	589	14	as	as	IN
cord-276598-tm0yj2sn	589	15	4-FC	4-fc	CD
cord-276598-tm0yj2sn	589	16	6	6	CD
cord-276598-tm0yj2sn	589	17	H	h	NN
cord-276598-tm0yj2sn	589	18	4	4	CD
cord-276598-tm0yj2sn	589	19	CH	CH	NNP
cord-276598-tm0yj2sn	589	20	2	2	CD
cord-276598-tm0yj2sn	589	21	,	,	,
cord-276598-tm0yj2sn	589	22	C	C	NNP
cord-276598-tm0yj2sn	589	23	6	6	CD
cord-276598-tm0yj2sn	589	24	H	h	NN
cord-276598-tm0yj2sn	589	25	4	4	CD
cord-276598-tm0yj2sn	589	26	CH	CH	NNP
cord-276598-tm0yj2sn	589	27	2	2	CD
cord-276598-tm0yj2sn	589	28	,	,	,
cord-276598-tm0yj2sn	589	29	C	C	NNP
cord-276598-tm0yj2sn	589	30	6	6	CD
cord-276598-tm0yj2sn	589	31	H	h	NN
cord-276598-tm0yj2sn	589	32	4	4	CD
cord-276598-tm0yj2sn	589	33	COCH	COCH	NNP
cord-276598-tm0yj2sn	589	34	3	3	CD
cord-276598-tm0yj2sn	589	35	,	,	,
cord-276598-tm0yj2sn	589	36	4-BrC	4-brc	CD
cord-276598-tm0yj2sn	589	37	6	6	CD
cord-276598-tm0yj2sn	589	38	H	h	NN
cord-276598-tm0yj2sn	589	39	4	4	CD
cord-276598-tm0yj2sn	589	40	,	,	,
cord-276598-tm0yj2sn	589	41	phenyl	phenyl	NN
cord-276598-tm0yj2sn	589	42	,	,	,
cord-276598-tm0yj2sn	589	43	and	and	CC
cord-276598-tm0yj2sn	589	44	methyl	methyl	NN
cord-276598-tm0yj2sn	589	45	.	.	.
cord-276598-tm0yj2sn	590	1	The	the	DT
cord-276598-tm0yj2sn	590	2	unsaturated	unsaturated	JJ
cord-276598-tm0yj2sn	590	3	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	590	4	derivatives	derivative	NNS
cord-276598-tm0yj2sn	590	5	that	that	WDT
cord-276598-tm0yj2sn	590	6	were	be	VBD
cord-276598-tm0yj2sn	590	7	used	use	VBN
cord-276598-tm0yj2sn	590	8	were	be	VBD
cord-276598-tm0yj2sn	590	9	3,7-dimethylocta-2,6-dienal	3,7-dimethylocta-2,6-dienal	JJ
cord-276598-tm0yj2sn	590	10	,	,	,
cord-276598-tm0yj2sn	590	11	3-methylbut-2-enal	3-methylbut-2-enal	CD
cord-276598-tm0yj2sn	590	12	,	,	,
cord-276598-tm0yj2sn	590	13	pent-2-enal	pent-2-enal	NNP
cord-276598-tm0yj2sn	590	14	,	,	,
cord-276598-tm0yj2sn	590	15	and	and	CC
cord-276598-tm0yj2sn	590	16	hex-2-enal	hex-2-enal	JJ
cord-276598-tm0yj2sn	590	17	.	.	.
cord-276598-tm0yj2sn	591	1	This	this	DT
cord-276598-tm0yj2sn	591	2	newest	new	JJS
cord-276598-tm0yj2sn	591	3	route	route	NN
cord-276598-tm0yj2sn	591	4	for	for	IN
cord-276598-tm0yj2sn	591	5	P	p	NN
cord-276598-tm0yj2sn	591	6	-	-	HYPH
cord-276598-tm0yj2sn	591	7	N	n	CD
cord-276598-tm0yj2sn	591	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	591	9	uses	use	VBZ
cord-276598-tm0yj2sn	591	10	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	591	11	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	591	12	,	,	,
cord-276598-tm0yj2sn	591	13	generates	generate	VBZ
cord-276598-tm0yj2sn	591	14	only	only	RB
cord-276598-tm0yj2sn	591	15	H	h	NN
cord-276598-tm0yj2sn	591	16	2	2	CD
cord-276598-tm0yj2sn	591	17	O	o	NN
cord-276598-tm0yj2sn	591	18	as	as	IN
cord-276598-tm0yj2sn	591	19	a	a	DT
cord-276598-tm0yj2sn	591	20	by	by	IN
cord-276598-tm0yj2sn	591	21	-	-	HYPH
cord-276598-tm0yj2sn	591	22	product	product	NN
cord-276598-tm0yj2sn	591	23	in	in	IN
cord-276598-tm0yj2sn	591	24	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	591	25	amounts	amount	NNS
cord-276598-tm0yj2sn	591	26	,	,	,
cord-276598-tm0yj2sn	591	27	and	and	CC
cord-276598-tm0yj2sn	591	28	demonstrates	demonstrate	VBZ
cord-276598-tm0yj2sn	591	29	an	an	DT
cord-276598-tm0yj2sn	591	30	important	important	JJ
cord-276598-tm0yj2sn	591	31	route	route	NN
cord-276598-tm0yj2sn	591	32	to	to	IN
cord-276598-tm0yj2sn	591	33	the	the	DT
cord-276598-tm0yj2sn	591	34	synthesis	synthesis	NN
cord-276598-tm0yj2sn	591	35	of	of	IN
cord-276598-tm0yj2sn	591	36	polyfunctionalized	polyfunctionalized	NNP
cord-276598-tm0yj2sn	591	37	P	P	NNP
cord-276598-tm0yj2sn	591	38	-	-	HYPH
cord-276598-tm0yj2sn	591	39	N	N	NNP
cord-276598-tm0yj2sn	591	40	compounds	compound	NNS
cord-276598-tm0yj2sn	591	41	.	.	.
cord-276598-tm0yj2sn	592	1	Zimin	Zimin	NNP
cord-276598-tm0yj2sn	592	2	et	et	NNP
cord-276598-tm0yj2sn	592	3	al	al	NNP
cord-276598-tm0yj2sn	592	4	.	.	NNP
cord-276598-tm0yj2sn	592	5	reported	report	VBD
cord-276598-tm0yj2sn	592	6	the	the	DT
cord-276598-tm0yj2sn	592	7	1,2-hydrophosphinylation	1,2-hydrophosphinylation	CD
cord-276598-tm0yj2sn	592	8	of	of	IN
cord-276598-tm0yj2sn	592	9	alkyl	alkyl	NN
cord-276598-tm0yj2sn	592	10	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	592	11	(	(	-LRB-
cord-276598-tm0yj2sn	592	12	R'-CN	R'-CN	NNS
cord-276598-tm0yj2sn	592	13	,	,	,
cord-276598-tm0yj2sn	592	14	R	r	NN
cord-276598-tm0yj2sn	592	15	'	'	''
cord-276598-tm0yj2sn	593	1	=	=	NFP
cord-276598-tm0yj2sn	593	2	alkyl	alkyl	NN
cord-276598-tm0yj2sn	593	3	,	,	,
cord-276598-tm0yj2sn	593	4	Ph	Ph	NNP
cord-276598-tm0yj2sn	593	5	,	,	,
cord-276598-tm0yj2sn	593	6	Bn	Bn	NNP
cord-276598-tm0yj2sn	593	7	)	)	-RRB-
cord-276598-tm0yj2sn	593	8	using	use	VBG
cord-276598-tm0yj2sn	593	9	sodium	sodium	NN
cord-276598-tm0yj2sn	593	10	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	593	11	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	593	12	(	(	-LRB-
cord-276598-tm0yj2sn	593	13	(	(	-LRB-
cord-276598-tm0yj2sn	593	14	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	593	15	,	,	,
cord-276598-tm0yj2sn	593	16	R	r	NN
cord-276598-tm0yj2sn	593	17	=	=	FW
cord-276598-tm0yj2sn	593	18	Et	et	NN
cord-276598-tm0yj2sn	593	19	,	,	,
cord-276598-tm0yj2sn	593	20	Pr	Pr	NNP
cord-276598-tm0yj2sn	593	21	)	)	-RRB-
cord-276598-tm0yj2sn	593	22	to	to	TO
cord-276598-tm0yj2sn	593	23	achieve	achieve	VB
cord-276598-tm0yj2sn	593	24	the	the	DT
cord-276598-tm0yj2sn	593	25	formation	formation	NN
cord-276598-tm0yj2sn	593	26	of	of	IN
cord-276598-tm0yj2sn	593	27	a	a	DT
cord-276598-tm0yj2sn	593	28	P	P	NNP
cord-276598-tm0yj2sn	593	29	-	-	HYPH
cord-276598-tm0yj2sn	593	30	N	n	NN
cord-276598-tm0yj2sn	593	31	featuring	feature	VBG
cord-276598-tm0yj2sn	593	32	a	a	DT
cord-276598-tm0yj2sn	593	33	P	P	NNP
cord-276598-tm0yj2sn	593	34	-	-	HYPH
cord-276598-tm0yj2sn	593	35	C	C	NNP
cord-276598-tm0yj2sn	593	36	-	-	HYPH
cord-276598-tm0yj2sn	593	37	N	N	NNP
cord-276598-tm0yj2sn	593	38	-	-	HYPH
cord-276598-tm0yj2sn	593	39	P	p	NN
cord-276598-tm0yj2sn	593	40	linkage	linkage	NN
cord-276598-tm0yj2sn	593	41	in	in	IN
cord-276598-tm0yj2sn	593	42	which	which	WDT
cord-276598-tm0yj2sn	593	43	the	the	DT
cord-276598-tm0yj2sn	593	44	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	593	45	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	593	46	group	group	NNP
cord-276598-tm0yj2sn	593	47	of	of	IN
cord-276598-tm0yj2sn	593	48	(	(	-LRB-
cord-276598-tm0yj2sn	593	49	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	593	50	was	be	VBD
cord-276598-tm0yj2sn	593	51	added	add	VBN
cord-276598-tm0yj2sn	593	52	to	to	IN
cord-276598-tm0yj2sn	593	53	the	the	DT
cord-276598-tm0yj2sn	593	54	carbon	carbon	NN
cord-276598-tm0yj2sn	593	55	and	and	CC
cord-276598-tm0yj2sn	593	56	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	593	57	atoms	atom	NNS
cord-276598-tm0yj2sn	593	58	of	of	IN
cord-276598-tm0yj2sn	593	59	the	the	DT
cord-276598-tm0yj2sn	593	60	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	593	61	(	(	-LRB-
cord-276598-tm0yj2sn	593	62	Scheme	scheme	NN
cord-276598-tm0yj2sn	593	63	16	16	CD
cord-276598-tm0yj2sn	593	64	)	)	-RRB-
cord-276598-tm0yj2sn	593	65	[	[	-LRB-
cord-276598-tm0yj2sn	593	66	120	120	CD
cord-276598-tm0yj2sn	593	67	]	]	-RRB-
cord-276598-tm0yj2sn	593	68	.	.	.
cord-276598-tm0yj2sn	594	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	594	2	16	16	CD
cord-276598-tm0yj2sn	594	3	.	.	.
cord-276598-tm0yj2sn	595	1	A	a	DT
cord-276598-tm0yj2sn	595	2	1,2-hydrophosphinylation	1,2-hydrophosphinylation	CD
cord-276598-tm0yj2sn	595	3	of	of	IN
cord-276598-tm0yj2sn	595	4	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	595	5	to	to	TO
cord-276598-tm0yj2sn	595	6	form	form	VB
cord-276598-tm0yj2sn	595	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	595	8	.	.	.
cord-276598-tm0yj2sn	596	1	Chabour	Chabour	NNP
cord-276598-tm0yj2sn	596	2	et	et	FW
cord-276598-tm0yj2sn	596	3	al	al	NNP
cord-276598-tm0yj2sn	596	4	.	.	NNP
cord-276598-tm0yj2sn	596	5	reported	report	VBD
cord-276598-tm0yj2sn	596	6	a	a	DT
cord-276598-tm0yj2sn	596	7	diastereoselective	diastereoselective	NN
cord-276598-tm0yj2sn	596	8	P	P	NNP
cord-276598-tm0yj2sn	596	9	-	-	HYPH
cord-276598-tm0yj2sn	596	10	N	n	CD
cord-276598-tm0yj2sn	596	11	synthesis	synthesis	NN
cord-276598-tm0yj2sn	596	12	via	via	IN
cord-276598-tm0yj2sn	596	13	the	the	DT
cord-276598-tm0yj2sn	596	14	PAD	pad	NN
cord-276598-tm0yj2sn	596	15	process	process	NN
cord-276598-tm0yj2sn	596	16	using	use	VBG
cord-276598-tm0yj2sn	596	17	a	a	DT
cord-276598-tm0yj2sn	596	18	TsOH	TsOH	NNP
cord-276598-tm0yj2sn	596	19	acid	acid	NN
cord-276598-tm0yj2sn	596	20	catalyst	catalyst	NN
cord-276598-tm0yj2sn	596	21	and	and	CC
cord-276598-tm0yj2sn	596	22	a	a	DT
cord-276598-tm0yj2sn	596	23	dienophile	dienophile	NN
cord-276598-tm0yj2sn	596	24	,	,	,
cord-276598-tm0yj2sn	596	25	maleimide	maleimide	NNP
cord-276598-tm0yj2sn	596	26	(	(	-LRB-
cord-276598-tm0yj2sn	596	27	Scheme	scheme	NN
cord-276598-tm0yj2sn	596	28	17	17	CD
cord-276598-tm0yj2sn	596	29	)	)	-RRB-
cord-276598-tm0yj2sn	596	30	[	[	-LRB-
cord-276598-tm0yj2sn	596	31	1	1	CD
cord-276598-tm0yj2sn	596	32	]	]	-RRB-
cord-276598-tm0yj2sn	596	33	.	.	.
cord-276598-tm0yj2sn	597	1	Flash	flash	NN
cord-276598-tm0yj2sn	597	2	chromatography	chromatography	NN
cord-276598-tm0yj2sn	597	3	was	be	VBD
cord-276598-tm0yj2sn	597	4	used	use	VBN
cord-276598-tm0yj2sn	597	5	to	to	TO
cord-276598-tm0yj2sn	597	6	isolate	isolate	VB
cord-276598-tm0yj2sn	597	7	the	the	DT
cord-276598-tm0yj2sn	597	8	desired	desire	VBN
cord-276598-tm0yj2sn	597	9	product	product	NN
cord-276598-tm0yj2sn	597	10	in	in	IN
cord-276598-tm0yj2sn	597	11	40	40	CD
cord-276598-tm0yj2sn	597	12	-	-	SYM
cord-276598-tm0yj2sn	597	13	88	88	CD
cord-276598-tm0yj2sn	597	14	%	%	NN
cord-276598-tm0yj2sn	597	15	yield	yield	NN
cord-276598-tm0yj2sn	597	16	.	.	.
cord-276598-tm0yj2sn	598	1	The	the	DT
cord-276598-tm0yj2sn	598	2	scope	scope	NN
cord-276598-tm0yj2sn	598	3	of	of	IN
cord-276598-tm0yj2sn	598	4	the	the	DT
cord-276598-tm0yj2sn	598	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	598	6	was	be	VBD
cord-276598-tm0yj2sn	598	7	explored	explore	VBN
cord-276598-tm0yj2sn	598	8	with	with	IN
cord-276598-tm0yj2sn	598	9	maleimide	maleimide	NNP
cord-276598-tm0yj2sn	598	10	derivatives	derivative	NNS
cord-276598-tm0yj2sn	598	11	with	with	IN
cord-276598-tm0yj2sn	598	12	substituents	substituent	NNS
cord-276598-tm0yj2sn	598	13	such	such	JJ
cord-276598-tm0yj2sn	598	14	as	as	IN
cord-276598-tm0yj2sn	598	15	4-FC6H4CH2	4-fc6h4ch2	CD
cord-276598-tm0yj2sn	598	16	,	,	,
cord-276598-tm0yj2sn	598	17	C6H4CH2	c6h4ch2	CD
cord-276598-tm0yj2sn	598	18	,	,	,
cord-276598-tm0yj2sn	598	19	C6H4COCH3	C6H4COCH3	NNP
cord-276598-tm0yj2sn	598	20	,	,	,
cord-276598-tm0yj2sn	598	21	4-BrC6H4	4-brc6h4	CD
cord-276598-tm0yj2sn	598	22	,	,	,
cord-276598-tm0yj2sn	598	23	phenyl	phenyl	CD
cord-276598-tm0yj2sn	598	24	,	,	,
cord-276598-tm0yj2sn	598	25	and	and	CC
cord-276598-tm0yj2sn	598	26	methyl	methyl	NN
cord-276598-tm0yj2sn	598	27	.	.	.
cord-276598-tm0yj2sn	599	1	The	the	DT
cord-276598-tm0yj2sn	599	2	unsaturated	unsaturated	JJ
cord-276598-tm0yj2sn	599	3	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	599	4	derivatives	derivative	NNS
cord-276598-tm0yj2sn	599	5	that	that	WDT
cord-276598-tm0yj2sn	599	6	were	be	VBD
cord-276598-tm0yj2sn	599	7	used	use	VBN
cord-276598-tm0yj2sn	599	8	were	be	VBD
cord-276598-tm0yj2sn	599	9	3,7-dimethylocta-2,6-dienal	3,7-dimethylocta-2,6-dienal	JJ
cord-276598-tm0yj2sn	599	10	,	,	,
cord-276598-tm0yj2sn	599	11	3-methylbut-2-enal	3-methylbut-2-enal	CD
cord-276598-tm0yj2sn	599	12	,	,	,
cord-276598-tm0yj2sn	599	13	pent-2-enal	pent-2-enal	NNP
cord-276598-tm0yj2sn	599	14	,	,	,
cord-276598-tm0yj2sn	599	15	and	and	CC
cord-276598-tm0yj2sn	599	16	hex-2-enal	hex-2-enal	JJ
cord-276598-tm0yj2sn	599	17	.	.	.
cord-276598-tm0yj2sn	600	1	This	this	DT
cord-276598-tm0yj2sn	600	2	newest	new	JJS
cord-276598-tm0yj2sn	600	3	route	route	NN
cord-276598-tm0yj2sn	600	4	for	for	IN
cord-276598-tm0yj2sn	600	5	P	p	NN
cord-276598-tm0yj2sn	600	6	-	-	HYPH
cord-276598-tm0yj2sn	600	7	N	n	CD
cord-276598-tm0yj2sn	600	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	600	9	uses	use	VBZ
cord-276598-tm0yj2sn	600	10	inexpensive	inexpensive	JJ
cord-276598-tm0yj2sn	600	11	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	600	12	,	,	,
cord-276598-tm0yj2sn	600	13	generates	generate	VBZ
cord-276598-tm0yj2sn	600	14	only	only	RB
cord-276598-tm0yj2sn	600	15	H2O	h2o	NN
cord-276598-tm0yj2sn	600	16	as	as	IN
cord-276598-tm0yj2sn	600	17	a	a	DT
cord-276598-tm0yj2sn	600	18	by	by	IN
cord-276598-tm0yj2sn	600	19	-	-	HYPH
cord-276598-tm0yj2sn	600	20	product	product	NN
cord-276598-tm0yj2sn	600	21	in	in	IN
cord-276598-tm0yj2sn	600	22	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	600	23	amounts	amount	NNS
cord-276598-tm0yj2sn	600	24	,	,	,
cord-276598-tm0yj2sn	600	25	and	and	CC
cord-276598-tm0yj2sn	600	26	demonstrates	demonstrate	VBZ
cord-276598-tm0yj2sn	600	27	an	an	DT
cord-276598-tm0yj2sn	600	28	important	important	JJ
cord-276598-tm0yj2sn	600	29	route	route	NN
cord-276598-tm0yj2sn	600	30	to	to	IN
cord-276598-tm0yj2sn	600	31	the	the	DT
cord-276598-tm0yj2sn	600	32	synthesis	synthesis	NN
cord-276598-tm0yj2sn	600	33	of	of	IN
cord-276598-tm0yj2sn	600	34	polyfunctionalized	polyfunctionalized	NNP
cord-276598-tm0yj2sn	600	35	P	P	NNP
cord-276598-tm0yj2sn	600	36	-	-	HYPH
cord-276598-tm0yj2sn	600	37	N	N	NNP
cord-276598-tm0yj2sn	600	38	compounds	compound	NNS
cord-276598-tm0yj2sn	600	39	.	.	.
cord-276598-tm0yj2sn	600	40	 	 	_SP
cord-276598-tm0yj2sn	601	1	A	a	DT
cord-276598-tm0yj2sn	601	2	wealth	wealth	NN
cord-276598-tm0yj2sn	601	3	of	of	IN
cord-276598-tm0yj2sn	601	4	information	information	NN
cord-276598-tm0yj2sn	601	5	on	on	IN
cord-276598-tm0yj2sn	601	6	the	the	DT
cord-276598-tm0yj2sn	601	7	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	601	8	for	for	IN
cord-276598-tm0yj2sn	601	9	the	the	DT
cord-276598-tm0yj2sn	601	10	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	601	11	routes	route	NNS
cord-276598-tm0yj2sn	601	12	to	to	IN
cord-276598-tm0yj2sn	601	13	P	p	NN
cord-276598-tm0yj2sn	601	14	-	-	HYPH
cord-276598-tm0yj2sn	601	15	Ns	Ns	NNP
cord-276598-tm0yj2sn	601	16	is	be	VBZ
cord-276598-tm0yj2sn	601	17	available	available	JJ
cord-276598-tm0yj2sn	601	18	.	.	.
cord-276598-tm0yj2sn	602	1	For	for	IN
cord-276598-tm0yj2sn	602	2	each	each	DT
cord-276598-tm0yj2sn	602	3	of	of	IN
cord-276598-tm0yj2sn	602	4	the	the	DT
cord-276598-tm0yj2sn	602	5	main	main	JJ
cord-276598-tm0yj2sn	602	6	categories	category	NNS
cord-276598-tm0yj2sn	602	7	highlighted	highlight	VBN
cord-276598-tm0yj2sn	602	8	above	above	RB
cord-276598-tm0yj2sn	602	9	,	,	,
cord-276598-tm0yj2sn	602	10	researchers	researcher	NNS
cord-276598-tm0yj2sn	602	11	have	have	VBP
cord-276598-tm0yj2sn	602	12	provided	provide	VBN
cord-276598-tm0yj2sn	602	13	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	602	14	insight	insight	NN
cord-276598-tm0yj2sn	602	15	into	into	IN
cord-276598-tm0yj2sn	602	16	the	the	DT
cord-276598-tm0yj2sn	602	17	reaction	reaction	NN
cord-276598-tm0yj2sn	602	18	by	by	IN
cord-276598-tm0yj2sn	602	19	determining	determine	VBG
cord-276598-tm0yj2sn	602	20	the	the	DT
cord-276598-tm0yj2sn	602	21	main	main	JJ
cord-276598-tm0yj2sn	602	22	sources	source	NNS
cord-276598-tm0yj2sn	602	23	of	of	IN
cord-276598-tm0yj2sn	602	24	oxidation	oxidation	NN
cord-276598-tm0yj2sn	602	25	as	as	RB
cord-276598-tm0yj2sn	602	26	well	well	RB
cord-276598-tm0yj2sn	602	27	as	as	IN
cord-276598-tm0yj2sn	602	28	electronic	electronic	JJ
cord-276598-tm0yj2sn	602	29	and	and	CC
cord-276598-tm0yj2sn	602	30	steric	steric	JJ
cord-276598-tm0yj2sn	602	31	factors	factor	NNS
cord-276598-tm0yj2sn	602	32	provided	provide	VBN
cord-276598-tm0yj2sn	602	33	from	from	IN
cord-276598-tm0yj2sn	602	34	the	the	DT
cord-276598-tm0yj2sn	602	35	substituents	substituent	NNS
cord-276598-tm0yj2sn	602	36	that	that	WDT
cord-276598-tm0yj2sn	602	37	influence	influence	VBP
cord-276598-tm0yj2sn	602	38	the	the	DT
cord-276598-tm0yj2sn	602	39	reaction	reaction	NN
cord-276598-tm0yj2sn	602	40	rate	rate	NN
cord-276598-tm0yj2sn	602	41	.	.	.
cord-276598-tm0yj2sn	603	1	Several	several	JJ
cord-276598-tm0yj2sn	603	2	examples	example	NNS
cord-276598-tm0yj2sn	603	3	of	of	IN
cord-276598-tm0yj2sn	603	4	postulated	postulate	VBN
cord-276598-tm0yj2sn	603	5	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	603	6	cycles	cycle	NNS
cord-276598-tm0yj2sn	603	7	will	will	MD
cord-276598-tm0yj2sn	603	8	be	be	VB
cord-276598-tm0yj2sn	603	9	provided	provide	VBN
cord-276598-tm0yj2sn	603	10	below	below	RB
cord-276598-tm0yj2sn	603	11	,	,	,
cord-276598-tm0yj2sn	603	12	illustrating	illustrate	VBG
cord-276598-tm0yj2sn	603	13	the	the	DT
cord-276598-tm0yj2sn	603	14	key	key	JJ
cord-276598-tm0yj2sn	603	15	steps	step	NNS
cord-276598-tm0yj2sn	603	16	,	,	,
cord-276598-tm0yj2sn	603	17	similarities	similarity	NNS
cord-276598-tm0yj2sn	603	18	,	,	,
cord-276598-tm0yj2sn	603	19	and	and	CC
cord-276598-tm0yj2sn	603	20	differences	difference	NNS
cord-276598-tm0yj2sn	603	21	between	between	IN
cord-276598-tm0yj2sn	603	22	them	-PRON-	PRP
cord-276598-tm0yj2sn	603	23	.	.	.
cord-276598-tm0yj2sn	604	1	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	604	2	,	,	,
cord-276598-tm0yj2sn	604	3	Openshaw	Openshaw	NNP
cord-276598-tm0yj2sn	604	4	and	and	CC
cord-276598-tm0yj2sn	604	5	Todd	Todd	NNP
cord-276598-tm0yj2sn	604	6	suggested	suggest	VBD
cord-276598-tm0yj2sn	604	7	that	that	IN
cord-276598-tm0yj2sn	604	8	the	the	DT
cord-276598-tm0yj2sn	604	9	two	two	CD
cord-276598-tm0yj2sn	604	10	-	-	HYPH
cord-276598-tm0yj2sn	604	11	step	step	NN
cord-276598-tm0yj2sn	604	12	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	604	13	process	process	NN
cord-276598-tm0yj2sn	604	14	for	for	IN
cord-276598-tm0yj2sn	604	15	the	the	DT
cord-276598-tm0yj2sn	604	16	salt	salt	NN
cord-276598-tm0yj2sn	604	17	elimination	elimination	NN
cord-276598-tm0yj2sn	604	18	could	could	MD
cord-276598-tm0yj2sn	604	19	involve	involve	VB
cord-276598-tm0yj2sn	604	20	the	the	DT
cord-276598-tm0yj2sn	604	21	formation	formation	NN
cord-276598-tm0yj2sn	604	22	of	of	IN
cord-276598-tm0yj2sn	604	23	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	604	24	or	or	CC
cord-276598-tm0yj2sn	604	25	dibenzyl	dibenzyl	NNP
cord-276598-tm0yj2sn	604	26	(	(	-LRB-
cord-276598-tm0yj2sn	604	27	trichloromethyl)phosphonate	trichloromethyl)phosphonate	NNP
cord-276598-tm0yj2sn	604	28	in	in	IN
cord-276598-tm0yj2sn	604	29	the	the	DT
cord-276598-tm0yj2sn	604	30	first	first	JJ
cord-276598-tm0yj2sn	604	31	step	step	NN
cord-276598-tm0yj2sn	604	32	,	,	,
cord-276598-tm0yj2sn	604	33	from	from	IN
cord-276598-tm0yj2sn	604	34	a	a	DT
cord-276598-tm0yj2sn	604	35	reaction	reaction	NN
cord-276598-tm0yj2sn	604	36	of	of	IN
cord-276598-tm0yj2sn	604	37	(	(	-LRB-
cord-276598-tm0yj2sn	604	38	RO	ro	NN
cord-276598-tm0yj2sn	604	39	)	)	-RRB-
cord-276598-tm0yj2sn	604	40	2	2	CD
cord-276598-tm0yj2sn	604	41	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	604	42	(	(	-LRB-
cord-276598-tm0yj2sn	604	43	H	H	NNP
cord-276598-tm0yj2sn	604	44	-	-	HYPH
cord-276598-tm0yj2sn	604	45	P	p	NN
cord-276598-tm0yj2sn	604	46	;	;	:
cord-276598-tm0yj2sn	604	47	R	r	NN
cord-276598-tm0yj2sn	604	48	=	=	NN
cord-276598-tm0yj2sn	604	49	alkyl	alkyl	NN
cord-276598-tm0yj2sn	604	50	)	)	-RRB-
cord-276598-tm0yj2sn	604	51	and	and	CC
cord-276598-tm0yj2sn	604	52	CCl	CCl	NNS
cord-276598-tm0yj2sn	604	53	4	4	CD
cord-276598-tm0yj2sn	604	54	in	in	IN
cord-276598-tm0yj2sn	604	55	the	the	DT
cord-276598-tm0yj2sn	604	56	presence	presence	NN
cord-276598-tm0yj2sn	604	57	of	of	IN
cord-276598-tm0yj2sn	604	58	Et	Et	NNP
cord-276598-tm0yj2sn	604	59	3	3	CD
cord-276598-tm0yj2sn	604	60	N	N	NNP
cord-276598-tm0yj2sn	604	61	[	[	-LRB-
cord-276598-tm0yj2sn	604	62	78	78	CD
cord-276598-tm0yj2sn	604	63	]	]	-RRB-
cord-276598-tm0yj2sn	604	64	.	.	.
cord-276598-tm0yj2sn	605	1	The	the	DT
cord-276598-tm0yj2sn	605	2	desired	desire	VBN
cord-276598-tm0yj2sn	605	3	product	product	NN
cord-276598-tm0yj2sn	605	4	is	be	VBZ
cord-276598-tm0yj2sn	605	5	formed	form	VBN
cord-276598-tm0yj2sn	605	6	in	in	IN
cord-276598-tm0yj2sn	605	7	the	the	DT
cord-276598-tm0yj2sn	605	8	second	second	JJ
cord-276598-tm0yj2sn	605	9	step	step	NN
cord-276598-tm0yj2sn	606	1	when	when	WRB
cord-276598-tm0yj2sn	606	2	the	the	DT
cord-276598-tm0yj2sn	606	3	(	(	-LRB-
cord-276598-tm0yj2sn	606	4	trichloromethyl)phosphonate	trichloromethyl)phosphonate	NNP
cord-276598-tm0yj2sn	606	5	reacts	react	NNS
cord-276598-tm0yj2sn	606	6	with	with	IN
cord-276598-tm0yj2sn	606	7	amine	amine	NN
cord-276598-tm0yj2sn	606	8	,	,	,
cord-276598-tm0yj2sn	606	9	forming	form	VBG
cord-276598-tm0yj2sn	606	10	also	also	RB
cord-276598-tm0yj2sn	606	11	CHCl	CHCl	VBZ
cord-276598-tm0yj2sn	606	12	3	3	CD
cord-276598-tm0yj2sn	606	13	in	in	IN
cord-276598-tm0yj2sn	606	14	the	the	DT
cord-276598-tm0yj2sn	606	15	process	process	NN
cord-276598-tm0yj2sn	606	16	(	(	-LRB-
cord-276598-tm0yj2sn	606	17	Scheme	scheme	NN
cord-276598-tm0yj2sn	606	18	18	18	CD
cord-276598-tm0yj2sn	606	19	)	)	-RRB-
cord-276598-tm0yj2sn	606	20	.	.	.
cord-276598-tm0yj2sn	607	1	Although	although	IN
cord-276598-tm0yj2sn	607	2	this	this	DT
cord-276598-tm0yj2sn	607	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	607	4	is	be	VBZ
cord-276598-tm0yj2sn	607	5	plausible	plausible	JJ
cord-276598-tm0yj2sn	607	6	,	,	,
cord-276598-tm0yj2sn	607	7	evidence	evidence	NN
cord-276598-tm0yj2sn	607	8	by	by	IN
cord-276598-tm0yj2sn	607	9	NMR	NMR	NNP
cord-276598-tm0yj2sn	607	10	spectroscopy	spectroscopy	NN
cord-276598-tm0yj2sn	607	11	suggests	suggest	VBZ
cord-276598-tm0yj2sn	607	12	that	that	IN
cord-276598-tm0yj2sn	607	13	in	in	IN
cord-276598-tm0yj2sn	607	14	the	the	DT
cord-276598-tm0yj2sn	607	15	first	first	JJ
cord-276598-tm0yj2sn	607	16	step	step	NN
cord-276598-tm0yj2sn	607	17	,	,	,
cord-276598-tm0yj2sn	607	18	a	a	DT
cord-276598-tm0yj2sn	607	19	reaction	reaction	NN
cord-276598-tm0yj2sn	607	20	of	of	IN
cord-276598-tm0yj2sn	607	21	the	the	DT
cord-276598-tm0yj2sn	607	22	base	base	NN
cord-276598-tm0yj2sn	607	23	and	and	CC
cord-276598-tm0yj2sn	607	24	CCl	CCl	NNS
cord-276598-tm0yj2sn	607	25	4	4	CD
cord-276598-tm0yj2sn	607	26	results	result	NNS
cord-276598-tm0yj2sn	607	27	in	in	IN
cord-276598-tm0yj2sn	607	28	salt	salt	NN
cord-276598-tm0yj2sn	607	29	formation	formation	NN
cord-276598-tm0yj2sn	607	30	[	[	-LRB-
cord-276598-tm0yj2sn	607	31	Et	et	NN
cord-276598-tm0yj2sn	607	32	3	3	CD
cord-276598-tm0yj2sn	607	33	NCl	NCl	NNS
cord-276598-tm0yj2sn	607	34	]	]	-RRB-
cord-276598-tm0yj2sn	607	35	+	+	CC
cord-276598-tm0yj2sn	607	36	[	[	-LRB-
cord-276598-tm0yj2sn	607	37	CCl	CCl	NNS
cord-276598-tm0yj2sn	607	38	3	3	CD
cord-276598-tm0yj2sn	607	39	]	]	-RRB-
cord-276598-tm0yj2sn	607	40	−	−	NN
cord-276598-tm0yj2sn	607	41	[	[	-LRB-
cord-276598-tm0yj2sn	607	42	121	121	CD
cord-276598-tm0yj2sn	607	43	]	]	-RRB-
cord-276598-tm0yj2sn	607	44	.	.	.
cord-276598-tm0yj2sn	608	1	The	the	DT
cord-276598-tm0yj2sn	608	2	H	H	NNP
cord-276598-tm0yj2sn	608	3	-	-	HYPH
cord-276598-tm0yj2sn	608	4	P	p	NN
cord-276598-tm0yj2sn	608	5	is	be	VBZ
cord-276598-tm0yj2sn	608	6	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	608	7	by	by	IN
cord-276598-tm0yj2sn	608	8	[	[	-LRB-
cord-276598-tm0yj2sn	608	9	CCl	CCl	NNS
cord-276598-tm0yj2sn	608	10	3	3	CD
cord-276598-tm0yj2sn	608	11	]	]	-RRB-
cord-276598-tm0yj2sn	608	12	−	−	NNP
cord-276598-tm0yj2sn	608	13	to	to	TO
cord-276598-tm0yj2sn	608	14	form	form	VB
cord-276598-tm0yj2sn	608	15	CHCl	CHCl	NNS
cord-276598-tm0yj2sn	608	16	3	3	CD
cord-276598-tm0yj2sn	608	17	and	and	CC
cord-276598-tm0yj2sn	608	18	anionic	anionic	JJ
cord-276598-tm0yj2sn	608	19	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	608	20	,	,	,
cord-276598-tm0yj2sn	608	21	which	which	WDT
cord-276598-tm0yj2sn	608	22	reacts	react	VBZ
cord-276598-tm0yj2sn	608	23	further	further	RB
cord-276598-tm0yj2sn	608	24	with	with	IN
cord-276598-tm0yj2sn	608	25	[	[	-LRB-
cord-276598-tm0yj2sn	608	26	Et	et	NN
cord-276598-tm0yj2sn	608	27	3	3	CD
cord-276598-tm0yj2sn	608	28	NCl	NCl	NNS
cord-276598-tm0yj2sn	608	29	]	]	-RRB-
cord-276598-tm0yj2sn	608	30	+	+	SYM
cord-276598-tm0yj2sn	608	31	to	to	TO
cord-276598-tm0yj2sn	608	32	form	form	VB
cord-276598-tm0yj2sn	608	33	(	(	-LRB-
cord-276598-tm0yj2sn	608	34	RO	ro	NN
cord-276598-tm0yj2sn	608	35	)	)	-RRB-
cord-276598-tm0yj2sn	608	36	2	2	CD
cord-276598-tm0yj2sn	609	1	P(O)Cl	P(O)Cl	NNP
cord-276598-tm0yj2sn	609	2	(	(	-LRB-
cord-276598-tm0yj2sn	609	3	dACP	dacp	NN
cord-276598-tm0yj2sn	609	4	;	;	:
cord-276598-tm0yj2sn	609	5	R	r	NN
cord-276598-tm0yj2sn	609	6	=	=	NN
cord-276598-tm0yj2sn	609	7	alkyl	alkyl	NN
cord-276598-tm0yj2sn	609	8	)	)	-RRB-
cord-276598-tm0yj2sn	609	9	.	.	.
cord-276598-tm0yj2sn	610	1	In	in	IN
cord-276598-tm0yj2sn	610	2	the	the	DT
cord-276598-tm0yj2sn	610	3	second	second	JJ
cord-276598-tm0yj2sn	610	4	step	step	NN
cord-276598-tm0yj2sn	610	5	,	,	,
cord-276598-tm0yj2sn	610	6	dACP	dacp	NN
cord-276598-tm0yj2sn	610	7	reacts	react	VBZ
cord-276598-tm0yj2sn	610	8	with	with	IN
cord-276598-tm0yj2sn	610	9	amine	amine	NN
cord-276598-tm0yj2sn	610	10	to	to	TO
cord-276598-tm0yj2sn	610	11	give	give	VB
cord-276598-tm0yj2sn	610	12	the	the	DT
cord-276598-tm0yj2sn	610	13	product	product	NN
cord-276598-tm0yj2sn	610	14	.	.	.
cord-276598-tm0yj2sn	611	1	desired	desire	VBN
cord-276598-tm0yj2sn	611	2	product	product	NN
cord-276598-tm0yj2sn	611	3	is	be	VBZ
cord-276598-tm0yj2sn	611	4	formed	form	VBN
cord-276598-tm0yj2sn	611	5	in	in	IN
cord-276598-tm0yj2sn	611	6	the	the	DT
cord-276598-tm0yj2sn	611	7	second	second	JJ
cord-276598-tm0yj2sn	611	8	step	step	NN
cord-276598-tm0yj2sn	612	1	when	when	WRB
cord-276598-tm0yj2sn	612	2	the	the	DT
cord-276598-tm0yj2sn	612	3	(	(	-LRB-
cord-276598-tm0yj2sn	612	4	trichloromethyl)phosphonate	trichloromethyl)phosphonate	NNP
cord-276598-tm0yj2sn	612	5	reacts	react	NNS
cord-276598-tm0yj2sn	612	6	with	with	IN
cord-276598-tm0yj2sn	612	7	amine	amine	NN
cord-276598-tm0yj2sn	612	8	,	,	,
cord-276598-tm0yj2sn	612	9	forming	form	VBG
cord-276598-tm0yj2sn	612	10	also	also	RB
cord-276598-tm0yj2sn	612	11	CHCl3	chcl3	VB
cord-276598-tm0yj2sn	612	12	in	in	IN
cord-276598-tm0yj2sn	612	13	the	the	DT
cord-276598-tm0yj2sn	612	14	process	process	NN
cord-276598-tm0yj2sn	612	15	(	(	-LRB-
cord-276598-tm0yj2sn	612	16	Scheme	scheme	NN
cord-276598-tm0yj2sn	612	17	18	18	CD
cord-276598-tm0yj2sn	612	18	)	)	-RRB-
cord-276598-tm0yj2sn	612	19	.	.	.
cord-276598-tm0yj2sn	613	1	Although	although	IN
cord-276598-tm0yj2sn	613	2	this	this	DT
cord-276598-tm0yj2sn	613	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	613	4	is	be	VBZ
cord-276598-tm0yj2sn	613	5	plausible	plausible	JJ
cord-276598-tm0yj2sn	613	6	,	,	,
cord-276598-tm0yj2sn	613	7	evidence	evidence	NN
cord-276598-tm0yj2sn	613	8	by	by	IN
cord-276598-tm0yj2sn	613	9	NMR	NMR	NNP
cord-276598-tm0yj2sn	613	10	spectroscopy	spectroscopy	NN
cord-276598-tm0yj2sn	613	11	suggests	suggest	VBZ
cord-276598-tm0yj2sn	613	12	that	that	IN
cord-276598-tm0yj2sn	613	13	in	in	IN
cord-276598-tm0yj2sn	613	14	the	the	DT
cord-276598-tm0yj2sn	613	15	first	first	JJ
cord-276598-tm0yj2sn	613	16	step	step	NN
cord-276598-tm0yj2sn	613	17	,	,	,
cord-276598-tm0yj2sn	613	18	a	a	DT
cord-276598-tm0yj2sn	613	19	reaction	reaction	NN
cord-276598-tm0yj2sn	613	20	of	of	IN
cord-276598-tm0yj2sn	613	21	the	the	DT
cord-276598-tm0yj2sn	613	22	base	base	NN
cord-276598-tm0yj2sn	613	23	and	and	CC
cord-276598-tm0yj2sn	613	24	CCl4	ccl4	NN
cord-276598-tm0yj2sn	613	25	results	result	NNS
cord-276598-tm0yj2sn	613	26	in	in	IN
cord-276598-tm0yj2sn	613	27	salt	salt	NN
cord-276598-tm0yj2sn	613	28	formation	formation	NN
cord-276598-tm0yj2sn	613	29	[	[	-LRB-
cord-276598-tm0yj2sn	613	30	Et3NCl	et3ncl	NN
cord-276598-tm0yj2sn	613	31	]	]	-RRB-
cord-276598-tm0yj2sn	613	32	+	+	CC
cord-276598-tm0yj2sn	613	33	[	[	-LRB-
cord-276598-tm0yj2sn	613	34	CCl3	CCl3	NNP
cord-276598-tm0yj2sn	613	35	]	]	-RRB-
cord-276598-tm0yj2sn	613	36	−	−	NNP
cord-276598-tm0yj2sn	613	37	[	[	-LRB-
cord-276598-tm0yj2sn	613	38	121	121	CD
cord-276598-tm0yj2sn	613	39	]	]	-RRB-
cord-276598-tm0yj2sn	613	40	.	.	.
cord-276598-tm0yj2sn	614	1	The	the	DT
cord-276598-tm0yj2sn	614	2	H	H	NNP
cord-276598-tm0yj2sn	614	3	-	-	HYPH
cord-276598-tm0yj2sn	614	4	P	p	NN
cord-276598-tm0yj2sn	614	5	is	be	VBZ
cord-276598-tm0yj2sn	614	6	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	614	7	by	by	IN
cord-276598-tm0yj2sn	614	8	[	[	-LRB-
cord-276598-tm0yj2sn	614	9	CCl3	CCl3	NNP
cord-276598-tm0yj2sn	614	10	]	]	-RRB-
cord-276598-tm0yj2sn	614	11	−	−	NNP
cord-276598-tm0yj2sn	614	12	to	to	TO
cord-276598-tm0yj2sn	614	13	form	form	VB
cord-276598-tm0yj2sn	614	14	CHCl3	CHCl3	NNP
cord-276598-tm0yj2sn	614	15	and	and	CC
cord-276598-tm0yj2sn	614	16	anionic	anionic	JJ
cord-276598-tm0yj2sn	614	17	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	614	18	,	,	,
cord-276598-tm0yj2sn	614	19	which	which	WDT
cord-276598-tm0yj2sn	614	20	reacts	react	VBZ
cord-276598-tm0yj2sn	614	21	further	further	RB
cord-276598-tm0yj2sn	614	22	with	with	IN
cord-276598-tm0yj2sn	614	23	[	[	-LRB-
cord-276598-tm0yj2sn	614	24	Et3NCl	Et3NCl	NNP
cord-276598-tm0yj2sn	614	25	]	]	-RRB-
cord-276598-tm0yj2sn	614	26	+	+	SYM
cord-276598-tm0yj2sn	614	27	to	to	TO
cord-276598-tm0yj2sn	614	28	form	form	VB
cord-276598-tm0yj2sn	614	29	(	(	-LRB-
cord-276598-tm0yj2sn	615	1	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	615	2	(	(	-LRB-
cord-276598-tm0yj2sn	615	3	dACP	dacp	NN
cord-276598-tm0yj2sn	615	4	;	;	:
cord-276598-tm0yj2sn	615	5	R	r	NN
cord-276598-tm0yj2sn	615	6	=	=	NN
cord-276598-tm0yj2sn	615	7	alkyl	alkyl	NN
cord-276598-tm0yj2sn	615	8	)	)	-RRB-
cord-276598-tm0yj2sn	615	9	.	.	.
cord-276598-tm0yj2sn	616	1	In	in	IN
cord-276598-tm0yj2sn	616	2	the	the	DT
cord-276598-tm0yj2sn	616	3	second	second	JJ
cord-276598-tm0yj2sn	616	4	step	step	NN
cord-276598-tm0yj2sn	616	5	,	,	,
cord-276598-tm0yj2sn	616	6	dACP	dacp	NN
cord-276598-tm0yj2sn	616	7	reacts	react	VBZ
cord-276598-tm0yj2sn	616	8	with	with	IN
cord-276598-tm0yj2sn	616	9	amine	amine	NN
cord-276598-tm0yj2sn	616	10	to	to	TO
cord-276598-tm0yj2sn	616	11	give	give	VB
cord-276598-tm0yj2sn	616	12	the	the	DT
cord-276598-tm0yj2sn	616	13	product	product	NN
cord-276598-tm0yj2sn	616	14	.	.	.
cord-276598-tm0yj2sn	617	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	617	2	18	18	CD
cord-276598-tm0yj2sn	617	3	.	.	.
cord-276598-tm0yj2sn	618	1	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	618	2	-	-	HYPH
cord-276598-tm0yj2sn	618	3	Todd	Todd	NNP
cord-276598-tm0yj2sn	618	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	618	5	proposed	propose	VBN
cord-276598-tm0yj2sn	618	6	for	for	IN
cord-276598-tm0yj2sn	618	7	the	the	DT
cord-276598-tm0yj2sn	618	8	formation	formation	NN
cord-276598-tm0yj2sn	618	9	of	of	IN
cord-276598-tm0yj2sn	618	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	618	11	.	.	.
cord-276598-tm0yj2sn	619	1	For	for	IN
cord-276598-tm0yj2sn	619	2	the	the	DT
cord-276598-tm0yj2sn	619	3	modified	modify	VBN
cord-276598-tm0yj2sn	619	4	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	619	5	-	-	HYPH
cord-276598-tm0yj2sn	619	6	Todd	Todd	NNP
cord-276598-tm0yj2sn	619	7	reaction	reaction	NN
cord-276598-tm0yj2sn	619	8	,	,	,
cord-276598-tm0yj2sn	619	9	the	the	DT
cord-276598-tm0yj2sn	619	10	two	two	CD
cord-276598-tm0yj2sn	619	11	-	-	HYPH
cord-276598-tm0yj2sn	619	12	step	step	NN
cord-276598-tm0yj2sn	619	13	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	619	14	process	process	NN
cord-276598-tm0yj2sn	619	15	involves	involve	VBZ
cord-276598-tm0yj2sn	619	16	the	the	DT
cord-276598-tm0yj2sn	619	17	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	619	18	of	of	IN
cord-276598-tm0yj2sn	619	19	H	H	NNP
cord-276598-tm0yj2sn	619	20	-	-	HYPH
cord-276598-tm0yj2sn	619	21	P	p	NN
cord-276598-tm0yj2sn	619	22	by	by	IN
cord-276598-tm0yj2sn	619	23	DBU	DBU	NNP
cord-276598-tm0yj2sn	619	24	,	,	,
cord-276598-tm0yj2sn	619	25	and	and	CC
cord-276598-tm0yj2sn	619	26	the	the	DT
cord-276598-tm0yj2sn	619	27	radical	radical	JJ
cord-276598-tm0yj2sn	619	28	formed	form	VBN
cord-276598-tm0yj2sn	619	29	is	be	VBZ
cord-276598-tm0yj2sn	619	30	autoxidized	autoxidize	VBN
cord-276598-tm0yj2sn	619	31	by	by	IN
cord-276598-tm0yj2sn	619	32	O2	O2	NNP
cord-276598-tm0yj2sn	619	33	before	before	IN
cord-276598-tm0yj2sn	619	34	it	-PRON-	PRP
cord-276598-tm0yj2sn	619	35	abstracts	abstract	VBZ
cord-276598-tm0yj2sn	619	36	chlorine	chlorine	NN
cord-276598-tm0yj2sn	619	37	from	from	IN
cord-276598-tm0yj2sn	619	38	CHCl3	CHCl3	NNP
cord-276598-tm0yj2sn	619	39	to	to	TO
cord-276598-tm0yj2sn	619	40	form	form	VB
cord-276598-tm0yj2sn	619	41	dACP	dACP	.
cord-276598-tm0yj2sn	620	1	(	(	-LRB-
cord-276598-tm0yj2sn	620	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	620	3	19	19	CD
cord-276598-tm0yj2sn	620	4	)	)	-RRB-
cord-276598-tm0yj2sn	620	5	[	[	-LRB-
cord-276598-tm0yj2sn	620	6	95	95	CD
cord-276598-tm0yj2sn	620	7	]	]	-RRB-
cord-276598-tm0yj2sn	620	8	.	.	.
cord-276598-tm0yj2sn	621	1	The	the	DT
cord-276598-tm0yj2sn	621	2	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	621	3	substitution	substitution	NN
cord-276598-tm0yj2sn	621	4	of	of	IN
cord-276598-tm0yj2sn	621	5	dACP	dacp	NN
cord-276598-tm0yj2sn	621	6	by	by	IN
cord-276598-tm0yj2sn	621	7	the	the	DT
cord-276598-tm0yj2sn	621	8	amine	amine	NN
cord-276598-tm0yj2sn	621	9	affords	afford	VBZ
cord-276598-tm0yj2sn	621	10	the	the	DT
cord-276598-tm0yj2sn	621	11	P	P	NNP
cord-276598-tm0yj2sn	621	12	-	-	HYPH
cord-276598-tm0yj2sn	621	13	N	n	CD
cord-276598-tm0yj2sn	621	14	product	product	NN
cord-276598-tm0yj2sn	621	15	.	.	.
cord-276598-tm0yj2sn	621	16	 	 	_SP
cord-276598-tm0yj2sn	622	1	In	in	IN
cord-276598-tm0yj2sn	622	2	the	the	DT
cord-276598-tm0yj2sn	622	3	plausible	plausible	JJ
cord-276598-tm0yj2sn	622	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	622	5	for	for	IN
cord-276598-tm0yj2sn	622	6	the	the	DT
cord-276598-tm0yj2sn	622	7	direct	direct	JJ
cord-276598-tm0yj2sn	622	8	conversion	conversion	NN
cord-276598-tm0yj2sn	622	9	of	of	IN
cord-276598-tm0yj2sn	622	10	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	622	11	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	622	12	phosphate	phosphate	NN
cord-276598-tm0yj2sn	622	13	,	,	,
cord-276598-tm0yj2sn	622	14	hexamethyltriaminophosphine	hexamethyltriaminophosphine	NNP
cord-276598-tm0yj2sn	622	15	P(NMe2)3	P(NMe2)3	NNP
cord-276598-tm0yj2sn	622	16	is	be	VBZ
cord-276598-tm0yj2sn	622	17	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	622	18	to	to	IN
cord-276598-tm0yj2sn	622	19	hexamethyltriaminodibromophosphorane	hexamethyltriaminodibromophosphorane	NNP
cord-276598-tm0yj2sn	622	20	(	(	-LRB-
cord-276598-tm0yj2sn	622	21	(	(	-LRB-
cord-276598-tm0yj2sn	622	22	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	622	23	)	)	-RRB-
cord-276598-tm0yj2sn	622	24	which	which	WDT
cord-276598-tm0yj2sn	622	25	is	be	VBZ
cord-276598-tm0yj2sn	622	26	ionized	ionize	VBN
cord-276598-tm0yj2sn	622	27	in	in	IN
cord-276598-tm0yj2sn	622	28	solution	solution	NN
cord-276598-tm0yj2sn	622	29	(	(	-LRB-
cord-276598-tm0yj2sn	622	30	Scheme	scheme	NN
cord-276598-tm0yj2sn	622	31	20	20	CD
cord-276598-tm0yj2sn	622	32	)	)	-RRB-
cord-276598-tm0yj2sn	622	33	[	[	-LRB-
cord-276598-tm0yj2sn	622	34	90	90	CD
cord-276598-tm0yj2sn	622	35	]	]	-RRB-
cord-276598-tm0yj2sn	622	36	.	.	.
cord-276598-tm0yj2sn	623	1	Subsequently	subsequently	RB
cord-276598-tm0yj2sn	623	2	,	,	,
cord-276598-tm0yj2sn	623	3	the	the	DT
cord-276598-tm0yj2sn	623	4	ionized	ionized	JJ
cord-276598-tm0yj2sn	623	5	(	(	-LRB-
cord-276598-tm0yj2sn	623	6	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	623	7	and	and	CC
cord-276598-tm0yj2sn	623	8	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	623	9	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	623	10	phosphate	phosphate	NN
cord-276598-tm0yj2sn	623	11	undergo	undergo	VBP
cord-276598-tm0yj2sn	623	12	ligand	ligand	NN
cord-276598-tm0yj2sn	623	13	exchange	exchange	NN
cord-276598-tm0yj2sn	623	14	in	in	IN
cord-276598-tm0yj2sn	623	15	the	the	DT
cord-276598-tm0yj2sn	623	16	presence	presence	NN
cord-276598-tm0yj2sn	623	17	of	of	IN
cord-276598-tm0yj2sn	623	18	Et3N	Et3N	NNP
cord-276598-tm0yj2sn	623	19	to	to	TO
cord-276598-tm0yj2sn	623	20	form	form	VB
cord-276598-tm0yj2sn	623	21	the	the	DT
cord-276598-tm0yj2sn	623	22	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	623	23	18	18	CD
cord-276598-tm0yj2sn	623	24	.	.	.
cord-276598-tm0yj2sn	624	1	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	624	2	-	-	HYPH
cord-276598-tm0yj2sn	624	3	Todd	Todd	NNP
cord-276598-tm0yj2sn	624	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	624	5	proposed	propose	VBN
cord-276598-tm0yj2sn	624	6	for	for	IN
cord-276598-tm0yj2sn	624	7	the	the	DT
cord-276598-tm0yj2sn	624	8	formation	formation	NN
cord-276598-tm0yj2sn	624	9	of	of	IN
cord-276598-tm0yj2sn	624	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	624	11	.	.	.
cord-276598-tm0yj2sn	625	1	For	for	IN
cord-276598-tm0yj2sn	625	2	the	the	DT
cord-276598-tm0yj2sn	625	3	modified	modify	VBN
cord-276598-tm0yj2sn	625	4	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	625	5	-	-	HYPH
cord-276598-tm0yj2sn	625	6	Todd	Todd	NNP
cord-276598-tm0yj2sn	625	7	reaction	reaction	NN
cord-276598-tm0yj2sn	625	8	,	,	,
cord-276598-tm0yj2sn	625	9	the	the	DT
cord-276598-tm0yj2sn	625	10	two	two	CD
cord-276598-tm0yj2sn	625	11	-	-	HYPH
cord-276598-tm0yj2sn	625	12	step	step	NN
cord-276598-tm0yj2sn	625	13	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	625	14	process	process	NN
cord-276598-tm0yj2sn	625	15	involves	involve	VBZ
cord-276598-tm0yj2sn	625	16	the	the	DT
cord-276598-tm0yj2sn	625	17	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	625	18	of	of	IN
cord-276598-tm0yj2sn	625	19	H	H	NNP
cord-276598-tm0yj2sn	625	20	-	-	HYPH
cord-276598-tm0yj2sn	625	21	P	p	NN
cord-276598-tm0yj2sn	625	22	by	by	IN
cord-276598-tm0yj2sn	625	23	DBU	DBU	NNP
cord-276598-tm0yj2sn	625	24	,	,	,
cord-276598-tm0yj2sn	625	25	and	and	CC
cord-276598-tm0yj2sn	625	26	the	the	DT
cord-276598-tm0yj2sn	625	27	radical	radical	JJ
cord-276598-tm0yj2sn	625	28	formed	form	VBN
cord-276598-tm0yj2sn	625	29	is	be	VBZ
cord-276598-tm0yj2sn	625	30	autoxidized	autoxidize	VBN
cord-276598-tm0yj2sn	625	31	by	by	IN
cord-276598-tm0yj2sn	625	32	O	o	NN
cord-276598-tm0yj2sn	625	33	2	2	CD
cord-276598-tm0yj2sn	625	34	before	before	IN
cord-276598-tm0yj2sn	625	35	it	-PRON-	PRP
cord-276598-tm0yj2sn	625	36	abstracts	abstract	VBZ
cord-276598-tm0yj2sn	625	37	chlorine	chlorine	NN
cord-276598-tm0yj2sn	625	38	from	from	IN
cord-276598-tm0yj2sn	625	39	CHCl	CHCl	NNS
cord-276598-tm0yj2sn	625	40	3	3	CD
cord-276598-tm0yj2sn	625	41	to	to	TO
cord-276598-tm0yj2sn	625	42	form	form	VB
cord-276598-tm0yj2sn	625	43	dACP	dACP	.
cord-276598-tm0yj2sn	626	1	(	(	-LRB-
cord-276598-tm0yj2sn	626	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	626	3	19	19	CD
cord-276598-tm0yj2sn	626	4	)	)	-RRB-
cord-276598-tm0yj2sn	626	5	[	[	-LRB-
cord-276598-tm0yj2sn	626	6	95	95	CD
cord-276598-tm0yj2sn	626	7	]	]	-RRB-
cord-276598-tm0yj2sn	626	8	.	.	.
cord-276598-tm0yj2sn	627	1	The	the	DT
cord-276598-tm0yj2sn	627	2	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	627	3	substitution	substitution	NN
cord-276598-tm0yj2sn	627	4	of	of	IN
cord-276598-tm0yj2sn	627	5	dACP	dacp	NN
cord-276598-tm0yj2sn	627	6	by	by	IN
cord-276598-tm0yj2sn	627	7	the	the	DT
cord-276598-tm0yj2sn	627	8	amine	amine	NN
cord-276598-tm0yj2sn	627	9	affords	afford	VBZ
cord-276598-tm0yj2sn	627	10	the	the	DT
cord-276598-tm0yj2sn	627	11	P	P	NNP
cord-276598-tm0yj2sn	627	12	-	-	HYPH
cord-276598-tm0yj2sn	627	13	N	n	CD
cord-276598-tm0yj2sn	627	14	product	product	NN
cord-276598-tm0yj2sn	627	15	.	.	.
cord-276598-tm0yj2sn	628	1	first	first	JJ
cord-276598-tm0yj2sn	628	2	step	step	NN
cord-276598-tm0yj2sn	628	3	,	,	,
cord-276598-tm0yj2sn	628	4	from	from	IN
cord-276598-tm0yj2sn	628	5	a	a	DT
cord-276598-tm0yj2sn	628	6	reaction	reaction	NN
cord-276598-tm0yj2sn	628	7	of	of	IN
cord-276598-tm0yj2sn	628	8	(	(	-LRB-
cord-276598-tm0yj2sn	628	9	RO)2P(O)H	ro)2p(o)h	NN
cord-276598-tm0yj2sn	628	10	(	(	-LRB-
cord-276598-tm0yj2sn	628	11	H	h	NN
cord-276598-tm0yj2sn	628	12	-	-	HYPH
cord-276598-tm0yj2sn	628	13	P	p	NN
cord-276598-tm0yj2sn	628	14	;	;	:
cord-276598-tm0yj2sn	628	15	R	r	NN
cord-276598-tm0yj2sn	628	16	=	=	NN
cord-276598-tm0yj2sn	628	17	alkyl	alkyl	NN
cord-276598-tm0yj2sn	628	18	)	)	-RRB-
cord-276598-tm0yj2sn	628	19	and	and	CC
cord-276598-tm0yj2sn	628	20	CCl4	ccl4	NN
cord-276598-tm0yj2sn	628	21	in	in	IN
cord-276598-tm0yj2sn	628	22	the	the	DT
cord-276598-tm0yj2sn	628	23	presence	presence	NN
cord-276598-tm0yj2sn	628	24	of	of	IN
cord-276598-tm0yj2sn	628	25	Et3N	Et3N	NNP
cord-276598-tm0yj2sn	628	26	[	[	-LRB-
cord-276598-tm0yj2sn	628	27	78	78	CD
cord-276598-tm0yj2sn	628	28	]	]	-RRB-
cord-276598-tm0yj2sn	628	29	.	.	.
cord-276598-tm0yj2sn	629	1	The	the	DT
cord-276598-tm0yj2sn	629	2	desired	desire	VBN
cord-276598-tm0yj2sn	629	3	product	product	NN
cord-276598-tm0yj2sn	629	4	is	be	VBZ
cord-276598-tm0yj2sn	629	5	formed	form	VBN
cord-276598-tm0yj2sn	629	6	in	in	IN
cord-276598-tm0yj2sn	629	7	the	the	DT
cord-276598-tm0yj2sn	629	8	second	second	JJ
cord-276598-tm0yj2sn	629	9	step	step	NN
cord-276598-tm0yj2sn	630	1	when	when	WRB
cord-276598-tm0yj2sn	630	2	the	the	DT
cord-276598-tm0yj2sn	630	3	(	(	-LRB-
cord-276598-tm0yj2sn	630	4	trichloromethyl)phosphonate	trichloromethyl)phosphonate	NNP
cord-276598-tm0yj2sn	630	5	reacts	react	NNS
cord-276598-tm0yj2sn	630	6	with	with	IN
cord-276598-tm0yj2sn	630	7	amine	amine	NN
cord-276598-tm0yj2sn	630	8	,	,	,
cord-276598-tm0yj2sn	630	9	forming	form	VBG
cord-276598-tm0yj2sn	630	10	also	also	RB
cord-276598-tm0yj2sn	630	11	CHCl3	chcl3	VB
cord-276598-tm0yj2sn	630	12	in	in	IN
cord-276598-tm0yj2sn	630	13	the	the	DT
cord-276598-tm0yj2sn	630	14	process	process	NN
cord-276598-tm0yj2sn	630	15	(	(	-LRB-
cord-276598-tm0yj2sn	630	16	Scheme	scheme	NN
cord-276598-tm0yj2sn	630	17	18	18	CD
cord-276598-tm0yj2sn	630	18	)	)	-RRB-
cord-276598-tm0yj2sn	630	19	.	.	.
cord-276598-tm0yj2sn	631	1	Although	although	IN
cord-276598-tm0yj2sn	631	2	this	this	DT
cord-276598-tm0yj2sn	631	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	631	4	is	be	VBZ
cord-276598-tm0yj2sn	631	5	plausible	plausible	JJ
cord-276598-tm0yj2sn	631	6	,	,	,
cord-276598-tm0yj2sn	631	7	evidence	evidence	NN
cord-276598-tm0yj2sn	631	8	by	by	IN
cord-276598-tm0yj2sn	631	9	NMR	NMR	NNP
cord-276598-tm0yj2sn	631	10	spectroscopy	spectroscopy	NN
cord-276598-tm0yj2sn	631	11	suggests	suggest	VBZ
cord-276598-tm0yj2sn	631	12	that	that	IN
cord-276598-tm0yj2sn	631	13	in	in	IN
cord-276598-tm0yj2sn	631	14	the	the	DT
cord-276598-tm0yj2sn	631	15	first	first	JJ
cord-276598-tm0yj2sn	631	16	step	step	NN
cord-276598-tm0yj2sn	631	17	,	,	,
cord-276598-tm0yj2sn	631	18	a	a	DT
cord-276598-tm0yj2sn	631	19	reaction	reaction	NN
cord-276598-tm0yj2sn	631	20	of	of	IN
cord-276598-tm0yj2sn	631	21	the	the	DT
cord-276598-tm0yj2sn	631	22	base	base	NN
cord-276598-tm0yj2sn	631	23	and	and	CC
cord-276598-tm0yj2sn	631	24	CCl4	ccl4	NN
cord-276598-tm0yj2sn	631	25	results	result	NNS
cord-276598-tm0yj2sn	631	26	in	in	IN
cord-276598-tm0yj2sn	631	27	salt	salt	NN
cord-276598-tm0yj2sn	631	28	formation	formation	NN
cord-276598-tm0yj2sn	631	29	[	[	-LRB-
cord-276598-tm0yj2sn	631	30	Et3NCl	et3ncl	NN
cord-276598-tm0yj2sn	631	31	]	]	-RRB-
cord-276598-tm0yj2sn	631	32	+	+	CC
cord-276598-tm0yj2sn	631	33	[	[	-LRB-
cord-276598-tm0yj2sn	631	34	CCl3	CCl3	NNP
cord-276598-tm0yj2sn	631	35	]	]	-RRB-
cord-276598-tm0yj2sn	631	36	−	−	NNP
cord-276598-tm0yj2sn	631	37	[	[	-LRB-
cord-276598-tm0yj2sn	631	38	121	121	CD
cord-276598-tm0yj2sn	631	39	]	]	-RRB-
cord-276598-tm0yj2sn	631	40	.	.	.
cord-276598-tm0yj2sn	632	1	The	the	DT
cord-276598-tm0yj2sn	632	2	H	H	NNP
cord-276598-tm0yj2sn	632	3	-	-	HYPH
cord-276598-tm0yj2sn	632	4	P	p	NN
cord-276598-tm0yj2sn	632	5	is	be	VBZ
cord-276598-tm0yj2sn	632	6	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	632	7	by	by	IN
cord-276598-tm0yj2sn	632	8	[	[	-LRB-
cord-276598-tm0yj2sn	632	9	CCl3	CCl3	NNP
cord-276598-tm0yj2sn	632	10	]	]	-RRB-
cord-276598-tm0yj2sn	632	11	−	−	NNP
cord-276598-tm0yj2sn	632	12	to	to	TO
cord-276598-tm0yj2sn	632	13	form	form	VB
cord-276598-tm0yj2sn	632	14	CHCl3	CHCl3	NNP
cord-276598-tm0yj2sn	632	15	and	and	CC
cord-276598-tm0yj2sn	632	16	anionic	anionic	JJ
cord-276598-tm0yj2sn	632	17	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	632	18	,	,	,
cord-276598-tm0yj2sn	632	19	which	which	WDT
cord-276598-tm0yj2sn	632	20	reacts	react	VBZ
cord-276598-tm0yj2sn	632	21	further	further	RB
cord-276598-tm0yj2sn	632	22	with	with	IN
cord-276598-tm0yj2sn	632	23	[	[	-LRB-
cord-276598-tm0yj2sn	632	24	Et3NCl	Et3NCl	NNP
cord-276598-tm0yj2sn	632	25	]	]	-RRB-
cord-276598-tm0yj2sn	632	26	+	+	SYM
cord-276598-tm0yj2sn	632	27	to	to	TO
cord-276598-tm0yj2sn	632	28	form	form	VB
cord-276598-tm0yj2sn	632	29	(	(	-LRB-
cord-276598-tm0yj2sn	633	1	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	633	2	(	(	-LRB-
cord-276598-tm0yj2sn	633	3	dACP	dacp	NN
cord-276598-tm0yj2sn	633	4	;	;	:
cord-276598-tm0yj2sn	633	5	R	r	NN
cord-276598-tm0yj2sn	633	6	=	=	NN
cord-276598-tm0yj2sn	633	7	alkyl	alkyl	NN
cord-276598-tm0yj2sn	633	8	)	)	-RRB-
cord-276598-tm0yj2sn	633	9	.	.	.
cord-276598-tm0yj2sn	634	1	In	in	IN
cord-276598-tm0yj2sn	634	2	the	the	DT
cord-276598-tm0yj2sn	634	3	second	second	JJ
cord-276598-tm0yj2sn	634	4	step	step	NN
cord-276598-tm0yj2sn	634	5	,	,	,
cord-276598-tm0yj2sn	634	6	dACP	dacp	NN
cord-276598-tm0yj2sn	634	7	reacts	react	VBZ
cord-276598-tm0yj2sn	634	8	with	with	IN
cord-276598-tm0yj2sn	634	9	amine	amine	NN
cord-276598-tm0yj2sn	634	10	to	to	TO
cord-276598-tm0yj2sn	634	11	give	give	VB
cord-276598-tm0yj2sn	634	12	the	the	DT
cord-276598-tm0yj2sn	634	13	product	product	NN
cord-276598-tm0yj2sn	634	14	.	.	.
cord-276598-tm0yj2sn	635	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	635	2	18	18	CD
cord-276598-tm0yj2sn	635	3	.	.	.
cord-276598-tm0yj2sn	636	1	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	636	2	-	-	HYPH
cord-276598-tm0yj2sn	636	3	Todd	Todd	NNP
cord-276598-tm0yj2sn	636	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	636	5	proposed	propose	VBN
cord-276598-tm0yj2sn	636	6	for	for	IN
cord-276598-tm0yj2sn	636	7	the	the	DT
cord-276598-tm0yj2sn	636	8	formation	formation	NN
cord-276598-tm0yj2sn	636	9	of	of	IN
cord-276598-tm0yj2sn	636	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	636	11	.	.	.
cord-276598-tm0yj2sn	637	1	For	for	IN
cord-276598-tm0yj2sn	637	2	the	the	DT
cord-276598-tm0yj2sn	637	3	modified	modify	VBN
cord-276598-tm0yj2sn	637	4	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	637	5	-	-	HYPH
cord-276598-tm0yj2sn	637	6	Todd	Todd	NNP
cord-276598-tm0yj2sn	637	7	reaction	reaction	NN
cord-276598-tm0yj2sn	637	8	,	,	,
cord-276598-tm0yj2sn	637	9	the	the	DT
cord-276598-tm0yj2sn	637	10	two	two	CD
cord-276598-tm0yj2sn	637	11	-	-	HYPH
cord-276598-tm0yj2sn	637	12	step	step	NN
cord-276598-tm0yj2sn	637	13	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	637	14	process	process	NN
cord-276598-tm0yj2sn	637	15	involves	involve	VBZ
cord-276598-tm0yj2sn	637	16	the	the	DT
cord-276598-tm0yj2sn	637	17	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	637	18	of	of	IN
cord-276598-tm0yj2sn	637	19	H	H	NNP
cord-276598-tm0yj2sn	637	20	-	-	HYPH
cord-276598-tm0yj2sn	637	21	P	p	NN
cord-276598-tm0yj2sn	637	22	by	by	IN
cord-276598-tm0yj2sn	637	23	DBU	DBU	NNP
cord-276598-tm0yj2sn	637	24	,	,	,
cord-276598-tm0yj2sn	637	25	and	and	CC
cord-276598-tm0yj2sn	637	26	the	the	DT
cord-276598-tm0yj2sn	637	27	radical	radical	JJ
cord-276598-tm0yj2sn	637	28	formed	form	VBN
cord-276598-tm0yj2sn	637	29	is	be	VBZ
cord-276598-tm0yj2sn	637	30	autoxidized	autoxidize	VBN
cord-276598-tm0yj2sn	637	31	by	by	IN
cord-276598-tm0yj2sn	637	32	O2	O2	NNP
cord-276598-tm0yj2sn	637	33	before	before	IN
cord-276598-tm0yj2sn	637	34	it	-PRON-	PRP
cord-276598-tm0yj2sn	637	35	abstracts	abstract	VBZ
cord-276598-tm0yj2sn	637	36	chlorine	chlorine	NN
cord-276598-tm0yj2sn	637	37	from	from	IN
cord-276598-tm0yj2sn	637	38	CHCl3	CHCl3	NNP
cord-276598-tm0yj2sn	637	39	to	to	TO
cord-276598-tm0yj2sn	637	40	form	form	VB
cord-276598-tm0yj2sn	637	41	dACP	dACP	.
cord-276598-tm0yj2sn	638	1	(	(	-LRB-
cord-276598-tm0yj2sn	638	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	638	3	19	19	CD
cord-276598-tm0yj2sn	638	4	)	)	-RRB-
cord-276598-tm0yj2sn	638	5	[	[	-LRB-
cord-276598-tm0yj2sn	638	6	95	95	CD
cord-276598-tm0yj2sn	638	7	]	]	-RRB-
cord-276598-tm0yj2sn	638	8	.	.	.
cord-276598-tm0yj2sn	639	1	The	the	DT
cord-276598-tm0yj2sn	639	2	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	639	3	substitution	substitution	NN
cord-276598-tm0yj2sn	639	4	of	of	IN
cord-276598-tm0yj2sn	639	5	dACP	dacp	NN
cord-276598-tm0yj2sn	639	6	by	by	IN
cord-276598-tm0yj2sn	639	7	the	the	DT
cord-276598-tm0yj2sn	639	8	amine	amine	NN
cord-276598-tm0yj2sn	639	9	affords	afford	VBZ
cord-276598-tm0yj2sn	639	10	the	the	DT
cord-276598-tm0yj2sn	639	11	P	P	NNP
cord-276598-tm0yj2sn	639	12	-	-	HYPH
cord-276598-tm0yj2sn	639	13	N	n	CD
cord-276598-tm0yj2sn	639	14	product	product	NN
cord-276598-tm0yj2sn	639	15	.	.	.
cord-276598-tm0yj2sn	639	16	 	 	_SP
cord-276598-tm0yj2sn	640	1	In	in	IN
cord-276598-tm0yj2sn	640	2	the	the	DT
cord-276598-tm0yj2sn	640	3	plausible	plausible	JJ
cord-276598-tm0yj2sn	640	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	640	5	for	for	IN
cord-276598-tm0yj2sn	640	6	the	the	DT
cord-276598-tm0yj2sn	640	7	direct	direct	JJ
cord-276598-tm0yj2sn	640	8	conversion	conversion	NN
cord-276598-tm0yj2sn	640	9	of	of	IN
cord-276598-tm0yj2sn	640	10	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	640	11	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	640	12	phosphate	phosphate	NN
cord-276598-tm0yj2sn	640	13	,	,	,
cord-276598-tm0yj2sn	640	14	hexamethyltriaminophosphine	hexamethyltriaminophosphine	NNP
cord-276598-tm0yj2sn	640	15	P(NMe2)3	P(NMe2)3	NNP
cord-276598-tm0yj2sn	640	16	is	be	VBZ
cord-276598-tm0yj2sn	640	17	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	640	18	to	to	IN
cord-276598-tm0yj2sn	640	19	hexamethyltriaminodibromophosphorane	hexamethyltriaminodibromophosphorane	NNP
cord-276598-tm0yj2sn	640	20	(	(	-LRB-
cord-276598-tm0yj2sn	640	21	(	(	-LRB-
cord-276598-tm0yj2sn	640	22	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	640	23	)	)	-RRB-
cord-276598-tm0yj2sn	640	24	which	which	WDT
cord-276598-tm0yj2sn	640	25	is	be	VBZ
cord-276598-tm0yj2sn	640	26	ionized	ionize	VBN
cord-276598-tm0yj2sn	640	27	in	in	IN
cord-276598-tm0yj2sn	640	28	solution	solution	NN
cord-276598-tm0yj2sn	640	29	(	(	-LRB-
cord-276598-tm0yj2sn	640	30	Scheme	scheme	NN
cord-276598-tm0yj2sn	640	31	20	20	CD
cord-276598-tm0yj2sn	640	32	)	)	-RRB-
cord-276598-tm0yj2sn	640	33	[	[	-LRB-
cord-276598-tm0yj2sn	640	34	90	90	CD
cord-276598-tm0yj2sn	640	35	]	]	-RRB-
cord-276598-tm0yj2sn	640	36	.	.	.
cord-276598-tm0yj2sn	641	1	Subsequently	subsequently	RB
cord-276598-tm0yj2sn	641	2	,	,	,
cord-276598-tm0yj2sn	641	3	the	the	DT
cord-276598-tm0yj2sn	641	4	ionized	ionized	JJ
cord-276598-tm0yj2sn	641	5	(	(	-LRB-
cord-276598-tm0yj2sn	641	6	Me2N)3PBr2	Me2N)3PBr2	NNP
cord-276598-tm0yj2sn	641	7	and	and	CC
cord-276598-tm0yj2sn	641	8	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	641	9	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	641	10	phosphate	phosphate	NN
cord-276598-tm0yj2sn	641	11	undergo	undergo	VBP
cord-276598-tm0yj2sn	641	12	ligand	ligand	NN
cord-276598-tm0yj2sn	641	13	exchange	exchange	NN
cord-276598-tm0yj2sn	641	14	in	in	IN
cord-276598-tm0yj2sn	641	15	the	the	DT
cord-276598-tm0yj2sn	641	16	presence	presence	NN
cord-276598-tm0yj2sn	641	17	of	of	IN
cord-276598-tm0yj2sn	641	18	Et3N	Et3N	NNP
cord-276598-tm0yj2sn	641	19	to	to	TO
cord-276598-tm0yj2sn	641	20	form	form	VB
cord-276598-tm0yj2sn	641	21	the	the	DT
cord-276598-tm0yj2sn	641	22	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	641	23	19	19	CD
cord-276598-tm0yj2sn	641	24	.	.	.
cord-276598-tm0yj2sn	642	1	Modified	Modified	NNP
cord-276598-tm0yj2sn	642	2	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	642	3	-	-	HYPH
cord-276598-tm0yj2sn	642	4	Todd	Todd	NNP
cord-276598-tm0yj2sn	642	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	642	6	proposed	propose	VBN
cord-276598-tm0yj2sn	642	7	in	in	IN
cord-276598-tm0yj2sn	642	8	the	the	DT
cord-276598-tm0yj2sn	642	9	formation	formation	NN
cord-276598-tm0yj2sn	642	10	of	of	IN
cord-276598-tm0yj2sn	642	11	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	642	12	.	.	.
cord-276598-tm0yj2sn	643	1	In	in	IN
cord-276598-tm0yj2sn	643	2	the	the	DT
cord-276598-tm0yj2sn	643	3	plausible	plausible	JJ
cord-276598-tm0yj2sn	643	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	643	5	for	for	IN
cord-276598-tm0yj2sn	643	6	the	the	DT
cord-276598-tm0yj2sn	643	7	direct	direct	JJ
cord-276598-tm0yj2sn	643	8	conversion	conversion	NN
cord-276598-tm0yj2sn	643	9	of	of	IN
cord-276598-tm0yj2sn	643	10	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	643	11	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	643	12	phosphate	phosphate	NN
cord-276598-tm0yj2sn	643	13	,	,	,
cord-276598-tm0yj2sn	643	14	hexamethyltriaminophosphine	hexamethyltriaminophosphine	NNP
cord-276598-tm0yj2sn	643	15	P(NMe	P(NMe	NNP
cord-276598-tm0yj2sn	643	16	2	2	CD
cord-276598-tm0yj2sn	643	17	)	)	-RRB-
cord-276598-tm0yj2sn	643	18	3	3	CD
cord-276598-tm0yj2sn	643	19	is	be	VBZ
cord-276598-tm0yj2sn	643	20	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	643	21	to	to	IN
cord-276598-tm0yj2sn	643	22	hexamethyltriaminodibromophosphorane	hexamethyltriaminodibromophosphorane	NNP
cord-276598-tm0yj2sn	643	23	(	(	-LRB-
cord-276598-tm0yj2sn	643	24	(	(	-LRB-
cord-276598-tm0yj2sn	643	25	Me	Me	NNP
cord-276598-tm0yj2sn	643	26	2	2	CD
cord-276598-tm0yj2sn	643	27	N	n	CD
cord-276598-tm0yj2sn	643	28	)	)	-RRB-
cord-276598-tm0yj2sn	643	29	3	3	CD
cord-276598-tm0yj2sn	643	30	PBr	PBr	NNS
cord-276598-tm0yj2sn	643	31	2	2	CD
cord-276598-tm0yj2sn	643	32	)	)	-RRB-
cord-276598-tm0yj2sn	643	33	which	which	WDT
cord-276598-tm0yj2sn	643	34	is	be	VBZ
cord-276598-tm0yj2sn	643	35	ionized	ionize	VBN
cord-276598-tm0yj2sn	643	36	in	in	IN
cord-276598-tm0yj2sn	643	37	solution	solution	NN
cord-276598-tm0yj2sn	643	38	(	(	-LRB-
cord-276598-tm0yj2sn	643	39	Scheme	scheme	NN
cord-276598-tm0yj2sn	643	40	20	20	CD
cord-276598-tm0yj2sn	643	41	)	)	-RRB-
cord-276598-tm0yj2sn	643	42	[	[	-LRB-
cord-276598-tm0yj2sn	643	43	90	90	CD
cord-276598-tm0yj2sn	643	44	]	]	-RRB-
cord-276598-tm0yj2sn	643	45	.	.	.
cord-276598-tm0yj2sn	644	1	Subsequently	subsequently	RB
cord-276598-tm0yj2sn	644	2	,	,	,
cord-276598-tm0yj2sn	644	3	the	the	DT
cord-276598-tm0yj2sn	644	4	ionized	ionized	JJ
cord-276598-tm0yj2sn	644	5	(	(	-LRB-
cord-276598-tm0yj2sn	644	6	Me	Me	NNP
cord-276598-tm0yj2sn	644	7	2	2	CD
cord-276598-tm0yj2sn	644	8	N	n	CD
cord-276598-tm0yj2sn	644	9	)	)	-RRB-
cord-276598-tm0yj2sn	644	10	3	3	CD
cord-276598-tm0yj2sn	644	11	PBr	PBr	NNS
cord-276598-tm0yj2sn	644	12	2	2	CD
cord-276598-tm0yj2sn	644	13	and	and	CC
cord-276598-tm0yj2sn	644	14	diethyl	diethyl	NN
cord-276598-tm0yj2sn	644	15	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	644	16	phosphate	phosphate	NN
cord-276598-tm0yj2sn	644	17	undergo	undergo	VBP
cord-276598-tm0yj2sn	644	18	ligand	ligand	NN
cord-276598-tm0yj2sn	644	19	exchange	exchange	NN
cord-276598-tm0yj2sn	644	20	in	in	IN
cord-276598-tm0yj2sn	644	21	the	the	DT
cord-276598-tm0yj2sn	644	22	presence	presence	NN
cord-276598-tm0yj2sn	644	23	of	of	IN
cord-276598-tm0yj2sn	644	24	Et	Et	NNP
cord-276598-tm0yj2sn	644	25	3	3	CD
cord-276598-tm0yj2sn	644	26	N	N	NNP
cord-276598-tm0yj2sn	644	27	to	to	TO
cord-276598-tm0yj2sn	644	28	form	form	VB
cord-276598-tm0yj2sn	644	29	the	the	DT
cord-276598-tm0yj2sn	644	30	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	644	31	,	,	,
cord-276598-tm0yj2sn	644	32	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	644	33	(	(	-LRB-
cord-276598-tm0yj2sn	644	34	phosphaneyloxy)phosphonate	phosphaneyloxy)phosphonate	NNP
cord-276598-tm0yj2sn	644	35	amino	amino	NN
cord-276598-tm0yj2sn	644	36	-	-	HYPH
cord-276598-tm0yj2sn	644	37	hydrazine	hydrazine	NN
cord-276598-tm0yj2sn	644	38	-	-	HYPH
cord-276598-tm0yj2sn	644	39	bromide	bromide	NN
cord-276598-tm0yj2sn	644	40	salt	salt	NN
cord-276598-tm0yj2sn	644	41	complex	complex	NN
cord-276598-tm0yj2sn	644	42	.	.	.
cord-276598-tm0yj2sn	645	1	Nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	645	2	attack	attack	NN
cord-276598-tm0yj2sn	645	3	from	from	IN
cord-276598-tm0yj2sn	645	4	the	the	DT
cord-276598-tm0yj2sn	645	5	amine	amine	NN
cord-276598-tm0yj2sn	645	6	onto	onto	IN
cord-276598-tm0yj2sn	645	7	the	the	DT
cord-276598-tm0yj2sn	645	8	positively	positively	RB
cord-276598-tm0yj2sn	645	9	charged	charge	VBN
cord-276598-tm0yj2sn	645	10	P	p	NN
cord-276598-tm0yj2sn	645	11	results	result	NNS
cord-276598-tm0yj2sn	645	12	in	in	IN
cord-276598-tm0yj2sn	645	13	the	the	DT
cord-276598-tm0yj2sn	645	14	diethyl	diethyl	NN
cord-276598-tm0yj2sn	645	15	phosphoramidate	phosphoramidate	JJ
cord-276598-tm0yj2sn	645	16	bromide	bromide	NN
cord-276598-tm0yj2sn	645	17	salt	salt	NN
cord-276598-tm0yj2sn	645	18	,	,	,
cord-276598-tm0yj2sn	645	19	which	which	WDT
cord-276598-tm0yj2sn	645	20	reacts	react	VBZ
cord-276598-tm0yj2sn	645	21	with	with	IN
cord-276598-tm0yj2sn	645	22	Et	Et	NNP
cord-276598-tm0yj2sn	645	23	3	3	CD
cord-276598-tm0yj2sn	645	24	N	N	NNP
cord-276598-tm0yj2sn	645	25	to	to	TO
cord-276598-tm0yj2sn	645	26	give	give	VB
cord-276598-tm0yj2sn	645	27	the	the	DT
cord-276598-tm0yj2sn	645	28	desired	desire	VBN
cord-276598-tm0yj2sn	645	29	product	product	NN
cord-276598-tm0yj2sn	645	30	with	with	IN
cord-276598-tm0yj2sn	645	31	a	a	DT
cord-276598-tm0yj2sn	645	32	concomitant	concomitant	JJ
cord-276598-tm0yj2sn	645	33	elimination	elimination	NN
cord-276598-tm0yj2sn	645	34	of	of	IN
cord-276598-tm0yj2sn	645	35	triethylammonium	triethylammonium	NN
cord-276598-tm0yj2sn	645	36	bromide	bromide	NN
cord-276598-tm0yj2sn	645	37	.	.	.
cord-276598-tm0yj2sn	646	1	Apart	apart	RB
cord-276598-tm0yj2sn	646	2	from	from	IN
cord-276598-tm0yj2sn	646	3	the	the	DT
cord-276598-tm0yj2sn	646	4	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	646	5	Et	Et	NNP
cord-276598-tm0yj2sn	646	6	3	3	CD
cord-276598-tm0yj2sn	646	7	N	n	NN
cord-276598-tm0yj2sn	646	8	salt	salt	NN
cord-276598-tm0yj2sn	646	9	waste	waste	NN
cord-276598-tm0yj2sn	646	10	generated	generate	VBN
cord-276598-tm0yj2sn	646	11	,	,	,
cord-276598-tm0yj2sn	646	12	the	the	DT
cord-276598-tm0yj2sn	646	13	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	646	14	process	process	NN
cord-276598-tm0yj2sn	646	15	is	be	VBZ
cord-276598-tm0yj2sn	646	16	prone	prone	JJ
cord-276598-tm0yj2sn	646	17	to	to	IN
cord-276598-tm0yj2sn	646	18	the	the	DT
cord-276598-tm0yj2sn	646	19	formation	formation	NN
cord-276598-tm0yj2sn	646	20	of	of	IN
cord-276598-tm0yj2sn	646	21	significant	significant	JJ
cord-276598-tm0yj2sn	646	22	quantities	quantity	NNS
cord-276598-tm0yj2sn	646	23	of	of	IN
cord-276598-tm0yj2sn	646	24	pyrophosphate	pyrophosphate	NN
cord-276598-tm0yj2sn	646	25	or	or	CC
cord-276598-tm0yj2sn	646	26	phosphanetetraamine	phosphanetetraamine	JJ
cord-276598-tm0yj2sn	646	27	bromide	bromide	NN
cord-276598-tm0yj2sn	646	28	salt	salt	NN
cord-276598-tm0yj2sn	646	29	side	side	NN
cord-276598-tm0yj2sn	646	30	products	product	NNS
cord-276598-tm0yj2sn	646	31	,	,	,
cord-276598-tm0yj2sn	646	32	resulting	result	VBG
cord-276598-tm0yj2sn	646	33	in	in	IN
cord-276598-tm0yj2sn	646	34	a	a	DT
cord-276598-tm0yj2sn	646	35	low	low	JJ
cord-276598-tm0yj2sn	646	36	yield	yield	NN
cord-276598-tm0yj2sn	646	37	.	.	.
cord-276598-tm0yj2sn	647	1	Nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	647	2	attack	attack	NN
cord-276598-tm0yj2sn	647	3	from	from	IN
cord-276598-tm0yj2sn	647	4	the	the	DT
cord-276598-tm0yj2sn	647	5	amine	amine	NN
cord-276598-tm0yj2sn	647	6	onto	onto	IN
cord-276598-tm0yj2sn	647	7	the	the	DT
cord-276598-tm0yj2sn	647	8	positively	positively	RB
cord-276598-tm0yj2sn	647	9	charged	charge	VBN
cord-276598-tm0yj2sn	647	10	P	p	NN
cord-276598-tm0yj2sn	647	11	results	result	NNS
cord-276598-tm0yj2sn	647	12	in	in	IN
cord-276598-tm0yj2sn	647	13	the	the	DT
cord-276598-tm0yj2sn	647	14	diethyl	diethyl	NN
cord-276598-tm0yj2sn	647	15	phosphoramidate	phosphoramidate	JJ
cord-276598-tm0yj2sn	647	16	bromide	bromide	NN
cord-276598-tm0yj2sn	647	17	salt	salt	NN
cord-276598-tm0yj2sn	647	18	,	,	,
cord-276598-tm0yj2sn	647	19	which	which	WDT
cord-276598-tm0yj2sn	647	20	reacts	react	VBZ
cord-276598-tm0yj2sn	647	21	with	with	IN
cord-276598-tm0yj2sn	647	22	Et3N	Et3N	NNP
cord-276598-tm0yj2sn	647	23	to	to	TO
cord-276598-tm0yj2sn	647	24	give	give	VB
cord-276598-tm0yj2sn	647	25	the	the	DT
cord-276598-tm0yj2sn	647	26	desired	desire	VBN
cord-276598-tm0yj2sn	647	27	product	product	NN
cord-276598-tm0yj2sn	647	28	with	with	IN
cord-276598-tm0yj2sn	647	29	a	a	DT
cord-276598-tm0yj2sn	647	30	concomitant	concomitant	JJ
cord-276598-tm0yj2sn	647	31	elimination	elimination	NN
cord-276598-tm0yj2sn	647	32	of	of	IN
cord-276598-tm0yj2sn	647	33	triethylammonium	triethylammonium	NN
cord-276598-tm0yj2sn	647	34	bromide	bromide	NN
cord-276598-tm0yj2sn	647	35	.	.	.
cord-276598-tm0yj2sn	648	1	Apart	apart	RB
cord-276598-tm0yj2sn	648	2	from	from	IN
cord-276598-tm0yj2sn	648	3	the	the	DT
cord-276598-tm0yj2sn	648	4	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	648	5	Et3N	Et3N	NNP
cord-276598-tm0yj2sn	648	6	salt	salt	NN
cord-276598-tm0yj2sn	648	7	waste	waste	NN
cord-276598-tm0yj2sn	648	8	generated	generate	VBN
cord-276598-tm0yj2sn	648	9	,	,	,
cord-276598-tm0yj2sn	648	10	the	the	DT
cord-276598-tm0yj2sn	648	11	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	648	12	process	process	NN
cord-276598-tm0yj2sn	648	13	is	be	VBZ
cord-276598-tm0yj2sn	648	14	prone	prone	JJ
cord-276598-tm0yj2sn	648	15	to	to	IN
cord-276598-tm0yj2sn	648	16	the	the	DT
cord-276598-tm0yj2sn	648	17	formation	formation	NN
cord-276598-tm0yj2sn	648	18	of	of	IN
cord-276598-tm0yj2sn	648	19	significant	significant	JJ
cord-276598-tm0yj2sn	648	20	quantities	quantity	NNS
cord-276598-tm0yj2sn	648	21	of	of	IN
cord-276598-tm0yj2sn	648	22	pyrophosphate	pyrophosphate	NN
cord-276598-tm0yj2sn	648	23	or	or	CC
cord-276598-tm0yj2sn	648	24	phosphanetetraamine	phosphanetetraamine	JJ
cord-276598-tm0yj2sn	648	25	bromide	bromide	NN
cord-276598-tm0yj2sn	648	26	salt	salt	NN
cord-276598-tm0yj2sn	648	27	side	side	NN
cord-276598-tm0yj2sn	648	28	products	product	NNS
cord-276598-tm0yj2sn	648	29	,	,	,
cord-276598-tm0yj2sn	648	30	resulting	result	VBG
cord-276598-tm0yj2sn	648	31	in	in	IN
cord-276598-tm0yj2sn	648	32	a	a	DT
cord-276598-tm0yj2sn	648	33	low	low	JJ
cord-276598-tm0yj2sn	648	34	yield	yield	NN
cord-276598-tm0yj2sn	648	35	.	.	.
cord-276598-tm0yj2sn	649	1	The	the	DT
cord-276598-tm0yj2sn	649	2	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	649	3	steps	step	NNS
cord-276598-tm0yj2sn	649	4	for	for	IN
cord-276598-tm0yj2sn	649	5	the	the	DT
cord-276598-tm0yj2sn	649	6	synthesis	synthesis	NN
cord-276598-tm0yj2sn	649	7	of	of	IN
cord-276598-tm0yj2sn	649	8	P	P	NNP
cord-276598-tm0yj2sn	649	9	-	-	HYPH
cord-276598-tm0yj2sn	649	10	N	N	NNP
cord-276598-tm0yj2sn	649	11	via	via	IN
cord-276598-tm0yj2sn	649	12	a	a	DT
cord-276598-tm0yj2sn	649	13	salt	salt	NN
cord-276598-tm0yj2sn	649	14	elimination	elimination	NN
cord-276598-tm0yj2sn	649	15	route	route	NN
cord-276598-tm0yj2sn	649	16	were	be	VBD
cord-276598-tm0yj2sn	649	17	not	not	RB
cord-276598-tm0yj2sn	649	18	proposed	propose	VBN
cord-276598-tm0yj2sn	649	19	by	by	IN
cord-276598-tm0yj2sn	649	20	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	649	21	et	et	FW
cord-276598-tm0yj2sn	649	22	al	al	NNP
cord-276598-tm0yj2sn	649	23	.	.	.
cord-276598-tm0yj2sn	650	1	[	[	-LRB-
cord-276598-tm0yj2sn	650	2	89	89	CD
cord-276598-tm0yj2sn	650	3	]	]	-RRB-
cord-276598-tm0yj2sn	650	4	;	;	:
cord-276598-tm0yj2sn	650	5	however	however	RB
cord-276598-tm0yj2sn	650	6	,	,	,
cord-276598-tm0yj2sn	650	7	based	base	VBN
cord-276598-tm0yj2sn	650	8	on	on	IN
cord-276598-tm0yj2sn	650	9	the	the	DT
cord-276598-tm0yj2sn	650	10	roles	role	NNS
cord-276598-tm0yj2sn	650	11	of	of	IN
cord-276598-tm0yj2sn	650	12	KHCO3	KHCO3	NNP
cord-276598-tm0yj2sn	650	13	,	,	,
cord-276598-tm0yj2sn	650	14	K2CO3	K2CO3	NNP
cord-276598-tm0yj2sn	650	15	,	,	,
cord-276598-tm0yj2sn	650	16	and	and	CC
cord-276598-tm0yj2sn	650	17	[	[	-LRB-
cord-276598-tm0yj2sn	650	18	n	n	NN
cord-276598-tm0yj2sn	650	19	-	-	HYPH
cord-276598-tm0yj2sn	650	20	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	650	21	as	as	IN
cord-276598-tm0yj2sn	650	22	outlined	outline	VBN
cord-276598-tm0yj2sn	650	23	in	in	IN
cord-276598-tm0yj2sn	650	24	the	the	DT
cord-276598-tm0yj2sn	650	25	paper	paper	NN
cord-276598-tm0yj2sn	650	26	and	and	CC
cord-276598-tm0yj2sn	650	27	a	a	DT
cord-276598-tm0yj2sn	650	28	recently	recently	RB
cord-276598-tm0yj2sn	650	29	proposed	propose	VBN
cord-276598-tm0yj2sn	650	30	mechanism	mechanism	NN
cord-276598-tm0yj2sn	650	31	for	for	IN
cord-276598-tm0yj2sn	650	32	an	an	DT
cord-276598-tm0yj2sn	650	33	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	650	34	-	-	HYPH
cord-276598-tm0yj2sn	650	35	Todd	Todd	NNP
cord-276598-tm0yj2sn	650	36	type	type	NN
cord-276598-tm0yj2sn	650	37	reaction	reaction	NN
cord-276598-tm0yj2sn	650	38	,	,	,
cord-276598-tm0yj2sn	650	39	a	a	DT
cord-276598-tm0yj2sn	650	40	probable	probable	JJ
cord-276598-tm0yj2sn	650	41	mechanism	mechanism	NN
cord-276598-tm0yj2sn	650	42	can	can	MD
cord-276598-tm0yj2sn	650	43	be	be	VB
cord-276598-tm0yj2sn	650	44	postulated	postulate	VBN
cord-276598-tm0yj2sn	650	45	(	(	-LRB-
cord-276598-tm0yj2sn	650	46	Scheme	scheme	NN
cord-276598-tm0yj2sn	650	47	21	21	CD
cord-276598-tm0yj2sn	650	48	)	)	-RRB-
cord-276598-tm0yj2sn	650	49	[	[	-LRB-
cord-276598-tm0yj2sn	650	50	121	121	CD
cord-276598-tm0yj2sn	650	51	]	]	-RRB-
cord-276598-tm0yj2sn	650	52	.	.	.
cord-276598-tm0yj2sn	651	1	In	in	IN
cord-276598-tm0yj2sn	651	2	the	the	DT
cord-276598-tm0yj2sn	651	3	reacting	react	VBG
cord-276598-tm0yj2sn	651	4	system	system	NN
cord-276598-tm0yj2sn	651	5	,	,	,
cord-276598-tm0yj2sn	651	6	the	the	DT
cord-276598-tm0yj2sn	651	7	HCO3	HCO3	NNP
cord-276598-tm0yj2sn	651	8	−	−	NNP
cord-276598-tm0yj2sn	651	9	migrates	migrate	VBZ
cord-276598-tm0yj2sn	651	10	to	to	IN
cord-276598-tm0yj2sn	651	11	the	the	DT
cord-276598-tm0yj2sn	651	12	The	the	DT
cord-276598-tm0yj2sn	651	13	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	651	14	steps	step	NNS
cord-276598-tm0yj2sn	651	15	for	for	IN
cord-276598-tm0yj2sn	651	16	the	the	DT
cord-276598-tm0yj2sn	651	17	synthesis	synthesis	NN
cord-276598-tm0yj2sn	651	18	of	of	IN
cord-276598-tm0yj2sn	651	19	P	P	NNP
cord-276598-tm0yj2sn	651	20	-	-	HYPH
cord-276598-tm0yj2sn	651	21	N	N	NNP
cord-276598-tm0yj2sn	651	22	via	via	IN
cord-276598-tm0yj2sn	651	23	a	a	DT
cord-276598-tm0yj2sn	651	24	salt	salt	NN
cord-276598-tm0yj2sn	651	25	elimination	elimination	NN
cord-276598-tm0yj2sn	651	26	route	route	NN
cord-276598-tm0yj2sn	651	27	were	be	VBD
cord-276598-tm0yj2sn	651	28	not	not	RB
cord-276598-tm0yj2sn	651	29	proposed	propose	VBN
cord-276598-tm0yj2sn	651	30	by	by	IN
cord-276598-tm0yj2sn	651	31	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	651	32	et	et	FW
cord-276598-tm0yj2sn	651	33	al	al	NNP
cord-276598-tm0yj2sn	651	34	.	.	.
cord-276598-tm0yj2sn	652	1	[	[	-LRB-
cord-276598-tm0yj2sn	652	2	89	89	CD
cord-276598-tm0yj2sn	652	3	]	]	-RRB-
cord-276598-tm0yj2sn	652	4	;	;	:
cord-276598-tm0yj2sn	652	5	however	however	RB
cord-276598-tm0yj2sn	652	6	,	,	,
cord-276598-tm0yj2sn	652	7	based	base	VBN
cord-276598-tm0yj2sn	652	8	on	on	IN
cord-276598-tm0yj2sn	652	9	the	the	DT
cord-276598-tm0yj2sn	652	10	roles	role	NNS
cord-276598-tm0yj2sn	652	11	of	of	IN
cord-276598-tm0yj2sn	652	12	KHCO	KHCO	NNP
cord-276598-tm0yj2sn	652	13	3	3	CD
cord-276598-tm0yj2sn	652	14	,	,	,
cord-276598-tm0yj2sn	652	15	K	K	NNP
cord-276598-tm0yj2sn	652	16	2	2	CD
cord-276598-tm0yj2sn	652	17	CO	CO	NNP
cord-276598-tm0yj2sn	652	18	3	3	CD
cord-276598-tm0yj2sn	652	19	,	,	,
cord-276598-tm0yj2sn	652	20	and	and	CC
cord-276598-tm0yj2sn	652	21	[	[	-LRB-
cord-276598-tm0yj2sn	652	22	n	n	NNP
cord-276598-tm0yj2sn	652	23	-	-	HYPH
cord-276598-tm0yj2sn	652	24	Bu	Bu	NNP
cord-276598-tm0yj2sn	652	25	4	4	CD
cord-276598-tm0yj2sn	652	26	N]Br	N]Br	NNP
cord-276598-tm0yj2sn	652	27	as	as	IN
cord-276598-tm0yj2sn	652	28	outlined	outline	VBN
cord-276598-tm0yj2sn	652	29	in	in	IN
cord-276598-tm0yj2sn	652	30	the	the	DT
cord-276598-tm0yj2sn	652	31	paper	paper	NN
cord-276598-tm0yj2sn	652	32	and	and	CC
cord-276598-tm0yj2sn	652	33	a	a	DT
cord-276598-tm0yj2sn	652	34	recently	recently	RB
cord-276598-tm0yj2sn	652	35	proposed	propose	VBN
cord-276598-tm0yj2sn	652	36	mechanism	mechanism	NN
cord-276598-tm0yj2sn	652	37	for	for	IN
cord-276598-tm0yj2sn	652	38	an	an	DT
cord-276598-tm0yj2sn	652	39	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	652	40	-	-	HYPH
cord-276598-tm0yj2sn	652	41	Todd	Todd	NNP
cord-276598-tm0yj2sn	652	42	type	type	NN
cord-276598-tm0yj2sn	652	43	reaction	reaction	NN
cord-276598-tm0yj2sn	652	44	,	,	,
cord-276598-tm0yj2sn	652	45	a	a	DT
cord-276598-tm0yj2sn	652	46	probable	probable	JJ
cord-276598-tm0yj2sn	652	47	mechanism	mechanism	NN
cord-276598-tm0yj2sn	652	48	can	can	MD
cord-276598-tm0yj2sn	652	49	be	be	VB
cord-276598-tm0yj2sn	652	50	postulated	postulate	VBN
cord-276598-tm0yj2sn	652	51	(	(	-LRB-
cord-276598-tm0yj2sn	652	52	Scheme	scheme	NN
cord-276598-tm0yj2sn	652	53	21	21	CD
cord-276598-tm0yj2sn	652	54	)	)	-RRB-
cord-276598-tm0yj2sn	652	55	[	[	-LRB-
cord-276598-tm0yj2sn	652	56	121	121	CD
cord-276598-tm0yj2sn	652	57	]	]	-RRB-
cord-276598-tm0yj2sn	652	58	.	.	.
cord-276598-tm0yj2sn	653	1	In	in	IN
cord-276598-tm0yj2sn	653	2	the	the	DT
cord-276598-tm0yj2sn	653	3	reacting	react	VBG
cord-276598-tm0yj2sn	653	4	system	system	NN
cord-276598-tm0yj2sn	653	5	,	,	,
cord-276598-tm0yj2sn	653	6	the	the	DT
cord-276598-tm0yj2sn	653	7	HCO	HCO	NNP
cord-276598-tm0yj2sn	653	8	3	3	CD
cord-276598-tm0yj2sn	653	9	−	−	NNP
cord-276598-tm0yj2sn	653	10	migrates	migrate	VBZ
cord-276598-tm0yj2sn	653	11	to	to	IN
cord-276598-tm0yj2sn	653	12	the	the	DT
cord-276598-tm0yj2sn	653	13	organic	organic	JJ
cord-276598-tm0yj2sn	653	14	phase	phase	NN
cord-276598-tm0yj2sn	653	15	in	in	IN
cord-276598-tm0yj2sn	653	16	the	the	DT
cord-276598-tm0yj2sn	653	17	presence	presence	NN
cord-276598-tm0yj2sn	653	18	of	of	IN
cord-276598-tm0yj2sn	653	19	[	[	-LRB-
cord-276598-tm0yj2sn	653	20	n	n	NNP
cord-276598-tm0yj2sn	653	21	-	-	HYPH
cord-276598-tm0yj2sn	653	22	Bu	Bu	NNP
cord-276598-tm0yj2sn	653	23	4	4	CD
cord-276598-tm0yj2sn	653	24	N]Br	N]Br	NNP
cord-276598-tm0yj2sn	653	25	as	as	IN
cord-276598-tm0yj2sn	653	26	the	the	DT
cord-276598-tm0yj2sn	653	27	catalyst	catalyst	NN
cord-276598-tm0yj2sn	653	28	,	,	,
cord-276598-tm0yj2sn	653	29	where	where	WRB
cord-276598-tm0yj2sn	653	30	it	-PRON-	PRP
cord-276598-tm0yj2sn	653	31	is	be	VBZ
cord-276598-tm0yj2sn	653	32	protonated	protonate	VBN
cord-276598-tm0yj2sn	653	33	and	and	CC
cord-276598-tm0yj2sn	653	34	reacts	react	VBZ
cord-276598-tm0yj2sn	653	35	with	with	IN
cord-276598-tm0yj2sn	653	36	CCl	CCl	NNS
cord-276598-tm0yj2sn	653	37	4	4	CD
cord-276598-tm0yj2sn	653	38	to	to	TO
cord-276598-tm0yj2sn	653	39	form	form	VB
cord-276598-tm0yj2sn	653	40	anionic	anionic	JJ
cord-276598-tm0yj2sn	653	41	HCO	HCO	NNP
cord-276598-tm0yj2sn	653	42	3	3	CD
cord-276598-tm0yj2sn	653	43	ClH	ClH	NNP
cord-276598-tm0yj2sn	653	44	−	−	NN
cord-276598-tm0yj2sn	653	45	and	and	CC
cord-276598-tm0yj2sn	653	46	cationic	cationic	JJ
cord-276598-tm0yj2sn	653	47	Cl	Cl	NNP
cord-276598-tm0yj2sn	653	48	3	3	CD
cord-276598-tm0yj2sn	653	49	C	C	NNP
cord-276598-tm0yj2sn	654	1	+	+	UH
cord-276598-tm0yj2sn	654	2	.	.	.
cord-276598-tm0yj2sn	655	1	The	the	DT
cord-276598-tm0yj2sn	655	2	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	655	3	H	H	NNP
cord-276598-tm0yj2sn	655	4	-	-	HYPH
cord-276598-tm0yj2sn	655	5	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	655	6	(	(	-LRB-
cord-276598-tm0yj2sn	655	7	(	(	-LRB-
cord-276598-tm0yj2sn	655	8	RO	RO	NNP
cord-276598-tm0yj2sn	655	9	)	)	-RRB-
cord-276598-tm0yj2sn	655	10	2	2	CD
cord-276598-tm0yj2sn	656	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	657	1	,	,	,
cord-276598-tm0yj2sn	657	2	R	r	NN
cord-276598-tm0yj2sn	657	3	=	=	NN
cord-276598-tm0yj2sn	657	4	alkyl	alkyl	NN
cord-276598-tm0yj2sn	657	5	)	)	-RRB-
cord-276598-tm0yj2sn	657	6	is	be	VBZ
cord-276598-tm0yj2sn	657	7	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	657	8	by	by	IN
cord-276598-tm0yj2sn	657	9	the	the	DT
cord-276598-tm0yj2sn	657	10	cationic	cationic	JJ
cord-276598-tm0yj2sn	657	11	Cl	Cl	NNP
cord-276598-tm0yj2sn	657	12	3	3	CD
cord-276598-tm0yj2sn	657	13	C	C	NNP
cord-276598-tm0yj2sn	657	14	+	+	CC
cord-276598-tm0yj2sn	657	15	to	to	TO
cord-276598-tm0yj2sn	657	16	yield	yield	VB
cord-276598-tm0yj2sn	657	17	CHCl	CHCl	NNS
cord-276598-tm0yj2sn	657	18	3	3	CD
cord-276598-tm0yj2sn	657	19	and	and	CC
cord-276598-tm0yj2sn	657	20	anionic	anionic	JJ
cord-276598-tm0yj2sn	657	21	phosphate	phosphate	NN
cord-276598-tm0yj2sn	657	22	,	,	,
cord-276598-tm0yj2sn	657	23	(	(	-LRB-
cord-276598-tm0yj2sn	657	24	RO	ro	NN
cord-276598-tm0yj2sn	657	25	)	)	-RRB-
cord-276598-tm0yj2sn	657	26	2	2	CD
cord-276598-tm0yj2sn	657	27	P(O	P(O	NNP
cord-276598-tm0yj2sn	657	28	)	)	-RRB-
cord-276598-tm0yj2sn	657	29	−	−	NNS
cord-276598-tm0yj2sn	657	30	.	.	.
cord-276598-tm0yj2sn	658	1	Next	next	RB
cord-276598-tm0yj2sn	658	2	,	,	,
cord-276598-tm0yj2sn	658	3	the	the	DT
cord-276598-tm0yj2sn	658	4	anionic	anionic	JJ
cord-276598-tm0yj2sn	658	5	phosphate	phosphate	NN
cord-276598-tm0yj2sn	658	6	reacts	react	VBZ
cord-276598-tm0yj2sn	658	7	with	with	IN
cord-276598-tm0yj2sn	658	8	HCO	HCO	NNP
cord-276598-tm0yj2sn	658	9	3	3	CD
cord-276598-tm0yj2sn	658	10	ClH	clh	NN
cord-276598-tm0yj2sn	658	11	−	−	NNP
cord-276598-tm0yj2sn	658	12	to	to	TO
cord-276598-tm0yj2sn	658	13	form	form	VB
cord-276598-tm0yj2sn	658	14	(	(	-LRB-
cord-276598-tm0yj2sn	658	15	RO	ro	NN
cord-276598-tm0yj2sn	658	16	)	)	-RRB-
cord-276598-tm0yj2sn	658	17	2	2	CD
cord-276598-tm0yj2sn	659	1	P(O)Cl	P(O)Cl	VBN
cord-276598-tm0yj2sn	660	1	(	(	-LRB-
cord-276598-tm0yj2sn	660	2	dACP	dacp	JJ
cord-276598-tm0yj2sn	660	3	;	;	:
cord-276598-tm0yj2sn	660	4	R	r	NN
cord-276598-tm0yj2sn	660	5	=	=	NN
cord-276598-tm0yj2sn	660	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	660	7	)	)	-RRB-
cord-276598-tm0yj2sn	660	8	and	and	CC
cord-276598-tm0yj2sn	660	9	H	H	NNP
cord-276598-tm0yj2sn	660	10	2	2	CD
cord-276598-tm0yj2sn	660	11	CO	CO	NNP
cord-276598-tm0yj2sn	660	12	3	3	CD
cord-276598-tm0yj2sn	660	13	.	.	.
cord-276598-tm0yj2sn	661	1	In	in	IN
cord-276598-tm0yj2sn	661	2	the	the	DT
cord-276598-tm0yj2sn	661	3	following	follow	VBG
cord-276598-tm0yj2sn	661	4	step	step	NN
cord-276598-tm0yj2sn	661	5	,	,	,
cord-276598-tm0yj2sn	661	6	a	a	DT
cord-276598-tm0yj2sn	661	7	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	661	8	substitution	substitution	NN
cord-276598-tm0yj2sn	661	9	between	between	IN
cord-276598-tm0yj2sn	661	10	the	the	DT
cord-276598-tm0yj2sn	661	11	amine	amine	NN
cord-276598-tm0yj2sn	661	12	and	and	CC
cord-276598-tm0yj2sn	661	13	dACP	dacp	NN
cord-276598-tm0yj2sn	661	14	results	result	NNS
cord-276598-tm0yj2sn	661	15	in	in	IN
cord-276598-tm0yj2sn	661	16	the	the	DT
cord-276598-tm0yj2sn	661	17	formation	formation	NN
cord-276598-tm0yj2sn	661	18	of	of	IN
cord-276598-tm0yj2sn	661	19	the	the	DT
cord-276598-tm0yj2sn	661	20	desired	desire	VBN
cord-276598-tm0yj2sn	661	21	product	product	NN
cord-276598-tm0yj2sn	661	22	.	.	.
cord-276598-tm0yj2sn	662	1	Meanwhile	meanwhile	RB
cord-276598-tm0yj2sn	662	2	,	,	,
cord-276598-tm0yj2sn	662	3	K	K	NNP
cord-276598-tm0yj2sn	662	4	2	2	CD
cord-276598-tm0yj2sn	662	5	CO	CO	NNP
cord-276598-tm0yj2sn	662	6	3	3	CD
cord-276598-tm0yj2sn	662	7	serves	serve	VBZ
cord-276598-tm0yj2sn	662	8	as	as	IN
cord-276598-tm0yj2sn	662	9	the	the	DT
cord-276598-tm0yj2sn	662	10	dehydrating	dehydrate	VBG
cord-276598-tm0yj2sn	662	11	agent	agent	NN
cord-276598-tm0yj2sn	662	12	in	in	IN
cord-276598-tm0yj2sn	662	13	the	the	DT
cord-276598-tm0yj2sn	662	14	reacting	react	VBG
cord-276598-tm0yj2sn	662	15	system	system	NN
cord-276598-tm0yj2sn	662	16	.	.	.
cord-276598-tm0yj2sn	663	1	The	the	DT
cord-276598-tm0yj2sn	663	2	plausible	plausible	JJ
cord-276598-tm0yj2sn	663	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	663	4	is	be	VBZ
cord-276598-tm0yj2sn	663	5	also	also	RB
cord-276598-tm0yj2sn	663	6	similar	similar	JJ
cord-276598-tm0yj2sn	663	7	when	when	WRB
cord-276598-tm0yj2sn	663	8	NaOH	NaOH	NNP
cord-276598-tm0yj2sn	663	9	and	and	CC
cord-276598-tm0yj2sn	663	10	The	the	DT
cord-276598-tm0yj2sn	663	11	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	663	12	steps	step	NNS
cord-276598-tm0yj2sn	663	13	for	for	IN
cord-276598-tm0yj2sn	663	14	the	the	DT
cord-276598-tm0yj2sn	663	15	synthesis	synthesis	NN
cord-276598-tm0yj2sn	663	16	of	of	IN
cord-276598-tm0yj2sn	663	17	P	P	NNP
cord-276598-tm0yj2sn	663	18	-	-	HYPH
cord-276598-tm0yj2sn	663	19	N	N	NNP
cord-276598-tm0yj2sn	663	20	via	via	IN
cord-276598-tm0yj2sn	663	21	a	a	DT
cord-276598-tm0yj2sn	663	22	salt	salt	NN
cord-276598-tm0yj2sn	663	23	elimination	elimination	NN
cord-276598-tm0yj2sn	663	24	route	route	NN
cord-276598-tm0yj2sn	663	25	were	be	VBD
cord-276598-tm0yj2sn	663	26	not	not	RB
cord-276598-tm0yj2sn	663	27	proposed	propose	VBN
cord-276598-tm0yj2sn	663	28	by	by	IN
cord-276598-tm0yj2sn	663	29	Zwierzak	Zwierzak	NNP
cord-276598-tm0yj2sn	663	30	et	et	FW
cord-276598-tm0yj2sn	663	31	al	al	NNP
cord-276598-tm0yj2sn	663	32	.	.	.
cord-276598-tm0yj2sn	664	1	[	[	-LRB-
cord-276598-tm0yj2sn	664	2	89	89	CD
cord-276598-tm0yj2sn	664	3	]	]	-RRB-
cord-276598-tm0yj2sn	664	4	;	;	:
cord-276598-tm0yj2sn	664	5	however	however	RB
cord-276598-tm0yj2sn	664	6	,	,	,
cord-276598-tm0yj2sn	664	7	based	base	VBN
cord-276598-tm0yj2sn	664	8	on	on	IN
cord-276598-tm0yj2sn	664	9	the	the	DT
cord-276598-tm0yj2sn	664	10	roles	role	NNS
cord-276598-tm0yj2sn	664	11	of	of	IN
cord-276598-tm0yj2sn	664	12	KHCO3	KHCO3	NNP
cord-276598-tm0yj2sn	664	13	,	,	,
cord-276598-tm0yj2sn	664	14	K2CO3	K2CO3	NNP
cord-276598-tm0yj2sn	664	15	,	,	,
cord-276598-tm0yj2sn	664	16	and	and	CC
cord-276598-tm0yj2sn	664	17	[	[	-LRB-
cord-276598-tm0yj2sn	664	18	n	n	NN
cord-276598-tm0yj2sn	664	19	-	-	HYPH
cord-276598-tm0yj2sn	664	20	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	664	21	as	as	IN
cord-276598-tm0yj2sn	664	22	outlined	outline	VBN
cord-276598-tm0yj2sn	664	23	in	in	IN
cord-276598-tm0yj2sn	664	24	the	the	DT
cord-276598-tm0yj2sn	664	25	paper	paper	NN
cord-276598-tm0yj2sn	664	26	and	and	CC
cord-276598-tm0yj2sn	664	27	a	a	DT
cord-276598-tm0yj2sn	664	28	recently	recently	RB
cord-276598-tm0yj2sn	664	29	proposed	propose	VBN
cord-276598-tm0yj2sn	664	30	mechanism	mechanism	NN
cord-276598-tm0yj2sn	664	31	for	for	IN
cord-276598-tm0yj2sn	664	32	an	an	DT
cord-276598-tm0yj2sn	664	33	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	664	34	-	-	HYPH
cord-276598-tm0yj2sn	664	35	Todd	Todd	NNP
cord-276598-tm0yj2sn	664	36	type	type	NN
cord-276598-tm0yj2sn	664	37	reaction	reaction	NN
cord-276598-tm0yj2sn	664	38	,	,	,
cord-276598-tm0yj2sn	664	39	a	a	DT
cord-276598-tm0yj2sn	664	40	probable	probable	JJ
cord-276598-tm0yj2sn	664	41	mechanism	mechanism	NN
cord-276598-tm0yj2sn	664	42	can	can	MD
cord-276598-tm0yj2sn	664	43	be	be	VB
cord-276598-tm0yj2sn	664	44	postulated	postulate	VBN
cord-276598-tm0yj2sn	664	45	(	(	-LRB-
cord-276598-tm0yj2sn	664	46	Scheme	scheme	NN
cord-276598-tm0yj2sn	664	47	21	21	CD
cord-276598-tm0yj2sn	664	48	)	)	-RRB-
cord-276598-tm0yj2sn	664	49	[	[	-LRB-
cord-276598-tm0yj2sn	664	50	121	121	CD
cord-276598-tm0yj2sn	664	51	]	]	-RRB-
cord-276598-tm0yj2sn	664	52	.	.	.
cord-276598-tm0yj2sn	665	1	In	in	IN
cord-276598-tm0yj2sn	665	2	the	the	DT
cord-276598-tm0yj2sn	665	3	reacting	react	VBG
cord-276598-tm0yj2sn	665	4	system	system	NN
cord-276598-tm0yj2sn	665	5	,	,	,
cord-276598-tm0yj2sn	665	6	the	the	DT
cord-276598-tm0yj2sn	665	7	HCO3	HCO3	NNP
cord-276598-tm0yj2sn	665	8	−	−	NNP
cord-276598-tm0yj2sn	665	9	migrates	migrate	VBZ
cord-276598-tm0yj2sn	665	10	to	to	IN
cord-276598-tm0yj2sn	665	11	the	the	DT
cord-276598-tm0yj2sn	665	12	organic	organic	JJ
cord-276598-tm0yj2sn	665	13	phase	phase	NN
cord-276598-tm0yj2sn	665	14	in	in	IN
cord-276598-tm0yj2sn	665	15	the	the	DT
cord-276598-tm0yj2sn	665	16	presence	presence	NN
cord-276598-tm0yj2sn	665	17	of	of	IN
cord-276598-tm0yj2sn	665	18	[	[	-LRB-
cord-276598-tm0yj2sn	665	19	n	n	NNP
cord-276598-tm0yj2sn	665	20	-	-	HYPH
cord-276598-tm0yj2sn	665	21	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	665	22	as	as	IN
cord-276598-tm0yj2sn	665	23	the	the	DT
cord-276598-tm0yj2sn	665	24	catalyst	catalyst	NN
cord-276598-tm0yj2sn	665	25	,	,	,
cord-276598-tm0yj2sn	665	26	where	where	WRB
cord-276598-tm0yj2sn	665	27	it	-PRON-	PRP
cord-276598-tm0yj2sn	665	28	is	be	VBZ
cord-276598-tm0yj2sn	665	29	protonated	protonate	VBN
cord-276598-tm0yj2sn	665	30	and	and	CC
cord-276598-tm0yj2sn	665	31	reacts	react	VBZ
cord-276598-tm0yj2sn	665	32	with	with	IN
cord-276598-tm0yj2sn	665	33	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	665	34	to	to	TO
cord-276598-tm0yj2sn	665	35	form	form	VB
cord-276598-tm0yj2sn	665	36	anionic	anionic	JJ
cord-276598-tm0yj2sn	665	37	HCO3ClH	HCO3ClH	NNP
cord-276598-tm0yj2sn	665	38	−	−	NNP
cord-276598-tm0yj2sn	665	39	and	and	CC
cord-276598-tm0yj2sn	665	40	cationic	cationic	JJ
cord-276598-tm0yj2sn	665	41	Cl3C	Cl3C	NNS
cord-276598-tm0yj2sn	666	1	+	+	UH
cord-276598-tm0yj2sn	666	2	.	.	.
cord-276598-tm0yj2sn	667	1	The	the	DT
cord-276598-tm0yj2sn	667	2	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	667	3	H	H	NNP
cord-276598-tm0yj2sn	667	4	-	-	HYPH
cord-276598-tm0yj2sn	667	5	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	667	6	(	(	-LRB-
cord-276598-tm0yj2sn	667	7	(	(	-LRB-
cord-276598-tm0yj2sn	667	8	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	667	9	,	,	,
cord-276598-tm0yj2sn	667	10	R	r	NN
cord-276598-tm0yj2sn	667	11	=	=	NN
cord-276598-tm0yj2sn	667	12	alkyl	alkyl	NN
cord-276598-tm0yj2sn	667	13	)	)	-RRB-
cord-276598-tm0yj2sn	667	14	is	be	VBZ
cord-276598-tm0yj2sn	667	15	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	667	16	by	by	IN
cord-276598-tm0yj2sn	667	17	the	the	DT
cord-276598-tm0yj2sn	667	18	cationic	cationic	JJ
cord-276598-tm0yj2sn	667	19	Cl3C	Cl3C	NNS
cord-276598-tm0yj2sn	667	20	+	+	SYM
cord-276598-tm0yj2sn	667	21	to	to	TO
cord-276598-tm0yj2sn	667	22	yield	yield	VB
cord-276598-tm0yj2sn	667	23	CHCl3	CHCl3	NNP
cord-276598-tm0yj2sn	667	24	and	and	CC
cord-276598-tm0yj2sn	667	25	anionic	anionic	JJ
cord-276598-tm0yj2sn	667	26	phosphate	phosphate	NN
cord-276598-tm0yj2sn	667	27	,	,	,
cord-276598-tm0yj2sn	667	28	(	(	-LRB-
cord-276598-tm0yj2sn	667	29	RO)2P(O	ro)2p(o	NN
cord-276598-tm0yj2sn	667	30	)	)	-RRB-
cord-276598-tm0yj2sn	667	31	−	−	NNS
cord-276598-tm0yj2sn	667	32	.	.	.
cord-276598-tm0yj2sn	668	1	Next	next	RB
cord-276598-tm0yj2sn	668	2	,	,	,
cord-276598-tm0yj2sn	668	3	the	the	DT
cord-276598-tm0yj2sn	668	4	anionic	anionic	JJ
cord-276598-tm0yj2sn	668	5	phosphate	phosphate	NN
cord-276598-tm0yj2sn	668	6	reacts	react	VBZ
cord-276598-tm0yj2sn	668	7	with	with	IN
cord-276598-tm0yj2sn	668	8	HCO3ClH	HCO3ClH	NNP
cord-276598-tm0yj2sn	668	9	−	−	NNP
cord-276598-tm0yj2sn	668	10	to	to	TO
cord-276598-tm0yj2sn	668	11	form	form	VB
cord-276598-tm0yj2sn	669	1	(	(	-LRB-
cord-276598-tm0yj2sn	669	2	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	669	3	(	(	-LRB-
cord-276598-tm0yj2sn	669	4	dACP	dacp	NN
cord-276598-tm0yj2sn	669	5	;	;	:
cord-276598-tm0yj2sn	669	6	R	r	NN
cord-276598-tm0yj2sn	669	7	=	=	NN
cord-276598-tm0yj2sn	669	8	alkyl	alkyl	NN
cord-276598-tm0yj2sn	669	9	)	)	-RRB-
cord-276598-tm0yj2sn	669	10	and	and	CC
cord-276598-tm0yj2sn	669	11	H2CO3	H2CO3	NNP
cord-276598-tm0yj2sn	669	12	.	.	.
cord-276598-tm0yj2sn	670	1	In	in	IN
cord-276598-tm0yj2sn	670	2	the	the	DT
cord-276598-tm0yj2sn	670	3	following	follow	VBG
cord-276598-tm0yj2sn	670	4	step	step	NN
cord-276598-tm0yj2sn	670	5	,	,	,
cord-276598-tm0yj2sn	670	6	a	a	DT
cord-276598-tm0yj2sn	670	7	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	670	8	substitution	substitution	NN
cord-276598-tm0yj2sn	670	9	between	between	IN
cord-276598-tm0yj2sn	670	10	the	the	DT
cord-276598-tm0yj2sn	670	11	amine	amine	NN
cord-276598-tm0yj2sn	670	12	and	and	CC
cord-276598-tm0yj2sn	670	13	dACP	dacp	NN
cord-276598-tm0yj2sn	670	14	results	result	NNS
cord-276598-tm0yj2sn	670	15	in	in	IN
cord-276598-tm0yj2sn	670	16	the	the	DT
cord-276598-tm0yj2sn	670	17	formation	formation	NN
cord-276598-tm0yj2sn	670	18	of	of	IN
cord-276598-tm0yj2sn	670	19	the	the	DT
cord-276598-tm0yj2sn	670	20	desired	desire	VBN
cord-276598-tm0yj2sn	670	21	product	product	NN
cord-276598-tm0yj2sn	670	22	.	.	.
cord-276598-tm0yj2sn	671	1	Meanwhile	meanwhile	RB
cord-276598-tm0yj2sn	671	2	,	,	,
cord-276598-tm0yj2sn	671	3	K2CO3	K2CO3	NNP
cord-276598-tm0yj2sn	671	4	serves	serve	VBZ
cord-276598-tm0yj2sn	671	5	as	as	IN
cord-276598-tm0yj2sn	671	6	the	the	DT
cord-276598-tm0yj2sn	671	7	dehydrating	dehydrate	VBG
cord-276598-tm0yj2sn	671	8	agent	agent	NN
cord-276598-tm0yj2sn	671	9	in	in	IN
cord-276598-tm0yj2sn	671	10	the	the	DT
cord-276598-tm0yj2sn	671	11	reacting	react	VBG
cord-276598-tm0yj2sn	671	12	system	system	NN
cord-276598-tm0yj2sn	671	13	.	.	.
cord-276598-tm0yj2sn	672	1	The	the	DT
cord-276598-tm0yj2sn	672	2	plausible	plausible	JJ
cord-276598-tm0yj2sn	672	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	672	4	is	be	VBZ
cord-276598-tm0yj2sn	672	5	also	also	RB
cord-276598-tm0yj2sn	672	6	similar	similar	JJ
cord-276598-tm0yj2sn	672	7	when	when	WRB
cord-276598-tm0yj2sn	672	8	NaOH	NaOH	NNP
cord-276598-tm0yj2sn	672	9	and	and	CC
cord-276598-tm0yj2sn	672	10	[	[	-LRB-
cord-276598-tm0yj2sn	672	11	BnEt3N]Cl	BnEt3N]Cl	NNP
cord-276598-tm0yj2sn	672	12	are	be	VBP
cord-276598-tm0yj2sn	672	13	used	use	VBN
cord-276598-tm0yj2sn	672	14	in	in	IN
cord-276598-tm0yj2sn	672	15	place	place	NN
cord-276598-tm0yj2sn	672	16	of	of	IN
cord-276598-tm0yj2sn	672	17	KHCO3	KHCO3	NNP
cord-276598-tm0yj2sn	672	18	and	and	CC
cord-276598-tm0yj2sn	672	19	[	[	-LRB-
cord-276598-tm0yj2sn	672	20	n	n	NNP
cord-276598-tm0yj2sn	672	21	-	-	HYPH
cord-276598-tm0yj2sn	672	22	Bu4N]Br	Bu4N]Br	NNP
cord-276598-tm0yj2sn	672	23	,	,	,
cord-276598-tm0yj2sn	672	24	respectively	respectively	RB
cord-276598-tm0yj2sn	672	25	.	.	.
cord-276598-tm0yj2sn	673	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	673	2	21	21	CD
cord-276598-tm0yj2sn	673	3	.	.	.
cord-276598-tm0yj2sn	674	1	Potential	potential	JJ
cord-276598-tm0yj2sn	674	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	674	3	for	for	IN
cord-276598-tm0yj2sn	674	4	the	the	DT
cord-276598-tm0yj2sn	674	5	formation	formation	NN
cord-276598-tm0yj2sn	674	6	of	of	IN
cord-276598-tm0yj2sn	674	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	674	8	using	use	VBG
cord-276598-tm0yj2sn	674	9	a	a	DT
cord-276598-tm0yj2sn	674	10	salt	salt	NN
cord-276598-tm0yj2sn	674	11	elimination	elimination	NN
cord-276598-tm0yj2sn	674	12	route	route	NN
cord-276598-tm0yj2sn	674	13	.	.	.
cord-276598-tm0yj2sn	675	1	[	[	-LRB-
cord-276598-tm0yj2sn	675	2	96	96	CD
cord-276598-tm0yj2sn	675	3	]	]	-RRB-
cord-276598-tm0yj2sn	675	4	.	.	.
cord-276598-tm0yj2sn	676	1	Then	then	RB
cord-276598-tm0yj2sn	676	2	,	,	,
cord-276598-tm0yj2sn	676	3	the	the	DT
cord-276598-tm0yj2sn	676	4	dACP	dacp	NN
cord-276598-tm0yj2sn	676	5	reacts	react	VBZ
cord-276598-tm0yj2sn	676	6	with	with	IN
cord-276598-tm0yj2sn	676	7	N	n	CD
cord-276598-tm0yj2sn	676	8	-	-	HYPH
cord-276598-tm0yj2sn	676	9	phenylformamide	phenylformamide	NN
cord-276598-tm0yj2sn	676	10	or	or	CC
cord-276598-tm0yj2sn	676	11	the	the	DT
cord-276598-tm0yj2sn	676	12	2-chloro	2-chloro	CD
cord-276598-tm0yj2sn	676	13	-	-	HYPH
cord-276598-tm0yj2sn	676	14	N	n	CD
cord-276598-tm0yj2sn	676	15	-	-	HYPH
cord-276598-tm0yj2sn	676	16	phenylacetamide	phenylacetamide	NN
cord-276598-tm0yj2sn	676	17	derivative	derivative	NN
cord-276598-tm0yj2sn	676	18	to	to	TO
cord-276598-tm0yj2sn	676	19	form	form	VB
cord-276598-tm0yj2sn	676	20	the	the	DT
cord-276598-tm0yj2sn	676	21	product	product	NN
cord-276598-tm0yj2sn	676	22	.	.	.
cord-276598-tm0yj2sn	677	1	Alternatively	alternatively	RB
cord-276598-tm0yj2sn	677	2	,	,	,
cord-276598-tm0yj2sn	677	3	the	the	DT
cord-276598-tm0yj2sn	677	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	677	5	could	could	MD
cord-276598-tm0yj2sn	677	6	proceed	proceed	VB
cord-276598-tm0yj2sn	677	7	via	via	IN
cord-276598-tm0yj2sn	677	8	a	a	DT
cord-276598-tm0yj2sn	677	9	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	677	10	(	(	-LRB-
cord-276598-tm0yj2sn	677	11	acetyl)(phenyl)phosphoramidate	acetyl)(phenyl)phosphoramidate	NNP
cord-276598-tm0yj2sn	677	12	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	677	13	,	,	,
cord-276598-tm0yj2sn	677	14	which	which	WDT
cord-276598-tm0yj2sn	677	15	subsequently	subsequently	RB
cord-276598-tm0yj2sn	677	16	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	677	17	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	677	18	to	to	TO
cord-276598-tm0yj2sn	677	19	afford	afford	VB
cord-276598-tm0yj2sn	677	20	the	the	DT
cord-276598-tm0yj2sn	677	21	product	product	NN
cord-276598-tm0yj2sn	677	22	.	.	.
cord-276598-tm0yj2sn	678	1	The	the	DT
cord-276598-tm0yj2sn	678	2	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	678	3	of	of	IN
cord-276598-tm0yj2sn	678	4	P	P	NNP
cord-276598-tm0yj2sn	678	5	-	-	HYPH
cord-276598-tm0yj2sn	678	6	N	n	CD
cord-276598-tm0yj2sn	678	7	formation	formation	NN
cord-276598-tm0yj2sn	678	8	from	from	IN
cord-276598-tm0yj2sn	678	9	Gupta	Gupta	NNP
cord-276598-tm0yj2sn	678	10	et	et	NNP
cord-276598-tm0yj2sn	678	11	al	al	NNP
cord-276598-tm0yj2sn	678	12	.	.	.
cord-276598-tm0yj2sn	679	1	[	[	-LRB-
cord-276598-tm0yj2sn	679	2	97	97	CD
cord-276598-tm0yj2sn	679	3	]	]	-RRB-
cord-276598-tm0yj2sn	679	4	and	and	CC
cord-276598-tm0yj2sn	679	5	Kaboudin	Kaboudin	NNP
cord-276598-tm0yj2sn	679	6	et	et	NNP
cord-276598-tm0yj2sn	679	7	al	al	NNP
cord-276598-tm0yj2sn	679	8	.	.	.
cord-276598-tm0yj2sn	680	1	[	[	-LRB-
cord-276598-tm0yj2sn	680	2	98	98	CD
cord-276598-tm0yj2sn	680	3	]	]	-RRB-
cord-276598-tm0yj2sn	680	4	suggest	suggest	VBP
cord-276598-tm0yj2sn	680	5	that	that	IN
cord-276598-tm0yj2sn	680	6	the	the	DT
cord-276598-tm0yj2sn	680	7	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	680	8	H	H	NNP
cord-276598-tm0yj2sn	680	9	-	-	HYPH
cord-276598-tm0yj2sn	680	10	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	680	11	(	(	-LRB-
cord-276598-tm0yj2sn	680	12	(	(	-LRB-
cord-276598-tm0yj2sn	680	13	RO	RO	NNP
cord-276598-tm0yj2sn	680	14	)	)	-RRB-
cord-276598-tm0yj2sn	680	15	2	2	CD
cord-276598-tm0yj2sn	681	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	682	1	,	,	,
cord-276598-tm0yj2sn	682	2	R	r	NN
cord-276598-tm0yj2sn	682	3	=	=	NN
cord-276598-tm0yj2sn	682	4	alkyl	alkyl	NN
cord-276598-tm0yj2sn	682	5	)	)	-RRB-
cord-276598-tm0yj2sn	682	6	reacts	react	VBZ
cord-276598-tm0yj2sn	682	7	with	with	IN
cord-276598-tm0yj2sn	682	8	trichloroisocyanuric	trichloroisocyanuric	NN
cord-276598-tm0yj2sn	682	9	acid	acid	NN
cord-276598-tm0yj2sn	682	10	(	(	-LRB-
cord-276598-tm0yj2sn	682	11	tCiC	tCiC	NNP
cord-276598-tm0yj2sn	682	12	-	-	HYPH
cord-276598-tm0yj2sn	682	13	A	a	NN
cord-276598-tm0yj2sn	682	14	)	)	-RRB-
cord-276598-tm0yj2sn	682	15	to	to	TO
cord-276598-tm0yj2sn	682	16	form	form	VB
cord-276598-tm0yj2sn	682	17	the	the	DT
cord-276598-tm0yj2sn	682	18	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	682	19	(	(	-LRB-
cord-276598-tm0yj2sn	682	20	RO	RO	NNP
cord-276598-tm0yj2sn	682	21	)	)	-RRB-
cord-276598-tm0yj2sn	682	22	2	2	CD
cord-276598-tm0yj2sn	683	1	P(O)Cl	P(O)Cl	VBN
cord-276598-tm0yj2sn	684	1	(	(	-LRB-
cord-276598-tm0yj2sn	684	2	dACP	dacp	JJ
cord-276598-tm0yj2sn	684	3	;	;	:
cord-276598-tm0yj2sn	684	4	R	r	NN
cord-276598-tm0yj2sn	684	5	=	=	NN
cord-276598-tm0yj2sn	684	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	684	7	)	)	-RRB-
cord-276598-tm0yj2sn	684	8	and	and	CC
cord-276598-tm0yj2sn	684	9	1,3,5-triazinane-2,4,6-trione	1,3,5-triazinane-2,4,6-trione	CD
cord-276598-tm0yj2sn	684	10	(	(	-LRB-
cord-276598-tm0yj2sn	684	11	tAtO	tato	NN
cord-276598-tm0yj2sn	684	12	)	)	-RRB-
cord-276598-tm0yj2sn	685	1	(	(	-LRB-
cord-276598-tm0yj2sn	685	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	685	3	22	22	CD
cord-276598-tm0yj2sn	685	4	)	)	-RRB-
cord-276598-tm0yj2sn	685	5	.	.	.
cord-276598-tm0yj2sn	686	1	Following	follow	VBG
cord-276598-tm0yj2sn	686	2	,	,	,
cord-276598-tm0yj2sn	686	3	a	a	DT
cord-276598-tm0yj2sn	686	4	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	686	5	substitution	substitution	NN
cord-276598-tm0yj2sn	686	6	between	between	IN
cord-276598-tm0yj2sn	686	7	the	the	DT
cord-276598-tm0yj2sn	686	8	dACP	dacp	NN
cord-276598-tm0yj2sn	686	9	and	and	CC
cord-276598-tm0yj2sn	686	10	the	the	DT
cord-276598-tm0yj2sn	686	11	amine	amine	NN
cord-276598-tm0yj2sn	686	12	result	result	NN
cord-276598-tm0yj2sn	686	13	in	in	IN
cord-276598-tm0yj2sn	686	14	the	the	DT
cord-276598-tm0yj2sn	686	15	P	P	NNP
cord-276598-tm0yj2sn	686	16	-	-	HYPH
cord-276598-tm0yj2sn	686	17	N	N	NNP
cord-276598-tm0yj2sn	686	18	with	with	IN
cord-276598-tm0yj2sn	686	19	HCl	HCl	NNP
cord-276598-tm0yj2sn	686	20	as	as	IN
cord-276598-tm0yj2sn	686	21	the	the	DT
cord-276598-tm0yj2sn	686	22	major	major	JJ
cord-276598-tm0yj2sn	686	23	by	by	IN
cord-276598-tm0yj2sn	686	24	-	-	HYPH
cord-276598-tm0yj2sn	686	25	product	product	NN
cord-276598-tm0yj2sn	686	26	.	.	.
cord-276598-tm0yj2sn	687	1	The	the	DT
cord-276598-tm0yj2sn	687	2	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	687	3	of	of	IN
cord-276598-tm0yj2sn	687	4	P	P	NNP
cord-276598-tm0yj2sn	687	5	-	-	HYPH
cord-276598-tm0yj2sn	687	6	N	n	CD
cord-276598-tm0yj2sn	687	7	formation	formation	NN
cord-276598-tm0yj2sn	687	8	from	from	IN
cord-276598-tm0yj2sn	687	9	Gupta	Gupta	NNP
cord-276598-tm0yj2sn	687	10	et	et	NNP
cord-276598-tm0yj2sn	687	11	al	al	NNP
cord-276598-tm0yj2sn	687	12	.	.	.
cord-276598-tm0yj2sn	688	1	[	[	-LRB-
cord-276598-tm0yj2sn	688	2	97	97	CD
cord-276598-tm0yj2sn	688	3	]	]	-RRB-
cord-276598-tm0yj2sn	688	4	and	and	CC
cord-276598-tm0yj2sn	688	5	Kaboudin	Kaboudin	NNP
cord-276598-tm0yj2sn	688	6	et	et	NNP
cord-276598-tm0yj2sn	688	7	al	al	NNP
cord-276598-tm0yj2sn	688	8	.	.	.
cord-276598-tm0yj2sn	689	1	[	[	-LRB-
cord-276598-tm0yj2sn	689	2	98	98	CD
cord-276598-tm0yj2sn	689	3	]	]	-RRB-
cord-276598-tm0yj2sn	689	4	suggest	suggest	VBP
cord-276598-tm0yj2sn	689	5	that	that	IN
cord-276598-tm0yj2sn	689	6	the	the	DT
cord-276598-tm0yj2sn	689	7	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	689	8	H	H	NNP
cord-276598-tm0yj2sn	689	9	-	-	HYPH
cord-276598-tm0yj2sn	689	10	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	689	11	(	(	-LRB-
cord-276598-tm0yj2sn	689	12	(	(	-LRB-
cord-276598-tm0yj2sn	689	13	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	689	14	,	,	,
cord-276598-tm0yj2sn	689	15	R	r	NN
cord-276598-tm0yj2sn	689	16	=	=	NN
cord-276598-tm0yj2sn	689	17	alkyl	alkyl	NN
cord-276598-tm0yj2sn	689	18	)	)	-RRB-
cord-276598-tm0yj2sn	689	19	reacts	react	VBZ
cord-276598-tm0yj2sn	689	20	with	with	IN
cord-276598-tm0yj2sn	689	21	trichloroisocyanuric	trichloroisocyanuric	NN
cord-276598-tm0yj2sn	689	22	acid	acid	NN
cord-276598-tm0yj2sn	689	23	(	(	-LRB-
cord-276598-tm0yj2sn	689	24	tCiC	tCiC	NNP
cord-276598-tm0yj2sn	689	25	-	-	HYPH
cord-276598-tm0yj2sn	689	26	A	a	NN
cord-276598-tm0yj2sn	689	27	)	)	-RRB-
cord-276598-tm0yj2sn	689	28	to	to	TO
cord-276598-tm0yj2sn	689	29	form	form	VB
cord-276598-tm0yj2sn	689	30	the	the	DT
cord-276598-tm0yj2sn	689	31	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	689	32	(	(	-LRB-
cord-276598-tm0yj2sn	689	33	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	689	34	(	(	-LRB-
cord-276598-tm0yj2sn	689	35	dACP	dacp	NN
cord-276598-tm0yj2sn	689	36	;	;	:
cord-276598-tm0yj2sn	689	37	R	r	NN
cord-276598-tm0yj2sn	689	38	=	=	NN
cord-276598-tm0yj2sn	689	39	alkyl	alkyl	NN
cord-276598-tm0yj2sn	689	40	)	)	-RRB-
cord-276598-tm0yj2sn	689	41	and	and	CC
cord-276598-tm0yj2sn	689	42	1,3,5-triazinane-2,4,6-trione	1,3,5-triazinane-2,4,6-trione	CD
cord-276598-tm0yj2sn	689	43	(	(	-LRB-
cord-276598-tm0yj2sn	689	44	tAtO	tato	NN
cord-276598-tm0yj2sn	689	45	)	)	-RRB-
cord-276598-tm0yj2sn	690	1	(	(	-LRB-
cord-276598-tm0yj2sn	690	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	690	3	22	22	CD
cord-276598-tm0yj2sn	690	4	)	)	-RRB-
cord-276598-tm0yj2sn	690	5	.	.	.
cord-276598-tm0yj2sn	691	1	Following	follow	VBG
cord-276598-tm0yj2sn	691	2	,	,	,
cord-276598-tm0yj2sn	691	3	a	a	DT
cord-276598-tm0yj2sn	691	4	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	691	5	substitution	substitution	NN
cord-276598-tm0yj2sn	691	6	between	between	IN
cord-276598-tm0yj2sn	691	7	the	the	DT
cord-276598-tm0yj2sn	691	8	dACP	dacp	NN
cord-276598-tm0yj2sn	691	9	and	and	CC
cord-276598-tm0yj2sn	691	10	the	the	DT
cord-276598-tm0yj2sn	691	11	amine	amine	NN
cord-276598-tm0yj2sn	691	12	result	result	NN
cord-276598-tm0yj2sn	691	13	in	in	IN
cord-276598-tm0yj2sn	691	14	the	the	DT
cord-276598-tm0yj2sn	691	15	P	P	NNP
cord-276598-tm0yj2sn	691	16	-	-	HYPH
cord-276598-tm0yj2sn	691	17	N	N	NNP
cord-276598-tm0yj2sn	691	18	with	with	IN
cord-276598-tm0yj2sn	691	19	HCl	HCl	NNP
cord-276598-tm0yj2sn	691	20	as	as	IN
cord-276598-tm0yj2sn	691	21	the	the	DT
cord-276598-tm0yj2sn	691	22	major	major	JJ
cord-276598-tm0yj2sn	691	23	by	by	IN
cord-276598-tm0yj2sn	691	24	-	-	HYPH
cord-276598-tm0yj2sn	691	25	product	product	NN
cord-276598-tm0yj2sn	691	26	.	.	.
cord-276598-tm0yj2sn	692	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	692	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	692	3	for	for	IN
cord-276598-tm0yj2sn	692	4	the	the	DT
cord-276598-tm0yj2sn	692	5	base	base	NN
cord-276598-tm0yj2sn	692	6	-	-	HYPH
cord-276598-tm0yj2sn	692	7	free	free	JJ
cord-276598-tm0yj2sn	692	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	692	9	of	of	IN
cord-276598-tm0yj2sn	692	10	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	692	11	using	use	VBG
cord-276598-tm0yj2sn	692	12	a	a	DT
cord-276598-tm0yj2sn	692	13	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	692	14	agent	agent	NN
cord-276598-tm0yj2sn	692	15	.	.	.
cord-276598-tm0yj2sn	693	1	The	the	DT
cord-276598-tm0yj2sn	693	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	693	3	of	of	IN
cord-276598-tm0yj2sn	693	4	the	the	DT
cord-276598-tm0yj2sn	693	5	reaction	reaction	NN
cord-276598-tm0yj2sn	693	6	by	by	IN
cord-276598-tm0yj2sn	693	7	Jang	Jang	NNP
cord-276598-tm0yj2sn	693	8	et	et	FW
cord-276598-tm0yj2sn	693	9	al	al	NNP
cord-276598-tm0yj2sn	693	10	.	.	NNP
cord-276598-tm0yj2sn	693	11	suggests	suggest	VBZ
cord-276598-tm0yj2sn	693	12	that	that	IN
cord-276598-tm0yj2sn	693	13	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	693	14	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	693	15	acid	acid	NN
cord-276598-tm0yj2sn	693	16	(	(	-LRB-
cord-276598-tm0yj2sn	693	17	dPPA	dppa	NN
cord-276598-tm0yj2sn	693	18	)	)	-RRB-
cord-276598-tm0yj2sn	693	19	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	693	20	chlorination	chlorination	NN
cord-276598-tm0yj2sn	693	21	in	in	IN
cord-276598-tm0yj2sn	693	22	the	the	DT
cord-276598-tm0yj2sn	693	23	presence	presence	NN
cord-276598-tm0yj2sn	693	24	of	of	IN
cord-276598-tm0yj2sn	693	25	a	a	DT
cord-276598-tm0yj2sn	693	26	base	base	NN
cord-276598-tm0yj2sn	693	27	,	,	,
cord-276598-tm0yj2sn	693	28	which	which	WDT
cord-276598-tm0yj2sn	693	29	is	be	VBZ
cord-276598-tm0yj2sn	693	30	subsequently	subsequently	RB
cord-276598-tm0yj2sn	693	31	attacked	attack	VBN
cord-276598-tm0yj2sn	693	32	by	by	IN
cord-276598-tm0yj2sn	693	33	the	the	DT
cord-276598-tm0yj2sn	693	34	amine	amine	NN
cord-276598-tm0yj2sn	693	35	to	to	TO
cord-276598-tm0yj2sn	693	36	afford	afford	VB
cord-276598-tm0yj2sn	693	37	the	the	DT
cord-276598-tm0yj2sn	693	38	P	P	NNP
cord-276598-tm0yj2sn	693	39	-	-	HYPH
cord-276598-tm0yj2sn	693	40	N	n	CD
cord-276598-tm0yj2sn	693	41	product	product	NN
cord-276598-tm0yj2sn	693	42	[	[	-LRB-
cord-276598-tm0yj2sn	693	43	99	99	CD
cord-276598-tm0yj2sn	693	44	]	]	-RRB-
cord-276598-tm0yj2sn	693	45	.	.	.
cord-276598-tm0yj2sn	694	1	Although	although	IN
cord-276598-tm0yj2sn	694	2	the	the	DT
cord-276598-tm0yj2sn	694	3	authors	author	NNS
cord-276598-tm0yj2sn	694	4	did	do	VBD
cord-276598-tm0yj2sn	694	5	not	not	RB
cord-276598-tm0yj2sn	694	6	propose	propose	VB
cord-276598-tm0yj2sn	694	7	any	any	DT
cord-276598-tm0yj2sn	694	8	mechanism	mechanism	NN
cord-276598-tm0yj2sn	694	9	,	,	,
cord-276598-tm0yj2sn	694	10	they	-PRON-	PRP
cord-276598-tm0yj2sn	694	11	suggested	suggest	VBD
cord-276598-tm0yj2sn	694	12	that	that	IN
cord-276598-tm0yj2sn	694	13	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	694	14	attack	attack	NN
cord-276598-tm0yj2sn	694	15	on	on	IN
cord-276598-tm0yj2sn	694	16	the	the	DT
cord-276598-tm0yj2sn	694	17	P	p	NN
cord-276598-tm0yj2sn	694	18	atom	atom	NN
cord-276598-tm0yj2sn	694	19	was	be	VBD
cord-276598-tm0yj2sn	694	20	consistent	consistent	JJ
cord-276598-tm0yj2sn	694	21	with	with	IN
cord-276598-tm0yj2sn	694	22	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	694	23	amines	amine	NNS
cord-276598-tm0yj2sn	694	24	resulting	result	VBG
cord-276598-tm0yj2sn	694	25	in	in	IN
cord-276598-tm0yj2sn	694	26	a	a	DT
cord-276598-tm0yj2sn	694	27	higher	high	JJR
cord-276598-tm0yj2sn	694	28	yield	yield	NN
cord-276598-tm0yj2sn	694	29	of	of	IN
cord-276598-tm0yj2sn	694	30	products	product	NNS
cord-276598-tm0yj2sn	694	31	than	than	IN
cord-276598-tm0yj2sn	694	32	the	the	DT
cord-276598-tm0yj2sn	694	33	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	694	34	amines	amine	NNS
cord-276598-tm0yj2sn	694	35	because	because	IN
cord-276598-tm0yj2sn	694	36	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	694	37	amines	amine	NNS
cord-276598-tm0yj2sn	694	38	are	be	VBP
cord-276598-tm0yj2sn	694	39	more	more	RBR
cord-276598-tm0yj2sn	694	40	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	694	41	.	.	.
cord-276598-tm0yj2sn	695	1	The	the	DT
cord-276598-tm0yj2sn	695	2	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	695	3	step	step	NN
cord-276598-tm0yj2sn	695	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	695	5	by	by	IN
cord-276598-tm0yj2sn	695	6	Appel	Appel	NNP
cord-276598-tm0yj2sn	695	7	and	and	CC
cord-276598-tm0yj2sn	695	8	Einig	Einig	NNP
cord-276598-tm0yj2sn	695	9	involves	involve	VBZ
cord-276598-tm0yj2sn	695	10	the	the	DT
cord-276598-tm0yj2sn	695	11	formation	formation	NN
cord-276598-tm0yj2sn	695	12	of	of	IN
cord-276598-tm0yj2sn	695	13	oxo	oxo	NN
cord-276598-tm0yj2sn	695	14	-	-	HYPH
cord-276598-tm0yj2sn	695	15	triphenyl	triphenyl	NN
cord-276598-tm0yj2sn	695	16	-	-	HYPH
cord-276598-tm0yj2sn	695	17	diphosphoxanium	diphosphoxanium	NN
cord-276598-tm0yj2sn	695	18	salt	salt	NN
cord-276598-tm0yj2sn	695	19	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	695	20	from	from	IN
cord-276598-tm0yj2sn	695	21	a	a	DT
cord-276598-tm0yj2sn	695	22	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	695	23	of	of	IN
cord-276598-tm0yj2sn	695	24	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	695	25	acid	acid	NN
cord-276598-tm0yj2sn	695	26	by	by	IN
cord-276598-tm0yj2sn	695	27	CCl4	ccl4	NN
cord-276598-tm0yj2sn	695	28	in	in	IN
cord-276598-tm0yj2sn	695	29	the	the	DT
cord-276598-tm0yj2sn	695	30	presence	presence	NN
cord-276598-tm0yj2sn	695	31	of	of	IN
cord-276598-tm0yj2sn	695	32	phosphine	phosphine	NN
cord-276598-tm0yj2sn	695	33	(	(	-LRB-
cord-276598-tm0yj2sn	695	34	Scheme	scheme	NN
cord-276598-tm0yj2sn	695	35	23	23	CD
cord-276598-tm0yj2sn	695	36	)	)	-RRB-
cord-276598-tm0yj2sn	695	37	[	[	-LRB-
cord-276598-tm0yj2sn	695	38	86	86	CD
cord-276598-tm0yj2sn	695	39	]	]	-RRB-
cord-276598-tm0yj2sn	695	40	.	.	.
cord-276598-tm0yj2sn	696	1	Nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	696	2	substitution	substitution	NN
cord-276598-tm0yj2sn	696	3	from	from	IN
cord-276598-tm0yj2sn	696	4	amine	amine	NN
cord-276598-tm0yj2sn	696	5	results	result	NNS
cord-276598-tm0yj2sn	696	6	in	in	IN
cord-276598-tm0yj2sn	696	7	the	the	DT
cord-276598-tm0yj2sn	696	8	desired	desire	VBN
cord-276598-tm0yj2sn	696	9	product	product	NN
cord-276598-tm0yj2sn	696	10	and	and	CC
cord-276598-tm0yj2sn	696	11	triphenylphosphate	triphenylphosphate	NN
cord-276598-tm0yj2sn	696	12	as	as	IN
cord-276598-tm0yj2sn	696	13	the	the	DT
cord-276598-tm0yj2sn	696	14	by	by	IN
cord-276598-tm0yj2sn	696	15	-	-	HYPH
cord-276598-tm0yj2sn	696	16	product	product	NN
cord-276598-tm0yj2sn	696	17	.	.	.
cord-276598-tm0yj2sn	697	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	697	2	23	23	CD
cord-276598-tm0yj2sn	697	3	.	.	.
cord-276598-tm0yj2sn	698	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	698	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	698	3	for	for	IN
cord-276598-tm0yj2sn	698	4	the	the	DT
cord-276598-tm0yj2sn	698	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	698	6	of	of	IN
cord-276598-tm0yj2sn	698	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	698	8	from	from	IN
cord-276598-tm0yj2sn	698	9	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	698	10	acid	acid	NN
cord-276598-tm0yj2sn	698	11	and	and	CC
cord-276598-tm0yj2sn	698	12	amine	amine	NN
cord-276598-tm0yj2sn	698	13	in	in	IN
cord-276598-tm0yj2sn	698	14	the	the	DT
cord-276598-tm0yj2sn	698	15	presence	presence	NN
cord-276598-tm0yj2sn	698	16	of	of	IN
cord-276598-tm0yj2sn	698	17	phosphine	phosphine	NN
cord-276598-tm0yj2sn	698	18	and	and	CC
cord-276598-tm0yj2sn	698	19	CCl4	ccl4	NN
cord-276598-tm0yj2sn	698	20	.	.	.
cord-276598-tm0yj2sn	699	1	In	in	IN
cord-276598-tm0yj2sn	699	2	the	the	DT
cord-276598-tm0yj2sn	699	3	suggested	suggest	VBN
cord-276598-tm0yj2sn	699	4	reaction	reaction	NN
cord-276598-tm0yj2sn	699	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	699	6	by	by	IN
cord-276598-tm0yj2sn	699	7	[	[	-LRB-
cord-276598-tm0yj2sn	699	8	100	100	CD
cord-276598-tm0yj2sn	699	9	]	]	-RRB-
cord-276598-tm0yj2sn	699	10	,	,	,
cord-276598-tm0yj2sn	699	11	iodine	iodine	NN
cord-276598-tm0yj2sn	699	12	reacts	react	VBZ
cord-276598-tm0yj2sn	699	13	with	with	IN
cord-276598-tm0yj2sn	699	14	(	(	-LRB-
cord-276598-tm0yj2sn	699	15	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	699	16	(	(	-LRB-
cord-276598-tm0yj2sn	699	17	R	r	NN
cord-276598-tm0yj2sn	699	18	=	=	NN
cord-276598-tm0yj2sn	699	19	alkyl	alkyl	NN
cord-276598-tm0yj2sn	699	20	)	)	-RRB-
cord-276598-tm0yj2sn	699	21	to	to	TO
cord-276598-tm0yj2sn	699	22	form	form	VB
cord-276598-tm0yj2sn	699	23	trialkoxyiodophosphonium	trialkoxyiodophosphonium	NN
cord-276598-tm0yj2sn	699	24	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	699	25	,	,	,
cord-276598-tm0yj2sn	699	26	which	which	WDT
cord-276598-tm0yj2sn	699	27	is	be	VBZ
cord-276598-tm0yj2sn	699	28	further	further	RB
cord-276598-tm0yj2sn	699	29	attacked	attack	VBN
cord-276598-tm0yj2sn	699	30	by	by	IN
cord-276598-tm0yj2sn	699	31	iodide	iodide	NN
cord-276598-tm0yj2sn	699	32	ion	ion	NN
cord-276598-tm0yj2sn	699	33	to	to	TO
cord-276598-tm0yj2sn	699	34	form	form	VB
cord-276598-tm0yj2sn	699	35	dialkyl	dialkyl	FW
cord-276598-tm0yj2sn	699	36	phosphoriodidate	phosphoriodidate	NNP
cord-276598-tm0yj2sn	699	37	(	(	-LRB-
cord-276598-tm0yj2sn	699	38	dAPPI	dappi	NN
cord-276598-tm0yj2sn	699	39	)	)	-RRB-
cord-276598-tm0yj2sn	700	1	(	(	-LRB-
cord-276598-tm0yj2sn	700	2	Arbuzov	Arbuzov	NNP
cord-276598-tm0yj2sn	700	3	reaction	reaction	NN
cord-276598-tm0yj2sn	700	4	,	,	,
cord-276598-tm0yj2sn	700	5	Scheme	scheme	NN
cord-276598-tm0yj2sn	700	6	24	24	CD
cord-276598-tm0yj2sn	700	7	)	)	-RRB-
cord-276598-tm0yj2sn	700	8	.	.	.
cord-276598-tm0yj2sn	701	1	Then	then	RB
cord-276598-tm0yj2sn	701	2	,	,	,
cord-276598-tm0yj2sn	701	3	the	the	DT
cord-276598-tm0yj2sn	701	4	dAPPI	dappi	NN
cord-276598-tm0yj2sn	701	5	is	be	VBZ
cord-276598-tm0yj2sn	701	6	attacked	attack	VBN
cord-276598-tm0yj2sn	701	7	by	by	IN
cord-276598-tm0yj2sn	701	8	the	the	DT
cord-276598-tm0yj2sn	701	9	amine	amine	NN
cord-276598-tm0yj2sn	701	10	to	to	TO
cord-276598-tm0yj2sn	701	11	give	give	VB
cord-276598-tm0yj2sn	701	12	the	the	DT
cord-276598-tm0yj2sn	701	13	desired	desire	VBN
cord-276598-tm0yj2sn	701	14	P	P	NNP
cord-276598-tm0yj2sn	701	15	-	-	HYPH
cord-276598-tm0yj2sn	701	16	N	N	NNP
cord-276598-tm0yj2sn	701	17	with	with	IN
cord-276598-tm0yj2sn	701	18	an	an	DT
cord-276598-tm0yj2sn	701	19	elimination	elimination	NN
cord-276598-tm0yj2sn	701	20	of	of	IN
cord-276598-tm0yj2sn	701	21	HI	HI	NNP
cord-276598-tm0yj2sn	701	22	.	.	.
cord-276598-tm0yj2sn	702	1	N	N	NNP
cord-276598-tm0yj2sn	702	2	-	-	HYPH
cord-276598-tm0yj2sn	702	3	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	702	4	amino	amino	NN
cord-276598-tm0yj2sn	702	5	acid	acid	NN
cord-276598-tm0yj2sn	702	6	esters	ester	NNS
cord-276598-tm0yj2sn	702	7	and	and	CC
cord-276598-tm0yj2sn	702	8	P	P	NNP
cord-276598-tm0yj2sn	702	9	-	-	HYPH
cord-276598-tm0yj2sn	702	10	N	N	NNP
cord-276598-tm0yj2sn	702	11	with	with	IN
cord-276598-tm0yj2sn	702	12	a	a	DT
cord-276598-tm0yj2sn	702	13	free	free	JJ
cord-276598-tm0yj2sn	702	14	amino	amino	NN
cord-276598-tm0yj2sn	702	15	group	group	NN
cord-276598-tm0yj2sn	702	16	were	be	VBD
cord-276598-tm0yj2sn	702	17	also	also	RB
cord-276598-tm0yj2sn	702	18	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	702	19	using	use	VBG
cord-276598-tm0yj2sn	702	20	the	the	DT
cord-276598-tm0yj2sn	702	21	iodine	iodine	NN
cord-276598-tm0yj2sn	702	22	-	-	HYPH
cord-276598-tm0yj2sn	702	23	mediated	mediate	VBN
cord-276598-tm0yj2sn	702	24	synthesis	synthesis	NN
cord-276598-tm0yj2sn	702	25	method	method	NN
cord-276598-tm0yj2sn	702	26	.	.	.
cord-276598-tm0yj2sn	703	1	The	the	DT
cord-276598-tm0yj2sn	703	2	challenges	challenge	NNS
cord-276598-tm0yj2sn	703	3	with	with	IN
cord-276598-tm0yj2sn	703	4	this	this	DT
cord-276598-tm0yj2sn	703	5	iodine	iodine	NN
cord-276598-tm0yj2sn	703	6	-	-	HYPH
cord-276598-tm0yj2sn	703	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	703	8	P	p	NN
cord-276598-tm0yj2sn	703	9	-	-	HYPH
cord-276598-tm0yj2sn	703	10	N	n	CD
cord-276598-tm0yj2sn	703	11	formation	formation	NN
cord-276598-tm0yj2sn	703	12	is	be	VBZ
cord-276598-tm0yj2sn	703	13	that	that	IN
cord-276598-tm0yj2sn	703	14	many	many	JJ
cord-276598-tm0yj2sn	703	15	side	side	NN
cord-276598-tm0yj2sn	703	16	products	product	NNS
cord-276598-tm0yj2sn	703	17	are	be	VBP
cord-276598-tm0yj2sn	703	18	formed	form	VBN
cord-276598-tm0yj2sn	703	19	,	,	,
cord-276598-tm0yj2sn	703	20	and	and	CC
cord-276598-tm0yj2sn	703	21	the	the	DT
cord-276598-tm0yj2sn	703	22	Proposed	propose	VBN
cord-276598-tm0yj2sn	703	23	mechanism	mechanism	NN
cord-276598-tm0yj2sn	703	24	for	for	IN
cord-276598-tm0yj2sn	703	25	the	the	DT
cord-276598-tm0yj2sn	703	26	base	base	NN
cord-276598-tm0yj2sn	703	27	-	-	HYPH
cord-276598-tm0yj2sn	703	28	free	free	JJ
cord-276598-tm0yj2sn	703	29	synthesis	synthesis	NN
cord-276598-tm0yj2sn	703	30	of	of	IN
cord-276598-tm0yj2sn	703	31	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	703	32	using	use	VBG
cord-276598-tm0yj2sn	703	33	a	a	DT
cord-276598-tm0yj2sn	703	34	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	703	35	agent	agent	NN
cord-276598-tm0yj2sn	703	36	.	.	.
cord-276598-tm0yj2sn	704	1	The	the	DT
cord-276598-tm0yj2sn	704	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	704	3	of	of	IN
cord-276598-tm0yj2sn	704	4	the	the	DT
cord-276598-tm0yj2sn	704	5	reaction	reaction	NN
cord-276598-tm0yj2sn	704	6	by	by	IN
cord-276598-tm0yj2sn	704	7	Jang	Jang	NNP
cord-276598-tm0yj2sn	704	8	et	et	FW
cord-276598-tm0yj2sn	704	9	al	al	NNP
cord-276598-tm0yj2sn	704	10	.	.	NNP
cord-276598-tm0yj2sn	704	11	suggests	suggest	VBZ
cord-276598-tm0yj2sn	704	12	that	that	IN
cord-276598-tm0yj2sn	704	13	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	704	14	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	704	15	acid	acid	NN
cord-276598-tm0yj2sn	704	16	(	(	-LRB-
cord-276598-tm0yj2sn	704	17	dPPA	dppa	NN
cord-276598-tm0yj2sn	704	18	)	)	-RRB-
cord-276598-tm0yj2sn	704	19	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	704	20	chlorination	chlorination	NN
cord-276598-tm0yj2sn	704	21	in	in	IN
cord-276598-tm0yj2sn	704	22	the	the	DT
cord-276598-tm0yj2sn	704	23	presence	presence	NN
cord-276598-tm0yj2sn	704	24	of	of	IN
cord-276598-tm0yj2sn	704	25	a	a	DT
cord-276598-tm0yj2sn	704	26	base	base	NN
cord-276598-tm0yj2sn	704	27	,	,	,
cord-276598-tm0yj2sn	704	28	which	which	WDT
cord-276598-tm0yj2sn	704	29	is	be	VBZ
cord-276598-tm0yj2sn	704	30	subsequently	subsequently	RB
cord-276598-tm0yj2sn	704	31	attacked	attack	VBN
cord-276598-tm0yj2sn	704	32	by	by	IN
cord-276598-tm0yj2sn	704	33	the	the	DT
cord-276598-tm0yj2sn	704	34	amine	amine	NN
cord-276598-tm0yj2sn	704	35	to	to	TO
cord-276598-tm0yj2sn	704	36	afford	afford	VB
cord-276598-tm0yj2sn	704	37	the	the	DT
cord-276598-tm0yj2sn	704	38	P	P	NNP
cord-276598-tm0yj2sn	704	39	-	-	HYPH
cord-276598-tm0yj2sn	704	40	N	n	CD
cord-276598-tm0yj2sn	704	41	product	product	NN
cord-276598-tm0yj2sn	704	42	[	[	-LRB-
cord-276598-tm0yj2sn	704	43	99	99	CD
cord-276598-tm0yj2sn	704	44	]	]	-RRB-
cord-276598-tm0yj2sn	704	45	.	.	.
cord-276598-tm0yj2sn	705	1	Although	although	IN
cord-276598-tm0yj2sn	705	2	the	the	DT
cord-276598-tm0yj2sn	705	3	authors	author	NNS
cord-276598-tm0yj2sn	705	4	did	do	VBD
cord-276598-tm0yj2sn	705	5	not	not	RB
cord-276598-tm0yj2sn	705	6	propose	propose	VB
cord-276598-tm0yj2sn	705	7	any	any	DT
cord-276598-tm0yj2sn	705	8	mechanism	mechanism	NN
cord-276598-tm0yj2sn	705	9	,	,	,
cord-276598-tm0yj2sn	705	10	they	-PRON-	PRP
cord-276598-tm0yj2sn	705	11	suggested	suggest	VBD
cord-276598-tm0yj2sn	705	12	that	that	IN
cord-276598-tm0yj2sn	705	13	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	705	14	attack	attack	NN
cord-276598-tm0yj2sn	705	15	on	on	IN
cord-276598-tm0yj2sn	705	16	the	the	DT
cord-276598-tm0yj2sn	705	17	P	p	NN
cord-276598-tm0yj2sn	705	18	atom	atom	NN
cord-276598-tm0yj2sn	705	19	was	be	VBD
cord-276598-tm0yj2sn	705	20	consistent	consistent	JJ
cord-276598-tm0yj2sn	705	21	with	with	IN
cord-276598-tm0yj2sn	705	22	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	705	23	amines	amine	NNS
cord-276598-tm0yj2sn	705	24	resulting	result	VBG
cord-276598-tm0yj2sn	705	25	in	in	IN
cord-276598-tm0yj2sn	705	26	a	a	DT
cord-276598-tm0yj2sn	705	27	higher	high	JJR
cord-276598-tm0yj2sn	705	28	yield	yield	NN
cord-276598-tm0yj2sn	705	29	of	of	IN
cord-276598-tm0yj2sn	705	30	products	product	NNS
cord-276598-tm0yj2sn	705	31	than	than	IN
cord-276598-tm0yj2sn	705	32	the	the	DT
cord-276598-tm0yj2sn	705	33	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	705	34	amines	amine	NNS
cord-276598-tm0yj2sn	705	35	because	because	IN
cord-276598-tm0yj2sn	705	36	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	705	37	amines	amine	NNS
cord-276598-tm0yj2sn	705	38	are	be	VBP
cord-276598-tm0yj2sn	705	39	more	more	RBR
cord-276598-tm0yj2sn	705	40	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	705	41	.	.	.
cord-276598-tm0yj2sn	706	1	The	the	DT
cord-276598-tm0yj2sn	706	2	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	706	3	step	step	NN
cord-276598-tm0yj2sn	706	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	706	5	by	by	IN
cord-276598-tm0yj2sn	706	6	Appel	Appel	NNP
cord-276598-tm0yj2sn	706	7	and	and	CC
cord-276598-tm0yj2sn	706	8	Einig	Einig	NNP
cord-276598-tm0yj2sn	706	9	involves	involve	VBZ
cord-276598-tm0yj2sn	706	10	the	the	DT
cord-276598-tm0yj2sn	706	11	formation	formation	NN
cord-276598-tm0yj2sn	706	12	of	of	IN
cord-276598-tm0yj2sn	706	13	oxo	oxo	NN
cord-276598-tm0yj2sn	706	14	-	-	HYPH
cord-276598-tm0yj2sn	706	15	triphenyl	triphenyl	NN
cord-276598-tm0yj2sn	706	16	-	-	HYPH
cord-276598-tm0yj2sn	706	17	diphosphoxanium	diphosphoxanium	NN
cord-276598-tm0yj2sn	706	18	salt	salt	NN
cord-276598-tm0yj2sn	706	19	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	706	20	from	from	IN
cord-276598-tm0yj2sn	706	21	a	a	DT
cord-276598-tm0yj2sn	706	22	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	706	23	of	of	IN
cord-276598-tm0yj2sn	706	24	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	706	25	acid	acid	NN
cord-276598-tm0yj2sn	706	26	by	by	IN
cord-276598-tm0yj2sn	706	27	CCl	CCl	NNS
cord-276598-tm0yj2sn	706	28	4	4	CD
cord-276598-tm0yj2sn	706	29	in	in	IN
cord-276598-tm0yj2sn	706	30	the	the	DT
cord-276598-tm0yj2sn	706	31	presence	presence	NN
cord-276598-tm0yj2sn	706	32	of	of	IN
cord-276598-tm0yj2sn	706	33	phosphine	phosphine	NN
cord-276598-tm0yj2sn	706	34	(	(	-LRB-
cord-276598-tm0yj2sn	706	35	Scheme	scheme	NN
cord-276598-tm0yj2sn	706	36	23	23	CD
cord-276598-tm0yj2sn	706	37	)	)	-RRB-
cord-276598-tm0yj2sn	706	38	[	[	-LRB-
cord-276598-tm0yj2sn	706	39	86	86	CD
cord-276598-tm0yj2sn	706	40	]	]	-RRB-
cord-276598-tm0yj2sn	706	41	.	.	.
cord-276598-tm0yj2sn	707	1	Nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	707	2	substitution	substitution	NN
cord-276598-tm0yj2sn	707	3	from	from	IN
cord-276598-tm0yj2sn	707	4	amine	amine	NN
cord-276598-tm0yj2sn	707	5	results	result	NNS
cord-276598-tm0yj2sn	707	6	in	in	IN
cord-276598-tm0yj2sn	707	7	the	the	DT
cord-276598-tm0yj2sn	707	8	desired	desire	VBN
cord-276598-tm0yj2sn	707	9	product	product	NN
cord-276598-tm0yj2sn	707	10	and	and	CC
cord-276598-tm0yj2sn	707	11	triphenylphosphate	triphenylphosphate	NN
cord-276598-tm0yj2sn	707	12	as	as	IN
cord-276598-tm0yj2sn	707	13	the	the	DT
cord-276598-tm0yj2sn	707	14	by	by	IN
cord-276598-tm0yj2sn	707	15	-	-	HYPH
cord-276598-tm0yj2sn	707	16	product	product	NN
cord-276598-tm0yj2sn	707	17	.	.	.
cord-276598-tm0yj2sn	708	1	The	the	DT
cord-276598-tm0yj2sn	708	2	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	708	3	of	of	IN
cord-276598-tm0yj2sn	708	4	P	P	NNP
cord-276598-tm0yj2sn	708	5	-	-	HYPH
cord-276598-tm0yj2sn	708	6	N	n	CD
cord-276598-tm0yj2sn	708	7	formation	formation	NN
cord-276598-tm0yj2sn	708	8	from	from	IN
cord-276598-tm0yj2sn	708	9	Gupta	Gupta	NNP
cord-276598-tm0yj2sn	708	10	et	et	NNP
cord-276598-tm0yj2sn	708	11	al	al	NNP
cord-276598-tm0yj2sn	708	12	.	.	.
cord-276598-tm0yj2sn	709	1	[	[	-LRB-
cord-276598-tm0yj2sn	709	2	97	97	CD
cord-276598-tm0yj2sn	709	3	]	]	-RRB-
cord-276598-tm0yj2sn	709	4	and	and	CC
cord-276598-tm0yj2sn	709	5	Kaboudin	Kaboudin	NNP
cord-276598-tm0yj2sn	709	6	et	et	NNP
cord-276598-tm0yj2sn	709	7	al	al	NNP
cord-276598-tm0yj2sn	709	8	.	.	.
cord-276598-tm0yj2sn	710	1	[	[	-LRB-
cord-276598-tm0yj2sn	710	2	98	98	CD
cord-276598-tm0yj2sn	710	3	]	]	-RRB-
cord-276598-tm0yj2sn	710	4	suggest	suggest	VBP
cord-276598-tm0yj2sn	710	5	that	that	IN
cord-276598-tm0yj2sn	710	6	the	the	DT
cord-276598-tm0yj2sn	710	7	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	710	8	H	H	NNP
cord-276598-tm0yj2sn	710	9	-	-	HYPH
cord-276598-tm0yj2sn	710	10	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	710	11	(	(	-LRB-
cord-276598-tm0yj2sn	710	12	(	(	-LRB-
cord-276598-tm0yj2sn	710	13	RO)2P(O)H	RO)2P(O)H	NNP
cord-276598-tm0yj2sn	710	14	,	,	,
cord-276598-tm0yj2sn	710	15	R	r	NN
cord-276598-tm0yj2sn	710	16	=	=	NN
cord-276598-tm0yj2sn	710	17	alkyl	alkyl	NN
cord-276598-tm0yj2sn	710	18	)	)	-RRB-
cord-276598-tm0yj2sn	710	19	reacts	react	VBZ
cord-276598-tm0yj2sn	710	20	with	with	IN
cord-276598-tm0yj2sn	710	21	trichloroisocyanuric	trichloroisocyanuric	NN
cord-276598-tm0yj2sn	710	22	acid	acid	NN
cord-276598-tm0yj2sn	710	23	(	(	-LRB-
cord-276598-tm0yj2sn	710	24	tCiC	tCiC	NNP
cord-276598-tm0yj2sn	710	25	-	-	HYPH
cord-276598-tm0yj2sn	710	26	A	a	NN
cord-276598-tm0yj2sn	710	27	)	)	-RRB-
cord-276598-tm0yj2sn	710	28	to	to	TO
cord-276598-tm0yj2sn	710	29	form	form	VB
cord-276598-tm0yj2sn	710	30	the	the	DT
cord-276598-tm0yj2sn	710	31	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	710	32	(	(	-LRB-
cord-276598-tm0yj2sn	710	33	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	710	34	(	(	-LRB-
cord-276598-tm0yj2sn	710	35	dACP	dacp	NN
cord-276598-tm0yj2sn	710	36	;	;	:
cord-276598-tm0yj2sn	710	37	R	r	NN
cord-276598-tm0yj2sn	710	38	=	=	NN
cord-276598-tm0yj2sn	710	39	alkyl	alkyl	NN
cord-276598-tm0yj2sn	710	40	)	)	-RRB-
cord-276598-tm0yj2sn	710	41	and	and	CC
cord-276598-tm0yj2sn	710	42	1,3,5-triazinane-2,4,6-trione	1,3,5-triazinane-2,4,6-trione	CD
cord-276598-tm0yj2sn	710	43	(	(	-LRB-
cord-276598-tm0yj2sn	710	44	tAtO	tato	NN
cord-276598-tm0yj2sn	710	45	)	)	-RRB-
cord-276598-tm0yj2sn	711	1	(	(	-LRB-
cord-276598-tm0yj2sn	711	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	711	3	22	22	CD
cord-276598-tm0yj2sn	711	4	)	)	-RRB-
cord-276598-tm0yj2sn	711	5	.	.	.
cord-276598-tm0yj2sn	712	1	Following	follow	VBG
cord-276598-tm0yj2sn	712	2	,	,	,
cord-276598-tm0yj2sn	712	3	a	a	DT
cord-276598-tm0yj2sn	712	4	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	712	5	substitution	substitution	NN
cord-276598-tm0yj2sn	712	6	between	between	IN
cord-276598-tm0yj2sn	712	7	the	the	DT
cord-276598-tm0yj2sn	712	8	dACP	dacp	NN
cord-276598-tm0yj2sn	712	9	and	and	CC
cord-276598-tm0yj2sn	712	10	the	the	DT
cord-276598-tm0yj2sn	712	11	amine	amine	NN
cord-276598-tm0yj2sn	712	12	result	result	NN
cord-276598-tm0yj2sn	712	13	in	in	IN
cord-276598-tm0yj2sn	712	14	the	the	DT
cord-276598-tm0yj2sn	712	15	P	P	NNP
cord-276598-tm0yj2sn	712	16	-	-	HYPH
cord-276598-tm0yj2sn	712	17	N	N	NNP
cord-276598-tm0yj2sn	712	18	with	with	IN
cord-276598-tm0yj2sn	712	19	HCl	HCl	NNP
cord-276598-tm0yj2sn	712	20	as	as	IN
cord-276598-tm0yj2sn	712	21	the	the	DT
cord-276598-tm0yj2sn	712	22	major	major	JJ
cord-276598-tm0yj2sn	712	23	by	by	IN
cord-276598-tm0yj2sn	712	24	-	-	HYPH
cord-276598-tm0yj2sn	712	25	product	product	NN
cord-276598-tm0yj2sn	712	26	.	.	.
cord-276598-tm0yj2sn	713	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	713	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	713	3	for	for	IN
cord-276598-tm0yj2sn	713	4	the	the	DT
cord-276598-tm0yj2sn	713	5	base	base	NN
cord-276598-tm0yj2sn	713	6	-	-	HYPH
cord-276598-tm0yj2sn	713	7	free	free	JJ
cord-276598-tm0yj2sn	713	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	713	9	of	of	IN
cord-276598-tm0yj2sn	713	10	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	713	11	using	use	VBG
cord-276598-tm0yj2sn	713	12	a	a	DT
cord-276598-tm0yj2sn	713	13	chlorinating	chlorinate	VBG
cord-276598-tm0yj2sn	713	14	agent	agent	NN
cord-276598-tm0yj2sn	713	15	.	.	.
cord-276598-tm0yj2sn	714	1	The	the	DT
cord-276598-tm0yj2sn	714	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	714	3	of	of	IN
cord-276598-tm0yj2sn	714	4	the	the	DT
cord-276598-tm0yj2sn	714	5	reaction	reaction	NN
cord-276598-tm0yj2sn	714	6	by	by	IN
cord-276598-tm0yj2sn	714	7	Jang	Jang	NNP
cord-276598-tm0yj2sn	714	8	et	et	FW
cord-276598-tm0yj2sn	714	9	al	al	NNP
cord-276598-tm0yj2sn	714	10	.	.	NNP
cord-276598-tm0yj2sn	714	11	suggests	suggest	VBZ
cord-276598-tm0yj2sn	714	12	that	that	IN
cord-276598-tm0yj2sn	714	13	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	714	14	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	714	15	acid	acid	NN
cord-276598-tm0yj2sn	714	16	(	(	-LRB-
cord-276598-tm0yj2sn	714	17	dPPA	dppa	NN
cord-276598-tm0yj2sn	714	18	)	)	-RRB-
cord-276598-tm0yj2sn	714	19	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	714	20	chlorination	chlorination	NN
cord-276598-tm0yj2sn	714	21	in	in	IN
cord-276598-tm0yj2sn	714	22	the	the	DT
cord-276598-tm0yj2sn	714	23	presence	presence	NN
cord-276598-tm0yj2sn	714	24	of	of	IN
cord-276598-tm0yj2sn	714	25	a	a	DT
cord-276598-tm0yj2sn	714	26	base	base	NN
cord-276598-tm0yj2sn	714	27	,	,	,
cord-276598-tm0yj2sn	714	28	which	which	WDT
cord-276598-tm0yj2sn	714	29	is	be	VBZ
cord-276598-tm0yj2sn	714	30	subsequently	subsequently	RB
cord-276598-tm0yj2sn	714	31	attacked	attack	VBN
cord-276598-tm0yj2sn	714	32	by	by	IN
cord-276598-tm0yj2sn	714	33	the	the	DT
cord-276598-tm0yj2sn	714	34	amine	amine	NN
cord-276598-tm0yj2sn	714	35	to	to	TO
cord-276598-tm0yj2sn	714	36	afford	afford	VB
cord-276598-tm0yj2sn	714	37	the	the	DT
cord-276598-tm0yj2sn	714	38	P	P	NNP
cord-276598-tm0yj2sn	714	39	-	-	HYPH
cord-276598-tm0yj2sn	714	40	N	n	CD
cord-276598-tm0yj2sn	714	41	product	product	NN
cord-276598-tm0yj2sn	714	42	[	[	-LRB-
cord-276598-tm0yj2sn	714	43	99	99	CD
cord-276598-tm0yj2sn	714	44	]	]	-RRB-
cord-276598-tm0yj2sn	714	45	.	.	.
cord-276598-tm0yj2sn	715	1	Although	although	IN
cord-276598-tm0yj2sn	715	2	the	the	DT
cord-276598-tm0yj2sn	715	3	authors	author	NNS
cord-276598-tm0yj2sn	715	4	did	do	VBD
cord-276598-tm0yj2sn	715	5	not	not	RB
cord-276598-tm0yj2sn	715	6	propose	propose	VB
cord-276598-tm0yj2sn	715	7	any	any	DT
cord-276598-tm0yj2sn	715	8	mechanism	mechanism	NN
cord-276598-tm0yj2sn	715	9	,	,	,
cord-276598-tm0yj2sn	715	10	they	-PRON-	PRP
cord-276598-tm0yj2sn	715	11	suggested	suggest	VBD
cord-276598-tm0yj2sn	715	12	that	that	IN
cord-276598-tm0yj2sn	715	13	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	715	14	attack	attack	NN
cord-276598-tm0yj2sn	715	15	on	on	IN
cord-276598-tm0yj2sn	715	16	the	the	DT
cord-276598-tm0yj2sn	715	17	P	p	NN
cord-276598-tm0yj2sn	715	18	atom	atom	NN
cord-276598-tm0yj2sn	715	19	was	be	VBD
cord-276598-tm0yj2sn	715	20	consistent	consistent	JJ
cord-276598-tm0yj2sn	715	21	with	with	IN
cord-276598-tm0yj2sn	715	22	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	715	23	amines	amine	NNS
cord-276598-tm0yj2sn	715	24	resulting	result	VBG
cord-276598-tm0yj2sn	715	25	in	in	IN
cord-276598-tm0yj2sn	715	26	a	a	DT
cord-276598-tm0yj2sn	715	27	higher	high	JJR
cord-276598-tm0yj2sn	715	28	yield	yield	NN
cord-276598-tm0yj2sn	715	29	of	of	IN
cord-276598-tm0yj2sn	715	30	products	product	NNS
cord-276598-tm0yj2sn	715	31	than	than	IN
cord-276598-tm0yj2sn	715	32	the	the	DT
cord-276598-tm0yj2sn	715	33	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	715	34	amines	amine	NNS
cord-276598-tm0yj2sn	715	35	because	because	IN
cord-276598-tm0yj2sn	715	36	aliphatic	aliphatic	JJ
cord-276598-tm0yj2sn	715	37	amines	amine	NNS
cord-276598-tm0yj2sn	715	38	are	be	VBP
cord-276598-tm0yj2sn	715	39	more	more	RBR
cord-276598-tm0yj2sn	715	40	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	715	41	.	.	.
cord-276598-tm0yj2sn	716	1	The	the	DT
cord-276598-tm0yj2sn	716	2	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	716	3	step	step	NN
cord-276598-tm0yj2sn	716	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	716	5	by	by	IN
cord-276598-tm0yj2sn	716	6	Appel	Appel	NNP
cord-276598-tm0yj2sn	716	7	and	and	CC
cord-276598-tm0yj2sn	716	8	Einig	Einig	NNP
cord-276598-tm0yj2sn	716	9	involves	involve	VBZ
cord-276598-tm0yj2sn	716	10	the	the	DT
cord-276598-tm0yj2sn	716	11	formation	formation	NN
cord-276598-tm0yj2sn	716	12	of	of	IN
cord-276598-tm0yj2sn	716	13	oxo	oxo	NN
cord-276598-tm0yj2sn	716	14	-	-	HYPH
cord-276598-tm0yj2sn	716	15	triphenyl	triphenyl	NN
cord-276598-tm0yj2sn	716	16	-	-	HYPH
cord-276598-tm0yj2sn	716	17	diphosphoxanium	diphosphoxanium	NN
cord-276598-tm0yj2sn	716	18	salt	salt	NN
cord-276598-tm0yj2sn	716	19	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	716	20	from	from	IN
cord-276598-tm0yj2sn	716	21	a	a	DT
cord-276598-tm0yj2sn	716	22	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	716	23	of	of	IN
cord-276598-tm0yj2sn	716	24	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	716	25	acid	acid	NN
cord-276598-tm0yj2sn	716	26	by	by	IN
cord-276598-tm0yj2sn	716	27	CCl4	ccl4	NN
cord-276598-tm0yj2sn	716	28	in	in	IN
cord-276598-tm0yj2sn	716	29	the	the	DT
cord-276598-tm0yj2sn	716	30	presence	presence	NN
cord-276598-tm0yj2sn	716	31	of	of	IN
cord-276598-tm0yj2sn	716	32	phosphine	phosphine	NN
cord-276598-tm0yj2sn	716	33	(	(	-LRB-
cord-276598-tm0yj2sn	716	34	Scheme	scheme	NN
cord-276598-tm0yj2sn	716	35	23	23	CD
cord-276598-tm0yj2sn	716	36	)	)	-RRB-
cord-276598-tm0yj2sn	716	37	[	[	-LRB-
cord-276598-tm0yj2sn	716	38	86	86	CD
cord-276598-tm0yj2sn	716	39	]	]	-RRB-
cord-276598-tm0yj2sn	716	40	.	.	.
cord-276598-tm0yj2sn	717	1	Nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	717	2	substitution	substitution	NN
cord-276598-tm0yj2sn	717	3	from	from	IN
cord-276598-tm0yj2sn	717	4	amine	amine	NN
cord-276598-tm0yj2sn	717	5	results	result	NNS
cord-276598-tm0yj2sn	717	6	in	in	IN
cord-276598-tm0yj2sn	717	7	the	the	DT
cord-276598-tm0yj2sn	717	8	desired	desire	VBN
cord-276598-tm0yj2sn	717	9	product	product	NN
cord-276598-tm0yj2sn	717	10	and	and	CC
cord-276598-tm0yj2sn	717	11	triphenylphosphate	triphenylphosphate	NN
cord-276598-tm0yj2sn	717	12	as	as	IN
cord-276598-tm0yj2sn	717	13	the	the	DT
cord-276598-tm0yj2sn	717	14	by	by	IN
cord-276598-tm0yj2sn	717	15	-	-	HYPH
cord-276598-tm0yj2sn	717	16	product	product	NN
cord-276598-tm0yj2sn	717	17	.	.	.
cord-276598-tm0yj2sn	718	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	718	2	23	23	CD
cord-276598-tm0yj2sn	718	3	.	.	.
cord-276598-tm0yj2sn	719	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	719	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	719	3	for	for	IN
cord-276598-tm0yj2sn	719	4	the	the	DT
cord-276598-tm0yj2sn	719	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	719	6	of	of	IN
cord-276598-tm0yj2sn	719	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	719	8	from	from	IN
cord-276598-tm0yj2sn	719	9	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	719	10	acid	acid	NN
cord-276598-tm0yj2sn	719	11	and	and	CC
cord-276598-tm0yj2sn	719	12	amine	amine	NN
cord-276598-tm0yj2sn	719	13	in	in	IN
cord-276598-tm0yj2sn	719	14	the	the	DT
cord-276598-tm0yj2sn	719	15	presence	presence	NN
cord-276598-tm0yj2sn	719	16	of	of	IN
cord-276598-tm0yj2sn	719	17	phosphine	phosphine	NN
cord-276598-tm0yj2sn	719	18	and	and	CC
cord-276598-tm0yj2sn	719	19	CCl4	ccl4	NN
cord-276598-tm0yj2sn	719	20	.	.	.
cord-276598-tm0yj2sn	720	1	In	in	IN
cord-276598-tm0yj2sn	720	2	the	the	DT
cord-276598-tm0yj2sn	720	3	suggested	suggest	VBN
cord-276598-tm0yj2sn	720	4	reaction	reaction	NN
cord-276598-tm0yj2sn	720	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	720	6	by	by	IN
cord-276598-tm0yj2sn	720	7	[	[	-LRB-
cord-276598-tm0yj2sn	720	8	100	100	CD
cord-276598-tm0yj2sn	720	9	]	]	-RRB-
cord-276598-tm0yj2sn	720	10	,	,	,
cord-276598-tm0yj2sn	720	11	iodine	iodine	NN
cord-276598-tm0yj2sn	720	12	reacts	react	VBZ
cord-276598-tm0yj2sn	720	13	with	with	IN
cord-276598-tm0yj2sn	720	14	(	(	-LRB-
cord-276598-tm0yj2sn	720	15	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	720	16	(	(	-LRB-
cord-276598-tm0yj2sn	720	17	R	r	NN
cord-276598-tm0yj2sn	720	18	=	=	NN
cord-276598-tm0yj2sn	720	19	alkyl	alkyl	NN
cord-276598-tm0yj2sn	720	20	)	)	-RRB-
cord-276598-tm0yj2sn	720	21	to	to	TO
cord-276598-tm0yj2sn	720	22	form	form	VB
cord-276598-tm0yj2sn	720	23	trialkoxyiodophosphonium	trialkoxyiodophosphonium	NN
cord-276598-tm0yj2sn	720	24	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	720	25	,	,	,
cord-276598-tm0yj2sn	720	26	which	which	WDT
cord-276598-tm0yj2sn	720	27	is	be	VBZ
cord-276598-tm0yj2sn	720	28	further	further	RB
cord-276598-tm0yj2sn	720	29	attacked	attack	VBN
cord-276598-tm0yj2sn	720	30	by	by	IN
cord-276598-tm0yj2sn	720	31	iodide	iodide	NN
cord-276598-tm0yj2sn	720	32	ion	ion	NN
cord-276598-tm0yj2sn	720	33	to	to	TO
cord-276598-tm0yj2sn	720	34	form	form	VB
cord-276598-tm0yj2sn	720	35	dialkyl	dialkyl	FW
cord-276598-tm0yj2sn	720	36	phosphoriodidate	phosphoriodidate	NNP
cord-276598-tm0yj2sn	720	37	(	(	-LRB-
cord-276598-tm0yj2sn	720	38	dAPPI	dappi	NN
cord-276598-tm0yj2sn	720	39	)	)	-RRB-
cord-276598-tm0yj2sn	721	1	(	(	-LRB-
cord-276598-tm0yj2sn	721	2	Arbuzov	Arbuzov	NNP
cord-276598-tm0yj2sn	721	3	reaction	reaction	NN
cord-276598-tm0yj2sn	721	4	,	,	,
cord-276598-tm0yj2sn	721	5	Scheme	scheme	NN
cord-276598-tm0yj2sn	721	6	24	24	CD
cord-276598-tm0yj2sn	721	7	)	)	-RRB-
cord-276598-tm0yj2sn	721	8	.	.	.
cord-276598-tm0yj2sn	722	1	Then	then	RB
cord-276598-tm0yj2sn	722	2	,	,	,
cord-276598-tm0yj2sn	722	3	the	the	DT
cord-276598-tm0yj2sn	722	4	dAPPI	dappi	NN
cord-276598-tm0yj2sn	722	5	is	be	VBZ
cord-276598-tm0yj2sn	722	6	attacked	attack	VBN
cord-276598-tm0yj2sn	722	7	by	by	IN
cord-276598-tm0yj2sn	722	8	the	the	DT
cord-276598-tm0yj2sn	722	9	amine	amine	NN
cord-276598-tm0yj2sn	722	10	to	to	TO
cord-276598-tm0yj2sn	722	11	give	give	VB
cord-276598-tm0yj2sn	722	12	the	the	DT
cord-276598-tm0yj2sn	722	13	desired	desire	VBN
cord-276598-tm0yj2sn	722	14	P	P	NNP
cord-276598-tm0yj2sn	722	15	-	-	HYPH
cord-276598-tm0yj2sn	722	16	N	N	NNP
cord-276598-tm0yj2sn	722	17	with	with	IN
cord-276598-tm0yj2sn	722	18	an	an	DT
cord-276598-tm0yj2sn	722	19	elimination	elimination	NN
cord-276598-tm0yj2sn	722	20	of	of	IN
cord-276598-tm0yj2sn	722	21	HI	HI	NNP
cord-276598-tm0yj2sn	722	22	.	.	.
cord-276598-tm0yj2sn	723	1	N	N	NNP
cord-276598-tm0yj2sn	723	2	-	-	HYPH
cord-276598-tm0yj2sn	723	3	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	723	4	amino	amino	NN
cord-276598-tm0yj2sn	723	5	acid	acid	NN
cord-276598-tm0yj2sn	723	6	esters	ester	NNS
cord-276598-tm0yj2sn	723	7	and	and	CC
cord-276598-tm0yj2sn	723	8	P	P	NNP
cord-276598-tm0yj2sn	723	9	-	-	HYPH
cord-276598-tm0yj2sn	723	10	N	N	NNP
cord-276598-tm0yj2sn	723	11	with	with	IN
cord-276598-tm0yj2sn	723	12	a	a	DT
cord-276598-tm0yj2sn	723	13	free	free	JJ
cord-276598-tm0yj2sn	723	14	amino	amino	NN
cord-276598-tm0yj2sn	723	15	group	group	NN
cord-276598-tm0yj2sn	723	16	were	be	VBD
cord-276598-tm0yj2sn	723	17	also	also	RB
cord-276598-tm0yj2sn	723	18	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	723	19	using	use	VBG
cord-276598-tm0yj2sn	723	20	the	the	DT
cord-276598-tm0yj2sn	723	21	iodine	iodine	NN
cord-276598-tm0yj2sn	723	22	-	-	HYPH
cord-276598-tm0yj2sn	723	23	mediated	mediate	VBN
cord-276598-tm0yj2sn	723	24	synthesis	synthesis	NN
cord-276598-tm0yj2sn	723	25	method	method	NN
cord-276598-tm0yj2sn	723	26	.	.	.
cord-276598-tm0yj2sn	724	1	The	the	DT
cord-276598-tm0yj2sn	724	2	challenges	challenge	NNS
cord-276598-tm0yj2sn	724	3	with	with	IN
cord-276598-tm0yj2sn	724	4	this	this	DT
cord-276598-tm0yj2sn	724	5	iodine	iodine	NN
cord-276598-tm0yj2sn	724	6	-	-	HYPH
cord-276598-tm0yj2sn	724	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	724	8	P	p	NN
cord-276598-tm0yj2sn	724	9	-	-	HYPH
cord-276598-tm0yj2sn	724	10	N	n	CD
cord-276598-tm0yj2sn	724	11	formation	formation	NN
cord-276598-tm0yj2sn	724	12	is	be	VBZ
cord-276598-tm0yj2sn	724	13	that	that	IN
cord-276598-tm0yj2sn	724	14	many	many	JJ
cord-276598-tm0yj2sn	724	15	side	side	NN
cord-276598-tm0yj2sn	724	16	products	product	NNS
cord-276598-tm0yj2sn	724	17	are	be	VBP
cord-276598-tm0yj2sn	724	18	formed	form	VBN
cord-276598-tm0yj2sn	724	19	,	,	,
cord-276598-tm0yj2sn	724	20	and	and	CC
cord-276598-tm0yj2sn	724	21	the	the	DT
cord-276598-tm0yj2sn	724	22	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	724	23	23	23	CD
cord-276598-tm0yj2sn	724	24	.	.	.
cord-276598-tm0yj2sn	725	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	725	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	725	3	for	for	IN
cord-276598-tm0yj2sn	725	4	the	the	DT
cord-276598-tm0yj2sn	725	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	725	6	of	of	IN
cord-276598-tm0yj2sn	725	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	725	8	from	from	IN
cord-276598-tm0yj2sn	725	9	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	725	10	acid	acid	NN
cord-276598-tm0yj2sn	725	11	and	and	CC
cord-276598-tm0yj2sn	725	12	amine	amine	NN
cord-276598-tm0yj2sn	725	13	in	in	IN
cord-276598-tm0yj2sn	725	14	the	the	DT
cord-276598-tm0yj2sn	725	15	presence	presence	NN
cord-276598-tm0yj2sn	725	16	of	of	IN
cord-276598-tm0yj2sn	725	17	phosphine	phosphine	NN
cord-276598-tm0yj2sn	725	18	and	and	CC
cord-276598-tm0yj2sn	725	19	CCl	CCl	NNS
cord-276598-tm0yj2sn	725	20	4	4	CD
cord-276598-tm0yj2sn	725	21	.	.	.
cord-276598-tm0yj2sn	726	1	In	in	IN
cord-276598-tm0yj2sn	726	2	the	the	DT
cord-276598-tm0yj2sn	726	3	suggested	suggest	VBN
cord-276598-tm0yj2sn	726	4	reaction	reaction	NN
cord-276598-tm0yj2sn	726	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	726	6	by	by	IN
cord-276598-tm0yj2sn	726	7	[	[	-LRB-
cord-276598-tm0yj2sn	726	8	100	100	CD
cord-276598-tm0yj2sn	726	9	]	]	-RRB-
cord-276598-tm0yj2sn	726	10	,	,	,
cord-276598-tm0yj2sn	726	11	iodine	iodine	NN
cord-276598-tm0yj2sn	726	12	reacts	react	VBZ
cord-276598-tm0yj2sn	726	13	with	with	IN
cord-276598-tm0yj2sn	726	14	(	(	-LRB-
cord-276598-tm0yj2sn	726	15	RO	ro	NN
cord-276598-tm0yj2sn	726	16	)	)	-RRB-
cord-276598-tm0yj2sn	726	17	3	3	CD
cord-276598-tm0yj2sn	726	18	P	p	NN
cord-276598-tm0yj2sn	726	19	(	(	-LRB-
cord-276598-tm0yj2sn	726	20	R	r	NN
cord-276598-tm0yj2sn	726	21	=	=	NN
cord-276598-tm0yj2sn	726	22	alkyl	alkyl	NN
cord-276598-tm0yj2sn	726	23	)	)	-RRB-
cord-276598-tm0yj2sn	726	24	to	to	TO
cord-276598-tm0yj2sn	726	25	form	form	VB
cord-276598-tm0yj2sn	726	26	trialkoxyiodophosphonium	trialkoxyiodophosphonium	NN
cord-276598-tm0yj2sn	726	27	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	726	28	,	,	,
cord-276598-tm0yj2sn	726	29	which	which	WDT
cord-276598-tm0yj2sn	726	30	is	be	VBZ
cord-276598-tm0yj2sn	726	31	further	further	RB
cord-276598-tm0yj2sn	726	32	attacked	attack	VBN
cord-276598-tm0yj2sn	726	33	by	by	IN
cord-276598-tm0yj2sn	726	34	iodide	iodide	NN
cord-276598-tm0yj2sn	726	35	ion	ion	NN
cord-276598-tm0yj2sn	726	36	to	to	TO
cord-276598-tm0yj2sn	726	37	form	form	VB
cord-276598-tm0yj2sn	726	38	dialkyl	dialkyl	FW
cord-276598-tm0yj2sn	726	39	phosphoriodidate	phosphoriodidate	NNP
cord-276598-tm0yj2sn	726	40	(	(	-LRB-
cord-276598-tm0yj2sn	726	41	dAPPI	dappi	NN
cord-276598-tm0yj2sn	726	42	)	)	-RRB-
cord-276598-tm0yj2sn	727	1	(	(	-LRB-
cord-276598-tm0yj2sn	727	2	Arbuzov	Arbuzov	NNP
cord-276598-tm0yj2sn	727	3	reaction	reaction	NN
cord-276598-tm0yj2sn	727	4	,	,	,
cord-276598-tm0yj2sn	727	5	Scheme	scheme	NN
cord-276598-tm0yj2sn	727	6	24	24	CD
cord-276598-tm0yj2sn	727	7	)	)	-RRB-
cord-276598-tm0yj2sn	727	8	.	.	.
cord-276598-tm0yj2sn	728	1	Then	then	RB
cord-276598-tm0yj2sn	728	2	,	,	,
cord-276598-tm0yj2sn	728	3	the	the	DT
cord-276598-tm0yj2sn	728	4	dAPPI	dappi	NN
cord-276598-tm0yj2sn	728	5	is	be	VBZ
cord-276598-tm0yj2sn	728	6	attacked	attack	VBN
cord-276598-tm0yj2sn	728	7	by	by	IN
cord-276598-tm0yj2sn	728	8	the	the	DT
cord-276598-tm0yj2sn	728	9	amine	amine	NN
cord-276598-tm0yj2sn	728	10	to	to	TO
cord-276598-tm0yj2sn	728	11	give	give	VB
cord-276598-tm0yj2sn	728	12	the	the	DT
cord-276598-tm0yj2sn	728	13	desired	desire	VBN
cord-276598-tm0yj2sn	728	14	P	P	NNP
cord-276598-tm0yj2sn	728	15	-	-	HYPH
cord-276598-tm0yj2sn	728	16	N	N	NNP
cord-276598-tm0yj2sn	728	17	with	with	IN
cord-276598-tm0yj2sn	728	18	an	an	DT
cord-276598-tm0yj2sn	728	19	elimination	elimination	NN
cord-276598-tm0yj2sn	728	20	of	of	IN
cord-276598-tm0yj2sn	728	21	HI	HI	NNP
cord-276598-tm0yj2sn	728	22	.	.	.
cord-276598-tm0yj2sn	729	1	N	N	NNP
cord-276598-tm0yj2sn	729	2	-	-	HYPH
cord-276598-tm0yj2sn	729	3	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	729	4	amino	amino	NN
cord-276598-tm0yj2sn	729	5	acid	acid	NN
cord-276598-tm0yj2sn	729	6	esters	ester	NNS
cord-276598-tm0yj2sn	729	7	and	and	CC
cord-276598-tm0yj2sn	729	8	P	P	NNP
cord-276598-tm0yj2sn	729	9	-	-	HYPH
cord-276598-tm0yj2sn	729	10	N	N	NNP
cord-276598-tm0yj2sn	729	11	with	with	IN
cord-276598-tm0yj2sn	729	12	a	a	DT
cord-276598-tm0yj2sn	729	13	free	free	JJ
cord-276598-tm0yj2sn	729	14	amino	amino	NN
cord-276598-tm0yj2sn	729	15	group	group	NN
cord-276598-tm0yj2sn	729	16	were	be	VBD
cord-276598-tm0yj2sn	729	17	also	also	RB
cord-276598-tm0yj2sn	729	18	synthesized	synthesize	VBN
cord-276598-tm0yj2sn	729	19	using	use	VBG
cord-276598-tm0yj2sn	729	20	the	the	DT
cord-276598-tm0yj2sn	729	21	iodine	iodine	NN
cord-276598-tm0yj2sn	729	22	-	-	HYPH
cord-276598-tm0yj2sn	729	23	mediated	mediate	VBN
cord-276598-tm0yj2sn	729	24	synthesis	synthesis	NN
cord-276598-tm0yj2sn	729	25	method	method	NN
cord-276598-tm0yj2sn	729	26	.	.	.
cord-276598-tm0yj2sn	730	1	The	the	DT
cord-276598-tm0yj2sn	730	2	challenges	challenge	NNS
cord-276598-tm0yj2sn	730	3	with	with	IN
cord-276598-tm0yj2sn	730	4	this	this	DT
cord-276598-tm0yj2sn	730	5	iodine	iodine	NN
cord-276598-tm0yj2sn	730	6	-	-	HYPH
cord-276598-tm0yj2sn	730	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	730	8	P	p	NN
cord-276598-tm0yj2sn	730	9	-	-	HYPH
cord-276598-tm0yj2sn	730	10	N	n	CD
cord-276598-tm0yj2sn	730	11	formation	formation	NN
cord-276598-tm0yj2sn	730	12	is	be	VBZ
cord-276598-tm0yj2sn	730	13	that	that	IN
cord-276598-tm0yj2sn	730	14	many	many	JJ
cord-276598-tm0yj2sn	730	15	side	side	NN
cord-276598-tm0yj2sn	730	16	products	product	NNS
cord-276598-tm0yj2sn	730	17	are	be	VBP
cord-276598-tm0yj2sn	730	18	formed	form	VBN
cord-276598-tm0yj2sn	730	19	,	,	,
cord-276598-tm0yj2sn	730	20	and	and	CC
cord-276598-tm0yj2sn	730	21	the	the	DT
cord-276598-tm0yj2sn	730	22	reaction	reaction	NN
cord-276598-tm0yj2sn	730	23	procedure	procedure	NN
cord-276598-tm0yj2sn	730	24	does	do	VBZ
cord-276598-tm0yj2sn	730	25	not	not	RB
cord-276598-tm0yj2sn	730	26	generate	generate	VB
cord-276598-tm0yj2sn	730	27	the	the	DT
cord-276598-tm0yj2sn	730	28	desired	desire	VBN
cord-276598-tm0yj2sn	730	29	product	product	NN
cord-276598-tm0yj2sn	730	30	when	when	WRB
cord-276598-tm0yj2sn	730	31	N	n	CD
cord-276598-tm0yj2sn	730	32	-	-	HYPH
cord-276598-tm0yj2sn	730	33	iodosuccinimide	iodosuccinimide	NNP
cord-276598-tm0yj2sn	730	34	(	(	-LRB-
cord-276598-tm0yj2sn	730	35	NIS	NIS	NNP
cord-276598-tm0yj2sn	730	36	)	)	-RRB-
cord-276598-tm0yj2sn	730	37	is	be	VBZ
cord-276598-tm0yj2sn	730	38	used	use	VBN
cord-276598-tm0yj2sn	730	39	as	as	IN
cord-276598-tm0yj2sn	730	40	the	the	DT
cord-276598-tm0yj2sn	730	41	iodine	iodine	NN
cord-276598-tm0yj2sn	730	42	source	source	NN
cord-276598-tm0yj2sn	730	43	.	.	.
cord-276598-tm0yj2sn	731	1	In	in	IN
cord-276598-tm0yj2sn	731	2	addition	addition	NN
cord-276598-tm0yj2sn	731	3	,	,	,
cord-276598-tm0yj2sn	731	4	the	the	DT
cord-276598-tm0yj2sn	731	5	reaction	reaction	NN
cord-276598-tm0yj2sn	731	6	process	process	NN
cord-276598-tm0yj2sn	731	7	is	be	VBZ
cord-276598-tm0yj2sn	731	8	ineffective	ineffective	JJ
cord-276598-tm0yj2sn	731	9	with	with	IN
cord-276598-tm0yj2sn	731	10	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	731	11	H	h	NN
cord-276598-tm0yj2sn	731	12	-	-	HYPH
cord-276598-tm0yj2sn	731	13	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	731	14	because	because	IN
cord-276598-tm0yj2sn	731	15	the	the	DT
cord-276598-tm0yj2sn	731	16	reaction	reaction	NN
cord-276598-tm0yj2sn	731	17	is	be	VBZ
cord-276598-tm0yj2sn	731	18	affected	affect	VBN
cord-276598-tm0yj2sn	731	19	by	by	IN
cord-276598-tm0yj2sn	731	20	steric	steric	JJ
cord-276598-tm0yj2sn	731	21	effects	effect	NNS
cord-276598-tm0yj2sn	731	22	on	on	IN
cord-276598-tm0yj2sn	731	23	the	the	DT
cord-276598-tm0yj2sn	731	24	substituents	substituent	NNS
cord-276598-tm0yj2sn	731	25	.	.	.
cord-276598-tm0yj2sn	732	1	In	in	IN
cord-276598-tm0yj2sn	732	2	a	a	DT
cord-276598-tm0yj2sn	732	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	732	4	of	of	IN
cord-276598-tm0yj2sn	732	5	the	the	DT
cord-276598-tm0yj2sn	732	6	I	I	NNP
cord-276598-tm0yj2sn	732	7	2	2	CD
cord-276598-tm0yj2sn	732	8	-mediated	-mediated	JJ
cord-276598-tm0yj2sn	732	9	P	P	NNP
cord-276598-tm0yj2sn	732	10	-	-	HYPH
cord-276598-tm0yj2sn	732	11	N	n	CD
cord-276598-tm0yj2sn	732	12	formation	formation	NN
cord-276598-tm0yj2sn	732	13	,	,	,
cord-276598-tm0yj2sn	732	14	according	accord	VBG
cord-276598-tm0yj2sn	732	15	to	to	IN
cord-276598-tm0yj2sn	732	16	Singh	Singh	NNP
cord-276598-tm0yj2sn	732	17	et	et	NNP
cord-276598-tm0yj2sn	732	18	al	al	NNP
cord-276598-tm0yj2sn	732	19	.	.	.
cord-276598-tm0yj2sn	733	1	,	,	,
cord-276598-tm0yj2sn	733	2	H	H	NNP
cord-276598-tm0yj2sn	733	3	-	-	HYPH
cord-276598-tm0yj2sn	733	4	P	P	NNP
cord-276598-tm0yj2sn	733	5	reacts	react	VBZ
cord-276598-tm0yj2sn	733	6	with	with	IN
cord-276598-tm0yj2sn	733	7	I	-PRON-	PRP
cord-276598-tm0yj2sn	733	8	2	2	CD
cord-276598-tm0yj2sn	733	9	to	to	TO
cord-276598-tm0yj2sn	733	10	form	form	VB
cord-276598-tm0yj2sn	733	11	an	an	DT
cord-276598-tm0yj2sn	733	12	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	733	13	,	,	,
cord-276598-tm0yj2sn	733	14	which	which	WDT
cord-276598-tm0yj2sn	733	15	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	733	16	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	733	17	attack	attack	NN
cord-276598-tm0yj2sn	733	18	from	from	IN
cord-276598-tm0yj2sn	733	19	the	the	DT
cord-276598-tm0yj2sn	733	20	amine	amine	NN
cord-276598-tm0yj2sn	733	21	to	to	TO
cord-276598-tm0yj2sn	733	22	generate	generate	VB
cord-276598-tm0yj2sn	733	23	a	a	DT
cord-276598-tm0yj2sn	733	24	hydroxylated	hydroxylate	VBN
cord-276598-tm0yj2sn	733	25	-	-	HYPH
cord-276598-tm0yj2sn	733	26	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	733	27	phenylphosphoramidate	phenylphosphoramidate	NN
cord-276598-tm0yj2sn	733	28	complex	complex	NN
cord-276598-tm0yj2sn	733	29	with	with	IN
cord-276598-tm0yj2sn	733	30	an	an	DT
cord-276598-tm0yj2sn	733	31	elimination	elimination	NN
cord-276598-tm0yj2sn	733	32	of	of	IN
cord-276598-tm0yj2sn	733	33	I	i	NN
cord-276598-tm0yj2sn	733	34	2	2	CD
cord-276598-tm0yj2sn	733	35	(	(	-LRB-
cord-276598-tm0yj2sn	733	36	Scheme	scheme	NN
cord-276598-tm0yj2sn	733	37	25	25	CD
cord-276598-tm0yj2sn	733	38	)	)	-RRB-
cord-276598-tm0yj2sn	734	1	[	[	-LRB-
cord-276598-tm0yj2sn	734	2	101	101	CD
cord-276598-tm0yj2sn	734	3	]	]	-RRB-
cord-276598-tm0yj2sn	734	4	.	.	.
cord-276598-tm0yj2sn	735	1	The	the	DT
cord-276598-tm0yj2sn	735	2	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	735	3	complex	complex	NN
cord-276598-tm0yj2sn	735	4	further	further	RB
cord-276598-tm0yj2sn	735	5	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	735	6	dehydrogenation	dehydrogenation	NN
cord-276598-tm0yj2sn	735	7	to	to	TO
cord-276598-tm0yj2sn	735	8	eliminate	eliminate	VB
cord-276598-tm0yj2sn	735	9	H	H	NNP
cord-276598-tm0yj2sn	735	10	2	2	CD
cord-276598-tm0yj2sn	735	11	in	in	IN
cord-276598-tm0yj2sn	735	12	form	form	NN
cord-276598-tm0yj2sn	735	13	of	of	IN
cord-276598-tm0yj2sn	735	14	H	h	NN
cord-276598-tm0yj2sn	735	15	2	2	CD
cord-276598-tm0yj2sn	735	16	O	o	NN
cord-276598-tm0yj2sn	735	17	and	and	CC
cord-276598-tm0yj2sn	735	18	afford	afford	VB
cord-276598-tm0yj2sn	735	19	the	the	DT
cord-276598-tm0yj2sn	735	20	desired	desire	VBN
cord-276598-tm0yj2sn	735	21	products	product	NNS
cord-276598-tm0yj2sn	735	22	.	.	.
cord-276598-tm0yj2sn	736	1	The	the	DT
cord-276598-tm0yj2sn	736	2	suggested	suggested	JJ
cord-276598-tm0yj2sn	736	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	736	4	of	of	IN
cord-276598-tm0yj2sn	736	5	a	a	DT
cord-276598-tm0yj2sn	736	6	similar	similar	JJ
cord-276598-tm0yj2sn	736	7	reaction	reaction	NN
cord-276598-tm0yj2sn	736	8	reported	report	VBN
cord-276598-tm0yj2sn	736	9	by	by	IN
cord-276598-tm0yj2sn	736	10	Prabhu	Prabhu	NNP
cord-276598-tm0yj2sn	736	11	et	et	NNP
cord-276598-tm0yj2sn	736	12	al	al	NNP
cord-276598-tm0yj2sn	736	13	.	.	.
cord-276598-tm0yj2sn	737	1	instead	instead	RB
cord-276598-tm0yj2sn	737	2	involves	involve	VBZ
cord-276598-tm0yj2sn	737	3	the	the	DT
cord-276598-tm0yj2sn	737	4	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	737	5	substitution	substitution	NN
cord-276598-tm0yj2sn	737	6	of	of	IN
cord-276598-tm0yj2sn	737	7	phosphoriodate	phosphoriodate	NN
cord-276598-tm0yj2sn	737	8	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	737	9	after	after	IN
cord-276598-tm0yj2sn	737	10	the	the	DT
cord-276598-tm0yj2sn	737	11	electrophilic	electrophilic	JJ
cord-276598-tm0yj2sn	737	12	iodination	iodination	NN
cord-276598-tm0yj2sn	737	13	of	of	IN
cord-276598-tm0yj2sn	737	14	the	the	DT
cord-276598-tm0yj2sn	737	15	H	H	NNP
cord-276598-tm0yj2sn	737	16	-	-	HYPH
cord-276598-tm0yj2sn	737	17	P	p	NN
cord-276598-tm0yj2sn	737	18	starting	starting	NN
cord-276598-tm0yj2sn	737	19	material	material	NN
cord-276598-tm0yj2sn	737	20	(	(	-LRB-
cord-276598-tm0yj2sn	737	21	Scheme	scheme	NN
cord-276598-tm0yj2sn	737	22	26	26	CD
cord-276598-tm0yj2sn	737	23	)	)	-RRB-
cord-276598-tm0yj2sn	737	24	[	[	-LRB-
cord-276598-tm0yj2sn	737	25	102	102	CD
cord-276598-tm0yj2sn	737	26	]	]	-RRB-
cord-276598-tm0yj2sn	737	27	.	.	.
cord-276598-tm0yj2sn	738	1	Then	then	RB
cord-276598-tm0yj2sn	738	2	,	,	,
cord-276598-tm0yj2sn	738	3	the	the	DT
cord-276598-tm0yj2sn	738	4	iodide	iodide	NN
cord-276598-tm0yj2sn	738	5	ion	ion	NN
cord-276598-tm0yj2sn	738	6	is	be	VBZ
cord-276598-tm0yj2sn	738	7	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	738	8	to	to	IN
cord-276598-tm0yj2sn	738	9	active	active	JJ
cord-276598-tm0yj2sn	738	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	738	11	,	,	,
cord-276598-tm0yj2sn	738	12	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	738	13	acid	acid	NN
cord-276598-tm0yj2sn	738	14	,	,	,
cord-276598-tm0yj2sn	738	15	in	in	IN
cord-276598-tm0yj2sn	738	16	the	the	DT
cord-276598-tm0yj2sn	738	17	presence	presence	NN
cord-276598-tm0yj2sn	738	18	of	of	IN
cord-276598-tm0yj2sn	738	19	H	h	NN
cord-276598-tm0yj2sn	738	20	2	2	CD
cord-276598-tm0yj2sn	738	21	O	o	NN
cord-276598-tm0yj2sn	738	22	2	2	CD
cord-276598-tm0yj2sn	738	23	.	.	.
cord-276598-tm0yj2sn	739	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	739	2	2020	2020	CD
cord-276598-tm0yj2sn	739	3	,	,	,
cord-276598-tm0yj2sn	739	4	25	25	CD
cord-276598-tm0yj2sn	739	5	,	,	,
cord-276598-tm0yj2sn	739	6	x	x	NN
cord-276598-tm0yj2sn	739	7	FOR	for	IN
cord-276598-tm0yj2sn	739	8	PEER	PEER	NNP
cord-276598-tm0yj2sn	739	9	REVIEW	REVIEW	NNP
cord-276598-tm0yj2sn	739	10	22	22	CD
cord-276598-tm0yj2sn	739	11	of	of	IN
cord-276598-tm0yj2sn	739	12	37	37	CD
cord-276598-tm0yj2sn	739	13	reaction	reaction	NN
cord-276598-tm0yj2sn	739	14	procedure	procedure	NN
cord-276598-tm0yj2sn	739	15	does	do	VBZ
cord-276598-tm0yj2sn	739	16	not	not	RB
cord-276598-tm0yj2sn	739	17	generate	generate	VB
cord-276598-tm0yj2sn	739	18	the	the	DT
cord-276598-tm0yj2sn	739	19	desired	desire	VBN
cord-276598-tm0yj2sn	739	20	product	product	NN
cord-276598-tm0yj2sn	739	21	when	when	WRB
cord-276598-tm0yj2sn	739	22	N	n	CD
cord-276598-tm0yj2sn	739	23	-	-	HYPH
cord-276598-tm0yj2sn	739	24	iodosuccinimide	iodosuccinimide	NNP
cord-276598-tm0yj2sn	739	25	(	(	-LRB-
cord-276598-tm0yj2sn	739	26	NIS	NIS	NNP
cord-276598-tm0yj2sn	739	27	)	)	-RRB-
cord-276598-tm0yj2sn	739	28	is	be	VBZ
cord-276598-tm0yj2sn	739	29	used	use	VBN
cord-276598-tm0yj2sn	739	30	as	as	IN
cord-276598-tm0yj2sn	739	31	the	the	DT
cord-276598-tm0yj2sn	739	32	iodine	iodine	NN
cord-276598-tm0yj2sn	739	33	source	source	NN
cord-276598-tm0yj2sn	739	34	.	.	.
cord-276598-tm0yj2sn	740	1	In	in	IN
cord-276598-tm0yj2sn	740	2	addition	addition	NN
cord-276598-tm0yj2sn	740	3	,	,	,
cord-276598-tm0yj2sn	740	4	the	the	DT
cord-276598-tm0yj2sn	740	5	reaction	reaction	NN
cord-276598-tm0yj2sn	740	6	process	process	NN
cord-276598-tm0yj2sn	740	7	is	be	VBZ
cord-276598-tm0yj2sn	740	8	ineffective	ineffective	JJ
cord-276598-tm0yj2sn	740	9	with	with	IN
cord-276598-tm0yj2sn	740	10	aromatic	aromatic	JJ
cord-276598-tm0yj2sn	740	11	H	h	NN
cord-276598-tm0yj2sn	740	12	-	-	HYPH
cord-276598-tm0yj2sn	740	13	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	740	14	because	because	IN
cord-276598-tm0yj2sn	740	15	the	the	DT
cord-276598-tm0yj2sn	740	16	reaction	reaction	NN
cord-276598-tm0yj2sn	740	17	is	be	VBZ
cord-276598-tm0yj2sn	740	18	affected	affect	VBN
cord-276598-tm0yj2sn	740	19	by	by	IN
cord-276598-tm0yj2sn	740	20	steric	steric	JJ
cord-276598-tm0yj2sn	740	21	effects	effect	NNS
cord-276598-tm0yj2sn	740	22	on	on	IN
cord-276598-tm0yj2sn	740	23	the	the	DT
cord-276598-tm0yj2sn	740	24	substituents	substituent	NNS
cord-276598-tm0yj2sn	740	25	.	.	.
cord-276598-tm0yj2sn	741	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	741	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	741	3	for	for	IN
cord-276598-tm0yj2sn	741	4	the	the	DT
cord-276598-tm0yj2sn	741	5	iodine	iodine	NN
cord-276598-tm0yj2sn	741	6	-	-	HYPH
cord-276598-tm0yj2sn	741	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	741	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	741	9	of	of	IN
cord-276598-tm0yj2sn	741	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	741	11	.	.	.
cord-276598-tm0yj2sn	742	1	In	in	IN
cord-276598-tm0yj2sn	742	2	a	a	DT
cord-276598-tm0yj2sn	742	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	742	4	of	of	IN
cord-276598-tm0yj2sn	742	5	the	the	DT
cord-276598-tm0yj2sn	742	6	I2-mediated	I2-mediated	NNP
cord-276598-tm0yj2sn	742	7	P	P	NNP
cord-276598-tm0yj2sn	742	8	-	-	HYPH
cord-276598-tm0yj2sn	742	9	N	N	NNP
cord-276598-tm0yj2sn	742	10	formation	formation	NN
cord-276598-tm0yj2sn	742	11	,	,	,
cord-276598-tm0yj2sn	742	12	according	accord	VBG
cord-276598-tm0yj2sn	742	13	to	to	IN
cord-276598-tm0yj2sn	742	14	Singh	Singh	NNP
cord-276598-tm0yj2sn	742	15	et	et	NNP
cord-276598-tm0yj2sn	742	16	al	al	NNP
cord-276598-tm0yj2sn	742	17	.	.	NNP
cord-276598-tm0yj2sn	742	18	,	,	,
cord-276598-tm0yj2sn	742	19	H	H	NNP
cord-276598-tm0yj2sn	742	20	-	-	HYPH
cord-276598-tm0yj2sn	742	21	P	P	NNP
cord-276598-tm0yj2sn	742	22	reacts	react	VBZ
cord-276598-tm0yj2sn	742	23	with	with	IN
cord-276598-tm0yj2sn	742	24	I2	I2	NNP
cord-276598-tm0yj2sn	742	25	to	to	TO
cord-276598-tm0yj2sn	742	26	form	form	VB
cord-276598-tm0yj2sn	742	27	an	an	DT
cord-276598-tm0yj2sn	742	28	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	742	29	,	,	,
cord-276598-tm0yj2sn	742	30	which	which	WDT
cord-276598-tm0yj2sn	742	31	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	742	32	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	742	33	attack	attack	NN
cord-276598-tm0yj2sn	742	34	from	from	IN
cord-276598-tm0yj2sn	742	35	the	the	DT
cord-276598-tm0yj2sn	742	36	amine	amine	NN
cord-276598-tm0yj2sn	742	37	to	to	TO
cord-276598-tm0yj2sn	742	38	generate	generate	VB
cord-276598-tm0yj2sn	742	39	a	a	DT
cord-276598-tm0yj2sn	742	40	hydroxylated	hydroxylate	VBN
cord-276598-tm0yj2sn	742	41	-	-	HYPH
cord-276598-tm0yj2sn	742	42	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	742	43	phenylphosphoramidate	phenylphosphoramidate	NN
cord-276598-tm0yj2sn	742	44	complex	complex	NN
cord-276598-tm0yj2sn	742	45	with	with	IN
cord-276598-tm0yj2sn	742	46	an	an	DT
cord-276598-tm0yj2sn	742	47	elimination	elimination	NN
cord-276598-tm0yj2sn	742	48	of	of	IN
cord-276598-tm0yj2sn	742	49	I2	I2	NNP
cord-276598-tm0yj2sn	742	50	(	(	-LRB-
cord-276598-tm0yj2sn	742	51	Scheme	scheme	NN
cord-276598-tm0yj2sn	742	52	25	25	CD
cord-276598-tm0yj2sn	742	53	)	)	-RRB-
cord-276598-tm0yj2sn	742	54	[	[	-LRB-
cord-276598-tm0yj2sn	742	55	101	101	CD
cord-276598-tm0yj2sn	742	56	]	]	-RRB-
cord-276598-tm0yj2sn	742	57	.	.	.
cord-276598-tm0yj2sn	743	1	The	the	DT
cord-276598-tm0yj2sn	743	2	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	743	3	complex	complex	NN
cord-276598-tm0yj2sn	743	4	further	further	RB
cord-276598-tm0yj2sn	743	5	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	743	6	dehydrogenation	dehydrogenation	NN
cord-276598-tm0yj2sn	743	7	to	to	TO
cord-276598-tm0yj2sn	743	8	eliminate	eliminate	VB
cord-276598-tm0yj2sn	743	9	H2	H2	NNP
cord-276598-tm0yj2sn	743	10	in	in	IN
cord-276598-tm0yj2sn	743	11	form	form	NN
cord-276598-tm0yj2sn	743	12	of	of	IN
cord-276598-tm0yj2sn	743	13	H2O	h2o	NN
cord-276598-tm0yj2sn	743	14	and	and	CC
cord-276598-tm0yj2sn	743	15	afford	afford	VB
cord-276598-tm0yj2sn	743	16	the	the	DT
cord-276598-tm0yj2sn	743	17	desired	desire	VBN
cord-276598-tm0yj2sn	743	18	products	product	NNS
cord-276598-tm0yj2sn	743	19	.	.	.
cord-276598-tm0yj2sn	744	1	[	[	-LRB-
cord-276598-tm0yj2sn	744	2	102	102	CD
cord-276598-tm0yj2sn	744	3	]	]	-RRB-
cord-276598-tm0yj2sn	744	4	.	.	.
cord-276598-tm0yj2sn	745	1	Then	then	RB
cord-276598-tm0yj2sn	745	2	,	,	,
cord-276598-tm0yj2sn	745	3	the	the	DT
cord-276598-tm0yj2sn	745	4	iodide	iodide	NN
cord-276598-tm0yj2sn	745	5	ion	ion	NN
cord-276598-tm0yj2sn	745	6	is	be	VBZ
cord-276598-tm0yj2sn	745	7	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	745	8	to	to	IN
cord-276598-tm0yj2sn	745	9	active	active	JJ
cord-276598-tm0yj2sn	745	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	745	11	,	,	,
cord-276598-tm0yj2sn	745	12	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	745	13	acid	acid	NN
cord-276598-tm0yj2sn	745	14	,	,	,
cord-276598-tm0yj2sn	745	15	in	in	IN
cord-276598-tm0yj2sn	745	16	the	the	DT
cord-276598-tm0yj2sn	745	17	presence	presence	NN
cord-276598-tm0yj2sn	745	18	of	of	IN
cord-276598-tm0yj2sn	745	19	H2O2	H2O2	NNP
cord-276598-tm0yj2sn	745	20	.	.	.
cord-276598-tm0yj2sn	746	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	746	2	26	26	CD
cord-276598-tm0yj2sn	746	3	.	.	.
cord-276598-tm0yj2sn	747	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	747	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	747	3	for	for	IN
cord-276598-tm0yj2sn	747	4	the	the	DT
cord-276598-tm0yj2sn	747	5	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	747	6	acid	acid	NN
cord-276598-tm0yj2sn	747	7	-	-	HYPH
cord-276598-tm0yj2sn	747	8	mediated	mediate	VBN
cord-276598-tm0yj2sn	747	9	synthesis	synthesis	NN
cord-276598-tm0yj2sn	747	10	of	of	IN
cord-276598-tm0yj2sn	747	11	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	747	12	.	.	.
cord-276598-tm0yj2sn	748	1	In	in	IN
cord-276598-tm0yj2sn	748	2	a	a	DT
cord-276598-tm0yj2sn	748	3	copper	copper	NN
cord-276598-tm0yj2sn	748	4	-	-	HYPH
cord-276598-tm0yj2sn	748	5	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	748	6	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	748	7	cross	cross	JJ
cord-276598-tm0yj2sn	748	8	-	-	JJ
cord-276598-tm0yj2sn	748	9	coupling	coupling	JJ
cord-276598-tm0yj2sn	748	10	reaction	reaction	NN
cord-276598-tm0yj2sn	748	11	,	,	,
cord-276598-tm0yj2sn	748	12	Hayes	Hayes	NNP
cord-276598-tm0yj2sn	748	13	et	et	NNP
cord-276598-tm0yj2sn	748	14	al	al	NNP
cord-276598-tm0yj2sn	748	15	.	.	NNP
cord-276598-tm0yj2sn	748	16	proposed	propose	VBD
cord-276598-tm0yj2sn	748	17	a	a	DT
cord-276598-tm0yj2sn	748	18	reaction	reaction	NN
cord-276598-tm0yj2sn	748	19	mechanism	mechanism	NN
cord-276598-tm0yj2sn	748	20	involving	involve	VBG
cord-276598-tm0yj2sn	748	21	single	single	JJ
cord-276598-tm0yj2sn	748	22	-	-	HYPH
cord-276598-tm0yj2sn	748	23	electron	electron	NN
cord-276598-tm0yj2sn	748	24	transfer	transfer	NN
cord-276598-tm0yj2sn	748	25	oxidation	oxidation	NN
cord-276598-tm0yj2sn	748	26	of	of	IN
cord-276598-tm0yj2sn	748	27	the	the	DT
cord-276598-tm0yj2sn	748	28	copper	copper	NN
cord-276598-tm0yj2sn	748	29	catalyst	catalyst	NN
cord-276598-tm0yj2sn	748	30	,	,	,
cord-276598-tm0yj2sn	748	31	which	which	WDT
cord-276598-tm0yj2sn	748	32	favored	favor	VBD
cord-276598-tm0yj2sn	748	33	the	the	DT
cord-276598-tm0yj2sn	748	34	formation	formation	NN
cord-276598-tm0yj2sn	748	35	of	of	IN
cord-276598-tm0yj2sn	748	36	the	the	DT
cord-276598-tm0yj2sn	748	37	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	748	38	complex	complex	NN
cord-276598-tm0yj2sn	748	39	(	(	-LRB-
cord-276598-tm0yj2sn	748	40	Scheme	scheme	NN
cord-276598-tm0yj2sn	748	41	27	27	CD
cord-276598-tm0yj2sn	748	42	)	)	-RRB-
cord-276598-tm0yj2sn	748	43	[	[	-LRB-
cord-276598-tm0yj2sn	748	44	103	103	CD
cord-276598-tm0yj2sn	748	45	]	]	-RRB-
cord-276598-tm0yj2sn	748	46	.	.	.
cord-276598-tm0yj2sn	749	1	The	the	DT
cord-276598-tm0yj2sn	749	2	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	749	3	complex	complex	NN
cord-276598-tm0yj2sn	749	4	is	be	VBZ
cord-276598-tm0yj2sn	749	5	further	further	JJ
cord-276598-tm0yj2sn	749	6	Scheme	scheme	NN
cord-276598-tm0yj2sn	749	7	24	24	CD
cord-276598-tm0yj2sn	749	8	.	.	.
cord-276598-tm0yj2sn	750	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	750	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	750	3	for	for	IN
cord-276598-tm0yj2sn	750	4	the	the	DT
cord-276598-tm0yj2sn	750	5	iodine	iodine	NN
cord-276598-tm0yj2sn	750	6	-	-	HYPH
cord-276598-tm0yj2sn	750	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	750	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	750	9	of	of	IN
cord-276598-tm0yj2sn	750	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	750	11	.	.	.
cord-276598-tm0yj2sn	751	1	because	because	IN
cord-276598-tm0yj2sn	751	2	the	the	DT
cord-276598-tm0yj2sn	751	3	reaction	reaction	NN
cord-276598-tm0yj2sn	751	4	is	be	VBZ
cord-276598-tm0yj2sn	751	5	affected	affect	VBN
cord-276598-tm0yj2sn	751	6	by	by	IN
cord-276598-tm0yj2sn	751	7	steric	steric	JJ
cord-276598-tm0yj2sn	751	8	effects	effect	NNS
cord-276598-tm0yj2sn	751	9	on	on	IN
cord-276598-tm0yj2sn	751	10	the	the	DT
cord-276598-tm0yj2sn	751	11	substituents	substituent	NNS
cord-276598-tm0yj2sn	751	12	.	.	.
cord-276598-tm0yj2sn	752	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	752	2	24	24	CD
cord-276598-tm0yj2sn	752	3	.	.	.
cord-276598-tm0yj2sn	753	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	753	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	753	3	for	for	IN
cord-276598-tm0yj2sn	753	4	the	the	DT
cord-276598-tm0yj2sn	753	5	iodine	iodine	NN
cord-276598-tm0yj2sn	753	6	-	-	HYPH
cord-276598-tm0yj2sn	753	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	753	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	753	9	of	of	IN
cord-276598-tm0yj2sn	753	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	753	11	.	.	.
cord-276598-tm0yj2sn	754	1	In	in	IN
cord-276598-tm0yj2sn	754	2	a	a	DT
cord-276598-tm0yj2sn	754	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	754	4	of	of	IN
cord-276598-tm0yj2sn	754	5	the	the	DT
cord-276598-tm0yj2sn	754	6	I2-mediated	I2-mediated	NNP
cord-276598-tm0yj2sn	754	7	P	P	NNP
cord-276598-tm0yj2sn	754	8	-	-	HYPH
cord-276598-tm0yj2sn	754	9	N	N	NNP
cord-276598-tm0yj2sn	754	10	formation	formation	NN
cord-276598-tm0yj2sn	754	11	,	,	,
cord-276598-tm0yj2sn	754	12	according	accord	VBG
cord-276598-tm0yj2sn	754	13	to	to	IN
cord-276598-tm0yj2sn	754	14	Singh	Singh	NNP
cord-276598-tm0yj2sn	754	15	et	et	NNP
cord-276598-tm0yj2sn	754	16	al	al	NNP
cord-276598-tm0yj2sn	754	17	.	.	NNP
cord-276598-tm0yj2sn	754	18	,	,	,
cord-276598-tm0yj2sn	754	19	H	H	NNP
cord-276598-tm0yj2sn	754	20	-	-	HYPH
cord-276598-tm0yj2sn	754	21	P	P	NNP
cord-276598-tm0yj2sn	754	22	reacts	react	VBZ
cord-276598-tm0yj2sn	754	23	with	with	IN
cord-276598-tm0yj2sn	754	24	I2	I2	NNP
cord-276598-tm0yj2sn	754	25	to	to	TO
cord-276598-tm0yj2sn	754	26	form	form	VB
cord-276598-tm0yj2sn	754	27	an	an	DT
cord-276598-tm0yj2sn	754	28	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	754	29	,	,	,
cord-276598-tm0yj2sn	754	30	which	which	WDT
cord-276598-tm0yj2sn	754	31	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	754	32	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	754	33	attack	attack	NN
cord-276598-tm0yj2sn	754	34	from	from	IN
cord-276598-tm0yj2sn	754	35	the	the	DT
cord-276598-tm0yj2sn	754	36	amine	amine	NN
cord-276598-tm0yj2sn	754	37	to	to	TO
cord-276598-tm0yj2sn	754	38	generate	generate	VB
cord-276598-tm0yj2sn	754	39	a	a	DT
cord-276598-tm0yj2sn	754	40	hydroxylated	hydroxylate	VBN
cord-276598-tm0yj2sn	754	41	-	-	HYPH
cord-276598-tm0yj2sn	754	42	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	754	43	phenylphosphoramidate	phenylphosphoramidate	NN
cord-276598-tm0yj2sn	754	44	complex	complex	NN
cord-276598-tm0yj2sn	754	45	with	with	IN
cord-276598-tm0yj2sn	754	46	an	an	DT
cord-276598-tm0yj2sn	754	47	elimination	elimination	NN
cord-276598-tm0yj2sn	754	48	of	of	IN
cord-276598-tm0yj2sn	754	49	I2	I2	NNP
cord-276598-tm0yj2sn	754	50	(	(	-LRB-
cord-276598-tm0yj2sn	754	51	Scheme	scheme	NN
cord-276598-tm0yj2sn	754	52	25	25	CD
cord-276598-tm0yj2sn	754	53	)	)	-RRB-
cord-276598-tm0yj2sn	754	54	[	[	-LRB-
cord-276598-tm0yj2sn	754	55	101	101	CD
cord-276598-tm0yj2sn	754	56	]	]	-RRB-
cord-276598-tm0yj2sn	754	57	.	.	.
cord-276598-tm0yj2sn	755	1	The	the	DT
cord-276598-tm0yj2sn	755	2	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	755	3	complex	complex	NN
cord-276598-tm0yj2sn	755	4	further	further	RB
cord-276598-tm0yj2sn	755	5	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	755	6	dehydrogenation	dehydrogenation	NN
cord-276598-tm0yj2sn	755	7	to	to	TO
cord-276598-tm0yj2sn	755	8	eliminate	eliminate	VB
cord-276598-tm0yj2sn	755	9	H2	H2	NNP
cord-276598-tm0yj2sn	755	10	in	in	IN
cord-276598-tm0yj2sn	755	11	form	form	NN
cord-276598-tm0yj2sn	755	12	of	of	IN
cord-276598-tm0yj2sn	755	13	H2O	h2o	NN
cord-276598-tm0yj2sn	755	14	and	and	CC
cord-276598-tm0yj2sn	755	15	afford	afford	VB
cord-276598-tm0yj2sn	755	16	the	the	DT
cord-276598-tm0yj2sn	755	17	desired	desire	VBN
cord-276598-tm0yj2sn	755	18	products	product	NNS
cord-276598-tm0yj2sn	755	19	.	.	.
cord-276598-tm0yj2sn	756	1	[	[	-LRB-
cord-276598-tm0yj2sn	756	2	102	102	CD
cord-276598-tm0yj2sn	756	3	]	]	-RRB-
cord-276598-tm0yj2sn	756	4	.	.	.
cord-276598-tm0yj2sn	757	1	Then	then	RB
cord-276598-tm0yj2sn	757	2	,	,	,
cord-276598-tm0yj2sn	757	3	the	the	DT
cord-276598-tm0yj2sn	757	4	iodide	iodide	NN
cord-276598-tm0yj2sn	757	5	ion	ion	NN
cord-276598-tm0yj2sn	757	6	is	be	VBZ
cord-276598-tm0yj2sn	757	7	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	757	8	to	to	IN
cord-276598-tm0yj2sn	757	9	active	active	JJ
cord-276598-tm0yj2sn	757	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	757	11	,	,	,
cord-276598-tm0yj2sn	757	12	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	757	13	acid	acid	NN
cord-276598-tm0yj2sn	757	14	,	,	,
cord-276598-tm0yj2sn	757	15	in	in	IN
cord-276598-tm0yj2sn	757	16	the	the	DT
cord-276598-tm0yj2sn	757	17	presence	presence	NN
cord-276598-tm0yj2sn	757	18	of	of	IN
cord-276598-tm0yj2sn	757	19	H2O2	H2O2	NNP
cord-276598-tm0yj2sn	757	20	.	.	.
cord-276598-tm0yj2sn	758	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	758	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	758	3	for	for	IN
cord-276598-tm0yj2sn	758	4	the	the	DT
cord-276598-tm0yj2sn	758	5	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	758	6	acid	acid	NN
cord-276598-tm0yj2sn	758	7	-	-	HYPH
cord-276598-tm0yj2sn	758	8	mediated	mediate	VBN
cord-276598-tm0yj2sn	758	9	synthesis	synthesis	NN
cord-276598-tm0yj2sn	758	10	of	of	IN
cord-276598-tm0yj2sn	758	11	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	758	12	.	.	.
cord-276598-tm0yj2sn	759	1	In	in	IN
cord-276598-tm0yj2sn	759	2	a	a	DT
cord-276598-tm0yj2sn	759	3	copper	copper	NN
cord-276598-tm0yj2sn	759	4	-	-	HYPH
cord-276598-tm0yj2sn	759	5	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	759	6	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	759	7	cross	cross	JJ
cord-276598-tm0yj2sn	759	8	-	-	JJ
cord-276598-tm0yj2sn	759	9	coupling	coupling	JJ
cord-276598-tm0yj2sn	759	10	reaction	reaction	NN
cord-276598-tm0yj2sn	759	11	,	,	,
cord-276598-tm0yj2sn	759	12	Hayes	Hayes	NNP
cord-276598-tm0yj2sn	759	13	et	et	NNP
cord-276598-tm0yj2sn	759	14	al	al	NNP
cord-276598-tm0yj2sn	759	15	.	.	NNP
cord-276598-tm0yj2sn	759	16	proposed	propose	VBD
cord-276598-tm0yj2sn	759	17	a	a	DT
cord-276598-tm0yj2sn	759	18	reaction	reaction	NN
cord-276598-tm0yj2sn	759	19	mechanism	mechanism	NN
cord-276598-tm0yj2sn	759	20	involving	involve	VBG
cord-276598-tm0yj2sn	759	21	single	single	JJ
cord-276598-tm0yj2sn	759	22	-	-	HYPH
cord-276598-tm0yj2sn	759	23	electron	electron	NN
cord-276598-tm0yj2sn	759	24	transfer	transfer	NN
cord-276598-tm0yj2sn	759	25	oxidation	oxidation	NN
cord-276598-tm0yj2sn	759	26	of	of	IN
cord-276598-tm0yj2sn	759	27	the	the	DT
cord-276598-tm0yj2sn	759	28	copper	copper	NN
cord-276598-tm0yj2sn	759	29	catalyst	catalyst	NN
cord-276598-tm0yj2sn	759	30	,	,	,
cord-276598-tm0yj2sn	759	31	which	which	WDT
cord-276598-tm0yj2sn	759	32	favored	favor	VBD
cord-276598-tm0yj2sn	759	33	the	the	DT
cord-276598-tm0yj2sn	759	34	formation	formation	NN
cord-276598-tm0yj2sn	759	35	of	of	IN
cord-276598-tm0yj2sn	759	36	the	the	DT
cord-276598-tm0yj2sn	759	37	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	759	38	complex	complex	NN
cord-276598-tm0yj2sn	759	39	(	(	-LRB-
cord-276598-tm0yj2sn	759	40	Scheme	scheme	NN
cord-276598-tm0yj2sn	759	41	27	27	CD
cord-276598-tm0yj2sn	759	42	)	)	-RRB-
cord-276598-tm0yj2sn	759	43	[	[	-LRB-
cord-276598-tm0yj2sn	759	44	103	103	CD
cord-276598-tm0yj2sn	759	45	]	]	-RRB-
cord-276598-tm0yj2sn	759	46	.	.	.
cord-276598-tm0yj2sn	760	1	The	the	DT
cord-276598-tm0yj2sn	760	2	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	760	3	complex	complex	NN
cord-276598-tm0yj2sn	760	4	is	be	VBZ
cord-276598-tm0yj2sn	760	5	further	further	JJ
cord-276598-tm0yj2sn	760	6	Scheme	scheme	NN
cord-276598-tm0yj2sn	760	7	25	25	CD
cord-276598-tm0yj2sn	760	8	.	.	.
cord-276598-tm0yj2sn	761	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	761	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	761	3	for	for	IN
cord-276598-tm0yj2sn	761	4	the	the	DT
cord-276598-tm0yj2sn	761	5	iodine	iodine	NN
cord-276598-tm0yj2sn	761	6	-	-	HYPH
cord-276598-tm0yj2sn	761	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	761	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	761	9	of	of	IN
cord-276598-tm0yj2sn	761	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	761	11	.	.	.
cord-276598-tm0yj2sn	762	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	762	2	24	24	CD
cord-276598-tm0yj2sn	762	3	.	.	.
cord-276598-tm0yj2sn	763	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	763	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	763	3	for	for	IN
cord-276598-tm0yj2sn	763	4	the	the	DT
cord-276598-tm0yj2sn	763	5	iodine	iodine	NN
cord-276598-tm0yj2sn	763	6	-	-	HYPH
cord-276598-tm0yj2sn	763	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	763	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	763	9	of	of	IN
cord-276598-tm0yj2sn	763	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	763	11	.	.	.
cord-276598-tm0yj2sn	764	1	In	in	IN
cord-276598-tm0yj2sn	764	2	a	a	DT
cord-276598-tm0yj2sn	764	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	764	4	of	of	IN
cord-276598-tm0yj2sn	764	5	the	the	DT
cord-276598-tm0yj2sn	764	6	I2-mediated	I2-mediated	NNP
cord-276598-tm0yj2sn	764	7	P	P	NNP
cord-276598-tm0yj2sn	764	8	-	-	HYPH
cord-276598-tm0yj2sn	764	9	N	N	NNP
cord-276598-tm0yj2sn	764	10	formation	formation	NN
cord-276598-tm0yj2sn	764	11	,	,	,
cord-276598-tm0yj2sn	764	12	according	accord	VBG
cord-276598-tm0yj2sn	764	13	to	to	IN
cord-276598-tm0yj2sn	764	14	Singh	Singh	NNP
cord-276598-tm0yj2sn	764	15	et	et	NNP
cord-276598-tm0yj2sn	764	16	al	al	NNP
cord-276598-tm0yj2sn	764	17	.	.	NNP
cord-276598-tm0yj2sn	764	18	,	,	,
cord-276598-tm0yj2sn	764	19	H	H	NNP
cord-276598-tm0yj2sn	764	20	-	-	HYPH
cord-276598-tm0yj2sn	764	21	P	P	NNP
cord-276598-tm0yj2sn	764	22	reacts	react	VBZ
cord-276598-tm0yj2sn	764	23	with	with	IN
cord-276598-tm0yj2sn	764	24	I2	I2	NNP
cord-276598-tm0yj2sn	764	25	to	to	TO
cord-276598-tm0yj2sn	764	26	form	form	VB
cord-276598-tm0yj2sn	764	27	an	an	DT
cord-276598-tm0yj2sn	764	28	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	764	29	,	,	,
cord-276598-tm0yj2sn	764	30	which	which	WDT
cord-276598-tm0yj2sn	764	31	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	764	32	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	764	33	attack	attack	NN
cord-276598-tm0yj2sn	764	34	from	from	IN
cord-276598-tm0yj2sn	764	35	the	the	DT
cord-276598-tm0yj2sn	764	36	amine	amine	NN
cord-276598-tm0yj2sn	764	37	to	to	TO
cord-276598-tm0yj2sn	764	38	generate	generate	VB
cord-276598-tm0yj2sn	764	39	a	a	DT
cord-276598-tm0yj2sn	764	40	hydroxylated	hydroxylate	VBN
cord-276598-tm0yj2sn	764	41	-	-	HYPH
cord-276598-tm0yj2sn	764	42	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	764	43	phenylphosphoramidate	phenylphosphoramidate	NN
cord-276598-tm0yj2sn	764	44	complex	complex	NN
cord-276598-tm0yj2sn	764	45	with	with	IN
cord-276598-tm0yj2sn	764	46	an	an	DT
cord-276598-tm0yj2sn	764	47	elimination	elimination	NN
cord-276598-tm0yj2sn	764	48	of	of	IN
cord-276598-tm0yj2sn	764	49	I2	I2	NNP
cord-276598-tm0yj2sn	764	50	(	(	-LRB-
cord-276598-tm0yj2sn	764	51	Scheme	scheme	NN
cord-276598-tm0yj2sn	764	52	25	25	CD
cord-276598-tm0yj2sn	764	53	)	)	-RRB-
cord-276598-tm0yj2sn	764	54	[	[	-LRB-
cord-276598-tm0yj2sn	764	55	101	101	CD
cord-276598-tm0yj2sn	764	56	]	]	-RRB-
cord-276598-tm0yj2sn	764	57	.	.	.
cord-276598-tm0yj2sn	765	1	The	the	DT
cord-276598-tm0yj2sn	765	2	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	765	3	complex	complex	NN
cord-276598-tm0yj2sn	765	4	further	further	RB
cord-276598-tm0yj2sn	765	5	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	765	6	dehydrogenation	dehydrogenation	NN
cord-276598-tm0yj2sn	765	7	to	to	TO
cord-276598-tm0yj2sn	765	8	eliminate	eliminate	VB
cord-276598-tm0yj2sn	765	9	H2	H2	NNP
cord-276598-tm0yj2sn	765	10	in	in	IN
cord-276598-tm0yj2sn	765	11	form	form	NN
cord-276598-tm0yj2sn	765	12	of	of	IN
cord-276598-tm0yj2sn	765	13	H2O	h2o	NN
cord-276598-tm0yj2sn	765	14	and	and	CC
cord-276598-tm0yj2sn	765	15	afford	afford	VB
cord-276598-tm0yj2sn	765	16	the	the	DT
cord-276598-tm0yj2sn	765	17	desired	desire	VBN
cord-276598-tm0yj2sn	765	18	products	product	NNS
cord-276598-tm0yj2sn	765	19	.	.	.
cord-276598-tm0yj2sn	766	1	[	[	-LRB-
cord-276598-tm0yj2sn	766	2	102	102	CD
cord-276598-tm0yj2sn	766	3	]	]	-RRB-
cord-276598-tm0yj2sn	766	4	.	.	.
cord-276598-tm0yj2sn	767	1	Then	then	RB
cord-276598-tm0yj2sn	767	2	,	,	,
cord-276598-tm0yj2sn	767	3	the	the	DT
cord-276598-tm0yj2sn	767	4	iodide	iodide	NN
cord-276598-tm0yj2sn	767	5	ion	ion	NN
cord-276598-tm0yj2sn	767	6	is	be	VBZ
cord-276598-tm0yj2sn	767	7	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	767	8	to	to	IN
cord-276598-tm0yj2sn	767	9	active	active	JJ
cord-276598-tm0yj2sn	767	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	767	11	,	,	,
cord-276598-tm0yj2sn	767	12	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	767	13	acid	acid	NN
cord-276598-tm0yj2sn	767	14	,	,	,
cord-276598-tm0yj2sn	767	15	in	in	IN
cord-276598-tm0yj2sn	767	16	the	the	DT
cord-276598-tm0yj2sn	767	17	presence	presence	NN
cord-276598-tm0yj2sn	767	18	of	of	IN
cord-276598-tm0yj2sn	767	19	H2O2	H2O2	NNP
cord-276598-tm0yj2sn	767	20	.	.	.
cord-276598-tm0yj2sn	768	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	768	2	26	26	CD
cord-276598-tm0yj2sn	768	3	.	.	.
cord-276598-tm0yj2sn	769	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	769	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	769	3	for	for	IN
cord-276598-tm0yj2sn	769	4	the	the	DT
cord-276598-tm0yj2sn	769	5	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	769	6	acid	acid	NN
cord-276598-tm0yj2sn	769	7	-	-	HYPH
cord-276598-tm0yj2sn	769	8	mediated	mediate	VBN
cord-276598-tm0yj2sn	769	9	synthesis	synthesis	NN
cord-276598-tm0yj2sn	769	10	of	of	IN
cord-276598-tm0yj2sn	769	11	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	769	12	.	.	.
cord-276598-tm0yj2sn	770	1	In	in	IN
cord-276598-tm0yj2sn	770	2	a	a	DT
cord-276598-tm0yj2sn	770	3	copper	copper	NN
cord-276598-tm0yj2sn	770	4	-	-	HYPH
cord-276598-tm0yj2sn	770	5	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	770	6	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	770	7	cross	cross	JJ
cord-276598-tm0yj2sn	770	8	-	-	JJ
cord-276598-tm0yj2sn	770	9	coupling	coupling	JJ
cord-276598-tm0yj2sn	770	10	reaction	reaction	NN
cord-276598-tm0yj2sn	770	11	,	,	,
cord-276598-tm0yj2sn	770	12	Hayes	Hayes	NNP
cord-276598-tm0yj2sn	770	13	et	et	NNP
cord-276598-tm0yj2sn	770	14	al	al	NNP
cord-276598-tm0yj2sn	770	15	.	.	NNP
cord-276598-tm0yj2sn	770	16	proposed	propose	VBD
cord-276598-tm0yj2sn	770	17	a	a	DT
cord-276598-tm0yj2sn	770	18	reaction	reaction	NN
cord-276598-tm0yj2sn	770	19	mechanism	mechanism	NN
cord-276598-tm0yj2sn	770	20	involving	involve	VBG
cord-276598-tm0yj2sn	770	21	single	single	JJ
cord-276598-tm0yj2sn	770	22	-	-	HYPH
cord-276598-tm0yj2sn	770	23	electron	electron	NN
cord-276598-tm0yj2sn	770	24	transfer	transfer	NN
cord-276598-tm0yj2sn	770	25	oxidation	oxidation	NN
cord-276598-tm0yj2sn	770	26	of	of	IN
cord-276598-tm0yj2sn	770	27	the	the	DT
cord-276598-tm0yj2sn	770	28	copper	copper	NN
cord-276598-tm0yj2sn	770	29	catalyst	catalyst	NN
cord-276598-tm0yj2sn	770	30	,	,	,
cord-276598-tm0yj2sn	770	31	which	which	WDT
cord-276598-tm0yj2sn	770	32	favored	favor	VBD
cord-276598-tm0yj2sn	770	33	the	the	DT
cord-276598-tm0yj2sn	770	34	formation	formation	NN
cord-276598-tm0yj2sn	770	35	of	of	IN
cord-276598-tm0yj2sn	770	36	the	the	DT
cord-276598-tm0yj2sn	770	37	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	770	38	complex	complex	NN
cord-276598-tm0yj2sn	770	39	(	(	-LRB-
cord-276598-tm0yj2sn	770	40	Scheme	scheme	NN
cord-276598-tm0yj2sn	770	41	27	27	CD
cord-276598-tm0yj2sn	770	42	)	)	-RRB-
cord-276598-tm0yj2sn	770	43	[	[	-LRB-
cord-276598-tm0yj2sn	770	44	103	103	CD
cord-276598-tm0yj2sn	770	45	]	]	-RRB-
cord-276598-tm0yj2sn	770	46	.	.	.
cord-276598-tm0yj2sn	771	1	The	the	DT
cord-276598-tm0yj2sn	771	2	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	771	3	complex	complex	NN
cord-276598-tm0yj2sn	771	4	is	be	VBZ
cord-276598-tm0yj2sn	771	5	further	further	JJ
cord-276598-tm0yj2sn	771	6	Scheme	scheme	NN
cord-276598-tm0yj2sn	771	7	26	26	CD
cord-276598-tm0yj2sn	771	8	.	.	.
cord-276598-tm0yj2sn	772	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	772	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	772	3	for	for	IN
cord-276598-tm0yj2sn	772	4	the	the	DT
cord-276598-tm0yj2sn	772	5	hypoiodous	hypoiodous	JJ
cord-276598-tm0yj2sn	772	6	acid	acid	NN
cord-276598-tm0yj2sn	772	7	-	-	HYPH
cord-276598-tm0yj2sn	772	8	mediated	mediate	VBN
cord-276598-tm0yj2sn	772	9	synthesis	synthesis	NN
cord-276598-tm0yj2sn	772	10	of	of	IN
cord-276598-tm0yj2sn	772	11	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	772	12	.	.	.
cord-276598-tm0yj2sn	773	1	In	in	IN
cord-276598-tm0yj2sn	773	2	a	a	DT
cord-276598-tm0yj2sn	773	3	copper	copper	NN
cord-276598-tm0yj2sn	773	4	-	-	HYPH
cord-276598-tm0yj2sn	773	5	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	773	6	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	773	7	cross	cross	JJ
cord-276598-tm0yj2sn	773	8	-	-	JJ
cord-276598-tm0yj2sn	773	9	coupling	coupling	JJ
cord-276598-tm0yj2sn	773	10	reaction	reaction	NN
cord-276598-tm0yj2sn	773	11	,	,	,
cord-276598-tm0yj2sn	773	12	Hayes	Hayes	NNP
cord-276598-tm0yj2sn	773	13	et	et	NNP
cord-276598-tm0yj2sn	773	14	al	al	NNP
cord-276598-tm0yj2sn	773	15	.	.	NNP
cord-276598-tm0yj2sn	773	16	proposed	propose	VBD
cord-276598-tm0yj2sn	773	17	a	a	DT
cord-276598-tm0yj2sn	773	18	reaction	reaction	NN
cord-276598-tm0yj2sn	773	19	mechanism	mechanism	NN
cord-276598-tm0yj2sn	773	20	involving	involve	VBG
cord-276598-tm0yj2sn	773	21	single	single	JJ
cord-276598-tm0yj2sn	773	22	-	-	HYPH
cord-276598-tm0yj2sn	773	23	electron	electron	NN
cord-276598-tm0yj2sn	773	24	transfer	transfer	NN
cord-276598-tm0yj2sn	773	25	oxidation	oxidation	NN
cord-276598-tm0yj2sn	773	26	of	of	IN
cord-276598-tm0yj2sn	773	27	the	the	DT
cord-276598-tm0yj2sn	773	28	copper	copper	NN
cord-276598-tm0yj2sn	773	29	catalyst	catalyst	NN
cord-276598-tm0yj2sn	773	30	,	,	,
cord-276598-tm0yj2sn	773	31	which	which	WDT
cord-276598-tm0yj2sn	773	32	favored	favor	VBD
cord-276598-tm0yj2sn	773	33	the	the	DT
cord-276598-tm0yj2sn	773	34	formation	formation	NN
cord-276598-tm0yj2sn	773	35	of	of	IN
cord-276598-tm0yj2sn	773	36	the	the	DT
cord-276598-tm0yj2sn	773	37	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	773	38	complex	complex	NN
cord-276598-tm0yj2sn	773	39	(	(	-LRB-
cord-276598-tm0yj2sn	773	40	Scheme	scheme	NN
cord-276598-tm0yj2sn	773	41	27	27	CD
cord-276598-tm0yj2sn	773	42	)	)	-RRB-
cord-276598-tm0yj2sn	773	43	[	[	-LRB-
cord-276598-tm0yj2sn	773	44	103	103	CD
cord-276598-tm0yj2sn	773	45	]	]	-RRB-
cord-276598-tm0yj2sn	773	46	.	.	.
cord-276598-tm0yj2sn	774	1	The	the	DT
cord-276598-tm0yj2sn	774	2	Cu(II)-amine	Cu(II)-amine	NNP
cord-276598-tm0yj2sn	774	3	complex	complex	NN
cord-276598-tm0yj2sn	774	4	is	be	VBZ
cord-276598-tm0yj2sn	774	5	further	further	RB
cord-276598-tm0yj2sn	774	6	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	774	7	to	to	TO
cord-276598-tm0yj2sn	774	8	form	form	VB
cord-276598-tm0yj2sn	774	9	the	the	DT
cord-276598-tm0yj2sn	774	10	Cu(III)-amine	Cu(III)-amine	NNP
cord-276598-tm0yj2sn	774	11	-	-	HYPH
cord-276598-tm0yj2sn	774	12	phosphonate	phosphonate	JJ
cord-276598-tm0yj2sn	774	13	complex	complex	NN
cord-276598-tm0yj2sn	774	14	,	,	,
cord-276598-tm0yj2sn	774	15	which	which	WDT
cord-276598-tm0yj2sn	774	16	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	774	17	reductive	reductive	JJ
cord-276598-tm0yj2sn	774	18	elimination	elimination	NN
cord-276598-tm0yj2sn	774	19	of	of	IN
cord-276598-tm0yj2sn	774	20	the	the	DT
cord-276598-tm0yj2sn	774	21	copper	copper	NN
cord-276598-tm0yj2sn	774	22	catalyst	catalyst	NN
cord-276598-tm0yj2sn	774	23	to	to	TO
cord-276598-tm0yj2sn	774	24	yield	yield	VB
cord-276598-tm0yj2sn	774	25	the	the	DT
cord-276598-tm0yj2sn	774	26	desired	desire	VBN
cord-276598-tm0yj2sn	774	27	P	p	NN
cord-276598-tm0yj2sn	774	28	-	-	HYPH
cord-276598-tm0yj2sn	774	29	N.	n.	NN
cord-276598-tm0yj2sn	775	1	Although	although	IN
cord-276598-tm0yj2sn	775	2	this	this	DT
cord-276598-tm0yj2sn	775	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	775	4	seems	seem	VBZ
cord-276598-tm0yj2sn	775	5	plausible	plausible	JJ
cord-276598-tm0yj2sn	775	6	,	,	,
cord-276598-tm0yj2sn	775	7	it	-PRON-	PRP
cord-276598-tm0yj2sn	775	8	could	could	MD
cord-276598-tm0yj2sn	775	9	not	not	RB
cord-276598-tm0yj2sn	775	10	easily	easily	RB
cord-276598-tm0yj2sn	775	11	explain	explain	VB
cord-276598-tm0yj2sn	775	12	the	the	DT
cord-276598-tm0yj2sn	775	13	formation	formation	NN
cord-276598-tm0yj2sn	775	14	of	of	IN
cord-276598-tm0yj2sn	775	15	the	the	DT
cord-276598-tm0yj2sn	775	16	side	side	NN
cord-276598-tm0yj2sn	775	17	products	product	NNS
cord-276598-tm0yj2sn	775	18	.	.	.
cord-276598-tm0yj2sn	776	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	776	2	2020	2020	CD
cord-276598-tm0yj2sn	776	3	,	,	,
cord-276598-tm0yj2sn	776	4	25	25	CD
cord-276598-tm0yj2sn	776	5	,	,	,
cord-276598-tm0yj2sn	776	6	x	x	NN
cord-276598-tm0yj2sn	776	7	FOR	for	IN
cord-276598-tm0yj2sn	776	8	PEER	peer	NN
cord-276598-tm0yj2sn	776	9	REVIEW	REVIEW	NNP
cord-276598-tm0yj2sn	776	10	23	23	CD
cord-276598-tm0yj2sn	776	11	of	of	IN
cord-276598-tm0yj2sn	776	12	37	37	CD
cord-276598-tm0yj2sn	776	13	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	776	14	to	to	TO
cord-276598-tm0yj2sn	776	15	form	form	VB
cord-276598-tm0yj2sn	776	16	the	the	DT
cord-276598-tm0yj2sn	776	17	Cu(III)-amine	Cu(III)-amine	NNP
cord-276598-tm0yj2sn	776	18	-	-	HYPH
cord-276598-tm0yj2sn	776	19	phosphonate	phosphonate	JJ
cord-276598-tm0yj2sn	776	20	complex	complex	NN
cord-276598-tm0yj2sn	776	21	,	,	,
cord-276598-tm0yj2sn	776	22	which	which	WDT
cord-276598-tm0yj2sn	776	23	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	776	24	reductive	reductive	JJ
cord-276598-tm0yj2sn	776	25	elimination	elimination	NN
cord-276598-tm0yj2sn	776	26	of	of	IN
cord-276598-tm0yj2sn	776	27	the	the	DT
cord-276598-tm0yj2sn	776	28	copper	copper	NN
cord-276598-tm0yj2sn	776	29	catalyst	catalyst	NN
cord-276598-tm0yj2sn	776	30	to	to	TO
cord-276598-tm0yj2sn	776	31	yield	yield	VB
cord-276598-tm0yj2sn	776	32	the	the	DT
cord-276598-tm0yj2sn	776	33	desired	desire	VBN
cord-276598-tm0yj2sn	776	34	P	p	NN
cord-276598-tm0yj2sn	776	35	-	-	HYPH
cord-276598-tm0yj2sn	776	36	N.	n.	NN
cord-276598-tm0yj2sn	777	1	Although	although	IN
cord-276598-tm0yj2sn	777	2	this	this	DT
cord-276598-tm0yj2sn	777	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	777	4	seems	seem	VBZ
cord-276598-tm0yj2sn	777	5	plausible	plausible	JJ
cord-276598-tm0yj2sn	777	6	,	,	,
cord-276598-tm0yj2sn	777	7	it	-PRON-	PRP
cord-276598-tm0yj2sn	777	8	could	could	MD
cord-276598-tm0yj2sn	777	9	not	not	RB
cord-276598-tm0yj2sn	777	10	easily	easily	RB
cord-276598-tm0yj2sn	777	11	explain	explain	VB
cord-276598-tm0yj2sn	777	12	the	the	DT
cord-276598-tm0yj2sn	777	13	formation	formation	NN
cord-276598-tm0yj2sn	777	14	of	of	IN
cord-276598-tm0yj2sn	777	15	the	the	DT
cord-276598-tm0yj2sn	777	16	side	side	NN
cord-276598-tm0yj2sn	777	17	products	product	NNS
cord-276598-tm0yj2sn	777	18	.	.	.
cord-276598-tm0yj2sn	778	1	According	accord	VBG
cord-276598-tm0yj2sn	778	2	the	the	DT
cord-276598-tm0yj2sn	778	3	plausible	plausible	JJ
cord-276598-tm0yj2sn	778	4	two	two	CD
cord-276598-tm0yj2sn	778	5	-	-	HYPH
cord-276598-tm0yj2sn	778	6	step	step	NN
cord-276598-tm0yj2sn	778	7	mechanism	mechanism	NN
cord-276598-tm0yj2sn	778	8	for	for	IN
cord-276598-tm0yj2sn	778	9	the	the	DT
cord-276598-tm0yj2sn	778	10	reaction	reaction	NN
cord-276598-tm0yj2sn	778	11	by	by	IN
cord-276598-tm0yj2sn	778	12	Purohit	Purohit	NNP
cord-276598-tm0yj2sn	778	13	et	et	NNP
cord-276598-tm0yj2sn	778	14	al	al	NNP
cord-276598-tm0yj2sn	778	15	.	.	NNP
cord-276598-tm0yj2sn	778	16	,	,	,
cord-276598-tm0yj2sn	778	17	(	(	-LRB-
cord-276598-tm0yj2sn	778	18	RO	RO	NNP
cord-276598-tm0yj2sn	778	19	)	)	-RRB-
cord-276598-tm0yj2sn	778	20	2	2	CD
cord-276598-tm0yj2sn	778	21	P(O)Cl	p(o)cl	NN
cord-276598-tm0yj2sn	778	22	(	(	-LRB-
cord-276598-tm0yj2sn	778	23	dACP	dACP	.
cord-276598-tm0yj2sn	779	1	;	;	:
cord-276598-tm0yj2sn	779	2	R	r	NN
cord-276598-tm0yj2sn	779	3	=	=	NN
cord-276598-tm0yj2sn	779	4	alkyl	alkyl	NN
cord-276598-tm0yj2sn	779	5	)	)	-RRB-
cord-276598-tm0yj2sn	779	6	is	be	VBZ
cord-276598-tm0yj2sn	779	7	first	first	RB
cord-276598-tm0yj2sn	779	8	generated	generate	VBN
cord-276598-tm0yj2sn	779	9	from	from	IN
cord-276598-tm0yj2sn	779	10	the	the	DT
cord-276598-tm0yj2sn	779	11	electrophilic	electrophilic	JJ
cord-276598-tm0yj2sn	779	12	displacement	displacement	NN
cord-276598-tm0yj2sn	779	13	of	of	IN
cord-276598-tm0yj2sn	779	14	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	779	15	on	on	IN
cord-276598-tm0yj2sn	779	16	the	the	DT
cord-276598-tm0yj2sn	779	17	dialkyl	dialkyl	NN
cord-276598-tm0yj2sn	779	18	H	H	NNP
cord-276598-tm0yj2sn	779	19	-	-	HYPH
cord-276598-tm0yj2sn	779	20	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	779	21	(	(	-LRB-
cord-276598-tm0yj2sn	779	22	(	(	-LRB-
cord-276598-tm0yj2sn	779	23	OR	or	NN
cord-276598-tm0yj2sn	779	24	)	)	-RRB-
cord-276598-tm0yj2sn	780	1	2	2	LS
cord-276598-tm0yj2sn	781	1	P(O)H	p(o)h	NN
cord-276598-tm0yj2sn	781	2	,	,	,
cord-276598-tm0yj2sn	781	3	R	r	NN
cord-276598-tm0yj2sn	781	4	=	=	NN
cord-276598-tm0yj2sn	781	5	alkyl	alkyl	NN
cord-276598-tm0yj2sn	781	6	)	)	-RRB-
cord-276598-tm0yj2sn	781	7	upon	upon	IN
cord-276598-tm0yj2sn	781	8	reacting	react	VBG
cord-276598-tm0yj2sn	781	9	with	with	IN
cord-276598-tm0yj2sn	781	10	CuCl	CuCl	NNP
cord-276598-tm0yj2sn	781	11	2	2	CD
cord-276598-tm0yj2sn	781	12	(	(	-LRB-
cord-276598-tm0yj2sn	781	13	Scheme	scheme	NN
cord-276598-tm0yj2sn	781	14	29a	29a	NNS
cord-276598-tm0yj2sn	781	15	)	)	-RRB-
cord-276598-tm0yj2sn	782	1	[	[	-LRB-
cord-276598-tm0yj2sn	782	2	106	106	CD
cord-276598-tm0yj2sn	782	3	]	]	-RRB-
cord-276598-tm0yj2sn	782	4	.	.	.
cord-276598-tm0yj2sn	783	1	The	the	DT
cord-276598-tm0yj2sn	783	2	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	783	3	is	be	VBZ
cord-276598-tm0yj2sn	783	4	formed	form	VBN
cord-276598-tm0yj2sn	783	5	in	in	IN
cord-276598-tm0yj2sn	783	6	the	the	DT
cord-276598-tm0yj2sn	783	7	second	second	JJ
cord-276598-tm0yj2sn	783	8	step	step	NN
cord-276598-tm0yj2sn	783	9	by	by	IN
cord-276598-tm0yj2sn	783	10	coupling	couple	VBG
cord-276598-tm0yj2sn	783	11	dACP	dacp	NN
cord-276598-tm0yj2sn	783	12	and	and	CC
cord-276598-tm0yj2sn	783	13	amine	amine	NN
cord-276598-tm0yj2sn	783	14	.	.	.
cord-276598-tm0yj2sn	784	1	However	however	RB
cord-276598-tm0yj2sn	784	2	,	,	,
cord-276598-tm0yj2sn	784	3	this	this	DT
cord-276598-tm0yj2sn	784	4	reported	report	VBN
cord-276598-tm0yj2sn	784	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	784	6	could	could	MD
cord-276598-tm0yj2sn	784	7	not	not	RB
cord-276598-tm0yj2sn	784	8	properly	properly	RB
cord-276598-tm0yj2sn	784	9	explain	explain	VB
cord-276598-tm0yj2sn	784	10	the	the	DT
cord-276598-tm0yj2sn	784	11	role	role	NN
cord-276598-tm0yj2sn	784	12	of	of	IN
cord-276598-tm0yj2sn	784	13	Cs	Cs	NNP
cord-276598-tm0yj2sn	784	14	2	2	CD
cord-276598-tm0yj2sn	784	15	CO	CO	NNP
cord-276598-tm0yj2sn	784	16	3	3	CD
cord-276598-tm0yj2sn	784	17	in	in	IN
cord-276598-tm0yj2sn	784	18	the	the	DT
cord-276598-tm0yj2sn	784	19	coupling	coupling	NN
cord-276598-tm0yj2sn	784	20	of	of	IN
cord-276598-tm0yj2sn	784	21	alkyl	alkyl	NNP
cord-276598-tm0yj2sn	784	22	chlorophosphate	chlorophosphate	NN
cord-276598-tm0yj2sn	784	23	and	and	CC
cord-276598-tm0yj2sn	784	24	the	the	DT
cord-276598-tm0yj2sn	784	25	amine	amine	NN
cord-276598-tm0yj2sn	784	26	to	to	TO
cord-276598-tm0yj2sn	784	27	give	give	VB
cord-276598-tm0yj2sn	784	28	the	the	DT
cord-276598-tm0yj2sn	784	29	P	p	NN
cord-276598-tm0yj2sn	784	30	-	-	HYPH
cord-276598-tm0yj2sn	784	31	N.	n.	NN
cord-276598-tm0yj2sn	785	1	This	this	DT
cord-276598-tm0yj2sn	785	2	is	be	VBZ
cord-276598-tm0yj2sn	785	3	because	because	IN
cord-276598-tm0yj2sn	785	4	the	the	DT
cord-276598-tm0yj2sn	785	5	coupling	coupling	NN
cord-276598-tm0yj2sn	785	6	reaction	reaction	NN
cord-276598-tm0yj2sn	785	7	was	be	VBD
cord-276598-tm0yj2sn	785	8	expected	expect	VBN
cord-276598-tm0yj2sn	785	9	to	to	TO
cord-276598-tm0yj2sn	785	10	eliminate	eliminate	VB
cord-276598-tm0yj2sn	785	11	other	other	JJ
cord-276598-tm0yj2sn	785	12	products	product	NNS
cord-276598-tm0yj2sn	785	13	along	along	IN
cord-276598-tm0yj2sn	785	14	with	with	IN
cord-276598-tm0yj2sn	785	15	CsCl	CsCl	NNP
cord-276598-tm0yj2sn	785	16	such	such	JJ
cord-276598-tm0yj2sn	785	17	as	as	IN
cord-276598-tm0yj2sn	785	18	a	a	DT
cord-276598-tm0yj2sn	785	19	highly	highly	RB
cord-276598-tm0yj2sn	785	20	reactive	reactive	JJ
cord-276598-tm0yj2sn	785	21	CsH	csh	NN
cord-276598-tm0yj2sn	785	22	and	and	CC
cord-276598-tm0yj2sn	785	23	a	a	DT
cord-276598-tm0yj2sn	785	24	carbonate	carbonate	NN
cord-276598-tm0yj2sn	785	25	.	.	.
cord-276598-tm0yj2sn	786	1	However	however	RB
cord-276598-tm0yj2sn	786	2	,	,	,
cord-276598-tm0yj2sn	786	3	it	-PRON-	PRP
cord-276598-tm0yj2sn	786	4	is	be	VBZ
cord-276598-tm0yj2sn	786	5	to	to	TO
cord-276598-tm0yj2sn	786	6	be	be	VB
cord-276598-tm0yj2sn	786	7	understood	understand	VBN
cord-276598-tm0yj2sn	786	8	that	that	IN
cord-276598-tm0yj2sn	786	9	the	the	DT
cord-276598-tm0yj2sn	786	10	use	use	NN
cord-276598-tm0yj2sn	786	11	of	of	IN
cord-276598-tm0yj2sn	786	12	Cs	Cs	NNP
cord-276598-tm0yj2sn	786	13	2	2	CD
cord-276598-tm0yj2sn	786	14	CO	CO	NNP
cord-276598-tm0yj2sn	786	15	3	3	CD
cord-276598-tm0yj2sn	786	16	as	as	IN
cord-276598-tm0yj2sn	786	17	the	the	DT
cord-276598-tm0yj2sn	786	18	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	786	19	base	base	NN
cord-276598-tm0yj2sn	786	20	was	be	VBD
cord-276598-tm0yj2sn	786	21	based	base	VBN
cord-276598-tm0yj2sn	786	22	on	on	IN
cord-276598-tm0yj2sn	786	23	the	the	DT
cord-276598-tm0yj2sn	786	24	poorly	poorly	RB
cord-276598-tm0yj2sn	786	25	understood	understand	VBN
cord-276598-tm0yj2sn	786	26	"	"	``
cord-276598-tm0yj2sn	786	27	caesium	caesium	NN
cord-276598-tm0yj2sn	786	28	effect	effect	NN
cord-276598-tm0yj2sn	786	29	"	"	''
cord-276598-tm0yj2sn	786	30	in	in	IN
cord-276598-tm0yj2sn	786	31	which	which	WDT
cord-276598-tm0yj2sn	786	32	the	the	DT
cord-276598-tm0yj2sn	786	33	highly	highly	RB
cord-276598-tm0yj2sn	786	34	soluble	soluble	JJ
cord-276598-tm0yj2sn	786	35	caesium	caesium	NN
cord-276598-tm0yj2sn	786	36	base	base	NN
cord-276598-tm0yj2sn	786	37	selectively	selectively	RB
cord-276598-tm0yj2sn	786	38	favors	favor	VBZ
cord-276598-tm0yj2sn	786	39	the	the	DT
cord-276598-tm0yj2sn	786	40	formation	formation	NN
cord-276598-tm0yj2sn	786	41	of	of	IN
cord-276598-tm0yj2sn	786	42	one	one	CD
cord-276598-tm0yj2sn	786	43	functional	functional	JJ
cord-276598-tm0yj2sn	786	44	group	group	NN
cord-276598-tm0yj2sn	786	45	in	in	IN
cord-276598-tm0yj2sn	786	46	preference	preference	NN
cord-276598-tm0yj2sn	786	47	to	to	IN
cord-276598-tm0yj2sn	786	48	another	another	DT
cord-276598-tm0yj2sn	786	49	[	[	-LRB-
cord-276598-tm0yj2sn	786	50	122	122	CD
cord-276598-tm0yj2sn	786	51	,	,	,
cord-276598-tm0yj2sn	786	52	123	123	CD
cord-276598-tm0yj2sn	786	53	]	]	-RRB-
cord-276598-tm0yj2sn	786	54	.	.	.
cord-276598-tm0yj2sn	787	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	787	2	2020	2020	CD
cord-276598-tm0yj2sn	787	3	,	,	,
cord-276598-tm0yj2sn	787	4	25	25	CD
cord-276598-tm0yj2sn	787	5	,	,	,
cord-276598-tm0yj2sn	787	6	x	x	NN
cord-276598-tm0yj2sn	787	7	FOR	for	IN
cord-276598-tm0yj2sn	787	8	PEER	PEER	NNP
cord-276598-tm0yj2sn	787	9	REVIEW	REVIEW	NNP
cord-276598-tm0yj2sn	787	10	24	24	CD
cord-276598-tm0yj2sn	787	11	of	of	IN
cord-276598-tm0yj2sn	787	12	37	37	CD
cord-276598-tm0yj2sn	787	13	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	787	14	is	be	VBZ
cord-276598-tm0yj2sn	787	15	formed	form	VBN
cord-276598-tm0yj2sn	787	16	in	in	IN
cord-276598-tm0yj2sn	787	17	the	the	DT
cord-276598-tm0yj2sn	787	18	second	second	JJ
cord-276598-tm0yj2sn	787	19	step	step	NN
cord-276598-tm0yj2sn	787	20	by	by	IN
cord-276598-tm0yj2sn	787	21	coupling	couple	VBG
cord-276598-tm0yj2sn	787	22	dACP	dacp	NN
cord-276598-tm0yj2sn	787	23	and	and	CC
cord-276598-tm0yj2sn	787	24	amine	amine	NN
cord-276598-tm0yj2sn	787	25	.	.	.
cord-276598-tm0yj2sn	788	1	However	however	RB
cord-276598-tm0yj2sn	788	2	,	,	,
cord-276598-tm0yj2sn	788	3	this	this	DT
cord-276598-tm0yj2sn	788	4	reported	report	VBN
cord-276598-tm0yj2sn	788	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	788	6	could	could	MD
cord-276598-tm0yj2sn	788	7	not	not	RB
cord-276598-tm0yj2sn	788	8	properly	properly	RB
cord-276598-tm0yj2sn	788	9	explain	explain	VB
cord-276598-tm0yj2sn	788	10	the	the	DT
cord-276598-tm0yj2sn	788	11	role	role	NN
cord-276598-tm0yj2sn	788	12	of	of	IN
cord-276598-tm0yj2sn	788	13	Cs2CO3	Cs2CO3	NNP
cord-276598-tm0yj2sn	788	14	in	in	IN
cord-276598-tm0yj2sn	788	15	the	the	DT
cord-276598-tm0yj2sn	788	16	coupling	coupling	NN
cord-276598-tm0yj2sn	788	17	of	of	IN
cord-276598-tm0yj2sn	788	18	alkyl	alkyl	NNP
cord-276598-tm0yj2sn	788	19	chlorophosphate	chlorophosphate	NN
cord-276598-tm0yj2sn	788	20	and	and	CC
cord-276598-tm0yj2sn	788	21	the	the	DT
cord-276598-tm0yj2sn	788	22	amine	amine	NN
cord-276598-tm0yj2sn	788	23	to	to	TO
cord-276598-tm0yj2sn	788	24	give	give	VB
cord-276598-tm0yj2sn	788	25	the	the	DT
cord-276598-tm0yj2sn	788	26	P	p	NN
cord-276598-tm0yj2sn	788	27	-	-	HYPH
cord-276598-tm0yj2sn	788	28	N.	n.	NN
cord-276598-tm0yj2sn	789	1	This	this	DT
cord-276598-tm0yj2sn	789	2	is	be	VBZ
cord-276598-tm0yj2sn	789	3	because	because	IN
cord-276598-tm0yj2sn	789	4	the	the	DT
cord-276598-tm0yj2sn	789	5	coupling	coupling	NN
cord-276598-tm0yj2sn	789	6	reaction	reaction	NN
cord-276598-tm0yj2sn	789	7	was	be	VBD
cord-276598-tm0yj2sn	789	8	expected	expect	VBN
cord-276598-tm0yj2sn	789	9	to	to	TO
cord-276598-tm0yj2sn	789	10	eliminate	eliminate	VB
cord-276598-tm0yj2sn	789	11	other	other	JJ
cord-276598-tm0yj2sn	789	12	products	product	NNS
cord-276598-tm0yj2sn	789	13	along	along	IN
cord-276598-tm0yj2sn	789	14	with	with	IN
cord-276598-tm0yj2sn	789	15	CsCl	CsCl	NNP
cord-276598-tm0yj2sn	789	16	such	such	JJ
cord-276598-tm0yj2sn	789	17	as	as	IN
cord-276598-tm0yj2sn	789	18	a	a	DT
cord-276598-tm0yj2sn	789	19	highly	highly	RB
cord-276598-tm0yj2sn	789	20	reactive	reactive	JJ
cord-276598-tm0yj2sn	789	21	CsH	csh	NN
cord-276598-tm0yj2sn	789	22	and	and	CC
cord-276598-tm0yj2sn	789	23	a	a	DT
cord-276598-tm0yj2sn	789	24	carbonate	carbonate	NN
cord-276598-tm0yj2sn	789	25	.	.	.
cord-276598-tm0yj2sn	790	1	However	however	RB
cord-276598-tm0yj2sn	790	2	,	,	,
cord-276598-tm0yj2sn	790	3	it	-PRON-	PRP
cord-276598-tm0yj2sn	790	4	is	be	VBZ
cord-276598-tm0yj2sn	790	5	to	to	TO
cord-276598-tm0yj2sn	790	6	be	be	VB
cord-276598-tm0yj2sn	790	7	understood	understand	VBN
cord-276598-tm0yj2sn	790	8	that	that	IN
cord-276598-tm0yj2sn	790	9	the	the	DT
cord-276598-tm0yj2sn	790	10	use	use	NN
cord-276598-tm0yj2sn	790	11	of	of	IN
cord-276598-tm0yj2sn	790	12	Cs2CO3	Cs2CO3	NNP
cord-276598-tm0yj2sn	790	13	as	as	IN
cord-276598-tm0yj2sn	790	14	the	the	DT
cord-276598-tm0yj2sn	790	15	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	790	16	base	base	NN
cord-276598-tm0yj2sn	790	17	was	be	VBD
cord-276598-tm0yj2sn	790	18	based	base	VBN
cord-276598-tm0yj2sn	790	19	on	on	IN
cord-276598-tm0yj2sn	790	20	the	the	DT
cord-276598-tm0yj2sn	790	21	poorly	poorly	RB
cord-276598-tm0yj2sn	790	22	understood	understand	VBN
cord-276598-tm0yj2sn	790	23	"	"	``
cord-276598-tm0yj2sn	790	24	caesium	caesium	NN
cord-276598-tm0yj2sn	790	25	effect	effect	NN
cord-276598-tm0yj2sn	790	26	"	"	''
cord-276598-tm0yj2sn	790	27	in	in	IN
cord-276598-tm0yj2sn	790	28	which	which	WDT
cord-276598-tm0yj2sn	790	29	the	the	DT
cord-276598-tm0yj2sn	790	30	highly	highly	RB
cord-276598-tm0yj2sn	790	31	soluble	soluble	JJ
cord-276598-tm0yj2sn	790	32	caesium	caesium	NN
cord-276598-tm0yj2sn	790	33	base	base	NN
cord-276598-tm0yj2sn	790	34	selectively	selectively	RB
cord-276598-tm0yj2sn	790	35	favors	favor	VBZ
cord-276598-tm0yj2sn	790	36	the	the	DT
cord-276598-tm0yj2sn	790	37	formation	formation	NN
cord-276598-tm0yj2sn	790	38	of	of	IN
cord-276598-tm0yj2sn	790	39	one	one	CD
cord-276598-tm0yj2sn	790	40	functional	functional	JJ
cord-276598-tm0yj2sn	790	41	group	group	NN
cord-276598-tm0yj2sn	790	42	in	in	IN
cord-276598-tm0yj2sn	790	43	preference	preference	NN
cord-276598-tm0yj2sn	790	44	to	to	IN
cord-276598-tm0yj2sn	790	45	another	another	DT
cord-276598-tm0yj2sn	790	46	[	[	-LRB-
cord-276598-tm0yj2sn	790	47	122	122	CD
cord-276598-tm0yj2sn	790	48	,	,	,
cord-276598-tm0yj2sn	790	49	123	123	CD
cord-276598-tm0yj2sn	790	50	]	]	-RRB-
cord-276598-tm0yj2sn	790	51	.	.	.
cord-276598-tm0yj2sn	791	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	791	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	791	3	for	for	IN
cord-276598-tm0yj2sn	791	4	the	the	DT
cord-276598-tm0yj2sn	791	5	Cu	cu	NN
cord-276598-tm0yj2sn	791	6	-	-	HYPH
cord-276598-tm0yj2sn	791	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	791	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	791	9	of	of	IN
cord-276598-tm0yj2sn	791	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	791	11	.	.	.
cord-276598-tm0yj2sn	792	1	Mizuno	Mizuno	NNP
cord-276598-tm0yj2sn	792	2	et	et	NNP
cord-276598-tm0yj2sn	792	3	al	al	NNP
cord-276598-tm0yj2sn	792	4	.	.	.
cord-276598-tm0yj2sn	793	1	proposed	propose	VBD
cord-276598-tm0yj2sn	793	2	a	a	DT
cord-276598-tm0yj2sn	793	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	793	4	for	for	IN
cord-276598-tm0yj2sn	793	5	the	the	DT
cord-276598-tm0yj2sn	793	6	reaction	reaction	NN
cord-276598-tm0yj2sn	793	7	in	in	IN
cord-276598-tm0yj2sn	793	8	which	which	WDT
cord-276598-tm0yj2sn	793	9	K2CO3	K2CO3	NNP
cord-276598-tm0yj2sn	793	10	first	first	JJ
cord-276598-tm0yj2sn	793	11	deprotonates	deprotonate	VBZ
cord-276598-tm0yj2sn	793	12	the	the	DT
cord-276598-tm0yj2sn	793	13	amide	amide	NN
cord-276598-tm0yj2sn	793	14	,	,	,
cord-276598-tm0yj2sn	793	15	affording	afford	VBG
cord-276598-tm0yj2sn	793	16	unpaired	unpaired	JJ
cord-276598-tm0yj2sn	793	17	electrons	electron	NNS
cord-276598-tm0yj2sn	793	18	on	on	IN
cord-276598-tm0yj2sn	793	19	a	a	DT
cord-276598-tm0yj2sn	793	20	Cu	cu	NN
cord-276598-tm0yj2sn	793	21	-	-	NN
cord-276598-tm0yj2sn	793	22	amide	amide	NN
cord-276598-tm0yj2sn	793	23	complex	complex	NN
cord-276598-tm0yj2sn	793	24	[	[	-LRB-
cord-276598-tm0yj2sn	793	25	107	107	CD
cord-276598-tm0yj2sn	793	26	]	]	-RRB-
cord-276598-tm0yj2sn	793	27	.	.	.
cord-276598-tm0yj2sn	794	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	794	2	,	,	,
cord-276598-tm0yj2sn	794	3	it	-PRON-	PRP
cord-276598-tm0yj2sn	794	4	was	be	VBD
cord-276598-tm0yj2sn	794	5	suggested	suggest	VBN
cord-276598-tm0yj2sn	794	6	that	that	IN
cord-276598-tm0yj2sn	794	7	it	-PRON-	PRP
cord-276598-tm0yj2sn	794	8	is	be	VBZ
cord-276598-tm0yj2sn	794	9	possible	possible	JJ
cord-276598-tm0yj2sn	794	10	that	that	IN
cord-276598-tm0yj2sn	794	11	K2CO3	K2CO3	NNP
cord-276598-tm0yj2sn	794	12	deprotonates	deprotonate	NNS
cord-276598-tm0yj2sn	794	13	H	H	NNP
cord-276598-tm0yj2sn	794	14	-	-	HYPH
cord-276598-tm0yj2sn	794	15	P	P	NNP
cord-276598-tm0yj2sn	794	16	or	or	CC
cord-276598-tm0yj2sn	794	17	provides	provide	VBZ
cord-276598-tm0yj2sn	794	18	a	a	DT
cord-276598-tm0yj2sn	794	19	medium	medium	NN
cord-276598-tm0yj2sn	794	20	for	for	IN
cord-276598-tm0yj2sn	794	21	the	the	DT
cord-276598-tm0yj2sn	794	22	H	H	NNP
cord-276598-tm0yj2sn	794	23	-	-	HYPH
cord-276598-tm0yj2sn	794	24	P	p	NN
cord-276598-tm0yj2sn	794	25	tautomer	tautomer	NN
cord-276598-tm0yj2sn	794	26	to	to	IN
cord-276598-tm0yj2sn	794	27	further	further	RB
cord-276598-tm0yj2sn	794	28	complex	complex	JJ
cord-276598-tm0yj2sn	794	29	with	with	IN
cord-276598-tm0yj2sn	794	30	the	the	DT
cord-276598-tm0yj2sn	794	31	Cu	cu	NN
cord-276598-tm0yj2sn	794	32	-	-	HYPH
cord-276598-tm0yj2sn	794	33	amide	amide	NN
cord-276598-tm0yj2sn	794	34	complex	complex	NN
cord-276598-tm0yj2sn	794	35	.	.	.
cord-276598-tm0yj2sn	795	1	The	the	DT
cord-276598-tm0yj2sn	795	2	Cu	cu	NN
cord-276598-tm0yj2sn	795	3	-	-	HYPH
cord-276598-tm0yj2sn	795	4	amide	amide	NN
cord-276598-tm0yj2sn	795	5	-	-	HYPH
cord-276598-tm0yj2sn	795	6	phosphite	phosphite	NN
cord-276598-tm0yj2sn	795	7	intermediate	intermediate	NN
cord-276598-tm0yj2sn	795	8	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	795	9	reductive	reductive	JJ
cord-276598-tm0yj2sn	795	10	elimination	elimination	NN
cord-276598-tm0yj2sn	795	11	to	to	TO
cord-276598-tm0yj2sn	795	12	afford	afford	VB
cord-276598-tm0yj2sn	795	13	the	the	DT
cord-276598-tm0yj2sn	795	14	desired	desire	VBN
cord-276598-tm0yj2sn	795	15	product	product	NN
cord-276598-tm0yj2sn	795	16	,	,	,
cord-276598-tm0yj2sn	795	17	while	while	IN
cord-276598-tm0yj2sn	795	18	O2	O2	NNP
cord-276598-tm0yj2sn	795	19	re	re	NNS
cord-276598-tm0yj2sn	795	20	-	-	NN
cord-276598-tm0yj2sn	795	21	oxidizes	oxidize	VBZ
cord-276598-tm0yj2sn	795	22	the	the	DT
cord-276598-tm0yj2sn	795	23	reduced	reduce	VBN
cord-276598-tm0yj2sn	795	24	Cu	Cu	NNP
cord-276598-tm0yj2sn	795	25	species	specie	NNS
cord-276598-tm0yj2sn	795	26	to	to	TO
cord-276598-tm0yj2sn	795	27	regenerate	regenerate	VB
cord-276598-tm0yj2sn	795	28	the	the	DT
cord-276598-tm0yj2sn	795	29	active	active	JJ
cord-276598-tm0yj2sn	795	30	catalyst	catalyst	NN
cord-276598-tm0yj2sn	795	31	.	.	.
cord-276598-tm0yj2sn	796	1	Although	although	IN
cord-276598-tm0yj2sn	796	2	the	the	DT
cord-276598-tm0yj2sn	796	3	oxidation	oxidation	NN
cord-276598-tm0yj2sn	796	4	state	state	NN
cord-276598-tm0yj2sn	796	5	of	of	IN
cord-276598-tm0yj2sn	796	6	Cu	Cu	NNP
cord-276598-tm0yj2sn	796	7	in	in	IN
cord-276598-tm0yj2sn	796	8	the	the	DT
cord-276598-tm0yj2sn	796	9	reaction	reaction	NN
cord-276598-tm0yj2sn	796	10	mechanism	mechanism	NN
cord-276598-tm0yj2sn	796	11	was	be	VBD
cord-276598-tm0yj2sn	796	12	not	not	RB
cord-276598-tm0yj2sn	796	13	explained	explain	VBN
cord-276598-tm0yj2sn	796	14	,	,	,
cord-276598-tm0yj2sn	796	15	the	the	DT
cord-276598-tm0yj2sn	796	16	authors	author	NNS
cord-276598-tm0yj2sn	796	17	suggested	suggest	VBD
cord-276598-tm0yj2sn	796	18	that	that	IN
cord-276598-tm0yj2sn	796	19	it	-PRON-	PRP
cord-276598-tm0yj2sn	796	20	could	could	MD
cord-276598-tm0yj2sn	796	21	be	be	VB
cord-276598-tm0yj2sn	796	22	+2	+2	XX
cord-276598-tm0yj2sn	796	23	,	,	,
cord-276598-tm0yj2sn	796	24	and	and	CC
cord-276598-tm0yj2sn	796	25	the	the	DT
cord-276598-tm0yj2sn	796	26	fact	fact	NN
cord-276598-tm0yj2sn	796	27	that	that	IN
cord-276598-tm0yj2sn	796	28	the	the	DT
cord-276598-tm0yj2sn	796	29	reaction	reaction	NN
cord-276598-tm0yj2sn	796	30	produced	produce	VBD
cord-276598-tm0yj2sn	796	31	only	only	RB
cord-276598-tm0yj2sn	796	32	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	796	33	amounts	amount	NNS
cord-276598-tm0yj2sn	796	34	of	of	IN
cord-276598-tm0yj2sn	796	35	the	the	DT
cord-276598-tm0yj2sn	796	36	desired	desire	VBN
cord-276598-tm0yj2sn	796	37	product	product	NN
cord-276598-tm0yj2sn	796	38	(	(	-LRB-
cord-276598-tm0yj2sn	796	39	relative	relative	JJ
cord-276598-tm0yj2sn	796	40	to	to	IN
cord-276598-tm0yj2sn	796	41	the	the	DT
cord-276598-tm0yj2sn	796	42	Cu	Cu	NNP
cord-276598-tm0yj2sn	796	43	catalyst	catalyst	NN
cord-276598-tm0yj2sn	796	44	)	)	-RRB-
cord-276598-tm0yj2sn	796	45	under	under	IN
cord-276598-tm0yj2sn	796	46	an	an	DT
cord-276598-tm0yj2sn	796	47	inert	inert	JJ
cord-276598-tm0yj2sn	796	48	atmosphere	atmosphere	NN
cord-276598-tm0yj2sn	796	49	was	be	VBD
cord-276598-tm0yj2sn	796	50	a	a	DT
cord-276598-tm0yj2sn	796	51	support	support	NN
cord-276598-tm0yj2sn	796	52	to	to	IN
cord-276598-tm0yj2sn	796	53	the	the	DT
cord-276598-tm0yj2sn	796	54	re	re	NN
cord-276598-tm0yj2sn	796	55	-	-	NN
cord-276598-tm0yj2sn	796	56	oxidation	oxidation	NN
cord-276598-tm0yj2sn	796	57	of	of	IN
cord-276598-tm0yj2sn	796	58	the	the	DT
cord-276598-tm0yj2sn	796	59	Cu	Cu	NNP
cord-276598-tm0yj2sn	796	60	species	specie	NNS
cord-276598-tm0yj2sn	796	61	in	in	IN
cord-276598-tm0yj2sn	796	62	air	air	NN
cord-276598-tm0yj2sn	796	63	.	.	.
cord-276598-tm0yj2sn	797	1	From	from	IN
cord-276598-tm0yj2sn	797	2	their	-PRON-	PRP$
cord-276598-tm0yj2sn	797	3	experimental	experimental	JJ
cord-276598-tm0yj2sn	797	4	observations	observation	NNS
cord-276598-tm0yj2sn	797	5	,	,	,
cord-276598-tm0yj2sn	797	6	Zhou	Zhou	NNP
cord-276598-tm0yj2sn	797	7	et	et	NNP
cord-276598-tm0yj2sn	797	8	al	al	NNP
cord-276598-tm0yj2sn	797	9	.	.	.
cord-276598-tm0yj2sn	798	1	strongly	strongly	RB
cord-276598-tm0yj2sn	798	2	suggested	suggest	VBD
cord-276598-tm0yj2sn	798	3	that	that	IN
cord-276598-tm0yj2sn	798	4	the	the	DT
cord-276598-tm0yj2sn	798	5	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	798	6	dehydrocoupling	dehydrocouple	VBG
cord-276598-tm0yj2sn	798	7	reaction	reaction	NN
cord-276598-tm0yj2sn	798	8	for	for	IN
cord-276598-tm0yj2sn	798	9	P	p	NN
cord-276598-tm0yj2sn	798	10	-	-	HYPH
cord-276598-tm0yj2sn	798	11	N	n	CD
cord-276598-tm0yj2sn	798	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	798	13	using	use	VBG
cord-276598-tm0yj2sn	798	14	Cu	cu	NN
cord-276598-tm0yj2sn	798	15	-	-	HYPH
cord-276598-tm0yj2sn	798	16	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	798	17	proceeds	proceed	NNS
cord-276598-tm0yj2sn	798	18	stereospecifically	stereospecifically	RB
cord-276598-tm0yj2sn	798	19	through	through	IN
cord-276598-tm0yj2sn	798	20	an	an	DT
cord-276598-tm0yj2sn	798	21	inversion	inversion	NN
cord-276598-tm0yj2sn	798	22	of	of	IN
cord-276598-tm0yj2sn	798	23	the	the	DT
cord-276598-tm0yj2sn	798	24	configuration	configuration	NN
cord-276598-tm0yj2sn	798	25	at	at	IN
cord-276598-tm0yj2sn	798	26	P	p	NN
cord-276598-tm0yj2sn	798	27	[	[	-LRB-
cord-276598-tm0yj2sn	798	28	108	108	CD
cord-276598-tm0yj2sn	798	29	]	]	-RRB-
cord-276598-tm0yj2sn	798	30	.	.	.
cord-276598-tm0yj2sn	799	1	This	this	DT
cord-276598-tm0yj2sn	799	2	stereospecific	stereospecific	NN
cord-276598-tm0yj2sn	799	3	inversion	inversion	NN
cord-276598-tm0yj2sn	799	4	chemistry	chemistry	NN
cord-276598-tm0yj2sn	799	5	was	be	VBD
cord-276598-tm0yj2sn	799	6	used	use	VBN
cord-276598-tm0yj2sn	799	7	as	as	IN
cord-276598-tm0yj2sn	799	8	an	an	DT
cord-276598-tm0yj2sn	799	9	argument	argument	NN
cord-276598-tm0yj2sn	799	10	in	in	IN
cord-276598-tm0yj2sn	799	11	the	the	DT
cord-276598-tm0yj2sn	799	12	proposed	propose	VBN
cord-276598-tm0yj2sn	799	13	mechanism	mechanism	NN
cord-276598-tm0yj2sn	799	14	to	to	TO
cord-276598-tm0yj2sn	799	15	support	support	VB
cord-276598-tm0yj2sn	799	16	a	a	DT
cord-276598-tm0yj2sn	799	17	formation	formation	NN
cord-276598-tm0yj2sn	799	18	of	of	IN
cord-276598-tm0yj2sn	799	19	halogen	halogen	NN
cord-276598-tm0yj2sn	799	20	-	-	HYPH
cord-276598-tm0yj2sn	799	21	phosphate	phosphate	NN
cord-276598-tm0yj2sn	799	22	intermediate	intermediate	NN
cord-276598-tm0yj2sn	799	23	when	when	WRB
cord-276598-tm0yj2sn	799	24	Cu	Cu	NNP
cord-276598-tm0yj2sn	799	25	catalyst	catalyst	NN
cord-276598-tm0yj2sn	799	26	is	be	VBZ
cord-276598-tm0yj2sn	799	27	reacted	react	VBN
cord-276598-tm0yj2sn	799	28	with	with	IN
cord-276598-tm0yj2sn	799	29	H	H	NNP
cord-276598-tm0yj2sn	799	30	-	-	HYPH
cord-276598-tm0yj2sn	799	31	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	799	32	(	(	-LRB-
cord-276598-tm0yj2sn	799	33	H	h	NN
cord-276598-tm0yj2sn	799	34	-	-	HYPH
cord-276598-tm0yj2sn	799	35	P	p	NN
cord-276598-tm0yj2sn	799	36	)	)	-RRB-
cord-276598-tm0yj2sn	799	37	.	.	.
cord-276598-tm0yj2sn	800	1	The	the	DT
cord-276598-tm0yj2sn	800	2	amine	amine	NN
cord-276598-tm0yj2sn	800	3	(	(	-LRB-
cord-276598-tm0yj2sn	800	4	as	as	IN
cord-276598-tm0yj2sn	800	5	a	a	DT
cord-276598-tm0yj2sn	800	6	nucleophile	nucleophile	NN
cord-276598-tm0yj2sn	800	7	)	)	-RRB-
cord-276598-tm0yj2sn	800	8	subsequently	subsequently	RB
cord-276598-tm0yj2sn	800	9	attacks	attack	VBZ
cord-276598-tm0yj2sn	800	10	the	the	DT
cord-276598-tm0yj2sn	800	11	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	800	12	from	from	IN
cord-276598-tm0yj2sn	800	13	behind	behind	RB
cord-276598-tm0yj2sn	800	14	to	to	TO
cord-276598-tm0yj2sn	800	15	give	give	VB
cord-276598-tm0yj2sn	800	16	the	the	DT
cord-276598-tm0yj2sn	800	17	product	product	NN
cord-276598-tm0yj2sn	800	18	,	,	,
cord-276598-tm0yj2sn	800	19	while	while	IN
cord-276598-tm0yj2sn	800	20	the	the	DT
cord-276598-tm0yj2sn	800	21	Cu(I	Cu(I	NNP
cord-276598-tm0yj2sn	800	22	)	)	-RRB-
cord-276598-tm0yj2sn	800	23	catalyst	catalyst	NN
cord-276598-tm0yj2sn	800	24	is	be	VBZ
cord-276598-tm0yj2sn	800	25	then	then	RB
cord-276598-tm0yj2sn	800	26	reoxidized	reoxidize	VBN
cord-276598-tm0yj2sn	800	27	by	by	IN
cord-276598-tm0yj2sn	800	28	O2	O2	NNP
cord-276598-tm0yj2sn	800	29	to	to	IN
cord-276598-tm0yj2sn	800	30	Cu(II	Cu(II	NNP
cord-276598-tm0yj2sn	800	31	)	)	-RRB-
cord-276598-tm0yj2sn	800	32	in	in	IN
cord-276598-tm0yj2sn	800	33	the	the	DT
cord-276598-tm0yj2sn	800	34	presence	presence	NN
cord-276598-tm0yj2sn	800	35	of	of	IN
cord-276598-tm0yj2sn	800	36	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	800	37	halide	halide	NN
cord-276598-tm0yj2sn	800	38	formed	form	VBN
cord-276598-tm0yj2sn	800	39	from	from	IN
cord-276598-tm0yj2sn	800	40	the	the	DT
cord-276598-tm0yj2sn	800	41	process	process	NN
cord-276598-tm0yj2sn	800	42	.	.	.
cord-276598-tm0yj2sn	801	1	Water	water	NN
cord-276598-tm0yj2sn	801	2	is	be	VBZ
cord-276598-tm0yj2sn	801	3	also	also	RB
cord-276598-tm0yj2sn	801	4	formed	form	VBN
cord-276598-tm0yj2sn	801	5	as	as	IN
cord-276598-tm0yj2sn	801	6	a	a	DT
cord-276598-tm0yj2sn	801	7	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	801	8	waste	waste	NN
cord-276598-tm0yj2sn	801	9	(	(	-LRB-
cord-276598-tm0yj2sn	801	10	Scheme	scheme	NN
cord-276598-tm0yj2sn	801	11	29b	29b	CD
cord-276598-tm0yj2sn	801	12	)	)	-RRB-
cord-276598-tm0yj2sn	801	13	.	.	.
cord-276598-tm0yj2sn	802	1	The	the	DT
cord-276598-tm0yj2sn	802	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	802	3	as	as	IN
cord-276598-tm0yj2sn	802	4	reported	report	VBN
cord-276598-tm0yj2sn	802	5	by	by	IN
cord-276598-tm0yj2sn	802	6	Dangroo	Dangroo	NNP
cord-276598-tm0yj2sn	802	7	et	et	NNP
cord-276598-tm0yj2sn	802	8	al	al	NNP
cord-276598-tm0yj2sn	802	9	.	.	.
cord-276598-tm0yj2sn	803	1	involved	involve	VBN
cord-276598-tm0yj2sn	803	2	transmetalation	transmetalation	NN
cord-276598-tm0yj2sn	803	3	to	to	TO
cord-276598-tm0yj2sn	803	4	form	form	VB
cord-276598-tm0yj2sn	803	5	an	an	DT
cord-276598-tm0yj2sn	803	6	azidocopper(II	azidocopper(II	NNP
cord-276598-tm0yj2sn	803	7	)	)	-RRB-
cord-276598-tm0yj2sn	803	8	species	specie	NNS
cord-276598-tm0yj2sn	803	9	in	in	IN
cord-276598-tm0yj2sn	803	10	the	the	DT
cord-276598-tm0yj2sn	803	11	first	first	JJ
cord-276598-tm0yj2sn	803	12	step	step	NN
cord-276598-tm0yj2sn	803	13	(	(	-LRB-
cord-276598-tm0yj2sn	803	14	Scheme	scheme	NN
cord-276598-tm0yj2sn	803	15	30	30	CD
cord-276598-tm0yj2sn	803	16	)	)	-RRB-
cord-276598-tm0yj2sn	803	17	[	[	-LRB-
cord-276598-tm0yj2sn	803	18	109	109	CD
cord-276598-tm0yj2sn	803	19	]	]	-RRB-
cord-276598-tm0yj2sn	803	20	.	.	.
cord-276598-tm0yj2sn	804	1	Similar	similar	JJ
cord-276598-tm0yj2sn	804	2	transmetalation	transmetalation	NN
cord-276598-tm0yj2sn	804	3	reactions	reaction	NNS
cord-276598-tm0yj2sn	804	4	involving	involve	VBG
cord-276598-tm0yj2sn	804	5	the	the	DT
cord-276598-tm0yj2sn	804	6	phenylboronic	phenylboronic	JJ
cord-276598-tm0yj2sn	804	7	acid	acid	NN
cord-276598-tm0yj2sn	804	8	-	-	HYPH
cord-276598-tm0yj2sn	804	9	based	base	VBN
cord-276598-tm0yj2sn	804	10	substrates	substrate	NNS
cord-276598-tm0yj2sn	804	11	and	and	CC
cord-276598-tm0yj2sn	804	12	the	the	DT
cord-276598-tm0yj2sn	804	13	azidocopper(II	azidocopper(II	NNP
cord-276598-tm0yj2sn	804	14	)	)	-RRB-
cord-276598-tm0yj2sn	804	15	species	specie	NNS
cord-276598-tm0yj2sn	804	16	in	in	IN
cord-276598-tm0yj2sn	804	17	the	the	DT
cord-276598-tm0yj2sn	804	18	second	second	JJ
cord-276598-tm0yj2sn	804	19	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	804	20	29	29	CD
cord-276598-tm0yj2sn	804	21	.	.	.
cord-276598-tm0yj2sn	805	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	805	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	805	3	for	for	IN
cord-276598-tm0yj2sn	805	4	the	the	DT
cord-276598-tm0yj2sn	805	5	Cu	cu	NN
cord-276598-tm0yj2sn	805	6	-	-	HYPH
cord-276598-tm0yj2sn	805	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	805	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	805	9	of	of	IN
cord-276598-tm0yj2sn	805	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	805	11	.	.	.
cord-276598-tm0yj2sn	806	1	Mizuno	Mizuno	NNP
cord-276598-tm0yj2sn	806	2	et	et	NNP
cord-276598-tm0yj2sn	806	3	al	al	NNP
cord-276598-tm0yj2sn	806	4	.	.	.
cord-276598-tm0yj2sn	807	1	proposed	propose	VBD
cord-276598-tm0yj2sn	807	2	a	a	DT
cord-276598-tm0yj2sn	807	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	807	4	for	for	IN
cord-276598-tm0yj2sn	807	5	the	the	DT
cord-276598-tm0yj2sn	807	6	reaction	reaction	NN
cord-276598-tm0yj2sn	807	7	in	in	IN
cord-276598-tm0yj2sn	807	8	which	which	WDT
cord-276598-tm0yj2sn	807	9	K	K	NNP
cord-276598-tm0yj2sn	807	10	2	2	CD
cord-276598-tm0yj2sn	807	11	CO	CO	NNP
cord-276598-tm0yj2sn	807	12	3	3	CD
cord-276598-tm0yj2sn	807	13	first	first	JJ
cord-276598-tm0yj2sn	807	14	deprotonates	deprotonate	NNS
cord-276598-tm0yj2sn	807	15	the	the	DT
cord-276598-tm0yj2sn	807	16	amide	amide	NN
cord-276598-tm0yj2sn	807	17	,	,	,
cord-276598-tm0yj2sn	807	18	affording	afford	VBG
cord-276598-tm0yj2sn	807	19	unpaired	unpaired	JJ
cord-276598-tm0yj2sn	807	20	electrons	electron	NNS
cord-276598-tm0yj2sn	807	21	on	on	IN
cord-276598-tm0yj2sn	807	22	a	a	DT
cord-276598-tm0yj2sn	807	23	Cu	cu	NN
cord-276598-tm0yj2sn	807	24	-	-	NN
cord-276598-tm0yj2sn	807	25	amide	amide	NN
cord-276598-tm0yj2sn	807	26	complex	complex	NN
cord-276598-tm0yj2sn	807	27	[	[	-LRB-
cord-276598-tm0yj2sn	807	28	107	107	CD
cord-276598-tm0yj2sn	807	29	]	]	-RRB-
cord-276598-tm0yj2sn	807	30	.	.	.
cord-276598-tm0yj2sn	808	1	Furthermore	furthermore	RB
cord-276598-tm0yj2sn	808	2	,	,	,
cord-276598-tm0yj2sn	808	3	it	-PRON-	PRP
cord-276598-tm0yj2sn	808	4	was	be	VBD
cord-276598-tm0yj2sn	808	5	suggested	suggest	VBN
cord-276598-tm0yj2sn	808	6	that	that	IN
cord-276598-tm0yj2sn	808	7	it	-PRON-	PRP
cord-276598-tm0yj2sn	808	8	is	be	VBZ
cord-276598-tm0yj2sn	808	9	possible	possible	JJ
cord-276598-tm0yj2sn	808	10	that	that	IN
cord-276598-tm0yj2sn	808	11	K	K	NNP
cord-276598-tm0yj2sn	808	12	2	2	CD
cord-276598-tm0yj2sn	808	13	CO	CO	NNP
cord-276598-tm0yj2sn	808	14	3	3	CD
cord-276598-tm0yj2sn	808	15	deprotonates	deprotonate	NNS
cord-276598-tm0yj2sn	808	16	H	h	NN
cord-276598-tm0yj2sn	808	17	-	-	HYPH
cord-276598-tm0yj2sn	808	18	P	p	NN
cord-276598-tm0yj2sn	808	19	or	or	CC
cord-276598-tm0yj2sn	808	20	provides	provide	VBZ
cord-276598-tm0yj2sn	808	21	a	a	DT
cord-276598-tm0yj2sn	808	22	medium	medium	NN
cord-276598-tm0yj2sn	808	23	for	for	IN
cord-276598-tm0yj2sn	808	24	the	the	DT
cord-276598-tm0yj2sn	808	25	H	H	NNP
cord-276598-tm0yj2sn	808	26	-	-	HYPH
cord-276598-tm0yj2sn	808	27	P	p	NN
cord-276598-tm0yj2sn	808	28	tautomer	tautomer	NN
cord-276598-tm0yj2sn	808	29	to	to	IN
cord-276598-tm0yj2sn	808	30	further	further	RB
cord-276598-tm0yj2sn	808	31	complex	complex	JJ
cord-276598-tm0yj2sn	808	32	with	with	IN
cord-276598-tm0yj2sn	808	33	the	the	DT
cord-276598-tm0yj2sn	808	34	Cu	cu	NN
cord-276598-tm0yj2sn	808	35	-	-	HYPH
cord-276598-tm0yj2sn	808	36	amide	amide	NN
cord-276598-tm0yj2sn	808	37	complex	complex	NN
cord-276598-tm0yj2sn	808	38	.	.	.
cord-276598-tm0yj2sn	809	1	The	the	DT
cord-276598-tm0yj2sn	809	2	Cu	cu	NN
cord-276598-tm0yj2sn	809	3	-	-	HYPH
cord-276598-tm0yj2sn	809	4	amide	amide	NN
cord-276598-tm0yj2sn	809	5	-	-	HYPH
cord-276598-tm0yj2sn	809	6	phosphite	phosphite	NN
cord-276598-tm0yj2sn	809	7	intermediate	intermediate	NN
cord-276598-tm0yj2sn	809	8	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	809	9	reductive	reductive	JJ
cord-276598-tm0yj2sn	809	10	elimination	elimination	NN
cord-276598-tm0yj2sn	809	11	to	to	TO
cord-276598-tm0yj2sn	809	12	afford	afford	VB
cord-276598-tm0yj2sn	809	13	the	the	DT
cord-276598-tm0yj2sn	809	14	desired	desire	VBN
cord-276598-tm0yj2sn	809	15	product	product	NN
cord-276598-tm0yj2sn	809	16	,	,	,
cord-276598-tm0yj2sn	809	17	while	while	IN
cord-276598-tm0yj2sn	809	18	O	o	NN
cord-276598-tm0yj2sn	809	19	2	2	CD
cord-276598-tm0yj2sn	809	20	re	re	NN
cord-276598-tm0yj2sn	809	21	-	-	NN
cord-276598-tm0yj2sn	809	22	oxidizes	oxidize	NNS
cord-276598-tm0yj2sn	810	1	the	the	DT
cord-276598-tm0yj2sn	810	2	reduced	reduce	VBN
cord-276598-tm0yj2sn	810	3	Cu	Cu	NNP
cord-276598-tm0yj2sn	810	4	species	specie	NNS
cord-276598-tm0yj2sn	810	5	to	to	TO
cord-276598-tm0yj2sn	810	6	regenerate	regenerate	VB
cord-276598-tm0yj2sn	810	7	the	the	DT
cord-276598-tm0yj2sn	810	8	active	active	JJ
cord-276598-tm0yj2sn	810	9	catalyst	catalyst	NN
cord-276598-tm0yj2sn	810	10	.	.	.
cord-276598-tm0yj2sn	811	1	Although	although	IN
cord-276598-tm0yj2sn	811	2	the	the	DT
cord-276598-tm0yj2sn	811	3	oxidation	oxidation	NN
cord-276598-tm0yj2sn	811	4	state	state	NN
cord-276598-tm0yj2sn	811	5	of	of	IN
cord-276598-tm0yj2sn	811	6	Cu	Cu	NNP
cord-276598-tm0yj2sn	811	7	in	in	IN
cord-276598-tm0yj2sn	811	8	the	the	DT
cord-276598-tm0yj2sn	811	9	reaction	reaction	NN
cord-276598-tm0yj2sn	811	10	mechanism	mechanism	NN
cord-276598-tm0yj2sn	811	11	was	be	VBD
cord-276598-tm0yj2sn	811	12	not	not	RB
cord-276598-tm0yj2sn	811	13	explained	explain	VBN
cord-276598-tm0yj2sn	811	14	,	,	,
cord-276598-tm0yj2sn	811	15	the	the	DT
cord-276598-tm0yj2sn	811	16	authors	author	NNS
cord-276598-tm0yj2sn	811	17	suggested	suggest	VBD
cord-276598-tm0yj2sn	811	18	that	that	IN
cord-276598-tm0yj2sn	811	19	it	-PRON-	PRP
cord-276598-tm0yj2sn	811	20	could	could	MD
cord-276598-tm0yj2sn	811	21	be	be	VB
cord-276598-tm0yj2sn	811	22	+2	+2	XX
cord-276598-tm0yj2sn	811	23	,	,	,
cord-276598-tm0yj2sn	811	24	and	and	CC
cord-276598-tm0yj2sn	811	25	the	the	DT
cord-276598-tm0yj2sn	811	26	fact	fact	NN
cord-276598-tm0yj2sn	811	27	that	that	IN
cord-276598-tm0yj2sn	811	28	the	the	DT
cord-276598-tm0yj2sn	811	29	reaction	reaction	NN
cord-276598-tm0yj2sn	811	30	produced	produce	VBD
cord-276598-tm0yj2sn	811	31	only	only	RB
cord-276598-tm0yj2sn	811	32	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	811	33	amounts	amount	NNS
cord-276598-tm0yj2sn	811	34	of	of	IN
cord-276598-tm0yj2sn	811	35	the	the	DT
cord-276598-tm0yj2sn	811	36	desired	desire	VBN
cord-276598-tm0yj2sn	811	37	product	product	NN
cord-276598-tm0yj2sn	811	38	(	(	-LRB-
cord-276598-tm0yj2sn	811	39	relative	relative	JJ
cord-276598-tm0yj2sn	811	40	to	to	IN
cord-276598-tm0yj2sn	811	41	the	the	DT
cord-276598-tm0yj2sn	811	42	Cu	Cu	NNP
cord-276598-tm0yj2sn	811	43	catalyst	catalyst	NN
cord-276598-tm0yj2sn	811	44	)	)	-RRB-
cord-276598-tm0yj2sn	811	45	under	under	IN
cord-276598-tm0yj2sn	811	46	an	an	DT
cord-276598-tm0yj2sn	811	47	inert	inert	JJ
cord-276598-tm0yj2sn	811	48	atmosphere	atmosphere	NN
cord-276598-tm0yj2sn	811	49	was	be	VBD
cord-276598-tm0yj2sn	811	50	a	a	DT
cord-276598-tm0yj2sn	811	51	support	support	NN
cord-276598-tm0yj2sn	811	52	to	to	IN
cord-276598-tm0yj2sn	811	53	the	the	DT
cord-276598-tm0yj2sn	811	54	re	re	NN
cord-276598-tm0yj2sn	811	55	-	-	NN
cord-276598-tm0yj2sn	811	56	oxidation	oxidation	NN
cord-276598-tm0yj2sn	811	57	of	of	IN
cord-276598-tm0yj2sn	811	58	the	the	DT
cord-276598-tm0yj2sn	811	59	Cu	Cu	NNP
cord-276598-tm0yj2sn	811	60	species	specie	NNS
cord-276598-tm0yj2sn	811	61	in	in	IN
cord-276598-tm0yj2sn	811	62	air	air	NN
cord-276598-tm0yj2sn	811	63	.	.	.
cord-276598-tm0yj2sn	812	1	From	from	IN
cord-276598-tm0yj2sn	812	2	their	-PRON-	PRP$
cord-276598-tm0yj2sn	812	3	experimental	experimental	JJ
cord-276598-tm0yj2sn	812	4	observations	observation	NNS
cord-276598-tm0yj2sn	812	5	,	,	,
cord-276598-tm0yj2sn	812	6	Zhou	Zhou	NNP
cord-276598-tm0yj2sn	812	7	et	et	NNP
cord-276598-tm0yj2sn	812	8	al	al	NNP
cord-276598-tm0yj2sn	812	9	.	.	.
cord-276598-tm0yj2sn	813	1	strongly	strongly	RB
cord-276598-tm0yj2sn	813	2	suggested	suggest	VBD
cord-276598-tm0yj2sn	813	3	that	that	IN
cord-276598-tm0yj2sn	813	4	the	the	DT
cord-276598-tm0yj2sn	813	5	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	813	6	dehydrocoupling	dehydrocouple	VBG
cord-276598-tm0yj2sn	813	7	reaction	reaction	NN
cord-276598-tm0yj2sn	813	8	for	for	IN
cord-276598-tm0yj2sn	813	9	P	p	NN
cord-276598-tm0yj2sn	813	10	-	-	HYPH
cord-276598-tm0yj2sn	813	11	N	n	CD
cord-276598-tm0yj2sn	813	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	813	13	using	use	VBG
cord-276598-tm0yj2sn	813	14	Cu	cu	NN
cord-276598-tm0yj2sn	813	15	-	-	HYPH
cord-276598-tm0yj2sn	813	16	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	813	17	proceeds	proceed	NNS
cord-276598-tm0yj2sn	813	18	stereospecifically	stereospecifically	RB
cord-276598-tm0yj2sn	813	19	through	through	IN
cord-276598-tm0yj2sn	813	20	an	an	DT
cord-276598-tm0yj2sn	813	21	inversion	inversion	NN
cord-276598-tm0yj2sn	813	22	of	of	IN
cord-276598-tm0yj2sn	813	23	the	the	DT
cord-276598-tm0yj2sn	813	24	configuration	configuration	NN
cord-276598-tm0yj2sn	813	25	at	at	IN
cord-276598-tm0yj2sn	813	26	P	p	NN
cord-276598-tm0yj2sn	813	27	[	[	-LRB-
cord-276598-tm0yj2sn	813	28	108	108	CD
cord-276598-tm0yj2sn	813	29	]	]	-RRB-
cord-276598-tm0yj2sn	813	30	.	.	.
cord-276598-tm0yj2sn	814	1	This	this	DT
cord-276598-tm0yj2sn	814	2	stereospecific	stereospecific	NN
cord-276598-tm0yj2sn	814	3	inversion	inversion	NN
cord-276598-tm0yj2sn	814	4	chemistry	chemistry	NN
cord-276598-tm0yj2sn	814	5	was	be	VBD
cord-276598-tm0yj2sn	814	6	used	use	VBN
cord-276598-tm0yj2sn	814	7	as	as	IN
cord-276598-tm0yj2sn	814	8	an	an	DT
cord-276598-tm0yj2sn	814	9	argument	argument	NN
cord-276598-tm0yj2sn	814	10	in	in	IN
cord-276598-tm0yj2sn	814	11	the	the	DT
cord-276598-tm0yj2sn	814	12	proposed	propose	VBN
cord-276598-tm0yj2sn	814	13	mechanism	mechanism	NN
cord-276598-tm0yj2sn	814	14	to	to	TO
cord-276598-tm0yj2sn	814	15	support	support	VB
cord-276598-tm0yj2sn	814	16	a	a	DT
cord-276598-tm0yj2sn	814	17	formation	formation	NN
cord-276598-tm0yj2sn	814	18	of	of	IN
cord-276598-tm0yj2sn	814	19	halogen	halogen	NN
cord-276598-tm0yj2sn	814	20	-	-	HYPH
cord-276598-tm0yj2sn	814	21	phosphate	phosphate	NN
cord-276598-tm0yj2sn	814	22	intermediate	intermediate	NN
cord-276598-tm0yj2sn	814	23	when	when	WRB
cord-276598-tm0yj2sn	814	24	Cu	Cu	NNP
cord-276598-tm0yj2sn	814	25	catalyst	catalyst	NN
cord-276598-tm0yj2sn	814	26	is	be	VBZ
cord-276598-tm0yj2sn	814	27	reacted	react	VBN
cord-276598-tm0yj2sn	814	28	with	with	IN
cord-276598-tm0yj2sn	814	29	H	H	NNP
cord-276598-tm0yj2sn	814	30	-	-	HYPH
cord-276598-tm0yj2sn	814	31	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	814	32	(	(	-LRB-
cord-276598-tm0yj2sn	814	33	H	h	NN
cord-276598-tm0yj2sn	814	34	-	-	HYPH
cord-276598-tm0yj2sn	814	35	P	p	NN
cord-276598-tm0yj2sn	814	36	)	)	-RRB-
cord-276598-tm0yj2sn	814	37	.	.	.
cord-276598-tm0yj2sn	815	1	The	the	DT
cord-276598-tm0yj2sn	815	2	amine	amine	NN
cord-276598-tm0yj2sn	815	3	(	(	-LRB-
cord-276598-tm0yj2sn	815	4	as	as	IN
cord-276598-tm0yj2sn	815	5	a	a	DT
cord-276598-tm0yj2sn	815	6	nucleophile	nucleophile	NN
cord-276598-tm0yj2sn	815	7	)	)	-RRB-
cord-276598-tm0yj2sn	815	8	subsequently	subsequently	RB
cord-276598-tm0yj2sn	815	9	attacks	attack	VBZ
cord-276598-tm0yj2sn	815	10	the	the	DT
cord-276598-tm0yj2sn	815	11	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	815	12	from	from	IN
cord-276598-tm0yj2sn	815	13	behind	behind	RB
cord-276598-tm0yj2sn	815	14	to	to	TO
cord-276598-tm0yj2sn	815	15	give	give	VB
cord-276598-tm0yj2sn	815	16	the	the	DT
cord-276598-tm0yj2sn	815	17	product	product	NN
cord-276598-tm0yj2sn	815	18	,	,	,
cord-276598-tm0yj2sn	815	19	while	while	IN
cord-276598-tm0yj2sn	815	20	the	the	DT
cord-276598-tm0yj2sn	815	21	Cu(I	Cu(I	NNP
cord-276598-tm0yj2sn	815	22	)	)	-RRB-
cord-276598-tm0yj2sn	815	23	catalyst	catalyst	NN
cord-276598-tm0yj2sn	815	24	is	be	VBZ
cord-276598-tm0yj2sn	815	25	then	then	RB
cord-276598-tm0yj2sn	815	26	reoxidized	reoxidize	VBN
cord-276598-tm0yj2sn	815	27	by	by	IN
cord-276598-tm0yj2sn	815	28	O	o	NN
cord-276598-tm0yj2sn	815	29	2	2	CD
cord-276598-tm0yj2sn	815	30	to	to	IN
cord-276598-tm0yj2sn	815	31	Cu(II	cu(ii	NN
cord-276598-tm0yj2sn	815	32	)	)	-RRB-
cord-276598-tm0yj2sn	815	33	in	in	IN
cord-276598-tm0yj2sn	815	34	the	the	DT
cord-276598-tm0yj2sn	815	35	presence	presence	NN
cord-276598-tm0yj2sn	815	36	of	of	IN
cord-276598-tm0yj2sn	815	37	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	815	38	halide	halide	NN
cord-276598-tm0yj2sn	815	39	formed	form	VBN
cord-276598-tm0yj2sn	815	40	from	from	IN
cord-276598-tm0yj2sn	815	41	the	the	DT
cord-276598-tm0yj2sn	815	42	process	process	NN
cord-276598-tm0yj2sn	815	43	.	.	.
cord-276598-tm0yj2sn	816	1	Water	water	NN
cord-276598-tm0yj2sn	816	2	is	be	VBZ
cord-276598-tm0yj2sn	816	3	also	also	RB
cord-276598-tm0yj2sn	816	4	formed	form	VBN
cord-276598-tm0yj2sn	816	5	as	as	IN
cord-276598-tm0yj2sn	816	6	a	a	DT
cord-276598-tm0yj2sn	816	7	stoichiometric	stoichiometric	JJ
cord-276598-tm0yj2sn	816	8	waste	waste	NN
cord-276598-tm0yj2sn	816	9	(	(	-LRB-
cord-276598-tm0yj2sn	816	10	Scheme	scheme	NN
cord-276598-tm0yj2sn	816	11	29b	29b	CD
cord-276598-tm0yj2sn	816	12	)	)	-RRB-
cord-276598-tm0yj2sn	816	13	.	.	.
cord-276598-tm0yj2sn	817	1	The	the	DT
cord-276598-tm0yj2sn	817	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	817	3	as	as	IN
cord-276598-tm0yj2sn	817	4	reported	report	VBN
cord-276598-tm0yj2sn	817	5	by	by	IN
cord-276598-tm0yj2sn	817	6	Dangroo	Dangroo	NNP
cord-276598-tm0yj2sn	817	7	et	et	NNP
cord-276598-tm0yj2sn	817	8	al	al	NNP
cord-276598-tm0yj2sn	817	9	.	.	.
cord-276598-tm0yj2sn	818	1	involved	involve	VBN
cord-276598-tm0yj2sn	818	2	transmetalation	transmetalation	NN
cord-276598-tm0yj2sn	818	3	to	to	TO
cord-276598-tm0yj2sn	818	4	form	form	VB
cord-276598-tm0yj2sn	818	5	an	an	DT
cord-276598-tm0yj2sn	818	6	azidocopper(II	azidocopper(II	NNP
cord-276598-tm0yj2sn	818	7	)	)	-RRB-
cord-276598-tm0yj2sn	818	8	species	specie	NNS
cord-276598-tm0yj2sn	818	9	in	in	IN
cord-276598-tm0yj2sn	818	10	the	the	DT
cord-276598-tm0yj2sn	818	11	first	first	JJ
cord-276598-tm0yj2sn	818	12	step	step	NN
cord-276598-tm0yj2sn	818	13	(	(	-LRB-
cord-276598-tm0yj2sn	818	14	Scheme	scheme	NN
cord-276598-tm0yj2sn	818	15	30	30	CD
cord-276598-tm0yj2sn	818	16	)	)	-RRB-
cord-276598-tm0yj2sn	818	17	[	[	-LRB-
cord-276598-tm0yj2sn	818	18	109	109	CD
cord-276598-tm0yj2sn	818	19	]	]	-RRB-
cord-276598-tm0yj2sn	818	20	.	.	.
cord-276598-tm0yj2sn	819	1	Similar	similar	JJ
cord-276598-tm0yj2sn	819	2	transmetalation	transmetalation	NN
cord-276598-tm0yj2sn	819	3	reactions	reaction	NNS
cord-276598-tm0yj2sn	819	4	involving	involve	VBG
cord-276598-tm0yj2sn	819	5	the	the	DT
cord-276598-tm0yj2sn	819	6	phenylboronic	phenylboronic	JJ
cord-276598-tm0yj2sn	819	7	acid	acid	NN
cord-276598-tm0yj2sn	819	8	-	-	HYPH
cord-276598-tm0yj2sn	819	9	based	base	VBN
cord-276598-tm0yj2sn	819	10	substrates	substrate	NNS
cord-276598-tm0yj2sn	819	11	and	and	CC
cord-276598-tm0yj2sn	819	12	the	the	DT
cord-276598-tm0yj2sn	819	13	azidocopper(II	azidocopper(II	NNP
cord-276598-tm0yj2sn	819	14	)	)	-RRB-
cord-276598-tm0yj2sn	819	15	species	specie	NNS
cord-276598-tm0yj2sn	819	16	in	in	IN
cord-276598-tm0yj2sn	819	17	the	the	DT
cord-276598-tm0yj2sn	819	18	second	second	JJ
cord-276598-tm0yj2sn	819	19	step	step	NN
cord-276598-tm0yj2sn	819	20	result	result	NN
cord-276598-tm0yj2sn	819	21	in	in	IN
cord-276598-tm0yj2sn	819	22	the	the	DT
cord-276598-tm0yj2sn	819	23	formation	formation	NN
cord-276598-tm0yj2sn	819	24	of	of	IN
cord-276598-tm0yj2sn	819	25	a	a	DT
cord-276598-tm0yj2sn	819	26	phenyl	phenyl	NNP
cord-276598-tm0yj2sn	819	27	-	-	HYPH
cord-276598-tm0yj2sn	819	28	azidocopper(II	azidocopper(II	NNP
cord-276598-tm0yj2sn	819	29	)	)	-RRB-
cord-276598-tm0yj2sn	819	30	complex	complex	NNP
cord-276598-tm0yj2sn	819	31	.	.	.
cord-276598-tm0yj2sn	820	1	The	the	DT
cord-276598-tm0yj2sn	820	2	complex	complex	NN
cord-276598-tm0yj2sn	820	3	is	be	VBZ
cord-276598-tm0yj2sn	820	4	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	820	5	in	in	IN
cord-276598-tm0yj2sn	820	6	the	the	DT
cord-276598-tm0yj2sn	820	7	presence	presence	NN
cord-276598-tm0yj2sn	820	8	of	of	IN
cord-276598-tm0yj2sn	820	9	Cu(II	Cu(II	NNP
cord-276598-tm0yj2sn	820	10	)	)	-RRB-
cord-276598-tm0yj2sn	820	11	to	to	IN
cord-276598-tm0yj2sn	820	12	a	a	DT
cord-276598-tm0yj2sn	820	13	phenyl	phenyl	NN
cord-276598-tm0yj2sn	820	14	-	-	HYPH
cord-276598-tm0yj2sn	820	15	azidocopper(III	azidocopper(iii	CD
cord-276598-tm0yj2sn	820	16	)	)	-RRB-
cord-276598-tm0yj2sn	820	17	complex	complex	NN
cord-276598-tm0yj2sn	820	18	,	,	,
cord-276598-tm0yj2sn	820	19	which	which	WDT
cord-276598-tm0yj2sn	820	20	results	result	VBZ
cord-276598-tm0yj2sn	820	21	in	in	IN
cord-276598-tm0yj2sn	820	22	the	the	DT
cord-276598-tm0yj2sn	820	23	formation	formation	NN
cord-276598-tm0yj2sn	820	24	of	of	IN
cord-276598-tm0yj2sn	820	25	the	the	DT
cord-276598-tm0yj2sn	820	26	organic	organic	JJ
cord-276598-tm0yj2sn	820	27	azide	azide	NN
cord-276598-tm0yj2sn	820	28	and	and	CC
cord-276598-tm0yj2sn	820	29	forms	form	VBZ
cord-276598-tm0yj2sn	820	30	Cu(I	Cu(I	NNP
cord-276598-tm0yj2sn	820	31	)	)	-RRB-
cord-276598-tm0yj2sn	820	32	after	after	IN
cord-276598-tm0yj2sn	820	33	reductive	reductive	JJ
cord-276598-tm0yj2sn	820	34	elimination	elimination	NN
cord-276598-tm0yj2sn	820	35	.	.	.
cord-276598-tm0yj2sn	821	1	From	from	IN
cord-276598-tm0yj2sn	821	2	this	this	DT
cord-276598-tm0yj2sn	821	3	,	,	,
cord-276598-tm0yj2sn	821	4	a	a	DT
cord-276598-tm0yj2sn	821	5	reaction	reaction	NN
cord-276598-tm0yj2sn	821	6	between	between	IN
cord-276598-tm0yj2sn	821	7	the	the	DT
cord-276598-tm0yj2sn	821	8	(	(	-LRB-
cord-276598-tm0yj2sn	821	9	RO	ro	NN
cord-276598-tm0yj2sn	821	10	)	)	-RRB-
cord-276598-tm0yj2sn	821	11	3	3	CD
cord-276598-tm0yj2sn	821	12	P	p	NN
cord-276598-tm0yj2sn	821	13	(	(	-LRB-
cord-276598-tm0yj2sn	821	14	R	r	NN
cord-276598-tm0yj2sn	821	15	=	=	NN
cord-276598-tm0yj2sn	821	16	alkyl	alkyl	NN
cord-276598-tm0yj2sn	821	17	)	)	-RRB-
cord-276598-tm0yj2sn	821	18	and	and	CC
cord-276598-tm0yj2sn	821	19	the	the	DT
cord-276598-tm0yj2sn	821	20	organic	organic	JJ
cord-276598-tm0yj2sn	821	21	azide	azide	NN
cord-276598-tm0yj2sn	821	22	gives	give	VBZ
cord-276598-tm0yj2sn	821	23	phosphorimidate	phosphorimidate	NNP
cord-276598-tm0yj2sn	821	24	(	(	-LRB-
cord-276598-tm0yj2sn	821	25	with	with	IN
cord-276598-tm0yj2sn	821	26	loss	loss	NN
cord-276598-tm0yj2sn	821	27	of	of	IN
cord-276598-tm0yj2sn	821	28	N	n	CD
cord-276598-tm0yj2sn	821	29	2	2	CD
cord-276598-tm0yj2sn	821	30	)	)	-RRB-
cord-276598-tm0yj2sn	821	31	,	,	,
cord-276598-tm0yj2sn	821	32	which	which	WDT
cord-276598-tm0yj2sn	821	33	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	821	34	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	821	35	to	to	TO
cord-276598-tm0yj2sn	821	36	afford	afford	VB
cord-276598-tm0yj2sn	821	37	the	the	DT
cord-276598-tm0yj2sn	821	38	desired	desire	VBN
cord-276598-tm0yj2sn	821	39	product	product	NN
cord-276598-tm0yj2sn	821	40	,	,	,
cord-276598-tm0yj2sn	821	41	while	while	IN
cord-276598-tm0yj2sn	821	42	the	the	DT
cord-276598-tm0yj2sn	821	43	Cu(I	Cu(I	NNP
cord-276598-tm0yj2sn	821	44	)	)	-RRB-
cord-276598-tm0yj2sn	821	45	is	be	VBZ
cord-276598-tm0yj2sn	821	46	reoxidized	reoxidize	VBN
cord-276598-tm0yj2sn	821	47	to	to	IN
cord-276598-tm0yj2sn	821	48	Cu(II	Cu(II	NNP
cord-276598-tm0yj2sn	821	49	)	)	-RRB-
cord-276598-tm0yj2sn	821	50	in	in	IN
cord-276598-tm0yj2sn	821	51	the	the	DT
cord-276598-tm0yj2sn	821	52	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	821	53	cycle	cycle	NN
cord-276598-tm0yj2sn	821	54	.	.	.
cord-276598-tm0yj2sn	822	1	Although	although	IN
cord-276598-tm0yj2sn	822	2	the	the	DT
cord-276598-tm0yj2sn	822	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	822	4	satisfies	satisfy	VBZ
cord-276598-tm0yj2sn	822	5	much	much	JJ
cord-276598-tm0yj2sn	822	6	of	of	IN
cord-276598-tm0yj2sn	822	7	the	the	DT
cord-276598-tm0yj2sn	822	8	observed	observed	JJ
cord-276598-tm0yj2sn	822	9	results	result	NNS
cord-276598-tm0yj2sn	822	10	,	,	,
cord-276598-tm0yj2sn	822	11	the	the	DT
cord-276598-tm0yj2sn	822	12	proposed	propose	VBN
cord-276598-tm0yj2sn	822	13	second	second	JJ
cord-276598-tm0yj2sn	822	14	step	step	NN
cord-276598-tm0yj2sn	822	15	,	,	,
cord-276598-tm0yj2sn	822	16	transmetalation	transmetalation	NN
cord-276598-tm0yj2sn	822	17	,	,	,
cord-276598-tm0yj2sn	822	18	would	would	MD
cord-276598-tm0yj2sn	822	19	have	have	VB
cord-276598-tm0yj2sn	822	20	resulted	result	VBN
cord-276598-tm0yj2sn	822	21	in	in	IN
cord-276598-tm0yj2sn	822	22	borazidic	borazidic	NN
cord-276598-tm0yj2sn	822	23	acid	acid	NN
cord-276598-tm0yj2sn	822	24	(	(	-LRB-
cord-276598-tm0yj2sn	822	25	i.e.	i.e.	FW
cord-276598-tm0yj2sn	822	26	,	,	,
cord-276598-tm0yj2sn	822	27	N	n	NN
cord-276598-tm0yj2sn	822	28	3	3	CD
cord-276598-tm0yj2sn	822	29	-B(OH	-B(OH	.
cord-276598-tm0yj2sn	822	30	)	)	-RRB-
cord-276598-tm0yj2sn	822	31	2	2	CD
cord-276598-tm0yj2sn	822	32	)	)	-RRB-
cord-276598-tm0yj2sn	822	33	and	and	CC
cord-276598-tm0yj2sn	822	34	Cu(II)-phenyl	Cu(II)-phenyl	NNP
cord-276598-tm0yj2sn	822	35	species	specie	NNS
cord-276598-tm0yj2sn	822	36	or	or	CC
cord-276598-tm0yj2sn	822	37	Cu(OH	Cu(OH	NNS
cord-276598-tm0yj2sn	822	38	)	)	-RRB-
cord-276598-tm0yj2sn	822	39	2	2	CD
cord-276598-tm0yj2sn	822	40	species	specie	NNS
cord-276598-tm0yj2sn	822	41	when	when	WRB
cord-276598-tm0yj2sn	822	42	the	the	DT
cord-276598-tm0yj2sn	822	43	azidocopper(II	azidocopper(II	NNP
cord-276598-tm0yj2sn	822	44	)	)	-RRB-
cord-276598-tm0yj2sn	822	45	species	specie	NNS
cord-276598-tm0yj2sn	822	46	reacted	react	VBD
cord-276598-tm0yj2sn	822	47	with	with	IN
cord-276598-tm0yj2sn	822	48	phenylboronic	phenylboronic	JJ
cord-276598-tm0yj2sn	822	49	acid	acid	NN
cord-276598-tm0yj2sn	822	50	-	-	HYPH
cord-276598-tm0yj2sn	822	51	based	base	VBN
cord-276598-tm0yj2sn	822	52	substrates	substrate	NNS
cord-276598-tm0yj2sn	822	53	,	,	,
cord-276598-tm0yj2sn	822	54	based	base	VBN
cord-276598-tm0yj2sn	822	55	on	on	IN
cord-276598-tm0yj2sn	822	56	the	the	DT
cord-276598-tm0yj2sn	822	57	exchange	exchange	NN
cord-276598-tm0yj2sn	822	58	of	of	IN
cord-276598-tm0yj2sn	822	59	ligands	ligand	NNS
cord-276598-tm0yj2sn	822	60	as	as	IN
cord-276598-tm0yj2sn	822	61	in	in	IN
cord-276598-tm0yj2sn	822	62	the	the	DT
cord-276598-tm0yj2sn	822	63	first	first	JJ
cord-276598-tm0yj2sn	822	64	step	step	NN
cord-276598-tm0yj2sn	822	65	.	.	.
cord-276598-tm0yj2sn	823	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	823	2	2020	2020	CD
cord-276598-tm0yj2sn	823	3	,	,	,
cord-276598-tm0yj2sn	823	4	25	25	CD
cord-276598-tm0yj2sn	823	5	,	,	,
cord-276598-tm0yj2sn	823	6	x	x	NN
cord-276598-tm0yj2sn	823	7	FOR	for	IN
cord-276598-tm0yj2sn	823	8	PEER	peer	NN
cord-276598-tm0yj2sn	823	9	REVIEW	REVIEW	NNP
cord-276598-tm0yj2sn	823	10	25	25	CD
cord-276598-tm0yj2sn	823	11	of	of	IN
cord-276598-tm0yj2sn	823	12	37	37	CD
cord-276598-tm0yj2sn	823	13	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	823	14	30	30	CD
cord-276598-tm0yj2sn	823	15	.	.	.
cord-276598-tm0yj2sn	824	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	824	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	824	3	of	of	IN
cord-276598-tm0yj2sn	824	4	the	the	DT
cord-276598-tm0yj2sn	824	5	Cu	cu	JJ
cord-276598-tm0yj2sn	824	6	-	-	HYPH
cord-276598-tm0yj2sn	824	7	catalyzed	catalyzed	JJ
cord-276598-tm0yj2sn	824	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	824	9	of	of	IN
cord-276598-tm0yj2sn	824	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	824	11	from	from	IN
cord-276598-tm0yj2sn	824	12	phenylboronic	phenylboronic	NNP
cord-276598-tm0yj2sn	824	13	acid	acid	NNP
cord-276598-tm0yj2sn	824	14	/	/	SYM
cord-276598-tm0yj2sn	824	15	ester	ester	NN
cord-276598-tm0yj2sn	824	16	-	-	HYPH
cord-276598-tm0yj2sn	824	17	based	base	VBN
cord-276598-tm0yj2sn	824	18	substrates	substrate	NNS
cord-276598-tm0yj2sn	824	19	and	and	CC
cord-276598-tm0yj2sn	824	20	trialkyl	trialkyl	NNP
cord-276598-tm0yj2sn	824	21	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	824	22	.	.	.
cord-276598-tm0yj2sn	825	1	In	in	IN
cord-276598-tm0yj2sn	825	2	a	a	DT
cord-276598-tm0yj2sn	825	3	suggested	suggest	VBN
cord-276598-tm0yj2sn	825	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	825	5	for	for	IN
cord-276598-tm0yj2sn	825	6	the	the	DT
cord-276598-tm0yj2sn	825	7	organophotocatalytic	organophotocatalytic	JJ
cord-276598-tm0yj2sn	825	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	825	9	of	of	IN
cord-276598-tm0yj2sn	825	10	P	P	NNP
cord-276598-tm0yj2sn	825	11	-	-	HYPH
cord-276598-tm0yj2sn	825	12	N	N	NNP
cord-276598-tm0yj2sn	825	13	,	,	,
cord-276598-tm0yj2sn	825	14	a	a	DT
cord-276598-tm0yj2sn	825	15	photon	photon	NN
cord-276598-tm0yj2sn	825	16	from	from	IN
cord-276598-tm0yj2sn	825	17	the	the	DT
cord-276598-tm0yj2sn	825	18	visible	visible	JJ
cord-276598-tm0yj2sn	825	19	light	light	JJ
cord-276598-tm0yj2sn	825	20	source	source	NN
cord-276598-tm0yj2sn	825	21	is	be	VBZ
cord-276598-tm0yj2sn	825	22	absorbed	absorb	VBN
cord-276598-tm0yj2sn	825	23	by	by	IN
cord-276598-tm0yj2sn	825	24	the	the	DT
cord-276598-tm0yj2sn	825	25	organic	organic	JJ
cord-276598-tm0yj2sn	825	26	dye	dye	NN
cord-276598-tm0yj2sn	825	27	to	to	TO
cord-276598-tm0yj2sn	825	28	become	become	VB
cord-276598-tm0yj2sn	825	29	an	an	DT
cord-276598-tm0yj2sn	825	30	excited	excited	JJ
cord-276598-tm0yj2sn	825	31	radical	radical	JJ
cord-276598-tm0yj2sn	825	32	(	(	-LRB-
cord-276598-tm0yj2sn	825	33	Scheme	scheme	NN
cord-276598-tm0yj2sn	825	34	31	31	CD
cord-276598-tm0yj2sn	825	35	)	)	-RRB-
cord-276598-tm0yj2sn	825	36	[	[	-LRB-
cord-276598-tm0yj2sn	825	37	110	110	CD
cord-276598-tm0yj2sn	825	38	]	]	-RRB-
cord-276598-tm0yj2sn	825	39	.	.	.
cord-276598-tm0yj2sn	826	1	By	by	IN
cord-276598-tm0yj2sn	826	2	a	a	DT
cord-276598-tm0yj2sn	826	3	single	single	JJ
cord-276598-tm0yj2sn	826	4	-	-	HYPH
cord-276598-tm0yj2sn	826	5	electron	electron	NN
cord-276598-tm0yj2sn	826	6	transfer	transfer	NN
cord-276598-tm0yj2sn	826	7	process	process	NN
cord-276598-tm0yj2sn	826	8	,	,	,
cord-276598-tm0yj2sn	826	9	the	the	DT
cord-276598-tm0yj2sn	826	10	excited	excited	JJ
cord-276598-tm0yj2sn	826	11	dye	dye	NN
cord-276598-tm0yj2sn	826	12	-	-	HYPH
cord-276598-tm0yj2sn	826	13	radical	radical	JJ
cord-276598-tm0yj2sn	826	14	abstracts	abstract	NNS
cord-276598-tm0yj2sn	826	15	an	an	DT
cord-276598-tm0yj2sn	826	16	electron	electron	NN
cord-276598-tm0yj2sn	826	17	from	from	IN
cord-276598-tm0yj2sn	826	18	the	the	DT
cord-276598-tm0yj2sn	826	19	N	n	CD
cord-276598-tm0yj2sn	826	20	atom	atom	NN
cord-276598-tm0yj2sn	826	21	of	of	IN
cord-276598-tm0yj2sn	826	22	the	the	DT
cord-276598-tm0yj2sn	826	23	amine	amine	NN
cord-276598-tm0yj2sn	826	24	to	to	TO
cord-276598-tm0yj2sn	826	25	form	form	VB
cord-276598-tm0yj2sn	826	26	an	an	DT
cord-276598-tm0yj2sn	826	27	anionic	anionic	JJ
cord-276598-tm0yj2sn	826	28	dye	dye	NN
cord-276598-tm0yj2sn	826	29	radical	radical	JJ
cord-276598-tm0yj2sn	826	30	and	and	CC
cord-276598-tm0yj2sn	826	31	cationic	cationic	JJ
cord-276598-tm0yj2sn	826	32	amine	amine	NN
cord-276598-tm0yj2sn	826	33	radical	radical	JJ
cord-276598-tm0yj2sn	826	34	.	.	.
cord-276598-tm0yj2sn	827	1	In	in	IN
cord-276598-tm0yj2sn	827	2	the	the	DT
cord-276598-tm0yj2sn	827	3	presence	presence	NN
cord-276598-tm0yj2sn	827	4	of	of	IN
cord-276598-tm0yj2sn	827	5	O2	O2	NNP
cord-276598-tm0yj2sn	827	6	,	,	,
cord-276598-tm0yj2sn	827	7	the	the	DT
cord-276598-tm0yj2sn	827	8	anionic	anionic	JJ
cord-276598-tm0yj2sn	827	9	dye	dye	NN
cord-276598-tm0yj2sn	827	10	radical	radical	JJ
cord-276598-tm0yj2sn	827	11	is	be	VBZ
cord-276598-tm0yj2sn	827	12	reoxidized	reoxidize	VBN
cord-276598-tm0yj2sn	827	13	to	to	IN
cord-276598-tm0yj2sn	827	14	the	the	DT
cord-276598-tm0yj2sn	827	15	organic	organic	JJ
cord-276598-tm0yj2sn	827	16	dye	dye	NN
cord-276598-tm0yj2sn	827	17	,	,	,
cord-276598-tm0yj2sn	827	18	while	while	IN
cord-276598-tm0yj2sn	827	19	the	the	DT
cord-276598-tm0yj2sn	827	20	anionic	anionic	JJ
cord-276598-tm0yj2sn	827	21	superoxide	superoxide	NN
cord-276598-tm0yj2sn	827	22	that	that	WDT
cord-276598-tm0yj2sn	827	23	is	be	VBZ
cord-276598-tm0yj2sn	827	24	formed	form	VBN
cord-276598-tm0yj2sn	827	25	in	in	IN
cord-276598-tm0yj2sn	827	26	the	the	DT
cord-276598-tm0yj2sn	827	27	process	process	NN
cord-276598-tm0yj2sn	827	28	reacts	react	VBZ
cord-276598-tm0yj2sn	827	29	with	with	IN
cord-276598-tm0yj2sn	827	30	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	827	31	H	H	NNP
cord-276598-tm0yj2sn	827	32	-	-	HYPH
cord-276598-tm0yj2sn	827	33	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	827	34	(	(	-LRB-
cord-276598-tm0yj2sn	827	35	H	h	NN
cord-276598-tm0yj2sn	827	36	-	-	HYPH
cord-276598-tm0yj2sn	827	37	P	p	NN
cord-276598-tm0yj2sn	827	38	)	)	-RRB-
cord-276598-tm0yj2sn	827	39	to	to	TO
cord-276598-tm0yj2sn	827	40	generate	generate	VB
cord-276598-tm0yj2sn	827	41	anionic	anionic	JJ
cord-276598-tm0yj2sn	827	42	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	827	43	peroxide	peroxide	NN
cord-276598-tm0yj2sn	827	44	and	and	CC
cord-276598-tm0yj2sn	827	45	a	a	DT
cord-276598-tm0yj2sn	827	46	diethyl	diethyl	NN
cord-276598-tm0yj2sn	827	47	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	827	48	radical	radical	JJ
cord-276598-tm0yj2sn	827	49	.	.	.
cord-276598-tm0yj2sn	828	1	Then	then	RB
cord-276598-tm0yj2sn	828	2	,	,	,
cord-276598-tm0yj2sn	828	3	the	the	DT
cord-276598-tm0yj2sn	828	4	radical	radical	JJ
cord-276598-tm0yj2sn	828	5	reacts	react	VBZ
cord-276598-tm0yj2sn	828	6	with	with	IN
cord-276598-tm0yj2sn	828	7	the	the	DT
cord-276598-tm0yj2sn	828	8	cationic	cationic	JJ
cord-276598-tm0yj2sn	828	9	-	-	HYPH
cord-276598-tm0yj2sn	828	10	amine	amine	NN
cord-276598-tm0yj2sn	828	11	radical	radical	JJ
cord-276598-tm0yj2sn	828	12	to	to	TO
cord-276598-tm0yj2sn	828	13	form	form	VB
cord-276598-tm0yj2sn	828	14	a	a	DT
cord-276598-tm0yj2sn	828	15	protonated	protonated	JJ
cord-276598-tm0yj2sn	828	16	P	p	NN
cord-276598-tm0yj2sn	828	17	-	-	HYPH
cord-276598-tm0yj2sn	828	18	N	N	NNP
cord-276598-tm0yj2sn	828	19	,	,	,
cord-276598-tm0yj2sn	828	20	which	which	WDT
cord-276598-tm0yj2sn	828	21	is	be	VBZ
cord-276598-tm0yj2sn	828	22	then	then	RB
cord-276598-tm0yj2sn	828	23	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	828	24	by	by	IN
cord-276598-tm0yj2sn	828	25	the	the	DT
cord-276598-tm0yj2sn	828	26	anionic	anionic	JJ
cord-276598-tm0yj2sn	828	27	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	828	28	peroxide	peroxide	NN
cord-276598-tm0yj2sn	828	29	.	.	.
cord-276598-tm0yj2sn	829	1	The	the	DT
cord-276598-tm0yj2sn	829	2	authors	author	NNS
cord-276598-tm0yj2sn	829	3	reported	report	VBD
cord-276598-tm0yj2sn	829	4	that	that	IN
cord-276598-tm0yj2sn	829	5	after	after	IN
cord-276598-tm0yj2sn	829	6	an	an	DT
cord-276598-tm0yj2sn	829	7	initial	initial	JJ
cord-276598-tm0yj2sn	829	8	74	74	CD
cord-276598-tm0yj2sn	829	9	%	%	NN
cord-276598-tm0yj2sn	829	10	isolated	isolated	JJ
cord-276598-tm0yj2sn	829	11	product	product	NN
cord-276598-tm0yj2sn	829	12	,	,	,
cord-276598-tm0yj2sn	829	13	the	the	DT
cord-276598-tm0yj2sn	829	14	organic	organic	JJ
cord-276598-tm0yj2sn	829	15	dye	dye	NN
cord-276598-tm0yj2sn	829	16	catalyst	catalyst	NN
cord-276598-tm0yj2sn	829	17	was	be	VBD
cord-276598-tm0yj2sn	829	18	recycled	recycle	VBN
cord-276598-tm0yj2sn	829	19	a	a	DT
cord-276598-tm0yj2sn	829	20	second	second	JJ
cord-276598-tm0yj2sn	829	21	time	time	NN
cord-276598-tm0yj2sn	829	22	using	use	VBG
cord-276598-tm0yj2sn	829	23	an	an	DT
cord-276598-tm0yj2sn	829	24	acid	acid	NN
cord-276598-tm0yj2sn	829	25	-	-	HYPH
cord-276598-tm0yj2sn	829	26	base	base	NN
cord-276598-tm0yj2sn	829	27	extraction	extraction	NN
cord-276598-tm0yj2sn	829	28	,	,	,
cord-276598-tm0yj2sn	829	29	and	and	CC
cord-276598-tm0yj2sn	829	30	67	67	CD
cord-276598-tm0yj2sn	829	31	%	%	NN
cord-276598-tm0yj2sn	829	32	isolated	isolated	JJ
cord-276598-tm0yj2sn	829	33	product	product	NN
cord-276598-tm0yj2sn	829	34	was	be	VBD
cord-276598-tm0yj2sn	829	35	obtained	obtain	VBN
cord-276598-tm0yj2sn	829	36	the	the	DT
cord-276598-tm0yj2sn	829	37	second	second	JJ
cord-276598-tm0yj2sn	829	38	time	time	NN
cord-276598-tm0yj2sn	829	39	.	.	.
cord-276598-tm0yj2sn	830	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	830	2	30	30	CD
cord-276598-tm0yj2sn	830	3	.	.	.
cord-276598-tm0yj2sn	831	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	831	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	831	3	of	of	IN
cord-276598-tm0yj2sn	831	4	the	the	DT
cord-276598-tm0yj2sn	831	5	Cu	cu	JJ
cord-276598-tm0yj2sn	831	6	-	-	HYPH
cord-276598-tm0yj2sn	831	7	catalyzed	catalyzed	JJ
cord-276598-tm0yj2sn	831	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	831	9	of	of	IN
cord-276598-tm0yj2sn	831	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	831	11	from	from	IN
cord-276598-tm0yj2sn	831	12	phenylboronic	phenylboronic	NNP
cord-276598-tm0yj2sn	831	13	acid	acid	NNP
cord-276598-tm0yj2sn	831	14	/	/	SYM
cord-276598-tm0yj2sn	831	15	ester	ester	NN
cord-276598-tm0yj2sn	831	16	-	-	HYPH
cord-276598-tm0yj2sn	831	17	based	base	VBN
cord-276598-tm0yj2sn	831	18	substrates	substrate	NNS
cord-276598-tm0yj2sn	831	19	and	and	CC
cord-276598-tm0yj2sn	831	20	trialkyl	trialkyl	NNP
cord-276598-tm0yj2sn	831	21	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	831	22	.	.	.
cord-276598-tm0yj2sn	832	1	In	in	IN
cord-276598-tm0yj2sn	832	2	a	a	DT
cord-276598-tm0yj2sn	832	3	suggested	suggest	VBN
cord-276598-tm0yj2sn	832	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	832	5	for	for	IN
cord-276598-tm0yj2sn	832	6	the	the	DT
cord-276598-tm0yj2sn	832	7	organophotocatalytic	organophotocatalytic	JJ
cord-276598-tm0yj2sn	832	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	832	9	of	of	IN
cord-276598-tm0yj2sn	832	10	P	P	NNP
cord-276598-tm0yj2sn	832	11	-	-	HYPH
cord-276598-tm0yj2sn	832	12	N	N	NNP
cord-276598-tm0yj2sn	832	13	,	,	,
cord-276598-tm0yj2sn	832	14	a	a	DT
cord-276598-tm0yj2sn	832	15	photon	photon	NN
cord-276598-tm0yj2sn	832	16	from	from	IN
cord-276598-tm0yj2sn	832	17	the	the	DT
cord-276598-tm0yj2sn	832	18	visible	visible	JJ
cord-276598-tm0yj2sn	832	19	light	light	JJ
cord-276598-tm0yj2sn	832	20	source	source	NN
cord-276598-tm0yj2sn	832	21	is	be	VBZ
cord-276598-tm0yj2sn	832	22	absorbed	absorb	VBN
cord-276598-tm0yj2sn	832	23	by	by	IN
cord-276598-tm0yj2sn	832	24	the	the	DT
cord-276598-tm0yj2sn	832	25	organic	organic	JJ
cord-276598-tm0yj2sn	832	26	dye	dye	NN
cord-276598-tm0yj2sn	832	27	to	to	TO
cord-276598-tm0yj2sn	832	28	become	become	VB
cord-276598-tm0yj2sn	832	29	an	an	DT
cord-276598-tm0yj2sn	832	30	excited	excited	JJ
cord-276598-tm0yj2sn	832	31	radical	radical	JJ
cord-276598-tm0yj2sn	832	32	(	(	-LRB-
cord-276598-tm0yj2sn	832	33	Scheme	scheme	NN
cord-276598-tm0yj2sn	832	34	31	31	CD
cord-276598-tm0yj2sn	832	35	)	)	-RRB-
cord-276598-tm0yj2sn	832	36	[	[	-LRB-
cord-276598-tm0yj2sn	832	37	110	110	CD
cord-276598-tm0yj2sn	832	38	]	]	-RRB-
cord-276598-tm0yj2sn	832	39	.	.	.
cord-276598-tm0yj2sn	833	1	By	by	IN
cord-276598-tm0yj2sn	833	2	a	a	DT
cord-276598-tm0yj2sn	833	3	single	single	JJ
cord-276598-tm0yj2sn	833	4	-	-	HYPH
cord-276598-tm0yj2sn	833	5	electron	electron	NN
cord-276598-tm0yj2sn	833	6	transfer	transfer	NN
cord-276598-tm0yj2sn	833	7	process	process	NN
cord-276598-tm0yj2sn	833	8	,	,	,
cord-276598-tm0yj2sn	833	9	the	the	DT
cord-276598-tm0yj2sn	833	10	excited	excited	JJ
cord-276598-tm0yj2sn	833	11	dye	dye	NN
cord-276598-tm0yj2sn	833	12	-	-	HYPH
cord-276598-tm0yj2sn	833	13	radical	radical	JJ
cord-276598-tm0yj2sn	833	14	abstracts	abstract	NNS
cord-276598-tm0yj2sn	833	15	an	an	DT
cord-276598-tm0yj2sn	833	16	electron	electron	NN
cord-276598-tm0yj2sn	833	17	from	from	IN
cord-276598-tm0yj2sn	833	18	the	the	DT
cord-276598-tm0yj2sn	833	19	N	n	CD
cord-276598-tm0yj2sn	833	20	atom	atom	NN
cord-276598-tm0yj2sn	833	21	of	of	IN
cord-276598-tm0yj2sn	833	22	the	the	DT
cord-276598-tm0yj2sn	833	23	amine	amine	NN
cord-276598-tm0yj2sn	833	24	to	to	TO
cord-276598-tm0yj2sn	833	25	form	form	VB
cord-276598-tm0yj2sn	833	26	an	an	DT
cord-276598-tm0yj2sn	833	27	anionic	anionic	JJ
cord-276598-tm0yj2sn	833	28	dye	dye	NN
cord-276598-tm0yj2sn	833	29	radical	radical	JJ
cord-276598-tm0yj2sn	833	30	and	and	CC
cord-276598-tm0yj2sn	833	31	cationic	cationic	JJ
cord-276598-tm0yj2sn	833	32	amine	amine	NN
cord-276598-tm0yj2sn	833	33	radical	radical	JJ
cord-276598-tm0yj2sn	833	34	.	.	.
cord-276598-tm0yj2sn	834	1	In	in	IN
cord-276598-tm0yj2sn	834	2	the	the	DT
cord-276598-tm0yj2sn	834	3	presence	presence	NN
cord-276598-tm0yj2sn	834	4	of	of	IN
cord-276598-tm0yj2sn	834	5	O	o	NN
cord-276598-tm0yj2sn	834	6	2	2	CD
cord-276598-tm0yj2sn	834	7	,	,	,
cord-276598-tm0yj2sn	834	8	the	the	DT
cord-276598-tm0yj2sn	834	9	anionic	anionic	JJ
cord-276598-tm0yj2sn	834	10	dye	dye	NN
cord-276598-tm0yj2sn	834	11	radical	radical	JJ
cord-276598-tm0yj2sn	834	12	is	be	VBZ
cord-276598-tm0yj2sn	834	13	reoxidized	reoxidize	VBN
cord-276598-tm0yj2sn	834	14	to	to	IN
cord-276598-tm0yj2sn	834	15	the	the	DT
cord-276598-tm0yj2sn	834	16	organic	organic	JJ
cord-276598-tm0yj2sn	834	17	dye	dye	NN
cord-276598-tm0yj2sn	834	18	,	,	,
cord-276598-tm0yj2sn	834	19	while	while	IN
cord-276598-tm0yj2sn	834	20	the	the	DT
cord-276598-tm0yj2sn	834	21	anionic	anionic	JJ
cord-276598-tm0yj2sn	834	22	superoxide	superoxide	NN
cord-276598-tm0yj2sn	834	23	that	that	WDT
cord-276598-tm0yj2sn	834	24	is	be	VBZ
cord-276598-tm0yj2sn	834	25	formed	form	VBN
cord-276598-tm0yj2sn	834	26	in	in	IN
cord-276598-tm0yj2sn	834	27	the	the	DT
cord-276598-tm0yj2sn	834	28	process	process	NN
cord-276598-tm0yj2sn	834	29	reacts	react	VBZ
cord-276598-tm0yj2sn	834	30	with	with	IN
cord-276598-tm0yj2sn	834	31	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	834	32	H	H	NNP
cord-276598-tm0yj2sn	834	33	-	-	HYPH
cord-276598-tm0yj2sn	834	34	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	834	35	(	(	-LRB-
cord-276598-tm0yj2sn	834	36	H	h	NN
cord-276598-tm0yj2sn	834	37	-	-	HYPH
cord-276598-tm0yj2sn	834	38	P	p	NN
cord-276598-tm0yj2sn	834	39	)	)	-RRB-
cord-276598-tm0yj2sn	834	40	to	to	TO
cord-276598-tm0yj2sn	834	41	generate	generate	VB
cord-276598-tm0yj2sn	834	42	anionic	anionic	JJ
cord-276598-tm0yj2sn	834	43	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	834	44	peroxide	peroxide	NN
cord-276598-tm0yj2sn	834	45	and	and	CC
cord-276598-tm0yj2sn	834	46	a	a	DT
cord-276598-tm0yj2sn	834	47	diethyl	diethyl	NN
cord-276598-tm0yj2sn	834	48	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	834	49	radical	radical	JJ
cord-276598-tm0yj2sn	834	50	.	.	.
cord-276598-tm0yj2sn	835	1	Then	then	RB
cord-276598-tm0yj2sn	835	2	,	,	,
cord-276598-tm0yj2sn	835	3	the	the	DT
cord-276598-tm0yj2sn	835	4	radical	radical	JJ
cord-276598-tm0yj2sn	835	5	reacts	react	VBZ
cord-276598-tm0yj2sn	835	6	with	with	IN
cord-276598-tm0yj2sn	835	7	the	the	DT
cord-276598-tm0yj2sn	835	8	cationic	cationic	JJ
cord-276598-tm0yj2sn	835	9	-	-	HYPH
cord-276598-tm0yj2sn	835	10	amine	amine	NN
cord-276598-tm0yj2sn	835	11	radical	radical	JJ
cord-276598-tm0yj2sn	835	12	to	to	TO
cord-276598-tm0yj2sn	835	13	form	form	VB
cord-276598-tm0yj2sn	835	14	a	a	DT
cord-276598-tm0yj2sn	835	15	protonated	protonated	JJ
cord-276598-tm0yj2sn	835	16	P	p	NN
cord-276598-tm0yj2sn	835	17	-	-	HYPH
cord-276598-tm0yj2sn	835	18	N	N	NNP
cord-276598-tm0yj2sn	835	19	,	,	,
cord-276598-tm0yj2sn	835	20	which	which	WDT
cord-276598-tm0yj2sn	835	21	is	be	VBZ
cord-276598-tm0yj2sn	835	22	then	then	RB
cord-276598-tm0yj2sn	835	23	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	835	24	by	by	IN
cord-276598-tm0yj2sn	835	25	the	the	DT
cord-276598-tm0yj2sn	835	26	anionic	anionic	JJ
cord-276598-tm0yj2sn	835	27	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	835	28	peroxide	peroxide	NN
cord-276598-tm0yj2sn	835	29	.	.	.
cord-276598-tm0yj2sn	836	1	The	the	DT
cord-276598-tm0yj2sn	836	2	authors	author	NNS
cord-276598-tm0yj2sn	836	3	reported	report	VBD
cord-276598-tm0yj2sn	836	4	that	that	IN
cord-276598-tm0yj2sn	836	5	after	after	IN
cord-276598-tm0yj2sn	836	6	an	an	DT
cord-276598-tm0yj2sn	836	7	initial	initial	JJ
cord-276598-tm0yj2sn	836	8	74	74	CD
cord-276598-tm0yj2sn	836	9	%	%	NN
cord-276598-tm0yj2sn	836	10	isolated	isolated	JJ
cord-276598-tm0yj2sn	836	11	product	product	NN
cord-276598-tm0yj2sn	836	12	,	,	,
cord-276598-tm0yj2sn	836	13	the	the	DT
cord-276598-tm0yj2sn	836	14	organic	organic	JJ
cord-276598-tm0yj2sn	836	15	dye	dye	NN
cord-276598-tm0yj2sn	836	16	catalyst	catalyst	NN
cord-276598-tm0yj2sn	836	17	was	be	VBD
cord-276598-tm0yj2sn	836	18	recycled	recycle	VBN
cord-276598-tm0yj2sn	836	19	a	a	DT
cord-276598-tm0yj2sn	836	20	second	second	JJ
cord-276598-tm0yj2sn	836	21	time	time	NN
cord-276598-tm0yj2sn	836	22	using	use	VBG
cord-276598-tm0yj2sn	836	23	an	an	DT
cord-276598-tm0yj2sn	836	24	acid	acid	NN
cord-276598-tm0yj2sn	836	25	-	-	HYPH
cord-276598-tm0yj2sn	836	26	base	base	NN
cord-276598-tm0yj2sn	836	27	extraction	extraction	NN
cord-276598-tm0yj2sn	836	28	,	,	,
cord-276598-tm0yj2sn	836	29	and	and	CC
cord-276598-tm0yj2sn	836	30	67	67	CD
cord-276598-tm0yj2sn	836	31	%	%	NN
cord-276598-tm0yj2sn	836	32	isolated	isolated	JJ
cord-276598-tm0yj2sn	836	33	product	product	NN
cord-276598-tm0yj2sn	836	34	was	be	VBD
cord-276598-tm0yj2sn	836	35	obtained	obtain	VBN
cord-276598-tm0yj2sn	836	36	the	the	DT
cord-276598-tm0yj2sn	836	37	second	second	JJ
cord-276598-tm0yj2sn	836	38	time	time	NN
cord-276598-tm0yj2sn	836	39	.	.	.
cord-276598-tm0yj2sn	837	1	the	the	DT
cord-276598-tm0yj2sn	837	2	amine	amine	NN
cord-276598-tm0yj2sn	837	3	to	to	TO
cord-276598-tm0yj2sn	837	4	form	form	VB
cord-276598-tm0yj2sn	837	5	an	an	DT
cord-276598-tm0yj2sn	837	6	anionic	anionic	JJ
cord-276598-tm0yj2sn	837	7	dye	dye	NN
cord-276598-tm0yj2sn	837	8	radical	radical	JJ
cord-276598-tm0yj2sn	837	9	and	and	CC
cord-276598-tm0yj2sn	837	10	cationic	cationic	JJ
cord-276598-tm0yj2sn	837	11	amine	amine	NN
cord-276598-tm0yj2sn	837	12	radical	radical	JJ
cord-276598-tm0yj2sn	837	13	.	.	.
cord-276598-tm0yj2sn	838	1	In	in	IN
cord-276598-tm0yj2sn	838	2	the	the	DT
cord-276598-tm0yj2sn	838	3	presence	presence	NN
cord-276598-tm0yj2sn	838	4	of	of	IN
cord-276598-tm0yj2sn	838	5	O2	O2	NNP
cord-276598-tm0yj2sn	838	6	,	,	,
cord-276598-tm0yj2sn	838	7	the	the	DT
cord-276598-tm0yj2sn	838	8	anionic	anionic	JJ
cord-276598-tm0yj2sn	838	9	dye	dye	NN
cord-276598-tm0yj2sn	838	10	radical	radical	JJ
cord-276598-tm0yj2sn	838	11	is	be	VBZ
cord-276598-tm0yj2sn	838	12	reoxidized	reoxidize	VBN
cord-276598-tm0yj2sn	838	13	to	to	IN
cord-276598-tm0yj2sn	838	14	the	the	DT
cord-276598-tm0yj2sn	838	15	organic	organic	JJ
cord-276598-tm0yj2sn	838	16	dye	dye	NN
cord-276598-tm0yj2sn	838	17	,	,	,
cord-276598-tm0yj2sn	838	18	while	while	IN
cord-276598-tm0yj2sn	838	19	the	the	DT
cord-276598-tm0yj2sn	838	20	anionic	anionic	JJ
cord-276598-tm0yj2sn	838	21	superoxide	superoxide	NN
cord-276598-tm0yj2sn	838	22	that	that	WDT
cord-276598-tm0yj2sn	838	23	is	be	VBZ
cord-276598-tm0yj2sn	838	24	formed	form	VBN
cord-276598-tm0yj2sn	838	25	in	in	IN
cord-276598-tm0yj2sn	838	26	the	the	DT
cord-276598-tm0yj2sn	838	27	process	process	NN
cord-276598-tm0yj2sn	838	28	reacts	react	VBZ
cord-276598-tm0yj2sn	838	29	with	with	IN
cord-276598-tm0yj2sn	838	30	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	838	31	H	H	NNP
cord-276598-tm0yj2sn	838	32	-	-	HYPH
cord-276598-tm0yj2sn	838	33	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	838	34	(	(	-LRB-
cord-276598-tm0yj2sn	838	35	H	h	NN
cord-276598-tm0yj2sn	838	36	-	-	HYPH
cord-276598-tm0yj2sn	838	37	P	p	NN
cord-276598-tm0yj2sn	838	38	)	)	-RRB-
cord-276598-tm0yj2sn	838	39	to	to	TO
cord-276598-tm0yj2sn	838	40	generate	generate	VB
cord-276598-tm0yj2sn	838	41	anionic	anionic	JJ
cord-276598-tm0yj2sn	838	42	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	838	43	peroxide	peroxide	NN
cord-276598-tm0yj2sn	838	44	and	and	CC
cord-276598-tm0yj2sn	838	45	a	a	DT
cord-276598-tm0yj2sn	838	46	diethyl	diethyl	NN
cord-276598-tm0yj2sn	838	47	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	838	48	radical	radical	JJ
cord-276598-tm0yj2sn	838	49	.	.	.
cord-276598-tm0yj2sn	839	1	Then	then	RB
cord-276598-tm0yj2sn	839	2	,	,	,
cord-276598-tm0yj2sn	839	3	the	the	DT
cord-276598-tm0yj2sn	839	4	radical	radical	JJ
cord-276598-tm0yj2sn	839	5	reacts	react	VBZ
cord-276598-tm0yj2sn	839	6	with	with	IN
cord-276598-tm0yj2sn	839	7	the	the	DT
cord-276598-tm0yj2sn	839	8	cationic	cationic	JJ
cord-276598-tm0yj2sn	839	9	-	-	HYPH
cord-276598-tm0yj2sn	839	10	amine	amine	NN
cord-276598-tm0yj2sn	839	11	radical	radical	JJ
cord-276598-tm0yj2sn	839	12	to	to	TO
cord-276598-tm0yj2sn	839	13	form	form	VB
cord-276598-tm0yj2sn	839	14	a	a	DT
cord-276598-tm0yj2sn	839	15	protonated	protonated	JJ
cord-276598-tm0yj2sn	839	16	P	p	NN
cord-276598-tm0yj2sn	839	17	-	-	HYPH
cord-276598-tm0yj2sn	839	18	N	N	NNP
cord-276598-tm0yj2sn	839	19	,	,	,
cord-276598-tm0yj2sn	839	20	which	which	WDT
cord-276598-tm0yj2sn	839	21	is	be	VBZ
cord-276598-tm0yj2sn	839	22	then	then	RB
cord-276598-tm0yj2sn	839	23	deprotonated	deprotonate	VBN
cord-276598-tm0yj2sn	839	24	by	by	IN
cord-276598-tm0yj2sn	839	25	the	the	DT
cord-276598-tm0yj2sn	839	26	anionic	anionic	JJ
cord-276598-tm0yj2sn	839	27	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	839	28	peroxide	peroxide	NN
cord-276598-tm0yj2sn	839	29	.	.	.
cord-276598-tm0yj2sn	840	1	The	the	DT
cord-276598-tm0yj2sn	840	2	authors	author	NNS
cord-276598-tm0yj2sn	840	3	reported	report	VBD
cord-276598-tm0yj2sn	840	4	that	that	IN
cord-276598-tm0yj2sn	840	5	after	after	IN
cord-276598-tm0yj2sn	840	6	an	an	DT
cord-276598-tm0yj2sn	840	7	initial	initial	JJ
cord-276598-tm0yj2sn	840	8	74	74	CD
cord-276598-tm0yj2sn	840	9	%	%	NN
cord-276598-tm0yj2sn	840	10	isolated	isolated	JJ
cord-276598-tm0yj2sn	840	11	product	product	NN
cord-276598-tm0yj2sn	840	12	,	,	,
cord-276598-tm0yj2sn	840	13	the	the	DT
cord-276598-tm0yj2sn	840	14	organic	organic	JJ
cord-276598-tm0yj2sn	840	15	dye	dye	NN
cord-276598-tm0yj2sn	840	16	catalyst	catalyst	NN
cord-276598-tm0yj2sn	840	17	was	be	VBD
cord-276598-tm0yj2sn	840	18	recycled	recycle	VBN
cord-276598-tm0yj2sn	840	19	a	a	DT
cord-276598-tm0yj2sn	840	20	second	second	JJ
cord-276598-tm0yj2sn	840	21	time	time	NN
cord-276598-tm0yj2sn	840	22	using	use	VBG
cord-276598-tm0yj2sn	840	23	an	an	DT
cord-276598-tm0yj2sn	840	24	acid	acid	NN
cord-276598-tm0yj2sn	840	25	-	-	HYPH
cord-276598-tm0yj2sn	840	26	base	base	NN
cord-276598-tm0yj2sn	840	27	extraction	extraction	NN
cord-276598-tm0yj2sn	840	28	,	,	,
cord-276598-tm0yj2sn	840	29	and	and	CC
cord-276598-tm0yj2sn	840	30	67	67	CD
cord-276598-tm0yj2sn	840	31	%	%	NN
cord-276598-tm0yj2sn	840	32	isolated	isolated	JJ
cord-276598-tm0yj2sn	840	33	product	product	NN
cord-276598-tm0yj2sn	840	34	was	be	VBD
cord-276598-tm0yj2sn	840	35	obtained	obtain	VBN
cord-276598-tm0yj2sn	840	36	the	the	DT
cord-276598-tm0yj2sn	840	37	second	second	JJ
cord-276598-tm0yj2sn	840	38	time	time	NN
cord-276598-tm0yj2sn	840	39	.	.	.
cord-276598-tm0yj2sn	841	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	841	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	841	3	for	for	IN
cord-276598-tm0yj2sn	841	4	the	the	DT
cord-276598-tm0yj2sn	841	5	visible	visible	JJ
cord-276598-tm0yj2sn	841	6	light	light	NN
cord-276598-tm0yj2sn	841	7	and	and	CC
cord-276598-tm0yj2sn	841	8	organic	organic	JJ
cord-276598-tm0yj2sn	841	9	dye	dye	NN
cord-276598-tm0yj2sn	841	10	-	-	HYPH
cord-276598-tm0yj2sn	841	11	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	841	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	841	13	of	of	IN
cord-276598-tm0yj2sn	841	14	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	841	15	.	.	.
cord-276598-tm0yj2sn	842	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	842	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	842	3	for	for	IN
cord-276598-tm0yj2sn	842	4	the	the	DT
cord-276598-tm0yj2sn	842	5	visible	visible	JJ
cord-276598-tm0yj2sn	842	6	light	light	NN
cord-276598-tm0yj2sn	842	7	and	and	CC
cord-276598-tm0yj2sn	842	8	organic	organic	JJ
cord-276598-tm0yj2sn	842	9	dye	dye	NN
cord-276598-tm0yj2sn	842	10	-	-	HYPH
cord-276598-tm0yj2sn	842	11	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	842	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	842	13	of	of	IN
cord-276598-tm0yj2sn	842	14	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	842	15	.	.	.
cord-276598-tm0yj2sn	843	1	In	in	IN
cord-276598-tm0yj2sn	843	2	the	the	DT
cord-276598-tm0yj2sn	843	3	overall	overall	JJ
cord-276598-tm0yj2sn	843	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	843	5	suggested	suggest	VBN
cord-276598-tm0yj2sn	843	6	for	for	IN
cord-276598-tm0yj2sn	843	7	the	the	DT
cord-276598-tm0yj2sn	843	8	alkali	alkali	NN
cord-276598-tm0yj2sn	843	9	-	-	HYPH
cord-276598-tm0yj2sn	843	10	metal	metal	NN
cord-276598-tm0yj2sn	843	11	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	843	12	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	843	13	cross	cross	JJ
cord-276598-tm0yj2sn	843	14	-	-	JJ
cord-276598-tm0yj2sn	843	15	coupling	coupling	JJ
cord-276598-tm0yj2sn	843	16	reaction	reaction	NN
cord-276598-tm0yj2sn	843	17	,	,	,
cord-276598-tm0yj2sn	843	18	a	a	DT
cord-276598-tm0yj2sn	843	19	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	843	20	iodide	iodide	NN
cord-276598-tm0yj2sn	843	21	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	843	22	and	and	CC
cord-276598-tm0yj2sn	843	23	LiOH	LiOH	NNP
cord-276598-tm0yj2sn	843	24	are	be	VBP
cord-276598-tm0yj2sn	843	25	generated	generate	VBN
cord-276598-tm0yj2sn	843	26	in	in	IN
cord-276598-tm0yj2sn	843	27	the	the	DT
cord-276598-tm0yj2sn	843	28	first	first	JJ
cord-276598-tm0yj2sn	843	29	step	step	NN
cord-276598-tm0yj2sn	843	30	from	from	IN
cord-276598-tm0yj2sn	843	31	a	a	DT
cord-276598-tm0yj2sn	843	32	reaction	reaction	NN
cord-276598-tm0yj2sn	843	33	of	of	IN
cord-276598-tm0yj2sn	843	34	LiI	lii	NN
cord-276598-tm0yj2sn	843	35	and	and	CC
cord-276598-tm0yj2sn	843	36	the	the	DT
cord-276598-tm0yj2sn	843	37	H	H	NNP
cord-276598-tm0yj2sn	843	38	-	-	HYPH
cord-276598-tm0yj2sn	843	39	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	843	40	(	(	-LRB-
cord-276598-tm0yj2sn	843	41	H	h	NN
cord-276598-tm0yj2sn	843	42	-	-	HYPH
cord-276598-tm0yj2sn	843	43	P	P	NNP
cord-276598-tm0yj2sn	843	44	)	)	-RRB-
cord-276598-tm0yj2sn	843	45	in	in	IN
cord-276598-tm0yj2sn	843	46	the	the	DT
cord-276598-tm0yj2sn	843	47	presence	presence	NN
cord-276598-tm0yj2sn	843	48	of	of	IN
cord-276598-tm0yj2sn	843	49	aq	aq	NNP
cord-276598-tm0yj2sn	843	50	.	.	.
cord-276598-tm0yj2sn	844	1	TBHP	TBHP	NNP
cord-276598-tm0yj2sn	845	1	(	(	-LRB-
cord-276598-tm0yj2sn	845	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	845	3	32	32	CD
cord-276598-tm0yj2sn	845	4	)	)	-RRB-
cord-276598-tm0yj2sn	845	5	[	[	-LRB-
cord-276598-tm0yj2sn	845	6	111	111	CD
cord-276598-tm0yj2sn	845	7	]	]	-RRB-
cord-276598-tm0yj2sn	845	8	.	.	.
cord-276598-tm0yj2sn	846	1	The	the	DT
cord-276598-tm0yj2sn	846	2	second	second	JJ
cord-276598-tm0yj2sn	846	3	step	step	NN
cord-276598-tm0yj2sn	846	4	involves	involve	VBZ
cord-276598-tm0yj2sn	846	5	the	the	DT
cord-276598-tm0yj2sn	846	6	removal	removal	NN
cord-276598-tm0yj2sn	846	7	of	of	IN
cord-276598-tm0yj2sn	846	8	a	a	DT
cord-276598-tm0yj2sn	846	9	proton	proton	NN
cord-276598-tm0yj2sn	846	10	from	from	IN
cord-276598-tm0yj2sn	846	11	the	the	DT
cord-276598-tm0yj2sn	846	12	amine	amine	NN
cord-276598-tm0yj2sn	846	13	by	by	IN
cord-276598-tm0yj2sn	846	14	the	the	DT
cord-276598-tm0yj2sn	846	15	LiOH	lioh	NN
cord-276598-tm0yj2sn	846	16	to	to	TO
cord-276598-tm0yj2sn	846	17	form	form	VB
cord-276598-tm0yj2sn	846	18	lithium	lithium	NN
cord-276598-tm0yj2sn	846	19	amide	amide	NN
cord-276598-tm0yj2sn	846	20	and	and	CC
cord-276598-tm0yj2sn	846	21	H	h	NN
cord-276598-tm0yj2sn	846	22	2	2	CD
cord-276598-tm0yj2sn	846	23	O	o	NN
cord-276598-tm0yj2sn	846	24	,	,	,
cord-276598-tm0yj2sn	846	25	and	and	CC
cord-276598-tm0yj2sn	846	26	the	the	DT
cord-276598-tm0yj2sn	846	27	desired	desire	VBN
cord-276598-tm0yj2sn	846	28	product	product	NN
cord-276598-tm0yj2sn	846	29	is	be	VBZ
cord-276598-tm0yj2sn	846	30	formed	form	VBN
cord-276598-tm0yj2sn	846	31	in	in	IN
cord-276598-tm0yj2sn	846	32	the	the	DT
cord-276598-tm0yj2sn	846	33	final	final	JJ
cord-276598-tm0yj2sn	846	34	step	step	NN
cord-276598-tm0yj2sn	846	35	from	from	IN
cord-276598-tm0yj2sn	846	36	the	the	DT
cord-276598-tm0yj2sn	846	37	reaction	reaction	NN
cord-276598-tm0yj2sn	846	38	of	of	IN
cord-276598-tm0yj2sn	846	39	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	846	40	iodide	iodide	NN
cord-276598-tm0yj2sn	846	41	and	and	CC
cord-276598-tm0yj2sn	846	42	lithium	lithium	NN
cord-276598-tm0yj2sn	846	43	amide	amide	NN
cord-276598-tm0yj2sn	846	44	.	.	.
cord-276598-tm0yj2sn	846	45	 	 	_SP
cord-276598-tm0yj2sn	847	1	In	in	IN
cord-276598-tm0yj2sn	847	2	the	the	DT
cord-276598-tm0yj2sn	847	3	overall	overall	JJ
cord-276598-tm0yj2sn	847	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	847	5	suggested	suggest	VBN
cord-276598-tm0yj2sn	847	6	for	for	IN
cord-276598-tm0yj2sn	847	7	the	the	DT
cord-276598-tm0yj2sn	847	8	alkali	alkali	NN
cord-276598-tm0yj2sn	847	9	-	-	HYPH
cord-276598-tm0yj2sn	847	10	metal	metal	NN
cord-276598-tm0yj2sn	847	11	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	847	12	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	847	13	cross	cross	JJ
cord-276598-tm0yj2sn	847	14	-	-	JJ
cord-276598-tm0yj2sn	847	15	coupling	coupling	JJ
cord-276598-tm0yj2sn	847	16	reaction	reaction	NN
cord-276598-tm0yj2sn	847	17	,	,	,
cord-276598-tm0yj2sn	847	18	a	a	DT
cord-276598-tm0yj2sn	847	19	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	847	20	iodide	iodide	NN
cord-276598-tm0yj2sn	847	21	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	847	22	and	and	CC
cord-276598-tm0yj2sn	847	23	LiOH	LiOH	NNP
cord-276598-tm0yj2sn	847	24	are	be	VBP
cord-276598-tm0yj2sn	847	25	generated	generate	VBN
cord-276598-tm0yj2sn	847	26	in	in	IN
cord-276598-tm0yj2sn	847	27	the	the	DT
cord-276598-tm0yj2sn	847	28	first	first	JJ
cord-276598-tm0yj2sn	847	29	step	step	NN
cord-276598-tm0yj2sn	847	30	from	from	IN
cord-276598-tm0yj2sn	847	31	a	a	DT
cord-276598-tm0yj2sn	847	32	reaction	reaction	NN
cord-276598-tm0yj2sn	847	33	of	of	IN
cord-276598-tm0yj2sn	847	34	LiI	lii	NN
cord-276598-tm0yj2sn	847	35	and	and	CC
cord-276598-tm0yj2sn	847	36	the	the	DT
cord-276598-tm0yj2sn	847	37	H	H	NNP
cord-276598-tm0yj2sn	847	38	-	-	HYPH
cord-276598-tm0yj2sn	847	39	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	847	40	(	(	-LRB-
cord-276598-tm0yj2sn	847	41	H	h	NN
cord-276598-tm0yj2sn	847	42	-	-	HYPH
cord-276598-tm0yj2sn	847	43	P	P	NNP
cord-276598-tm0yj2sn	847	44	)	)	-RRB-
cord-276598-tm0yj2sn	847	45	in	in	IN
cord-276598-tm0yj2sn	847	46	the	the	DT
cord-276598-tm0yj2sn	847	47	presence	presence	NN
cord-276598-tm0yj2sn	847	48	of	of	IN
cord-276598-tm0yj2sn	847	49	aq	aq	NNP
cord-276598-tm0yj2sn	847	50	.	.	.
cord-276598-tm0yj2sn	848	1	TBHP	TBHP	NNP
cord-276598-tm0yj2sn	849	1	(	(	-LRB-
cord-276598-tm0yj2sn	849	2	Scheme	scheme	NN
cord-276598-tm0yj2sn	849	3	32	32	CD
cord-276598-tm0yj2sn	849	4	)	)	-RRB-
cord-276598-tm0yj2sn	849	5	[	[	-LRB-
cord-276598-tm0yj2sn	849	6	111	111	CD
cord-276598-tm0yj2sn	849	7	]	]	-RRB-
cord-276598-tm0yj2sn	849	8	.	.	.
cord-276598-tm0yj2sn	850	1	The	the	DT
cord-276598-tm0yj2sn	850	2	second	second	JJ
cord-276598-tm0yj2sn	850	3	step	step	NN
cord-276598-tm0yj2sn	850	4	involves	involve	VBZ
cord-276598-tm0yj2sn	850	5	the	the	DT
cord-276598-tm0yj2sn	850	6	removal	removal	NN
cord-276598-tm0yj2sn	850	7	of	of	IN
cord-276598-tm0yj2sn	850	8	a	a	DT
cord-276598-tm0yj2sn	850	9	proton	proton	NN
cord-276598-tm0yj2sn	850	10	from	from	IN
cord-276598-tm0yj2sn	850	11	the	the	DT
cord-276598-tm0yj2sn	850	12	amine	amine	NN
cord-276598-tm0yj2sn	850	13	by	by	IN
cord-276598-tm0yj2sn	850	14	the	the	DT
cord-276598-tm0yj2sn	850	15	LiOH	lioh	NN
cord-276598-tm0yj2sn	850	16	to	to	TO
cord-276598-tm0yj2sn	850	17	form	form	VB
cord-276598-tm0yj2sn	850	18	lithium	lithium	NN
cord-276598-tm0yj2sn	850	19	amide	amide	NN
cord-276598-tm0yj2sn	850	20	and	and	CC
cord-276598-tm0yj2sn	850	21	H2O	h2o	NN
cord-276598-tm0yj2sn	850	22	,	,	,
cord-276598-tm0yj2sn	850	23	and	and	CC
cord-276598-tm0yj2sn	850	24	the	the	DT
cord-276598-tm0yj2sn	850	25	desired	desire	VBN
cord-276598-tm0yj2sn	850	26	product	product	NN
cord-276598-tm0yj2sn	850	27	is	be	VBZ
cord-276598-tm0yj2sn	850	28	formed	form	VBN
cord-276598-tm0yj2sn	850	29	in	in	IN
cord-276598-tm0yj2sn	850	30	the	the	DT
cord-276598-tm0yj2sn	850	31	final	final	JJ
cord-276598-tm0yj2sn	850	32	step	step	NN
cord-276598-tm0yj2sn	850	33	from	from	IN
cord-276598-tm0yj2sn	850	34	the	the	DT
cord-276598-tm0yj2sn	850	35	reaction	reaction	NN
cord-276598-tm0yj2sn	850	36	of	of	IN
cord-276598-tm0yj2sn	850	37	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	850	38	iodide	iodide	NN
cord-276598-tm0yj2sn	850	39	and	and	CC
cord-276598-tm0yj2sn	850	40	lithium	lithium	NN
cord-276598-tm0yj2sn	850	41	amide	amide	NN
cord-276598-tm0yj2sn	850	42	.	.	.
cord-276598-tm0yj2sn	851	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	851	2	32	32	CD
cord-276598-tm0yj2sn	851	3	.	.	.
cord-276598-tm0yj2sn	852	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	852	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	852	3	for	for	IN
cord-276598-tm0yj2sn	852	4	the	the	DT
cord-276598-tm0yj2sn	852	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	852	6	of	of	IN
cord-276598-tm0yj2sn	852	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	852	8	using	use	VBG
cord-276598-tm0yj2sn	852	9	alkali	alkali	NN
cord-276598-tm0yj2sn	852	10	-	-	HYPH
cord-276598-tm0yj2sn	852	11	metal	metal	NN
cord-276598-tm0yj2sn	852	12	catalyst	catalyst	NN
cord-276598-tm0yj2sn	852	13	.	.	.
cord-276598-tm0yj2sn	853	1	The	the	DT
cord-276598-tm0yj2sn	853	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	853	3	of	of	IN
cord-276598-tm0yj2sn	853	4	the	the	DT
cord-276598-tm0yj2sn	853	5	reaction	reaction	NN
cord-276598-tm0yj2sn	853	6	of	of	IN
cord-276598-tm0yj2sn	853	7	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	853	8	insertion	insertion	NN
cord-276598-tm0yj2sn	853	9	according	accord	VBG
cord-276598-tm0yj2sn	853	10	to	to	IN
cord-276598-tm0yj2sn	853	11	Chang	Chang	NNP
cord-276598-tm0yj2sn	853	12	,	,	,
cord-276598-tm0yj2sn	853	13	Kim	Kim	NNP
cord-276598-tm0yj2sn	853	14	,	,	,
cord-276598-tm0yj2sn	853	15	and	and	CC
cord-276598-tm0yj2sn	853	16	coworkers	coworker	NNS
cord-276598-tm0yj2sn	853	17	follows	follow	VBZ
cord-276598-tm0yj2sn	853	18	activation	activation	NN
cord-276598-tm0yj2sn	853	19	of	of	IN
cord-276598-tm0yj2sn	853	20	the	the	DT
cord-276598-tm0yj2sn	853	21	C	C	NNP
cord-276598-tm0yj2sn	853	22	-	-	HYPH
cord-276598-tm0yj2sn	853	23	H	h	NN
cord-276598-tm0yj2sn	853	24	bond	bond	NN
cord-276598-tm0yj2sn	853	25	cleavage	cleavage	NN
cord-276598-tm0yj2sn	853	26	on	on	IN
cord-276598-tm0yj2sn	853	27	the	the	DT
cord-276598-tm0yj2sn	853	28	amide	amide	NN
cord-276598-tm0yj2sn	853	29	or	or	CC
cord-276598-tm0yj2sn	853	30	ketone	ketone	NN
cord-276598-tm0yj2sn	853	31	substrate	substrate	NN
cord-276598-tm0yj2sn	853	32	by	by	IN
cord-276598-tm0yj2sn	853	33	the	the	DT
cord-276598-tm0yj2sn	853	34	Ir	Ir	NNP
cord-276598-tm0yj2sn	853	35	(	(	-LRB-
cord-276598-tm0yj2sn	853	36	III	III	NNP
cord-276598-tm0yj2sn	853	37	)	)	-RRB-
cord-276598-tm0yj2sn	853	38	-based	-based	JJ
cord-276598-tm0yj2sn	853	39	catalyst	catalyst	NN
cord-276598-tm0yj2sn	853	40	to	to	TO
cord-276598-tm0yj2sn	853	41	generate	generate	VB
cord-276598-tm0yj2sn	853	42	an	an	DT
cord-276598-tm0yj2sn	853	43	iridacyclic	iridacyclic	JJ
cord-276598-tm0yj2sn	853	44	intermediate	intermediate	NN
cord-276598-tm0yj2sn	853	45	,	,	,
cord-276598-tm0yj2sn	853	46	which	which	WDT
cord-276598-tm0yj2sn	853	47	then	then	RB
cord-276598-tm0yj2sn	853	48	reacts	react	VBZ
cord-276598-tm0yj2sn	853	49	with	with	IN
cord-276598-tm0yj2sn	853	50	the	the	DT
cord-276598-tm0yj2sn	853	51	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	853	52	azide	azide	NN
cord-276598-tm0yj2sn	853	53	to	to	TO
cord-276598-tm0yj2sn	853	54	produce	produce	VB
cord-276598-tm0yj2sn	853	55	a	a	DT
cord-276598-tm0yj2sn	853	56	coordinated	coordinated	JJ
cord-276598-tm0yj2sn	853	57	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	853	58	azide	azide	NN
cord-276598-tm0yj2sn	853	59	-	-	HYPH
cord-276598-tm0yj2sn	853	60	iridacyclic	iridacyclic	JJ
cord-276598-tm0yj2sn	853	61	adduct	adduct	NN
cord-276598-tm0yj2sn	853	62	(	(	-LRB-
cord-276598-tm0yj2sn	853	63	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	853	64	33	33	CD
cord-276598-tm0yj2sn	853	65	)	)	-RRB-
cord-276598-tm0yj2sn	853	66	[	[	-LRB-
cord-276598-tm0yj2sn	853	67	112	112	CD
cord-276598-tm0yj2sn	853	68	]	]	-RRB-
cord-276598-tm0yj2sn	853	69	.	.	.
cord-276598-tm0yj2sn	854	1	By	by	IN
cord-276598-tm0yj2sn	854	2	intramolecular	intramolecular	JJ
cord-276598-tm0yj2sn	854	3	migratory	migratory	JJ
cord-276598-tm0yj2sn	854	4	insertion	insertion	NN
cord-276598-tm0yj2sn	854	5	of	of	IN
cord-276598-tm0yj2sn	854	6	C	C	NNP
cord-276598-tm0yj2sn	854	7	-	-	HYPH
cord-276598-tm0yj2sn	854	8	N	N	NNP
cord-276598-tm0yj2sn	854	9	into	into	IN
cord-276598-tm0yj2sn	854	10	the	the	DT
cord-276598-tm0yj2sn	854	11	Ir	Ir	NNP
cord-276598-tm0yj2sn	854	12	-	-	HYPH
cord-276598-tm0yj2sn	854	13	C	C	NNP
cord-276598-tm0yj2sn	854	14	bond	bond	NN
cord-276598-tm0yj2sn	854	15	,	,	,
cord-276598-tm0yj2sn	854	16	with	with	IN
cord-276598-tm0yj2sn	854	17	removal	removal	NN
cord-276598-tm0yj2sn	854	18	of	of	IN
cord-276598-tm0yj2sn	854	19	N2	N2	NNP
cord-276598-tm0yj2sn	854	20	,	,	,
cord-276598-tm0yj2sn	854	21	or	or	CC
cord-276598-tm0yj2sn	854	22	by	by	IN
cord-276598-tm0yj2sn	854	23	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	854	24	attack	attack	NN
cord-276598-tm0yj2sn	854	25	from	from	IN
cord-276598-tm0yj2sn	854	26	the	the	DT
cord-276598-tm0yj2sn	854	27	azide	azide	NN
cord-276598-tm0yj2sn	854	28	group	group	NN
cord-276598-tm0yj2sn	854	29	on	on	IN
cord-276598-tm0yj2sn	854	30	the	the	DT
cord-276598-tm0yj2sn	854	31	Ir	Ir	NNP
cord-276598-tm0yj2sn	854	32	-	-	HYPH
cord-276598-tm0yj2sn	854	33	C	C	NNP
cord-276598-tm0yj2sn	854	34	bond	bond	NN
cord-276598-tm0yj2sn	854	35	to	to	TO
cord-276598-tm0yj2sn	854	36	form	form	VB
cord-276598-tm0yj2sn	854	37	the	the	DT
cord-276598-tm0yj2sn	854	38	C	C	NNP
cord-276598-tm0yj2sn	854	39	-	-	HYPH
cord-276598-tm0yj2sn	854	40	N	N	NNP
cord-276598-tm0yj2sn	854	41	bond	bond	NN
cord-276598-tm0yj2sn	854	42	with	with	IN
cord-276598-tm0yj2sn	854	43	the	the	DT
cord-276598-tm0yj2sn	854	44	elimination	elimination	NN
cord-276598-tm0yj2sn	854	45	of	of	IN
cord-276598-tm0yj2sn	854	46	N2	N2	NNP
cord-276598-tm0yj2sn	854	47	,	,	,
cord-276598-tm0yj2sn	854	48	a	a	DT
cord-276598-tm0yj2sn	854	49	complex	complex	NN
cord-276598-tm0yj2sn	854	50	of	of	IN
cord-276598-tm0yj2sn	854	51	Ir	Ir	NNP
cord-276598-tm0yj2sn	854	52	-	-	HYPH
cord-276598-tm0yj2sn	854	53	N	N	NNP
cord-276598-tm0yj2sn	854	54	-	-	HYPH
cord-276598-tm0yj2sn	854	55	C	C	NNP
cord-276598-tm0yj2sn	854	56	bond	bond	NN
cord-276598-tm0yj2sn	854	57	is	be	VBZ
cord-276598-tm0yj2sn	854	58	formed	form	VBN
cord-276598-tm0yj2sn	854	59	.	.	.
cord-276598-tm0yj2sn	855	1	Proto	proto	NN
cord-276598-tm0yj2sn	855	2	-	-	HYPH
cord-276598-tm0yj2sn	855	3	demetallation	demetallation	NN
cord-276598-tm0yj2sn	855	4	of	of	IN
cord-276598-tm0yj2sn	855	5	the	the	DT
cord-276598-tm0yj2sn	855	6	Ir	Ir	NNP
cord-276598-tm0yj2sn	855	7	(	(	-LRB-
cord-276598-tm0yj2sn	855	8	III	III	NNP
cord-276598-tm0yj2sn	855	9	)	)	-RRB-
cord-276598-tm0yj2sn	856	1	-based	-based	JJ
cord-276598-tm0yj2sn	856	2	catalyst	catalyst	NN
cord-276598-tm0yj2sn	856	3	affords	afford	VBZ
cord-276598-tm0yj2sn	856	4	the	the	DT
cord-276598-tm0yj2sn	856	5	desired	desire	VBN
cord-276598-tm0yj2sn	856	6	product	product	NN
cord-276598-tm0yj2sn	856	7	while	while	IN
cord-276598-tm0yj2sn	856	8	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	856	9	32	32	CD
cord-276598-tm0yj2sn	856	10	.	.	.
cord-276598-tm0yj2sn	857	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	857	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	857	3	for	for	IN
cord-276598-tm0yj2sn	857	4	the	the	DT
cord-276598-tm0yj2sn	857	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	857	6	of	of	IN
cord-276598-tm0yj2sn	857	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	857	8	using	use	VBG
cord-276598-tm0yj2sn	857	9	alkali	alkali	NN
cord-276598-tm0yj2sn	857	10	-	-	HYPH
cord-276598-tm0yj2sn	857	11	metal	metal	NN
cord-276598-tm0yj2sn	857	12	catalyst	catalyst	NN
cord-276598-tm0yj2sn	857	13	.	.	.
cord-276598-tm0yj2sn	858	1	The	the	DT
cord-276598-tm0yj2sn	858	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	858	3	of	of	IN
cord-276598-tm0yj2sn	858	4	the	the	DT
cord-276598-tm0yj2sn	858	5	reaction	reaction	NN
cord-276598-tm0yj2sn	858	6	of	of	IN
cord-276598-tm0yj2sn	858	7	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	858	8	insertion	insertion	NN
cord-276598-tm0yj2sn	858	9	according	accord	VBG
cord-276598-tm0yj2sn	858	10	to	to	IN
cord-276598-tm0yj2sn	858	11	Chang	Chang	NNP
cord-276598-tm0yj2sn	858	12	,	,	,
cord-276598-tm0yj2sn	858	13	Kim	Kim	NNP
cord-276598-tm0yj2sn	858	14	,	,	,
cord-276598-tm0yj2sn	858	15	and	and	CC
cord-276598-tm0yj2sn	858	16	coworkers	coworker	NNS
cord-276598-tm0yj2sn	858	17	follows	follow	VBZ
cord-276598-tm0yj2sn	858	18	activation	activation	NN
cord-276598-tm0yj2sn	858	19	of	of	IN
cord-276598-tm0yj2sn	858	20	the	the	DT
cord-276598-tm0yj2sn	858	21	C	C	NNP
cord-276598-tm0yj2sn	858	22	-	-	HYPH
cord-276598-tm0yj2sn	858	23	H	h	NN
cord-276598-tm0yj2sn	858	24	bond	bond	NN
cord-276598-tm0yj2sn	858	25	cleavage	cleavage	NN
cord-276598-tm0yj2sn	858	26	on	on	IN
cord-276598-tm0yj2sn	858	27	the	the	DT
cord-276598-tm0yj2sn	858	28	amide	amide	NN
cord-276598-tm0yj2sn	858	29	or	or	CC
cord-276598-tm0yj2sn	858	30	ketone	ketone	NN
cord-276598-tm0yj2sn	858	31	substrate	substrate	NN
cord-276598-tm0yj2sn	858	32	by	by	IN
cord-276598-tm0yj2sn	858	33	the	the	DT
cord-276598-tm0yj2sn	858	34	Ir	Ir	NNP
cord-276598-tm0yj2sn	858	35	(	(	-LRB-
cord-276598-tm0yj2sn	858	36	III	III	NNP
cord-276598-tm0yj2sn	858	37	)	)	-RRB-
cord-276598-tm0yj2sn	858	38	-based	-based	JJ
cord-276598-tm0yj2sn	858	39	catalyst	catalyst	NN
cord-276598-tm0yj2sn	858	40	to	to	TO
cord-276598-tm0yj2sn	858	41	generate	generate	VB
cord-276598-tm0yj2sn	858	42	an	an	DT
cord-276598-tm0yj2sn	858	43	iridacyclic	iridacyclic	JJ
cord-276598-tm0yj2sn	858	44	intermediate	intermediate	NN
cord-276598-tm0yj2sn	858	45	,	,	,
cord-276598-tm0yj2sn	858	46	which	which	WDT
cord-276598-tm0yj2sn	858	47	then	then	RB
cord-276598-tm0yj2sn	858	48	reacts	react	VBZ
cord-276598-tm0yj2sn	858	49	with	with	IN
cord-276598-tm0yj2sn	858	50	the	the	DT
cord-276598-tm0yj2sn	858	51	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	858	52	azide	azide	NN
cord-276598-tm0yj2sn	858	53	to	to	TO
cord-276598-tm0yj2sn	858	54	produce	produce	VB
cord-276598-tm0yj2sn	858	55	a	a	DT
cord-276598-tm0yj2sn	858	56	coordinated	coordinated	JJ
cord-276598-tm0yj2sn	858	57	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	858	58	azide	azide	NN
cord-276598-tm0yj2sn	858	59	-	-	HYPH
cord-276598-tm0yj2sn	858	60	iridacyclic	iridacyclic	JJ
cord-276598-tm0yj2sn	858	61	adduct	adduct	NN
cord-276598-tm0yj2sn	858	62	(	(	-LRB-
cord-276598-tm0yj2sn	858	63	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	858	64	33	33	CD
cord-276598-tm0yj2sn	858	65	)	)	-RRB-
cord-276598-tm0yj2sn	858	66	[	[	-LRB-
cord-276598-tm0yj2sn	858	67	112	112	CD
cord-276598-tm0yj2sn	858	68	]	]	-RRB-
cord-276598-tm0yj2sn	858	69	.	.	.
cord-276598-tm0yj2sn	859	1	By	by	IN
cord-276598-tm0yj2sn	859	2	intramolecular	intramolecular	JJ
cord-276598-tm0yj2sn	859	3	migratory	migratory	JJ
cord-276598-tm0yj2sn	859	4	insertion	insertion	NN
cord-276598-tm0yj2sn	859	5	of	of	IN
cord-276598-tm0yj2sn	859	6	C	C	NNP
cord-276598-tm0yj2sn	859	7	-	-	HYPH
cord-276598-tm0yj2sn	859	8	N	N	NNP
cord-276598-tm0yj2sn	859	9	into	into	IN
cord-276598-tm0yj2sn	859	10	the	the	DT
cord-276598-tm0yj2sn	859	11	Ir	Ir	NNP
cord-276598-tm0yj2sn	859	12	-	-	HYPH
cord-276598-tm0yj2sn	859	13	C	C	NNP
cord-276598-tm0yj2sn	859	14	bond	bond	NN
cord-276598-tm0yj2sn	859	15	,	,	,
cord-276598-tm0yj2sn	859	16	with	with	IN
cord-276598-tm0yj2sn	859	17	removal	removal	NN
cord-276598-tm0yj2sn	859	18	of	of	IN
cord-276598-tm0yj2sn	859	19	N	n	CD
cord-276598-tm0yj2sn	859	20	2	2	CD
cord-276598-tm0yj2sn	859	21	,	,	,
cord-276598-tm0yj2sn	859	22	or	or	CC
cord-276598-tm0yj2sn	859	23	by	by	IN
cord-276598-tm0yj2sn	859	24	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	859	25	attack	attack	NN
cord-276598-tm0yj2sn	859	26	from	from	IN
cord-276598-tm0yj2sn	859	27	the	the	DT
cord-276598-tm0yj2sn	859	28	azide	azide	NN
cord-276598-tm0yj2sn	859	29	group	group	NN
cord-276598-tm0yj2sn	859	30	on	on	IN
cord-276598-tm0yj2sn	859	31	the	the	DT
cord-276598-tm0yj2sn	859	32	Ir	Ir	NNP
cord-276598-tm0yj2sn	859	33	-	-	HYPH
cord-276598-tm0yj2sn	859	34	C	C	NNP
cord-276598-tm0yj2sn	859	35	bond	bond	NN
cord-276598-tm0yj2sn	859	36	to	to	TO
cord-276598-tm0yj2sn	859	37	form	form	VB
cord-276598-tm0yj2sn	859	38	the	the	DT
cord-276598-tm0yj2sn	859	39	C	C	NNP
cord-276598-tm0yj2sn	859	40	-	-	HYPH
cord-276598-tm0yj2sn	859	41	N	N	NNP
cord-276598-tm0yj2sn	859	42	bond	bond	NN
cord-276598-tm0yj2sn	859	43	with	with	IN
cord-276598-tm0yj2sn	859	44	the	the	DT
cord-276598-tm0yj2sn	859	45	elimination	elimination	NN
cord-276598-tm0yj2sn	859	46	of	of	IN
cord-276598-tm0yj2sn	859	47	N	n	CD
cord-276598-tm0yj2sn	859	48	2	2	CD
cord-276598-tm0yj2sn	859	49	,	,	,
cord-276598-tm0yj2sn	859	50	a	a	DT
cord-276598-tm0yj2sn	859	51	complex	complex	NN
cord-276598-tm0yj2sn	859	52	of	of	IN
cord-276598-tm0yj2sn	859	53	Ir	Ir	NNP
cord-276598-tm0yj2sn	859	54	-	-	HYPH
cord-276598-tm0yj2sn	859	55	N	N	NNP
cord-276598-tm0yj2sn	859	56	-	-	HYPH
cord-276598-tm0yj2sn	859	57	C	C	NNP
cord-276598-tm0yj2sn	859	58	bond	bond	NN
cord-276598-tm0yj2sn	859	59	is	be	VBZ
cord-276598-tm0yj2sn	859	60	formed	form	VBN
cord-276598-tm0yj2sn	859	61	.	.	.
cord-276598-tm0yj2sn	860	1	Proto	proto	NN
cord-276598-tm0yj2sn	860	2	-	-	HYPH
cord-276598-tm0yj2sn	860	3	demetallation	demetallation	NN
cord-276598-tm0yj2sn	860	4	of	of	IN
cord-276598-tm0yj2sn	860	5	the	the	DT
cord-276598-tm0yj2sn	860	6	Ir	Ir	NNP
cord-276598-tm0yj2sn	860	7	(	(	-LRB-
cord-276598-tm0yj2sn	860	8	III	III	NNP
cord-276598-tm0yj2sn	860	9	)	)	-RRB-
cord-276598-tm0yj2sn	861	1	-based	-based	JJ
cord-276598-tm0yj2sn	861	2	catalyst	catalyst	NN
cord-276598-tm0yj2sn	861	3	affords	afford	VBZ
cord-276598-tm0yj2sn	861	4	the	the	DT
cord-276598-tm0yj2sn	861	5	desired	desire	VBN
cord-276598-tm0yj2sn	861	6	product	product	NN
cord-276598-tm0yj2sn	861	7	while	while	IN
cord-276598-tm0yj2sn	861	8	regenerating	regenerate	VBG
cord-276598-tm0yj2sn	861	9	the	the	DT
cord-276598-tm0yj2sn	861	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	861	11	.	.	.
cord-276598-tm0yj2sn	862	1	According	accord	VBG
cord-276598-tm0yj2sn	862	2	to	to	IN
cord-276598-tm0yj2sn	862	3	Zhu	Zhu	NNP
cord-276598-tm0yj2sn	862	4	et	et	FW
cord-276598-tm0yj2sn	862	5	al	al	NNP
cord-276598-tm0yj2sn	862	6	.	.	NNP
cord-276598-tm0yj2sn	862	7	,	,	,
cord-276598-tm0yj2sn	862	8	the	the	DT
cord-276598-tm0yj2sn	862	9	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	862	10	steps	step	NNS
cord-276598-tm0yj2sn	862	11	involve	involve	VBP
cord-276598-tm0yj2sn	862	12	activation	activation	NN
cord-276598-tm0yj2sn	862	13	of	of	IN
cord-276598-tm0yj2sn	862	14	the	the	DT
cord-276598-tm0yj2sn	862	15	Ir	Ir	NNP
cord-276598-tm0yj2sn	862	16	(	(	-LRB-
cord-276598-tm0yj2sn	862	17	III	III	NNP
cord-276598-tm0yj2sn	862	18	)	)	-RRB-
cord-276598-tm0yj2sn	862	19	-based	-based	JJ
cord-276598-tm0yj2sn	862	20	catalyst	catalyst	NN
cord-276598-tm0yj2sn	862	21	in	in	IN
cord-276598-tm0yj2sn	862	22	the	the	DT
cord-276598-tm0yj2sn	862	23	presence	presence	NN
cord-276598-tm0yj2sn	862	24	of	of	IN
cord-276598-tm0yj2sn	862	25	AgOAc	AgOAc	NNS
cord-276598-tm0yj2sn	862	26	and	and	CC
cord-276598-tm0yj2sn	862	27	AgSbF	AgSbF	NNP
cord-276598-tm0yj2sn	862	28	6	6	CD
cord-276598-tm0yj2sn	862	29	,	,	,
cord-276598-tm0yj2sn	862	30	which	which	WDT
cord-276598-tm0yj2sn	862	31	abstracts	abstract	VBZ
cord-276598-tm0yj2sn	862	32	an	an	DT
cord-276598-tm0yj2sn	862	33	H	h	NN
cord-276598-tm0yj2sn	862	34	atom	atom	NN
cord-276598-tm0yj2sn	862	35	from	from	IN
cord-276598-tm0yj2sn	862	36	the	the	DT
cord-276598-tm0yj2sn	862	37	2-phenylpyridine	2-phenylpyridine	CD
cord-276598-tm0yj2sn	862	38	derivative	derivative	JJ
cord-276598-tm0yj2sn	862	39	to	to	IN
cord-276598-tm0yj2sn	862	40	cyclo-(2-phenylpyridine)iridium(III	cyclo-(2-phenylpyridine)iridium(iii	PRP
cord-276598-tm0yj2sn	862	41	)	)	-RRB-
cord-276598-tm0yj2sn	862	42	complex	complex	JJ
cord-276598-tm0yj2sn	862	43	[	[	-LRB-
cord-276598-tm0yj2sn	862	44	114	114	CD
cord-276598-tm0yj2sn	862	45	]	]	-RRB-
cord-276598-tm0yj2sn	862	46	.	.	.
cord-276598-tm0yj2sn	863	1	The	the	DT
cord-276598-tm0yj2sn	863	2	complex	complex	JJ
cord-276598-tm0yj2sn	863	3	further	further	RB
cord-276598-tm0yj2sn	863	4	coordinates	coordinate	VBZ
cord-276598-tm0yj2sn	863	5	with	with	IN
cord-276598-tm0yj2sn	863	6	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	863	7	azide	azide	NN
cord-276598-tm0yj2sn	863	8	to	to	TO
cord-276598-tm0yj2sn	863	9	form	form	VB
cord-276598-tm0yj2sn	863	10	a	a	DT
cord-276598-tm0yj2sn	863	11	cyclo-(2-phenylpyridine)iridium(III)-phosphoryl	cyclo-(2-phenylpyridine)iridium(iii)-phosphoryl	NN
cord-276598-tm0yj2sn	863	12	azide	azide	NN
cord-276598-tm0yj2sn	863	13	complex	complex	NN
cord-276598-tm0yj2sn	863	14	,	,	,
cord-276598-tm0yj2sn	863	15	which	which	WDT
cord-276598-tm0yj2sn	863	16	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	863	17	migratory	migratory	JJ
cord-276598-tm0yj2sn	863	18	insertion	insertion	NN
cord-276598-tm0yj2sn	863	19	to	to	TO
cord-276598-tm0yj2sn	863	20	give	give	VB
cord-276598-tm0yj2sn	863	21	a	a	DT
cord-276598-tm0yj2sn	863	22	complex	complex	NN
cord-276598-tm0yj2sn	863	23	containing	contain	VBG
cord-276598-tm0yj2sn	863	24	a	a	DT
cord-276598-tm0yj2sn	863	25	C	C	NNP
cord-276598-tm0yj2sn	863	26	-	-	HYPH
cord-276598-tm0yj2sn	863	27	N	N	NNP
cord-276598-tm0yj2sn	863	28	-	-	HYPH
cord-276598-tm0yj2sn	863	29	Ir	Ir	NNP
cord-276598-tm0yj2sn	863	30	(	(	-LRB-
cord-276598-tm0yj2sn	863	31	III	III	NNP
cord-276598-tm0yj2sn	863	32	)	)	-RRB-
cord-276598-tm0yj2sn	863	33	bond	bond	NN
cord-276598-tm0yj2sn	863	34	,	,	,
cord-276598-tm0yj2sn	863	35	releasing	release	VBG
cord-276598-tm0yj2sn	863	36	N	n	CD
cord-276598-tm0yj2sn	863	37	2	2	CD
cord-276598-tm0yj2sn	863	38	.	.	.
cord-276598-tm0yj2sn	864	1	The	the	DT
cord-276598-tm0yj2sn	864	2	Ir	Ir	NNP
cord-276598-tm0yj2sn	864	3	(	(	-LRB-
cord-276598-tm0yj2sn	864	4	III	III	NNP
cord-276598-tm0yj2sn	864	5	)	)	-RRB-
cord-276598-tm0yj2sn	865	1	-based	-based	JJ
cord-276598-tm0yj2sn	865	2	catalyst	catalyst	NN
cord-276598-tm0yj2sn	865	3	is	be	VBZ
cord-276598-tm0yj2sn	865	4	released	release	VBN
cord-276598-tm0yj2sn	865	5	through	through	IN
cord-276598-tm0yj2sn	865	6	proto	proto	NN
cord-276598-tm0yj2sn	865	7	-	-	HYPH
cord-276598-tm0yj2sn	865	8	demetallation	demetallation	NN
cord-276598-tm0yj2sn	865	9	to	to	TO
cord-276598-tm0yj2sn	865	10	generate	generate	VB
cord-276598-tm0yj2sn	865	11	the	the	DT
cord-276598-tm0yj2sn	865	12	desired	desire	VBN
cord-276598-tm0yj2sn	865	13	product	product	NN
cord-276598-tm0yj2sn	865	14	.	.	.
cord-276598-tm0yj2sn	866	1	For	for	IN
cord-276598-tm0yj2sn	866	2	the	the	DT
cord-276598-tm0yj2sn	866	3	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	866	4	insertion	insertion	NN
cord-276598-tm0yj2sn	866	5	using	use	VBG
cord-276598-tm0yj2sn	866	6	Ru	Ru	NNP
cord-276598-tm0yj2sn	866	7	IV	IV	NNP
cord-276598-tm0yj2sn	866	8	-porphyrin	-porphyrin	:
cord-276598-tm0yj2sn	866	9	-	-	HYPH
cord-276598-tm0yj2sn	866	10	based	base	VBN
cord-276598-tm0yj2sn	866	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	866	12	,	,	,
cord-276598-tm0yj2sn	866	13	Che	Che	NNP
cord-276598-tm0yj2sn	866	14	and	and	CC
cord-276598-tm0yj2sn	866	15	coworkers	coworker	NNS
cord-276598-tm0yj2sn	866	16	proposed	propose	VBD
cord-276598-tm0yj2sn	866	17	that	that	IN
cord-276598-tm0yj2sn	866	18	a	a	DT
cord-276598-tm0yj2sn	866	19	reactive	reactive	JJ
cord-276598-tm0yj2sn	866	20	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	866	21	Ru	Ru	NNP
cord-276598-tm0yj2sn	866	22	IV	IV	NNP
cord-276598-tm0yj2sn	866	23	-porphyrin	-porphyrin	NN
cord-276598-tm0yj2sn	866	24	-	-	HYPH
cord-276598-tm0yj2sn	866	25	phosphorylimide	phosphorylimide	NN
cord-276598-tm0yj2sn	866	26	species	species	NN
cord-276598-tm0yj2sn	866	27	is	be	VBZ
cord-276598-tm0yj2sn	866	28	first	first	RB
cord-276598-tm0yj2sn	866	29	formed	form	VBN
cord-276598-tm0yj2sn	866	30	from	from	IN
cord-276598-tm0yj2sn	866	31	the	the	DT
cord-276598-tm0yj2sn	866	32	interaction	interaction	NN
cord-276598-tm0yj2sn	866	33	of	of	IN
cord-276598-tm0yj2sn	866	34	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	866	35	azide	azide	NN
cord-276598-tm0yj2sn	866	36	and	and	CC
cord-276598-tm0yj2sn	866	37	the	the	DT
cord-276598-tm0yj2sn	866	38	Ru	Ru	NNP
cord-276598-tm0yj2sn	866	39	IV	IV	NNP
cord-276598-tm0yj2sn	866	40	-porphyrin	-porphyrin	HYPH
cord-276598-tm0yj2sn	866	41	catalyst	catalyst	NN
cord-276598-tm0yj2sn	866	42	[	[	-LRB-
cord-276598-tm0yj2sn	866	43	113	113	CD
cord-276598-tm0yj2sn	866	44	]	]	-RRB-
cord-276598-tm0yj2sn	866	45	.	.	.
cord-276598-tm0yj2sn	867	1	Then	then	RB
cord-276598-tm0yj2sn	867	2	,	,	,
cord-276598-tm0yj2sn	867	3	the	the	DT
cord-276598-tm0yj2sn	867	4	intermediate	intermediate	NN
cord-276598-tm0yj2sn	867	5	reacts	react	VBZ
cord-276598-tm0yj2sn	867	6	with	with	IN
cord-276598-tm0yj2sn	867	7	the	the	DT
cord-276598-tm0yj2sn	867	8	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	867	9	C	C	NNP
cord-276598-tm0yj2sn	867	10	-	-	HYPH
cord-276598-tm0yj2sn	867	11	H	H	NNP
cord-276598-tm0yj2sn	867	12	bond	bond	NN
cord-276598-tm0yj2sn	867	13	through	through	IN
cord-276598-tm0yj2sn	867	14	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	867	15	insertion	insertion	NN
cord-276598-tm0yj2sn	867	16	to	to	TO
cord-276598-tm0yj2sn	867	17	form	form	VB
cord-276598-tm0yj2sn	867	18	a	a	DT
cord-276598-tm0yj2sn	867	19	C	C	NNP
cord-276598-tm0yj2sn	867	20	-	-	HYPH
cord-276598-tm0yj2sn	867	21	N	n	NN
cord-276598-tm0yj2sn	867	22	bonded	bond	VBN
cord-276598-tm0yj2sn	867	23	Ru	Ru	NNP
cord-276598-tm0yj2sn	867	24	IV	IV	NNP
cord-276598-tm0yj2sn	867	25	-porphyrin	-porphyrin	:
cord-276598-tm0yj2sn	867	26	-	-	HYPH
cord-276598-tm0yj2sn	867	27	phosphorylimide	phosphorylimide	NN
cord-276598-tm0yj2sn	867	28	-	-	HYPH
cord-276598-tm0yj2sn	867	29	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	867	30	complex	complex	NN
cord-276598-tm0yj2sn	867	31	with	with	IN
cord-276598-tm0yj2sn	867	32	the	the	DT
cord-276598-tm0yj2sn	867	33	removal	removal	NN
cord-276598-tm0yj2sn	867	34	of	of	IN
cord-276598-tm0yj2sn	867	35	N	n	CD
cord-276598-tm0yj2sn	867	36	2	2	CD
cord-276598-tm0yj2sn	867	37	.	.	.
cord-276598-tm0yj2sn	868	1	The	the	DT
cord-276598-tm0yj2sn	868	2	desired	desire	VBN
cord-276598-tm0yj2sn	868	3	N	n	NN
cord-276598-tm0yj2sn	868	4	-	-	HYPH
cord-276598-tm0yj2sn	868	5	acylphosphoramidates	acylphosphoramidates	NNP
cord-276598-tm0yj2sn	868	6	(	(	-LRB-
cord-276598-tm0yj2sn	868	7	AcP	AcP	NNP
cord-276598-tm0yj2sn	868	8	-	-	HYPH
cord-276598-tm0yj2sn	868	9	N	N	NNP
cord-276598-tm0yj2sn	868	10	)	)	-RRB-
cord-276598-tm0yj2sn	868	11	product	product	NN
cord-276598-tm0yj2sn	868	12	is	be	VBZ
cord-276598-tm0yj2sn	868	13	formed	form	VBN
cord-276598-tm0yj2sn	868	14	after	after	IN
cord-276598-tm0yj2sn	868	15	proto	proto	NN
cord-276598-tm0yj2sn	868	16	-	-	HYPH
cord-276598-tm0yj2sn	868	17	demetallation	demetallation	NN
cord-276598-tm0yj2sn	868	18	of	of	IN
cord-276598-tm0yj2sn	868	19	the	the	DT
cord-276598-tm0yj2sn	868	20	Ru	Ru	NNP
cord-276598-tm0yj2sn	868	21	IV	IV	NNP
cord-276598-tm0yj2sn	868	22	-porphyrin	-porphyrin	HYPH
cord-276598-tm0yj2sn	868	23	catalyst	catalyst	NN
cord-276598-tm0yj2sn	868	24	,	,	,
cord-276598-tm0yj2sn	868	25	and	and	CC
cord-276598-tm0yj2sn	868	26	the	the	DT
cord-276598-tm0yj2sn	868	27	catalyst	catalyst	NN
cord-276598-tm0yj2sn	868	28	is	be	VBZ
cord-276598-tm0yj2sn	868	29	regenerated	regenerate	VBN
cord-276598-tm0yj2sn	868	30	in	in	IN
cord-276598-tm0yj2sn	868	31	the	the	DT
cord-276598-tm0yj2sn	868	32	process	process	NN
cord-276598-tm0yj2sn	868	33	.	.	.
cord-276598-tm0yj2sn	869	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	869	2	2020	2020	CD
cord-276598-tm0yj2sn	869	3	,	,	,
cord-276598-tm0yj2sn	869	4	25	25	CD
cord-276598-tm0yj2sn	870	1	For	for	IN
cord-276598-tm0yj2sn	870	2	the	the	DT
cord-276598-tm0yj2sn	870	3	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	870	4	insertion	insertion	NN
cord-276598-tm0yj2sn	870	5	using	use	VBG
cord-276598-tm0yj2sn	870	6	Ru	Ru	NNP
cord-276598-tm0yj2sn	870	7	IV	IV	NNP
cord-276598-tm0yj2sn	870	8	-porphyrin	-porphyrin	:
cord-276598-tm0yj2sn	870	9	-	-	HYPH
cord-276598-tm0yj2sn	870	10	based	base	VBN
cord-276598-tm0yj2sn	870	11	catalyst	catalyst	NN
cord-276598-tm0yj2sn	870	12	,	,	,
cord-276598-tm0yj2sn	870	13	Che	Che	NNP
cord-276598-tm0yj2sn	870	14	and	and	CC
cord-276598-tm0yj2sn	870	15	coworkers	coworker	NNS
cord-276598-tm0yj2sn	870	16	proposed	propose	VBD
cord-276598-tm0yj2sn	870	17	that	that	IN
cord-276598-tm0yj2sn	870	18	a	a	DT
cord-276598-tm0yj2sn	870	19	reactive	reactive	JJ
cord-276598-tm0yj2sn	870	20	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	870	21	Ru	Ru	NNP
cord-276598-tm0yj2sn	870	22	IV	IV	NNP
cord-276598-tm0yj2sn	870	23	-porphyrin	-porphyrin	NN
cord-276598-tm0yj2sn	870	24	-	-	HYPH
cord-276598-tm0yj2sn	870	25	phosphorylimide	phosphorylimide	NN
cord-276598-tm0yj2sn	870	26	species	species	NN
cord-276598-tm0yj2sn	870	27	is	be	VBZ
cord-276598-tm0yj2sn	870	28	first	first	RB
cord-276598-tm0yj2sn	870	29	formed	form	VBN
cord-276598-tm0yj2sn	870	30	from	from	IN
cord-276598-tm0yj2sn	870	31	the	the	DT
cord-276598-tm0yj2sn	870	32	interaction	interaction	NN
cord-276598-tm0yj2sn	870	33	of	of	IN
cord-276598-tm0yj2sn	870	34	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	870	35	azide	azide	NN
cord-276598-tm0yj2sn	870	36	and	and	CC
cord-276598-tm0yj2sn	870	37	the	the	DT
cord-276598-tm0yj2sn	870	38	Ru	Ru	NNP
cord-276598-tm0yj2sn	870	39	IV	IV	NNP
cord-276598-tm0yj2sn	870	40	-porphyrin	-porphyrin	HYPH
cord-276598-tm0yj2sn	870	41	catalyst	catalyst	NN
cord-276598-tm0yj2sn	870	42	[	[	-LRB-
cord-276598-tm0yj2sn	870	43	113	113	CD
cord-276598-tm0yj2sn	870	44	]	]	-RRB-
cord-276598-tm0yj2sn	870	45	.	.	.
cord-276598-tm0yj2sn	871	1	Then	then	RB
cord-276598-tm0yj2sn	871	2	,	,	,
cord-276598-tm0yj2sn	871	3	the	the	DT
cord-276598-tm0yj2sn	871	4	intermediate	intermediate	NN
cord-276598-tm0yj2sn	871	5	reacts	react	VBZ
cord-276598-tm0yj2sn	871	6	with	with	IN
cord-276598-tm0yj2sn	871	7	the	the	DT
cord-276598-tm0yj2sn	871	8	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	871	9	C	C	NNP
cord-276598-tm0yj2sn	871	10	-	-	HYPH
cord-276598-tm0yj2sn	871	11	H	H	NNP
cord-276598-tm0yj2sn	871	12	bond	bond	NN
cord-276598-tm0yj2sn	871	13	through	through	IN
cord-276598-tm0yj2sn	871	14	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	871	15	insertion	insertion	NN
cord-276598-tm0yj2sn	871	16	to	to	TO
cord-276598-tm0yj2sn	871	17	form	form	VB
cord-276598-tm0yj2sn	871	18	a	a	DT
cord-276598-tm0yj2sn	871	19	C	C	NNP
cord-276598-tm0yj2sn	871	20	-	-	HYPH
cord-276598-tm0yj2sn	871	21	N	n	NN
cord-276598-tm0yj2sn	871	22	bonded	bond	VBN
cord-276598-tm0yj2sn	871	23	Ru	Ru	NNP
cord-276598-tm0yj2sn	871	24	IV	IV	NNP
cord-276598-tm0yj2sn	871	25	-porphyrin	-porphyrin	:
cord-276598-tm0yj2sn	871	26	-	-	HYPH
cord-276598-tm0yj2sn	871	27	phosphorylimide	phosphorylimide	NN
cord-276598-tm0yj2sn	871	28	-	-	HYPH
cord-276598-tm0yj2sn	871	29	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	871	30	complex	complex	NN
cord-276598-tm0yj2sn	871	31	with	with	IN
cord-276598-tm0yj2sn	871	32	the	the	DT
cord-276598-tm0yj2sn	871	33	removal	removal	NN
cord-276598-tm0yj2sn	871	34	of	of	IN
cord-276598-tm0yj2sn	871	35	N2	N2	NNP
cord-276598-tm0yj2sn	871	36	.	.	.
cord-276598-tm0yj2sn	872	1	The	the	DT
cord-276598-tm0yj2sn	872	2	desired	desire	VBN
cord-276598-tm0yj2sn	872	3	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	872	4	33	33	CD
cord-276598-tm0yj2sn	872	5	.	.	.
cord-276598-tm0yj2sn	873	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	873	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	873	3	for	for	IN
cord-276598-tm0yj2sn	873	4	the	the	DT
cord-276598-tm0yj2sn	873	5	Ir	Ir	NNP
cord-276598-tm0yj2sn	873	6	-	-	HYPH
cord-276598-tm0yj2sn	873	7	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	873	8	synthesis	synthesis	NN
cord-276598-tm0yj2sn	873	9	of	of	IN
cord-276598-tm0yj2sn	873	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	873	11	.	.	.
cord-276598-tm0yj2sn	874	1	In	in	IN
cord-276598-tm0yj2sn	874	2	the	the	DT
cord-276598-tm0yj2sn	874	3	reported	report	VBN
cord-276598-tm0yj2sn	874	4	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	874	5	of	of	IN
cord-276598-tm0yj2sn	874	6	the	the	DT
cord-276598-tm0yj2sn	874	7	reaction	reaction	NN
cord-276598-tm0yj2sn	874	8	for	for	IN
cord-276598-tm0yj2sn	874	9	P	p	NN
cord-276598-tm0yj2sn	874	10	-	-	HYPH
cord-276598-tm0yj2sn	874	11	N	n	CD
cord-276598-tm0yj2sn	874	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	874	13	via	via	IN
cord-276598-tm0yj2sn	874	14	azide	azide	NN
cord-276598-tm0yj2sn	874	15	generation	generation	NN
cord-276598-tm0yj2sn	874	16	,	,	,
cord-276598-tm0yj2sn	874	17	organic	organic	JJ
cord-276598-tm0yj2sn	874	18	azide	azide	NN
cord-276598-tm0yj2sn	874	19	is	be	VBZ
cord-276598-tm0yj2sn	874	20	formed	form	VBN
cord-276598-tm0yj2sn	874	21	in	in	IN
cord-276598-tm0yj2sn	874	22	the	the	DT
cord-276598-tm0yj2sn	874	23	first	first	JJ
cord-276598-tm0yj2sn	874	24	step	step	NN
cord-276598-tm0yj2sn	874	25	from	from	IN
cord-276598-tm0yj2sn	874	26	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	874	27	substitution	substitution	NN
cord-276598-tm0yj2sn	874	28	of	of	IN
cord-276598-tm0yj2sn	874	29	the	the	DT
cord-276598-tm0yj2sn	874	30	organic	organic	JJ
cord-276598-tm0yj2sn	874	31	halide	halide	NN
cord-276598-tm0yj2sn	874	32	with	with	IN
cord-276598-tm0yj2sn	874	33	the	the	DT
cord-276598-tm0yj2sn	874	34	elimination	elimination	NN
cord-276598-tm0yj2sn	874	35	of	of	IN
cord-276598-tm0yj2sn	874	36	N	n	CD
cord-276598-tm0yj2sn	874	37	2	2	CD
cord-276598-tm0yj2sn	874	38	gas	gas	NN
cord-276598-tm0yj2sn	874	39	.	.	.
cord-276598-tm0yj2sn	875	1	In	in	IN
cord-276598-tm0yj2sn	875	2	the	the	DT
cord-276598-tm0yj2sn	875	3	second	second	JJ
cord-276598-tm0yj2sn	875	4	step	step	NN
cord-276598-tm0yj2sn	875	5	,	,	,
cord-276598-tm0yj2sn	875	6	the	the	DT
cord-276598-tm0yj2sn	875	7	organic	organic	JJ
cord-276598-tm0yj2sn	875	8	azide	azide	NN
cord-276598-tm0yj2sn	875	9	reacts	react	VBZ
cord-276598-tm0yj2sn	875	10	with	with	IN
cord-276598-tm0yj2sn	875	11	(	(	-LRB-
cord-276598-tm0yj2sn	875	12	RO	ro	NN
cord-276598-tm0yj2sn	875	13	)	)	-RRB-
cord-276598-tm0yj2sn	875	14	3	3	CD
cord-276598-tm0yj2sn	875	15	P	p	NN
cord-276598-tm0yj2sn	875	16	(	(	-LRB-
cord-276598-tm0yj2sn	875	17	R	r	NN
cord-276598-tm0yj2sn	875	18	=	=	NN
cord-276598-tm0yj2sn	875	19	alkyl	alkyl	NN
cord-276598-tm0yj2sn	875	20	)	)	-RRB-
cord-276598-tm0yj2sn	875	21	to	to	TO
cord-276598-tm0yj2sn	875	22	form	form	VB
cord-276598-tm0yj2sn	875	23	the	the	DT
cord-276598-tm0yj2sn	875	24	P	P	NNP
cord-276598-tm0yj2sn	875	25	-	-	HYPH
cord-276598-tm0yj2sn	875	26	N	N	NNP
cord-276598-tm0yj2sn	875	27	compound	compound	NN
cord-276598-tm0yj2sn	875	28	after	after	IN
cord-276598-tm0yj2sn	875	29	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	875	30	or	or	CC
cord-276598-tm0yj2sn	875	31	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	875	32	(	(	-LRB-
cord-276598-tm0yj2sn	875	33	Scheme	scheme	NN
cord-276598-tm0yj2sn	875	34	34	34	CD
cord-276598-tm0yj2sn	875	35	)	)	-RRB-
cord-276598-tm0yj2sn	875	36	[	[	-LRB-
cord-276598-tm0yj2sn	875	37	93	93	CD
cord-276598-tm0yj2sn	875	38	,	,	,
cord-276598-tm0yj2sn	875	39	115	115	CD
cord-276598-tm0yj2sn	875	40	,	,	,
cord-276598-tm0yj2sn	875	41	116	116	CD
cord-276598-tm0yj2sn	875	42	]	]	-RRB-
cord-276598-tm0yj2sn	875	43	.	.	.
cord-276598-tm0yj2sn	876	1	interaction	interaction	NN
cord-276598-tm0yj2sn	876	2	of	of	IN
cord-276598-tm0yj2sn	876	3	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	876	4	azide	azide	NN
cord-276598-tm0yj2sn	876	5	and	and	CC
cord-276598-tm0yj2sn	876	6	the	the	DT
cord-276598-tm0yj2sn	876	7	Ru	Ru	NNP
cord-276598-tm0yj2sn	876	8	IV	IV	NNP
cord-276598-tm0yj2sn	876	9	-porphyrin	-porphyrin	HYPH
cord-276598-tm0yj2sn	876	10	catalyst	catalyst	NN
cord-276598-tm0yj2sn	876	11	[	[	-LRB-
cord-276598-tm0yj2sn	876	12	113	113	CD
cord-276598-tm0yj2sn	876	13	]	]	-RRB-
cord-276598-tm0yj2sn	876	14	.	.	.
cord-276598-tm0yj2sn	877	1	Then	then	RB
cord-276598-tm0yj2sn	877	2	,	,	,
cord-276598-tm0yj2sn	877	3	the	the	DT
cord-276598-tm0yj2sn	877	4	intermediate	intermediate	NN
cord-276598-tm0yj2sn	877	5	reacts	react	VBZ
cord-276598-tm0yj2sn	877	6	with	with	IN
cord-276598-tm0yj2sn	877	7	the	the	DT
cord-276598-tm0yj2sn	877	8	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	877	9	C	C	NNP
cord-276598-tm0yj2sn	877	10	-	-	HYPH
cord-276598-tm0yj2sn	877	11	H	H	NNP
cord-276598-tm0yj2sn	877	12	bond	bond	NN
cord-276598-tm0yj2sn	877	13	through	through	IN
cord-276598-tm0yj2sn	877	14	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	877	15	insertion	insertion	NN
cord-276598-tm0yj2sn	877	16	to	to	TO
cord-276598-tm0yj2sn	877	17	form	form	VB
cord-276598-tm0yj2sn	877	18	a	a	DT
cord-276598-tm0yj2sn	877	19	C	C	NNP
cord-276598-tm0yj2sn	877	20	-	-	HYPH
cord-276598-tm0yj2sn	877	21	N	n	NN
cord-276598-tm0yj2sn	877	22	bonded	bond	VBN
cord-276598-tm0yj2sn	877	23	Ru	Ru	NNP
cord-276598-tm0yj2sn	877	24	IV	IV	NNP
cord-276598-tm0yj2sn	877	25	-porphyrin	-porphyrin	:
cord-276598-tm0yj2sn	877	26	-	-	HYPH
cord-276598-tm0yj2sn	877	27	phosphorylimide	phosphorylimide	NN
cord-276598-tm0yj2sn	877	28	-	-	HYPH
cord-276598-tm0yj2sn	877	29	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	877	30	complex	complex	NN
cord-276598-tm0yj2sn	877	31	with	with	IN
cord-276598-tm0yj2sn	877	32	the	the	DT
cord-276598-tm0yj2sn	877	33	removal	removal	NN
cord-276598-tm0yj2sn	877	34	of	of	IN
cord-276598-tm0yj2sn	877	35	N2	N2	NNP
cord-276598-tm0yj2sn	877	36	.	.	.
cord-276598-tm0yj2sn	878	1	The	the	DT
cord-276598-tm0yj2sn	878	2	desired	desire	VBN
cord-276598-tm0yj2sn	878	3	N	n	NN
cord-276598-tm0yj2sn	878	4	-	-	HYPH
cord-276598-tm0yj2sn	878	5	acylphosphoramidates	acylphosphoramidates	NNP
cord-276598-tm0yj2sn	878	6	(	(	-LRB-
cord-276598-tm0yj2sn	878	7	AcP	AcP	NNP
cord-276598-tm0yj2sn	878	8	-	-	HYPH
cord-276598-tm0yj2sn	878	9	N	N	NNP
cord-276598-tm0yj2sn	878	10	)	)	-RRB-
cord-276598-tm0yj2sn	878	11	product	product	NN
cord-276598-tm0yj2sn	878	12	is	be	VBZ
cord-276598-tm0yj2sn	878	13	formed	form	VBN
cord-276598-tm0yj2sn	878	14	after	after	IN
cord-276598-tm0yj2sn	878	15	proto	proto	NN
cord-276598-tm0yj2sn	878	16	-	-	HYPH
cord-276598-tm0yj2sn	878	17	demetallation	demetallation	NN
cord-276598-tm0yj2sn	878	18	of	of	IN
cord-276598-tm0yj2sn	878	19	the	the	DT
cord-276598-tm0yj2sn	878	20	Ru	Ru	NNP
cord-276598-tm0yj2sn	878	21	IV	IV	NNP
cord-276598-tm0yj2sn	878	22	-porphyrin	-porphyrin	HYPH
cord-276598-tm0yj2sn	878	23	catalyst	catalyst	NN
cord-276598-tm0yj2sn	878	24	,	,	,
cord-276598-tm0yj2sn	878	25	and	and	CC
cord-276598-tm0yj2sn	878	26	the	the	DT
cord-276598-tm0yj2sn	878	27	catalyst	catalyst	NN
cord-276598-tm0yj2sn	878	28	is	be	VBZ
cord-276598-tm0yj2sn	878	29	regenerated	regenerate	VBN
cord-276598-tm0yj2sn	878	30	in	in	IN
cord-276598-tm0yj2sn	878	31	the	the	DT
cord-276598-tm0yj2sn	878	32	process	process	NN
cord-276598-tm0yj2sn	878	33	.	.	.
cord-276598-tm0yj2sn	879	1	In	in	IN
cord-276598-tm0yj2sn	879	2	the	the	DT
cord-276598-tm0yj2sn	879	3	reported	report	VBN
cord-276598-tm0yj2sn	879	4	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	879	5	of	of	IN
cord-276598-tm0yj2sn	879	6	the	the	DT
cord-276598-tm0yj2sn	879	7	reaction	reaction	NN
cord-276598-tm0yj2sn	879	8	for	for	IN
cord-276598-tm0yj2sn	879	9	P	p	NN
cord-276598-tm0yj2sn	879	10	-	-	HYPH
cord-276598-tm0yj2sn	879	11	N	n	CD
cord-276598-tm0yj2sn	879	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	879	13	via	via	IN
cord-276598-tm0yj2sn	879	14	azide	azide	NN
cord-276598-tm0yj2sn	879	15	generation	generation	NN
cord-276598-tm0yj2sn	879	16	,	,	,
cord-276598-tm0yj2sn	879	17	organic	organic	JJ
cord-276598-tm0yj2sn	879	18	azide	azide	NN
cord-276598-tm0yj2sn	879	19	is	be	VBZ
cord-276598-tm0yj2sn	879	20	formed	form	VBN
cord-276598-tm0yj2sn	879	21	in	in	IN
cord-276598-tm0yj2sn	879	22	the	the	DT
cord-276598-tm0yj2sn	879	23	first	first	JJ
cord-276598-tm0yj2sn	879	24	step	step	NN
cord-276598-tm0yj2sn	879	25	from	from	IN
cord-276598-tm0yj2sn	879	26	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	879	27	substitution	substitution	NN
cord-276598-tm0yj2sn	879	28	of	of	IN
cord-276598-tm0yj2sn	879	29	the	the	DT
cord-276598-tm0yj2sn	879	30	organic	organic	JJ
cord-276598-tm0yj2sn	879	31	halide	halide	NN
cord-276598-tm0yj2sn	879	32	with	with	IN
cord-276598-tm0yj2sn	879	33	the	the	DT
cord-276598-tm0yj2sn	879	34	elimination	elimination	NN
cord-276598-tm0yj2sn	879	35	of	of	IN
cord-276598-tm0yj2sn	879	36	N2	N2	NNP
cord-276598-tm0yj2sn	879	37	gas	gas	NN
cord-276598-tm0yj2sn	879	38	.	.	.
cord-276598-tm0yj2sn	880	1	In	in	IN
cord-276598-tm0yj2sn	880	2	the	the	DT
cord-276598-tm0yj2sn	880	3	second	second	JJ
cord-276598-tm0yj2sn	880	4	step	step	NN
cord-276598-tm0yj2sn	880	5	,	,	,
cord-276598-tm0yj2sn	880	6	the	the	DT
cord-276598-tm0yj2sn	880	7	organic	organic	JJ
cord-276598-tm0yj2sn	880	8	azide	azide	NN
cord-276598-tm0yj2sn	880	9	reacts	react	VBZ
cord-276598-tm0yj2sn	880	10	with	with	IN
cord-276598-tm0yj2sn	880	11	(	(	-LRB-
cord-276598-tm0yj2sn	880	12	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	880	13	(	(	-LRB-
cord-276598-tm0yj2sn	880	14	R	r	NN
cord-276598-tm0yj2sn	880	15	=	=	NN
cord-276598-tm0yj2sn	880	16	alkyl	alkyl	NN
cord-276598-tm0yj2sn	880	17	)	)	-RRB-
cord-276598-tm0yj2sn	880	18	to	to	TO
cord-276598-tm0yj2sn	880	19	form	form	VB
cord-276598-tm0yj2sn	880	20	the	the	DT
cord-276598-tm0yj2sn	880	21	P	P	NNP
cord-276598-tm0yj2sn	880	22	-	-	HYPH
cord-276598-tm0yj2sn	880	23	N	N	NNP
cord-276598-tm0yj2sn	880	24	compound	compound	NN
cord-276598-tm0yj2sn	880	25	after	after	IN
cord-276598-tm0yj2sn	880	26	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	880	27	or	or	CC
cord-276598-tm0yj2sn	880	28	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	880	29	(	(	-LRB-
cord-276598-tm0yj2sn	880	30	Scheme	scheme	NN
cord-276598-tm0yj2sn	880	31	34	34	CD
cord-276598-tm0yj2sn	880	32	)	)	-RRB-
cord-276598-tm0yj2sn	880	33	[	[	-LRB-
cord-276598-tm0yj2sn	880	34	93	93	CD
cord-276598-tm0yj2sn	880	35	,	,	,
cord-276598-tm0yj2sn	880	36	115	115	CD
cord-276598-tm0yj2sn	880	37	,	,	,
cord-276598-tm0yj2sn	880	38	116	116	CD
cord-276598-tm0yj2sn	880	39	]	]	-RRB-
cord-276598-tm0yj2sn	880	40	.	.	.
cord-276598-tm0yj2sn	881	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	881	2	34	34	CD
cord-276598-tm0yj2sn	881	3	.	.	.
cord-276598-tm0yj2sn	882	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	882	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	882	3	to	to	IN
cord-276598-tm0yj2sn	882	4	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	882	5	via	via	IN
cord-276598-tm0yj2sn	882	6	azide	azide	NN
cord-276598-tm0yj2sn	882	7	generation	generation	NN
cord-276598-tm0yj2sn	882	8	.	.	.
cord-276598-tm0yj2sn	883	1	According	accord	VBG
cord-276598-tm0yj2sn	883	2	to	to	IN
cord-276598-tm0yj2sn	883	3	the	the	DT
cord-276598-tm0yj2sn	883	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	883	5	suggested	suggest	VBN
cord-276598-tm0yj2sn	883	6	by	by	IN
cord-276598-tm0yj2sn	883	7	Chen	Chen	NNP
cord-276598-tm0yj2sn	883	8	et	et	NNP
cord-276598-tm0yj2sn	883	9	al	al	NNP
cord-276598-tm0yj2sn	883	10	.	.	NNP
cord-276598-tm0yj2sn	883	11	,	,	,
cord-276598-tm0yj2sn	883	12	the	the	DT
cord-276598-tm0yj2sn	883	13	amine	amine	NN
cord-276598-tm0yj2sn	883	14	reacts	react	VBZ
cord-276598-tm0yj2sn	883	15	with	with	IN
cord-276598-tm0yj2sn	883	16	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	883	17	azide	azide	NN
cord-276598-tm0yj2sn	883	18	through	through	IN
cord-276598-tm0yj2sn	883	19	a	a	DT
cord-276598-tm0yj2sn	883	20	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	883	21	substitution	substitution	NN
cord-276598-tm0yj2sn	883	22	reaction	reaction	NN
cord-276598-tm0yj2sn	883	23	to	to	TO
cord-276598-tm0yj2sn	883	24	generate	generate	VB
cord-276598-tm0yj2sn	883	25	an	an	DT
cord-276598-tm0yj2sn	883	26	azido	azido	NN
cord-276598-tm0yj2sn	883	27	(	(	-LRB-
cord-276598-tm0yj2sn	883	28	hydroxy)-phosphanamine	hydroxy)-phosphanamine	JJ
cord-276598-tm0yj2sn	883	29	complex	complex	JJ
cord-276598-tm0yj2sn	883	30	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	883	31	in	in	IN
cord-276598-tm0yj2sn	883	32	the	the	DT
cord-276598-tm0yj2sn	883	33	first	first	JJ
cord-276598-tm0yj2sn	883	34	step	step	NN
cord-276598-tm0yj2sn	883	35	[	[	-LRB-
cord-276598-tm0yj2sn	883	36	117	117	CD
cord-276598-tm0yj2sn	883	37	]	]	-RRB-
cord-276598-tm0yj2sn	883	38	.	.	.
cord-276598-tm0yj2sn	884	1	In	in	IN
cord-276598-tm0yj2sn	884	2	the	the	DT
cord-276598-tm0yj2sn	884	3	second	second	JJ
cord-276598-tm0yj2sn	884	4	step	step	NN
cord-276598-tm0yj2sn	884	5	,	,	,
cord-276598-tm0yj2sn	884	6	the	the	DT
cord-276598-tm0yj2sn	884	7	azide	azide	NN
cord-276598-tm0yj2sn	884	8	anion	anion	NN
cord-276598-tm0yj2sn	884	9	departs	depart	VBZ
cord-276598-tm0yj2sn	884	10	as	as	IN
cord-276598-tm0yj2sn	884	11	the	the	DT
cord-276598-tm0yj2sn	884	12	leaving	leave	VBG
cord-276598-tm0yj2sn	884	13	group	group	NN
cord-276598-tm0yj2sn	884	14	to	to	TO
cord-276598-tm0yj2sn	884	15	give	give	VB
cord-276598-tm0yj2sn	884	16	a	a	DT
cord-276598-tm0yj2sn	884	17	stable	stable	JJ
cord-276598-tm0yj2sn	884	18	P	p	NN
cord-276598-tm0yj2sn	884	19	-	-	HYPH
cord-276598-tm0yj2sn	884	20	N	n	CD
cord-276598-tm0yj2sn	884	21	product	product	NN
cord-276598-tm0yj2sn	884	22	(	(	-LRB-
cord-276598-tm0yj2sn	884	23	Scheme	scheme	NN
cord-276598-tm0yj2sn	884	24	35	35	CD
cord-276598-tm0yj2sn	884	25	)	)	-RRB-
cord-276598-tm0yj2sn	884	26	.	.	.
cord-276598-tm0yj2sn	885	1	Although	although	IN
cord-276598-tm0yj2sn	885	2	the	the	DT
cord-276598-tm0yj2sn	885	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	885	4	looks	look	VBZ
cord-276598-tm0yj2sn	885	5	highly	highly	RB
cord-276598-tm0yj2sn	885	6	plausible	plausible	JJ
cord-276598-tm0yj2sn	885	7	,	,	,
cord-276598-tm0yj2sn	885	8	it	-PRON-	PRP
cord-276598-tm0yj2sn	885	9	is	be	VBZ
cord-276598-tm0yj2sn	885	10	noteworthy	noteworthy	JJ
cord-276598-tm0yj2sn	885	11	that	that	IN
cord-276598-tm0yj2sn	885	12	N3	n3	NN
cord-276598-tm0yj2sn	885	13	is	be	VBZ
cord-276598-tm0yj2sn	885	14	highly	highly	RB
cord-276598-tm0yj2sn	885	15	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	885	16	because	because	IN
cord-276598-tm0yj2sn	885	17	in	in	IN
cord-276598-tm0yj2sn	885	18	its	-PRON-	PRP$
cord-276598-tm0yj2sn	885	19	canonical	canonical	JJ
cord-276598-tm0yj2sn	885	20	structure	structure	NN
cord-276598-tm0yj2sn	885	21	,	,	,
cord-276598-tm0yj2sn	885	22	one	one	CD
cord-276598-tm0yj2sn	885	23	of	of	IN
cord-276598-tm0yj2sn	885	24	the	the	DT
cord-276598-tm0yj2sn	885	25	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	885	26	atoms	atom	NNS
cord-276598-tm0yj2sn	885	27	carries	carry	VBZ
cord-276598-tm0yj2sn	885	28	a	a	DT
cord-276598-tm0yj2sn	885	29	double	double	JJ
cord-276598-tm0yj2sn	885	30	negative	negative	JJ
cord-276598-tm0yj2sn	885	31	charge	charge	NN
cord-276598-tm0yj2sn	885	32	(	(	-LRB-
cord-276598-tm0yj2sn	885	33	N≡N	n≡n	NN
cord-276598-tm0yj2sn	885	34	+	+	SYM
cord-276598-tm0yj2sn	885	35	−	−	NN
cord-276598-tm0yj2sn	885	36	N	n	CD
cord-276598-tm0yj2sn	885	37	2−	2−	CD
cord-276598-tm0yj2sn	885	38	)	)	-RRB-
cord-276598-tm0yj2sn	885	39	[	[	-LRB-
cord-276598-tm0yj2sn	885	40	124	124	CD
cord-276598-tm0yj2sn	885	41	]	]	-RRB-
cord-276598-tm0yj2sn	885	42	,	,	,
cord-276598-tm0yj2sn	885	43	which	which	WDT
cord-276598-tm0yj2sn	885	44	makes	make	VBZ
cord-276598-tm0yj2sn	885	45	it	-PRON-	PRP
cord-276598-tm0yj2sn	885	46	stable	stable	JJ
cord-276598-tm0yj2sn	885	47	and	and	CC
cord-276598-tm0yj2sn	885	48	a	a	DT
cord-276598-tm0yj2sn	885	49	poor	poor	JJ
cord-276598-tm0yj2sn	885	50	leaving	leave	VBG
cord-276598-tm0yj2sn	885	51	group	group	NN
cord-276598-tm0yj2sn	885	52	as	as	IN
cord-276598-tm0yj2sn	885	53	N3	n3	NN
cord-276598-tm0yj2sn	885	54	in	in	IN
cord-276598-tm0yj2sn	885	55	the	the	DT
cord-276598-tm0yj2sn	885	56	presence	presence	NN
cord-276598-tm0yj2sn	885	57	of	of	IN
cord-276598-tm0yj2sn	885	58	amine	amine	NN
cord-276598-tm0yj2sn	885	59	[	[	-LRB-
cord-276598-tm0yj2sn	885	60	125	125	CD
cord-276598-tm0yj2sn	885	61	]	]	-RRB-
cord-276598-tm0yj2sn	885	62	.	.	.
cord-276598-tm0yj2sn	886	1	In	in	IN
cord-276598-tm0yj2sn	886	2	addition	addition	NN
cord-276598-tm0yj2sn	886	3	,	,	,
cord-276598-tm0yj2sn	886	4	the	the	DT
cord-276598-tm0yj2sn	886	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	886	6	does	do	VBZ
cord-276598-tm0yj2sn	886	7	account	account	VB
cord-276598-tm0yj2sn	886	8	for	for	IN
cord-276598-tm0yj2sn	886	9	the	the	DT
cord-276598-tm0yj2sn	886	10	potentially	potentially	RB
cord-276598-tm0yj2sn	886	11	explosive	explosive	JJ
cord-276598-tm0yj2sn	886	12	HN3	hn3	NN
cord-276598-tm0yj2sn	886	13	in	in	IN
cord-276598-tm0yj2sn	886	14	a	a	DT
cord-276598-tm0yj2sn	886	15	closed	closed	JJ
cord-276598-tm0yj2sn	886	16	flask	flask	NN
cord-276598-tm0yj2sn	886	17	at	at	IN
cord-276598-tm0yj2sn	886	18	120	120	CD
cord-276598-tm0yj2sn	886	19	°	°	NN
cord-276598-tm0yj2sn	886	20	C	c	NN
cord-276598-tm0yj2sn	886	21	.	.	.
cord-276598-tm0yj2sn	887	1	However	however	RB
cord-276598-tm0yj2sn	887	2	,	,	,
cord-276598-tm0yj2sn	887	3	it	-PRON-	PRP
cord-276598-tm0yj2sn	887	4	is	be	VBZ
cord-276598-tm0yj2sn	887	5	possible	possible	JJ
cord-276598-tm0yj2sn	887	6	that	that	IN
cord-276598-tm0yj2sn	887	7	in	in	IN
cord-276598-tm0yj2sn	887	8	the	the	DT
cord-276598-tm0yj2sn	887	9	reaction	reaction	NN
cord-276598-tm0yj2sn	887	10	process	process	NN
cord-276598-tm0yj2sn	887	11	,	,	,
cord-276598-tm0yj2sn	887	12	the	the	DT
cord-276598-tm0yj2sn	887	13	azide	azide	NN
cord-276598-tm0yj2sn	887	14	is	be	VBZ
cord-276598-tm0yj2sn	887	15	first	first	RB
cord-276598-tm0yj2sn	887	16	reduced	reduce	VBN
cord-276598-tm0yj2sn	887	17	or	or	CC
cord-276598-tm0yj2sn	887	18	decomposed	decompose	VBN
cord-276598-tm0yj2sn	887	19	to	to	IN
cord-276598-tm0yj2sn	887	20	a	a	DT
cord-276598-tm0yj2sn	887	21	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	887	22	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	887	23	radical	radical	JJ
cord-276598-tm0yj2sn	887	24	(	(	-LRB-
cord-276598-tm0yj2sn	887	25	(	(	-LRB-
cord-276598-tm0yj2sn	887	26	RO)2P(O)N	RO)2P(O)N	VBG
cord-276598-tm0yj2sn	887	27	;	;	:
cord-276598-tm0yj2sn	887	28	R	r	NN
cord-276598-tm0yj2sn	887	29	=	=	SYM
cord-276598-tm0yj2sn	887	30	Scheme	scheme	NN
cord-276598-tm0yj2sn	887	31	34	34	CD
cord-276598-tm0yj2sn	887	32	.	.	.
cord-276598-tm0yj2sn	888	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	888	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	888	3	to	to	IN
cord-276598-tm0yj2sn	888	4	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	888	5	via	via	IN
cord-276598-tm0yj2sn	888	6	azide	azide	NN
cord-276598-tm0yj2sn	888	7	generation	generation	NN
cord-276598-tm0yj2sn	888	8	.	.	.
cord-276598-tm0yj2sn	889	1	According	accord	VBG
cord-276598-tm0yj2sn	889	2	to	to	IN
cord-276598-tm0yj2sn	889	3	the	the	DT
cord-276598-tm0yj2sn	889	4	mechanism	mechanism	NN
cord-276598-tm0yj2sn	889	5	suggested	suggest	VBN
cord-276598-tm0yj2sn	889	6	by	by	IN
cord-276598-tm0yj2sn	889	7	Chen	Chen	NNP
cord-276598-tm0yj2sn	889	8	et	et	NNP
cord-276598-tm0yj2sn	889	9	al	al	NNP
cord-276598-tm0yj2sn	889	10	.	.	NNP
cord-276598-tm0yj2sn	889	11	,	,	,
cord-276598-tm0yj2sn	889	12	the	the	DT
cord-276598-tm0yj2sn	889	13	amine	amine	NN
cord-276598-tm0yj2sn	889	14	reacts	react	VBZ
cord-276598-tm0yj2sn	889	15	with	with	IN
cord-276598-tm0yj2sn	889	16	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	889	17	azide	azide	NN
cord-276598-tm0yj2sn	889	18	through	through	IN
cord-276598-tm0yj2sn	889	19	a	a	DT
cord-276598-tm0yj2sn	889	20	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	889	21	substitution	substitution	NN
cord-276598-tm0yj2sn	889	22	reaction	reaction	NN
cord-276598-tm0yj2sn	889	23	to	to	TO
cord-276598-tm0yj2sn	889	24	generate	generate	VB
cord-276598-tm0yj2sn	889	25	an	an	DT
cord-276598-tm0yj2sn	889	26	azido	azido	NN
cord-276598-tm0yj2sn	889	27	(	(	-LRB-
cord-276598-tm0yj2sn	889	28	hydroxy)-phosphanamine	hydroxy)-phosphanamine	JJ
cord-276598-tm0yj2sn	889	29	complex	complex	JJ
cord-276598-tm0yj2sn	889	30	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	889	31	in	in	IN
cord-276598-tm0yj2sn	889	32	the	the	DT
cord-276598-tm0yj2sn	889	33	first	first	JJ
cord-276598-tm0yj2sn	889	34	step	step	NN
cord-276598-tm0yj2sn	889	35	[	[	-LRB-
cord-276598-tm0yj2sn	889	36	117	117	CD
cord-276598-tm0yj2sn	889	37	]	]	-RRB-
cord-276598-tm0yj2sn	889	38	.	.	.
cord-276598-tm0yj2sn	890	1	In	in	IN
cord-276598-tm0yj2sn	890	2	the	the	DT
cord-276598-tm0yj2sn	890	3	second	second	JJ
cord-276598-tm0yj2sn	890	4	step	step	NN
cord-276598-tm0yj2sn	890	5	,	,	,
cord-276598-tm0yj2sn	890	6	the	the	DT
cord-276598-tm0yj2sn	890	7	azide	azide	NN
cord-276598-tm0yj2sn	890	8	anion	anion	NN
cord-276598-tm0yj2sn	890	9	departs	depart	VBZ
cord-276598-tm0yj2sn	890	10	as	as	IN
cord-276598-tm0yj2sn	890	11	the	the	DT
cord-276598-tm0yj2sn	890	12	leaving	leave	VBG
cord-276598-tm0yj2sn	890	13	group	group	NN
cord-276598-tm0yj2sn	890	14	to	to	TO
cord-276598-tm0yj2sn	890	15	give	give	VB
cord-276598-tm0yj2sn	890	16	a	a	DT
cord-276598-tm0yj2sn	890	17	stable	stable	JJ
cord-276598-tm0yj2sn	890	18	P	p	NN
cord-276598-tm0yj2sn	890	19	-	-	HYPH
cord-276598-tm0yj2sn	890	20	N	n	CD
cord-276598-tm0yj2sn	890	21	product	product	NN
cord-276598-tm0yj2sn	890	22	(	(	-LRB-
cord-276598-tm0yj2sn	890	23	Scheme	scheme	NN
cord-276598-tm0yj2sn	890	24	35	35	CD
cord-276598-tm0yj2sn	890	25	)	)	-RRB-
cord-276598-tm0yj2sn	890	26	.	.	.
cord-276598-tm0yj2sn	891	1	Although	although	IN
cord-276598-tm0yj2sn	891	2	the	the	DT
cord-276598-tm0yj2sn	891	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	891	4	looks	look	VBZ
cord-276598-tm0yj2sn	891	5	highly	highly	RB
cord-276598-tm0yj2sn	891	6	plausible	plausible	JJ
cord-276598-tm0yj2sn	891	7	,	,	,
cord-276598-tm0yj2sn	891	8	it	-PRON-	PRP
cord-276598-tm0yj2sn	891	9	is	be	VBZ
cord-276598-tm0yj2sn	891	10	noteworthy	noteworthy	JJ
cord-276598-tm0yj2sn	891	11	that	that	IN
cord-276598-tm0yj2sn	891	12	N	n	NN
cord-276598-tm0yj2sn	891	13	3	3	CD
cord-276598-tm0yj2sn	891	14	is	be	VBZ
cord-276598-tm0yj2sn	891	15	highly	highly	RB
cord-276598-tm0yj2sn	891	16	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	891	17	because	because	IN
cord-276598-tm0yj2sn	891	18	in	in	IN
cord-276598-tm0yj2sn	891	19	its	-PRON-	PRP$
cord-276598-tm0yj2sn	891	20	canonical	canonical	JJ
cord-276598-tm0yj2sn	891	21	structure	structure	NN
cord-276598-tm0yj2sn	891	22	,	,	,
cord-276598-tm0yj2sn	891	23	one	one	CD
cord-276598-tm0yj2sn	891	24	of	of	IN
cord-276598-tm0yj2sn	891	25	the	the	DT
cord-276598-tm0yj2sn	891	26	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	891	27	atoms	atom	NNS
cord-276598-tm0yj2sn	891	28	carries	carry	VBZ
cord-276598-tm0yj2sn	891	29	a	a	DT
cord-276598-tm0yj2sn	891	30	double	double	JJ
cord-276598-tm0yj2sn	891	31	negative	negative	JJ
cord-276598-tm0yj2sn	891	32	charge	charge	NN
cord-276598-tm0yj2sn	891	33	(	(	-LRB-
cord-276598-tm0yj2sn	891	34	N≡N	n≡n	NN
cord-276598-tm0yj2sn	891	35	+	+	SYM
cord-276598-tm0yj2sn	891	36	−	−	NN
cord-276598-tm0yj2sn	891	37	N	n	CD
cord-276598-tm0yj2sn	891	38	2−	2−	CD
cord-276598-tm0yj2sn	891	39	)	)	-RRB-
cord-276598-tm0yj2sn	891	40	[	[	-LRB-
cord-276598-tm0yj2sn	891	41	124	124	CD
cord-276598-tm0yj2sn	891	42	]	]	-RRB-
cord-276598-tm0yj2sn	891	43	,	,	,
cord-276598-tm0yj2sn	891	44	which	which	WDT
cord-276598-tm0yj2sn	891	45	makes	make	VBZ
cord-276598-tm0yj2sn	891	46	it	-PRON-	PRP
cord-276598-tm0yj2sn	891	47	stable	stable	JJ
cord-276598-tm0yj2sn	891	48	and	and	CC
cord-276598-tm0yj2sn	891	49	a	a	DT
cord-276598-tm0yj2sn	891	50	poor	poor	JJ
cord-276598-tm0yj2sn	891	51	leaving	leave	VBG
cord-276598-tm0yj2sn	891	52	group	group	NN
cord-276598-tm0yj2sn	891	53	as	as	IN
cord-276598-tm0yj2sn	891	54	N	n	CD
cord-276598-tm0yj2sn	891	55	3	3	CD
cord-276598-tm0yj2sn	891	56	in	in	IN
cord-276598-tm0yj2sn	891	57	the	the	DT
cord-276598-tm0yj2sn	891	58	presence	presence	NN
cord-276598-tm0yj2sn	891	59	of	of	IN
cord-276598-tm0yj2sn	891	60	amine	amine	NN
cord-276598-tm0yj2sn	891	61	[	[	-LRB-
cord-276598-tm0yj2sn	891	62	125	125	CD
cord-276598-tm0yj2sn	891	63	]	]	-RRB-
cord-276598-tm0yj2sn	891	64	.	.	.
cord-276598-tm0yj2sn	892	1	In	in	IN
cord-276598-tm0yj2sn	892	2	addition	addition	NN
cord-276598-tm0yj2sn	892	3	,	,	,
cord-276598-tm0yj2sn	892	4	the	the	DT
cord-276598-tm0yj2sn	892	5	mechanism	mechanism	NN
cord-276598-tm0yj2sn	892	6	does	do	VBZ
cord-276598-tm0yj2sn	892	7	account	account	VB
cord-276598-tm0yj2sn	892	8	for	for	IN
cord-276598-tm0yj2sn	892	9	the	the	DT
cord-276598-tm0yj2sn	892	10	potentially	potentially	RB
cord-276598-tm0yj2sn	892	11	explosive	explosive	JJ
cord-276598-tm0yj2sn	892	12	HN	HN	NNP
cord-276598-tm0yj2sn	892	13	3	3	CD
cord-276598-tm0yj2sn	892	14	in	in	IN
cord-276598-tm0yj2sn	892	15	a	a	DT
cord-276598-tm0yj2sn	892	16	closed	closed	JJ
cord-276598-tm0yj2sn	892	17	flask	flask	NN
cord-276598-tm0yj2sn	892	18	at	at	IN
cord-276598-tm0yj2sn	892	19	120	120	CD
cord-276598-tm0yj2sn	892	20	•	•	NNS
cord-276598-tm0yj2sn	892	21	C.	c.	NN
cord-276598-tm0yj2sn	893	1	However	however	RB
cord-276598-tm0yj2sn	893	2	,	,	,
cord-276598-tm0yj2sn	893	3	it	-PRON-	PRP
cord-276598-tm0yj2sn	893	4	is	be	VBZ
cord-276598-tm0yj2sn	893	5	possible	possible	JJ
cord-276598-tm0yj2sn	893	6	that	that	IN
cord-276598-tm0yj2sn	893	7	in	in	IN
cord-276598-tm0yj2sn	893	8	the	the	DT
cord-276598-tm0yj2sn	893	9	reaction	reaction	NN
cord-276598-tm0yj2sn	893	10	process	process	NN
cord-276598-tm0yj2sn	893	11	,	,	,
cord-276598-tm0yj2sn	893	12	the	the	DT
cord-276598-tm0yj2sn	893	13	azide	azide	NN
cord-276598-tm0yj2sn	893	14	is	be	VBZ
cord-276598-tm0yj2sn	893	15	first	first	RB
cord-276598-tm0yj2sn	893	16	reduced	reduce	VBN
cord-276598-tm0yj2sn	893	17	or	or	CC
cord-276598-tm0yj2sn	893	18	decomposed	decompose	VBN
cord-276598-tm0yj2sn	893	19	to	to	IN
cord-276598-tm0yj2sn	893	20	a	a	DT
cord-276598-tm0yj2sn	893	21	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	893	22	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	893	23	radical	radical	JJ
cord-276598-tm0yj2sn	893	24	(	(	-LRB-
cord-276598-tm0yj2sn	893	25	(	(	-LRB-
cord-276598-tm0yj2sn	893	26	RO	RO	NNP
cord-276598-tm0yj2sn	893	27	)	)	-RRB-
cord-276598-tm0yj2sn	893	28	2	2	CD
cord-276598-tm0yj2sn	893	29	P(O)N	P(O)N	NNP
cord-276598-tm0yj2sn	893	30	;	;	:
cord-276598-tm0yj2sn	893	31	R	r	NN
cord-276598-tm0yj2sn	893	32	=	=	NN
cord-276598-tm0yj2sn	893	33	alkyl	alkyl	NN
cord-276598-tm0yj2sn	893	34	,	,	,
cord-276598-tm0yj2sn	893	35	Ph	Ph	NNP
cord-276598-tm0yj2sn	893	36	)	)	-RRB-
cord-276598-tm0yj2sn	893	37	,	,	,
cord-276598-tm0yj2sn	893	38	while	while	IN
cord-276598-tm0yj2sn	893	39	N	n	CD
cord-276598-tm0yj2sn	893	40	2	2	CD
cord-276598-tm0yj2sn	893	41	is	be	VBZ
cord-276598-tm0yj2sn	893	42	liberated	liberate	VBN
cord-276598-tm0yj2sn	893	43	.	.	.
cord-276598-tm0yj2sn	894	1	In	in	IN
cord-276598-tm0yj2sn	894	2	the	the	DT
cord-276598-tm0yj2sn	894	3	second	second	JJ
cord-276598-tm0yj2sn	894	4	step	step	NN
cord-276598-tm0yj2sn	894	5	,	,	,
cord-276598-tm0yj2sn	894	6	the	the	DT
cord-276598-tm0yj2sn	894	7	electrophilic	electrophilic	JJ
cord-276598-tm0yj2sn	894	8	nitrene	nitrene	NNP
cord-276598-tm0yj2sn	894	9	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	894	10	radical	radical	NNP
cord-276598-tm0yj2sn	894	11	reacts	react	VBZ
cord-276598-tm0yj2sn	894	12	with	with	IN
cord-276598-tm0yj2sn	894	13	or	or	CC
cord-276598-tm0yj2sn	894	14	is	be	VBZ
cord-276598-tm0yj2sn	894	15	substituted	substitute	VBN
cord-276598-tm0yj2sn	894	16	by	by	IN
cord-276598-tm0yj2sn	894	17	the	the	DT
cord-276598-tm0yj2sn	894	18	nucleophile	nucleophile	JJ
cord-276598-tm0yj2sn	894	19	amine	amine	NN
cord-276598-tm0yj2sn	894	20	to	to	TO
cord-276598-tm0yj2sn	894	21	give	give	VB
cord-276598-tm0yj2sn	894	22	the	the	DT
cord-276598-tm0yj2sn	894	23	product	product	NN
cord-276598-tm0yj2sn	894	24	.	.	.
cord-276598-tm0yj2sn	895	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	895	2	2020	2020	CD
cord-276598-tm0yj2sn	895	3	,	,	,
cord-276598-tm0yj2sn	895	4	25	25	CD
cord-276598-tm0yj2sn	895	5	,	,	,
cord-276598-tm0yj2sn	895	6	x	x	NN
cord-276598-tm0yj2sn	895	7	FOR	for	IN
cord-276598-tm0yj2sn	895	8	PEER	peer	NN
cord-276598-tm0yj2sn	895	9	REVIEW	REVIEW	NNP
cord-276598-tm0yj2sn	895	10	28	28	CD
cord-276598-tm0yj2sn	895	11	of	of	IN
cord-276598-tm0yj2sn	895	12	37	37	CD
cord-276598-tm0yj2sn	895	13	alkyl	alkyl	NN
cord-276598-tm0yj2sn	895	14	,	,	,
cord-276598-tm0yj2sn	895	15	Ph	Ph	NNP
cord-276598-tm0yj2sn	895	16	)	)	-RRB-
cord-276598-tm0yj2sn	895	17	,	,	,
cord-276598-tm0yj2sn	895	18	while	while	IN
cord-276598-tm0yj2sn	895	19	N2	N2	NNP
cord-276598-tm0yj2sn	895	20	is	be	VBZ
cord-276598-tm0yj2sn	895	21	liberated	liberate	VBN
cord-276598-tm0yj2sn	895	22	.	.	.
cord-276598-tm0yj2sn	896	1	In	in	IN
cord-276598-tm0yj2sn	896	2	the	the	DT
cord-276598-tm0yj2sn	896	3	second	second	JJ
cord-276598-tm0yj2sn	896	4	step	step	NN
cord-276598-tm0yj2sn	896	5	,	,	,
cord-276598-tm0yj2sn	896	6	the	the	DT
cord-276598-tm0yj2sn	896	7	electrophilic	electrophilic	JJ
cord-276598-tm0yj2sn	896	8	nitrene	nitrene	NNP
cord-276598-tm0yj2sn	896	9	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	896	10	radical	radical	NNP
cord-276598-tm0yj2sn	896	11	reacts	react	VBZ
cord-276598-tm0yj2sn	896	12	with	with	IN
cord-276598-tm0yj2sn	896	13	or	or	CC
cord-276598-tm0yj2sn	896	14	is	be	VBZ
cord-276598-tm0yj2sn	896	15	substituted	substitute	VBN
cord-276598-tm0yj2sn	896	16	by	by	IN
cord-276598-tm0yj2sn	896	17	the	the	DT
cord-276598-tm0yj2sn	896	18	nucleophile	nucleophile	JJ
cord-276598-tm0yj2sn	896	19	amine	amine	NN
cord-276598-tm0yj2sn	896	20	to	to	TO
cord-276598-tm0yj2sn	896	21	give	give	VB
cord-276598-tm0yj2sn	896	22	the	the	DT
cord-276598-tm0yj2sn	896	23	product	product	NN
cord-276598-tm0yj2sn	896	24	.	.	.
cord-276598-tm0yj2sn	897	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	897	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	897	3	for	for	IN
cord-276598-tm0yj2sn	897	4	an	an	DT
cord-276598-tm0yj2sn	897	5	organic	organic	JJ
cord-276598-tm0yj2sn	897	6	azide	azide	NN
cord-276598-tm0yj2sn	897	7	route	route	NN
cord-276598-tm0yj2sn	897	8	to	to	IN
cord-276598-tm0yj2sn	897	9	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	897	10	.	.	.
cord-276598-tm0yj2sn	898	1	The	the	DT
cord-276598-tm0yj2sn	898	2	proposed	propose	VBN
cord-276598-tm0yj2sn	898	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	898	4	of	of	IN
cord-276598-tm0yj2sn	898	5	the	the	DT
cord-276598-tm0yj2sn	898	6	reaction	reaction	NN
cord-276598-tm0yj2sn	898	7	for	for	IN
cord-276598-tm0yj2sn	898	8	the	the	DT
cord-276598-tm0yj2sn	898	9	nitro	nitro	NN
cord-276598-tm0yj2sn	898	10	-	-	HYPH
cord-276598-tm0yj2sn	898	11	group	group	NN
cord-276598-tm0yj2sn	898	12	reduction	reduction	NN
cord-276598-tm0yj2sn	898	13	route	route	NN
cord-276598-tm0yj2sn	898	14	involves	involve	VBZ
cord-276598-tm0yj2sn	898	15	the	the	DT
cord-276598-tm0yj2sn	898	16	reduction	reduction	NN
cord-276598-tm0yj2sn	898	17	of	of	IN
cord-276598-tm0yj2sn	898	18	nitrobenzene	nitrobenzene	NN
cord-276598-tm0yj2sn	898	19	in	in	IN
cord-276598-tm0yj2sn	898	20	the	the	DT
cord-276598-tm0yj2sn	898	21	presence	presence	NN
cord-276598-tm0yj2sn	898	22	of	of	IN
cord-276598-tm0yj2sn	898	23	(	(	-LRB-
cord-276598-tm0yj2sn	898	24	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	898	25	(	(	-LRB-
cord-276598-tm0yj2sn	898	26	R	r	NN
cord-276598-tm0yj2sn	898	27	=	=	NN
cord-276598-tm0yj2sn	898	28	alkyl	alkyl	NN
cord-276598-tm0yj2sn	898	29	)	)	-RRB-
cord-276598-tm0yj2sn	898	30	to	to	TO
cord-276598-tm0yj2sn	898	31	give	give	VB
cord-276598-tm0yj2sn	898	32	nitrosobenzene	nitrosobenzene	NN
cord-276598-tm0yj2sn	898	33	with	with	IN
cord-276598-tm0yj2sn	898	34	a	a	DT
cord-276598-tm0yj2sn	898	35	phosphate	phosphate	NN
cord-276598-tm0yj2sn	898	36	side	side	NN
cord-276598-tm0yj2sn	898	37	product	product	NN
cord-276598-tm0yj2sn	898	38	(	(	-LRB-
cord-276598-tm0yj2sn	898	39	Scheme	scheme	NN
cord-276598-tm0yj2sn	898	40	36	36	CD
cord-276598-tm0yj2sn	898	41	)	)	-RRB-
cord-276598-tm0yj2sn	898	42	[	[	-LRB-
cord-276598-tm0yj2sn	898	43	118	118	CD
cord-276598-tm0yj2sn	898	44	]	]	-RRB-
cord-276598-tm0yj2sn	898	45	.	.	.
cord-276598-tm0yj2sn	899	1	In	in	IN
cord-276598-tm0yj2sn	899	2	the	the	DT
cord-276598-tm0yj2sn	899	3	second	second	JJ
cord-276598-tm0yj2sn	899	4	step	step	NN
cord-276598-tm0yj2sn	899	5	,	,	,
cord-276598-tm0yj2sn	899	6	the	the	DT
cord-276598-tm0yj2sn	899	7	nitrosobenzene	nitrosobenzene	NN
cord-276598-tm0yj2sn	899	8	is	be	VBZ
cord-276598-tm0yj2sn	899	9	reduced	reduce	VBN
cord-276598-tm0yj2sn	899	10	further	further	RB
cord-276598-tm0yj2sn	899	11	in	in	IN
cord-276598-tm0yj2sn	899	12	the	the	DT
cord-276598-tm0yj2sn	899	13	presence	presence	NN
cord-276598-tm0yj2sn	899	14	of	of	IN
cord-276598-tm0yj2sn	899	15	another	another	DT
cord-276598-tm0yj2sn	899	16	equivalent	equivalent	NN
cord-276598-tm0yj2sn	899	17	of	of	IN
cord-276598-tm0yj2sn	899	18	(	(	-LRB-
cord-276598-tm0yj2sn	899	19	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	899	20	,	,	,
cord-276598-tm0yj2sn	899	21	generating	generate	VBG
cord-276598-tm0yj2sn	899	22	phenylnitride	phenylnitride	NN
cord-276598-tm0yj2sn	899	23	with	with	IN
cord-276598-tm0yj2sn	899	24	another	another	DT
cord-276598-tm0yj2sn	899	25	phosphate	phosphate	NN
cord-276598-tm0yj2sn	899	26	side	side	NN
cord-276598-tm0yj2sn	899	27	product	product	NN
cord-276598-tm0yj2sn	899	28	.	.	.
cord-276598-tm0yj2sn	900	1	A	a	DT
cord-276598-tm0yj2sn	900	2	further	further	JJ
cord-276598-tm0yj2sn	900	3	reaction	reaction	NN
cord-276598-tm0yj2sn	900	4	of	of	IN
cord-276598-tm0yj2sn	900	5	(	(	-LRB-
cord-276598-tm0yj2sn	900	6	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	900	7	(	(	-LRB-
cord-276598-tm0yj2sn	900	8	R	r	NN
cord-276598-tm0yj2sn	900	9	=	=	NN
cord-276598-tm0yj2sn	900	10	alkyl	alkyl	NN
cord-276598-tm0yj2sn	900	11	)	)	-RRB-
cord-276598-tm0yj2sn	901	1	with	with	IN
cord-276598-tm0yj2sn	901	2	the	the	DT
cord-276598-tm0yj2sn	901	3	basic	basic	JJ
cord-276598-tm0yj2sn	901	4	phenylnitride	phenylnitride	NN
cord-276598-tm0yj2sn	901	5	generates	generate	VBZ
cord-276598-tm0yj2sn	901	6	a	a	DT
cord-276598-tm0yj2sn	901	7	trialkyl	trialkyl	JJ
cord-276598-tm0yj2sn	901	8	phenylphosphorimidate	phenylphosphorimidate	JJ
cord-276598-tm0yj2sn	901	9	intermediate	intermediate	NN
cord-276598-tm0yj2sn	901	10	,	,	,
cord-276598-tm0yj2sn	901	11	which	which	WDT
cord-276598-tm0yj2sn	901	12	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	901	13	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	901	14	to	to	TO
cord-276598-tm0yj2sn	901	15	give	give	VB
cord-276598-tm0yj2sn	901	16	the	the	DT
cord-276598-tm0yj2sn	901	17	desired	desire	VBN
cord-276598-tm0yj2sn	901	18	N	N	NNP
cord-276598-tm0yj2sn	901	19	-	-	HYPH
cord-276598-tm0yj2sn	901	20	arylphosphoramidate	arylphosphoramidate	JJ
cord-276598-tm0yj2sn	901	21	product	product	NN
cord-276598-tm0yj2sn	901	22	.	.	.
cord-276598-tm0yj2sn	902	1	Experiments	experiment	NNS
cord-276598-tm0yj2sn	902	2	to	to	TO
cord-276598-tm0yj2sn	902	3	verify	verify	VB
cord-276598-tm0yj2sn	902	4	the	the	DT
cord-276598-tm0yj2sn	902	5	proposed	propose	VBN
cord-276598-tm0yj2sn	902	6	mechanism	mechanism	NN
cord-276598-tm0yj2sn	902	7	using	use	VBG
cord-276598-tm0yj2sn	902	8	aniline	aniline	NN
cord-276598-tm0yj2sn	902	9	in	in	IN
cord-276598-tm0yj2sn	902	10	the	the	DT
cord-276598-tm0yj2sn	902	11	presence	presence	NN
cord-276598-tm0yj2sn	902	12	of	of	IN
cord-276598-tm0yj2sn	902	13	excess	excess	JJ
cord-276598-tm0yj2sn	902	14	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	902	15	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	902	16	or	or	CC
cord-276598-tm0yj2sn	902	17	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	902	18	phosphate	phosphate	NN
cord-276598-tm0yj2sn	902	19	did	do	VBD
cord-276598-tm0yj2sn	902	20	not	not	RB
cord-276598-tm0yj2sn	902	21	yield	yield	VB
cord-276598-tm0yj2sn	902	22	the	the	DT
cord-276598-tm0yj2sn	902	23	desired	desire	VBN
cord-276598-tm0yj2sn	902	24	product	product	NN
cord-276598-tm0yj2sn	902	25	under	under	IN
cord-276598-tm0yj2sn	902	26	the	the	DT
cord-276598-tm0yj2sn	902	27	optimized	optimize	VBN
cord-276598-tm0yj2sn	902	28	conditions	condition	NNS
cord-276598-tm0yj2sn	902	29	,	,	,
cord-276598-tm0yj2sn	902	30	suggesting	suggest	VBG
cord-276598-tm0yj2sn	902	31	that	that	IN
cord-276598-tm0yj2sn	902	32	the	the	DT
cord-276598-tm0yj2sn	902	33	reaction	reaction	NN
cord-276598-tm0yj2sn	902	34	proceeds	proceed	VBZ
cord-276598-tm0yj2sn	902	35	via	via	IN
cord-276598-tm0yj2sn	902	36	reduction	reduction	NN
cord-276598-tm0yj2sn	902	37	of	of	IN
cord-276598-tm0yj2sn	902	38	the	the	DT
cord-276598-tm0yj2sn	902	39	nitro	nitro	NN
cord-276598-tm0yj2sn	902	40	group	group	NN
cord-276598-tm0yj2sn	902	41	to	to	IN
cord-276598-tm0yj2sn	902	42	N	n	CD
cord-276598-tm0yj2sn	902	43	2−	2−	CD
cord-276598-tm0yj2sn	902	44	and	and	CC
cord-276598-tm0yj2sn	902	45	that	that	IN
cord-276598-tm0yj2sn	902	46	the	the	DT
cord-276598-tm0yj2sn	902	47	product	product	NN
cord-276598-tm0yj2sn	902	48	is	be	VBZ
cord-276598-tm0yj2sn	902	49	not	not	RB
cord-276598-tm0yj2sn	902	50	formed	form	VBN
cord-276598-tm0yj2sn	902	51	from	from	IN
cord-276598-tm0yj2sn	902	52	phosphate	phosphate	NN
cord-276598-tm0yj2sn	902	53	.	.	.
cord-276598-tm0yj2sn	903	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	903	2	36	36	CD
cord-276598-tm0yj2sn	903	3	.	.	.
cord-276598-tm0yj2sn	904	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	904	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	904	3	for	for	IN
cord-276598-tm0yj2sn	904	4	reduction	reduction	NN
cord-276598-tm0yj2sn	904	5	of	of	IN
cord-276598-tm0yj2sn	904	6	the	the	DT
cord-276598-tm0yj2sn	904	7	nitro	nitro	NN
cord-276598-tm0yj2sn	904	8	-	-	HYPH
cord-276598-tm0yj2sn	904	9	group	group	NN
cord-276598-tm0yj2sn	904	10	route	route	NN
cord-276598-tm0yj2sn	904	11	to	to	IN
cord-276598-tm0yj2sn	904	12	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	904	13	.	.	.
cord-276598-tm0yj2sn	905	1	The	the	DT
cord-276598-tm0yj2sn	905	2	plausible	plausible	JJ
cord-276598-tm0yj2sn	905	3	two	two	CD
cord-276598-tm0yj2sn	905	4	-	-	HYPH
cord-276598-tm0yj2sn	905	5	step	step	NN
cord-276598-tm0yj2sn	905	6	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	905	7	process	process	NN
cord-276598-tm0yj2sn	905	8	suggested	suggest	VBN
cord-276598-tm0yj2sn	905	9	by	by	IN
cord-276598-tm0yj2sn	905	10	Hackenberger	Hackenberger	NNP
cord-276598-tm0yj2sn	905	11	's	's	POS
cord-276598-tm0yj2sn	905	12	group	group	NN
cord-276598-tm0yj2sn	905	13	for	for	IN
cord-276598-tm0yj2sn	905	14	the	the	DT
cord-276598-tm0yj2sn	905	15	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	905	16	35	35	CD
cord-276598-tm0yj2sn	905	17	.	.	.
cord-276598-tm0yj2sn	906	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	906	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	906	3	for	for	IN
cord-276598-tm0yj2sn	906	4	an	an	DT
cord-276598-tm0yj2sn	906	5	organic	organic	JJ
cord-276598-tm0yj2sn	906	6	azide	azide	NN
cord-276598-tm0yj2sn	906	7	route	route	NN
cord-276598-tm0yj2sn	906	8	to	to	IN
cord-276598-tm0yj2sn	906	9	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	906	10	.	.	.
cord-276598-tm0yj2sn	907	1	The	the	DT
cord-276598-tm0yj2sn	907	2	proposed	propose	VBN
cord-276598-tm0yj2sn	907	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	907	4	of	of	IN
cord-276598-tm0yj2sn	907	5	the	the	DT
cord-276598-tm0yj2sn	907	6	reaction	reaction	NN
cord-276598-tm0yj2sn	907	7	for	for	IN
cord-276598-tm0yj2sn	907	8	the	the	DT
cord-276598-tm0yj2sn	907	9	nitro	nitro	NN
cord-276598-tm0yj2sn	907	10	-	-	HYPH
cord-276598-tm0yj2sn	907	11	group	group	NN
cord-276598-tm0yj2sn	907	12	reduction	reduction	NN
cord-276598-tm0yj2sn	907	13	route	route	NN
cord-276598-tm0yj2sn	907	14	involves	involve	VBZ
cord-276598-tm0yj2sn	907	15	the	the	DT
cord-276598-tm0yj2sn	907	16	reduction	reduction	NN
cord-276598-tm0yj2sn	907	17	of	of	IN
cord-276598-tm0yj2sn	907	18	nitrobenzene	nitrobenzene	NN
cord-276598-tm0yj2sn	907	19	in	in	IN
cord-276598-tm0yj2sn	907	20	the	the	DT
cord-276598-tm0yj2sn	907	21	presence	presence	NN
cord-276598-tm0yj2sn	907	22	of	of	IN
cord-276598-tm0yj2sn	907	23	(	(	-LRB-
cord-276598-tm0yj2sn	907	24	RO	ro	NN
cord-276598-tm0yj2sn	907	25	)	)	-RRB-
cord-276598-tm0yj2sn	907	26	3	3	CD
cord-276598-tm0yj2sn	907	27	P	p	NN
cord-276598-tm0yj2sn	907	28	(	(	-LRB-
cord-276598-tm0yj2sn	907	29	R	r	NN
cord-276598-tm0yj2sn	907	30	=	=	NN
cord-276598-tm0yj2sn	907	31	alkyl	alkyl	NN
cord-276598-tm0yj2sn	907	32	)	)	-RRB-
cord-276598-tm0yj2sn	907	33	to	to	TO
cord-276598-tm0yj2sn	907	34	give	give	VB
cord-276598-tm0yj2sn	907	35	nitrosobenzene	nitrosobenzene	NN
cord-276598-tm0yj2sn	907	36	with	with	IN
cord-276598-tm0yj2sn	907	37	a	a	DT
cord-276598-tm0yj2sn	907	38	phosphate	phosphate	NN
cord-276598-tm0yj2sn	907	39	side	side	NN
cord-276598-tm0yj2sn	907	40	product	product	NN
cord-276598-tm0yj2sn	907	41	(	(	-LRB-
cord-276598-tm0yj2sn	907	42	Scheme	scheme	NN
cord-276598-tm0yj2sn	907	43	36	36	CD
cord-276598-tm0yj2sn	907	44	)	)	-RRB-
cord-276598-tm0yj2sn	907	45	[	[	-LRB-
cord-276598-tm0yj2sn	907	46	118	118	CD
cord-276598-tm0yj2sn	907	47	]	]	-RRB-
cord-276598-tm0yj2sn	907	48	.	.	.
cord-276598-tm0yj2sn	908	1	In	in	IN
cord-276598-tm0yj2sn	908	2	the	the	DT
cord-276598-tm0yj2sn	908	3	second	second	JJ
cord-276598-tm0yj2sn	908	4	step	step	NN
cord-276598-tm0yj2sn	908	5	,	,	,
cord-276598-tm0yj2sn	908	6	the	the	DT
cord-276598-tm0yj2sn	908	7	nitrosobenzene	nitrosobenzene	NN
cord-276598-tm0yj2sn	908	8	is	be	VBZ
cord-276598-tm0yj2sn	908	9	reduced	reduce	VBN
cord-276598-tm0yj2sn	908	10	further	further	RB
cord-276598-tm0yj2sn	908	11	in	in	IN
cord-276598-tm0yj2sn	908	12	the	the	DT
cord-276598-tm0yj2sn	908	13	presence	presence	NN
cord-276598-tm0yj2sn	908	14	of	of	IN
cord-276598-tm0yj2sn	908	15	another	another	DT
cord-276598-tm0yj2sn	908	16	equivalent	equivalent	NN
cord-276598-tm0yj2sn	908	17	of	of	IN
cord-276598-tm0yj2sn	908	18	(	(	-LRB-
cord-276598-tm0yj2sn	908	19	RO	ro	NN
cord-276598-tm0yj2sn	908	20	)	)	-RRB-
cord-276598-tm0yj2sn	908	21	3	3	CD
cord-276598-tm0yj2sn	908	22	P	p	NN
cord-276598-tm0yj2sn	908	23	,	,	,
cord-276598-tm0yj2sn	908	24	generating	generate	VBG
cord-276598-tm0yj2sn	908	25	phenylnitride	phenylnitride	NN
cord-276598-tm0yj2sn	908	26	with	with	IN
cord-276598-tm0yj2sn	908	27	another	another	DT
cord-276598-tm0yj2sn	908	28	phosphate	phosphate	NN
cord-276598-tm0yj2sn	908	29	side	side	NN
cord-276598-tm0yj2sn	908	30	product	product	NN
cord-276598-tm0yj2sn	908	31	.	.	.
cord-276598-tm0yj2sn	909	1	A	a	DT
cord-276598-tm0yj2sn	909	2	further	further	JJ
cord-276598-tm0yj2sn	909	3	reaction	reaction	NN
cord-276598-tm0yj2sn	909	4	of	of	IN
cord-276598-tm0yj2sn	909	5	(	(	-LRB-
cord-276598-tm0yj2sn	909	6	RO	ro	NN
cord-276598-tm0yj2sn	909	7	)	)	-RRB-
cord-276598-tm0yj2sn	909	8	3	3	CD
cord-276598-tm0yj2sn	909	9	P	p	NN
cord-276598-tm0yj2sn	909	10	(	(	-LRB-
cord-276598-tm0yj2sn	909	11	R	r	NN
cord-276598-tm0yj2sn	909	12	=	=	NN
cord-276598-tm0yj2sn	909	13	alkyl	alkyl	NN
cord-276598-tm0yj2sn	909	14	)	)	-RRB-
cord-276598-tm0yj2sn	909	15	with	with	IN
cord-276598-tm0yj2sn	909	16	the	the	DT
cord-276598-tm0yj2sn	909	17	basic	basic	JJ
cord-276598-tm0yj2sn	909	18	phenylnitride	phenylnitride	NN
cord-276598-tm0yj2sn	909	19	generates	generate	VBZ
cord-276598-tm0yj2sn	909	20	a	a	DT
cord-276598-tm0yj2sn	909	21	trialkyl	trialkyl	JJ
cord-276598-tm0yj2sn	909	22	phenylphosphorimidate	phenylphosphorimidate	JJ
cord-276598-tm0yj2sn	909	23	intermediate	intermediate	NN
cord-276598-tm0yj2sn	909	24	,	,	,
cord-276598-tm0yj2sn	909	25	which	which	WDT
cord-276598-tm0yj2sn	909	26	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	909	27	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	909	28	to	to	TO
cord-276598-tm0yj2sn	909	29	give	give	VB
cord-276598-tm0yj2sn	909	30	the	the	DT
cord-276598-tm0yj2sn	909	31	desired	desire	VBN
cord-276598-tm0yj2sn	909	32	N	N	NNP
cord-276598-tm0yj2sn	909	33	-	-	HYPH
cord-276598-tm0yj2sn	909	34	arylphosphoramidate	arylphosphoramidate	JJ
cord-276598-tm0yj2sn	909	35	product	product	NN
cord-276598-tm0yj2sn	909	36	.	.	.
cord-276598-tm0yj2sn	910	1	Experiments	experiment	NNS
cord-276598-tm0yj2sn	910	2	to	to	TO
cord-276598-tm0yj2sn	910	3	verify	verify	VB
cord-276598-tm0yj2sn	910	4	the	the	DT
cord-276598-tm0yj2sn	910	5	proposed	propose	VBN
cord-276598-tm0yj2sn	910	6	mechanism	mechanism	NN
cord-276598-tm0yj2sn	910	7	using	use	VBG
cord-276598-tm0yj2sn	910	8	aniline	aniline	NN
cord-276598-tm0yj2sn	910	9	in	in	IN
cord-276598-tm0yj2sn	910	10	the	the	DT
cord-276598-tm0yj2sn	910	11	presence	presence	NN
cord-276598-tm0yj2sn	910	12	of	of	IN
cord-276598-tm0yj2sn	910	13	excess	excess	JJ
cord-276598-tm0yj2sn	910	14	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	910	15	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	910	16	or	or	CC
cord-276598-tm0yj2sn	910	17	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	910	18	phosphate	phosphate	NN
cord-276598-tm0yj2sn	910	19	did	do	VBD
cord-276598-tm0yj2sn	910	20	not	not	RB
cord-276598-tm0yj2sn	910	21	yield	yield	VB
cord-276598-tm0yj2sn	910	22	the	the	DT
cord-276598-tm0yj2sn	910	23	desired	desire	VBN
cord-276598-tm0yj2sn	910	24	product	product	NN
cord-276598-tm0yj2sn	910	25	under	under	IN
cord-276598-tm0yj2sn	910	26	the	the	DT
cord-276598-tm0yj2sn	910	27	optimized	optimize	VBN
cord-276598-tm0yj2sn	910	28	conditions	condition	NNS
cord-276598-tm0yj2sn	910	29	,	,	,
cord-276598-tm0yj2sn	910	30	suggesting	suggest	VBG
cord-276598-tm0yj2sn	910	31	that	that	IN
cord-276598-tm0yj2sn	910	32	the	the	DT
cord-276598-tm0yj2sn	910	33	reaction	reaction	NN
cord-276598-tm0yj2sn	910	34	proceeds	proceed	VBZ
cord-276598-tm0yj2sn	910	35	via	via	IN
cord-276598-tm0yj2sn	910	36	reduction	reduction	NN
cord-276598-tm0yj2sn	910	37	of	of	IN
cord-276598-tm0yj2sn	910	38	the	the	DT
cord-276598-tm0yj2sn	910	39	nitro	nitro	NN
cord-276598-tm0yj2sn	910	40	group	group	NN
cord-276598-tm0yj2sn	910	41	to	to	IN
cord-276598-tm0yj2sn	910	42	N	n	CD
cord-276598-tm0yj2sn	910	43	2−	2−	CD
cord-276598-tm0yj2sn	910	44	and	and	CC
cord-276598-tm0yj2sn	910	45	that	that	IN
cord-276598-tm0yj2sn	910	46	the	the	DT
cord-276598-tm0yj2sn	910	47	product	product	NN
cord-276598-tm0yj2sn	910	48	is	be	VBZ
cord-276598-tm0yj2sn	910	49	not	not	RB
cord-276598-tm0yj2sn	910	50	formed	form	VBN
cord-276598-tm0yj2sn	910	51	from	from	IN
cord-276598-tm0yj2sn	910	52	phosphate	phosphate	NN
cord-276598-tm0yj2sn	910	53	.	.	.
cord-276598-tm0yj2sn	911	1	in	in	IN
cord-276598-tm0yj2sn	911	2	the	the	DT
cord-276598-tm0yj2sn	911	3	presence	presence	NN
cord-276598-tm0yj2sn	911	4	of	of	IN
cord-276598-tm0yj2sn	911	5	another	another	DT
cord-276598-tm0yj2sn	911	6	equivalent	equivalent	NN
cord-276598-tm0yj2sn	911	7	of	of	IN
cord-276598-tm0yj2sn	911	8	(	(	-LRB-
cord-276598-tm0yj2sn	911	9	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	911	10	,	,	,
cord-276598-tm0yj2sn	911	11	generating	generate	VBG
cord-276598-tm0yj2sn	911	12	phenylnitride	phenylnitride	NN
cord-276598-tm0yj2sn	911	13	with	with	IN
cord-276598-tm0yj2sn	911	14	another	another	DT
cord-276598-tm0yj2sn	911	15	phosphate	phosphate	NN
cord-276598-tm0yj2sn	911	16	side	side	NN
cord-276598-tm0yj2sn	911	17	product	product	NN
cord-276598-tm0yj2sn	911	18	.	.	.
cord-276598-tm0yj2sn	912	1	A	a	DT
cord-276598-tm0yj2sn	912	2	further	further	JJ
cord-276598-tm0yj2sn	912	3	reaction	reaction	NN
cord-276598-tm0yj2sn	912	4	of	of	IN
cord-276598-tm0yj2sn	912	5	(	(	-LRB-
cord-276598-tm0yj2sn	912	6	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	912	7	(	(	-LRB-
cord-276598-tm0yj2sn	912	8	R	r	NN
cord-276598-tm0yj2sn	912	9	=	=	NN
cord-276598-tm0yj2sn	912	10	alkyl	alkyl	NN
cord-276598-tm0yj2sn	912	11	)	)	-RRB-
cord-276598-tm0yj2sn	913	1	with	with	IN
cord-276598-tm0yj2sn	913	2	the	the	DT
cord-276598-tm0yj2sn	913	3	basic	basic	JJ
cord-276598-tm0yj2sn	913	4	phenylnitride	phenylnitride	NN
cord-276598-tm0yj2sn	913	5	generates	generate	VBZ
cord-276598-tm0yj2sn	913	6	a	a	DT
cord-276598-tm0yj2sn	913	7	trialkyl	trialkyl	JJ
cord-276598-tm0yj2sn	913	8	phenylphosphorimidate	phenylphosphorimidate	JJ
cord-276598-tm0yj2sn	913	9	intermediate	intermediate	NN
cord-276598-tm0yj2sn	913	10	,	,	,
cord-276598-tm0yj2sn	913	11	which	which	WDT
cord-276598-tm0yj2sn	913	12	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	913	13	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	913	14	to	to	TO
cord-276598-tm0yj2sn	913	15	give	give	VB
cord-276598-tm0yj2sn	913	16	the	the	DT
cord-276598-tm0yj2sn	913	17	desired	desire	VBN
cord-276598-tm0yj2sn	913	18	N	N	NNP
cord-276598-tm0yj2sn	913	19	-	-	HYPH
cord-276598-tm0yj2sn	913	20	arylphosphoramidate	arylphosphoramidate	JJ
cord-276598-tm0yj2sn	913	21	product	product	NN
cord-276598-tm0yj2sn	913	22	.	.	.
cord-276598-tm0yj2sn	914	1	Experiments	experiment	NNS
cord-276598-tm0yj2sn	914	2	to	to	TO
cord-276598-tm0yj2sn	914	3	verify	verify	VB
cord-276598-tm0yj2sn	914	4	the	the	DT
cord-276598-tm0yj2sn	914	5	proposed	propose	VBN
cord-276598-tm0yj2sn	914	6	mechanism	mechanism	NN
cord-276598-tm0yj2sn	914	7	using	use	VBG
cord-276598-tm0yj2sn	914	8	aniline	aniline	NN
cord-276598-tm0yj2sn	914	9	in	in	IN
cord-276598-tm0yj2sn	914	10	the	the	DT
cord-276598-tm0yj2sn	914	11	presence	presence	NN
cord-276598-tm0yj2sn	914	12	of	of	IN
cord-276598-tm0yj2sn	914	13	excess	excess	JJ
cord-276598-tm0yj2sn	914	14	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	914	15	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	914	16	or	or	CC
cord-276598-tm0yj2sn	914	17	triethyl	triethyl	NNP
cord-276598-tm0yj2sn	914	18	phosphate	phosphate	NN
cord-276598-tm0yj2sn	914	19	did	do	VBD
cord-276598-tm0yj2sn	914	20	not	not	RB
cord-276598-tm0yj2sn	914	21	yield	yield	VB
cord-276598-tm0yj2sn	914	22	the	the	DT
cord-276598-tm0yj2sn	914	23	desired	desire	VBN
cord-276598-tm0yj2sn	914	24	product	product	NN
cord-276598-tm0yj2sn	914	25	under	under	IN
cord-276598-tm0yj2sn	914	26	the	the	DT
cord-276598-tm0yj2sn	914	27	optimized	optimize	VBN
cord-276598-tm0yj2sn	914	28	conditions	condition	NNS
cord-276598-tm0yj2sn	914	29	,	,	,
cord-276598-tm0yj2sn	914	30	suggesting	suggest	VBG
cord-276598-tm0yj2sn	914	31	that	that	IN
cord-276598-tm0yj2sn	914	32	the	the	DT
cord-276598-tm0yj2sn	914	33	reaction	reaction	NN
cord-276598-tm0yj2sn	914	34	proceeds	proceed	VBZ
cord-276598-tm0yj2sn	914	35	via	via	IN
cord-276598-tm0yj2sn	914	36	reduction	reduction	NN
cord-276598-tm0yj2sn	914	37	of	of	IN
cord-276598-tm0yj2sn	914	38	the	the	DT
cord-276598-tm0yj2sn	914	39	nitro	nitro	NN
cord-276598-tm0yj2sn	914	40	group	group	NN
cord-276598-tm0yj2sn	914	41	to	to	IN
cord-276598-tm0yj2sn	914	42	N	n	CD
cord-276598-tm0yj2sn	914	43	2−	2−	CD
cord-276598-tm0yj2sn	914	44	and	and	CC
cord-276598-tm0yj2sn	914	45	that	that	IN
cord-276598-tm0yj2sn	914	46	the	the	DT
cord-276598-tm0yj2sn	914	47	product	product	NN
cord-276598-tm0yj2sn	914	48	is	be	VBZ
cord-276598-tm0yj2sn	914	49	not	not	RB
cord-276598-tm0yj2sn	914	50	formed	form	VBN
cord-276598-tm0yj2sn	914	51	from	from	IN
cord-276598-tm0yj2sn	914	52	phosphate	phosphate	NN
cord-276598-tm0yj2sn	914	53	.	.	.
cord-276598-tm0yj2sn	915	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	915	2	36	36	CD
cord-276598-tm0yj2sn	915	3	.	.	.
cord-276598-tm0yj2sn	916	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	916	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	916	3	for	for	IN
cord-276598-tm0yj2sn	916	4	reduction	reduction	NN
cord-276598-tm0yj2sn	916	5	of	of	IN
cord-276598-tm0yj2sn	916	6	the	the	DT
cord-276598-tm0yj2sn	916	7	nitro	nitro	NN
cord-276598-tm0yj2sn	916	8	-	-	HYPH
cord-276598-tm0yj2sn	916	9	group	group	NN
cord-276598-tm0yj2sn	916	10	route	route	NN
cord-276598-tm0yj2sn	916	11	to	to	IN
cord-276598-tm0yj2sn	916	12	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	916	13	.	.	.
cord-276598-tm0yj2sn	917	1	The	the	DT
cord-276598-tm0yj2sn	917	2	plausible	plausible	JJ
cord-276598-tm0yj2sn	917	3	two	two	CD
cord-276598-tm0yj2sn	917	4	-	-	HYPH
cord-276598-tm0yj2sn	917	5	step	step	NN
cord-276598-tm0yj2sn	917	6	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	917	7	process	process	NN
cord-276598-tm0yj2sn	917	8	suggested	suggest	VBN
cord-276598-tm0yj2sn	917	9	by	by	IN
cord-276598-tm0yj2sn	917	10	Hackenberger	Hackenberger	NNP
cord-276598-tm0yj2sn	917	11	's	's	POS
cord-276598-tm0yj2sn	917	12	group	group	NN
cord-276598-tm0yj2sn	917	13	for	for	IN
cord-276598-tm0yj2sn	917	14	the	the	DT
cord-276598-tm0yj2sn	917	15	synthesis	synthesis	NN
cord-276598-tm0yj2sn	917	16	involves	involve	VBZ
cord-276598-tm0yj2sn	917	17	the	the	DT
cord-276598-tm0yj2sn	917	18	formation	formation	NN
cord-276598-tm0yj2sn	917	19	of	of	IN
cord-276598-tm0yj2sn	917	20	phosphorimidate	phosphorimidate	NNP
cord-276598-tm0yj2sn	917	21	from	from	IN
cord-276598-tm0yj2sn	917	22	the	the	DT
cord-276598-tm0yj2sn	917	23	reduction	reduction	NN
cord-276598-tm0yj2sn	917	24	of	of	IN
cord-276598-tm0yj2sn	917	25	azide	azide	NN
cord-276598-tm0yj2sn	917	26	in	in	IN
cord-276598-tm0yj2sn	917	27	the	the	DT
cord-276598-tm0yj2sn	917	28	presence	presence	NN
cord-276598-tm0yj2sn	917	29	of	of	IN
cord-276598-tm0yj2sn	917	30	(	(	-LRB-
cord-276598-tm0yj2sn	917	31	RO)3P	RO)3P	NNP
cord-276598-tm0yj2sn	917	32	(	(	-LRB-
cord-276598-tm0yj2sn	917	33	R	r	NN
cord-276598-tm0yj2sn	917	34	=	=	NN
cord-276598-tm0yj2sn	917	35	alkyl	alkyl	NN
cord-276598-tm0yj2sn	917	36	)	)	-RRB-
cord-276598-tm0yj2sn	917	37	,	,	,
cord-276598-tm0yj2sn	917	38	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	917	39	N2	N2	NNP
cord-276598-tm0yj2sn	917	40	,	,	,
cord-276598-tm0yj2sn	917	41	in	in	IN
cord-276598-tm0yj2sn	917	42	the	the	DT
cord-276598-tm0yj2sn	917	43	first	first	JJ
cord-276598-tm0yj2sn	917	44	step	step	NN
cord-276598-tm0yj2sn	917	45	(	(	-LRB-
cord-276598-tm0yj2sn	917	46	Scheme	scheme	NN
cord-276598-tm0yj2sn	917	47	37	37	CD
cord-276598-tm0yj2sn	917	48	)	)	-RRB-
cord-276598-tm0yj2sn	917	49	[	[	-LRB-
cord-276598-tm0yj2sn	917	50	119	119	CD
cord-276598-tm0yj2sn	917	51	]	]	-RRB-
cord-276598-tm0yj2sn	917	52	.	.	.
cord-276598-tm0yj2sn	918	1	In	in	IN
cord-276598-tm0yj2sn	918	2	the	the	DT
cord-276598-tm0yj2sn	918	3	second	second	JJ
cord-276598-tm0yj2sn	918	4	step	step	NN
cord-276598-tm0yj2sn	918	5	,	,	,
cord-276598-tm0yj2sn	918	6	BF3	BF3	NNP
cord-276598-tm0yj2sn	918	7	activates	activate	VBZ
cord-276598-tm0yj2sn	918	8	the	the	DT
cord-276598-tm0yj2sn	918	9	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	918	10	site	site	NN
cord-276598-tm0yj2sn	918	11	of	of	IN
cord-276598-tm0yj2sn	918	12	the	the	DT
cord-276598-tm0yj2sn	918	13	phosphorimidate	phosphorimidate	NN
cord-276598-tm0yj2sn	918	14	by	by	IN
cord-276598-tm0yj2sn	918	15	forming	form	VBG
cord-276598-tm0yj2sn	918	16	a	a	DT
cord-276598-tm0yj2sn	918	17	coordinated	coordinated	JJ
cord-276598-tm0yj2sn	918	18	complex	complex	NN
cord-276598-tm0yj2sn	918	19	.	.	.
cord-276598-tm0yj2sn	919	1	Electrophilic	Electrophilic	NNP
cord-276598-tm0yj2sn	919	2	attack	attack	NN
cord-276598-tm0yj2sn	919	3	by	by	IN
cord-276598-tm0yj2sn	919	4	a	a	DT
cord-276598-tm0yj2sn	919	5	neighbouring	neighbouring	JJ
cord-276598-tm0yj2sn	919	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	919	7	group	group	NN
cord-276598-tm0yj2sn	919	8	of	of	IN
cord-276598-tm0yj2sn	919	9	phosphorimidate	phosphorimidate	NNP
cord-276598-tm0yj2sn	919	10	on	on	IN
cord-276598-tm0yj2sn	919	11	the	the	DT
cord-276598-tm0yj2sn	919	12	negatively	negatively	RB
cord-276598-tm0yj2sn	919	13	charged	charge	VBN
cord-276598-tm0yj2sn	919	14	N	n	CD
cord-276598-tm0yj2sn	919	15	atom	atom	NN
cord-276598-tm0yj2sn	919	16	of	of	IN
cord-276598-tm0yj2sn	919	17	the	the	DT
cord-276598-tm0yj2sn	919	18	phosphorimidate	phosphorimidate	NNP
cord-276598-tm0yj2sn	919	19	-	-	HYPH
cord-276598-tm0yj2sn	919	20	BF3	BF3	NNP
cord-276598-tm0yj2sn	919	21	complex	complex	JJ
cord-276598-tm0yj2sn	919	22	results	result	NNS
cord-276598-tm0yj2sn	919	23	in	in	IN
cord-276598-tm0yj2sn	919	24	an	an	DT
cord-276598-tm0yj2sn	919	25	(	(	-LRB-
cord-276598-tm0yj2sn	919	26	(	(	-LRB-
cord-276598-tm0yj2sn	919	27	alkyl)amino)trialkoxyphosphonium	alkyl)amino)trialkoxyphosphonium	CD
cord-276598-tm0yj2sn	919	28	complex	complex	NN
cord-276598-tm0yj2sn	919	29	,	,	,
cord-276598-tm0yj2sn	919	30	cleaving	cleave	VBG
cord-276598-tm0yj2sn	919	31	off	off	RP
cord-276598-tm0yj2sn	919	32	BF3	BF3	NNP
cord-276598-tm0yj2sn	919	33	.	.	.
cord-276598-tm0yj2sn	920	1	Nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	920	2	attack	attack	NN
cord-276598-tm0yj2sn	920	3	on	on	IN
cord-276598-tm0yj2sn	920	4	the	the	DT
cord-276598-tm0yj2sn	920	5	trialkoxyphosphonium	trialkoxyphosphonium	NN
cord-276598-tm0yj2sn	920	6	complex	complex	NN
cord-276598-tm0yj2sn	920	7	from	from	IN
cord-276598-tm0yj2sn	920	8	a	a	DT
cord-276598-tm0yj2sn	920	9	neighboring	neighbor	VBG
cord-276598-tm0yj2sn	920	10	phosphorimidate	phosphorimidate	NN
cord-276598-tm0yj2sn	920	11	completes	complete	VBZ
cord-276598-tm0yj2sn	920	12	the	the	DT
cord-276598-tm0yj2sn	920	13	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	920	14	cycle	cycle	NN
cord-276598-tm0yj2sn	920	15	,	,	,
cord-276598-tm0yj2sn	920	16	affording	afford	VBG
cord-276598-tm0yj2sn	920	17	a	a	DT
cord-276598-tm0yj2sn	920	18	P	p	NN
cord-276598-tm0yj2sn	920	19	=	=	SYM
cord-276598-tm0yj2sn	920	20	O	o	NN
cord-276598-tm0yj2sn	920	21	bond	bond	NN
cord-276598-tm0yj2sn	920	22	of	of	IN
cord-276598-tm0yj2sn	920	23	the	the	DT
cord-276598-tm0yj2sn	920	24	desired	desire	VBN
cord-276598-tm0yj2sn	920	25	P	P	NNP
cord-276598-tm0yj2sn	920	26	-	-	HYPH
cord-276598-tm0yj2sn	920	27	N	n	CD
cord-276598-tm0yj2sn	920	28	product	product	NN
cord-276598-tm0yj2sn	920	29	.	.	.
cord-276598-tm0yj2sn	921	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	921	2	36	36	CD
cord-276598-tm0yj2sn	921	3	.	.	.
cord-276598-tm0yj2sn	922	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	922	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	922	3	for	for	IN
cord-276598-tm0yj2sn	922	4	reduction	reduction	NN
cord-276598-tm0yj2sn	922	5	of	of	IN
cord-276598-tm0yj2sn	922	6	the	the	DT
cord-276598-tm0yj2sn	922	7	nitro	nitro	NN
cord-276598-tm0yj2sn	922	8	-	-	HYPH
cord-276598-tm0yj2sn	922	9	group	group	NN
cord-276598-tm0yj2sn	922	10	route	route	NN
cord-276598-tm0yj2sn	922	11	to	to	IN
cord-276598-tm0yj2sn	922	12	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	922	13	.	.	.
cord-276598-tm0yj2sn	923	1	The	the	DT
cord-276598-tm0yj2sn	923	2	plausible	plausible	JJ
cord-276598-tm0yj2sn	923	3	two	two	CD
cord-276598-tm0yj2sn	923	4	-	-	HYPH
cord-276598-tm0yj2sn	923	5	step	step	NN
cord-276598-tm0yj2sn	923	6	mechanistic	mechanistic	JJ
cord-276598-tm0yj2sn	923	7	process	process	NN
cord-276598-tm0yj2sn	923	8	suggested	suggest	VBN
cord-276598-tm0yj2sn	923	9	by	by	IN
cord-276598-tm0yj2sn	923	10	Hackenberger	Hackenberger	NNP
cord-276598-tm0yj2sn	923	11	's	's	POS
cord-276598-tm0yj2sn	923	12	group	group	NN
cord-276598-tm0yj2sn	923	13	for	for	IN
cord-276598-tm0yj2sn	923	14	the	the	DT
cord-276598-tm0yj2sn	923	15	synthesis	synthesis	NN
cord-276598-tm0yj2sn	923	16	involves	involve	VBZ
cord-276598-tm0yj2sn	923	17	the	the	DT
cord-276598-tm0yj2sn	923	18	formation	formation	NN
cord-276598-tm0yj2sn	923	19	of	of	IN
cord-276598-tm0yj2sn	923	20	phosphorimidate	phosphorimidate	NNP
cord-276598-tm0yj2sn	923	21	from	from	IN
cord-276598-tm0yj2sn	923	22	the	the	DT
cord-276598-tm0yj2sn	923	23	reduction	reduction	NN
cord-276598-tm0yj2sn	923	24	of	of	IN
cord-276598-tm0yj2sn	923	25	azide	azide	NN
cord-276598-tm0yj2sn	923	26	in	in	IN
cord-276598-tm0yj2sn	923	27	the	the	DT
cord-276598-tm0yj2sn	923	28	presence	presence	NN
cord-276598-tm0yj2sn	923	29	of	of	IN
cord-276598-tm0yj2sn	923	30	(	(	-LRB-
cord-276598-tm0yj2sn	923	31	RO	ro	NN
cord-276598-tm0yj2sn	923	32	)	)	-RRB-
cord-276598-tm0yj2sn	923	33	3	3	CD
cord-276598-tm0yj2sn	923	34	P	p	NN
cord-276598-tm0yj2sn	923	35	(	(	-LRB-
cord-276598-tm0yj2sn	923	36	R	r	NN
cord-276598-tm0yj2sn	923	37	=	=	NN
cord-276598-tm0yj2sn	923	38	alkyl	alkyl	NN
cord-276598-tm0yj2sn	923	39	)	)	-RRB-
cord-276598-tm0yj2sn	923	40	,	,	,
cord-276598-tm0yj2sn	923	41	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	923	42	N	n	CD
cord-276598-tm0yj2sn	923	43	2	2	CD
cord-276598-tm0yj2sn	923	44	,	,	,
cord-276598-tm0yj2sn	923	45	in	in	IN
cord-276598-tm0yj2sn	923	46	the	the	DT
cord-276598-tm0yj2sn	923	47	first	first	JJ
cord-276598-tm0yj2sn	923	48	step	step	NN
cord-276598-tm0yj2sn	923	49	(	(	-LRB-
cord-276598-tm0yj2sn	923	50	Scheme	scheme	NN
cord-276598-tm0yj2sn	923	51	37	37	CD
cord-276598-tm0yj2sn	923	52	)	)	-RRB-
cord-276598-tm0yj2sn	923	53	[	[	-LRB-
cord-276598-tm0yj2sn	923	54	119	119	CD
cord-276598-tm0yj2sn	923	55	]	]	-RRB-
cord-276598-tm0yj2sn	923	56	.	.	.
cord-276598-tm0yj2sn	924	1	In	in	IN
cord-276598-tm0yj2sn	924	2	the	the	DT
cord-276598-tm0yj2sn	924	3	second	second	JJ
cord-276598-tm0yj2sn	924	4	step	step	NN
cord-276598-tm0yj2sn	924	5	,	,	,
cord-276598-tm0yj2sn	924	6	BF	BF	NNP
cord-276598-tm0yj2sn	924	7	3	3	CD
cord-276598-tm0yj2sn	924	8	activates	activate	VBZ
cord-276598-tm0yj2sn	924	9	the	the	DT
cord-276598-tm0yj2sn	924	10	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	924	11	site	site	NN
cord-276598-tm0yj2sn	924	12	of	of	IN
cord-276598-tm0yj2sn	924	13	the	the	DT
cord-276598-tm0yj2sn	924	14	phosphorimidate	phosphorimidate	NN
cord-276598-tm0yj2sn	924	15	by	by	IN
cord-276598-tm0yj2sn	924	16	forming	form	VBG
cord-276598-tm0yj2sn	924	17	a	a	DT
cord-276598-tm0yj2sn	924	18	coordinated	coordinated	JJ
cord-276598-tm0yj2sn	924	19	complex	complex	NN
cord-276598-tm0yj2sn	924	20	.	.	.
cord-276598-tm0yj2sn	925	1	Electrophilic	Electrophilic	NNP
cord-276598-tm0yj2sn	925	2	attack	attack	NN
cord-276598-tm0yj2sn	925	3	by	by	IN
cord-276598-tm0yj2sn	925	4	a	a	DT
cord-276598-tm0yj2sn	925	5	neighbouring	neighbouring	JJ
cord-276598-tm0yj2sn	925	6	alkyl	alkyl	NN
cord-276598-tm0yj2sn	925	7	group	group	NN
cord-276598-tm0yj2sn	925	8	of	of	IN
cord-276598-tm0yj2sn	925	9	phosphorimidate	phosphorimidate	NNP
cord-276598-tm0yj2sn	925	10	on	on	IN
cord-276598-tm0yj2sn	925	11	the	the	DT
cord-276598-tm0yj2sn	925	12	negatively	negatively	RB
cord-276598-tm0yj2sn	925	13	charged	charge	VBN
cord-276598-tm0yj2sn	925	14	N	n	CD
cord-276598-tm0yj2sn	925	15	atom	atom	NN
cord-276598-tm0yj2sn	925	16	of	of	IN
cord-276598-tm0yj2sn	925	17	the	the	DT
cord-276598-tm0yj2sn	925	18	phosphorimidate	phosphorimidate	NN
cord-276598-tm0yj2sn	925	19	-	-	HYPH
cord-276598-tm0yj2sn	925	20	BF	BF	NNP
cord-276598-tm0yj2sn	925	21	3	3	CD
cord-276598-tm0yj2sn	925	22	complex	complex	JJ
cord-276598-tm0yj2sn	925	23	results	result	NNS
cord-276598-tm0yj2sn	925	24	in	in	IN
cord-276598-tm0yj2sn	925	25	an	an	DT
cord-276598-tm0yj2sn	925	26	(	(	-LRB-
cord-276598-tm0yj2sn	925	27	(	(	-LRB-
cord-276598-tm0yj2sn	925	28	alkyl)amino)trialkoxyphosphonium	alkyl)amino)trialkoxyphosphonium	CD
cord-276598-tm0yj2sn	925	29	complex	complex	NN
cord-276598-tm0yj2sn	925	30	,	,	,
cord-276598-tm0yj2sn	925	31	cleaving	cleave	VBG
cord-276598-tm0yj2sn	925	32	off	off	RP
cord-276598-tm0yj2sn	925	33	BF	BF	NNP
cord-276598-tm0yj2sn	925	34	3	3	CD
cord-276598-tm0yj2sn	925	35	.	.	.
cord-276598-tm0yj2sn	926	1	Nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	926	2	attack	attack	NN
cord-276598-tm0yj2sn	926	3	on	on	IN
cord-276598-tm0yj2sn	926	4	the	the	DT
cord-276598-tm0yj2sn	926	5	trialkoxyphosphonium	trialkoxyphosphonium	NN
cord-276598-tm0yj2sn	926	6	complex	complex	NN
cord-276598-tm0yj2sn	926	7	from	from	IN
cord-276598-tm0yj2sn	926	8	a	a	DT
cord-276598-tm0yj2sn	926	9	neighboring	neighbor	VBG
cord-276598-tm0yj2sn	926	10	phosphorimidate	phosphorimidate	NN
cord-276598-tm0yj2sn	926	11	completes	complete	VBZ
cord-276598-tm0yj2sn	926	12	the	the	DT
cord-276598-tm0yj2sn	926	13	catalytic	catalytic	JJ
cord-276598-tm0yj2sn	926	14	cycle	cycle	NN
cord-276598-tm0yj2sn	926	15	,	,	,
cord-276598-tm0yj2sn	926	16	affording	afford	VBG
cord-276598-tm0yj2sn	926	17	a	a	DT
cord-276598-tm0yj2sn	926	18	P	p	NN
cord-276598-tm0yj2sn	926	19	=	=	SYM
cord-276598-tm0yj2sn	926	20	O	o	NN
cord-276598-tm0yj2sn	926	21	bond	bond	NN
cord-276598-tm0yj2sn	926	22	of	of	IN
cord-276598-tm0yj2sn	926	23	the	the	DT
cord-276598-tm0yj2sn	926	24	desired	desire	VBN
cord-276598-tm0yj2sn	926	25	P	P	NNP
cord-276598-tm0yj2sn	926	26	-	-	HYPH
cord-276598-tm0yj2sn	926	27	N	n	CD
cord-276598-tm0yj2sn	926	28	product	product	NN
cord-276598-tm0yj2sn	926	29	.	.	.
cord-276598-tm0yj2sn	927	1	Molecules	molecule	NNS
cord-276598-tm0yj2sn	927	2	2020	2020	CD
cord-276598-tm0yj2sn	927	3	,	,	,
cord-276598-tm0yj2sn	927	4	25	25	CD
cord-276598-tm0yj2sn	927	5	,	,	,
cord-276598-tm0yj2sn	927	6	x	x	NN
cord-276598-tm0yj2sn	927	7	FOR	for	IN
cord-276598-tm0yj2sn	927	8	PEER	PEER	NNP
cord-276598-tm0yj2sn	927	9	REVIEW	REVIEW	NNP
cord-276598-tm0yj2sn	927	10	29	29	CD
cord-276598-tm0yj2sn	927	11	of	of	IN
cord-276598-tm0yj2sn	927	12	37	37	CD
cord-276598-tm0yj2sn	927	13	Scheme	Scheme	NNP
cord-276598-tm0yj2sn	927	14	37	37	CD
cord-276598-tm0yj2sn	927	15	.	.	.
cord-276598-tm0yj2sn	928	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	928	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	928	3	for	for	IN
cord-276598-tm0yj2sn	928	4	the	the	DT
cord-276598-tm0yj2sn	928	5	catalyst	catalyst	NN
cord-276598-tm0yj2sn	928	6	-	-	HYPH
cord-276598-tm0yj2sn	928	7	free	free	JJ
cord-276598-tm0yj2sn	928	8	Staudinger	Staudinger	NNP
cord-276598-tm0yj2sn	928	9	reduction	reduction	NN
cord-276598-tm0yj2sn	928	10	and	and	CC
cord-276598-tm0yj2sn	928	11	Lewis	Lewis	NNP
cord-276598-tm0yj2sn	928	12	-	-	HYPH
cord-276598-tm0yj2sn	928	13	acid	acid	NN
cord-276598-tm0yj2sn	928	14	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	928	15	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	928	16	route	route	NN
cord-276598-tm0yj2sn	928	17	to	to	IN
cord-276598-tm0yj2sn	928	18	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	928	19	.	.	.
cord-276598-tm0yj2sn	929	1	For	for	IN
cord-276598-tm0yj2sn	929	2	the	the	DT
cord-276598-tm0yj2sn	929	3	hydrophosphinylation	hydrophosphinylation	NN
cord-276598-tm0yj2sn	929	4	route	route	NN
cord-276598-tm0yj2sn	929	5	to	to	IN
cord-276598-tm0yj2sn	929	6	P	P	NNP
cord-276598-tm0yj2sn	929	7	-	-	HYPH
cord-276598-tm0yj2sn	929	8	Ns	Ns	NNP
cord-276598-tm0yj2sn	929	9	,	,	,
cord-276598-tm0yj2sn	929	10	Zimin	Zimin	NNP
cord-276598-tm0yj2sn	929	11	et	et	NNP
cord-276598-tm0yj2sn	929	12	al	al	NNP
cord-276598-tm0yj2sn	929	13	.	.	NNP
cord-276598-tm0yj2sn	929	14	proposed	propose	VBD
cord-276598-tm0yj2sn	929	15	that	that	IN
cord-276598-tm0yj2sn	929	16	in	in	IN
cord-276598-tm0yj2sn	929	17	the	the	DT
cord-276598-tm0yj2sn	929	18	first	first	JJ
cord-276598-tm0yj2sn	929	19	step	step	NN
cord-276598-tm0yj2sn	929	20	,	,	,
cord-276598-tm0yj2sn	929	21	sodium	sodium	NNP
cord-276598-tm0yj2sn	929	22	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	929	23	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	929	24	(	(	-LRB-
cord-276598-tm0yj2sn	929	25	(	(	-LRB-
cord-276598-tm0yj2sn	929	26	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	929	27	,	,	,
cord-276598-tm0yj2sn	929	28	R	r	NN
cord-276598-tm0yj2sn	929	29	=	=	FW
cord-276598-tm0yj2sn	929	30	Et	Et	NNP
cord-276598-tm0yj2sn	929	31	,	,	,
cord-276598-tm0yj2sn	929	32	Ph	Ph	NNP
cord-276598-tm0yj2sn	929	33	)	)	-RRB-
cord-276598-tm0yj2sn	929	34	reacts	react	VBZ
cord-276598-tm0yj2sn	929	35	with	with	IN
cord-276598-tm0yj2sn	929	36	alkyl	alkyl	JJ
cord-276598-tm0yj2sn	929	37	nitrile	nitrile	NN
cord-276598-tm0yj2sn	929	38	to	to	TO
cord-276598-tm0yj2sn	929	39	form	form	VB
cord-276598-tm0yj2sn	929	40	an	an	DT
cord-276598-tm0yj2sn	929	41	imine	imine	NN
cord-276598-tm0yj2sn	929	42	(	(	-LRB-
cord-276598-tm0yj2sn	929	43	C	c	NN
cord-276598-tm0yj2sn	929	44	=	=	SYM
cord-276598-tm0yj2sn	929	45	N	N	NNP
cord-276598-tm0yj2sn	929	46	)	)	-RRB-
cord-276598-tm0yj2sn	929	47	,	,	,
cord-276598-tm0yj2sn	929	48	which	which	WDT
cord-276598-tm0yj2sn	929	49	reacts	react	VBZ
cord-276598-tm0yj2sn	929	50	further	further	RB
cord-276598-tm0yj2sn	929	51	with	with	IN
cord-276598-tm0yj2sn	929	52	a	a	DT
cord-276598-tm0yj2sn	929	53	second	second	JJ
cord-276598-tm0yj2sn	929	54	equivalent	equivalent	NN
cord-276598-tm0yj2sn	929	55	of	of	IN
cord-276598-tm0yj2sn	929	56	(	(	-LRB-
cord-276598-tm0yj2sn	929	57	RO)2PONa	ro)2pona	NN
cord-276598-tm0yj2sn	929	58	to	to	TO
cord-276598-tm0yj2sn	929	59	form	form	VB
cord-276598-tm0yj2sn	929	60	the	the	DT
cord-276598-tm0yj2sn	929	61	1,1-addition	1,1-addition	CD
cord-276598-tm0yj2sn	929	62	product	product	NN
cord-276598-tm0yj2sn	929	63	,	,	,
cord-276598-tm0yj2sn	929	64	sodium	sodium	NN
cord-276598-tm0yj2sn	929	65	(	(	-LRB-
cord-276598-tm0yj2sn	929	66	1,1-bis(dialkoxyphosphoryl)alkyl)amide	1,1-bis(dialkoxyphosphoryl)alkyl)amide	NNP
cord-276598-tm0yj2sn	929	67	(	(	-LRB-
cord-276598-tm0yj2sn	929	68	Scheme	scheme	NN
cord-276598-tm0yj2sn	929	69	38	38	CD
cord-276598-tm0yj2sn	929	70	)	)	-RRB-
cord-276598-tm0yj2sn	929	71	[	[	-LRB-
cord-276598-tm0yj2sn	929	72	120	120	CD
cord-276598-tm0yj2sn	929	73	]	]	-RRB-
cord-276598-tm0yj2sn	929	74	.	.	.
cord-276598-tm0yj2sn	930	1	In	in	IN
cord-276598-tm0yj2sn	930	2	the	the	DT
cord-276598-tm0yj2sn	930	3	second	second	JJ
cord-276598-tm0yj2sn	930	4	step	step	NN
cord-276598-tm0yj2sn	930	5	,	,	,
cord-276598-tm0yj2sn	930	6	sodium	sodium	NN
cord-276598-tm0yj2sn	930	7	(	(	-LRB-
cord-276598-tm0yj2sn	930	8	1,1-bis(dialkyoxyphosphoryl)alkyl)amide	1,1-bis(dialkyoxyphosphoryl)alkyl)amide	NNP
cord-276598-tm0yj2sn	930	9	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	930	10	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	930	11	and	and	CC
cord-276598-tm0yj2sn	930	12	isomerization	isomerization	NN
cord-276598-tm0yj2sn	930	13	to	to	TO
cord-276598-tm0yj2sn	930	14	give	give	VB
cord-276598-tm0yj2sn	930	15	the	the	DT
cord-276598-tm0yj2sn	930	16	1,2-addition	1,2-addition	CD
cord-276598-tm0yj2sn	930	17	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	930	18	product	product	NN
cord-276598-tm0yj2sn	930	19	containing	contain	VBG
cord-276598-tm0yj2sn	930	20	a	a	DT
cord-276598-tm0yj2sn	930	21	P	p	NN
cord-276598-tm0yj2sn	930	22	-	-	HYPH
cord-276598-tm0yj2sn	930	23	C	C	NNP
cord-276598-tm0yj2sn	930	24	-	-	HYPH
cord-276598-tm0yj2sn	930	25	N	N	NNP
cord-276598-tm0yj2sn	930	26	-	-	HYPH
cord-276598-tm0yj2sn	930	27	P	p	NN
cord-276598-tm0yj2sn	930	28	bond	bond	NN
cord-276598-tm0yj2sn	930	29	,	,	,
cord-276598-tm0yj2sn	930	30	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	930	31	a	a	DT
cord-276598-tm0yj2sn	930	32	sodium	sodium	NN
cord-276598-tm0yj2sn	930	33	cation	cation	NN
cord-276598-tm0yj2sn	930	34	in	in	IN
cord-276598-tm0yj2sn	930	35	the	the	DT
cord-276598-tm0yj2sn	930	36	process	process	NN
cord-276598-tm0yj2sn	930	37	.	.	.
cord-276598-tm0yj2sn	931	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	931	2	37	37	CD
cord-276598-tm0yj2sn	931	3	.	.	.
cord-276598-tm0yj2sn	932	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	932	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	932	3	for	for	IN
cord-276598-tm0yj2sn	932	4	the	the	DT
cord-276598-tm0yj2sn	932	5	catalyst	catalyst	NN
cord-276598-tm0yj2sn	932	6	-	-	HYPH
cord-276598-tm0yj2sn	932	7	free	free	JJ
cord-276598-tm0yj2sn	932	8	Staudinger	Staudinger	NNP
cord-276598-tm0yj2sn	932	9	reduction	reduction	NN
cord-276598-tm0yj2sn	932	10	and	and	CC
cord-276598-tm0yj2sn	932	11	Lewis	Lewis	NNP
cord-276598-tm0yj2sn	932	12	-	-	HYPH
cord-276598-tm0yj2sn	932	13	acid	acid	NN
cord-276598-tm0yj2sn	932	14	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	932	15	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	932	16	route	route	NN
cord-276598-tm0yj2sn	932	17	to	to	IN
cord-276598-tm0yj2sn	932	18	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	932	19	.	.	.
cord-276598-tm0yj2sn	933	1	For	for	IN
cord-276598-tm0yj2sn	933	2	the	the	DT
cord-276598-tm0yj2sn	933	3	hydrophosphinylation	hydrophosphinylation	NN
cord-276598-tm0yj2sn	933	4	route	route	NN
cord-276598-tm0yj2sn	933	5	to	to	IN
cord-276598-tm0yj2sn	933	6	P	P	NNP
cord-276598-tm0yj2sn	933	7	-	-	HYPH
cord-276598-tm0yj2sn	933	8	Ns	Ns	NNP
cord-276598-tm0yj2sn	933	9	,	,	,
cord-276598-tm0yj2sn	933	10	Zimin	Zimin	NNP
cord-276598-tm0yj2sn	933	11	et	et	NNP
cord-276598-tm0yj2sn	933	12	al	al	NNP
cord-276598-tm0yj2sn	933	13	.	.	NNP
cord-276598-tm0yj2sn	933	14	proposed	propose	VBD
cord-276598-tm0yj2sn	933	15	that	that	IN
cord-276598-tm0yj2sn	933	16	in	in	IN
cord-276598-tm0yj2sn	933	17	the	the	DT
cord-276598-tm0yj2sn	933	18	first	first	JJ
cord-276598-tm0yj2sn	933	19	step	step	NN
cord-276598-tm0yj2sn	933	20	,	,	,
cord-276598-tm0yj2sn	933	21	sodium	sodium	NNP
cord-276598-tm0yj2sn	933	22	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	933	23	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	933	24	(	(	-LRB-
cord-276598-tm0yj2sn	933	25	(	(	-LRB-
cord-276598-tm0yj2sn	933	26	RO	RO	NNP
cord-276598-tm0yj2sn	933	27	)	)	-RRB-
cord-276598-tm0yj2sn	933	28	2	2	CD
cord-276598-tm0yj2sn	933	29	PONa	PONa	NNS
cord-276598-tm0yj2sn	933	30	,	,	,
cord-276598-tm0yj2sn	933	31	R	r	NN
cord-276598-tm0yj2sn	933	32	=	=	NN
cord-276598-tm0yj2sn	933	33	Et	Et	NNP
cord-276598-tm0yj2sn	933	34	,	,	,
cord-276598-tm0yj2sn	933	35	Ph	Ph	NNP
cord-276598-tm0yj2sn	933	36	)	)	-RRB-
cord-276598-tm0yj2sn	933	37	reacts	react	VBZ
cord-276598-tm0yj2sn	933	38	with	with	IN
cord-276598-tm0yj2sn	933	39	alkyl	alkyl	JJ
cord-276598-tm0yj2sn	933	40	nitrile	nitrile	NN
cord-276598-tm0yj2sn	933	41	to	to	TO
cord-276598-tm0yj2sn	933	42	form	form	VB
cord-276598-tm0yj2sn	933	43	an	an	DT
cord-276598-tm0yj2sn	933	44	imine	imine	NN
cord-276598-tm0yj2sn	933	45	(	(	-LRB-
cord-276598-tm0yj2sn	933	46	C	c	NN
cord-276598-tm0yj2sn	933	47	=	=	SYM
cord-276598-tm0yj2sn	933	48	N	N	NNP
cord-276598-tm0yj2sn	933	49	)	)	-RRB-
cord-276598-tm0yj2sn	933	50	,	,	,
cord-276598-tm0yj2sn	933	51	which	which	WDT
cord-276598-tm0yj2sn	933	52	reacts	react	VBZ
cord-276598-tm0yj2sn	933	53	further	further	RB
cord-276598-tm0yj2sn	933	54	with	with	IN
cord-276598-tm0yj2sn	933	55	a	a	DT
cord-276598-tm0yj2sn	933	56	second	second	JJ
cord-276598-tm0yj2sn	933	57	equivalent	equivalent	NN
cord-276598-tm0yj2sn	933	58	of	of	IN
cord-276598-tm0yj2sn	933	59	(	(	-LRB-
cord-276598-tm0yj2sn	933	60	RO	RO	NNP
cord-276598-tm0yj2sn	933	61	)	)	-RRB-
cord-276598-tm0yj2sn	933	62	2	2	CD
cord-276598-tm0yj2sn	933	63	PONa	PONa	NNS
cord-276598-tm0yj2sn	933	64	to	to	TO
cord-276598-tm0yj2sn	933	65	form	form	VB
cord-276598-tm0yj2sn	933	66	the	the	DT
cord-276598-tm0yj2sn	933	67	1,1-addition	1,1-addition	CD
cord-276598-tm0yj2sn	933	68	product	product	NN
cord-276598-tm0yj2sn	933	69	,	,	,
cord-276598-tm0yj2sn	933	70	sodium	sodium	NN
cord-276598-tm0yj2sn	933	71	(	(	-LRB-
cord-276598-tm0yj2sn	933	72	1,1-bis(dialkoxyphosphoryl)alkyl)amide	1,1-bis(dialkoxyphosphoryl)alkyl)amide	NNP
cord-276598-tm0yj2sn	933	73	(	(	-LRB-
cord-276598-tm0yj2sn	933	74	Scheme	scheme	NN
cord-276598-tm0yj2sn	933	75	38	38	CD
cord-276598-tm0yj2sn	933	76	)	)	-RRB-
cord-276598-tm0yj2sn	933	77	[	[	-LRB-
cord-276598-tm0yj2sn	933	78	120	120	CD
cord-276598-tm0yj2sn	933	79	]	]	-RRB-
cord-276598-tm0yj2sn	933	80	.	.	.
cord-276598-tm0yj2sn	934	1	In	in	IN
cord-276598-tm0yj2sn	934	2	the	the	DT
cord-276598-tm0yj2sn	934	3	second	second	JJ
cord-276598-tm0yj2sn	934	4	step	step	NN
cord-276598-tm0yj2sn	934	5	,	,	,
cord-276598-tm0yj2sn	934	6	sodium	sodium	NN
cord-276598-tm0yj2sn	934	7	(	(	-LRB-
cord-276598-tm0yj2sn	934	8	1,1-bis(dialkyoxyphosphoryl)alkyl)amide	1,1-bis(dialkyoxyphosphoryl)alkyl)amide	NNP
cord-276598-tm0yj2sn	934	9	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	934	10	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	934	11	and	and	CC
cord-276598-tm0yj2sn	934	12	isomerization	isomerization	NN
cord-276598-tm0yj2sn	934	13	to	to	TO
cord-276598-tm0yj2sn	934	14	give	give	VB
cord-276598-tm0yj2sn	934	15	the	the	DT
cord-276598-tm0yj2sn	934	16	1,2-addition	1,2-addition	CD
cord-276598-tm0yj2sn	934	17	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	934	18	product	product	NN
cord-276598-tm0yj2sn	934	19	containing	contain	VBG
cord-276598-tm0yj2sn	934	20	a	a	DT
cord-276598-tm0yj2sn	934	21	P	p	NN
cord-276598-tm0yj2sn	934	22	-	-	HYPH
cord-276598-tm0yj2sn	934	23	C	C	NNP
cord-276598-tm0yj2sn	934	24	-	-	HYPH
cord-276598-tm0yj2sn	934	25	N	N	NNP
cord-276598-tm0yj2sn	934	26	-	-	HYPH
cord-276598-tm0yj2sn	934	27	P	p	NN
cord-276598-tm0yj2sn	934	28	bond	bond	NN
cord-276598-tm0yj2sn	934	29	,	,	,
cord-276598-tm0yj2sn	934	30	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	934	31	a	a	DT
cord-276598-tm0yj2sn	934	32	sodium	sodium	NN
cord-276598-tm0yj2sn	934	33	cation	cation	NN
cord-276598-tm0yj2sn	934	34	in	in	IN
cord-276598-tm0yj2sn	934	35	the	the	DT
cord-276598-tm0yj2sn	934	36	process	process	NN
cord-276598-tm0yj2sn	934	37	.	.	.
cord-276598-tm0yj2sn	935	1	For	for	IN
cord-276598-tm0yj2sn	935	2	the	the	DT
cord-276598-tm0yj2sn	935	3	hydrophosphinylation	hydrophosphinylation	NN
cord-276598-tm0yj2sn	935	4	route	route	NN
cord-276598-tm0yj2sn	935	5	to	to	IN
cord-276598-tm0yj2sn	935	6	P	P	NNP
cord-276598-tm0yj2sn	935	7	-	-	HYPH
cord-276598-tm0yj2sn	935	8	Ns	Ns	NNP
cord-276598-tm0yj2sn	935	9	,	,	,
cord-276598-tm0yj2sn	935	10	Zimin	Zimin	NNP
cord-276598-tm0yj2sn	935	11	et	et	NNP
cord-276598-tm0yj2sn	935	12	al	al	NNP
cord-276598-tm0yj2sn	935	13	.	.	NNP
cord-276598-tm0yj2sn	935	14	proposed	propose	VBD
cord-276598-tm0yj2sn	935	15	that	that	IN
cord-276598-tm0yj2sn	935	16	in	in	IN
cord-276598-tm0yj2sn	935	17	the	the	DT
cord-276598-tm0yj2sn	935	18	first	first	JJ
cord-276598-tm0yj2sn	935	19	step	step	NN
cord-276598-tm0yj2sn	935	20	,	,	,
cord-276598-tm0yj2sn	935	21	sodium	sodium	NNP
cord-276598-tm0yj2sn	935	22	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	935	23	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	935	24	(	(	-LRB-
cord-276598-tm0yj2sn	935	25	(	(	-LRB-
cord-276598-tm0yj2sn	935	26	RO)2PONa	RO)2PONa	NNP
cord-276598-tm0yj2sn	935	27	,	,	,
cord-276598-tm0yj2sn	935	28	R	r	NN
cord-276598-tm0yj2sn	935	29	=	=	FW
cord-276598-tm0yj2sn	935	30	Et	Et	NNP
cord-276598-tm0yj2sn	935	31	,	,	,
cord-276598-tm0yj2sn	935	32	Ph	Ph	NNP
cord-276598-tm0yj2sn	935	33	)	)	-RRB-
cord-276598-tm0yj2sn	935	34	reacts	react	VBZ
cord-276598-tm0yj2sn	935	35	with	with	IN
cord-276598-tm0yj2sn	935	36	alkyl	alkyl	JJ
cord-276598-tm0yj2sn	935	37	nitrile	nitrile	NN
cord-276598-tm0yj2sn	935	38	to	to	TO
cord-276598-tm0yj2sn	935	39	form	form	VB
cord-276598-tm0yj2sn	935	40	an	an	DT
cord-276598-tm0yj2sn	935	41	imine	imine	NN
cord-276598-tm0yj2sn	935	42	(	(	-LRB-
cord-276598-tm0yj2sn	935	43	C	c	NN
cord-276598-tm0yj2sn	935	44	=	=	SYM
cord-276598-tm0yj2sn	935	45	N	N	NNP
cord-276598-tm0yj2sn	935	46	)	)	-RRB-
cord-276598-tm0yj2sn	935	47	,	,	,
cord-276598-tm0yj2sn	935	48	which	which	WDT
cord-276598-tm0yj2sn	935	49	reacts	react	VBZ
cord-276598-tm0yj2sn	935	50	further	further	RB
cord-276598-tm0yj2sn	935	51	with	with	IN
cord-276598-tm0yj2sn	935	52	a	a	DT
cord-276598-tm0yj2sn	935	53	second	second	JJ
cord-276598-tm0yj2sn	935	54	equivalent	equivalent	NN
cord-276598-tm0yj2sn	935	55	of	of	IN
cord-276598-tm0yj2sn	935	56	(	(	-LRB-
cord-276598-tm0yj2sn	935	57	RO)2PONa	ro)2pona	NN
cord-276598-tm0yj2sn	935	58	to	to	TO
cord-276598-tm0yj2sn	935	59	form	form	VB
cord-276598-tm0yj2sn	935	60	the	the	DT
cord-276598-tm0yj2sn	935	61	1,1-addition	1,1-addition	CD
cord-276598-tm0yj2sn	935	62	product	product	NN
cord-276598-tm0yj2sn	935	63	,	,	,
cord-276598-tm0yj2sn	935	64	sodium	sodium	NN
cord-276598-tm0yj2sn	935	65	(	(	-LRB-
cord-276598-tm0yj2sn	935	66	1,1-bis(dialkoxyphosphoryl)alkyl)amide	1,1-bis(dialkoxyphosphoryl)alkyl)amide	NNP
cord-276598-tm0yj2sn	935	67	(	(	-LRB-
cord-276598-tm0yj2sn	935	68	Scheme	scheme	NN
cord-276598-tm0yj2sn	935	69	38	38	CD
cord-276598-tm0yj2sn	935	70	)	)	-RRB-
cord-276598-tm0yj2sn	935	71	[	[	-LRB-
cord-276598-tm0yj2sn	935	72	120	120	CD
cord-276598-tm0yj2sn	935	73	]	]	-RRB-
cord-276598-tm0yj2sn	935	74	.	.	.
cord-276598-tm0yj2sn	936	1	In	in	IN
cord-276598-tm0yj2sn	936	2	the	the	DT
cord-276598-tm0yj2sn	936	3	second	second	JJ
cord-276598-tm0yj2sn	936	4	step	step	NN
cord-276598-tm0yj2sn	936	5	,	,	,
cord-276598-tm0yj2sn	936	6	sodium	sodium	NN
cord-276598-tm0yj2sn	936	7	(	(	-LRB-
cord-276598-tm0yj2sn	936	8	1,1-bis(dialkyoxyphosphoryl)alkyl)amide	1,1-bis(dialkyoxyphosphoryl)alkyl)amide	NNP
cord-276598-tm0yj2sn	936	9	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	936	10	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	936	11	and	and	CC
cord-276598-tm0yj2sn	936	12	isomerization	isomerization	NN
cord-276598-tm0yj2sn	936	13	to	to	TO
cord-276598-tm0yj2sn	936	14	give	give	VB
cord-276598-tm0yj2sn	936	15	the	the	DT
cord-276598-tm0yj2sn	936	16	1,2-addition	1,2-addition	CD
cord-276598-tm0yj2sn	936	17	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	936	18	product	product	NN
cord-276598-tm0yj2sn	936	19	containing	contain	VBG
cord-276598-tm0yj2sn	936	20	a	a	DT
cord-276598-tm0yj2sn	936	21	P	p	NN
cord-276598-tm0yj2sn	936	22	-	-	HYPH
cord-276598-tm0yj2sn	936	23	C	C	NNP
cord-276598-tm0yj2sn	936	24	-	-	HYPH
cord-276598-tm0yj2sn	936	25	N	N	NNP
cord-276598-tm0yj2sn	936	26	-	-	HYPH
cord-276598-tm0yj2sn	936	27	P	p	NN
cord-276598-tm0yj2sn	936	28	bond	bond	NN
cord-276598-tm0yj2sn	936	29	,	,	,
cord-276598-tm0yj2sn	936	30	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	936	31	a	a	DT
cord-276598-tm0yj2sn	936	32	sodium	sodium	NN
cord-276598-tm0yj2sn	936	33	cation	cation	NN
cord-276598-tm0yj2sn	936	34	in	in	IN
cord-276598-tm0yj2sn	936	35	the	the	DT
cord-276598-tm0yj2sn	936	36	process	process	NN
cord-276598-tm0yj2sn	936	37	.	.	.
cord-276598-tm0yj2sn	937	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	937	2	38	38	CD
cord-276598-tm0yj2sn	937	3	.	.	.
cord-276598-tm0yj2sn	938	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	938	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	938	3	for	for	IN
cord-276598-tm0yj2sn	938	4	hydrophosphinylation	hydrophosphinylation	NNP
cord-276598-tm0yj2sn	938	5	route	route	NN
cord-276598-tm0yj2sn	938	6	to	to	IN
cord-276598-tm0yj2sn	938	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	938	8	.	.	.
cord-276598-tm0yj2sn	939	1	Chabour	Chabour	NNP
cord-276598-tm0yj2sn	939	2	et	et	FW
cord-276598-tm0yj2sn	939	3	al	al	NNP
cord-276598-tm0yj2sn	939	4	.	.	.
cord-276598-tm0yj2sn	940	1	proposed	propose	VBD
cord-276598-tm0yj2sn	940	2	a	a	DT
cord-276598-tm0yj2sn	940	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	940	4	of	of	IN
cord-276598-tm0yj2sn	940	5	the	the	DT
cord-276598-tm0yj2sn	940	6	reaction	reaction	NN
cord-276598-tm0yj2sn	940	7	in	in	IN
cord-276598-tm0yj2sn	940	8	which	which	WDT
cord-276598-tm0yj2sn	940	9	(	(	-LRB-
cord-276598-tm0yj2sn	940	10	EtO)2P(O)NH2	eto)2p(o)nh2	RB
cord-276598-tm0yj2sn	940	11	reacts	react	VBZ
cord-276598-tm0yj2sn	940	12	with	with	IN
cord-276598-tm0yj2sn	940	13	(	(	-LRB-
cord-276598-tm0yj2sn	940	14	or	or	CC
cord-276598-tm0yj2sn	940	15	is	be	VBZ
cord-276598-tm0yj2sn	940	16	activated	activate	VBN
cord-276598-tm0yj2sn	940	17	by	by	IN
cord-276598-tm0yj2sn	940	18	)	)	-RRB-
cord-276598-tm0yj2sn	941	1	acetic	acetic	JJ
cord-276598-tm0yj2sn	941	2	anhydride	anhydride	NN
cord-276598-tm0yj2sn	941	3	to	to	TO
cord-276598-tm0yj2sn	941	4	form	form	VB
cord-276598-tm0yj2sn	941	5	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	941	6	acetylphosphoramidate	acetylphosphoramidate	NN
cord-276598-tm0yj2sn	941	7	and	and	CC
cord-276598-tm0yj2sn	941	8	acetic	acetic	JJ
cord-276598-tm0yj2sn	941	9	acid	acid	NN
cord-276598-tm0yj2sn	941	10	(	(	-LRB-
cord-276598-tm0yj2sn	941	11	Scheme	scheme	NN
cord-276598-tm0yj2sn	941	12	39	39	CD
cord-276598-tm0yj2sn	941	13	)	)	-RRB-
cord-276598-tm0yj2sn	942	1	[	[	-LRB-
cord-276598-tm0yj2sn	942	2	1	1	CD
cord-276598-tm0yj2sn	942	3	]	]	-RRB-
cord-276598-tm0yj2sn	942	4	.	.	.
cord-276598-tm0yj2sn	943	1	Meanwhile	meanwhile	RB
cord-276598-tm0yj2sn	943	2	,	,	,
cord-276598-tm0yj2sn	943	3	the	the	DT
cord-276598-tm0yj2sn	943	4	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	943	5	protonated	protonate	VBN
cord-276598-tm0yj2sn	943	6	in	in	IN
cord-276598-tm0yj2sn	943	7	the	the	DT
cord-276598-tm0yj2sn	943	8	presence	presence	NN
cord-276598-tm0yj2sn	943	9	of	of	IN
cord-276598-tm0yj2sn	943	10	an	an	DT
cord-276598-tm0yj2sn	943	11	acid	acid	NN
cord-276598-tm0yj2sn	943	12	catalyst	catalyst	NN
cord-276598-tm0yj2sn	943	13	,	,	,
cord-276598-tm0yj2sn	943	14	TsOH	TsOH	NNP
cord-276598-tm0yj2sn	943	15	,	,	,
cord-276598-tm0yj2sn	943	16	reacts	react	VBZ
cord-276598-tm0yj2sn	943	17	with	with	IN
cord-276598-tm0yj2sn	943	18	the	the	DT
cord-276598-tm0yj2sn	943	19	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	943	20	acetylphosphoramidate	acetylphosphoramidate	NNP
cord-276598-tm0yj2sn	943	21	complex	complex	JJ
cord-276598-tm0yj2sn	943	22	to	to	TO
cord-276598-tm0yj2sn	943	23	give	give	VB
cord-276598-tm0yj2sn	943	24	the	the	DT
cord-276598-tm0yj2sn	943	25	cationic	cationic	JJ
cord-276598-tm0yj2sn	943	26	diethyl	diethyl	NN
cord-276598-tm0yj2sn	943	27	(	(	-LRB-
cord-276598-tm0yj2sn	943	28	alkene	alkene	NN
cord-276598-tm0yj2sn	943	29	-	-	HYPH
cord-276598-tm0yj2sn	943	30	acetamido)phosphonate	acetamido)phosphonate	NNP
cord-276598-tm0yj2sn	943	31	complex	complex	JJ
cord-276598-tm0yj2sn	943	32	intermediate	intermediate	NN
cord-276598-tm0yj2sn	943	33	.	.	.
cord-276598-tm0yj2sn	944	1	The	the	DT
cord-276598-tm0yj2sn	944	2	unstable	unstable	JJ
cord-276598-tm0yj2sn	944	3	cationic	cationic	JJ
cord-276598-tm0yj2sn	944	4	complex	complex	NN
cord-276598-tm0yj2sn	944	5	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	944	6	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	944	7	with	with	IN
cord-276598-tm0yj2sn	944	8	a	a	DT
cord-276598-tm0yj2sn	944	9	hydride	hydride	NN
cord-276598-tm0yj2sn	944	10	shift	shift	NN
cord-276598-tm0yj2sn	944	11	and	and	CC
cord-276598-tm0yj2sn	944	12	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	944	13	in	in	IN
cord-276598-tm0yj2sn	944	14	presence	presence	NN
cord-276598-tm0yj2sn	944	15	of	of	IN
cord-276598-tm0yj2sn	944	16	TsO	TsO	NNP
cord-276598-tm0yj2sn	944	17	−	−	NNP
cord-276598-tm0yj2sn	944	18	to	to	TO
cord-276598-tm0yj2sn	944	19	give	give	VB
cord-276598-tm0yj2sn	944	20	a	a	DT
cord-276598-tm0yj2sn	944	21	more	more	RBR
cord-276598-tm0yj2sn	944	22	stable	stable	JJ
cord-276598-tm0yj2sn	944	23	diethyl	diethyl	NN
cord-276598-tm0yj2sn	944	24	acetyl(alk-1,3-diene)phosphoramidate	acetyl(alk-1,3-diene)phosphoramidate	RB
cord-276598-tm0yj2sn	944	25	.	.	.
cord-276598-tm0yj2sn	945	1	The	the	DT
cord-276598-tm0yj2sn	945	2	subsequent	subsequent	JJ
cord-276598-tm0yj2sn	945	3	direct	direct	JJ
cord-276598-tm0yj2sn	945	4	addition	addition	NN
cord-276598-tm0yj2sn	945	5	of	of	IN
cord-276598-tm0yj2sn	945	6	the	the	DT
cord-276598-tm0yj2sn	945	7	maleimide	maleimide	JJ
cord-276598-tm0yj2sn	945	8	derivative	derivative	JJ
cord-276598-tm0yj2sn	945	9	results	result	NNS
cord-276598-tm0yj2sn	945	10	in	in	IN
cord-276598-tm0yj2sn	945	11	a	a	DT
cord-276598-tm0yj2sn	945	12	P	P	NNP
cord-276598-tm0yj2sn	945	13	-	-	HYPH
cord-276598-tm0yj2sn	945	14	N	n	CD
cord-276598-tm0yj2sn	945	15	adduct	adduct	NN
cord-276598-tm0yj2sn	945	16	intermediate	intermediate	NN
cord-276598-tm0yj2sn	945	17	,	,	,
cord-276598-tm0yj2sn	945	18	which	which	WDT
cord-276598-tm0yj2sn	945	19	is	be	VBZ
cord-276598-tm0yj2sn	945	20	deacetylated	deacetylate	VBN
cord-276598-tm0yj2sn	945	21	in	in	IN
cord-276598-tm0yj2sn	945	22	the	the	DT
cord-276598-tm0yj2sn	945	23	presence	presence	NN
cord-276598-tm0yj2sn	945	24	of	of	IN
cord-276598-tm0yj2sn	945	25	acetic	acetic	JJ
cord-276598-tm0yj2sn	945	26	acid	acid	NN
cord-276598-tm0yj2sn	945	27	to	to	TO
cord-276598-tm0yj2sn	945	28	afford	afford	VB
cord-276598-tm0yj2sn	945	29	the	the	DT
cord-276598-tm0yj2sn	945	30	desired	desire	VBN
cord-276598-tm0yj2sn	945	31	product	product	NN
cord-276598-tm0yj2sn	945	32	.	.	.
cord-276598-tm0yj2sn	946	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	946	2	38	38	CD
cord-276598-tm0yj2sn	946	3	.	.	.
cord-276598-tm0yj2sn	947	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	947	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	947	3	for	for	IN
cord-276598-tm0yj2sn	947	4	hydrophosphinylation	hydrophosphinylation	NNP
cord-276598-tm0yj2sn	947	5	route	route	NN
cord-276598-tm0yj2sn	947	6	to	to	IN
cord-276598-tm0yj2sn	947	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	947	8	.	.	.
cord-276598-tm0yj2sn	948	1	Chabour	Chabour	NNP
cord-276598-tm0yj2sn	948	2	et	et	FW
cord-276598-tm0yj2sn	948	3	al	al	NNP
cord-276598-tm0yj2sn	948	4	.	.	.
cord-276598-tm0yj2sn	949	1	proposed	propose	VBD
cord-276598-tm0yj2sn	949	2	a	a	DT
cord-276598-tm0yj2sn	949	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	949	4	of	of	IN
cord-276598-tm0yj2sn	949	5	the	the	DT
cord-276598-tm0yj2sn	949	6	reaction	reaction	NN
cord-276598-tm0yj2sn	949	7	in	in	IN
cord-276598-tm0yj2sn	949	8	which	which	WDT
cord-276598-tm0yj2sn	949	9	(	(	-LRB-
cord-276598-tm0yj2sn	949	10	EtO	EtO	NNP
cord-276598-tm0yj2sn	949	11	)	)	-RRB-
cord-276598-tm0yj2sn	949	12	2	2	CD
cord-276598-tm0yj2sn	949	13	P(O)NH	P(O)NH	NNP
cord-276598-tm0yj2sn	949	14	2	2	CD
cord-276598-tm0yj2sn	949	15	reacts	react	VBZ
cord-276598-tm0yj2sn	949	16	with	with	IN
cord-276598-tm0yj2sn	949	17	(	(	-LRB-
cord-276598-tm0yj2sn	949	18	or	or	CC
cord-276598-tm0yj2sn	949	19	is	be	VBZ
cord-276598-tm0yj2sn	949	20	activated	activate	VBN
cord-276598-tm0yj2sn	949	21	by	by	IN
cord-276598-tm0yj2sn	949	22	)	)	-RRB-
cord-276598-tm0yj2sn	950	1	acetic	acetic	JJ
cord-276598-tm0yj2sn	950	2	anhydride	anhydride	NN
cord-276598-tm0yj2sn	950	3	to	to	TO
cord-276598-tm0yj2sn	950	4	form	form	VB
cord-276598-tm0yj2sn	950	5	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	950	6	acetylphosphoramidate	acetylphosphoramidate	NN
cord-276598-tm0yj2sn	950	7	and	and	CC
cord-276598-tm0yj2sn	950	8	acetic	acetic	JJ
cord-276598-tm0yj2sn	950	9	acid	acid	NN
cord-276598-tm0yj2sn	950	10	(	(	-LRB-
cord-276598-tm0yj2sn	950	11	Scheme	scheme	NN
cord-276598-tm0yj2sn	950	12	39	39	CD
cord-276598-tm0yj2sn	950	13	)	)	-RRB-
cord-276598-tm0yj2sn	951	1	[	[	-LRB-
cord-276598-tm0yj2sn	951	2	1	1	CD
cord-276598-tm0yj2sn	951	3	]	]	-RRB-
cord-276598-tm0yj2sn	951	4	.	.	.
cord-276598-tm0yj2sn	952	1	Meanwhile	meanwhile	RB
cord-276598-tm0yj2sn	952	2	,	,	,
cord-276598-tm0yj2sn	952	3	the	the	DT
cord-276598-tm0yj2sn	952	4	aldehyde	aldehyde	NN
cord-276598-tm0yj2sn	952	5	protonated	protonate	VBN
cord-276598-tm0yj2sn	952	6	in	in	IN
cord-276598-tm0yj2sn	952	7	the	the	DT
cord-276598-tm0yj2sn	952	8	presence	presence	NN
cord-276598-tm0yj2sn	952	9	of	of	IN
cord-276598-tm0yj2sn	952	10	an	an	DT
cord-276598-tm0yj2sn	952	11	acid	acid	NN
cord-276598-tm0yj2sn	952	12	catalyst	catalyst	NN
cord-276598-tm0yj2sn	952	13	,	,	,
cord-276598-tm0yj2sn	952	14	TsOH	TsOH	NNP
cord-276598-tm0yj2sn	952	15	,	,	,
cord-276598-tm0yj2sn	952	16	reacts	react	VBZ
cord-276598-tm0yj2sn	952	17	with	with	IN
cord-276598-tm0yj2sn	952	18	the	the	DT
cord-276598-tm0yj2sn	952	19	diethyl	diethyl	NNP
cord-276598-tm0yj2sn	952	20	acetylphosphoramidate	acetylphosphoramidate	NNP
cord-276598-tm0yj2sn	952	21	complex	complex	JJ
cord-276598-tm0yj2sn	952	22	to	to	TO
cord-276598-tm0yj2sn	952	23	give	give	VB
cord-276598-tm0yj2sn	952	24	the	the	DT
cord-276598-tm0yj2sn	952	25	cationic	cationic	JJ
cord-276598-tm0yj2sn	952	26	diethyl	diethyl	NN
cord-276598-tm0yj2sn	952	27	(	(	-LRB-
cord-276598-tm0yj2sn	952	28	alkene	alkene	NN
cord-276598-tm0yj2sn	952	29	-	-	HYPH
cord-276598-tm0yj2sn	952	30	acetamido)phosphonate	acetamido)phosphonate	NNP
cord-276598-tm0yj2sn	952	31	complex	complex	JJ
cord-276598-tm0yj2sn	952	32	intermediate	intermediate	NN
cord-276598-tm0yj2sn	952	33	.	.	.
cord-276598-tm0yj2sn	953	1	The	the	DT
cord-276598-tm0yj2sn	953	2	unstable	unstable	JJ
cord-276598-tm0yj2sn	953	3	cationic	cationic	JJ
cord-276598-tm0yj2sn	953	4	complex	complex	NN
cord-276598-tm0yj2sn	953	5	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	953	6	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	953	7	with	with	IN
cord-276598-tm0yj2sn	953	8	a	a	DT
cord-276598-tm0yj2sn	953	9	hydride	hydride	NN
cord-276598-tm0yj2sn	953	10	shift	shift	NN
cord-276598-tm0yj2sn	953	11	and	and	CC
cord-276598-tm0yj2sn	953	12	deprotonation	deprotonation	NN
cord-276598-tm0yj2sn	953	13	in	in	IN
cord-276598-tm0yj2sn	953	14	presence	presence	NN
cord-276598-tm0yj2sn	953	15	of	of	IN
cord-276598-tm0yj2sn	953	16	TsO	TsO	NNP
cord-276598-tm0yj2sn	953	17	−	−	NNP
cord-276598-tm0yj2sn	953	18	to	to	TO
cord-276598-tm0yj2sn	953	19	give	give	VB
cord-276598-tm0yj2sn	953	20	a	a	DT
cord-276598-tm0yj2sn	953	21	more	more	RBR
cord-276598-tm0yj2sn	953	22	stable	stable	JJ
cord-276598-tm0yj2sn	953	23	diethyl	diethyl	NN
cord-276598-tm0yj2sn	953	24	acetyl(alk-1,3-diene)phosphoramidate	acetyl(alk-1,3-diene)phosphoramidate	RB
cord-276598-tm0yj2sn	953	25	.	.	.
cord-276598-tm0yj2sn	954	1	The	the	DT
cord-276598-tm0yj2sn	954	2	subsequent	subsequent	JJ
cord-276598-tm0yj2sn	954	3	direct	direct	JJ
cord-276598-tm0yj2sn	954	4	addition	addition	NN
cord-276598-tm0yj2sn	954	5	of	of	IN
cord-276598-tm0yj2sn	954	6	the	the	DT
cord-276598-tm0yj2sn	954	7	maleimide	maleimide	JJ
cord-276598-tm0yj2sn	954	8	derivative	derivative	JJ
cord-276598-tm0yj2sn	954	9	results	result	NNS
cord-276598-tm0yj2sn	954	10	in	in	IN
cord-276598-tm0yj2sn	954	11	a	a	DT
cord-276598-tm0yj2sn	954	12	P	P	NNP
cord-276598-tm0yj2sn	954	13	-	-	HYPH
cord-276598-tm0yj2sn	954	14	N	n	CD
cord-276598-tm0yj2sn	954	15	adduct	adduct	NN
cord-276598-tm0yj2sn	954	16	intermediate	intermediate	NN
cord-276598-tm0yj2sn	954	17	,	,	,
cord-276598-tm0yj2sn	954	18	which	which	WDT
cord-276598-tm0yj2sn	954	19	is	be	VBZ
cord-276598-tm0yj2sn	954	20	deacetylated	deacetylate	VBN
cord-276598-tm0yj2sn	954	21	in	in	IN
cord-276598-tm0yj2sn	954	22	the	the	DT
cord-276598-tm0yj2sn	954	23	presence	presence	NN
cord-276598-tm0yj2sn	954	24	of	of	IN
cord-276598-tm0yj2sn	954	25	acetic	acetic	JJ
cord-276598-tm0yj2sn	954	26	acid	acid	NN
cord-276598-tm0yj2sn	954	27	to	to	TO
cord-276598-tm0yj2sn	954	28	afford	afford	VB
cord-276598-tm0yj2sn	954	29	the	the	DT
cord-276598-tm0yj2sn	954	30	desired	desire	VBN
cord-276598-tm0yj2sn	954	31	product	product	NN
cord-276598-tm0yj2sn	954	32	.	.	.
cord-276598-tm0yj2sn	954	33	 	 	_SP
cord-276598-tm0yj2sn	955	1	In	in	IN
cord-276598-tm0yj2sn	955	2	this	this	DT
cord-276598-tm0yj2sn	955	3	review	review	NN
cord-276598-tm0yj2sn	955	4	,	,	,
cord-276598-tm0yj2sn	955	5	the	the	DT
cord-276598-tm0yj2sn	955	6	applications	application	NNS
cord-276598-tm0yj2sn	955	7	,	,	,
cord-276598-tm0yj2sn	955	8	syntheses	synthesis	NNS
cord-276598-tm0yj2sn	955	9	,	,	,
cord-276598-tm0yj2sn	955	10	and	and	CC
cord-276598-tm0yj2sn	955	11	corresponding	correspond	VBG
cord-276598-tm0yj2sn	955	12	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	955	13	of	of	IN
cord-276598-tm0yj2sn	955	14	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	955	15	have	have	VBP
cord-276598-tm0yj2sn	955	16	been	be	VBN
cord-276598-tm0yj2sn	955	17	discussed	discuss	VBN
cord-276598-tm0yj2sn	955	18	in	in	IN
cord-276598-tm0yj2sn	955	19	depth	depth	NN
cord-276598-tm0yj2sn	955	20	.	.	.
cord-276598-tm0yj2sn	956	1	As	as	IN
cord-276598-tm0yj2sn	956	2	demonstrated	demonstrate	VBN
cord-276598-tm0yj2sn	956	3	from	from	IN
cord-276598-tm0yj2sn	956	4	the	the	DT
cord-276598-tm0yj2sn	956	5	many	many	JJ
cord-276598-tm0yj2sn	956	6	categories	category	NNS
cord-276598-tm0yj2sn	956	7	for	for	IN
cord-276598-tm0yj2sn	956	8	the	the	DT
cord-276598-tm0yj2sn	956	9	uses	use	NNS
cord-276598-tm0yj2sn	956	10	of	of	IN
cord-276598-tm0yj2sn	956	11	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	956	12	P	p	NN
cord-276598-tm0yj2sn	956	13	-	-	HYPH
cord-276598-tm0yj2sn	956	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	956	15	,	,	,
cord-276598-tm0yj2sn	956	16	it	-PRON-	PRP
cord-276598-tm0yj2sn	956	17	is	be	VBZ
cord-276598-tm0yj2sn	956	18	clear	clear	JJ
cord-276598-tm0yj2sn	956	19	that	that	IN
cord-276598-tm0yj2sn	956	20	the	the	DT
cord-276598-tm0yj2sn	956	21	P	P	NNP
cord-276598-tm0yj2sn	956	22	-	-	HYPH
cord-276598-tm0yj2sn	956	23	N	n	CD
cord-276598-tm0yj2sn	956	24	bond	bond	NN
cord-276598-tm0yj2sn	956	25	motif	motif	NN
cord-276598-tm0yj2sn	956	26	has	have	VBZ
cord-276598-tm0yj2sn	956	27	structural	structural	JJ
cord-276598-tm0yj2sn	956	28	importance	importance	NN
cord-276598-tm0yj2sn	956	29	in	in	IN
cord-276598-tm0yj2sn	956	30	diverse	diverse	JJ
cord-276598-tm0yj2sn	956	31	fields	field	NNS
cord-276598-tm0yj2sn	956	32	.	.	.
cord-276598-tm0yj2sn	957	1	Early	early	JJ
cord-276598-tm0yj2sn	957	2	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	957	3	routes	route	NNS
cord-276598-tm0yj2sn	957	4	to	to	IN
cord-276598-tm0yj2sn	957	5	P	p	NN
cord-276598-tm0yj2sn	957	6	-	-	HYPH
cord-276598-tm0yj2sn	957	7	Ns	Ns	NNP
cord-276598-tm0yj2sn	957	8	are	be	VBP
cord-276598-tm0yj2sn	957	9	limited	limit	VBN
cord-276598-tm0yj2sn	957	10	due	due	IN
cord-276598-tm0yj2sn	957	11	to	to	IN
cord-276598-tm0yj2sn	957	12	harsh	harsh	JJ
cord-276598-tm0yj2sn	957	13	reaction	reaction	NN
cord-276598-tm0yj2sn	957	14	conditions	condition	NNS
cord-276598-tm0yj2sn	957	15	,	,	,
cord-276598-tm0yj2sn	957	16	air	air	NN
cord-276598-tm0yj2sn	957	17	and	and	CC
cord-276598-tm0yj2sn	957	18	Scheme	scheme	NN
cord-276598-tm0yj2sn	957	19	39	39	CD
cord-276598-tm0yj2sn	957	20	.	.	.
cord-276598-tm0yj2sn	958	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	958	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	958	3	for	for	IN
cord-276598-tm0yj2sn	958	4	the	the	DT
cord-276598-tm0yj2sn	958	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	958	6	of	of	IN
cord-276598-tm0yj2sn	958	7	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	958	8	via	via	IN
cord-276598-tm0yj2sn	958	9	the	the	DT
cord-276598-tm0yj2sn	958	10	phosphoamidatealdehyde	phosphoamidatealdehyde	NNP
cord-276598-tm0yj2sn	958	11	-	-	HYPH
cord-276598-tm0yj2sn	958	12	dienophile	dienophile	NNP
cord-276598-tm0yj2sn	958	13	(	(	-LRB-
cord-276598-tm0yj2sn	958	14	PAD	pad	NN
cord-276598-tm0yj2sn	958	15	)	)	-RRB-
cord-276598-tm0yj2sn	958	16	route	route	NN
cord-276598-tm0yj2sn	958	17	.	.	.
cord-276598-tm0yj2sn	959	1	In	in	IN
cord-276598-tm0yj2sn	959	2	this	this	DT
cord-276598-tm0yj2sn	959	3	review	review	NN
cord-276598-tm0yj2sn	959	4	,	,	,
cord-276598-tm0yj2sn	959	5	the	the	DT
cord-276598-tm0yj2sn	959	6	applications	application	NNS
cord-276598-tm0yj2sn	959	7	,	,	,
cord-276598-tm0yj2sn	959	8	syntheses	synthesis	NNS
cord-276598-tm0yj2sn	959	9	,	,	,
cord-276598-tm0yj2sn	959	10	and	and	CC
cord-276598-tm0yj2sn	959	11	corresponding	correspond	VBG
cord-276598-tm0yj2sn	959	12	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	959	13	of	of	IN
cord-276598-tm0yj2sn	959	14	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	959	15	have	have	VBP
cord-276598-tm0yj2sn	959	16	been	be	VBN
cord-276598-tm0yj2sn	959	17	discussed	discuss	VBN
cord-276598-tm0yj2sn	959	18	in	in	IN
cord-276598-tm0yj2sn	959	19	depth	depth	NN
cord-276598-tm0yj2sn	959	20	.	.	.
cord-276598-tm0yj2sn	960	1	As	as	IN
cord-276598-tm0yj2sn	960	2	demonstrated	demonstrate	VBN
cord-276598-tm0yj2sn	960	3	from	from	IN
cord-276598-tm0yj2sn	960	4	the	the	DT
cord-276598-tm0yj2sn	960	5	many	many	JJ
cord-276598-tm0yj2sn	960	6	categories	category	NNS
cord-276598-tm0yj2sn	960	7	for	for	IN
cord-276598-tm0yj2sn	960	8	the	the	DT
cord-276598-tm0yj2sn	960	9	uses	use	NNS
cord-276598-tm0yj2sn	960	10	of	of	IN
cord-276598-tm0yj2sn	960	11	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	960	12	P	p	NN
cord-276598-tm0yj2sn	960	13	-	-	HYPH
cord-276598-tm0yj2sn	960	14	Ns	Ns	NNP
cord-276598-tm0yj2sn	960	15	,	,	,
cord-276598-tm0yj2sn	960	16	it	-PRON-	PRP
cord-276598-tm0yj2sn	960	17	is	be	VBZ
cord-276598-tm0yj2sn	960	18	clear	clear	JJ
cord-276598-tm0yj2sn	960	19	that	that	IN
cord-276598-tm0yj2sn	960	20	the	the	DT
cord-276598-tm0yj2sn	960	21	P	P	NNP
cord-276598-tm0yj2sn	960	22	-	-	HYPH
cord-276598-tm0yj2sn	960	23	N	n	CD
cord-276598-tm0yj2sn	960	24	bond	bond	NN
cord-276598-tm0yj2sn	960	25	motif	motif	NN
cord-276598-tm0yj2sn	960	26	has	have	VBZ
cord-276598-tm0yj2sn	960	27	structural	structural	JJ
cord-276598-tm0yj2sn	960	28	importance	importance	NN
cord-276598-tm0yj2sn	960	29	in	in	IN
cord-276598-tm0yj2sn	960	30	diverse	diverse	JJ
cord-276598-tm0yj2sn	960	31	fields	field	NNS
cord-276598-tm0yj2sn	960	32	.	.	.
cord-276598-tm0yj2sn	961	1	Early	early	JJ
cord-276598-tm0yj2sn	961	2	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	961	3	routes	route	NNS
cord-276598-tm0yj2sn	961	4	to	to	IN
cord-276598-tm0yj2sn	961	5	P	p	NN
cord-276598-tm0yj2sn	961	6	-	-	HYPH
cord-276598-tm0yj2sn	961	7	Ns	Ns	NNP
cord-276598-tm0yj2sn	961	8	are	be	VBP
cord-276598-tm0yj2sn	961	9	limited	limit	VBN
cord-276598-tm0yj2sn	961	10	due	due	IN
cord-276598-tm0yj2sn	961	11	to	to	IN
cord-276598-tm0yj2sn	961	12	harsh	harsh	JJ
cord-276598-tm0yj2sn	961	13	reaction	reaction	NN
cord-276598-tm0yj2sn	961	14	conditions	condition	NNS
cord-276598-tm0yj2sn	961	15	,	,	,
cord-276598-tm0yj2sn	961	16	air	air	NN
cord-276598-tm0yj2sn	961	17	and	and	CC
cord-276598-tm0yj2sn	961	18	moisture	moisture	NN
cord-276598-tm0yj2sn	961	19	-	-	HYPH
cord-276598-tm0yj2sn	961	20	sensitive	sensitive	JJ
cord-276598-tm0yj2sn	961	21	reagents	reagent	NNS
cord-276598-tm0yj2sn	961	22	,	,	,
cord-276598-tm0yj2sn	961	23	multi	multi	JJ
cord-276598-tm0yj2sn	961	24	-	-	JJ
cord-276598-tm0yj2sn	961	25	step	step	JJ
cord-276598-tm0yj2sn	961	26	synthesis	synthesis	NN
cord-276598-tm0yj2sn	961	27	,	,	,
cord-276598-tm0yj2sn	961	28	and	and	CC
cord-276598-tm0yj2sn	961	29	undesirable	undesirable	JJ
cord-276598-tm0yj2sn	961	30	side	side	NN
cord-276598-tm0yj2sn	961	31	reactions	reaction	NNS
cord-276598-tm0yj2sn	961	32	.	.	.
cord-276598-tm0yj2sn	962	1	The	the	DT
cord-276598-tm0yj2sn	962	2	separation	separation	NN
cord-276598-tm0yj2sn	962	3	and	and	CC
cord-276598-tm0yj2sn	962	4	purification	purification	NN
cord-276598-tm0yj2sn	962	5	of	of	IN
cord-276598-tm0yj2sn	962	6	P	p	NN
cord-276598-tm0yj2sn	962	7	-	-	HYPH
cord-276598-tm0yj2sn	962	8	Ns	Ns	NNP
cord-276598-tm0yj2sn	962	9	is	be	VBZ
cord-276598-tm0yj2sn	962	10	also	also	RB
cord-276598-tm0yj2sn	962	11	a	a	DT
cord-276598-tm0yj2sn	962	12	challenge	challenge	NN
cord-276598-tm0yj2sn	962	13	.	.	.
cord-276598-tm0yj2sn	963	1	In	in	IN
cord-276598-tm0yj2sn	963	2	particular	particular	JJ
cord-276598-tm0yj2sn	963	3	,	,	,
cord-276598-tm0yj2sn	963	4	most	most	JJS
cord-276598-tm0yj2sn	963	5	of	of	IN
cord-276598-tm0yj2sn	963	6	the	the	DT
cord-276598-tm0yj2sn	963	7	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	963	8	strategies	strategy	NNS
cord-276598-tm0yj2sn	963	9	involve	involve	VBP
cord-276598-tm0yj2sn	963	10	extraction	extraction	NN
cord-276598-tm0yj2sn	963	11	and/or	and/or	CC
cord-276598-tm0yj2sn	963	12	column	column	NN
cord-276598-tm0yj2sn	963	13	chromatography	chromatography	NN
cord-276598-tm0yj2sn	963	14	,	,	,
cord-276598-tm0yj2sn	963	15	which	which	WDT
cord-276598-tm0yj2sn	963	16	not	not	RB
cord-276598-tm0yj2sn	963	17	only	only	RB
cord-276598-tm0yj2sn	963	18	requires	require	VBZ
cord-276598-tm0yj2sn	963	19	large	large	JJ
cord-276598-tm0yj2sn	963	20	amounts	amount	NNS
cord-276598-tm0yj2sn	963	21	of	of	IN
cord-276598-tm0yj2sn	963	22	solvent	solvent	NN
cord-276598-tm0yj2sn	963	23	,	,	,
cord-276598-tm0yj2sn	963	24	but	but	CC
cord-276598-tm0yj2sn	963	25	also	also	RB
cord-276598-tm0yj2sn	963	26	takes	take	VBZ
cord-276598-tm0yj2sn	963	27	a	a	DT
cord-276598-tm0yj2sn	963	28	significant	significant	JJ
cord-276598-tm0yj2sn	963	29	amount	amount	NN
cord-276598-tm0yj2sn	963	30	of	of	IN
cord-276598-tm0yj2sn	963	31	time	time	NN
cord-276598-tm0yj2sn	963	32	.	.	.
cord-276598-tm0yj2sn	964	1	Therefore	therefore	RB
cord-276598-tm0yj2sn	964	2	,	,	,
cord-276598-tm0yj2sn	964	3	unsurprisingly	unsurprisingly	RB
cord-276598-tm0yj2sn	964	4	,	,	,
cord-276598-tm0yj2sn	964	5	extensive	extensive	JJ
cord-276598-tm0yj2sn	964	6	studies	study	NNS
cord-276598-tm0yj2sn	964	7	have	have	VBP
cord-276598-tm0yj2sn	964	8	been	be	VBN
cord-276598-tm0yj2sn	964	9	undertaken	undertake	VBN
cord-276598-tm0yj2sn	964	10	(	(	-LRB-
cord-276598-tm0yj2sn	964	11	with	with	IN
cord-276598-tm0yj2sn	964	12	more	more	JJR
cord-276598-tm0yj2sn	964	13	to	to	TO
cord-276598-tm0yj2sn	964	14	come	come	VB
cord-276598-tm0yj2sn	964	15	in	in	IN
cord-276598-tm0yj2sn	964	16	the	the	DT
cord-276598-tm0yj2sn	964	17	future	future	NN
cord-276598-tm0yj2sn	964	18	)	)	-RRB-
cord-276598-tm0yj2sn	964	19	for	for	IN
cord-276598-tm0yj2sn	964	20	more	more	RBR
cord-276598-tm0yj2sn	964	21	sustainable	sustainable	JJ
cord-276598-tm0yj2sn	964	22	,	,	,
cord-276598-tm0yj2sn	964	23	efficient	efficient	JJ
cord-276598-tm0yj2sn	964	24	,	,	,
cord-276598-tm0yj2sn	964	25	atom	atom	NN
cord-276598-tm0yj2sn	964	26	economic	economic	JJ
cord-276598-tm0yj2sn	964	27	,	,	,
cord-276598-tm0yj2sn	964	28	selective	selective	JJ
cord-276598-tm0yj2sn	964	29	,	,	,
cord-276598-tm0yj2sn	964	30	and	and	CC
cord-276598-tm0yj2sn	964	31	milder	mild	JJR
cord-276598-tm0yj2sn	964	32	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	964	33	procedures	procedure	NNS
cord-276598-tm0yj2sn	964	34	toward	toward	IN
cord-276598-tm0yj2sn	964	35	P	p	NN
cord-276598-tm0yj2sn	964	36	-	-	HYPH
cord-276598-tm0yj2sn	964	37	Ns	Ns	NNP
cord-276598-tm0yj2sn	964	38	.	.	.
cord-276598-tm0yj2sn	965	1	In	in	IN
cord-276598-tm0yj2sn	965	2	addition	addition	NN
cord-276598-tm0yj2sn	965	3	,	,	,
cord-276598-tm0yj2sn	965	4	the	the	DT
cord-276598-tm0yj2sn	965	5	discussed	discuss	VBN
cord-276598-tm0yj2sn	965	6	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	965	7	require	require	VBP
cord-276598-tm0yj2sn	965	8	a	a	DT
cord-276598-tm0yj2sn	965	9	deeper	deep	JJR
cord-276598-tm0yj2sn	965	10	understanding	understanding	NN
cord-276598-tm0yj2sn	965	11	of	of	IN
cord-276598-tm0yj2sn	965	12	the	the	DT
cord-276598-tm0yj2sn	965	13	associated	associate	VBN
cord-276598-tm0yj2sn	965	14	phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	965	15	chemistry	chemistry	NN
cord-276598-tm0yj2sn	965	16	in	in	IN
cord-276598-tm0yj2sn	965	17	order	order	NN
cord-276598-tm0yj2sn	965	18	to	to	TO
cord-276598-tm0yj2sn	965	19	have	have	VB
cord-276598-tm0yj2sn	965	20	better	well	JJR
cord-276598-tm0yj2sn	965	21	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	965	22	control	control	NN
cord-276598-tm0yj2sn	965	23	and	and	CC
cord-276598-tm0yj2sn	965	24	to	to	TO
cord-276598-tm0yj2sn	965	25	optimize	optimize	VB
cord-276598-tm0yj2sn	965	26	the	the	DT
cord-276598-tm0yj2sn	965	27	yield	yield	NN
cord-276598-tm0yj2sn	965	28	and	and	CC
cord-276598-tm0yj2sn	965	29	selectivity	selectivity	NN
cord-276598-tm0yj2sn	965	30	toward	toward	IN
cord-276598-tm0yj2sn	965	31	P	P	NNP
cord-276598-tm0yj2sn	965	32	-	-	HYPH
cord-276598-tm0yj2sn	965	33	N	n	CD
cord-276598-tm0yj2sn	965	34	products	product	NNS
cord-276598-tm0yj2sn	965	35	.	.	.
cord-276598-tm0yj2sn	966	1	To	to	TO
cord-276598-tm0yj2sn	966	2	overcome	overcome	VB
cord-276598-tm0yj2sn	966	3	these	these	DT
cord-276598-tm0yj2sn	966	4	challenges	challenge	NNS
cord-276598-tm0yj2sn	966	5	,	,	,
cord-276598-tm0yj2sn	966	6	it	-PRON-	PRP
cord-276598-tm0yj2sn	966	7	is	be	VBZ
cord-276598-tm0yj2sn	966	8	predicted	predict	VBN
cord-276598-tm0yj2sn	966	9	that	that	IN
cord-276598-tm0yj2sn	966	10	better	well	JJR
cord-276598-tm0yj2sn	966	11	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	966	12	,	,	,
cord-276598-tm0yj2sn	966	13	improved	improve	VBN
cord-276598-tm0yj2sn	966	14	reaction	reaction	NN
cord-276598-tm0yj2sn	966	15	conditions	condition	NNS
cord-276598-tm0yj2sn	966	16	,	,	,
cord-276598-tm0yj2sn	966	17	and	and	CC
cord-276598-tm0yj2sn	966	18	new	new	JJ
cord-276598-tm0yj2sn	966	19	solvent	solvent	NN
cord-276598-tm0yj2sn	966	20	solutions	solution	NNS
cord-276598-tm0yj2sn	966	21	for	for	IN
cord-276598-tm0yj2sn	966	22	separating	separate	VBG
cord-276598-tm0yj2sn	966	23	the	the	DT
cord-276598-tm0yj2sn	966	24	product	product	NN
cord-276598-tm0yj2sn	966	25	from	from	IN
cord-276598-tm0yj2sn	966	26	the	the	DT
cord-276598-tm0yj2sn	966	27	by	by	NN
cord-276598-tm0yj2sn	966	28	-	-	HYPH
cord-276598-tm0yj2sn	966	29	products	product	NNS
cord-276598-tm0yj2sn	966	30	and	and	CC
cord-276598-tm0yj2sn	966	31	potentially	potentially	RB
cord-276598-tm0yj2sn	966	32	improving	improve	VBG
cord-276598-tm0yj2sn	966	33	selectivity	selectivity	NN
cord-276598-tm0yj2sn	966	34	are	be	VBP
cord-276598-tm0yj2sn	966	35	in	in	IN
cord-276598-tm0yj2sn	966	36	the	the	DT
cord-276598-tm0yj2sn	966	37	forecast	forecast	NN
cord-276598-tm0yj2sn	966	38	.	.	.
cord-276598-tm0yj2sn	967	1	For	for	IN
cord-276598-tm0yj2sn	967	2	example	example	NN
cord-276598-tm0yj2sn	967	3	,	,	,
cord-276598-tm0yj2sn	967	4	there	there	EX
cord-276598-tm0yj2sn	967	5	is	be	VBZ
cord-276598-tm0yj2sn	967	6	a	a	DT
cord-276598-tm0yj2sn	967	7	sharp	sharp	JJ
cord-276598-tm0yj2sn	967	8	rise	rise	NN
cord-276598-tm0yj2sn	967	9	into	into	IN
cord-276598-tm0yj2sn	967	10	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	967	11	research	research	NN
cord-276598-tm0yj2sn	967	12	under	under	IN
cord-276598-tm0yj2sn	967	13	solvent	solvent	NN
cord-276598-tm0yj2sn	967	14	-	-	HYPH
cord-276598-tm0yj2sn	967	15	free	free	JJ
cord-276598-tm0yj2sn	967	16	conditions	condition	NNS
cord-276598-tm0yj2sn	967	17	or	or	CC
cord-276598-tm0yj2sn	967	18	using	use	VBG
cord-276598-tm0yj2sn	967	19	ionic	ionic	JJ
cord-276598-tm0yj2sn	967	20	liquids	liquid	NNS
cord-276598-tm0yj2sn	967	21	(	(	-LRB-
cord-276598-tm0yj2sn	967	22	ILs	ILs	NNP
cord-276598-tm0yj2sn	967	23	)	)	-RRB-
cord-276598-tm0yj2sn	967	24	and	and	CC
cord-276598-tm0yj2sn	967	25	deep	deep	JJ
cord-276598-tm0yj2sn	967	26	eutectic	eutectic	JJ
cord-276598-tm0yj2sn	967	27	solvents	solvent	NNS
cord-276598-tm0yj2sn	967	28	(	(	-LRB-
cord-276598-tm0yj2sn	967	29	DES	DES	NNP
cord-276598-tm0yj2sn	967	30	)	)	-RRB-
cord-276598-tm0yj2sn	967	31	.	.	.
cord-276598-tm0yj2sn	968	1	These	these	DT
cord-276598-tm0yj2sn	968	2	can	can	MD
cord-276598-tm0yj2sn	968	3	be	be	VB
cord-276598-tm0yj2sn	968	4	environmentally	environmentally	RB
cord-276598-tm0yj2sn	968	5	benign	benign	JJ
cord-276598-tm0yj2sn	968	6	,	,	,
cord-276598-tm0yj2sn	968	7	highly	highly	RB
cord-276598-tm0yj2sn	968	8	versatile	versatile	JJ
cord-276598-tm0yj2sn	968	9	,	,	,
cord-276598-tm0yj2sn	968	10	selective	selective	JJ
cord-276598-tm0yj2sn	968	11	,	,	,
cord-276598-tm0yj2sn	968	12	and	and	CC
cord-276598-tm0yj2sn	968	13	recoverable	recoverable	JJ
cord-276598-tm0yj2sn	968	14	solvents	solvent	NNS
cord-276598-tm0yj2sn	968	15	for	for	IN
cord-276598-tm0yj2sn	968	16	use	use	NN
cord-276598-tm0yj2sn	968	17	in	in	IN
cord-276598-tm0yj2sn	968	18	catalysis	catalysis	NN
cord-276598-tm0yj2sn	968	19	.	.	.
cord-276598-tm0yj2sn	968	20	 	 	_SP
cord-276598-tm0yj2sn	969	1	Diastereoselective	diastereoselective	JJ
cord-276598-tm0yj2sn	969	2	multicomponent	multicomponent	NN
cord-276598-tm0yj2sn	969	3	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	969	4	-	-	HYPH
cord-276598-tm0yj2sn	969	5	aldehydedienophile	aldehydedienophile	NNP
cord-276598-tm0yj2sn	969	6	(	(	-LRB-
cord-276598-tm0yj2sn	969	7	PAD	pad	NN
cord-276598-tm0yj2sn	969	8	)	)	-RRB-
cord-276598-tm0yj2sn	969	9	process	process	NN
cord-276598-tm0yj2sn	969	10	for	for	IN
cord-276598-tm0yj2sn	969	11	the	the	DT
cord-276598-tm0yj2sn	969	12	synthesis	synthesis	NN
cord-276598-tm0yj2sn	969	13	of	of	IN
cord-276598-tm0yj2sn	969	14	polysubstituted	polysubstituted	NNP
cord-276598-tm0yj2sn	969	15	cyclohex-2-enyl	cyclohex-2-enyl	NN
cord-276598-tm0yj2sn	969	16	-	-	HYPH
cord-276598-tm0yj2sn	969	17	amine	amine	NN
cord-276598-tm0yj2sn	969	18	derivatives	derivative	NNS
cord-276598-tm0yj2sn	969	19	Total	Total	NNP
cord-276598-tm0yj2sn	969	20	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	969	21	of	of	IN
cord-276598-tm0yj2sn	969	22	Agrocin	Agrocin	NNP
cord-276598-tm0yj2sn	969	23	84	84	CD
cord-276598-tm0yj2sn	969	24	and	and	CC
cord-276598-tm0yj2sn	969	25	Phosmidosine	Phosmidosine	NNP
cord-276598-tm0yj2sn	969	26	as	as	IN
cord-276598-tm0yj2sn	969	27	Naturally	naturally	RB
cord-276598-tm0yj2sn	970	1	Occurring	occur	VBG
cord-276598-tm0yj2sn	970	2	Nucleotidic	Nucleotidic	NNP
cord-276598-tm0yj2sn	970	3	Antibiotics	Antibiotics	NNPS
cord-276598-tm0yj2sn	971	1	Having	have	VBG
cord-276598-tm0yj2sn	972	1	P	p	NN
cord-276598-tm0yj2sn	972	2	-	-	HYPH
cord-276598-tm0yj2sn	972	3	N	N	NNP
cord-276598-tm0yj2sn	972	4	Bond	Bond	NNP
cord-276598-tm0yj2sn	972	5	Linkages	Linkages	NNP
cord-276598-tm0yj2sn	972	6	Natural	Natural	NNP
cord-276598-tm0yj2sn	972	7	Products	Products	NNPS
cord-276598-tm0yj2sn	972	8	Containing	contain	VBG
cord-276598-tm0yj2sn	972	9	'	'	``
cord-276598-tm0yj2sn	972	10	Rare	Rare	NNP
cord-276598-tm0yj2sn	972	11	'	'	''
cord-276598-tm0yj2sn	972	12	Organophosphorus	Organophosphorus	NNP
cord-276598-tm0yj2sn	972	13	Functional	Functional	NNP
cord-276598-tm0yj2sn	972	14	Groups	Groups	NNPS
cord-276598-tm0yj2sn	972	15	Chemical	Chemical	NNP
cord-276598-tm0yj2sn	972	16	Structure	Structure	NNP
cord-276598-tm0yj2sn	972	17	and	and	CC
cord-276598-tm0yj2sn	972	18	Translation	Translation	NNP
cord-276598-tm0yj2sn	972	19	Inhibition	Inhibition	NNP
cord-276598-tm0yj2sn	972	20	Studies	Studies	NNPS
cord-276598-tm0yj2sn	972	21	of	of	IN
cord-276598-tm0yj2sn	972	22	the	the	DT
cord-276598-tm0yj2sn	972	23	Antibiotic	Antibiotic	NNP
cord-276598-tm0yj2sn	972	24	Microcin	Microcin	NNP
cord-276598-tm0yj2sn	972	25	C7	C7	NNP
cord-276598-tm0yj2sn	972	26	Properties	Properties	NNPS
cord-276598-tm0yj2sn	972	27	of	of	IN
cord-276598-tm0yj2sn	972	28	a	a	DT
cord-276598-tm0yj2sn	972	29	toxic	toxic	JJ
cord-276598-tm0yj2sn	972	30	phospholipid	phospholipid	NN
cord-276598-tm0yj2sn	972	31	in	in	IN
cord-276598-tm0yj2sn	972	32	the	the	DT
cord-276598-tm0yj2sn	972	33	northern	northern	JJ
cord-276598-tm0yj2sn	972	34	blenny	blenny	NN
cord-276598-tm0yj2sn	972	35	roe	roe	NNP
cord-276598-tm0yj2sn	972	36	Focus	Focus	NNP
cord-276598-tm0yj2sn	972	37	on	on	IN
cord-276598-tm0yj2sn	972	38	Phosphoarginine	Phosphoarginine	NNP
cord-276598-tm0yj2sn	972	39	and	and	CC
cord-276598-tm0yj2sn	972	40	Phospholysine	Phospholysine	NNP
cord-276598-tm0yj2sn	972	41	Encyclopedia	Encyclopedia	NNP
cord-276598-tm0yj2sn	972	42	of	of	IN
cord-276598-tm0yj2sn	972	43	Metalloproteins	Metalloproteins	NNP
cord-276598-tm0yj2sn	972	44	Chapter	Chapter	NNP
cord-276598-tm0yj2sn	972	45	111-Thermolysin	111-Thermolysin	NNP
cord-276598-tm0yj2sn	972	46	and	and	CC
cord-276598-tm0yj2sn	972	47	Related	related	JJ
cord-276598-tm0yj2sn	972	48	Bacillus	Bacillus	NNP
cord-276598-tm0yj2sn	972	49	Metallopeptidases	Metallopeptidases	NNP
cord-276598-tm0yj2sn	972	50	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	972	51	of	of	IN
cord-276598-tm0yj2sn	972	52	nucleotide	nucleotide	JJ
cord-276598-tm0yj2sn	972	53	antibiotics	antibiotic	NNS
cord-276598-tm0yj2sn	973	1	having	have	VBG
cord-276598-tm0yj2sn	973	2	N	n	CD
cord-276598-tm0yj2sn	973	3	-	-	HYPH
cord-276598-tm0yj2sn	973	4	acyl	acyl	NN
cord-276598-tm0yj2sn	973	5	phosphoramidate	phosphoramidate	NNP
cord-276598-tm0yj2sn	973	6	linkages	linkage	NNS
cord-276598-tm0yj2sn	973	7	Structure	Structure	NNP
cord-276598-tm0yj2sn	973	8	of	of	IN
cord-276598-tm0yj2sn	973	9	the	the	DT
cord-276598-tm0yj2sn	973	10	antifungal	antifungal	JJ
cord-276598-tm0yj2sn	973	11	nucleotide	nucleotide	NN
cord-276598-tm0yj2sn	973	12	antibiotic	antibiotic	JJ
cord-276598-tm0yj2sn	973	13	phosmidosine	phosmidosine	NNP
cord-276598-tm0yj2sn	974	1	The	the	DT
cord-276598-tm0yj2sn	974	2	diverse	diverse	JJ
cord-276598-tm0yj2sn	974	3	pharmacology	pharmacology	NN
cord-276598-tm0yj2sn	974	4	and	and	CC
cord-276598-tm0yj2sn	974	5	medicinal	medicinal	JJ
cord-276598-tm0yj2sn	974	6	chemistry	chemistry	NN
cord-276598-tm0yj2sn	974	7	of	of	IN
cord-276598-tm0yj2sn	974	8	phosphoramidates	phosphoramidates	NN
cord-276598-tm0yj2sn	974	9	-	-	HYPH
cord-276598-tm0yj2sn	974	10	A	a	DT
cord-276598-tm0yj2sn	974	11	review	review	NN
cord-276598-tm0yj2sn	974	12	Remdesivir	Remdesivir	NNP
cord-276598-tm0yj2sn	974	13	for	for	IN
cord-276598-tm0yj2sn	974	14	severe	severe	JJ
cord-276598-tm0yj2sn	974	15	acute	acute	JJ
cord-276598-tm0yj2sn	974	16	respiratory	respiratory	JJ
cord-276598-tm0yj2sn	974	17	syndrome	syndrome	NN
cord-276598-tm0yj2sn	974	18	coronavirus	coronavirus	NN
cord-276598-tm0yj2sn	974	19	2	2	CD
cord-276598-tm0yj2sn	974	20	causing	cause	VBG
cord-276598-tm0yj2sn	974	21	COVID-19	covid-19	CD
cord-276598-tm0yj2sn	974	22	:	:	:
cord-276598-tm0yj2sn	975	1	An	an	DT
cord-276598-tm0yj2sn	975	2	evaluation	evaluation	NN
cord-276598-tm0yj2sn	975	3	of	of	IN
cord-276598-tm0yj2sn	975	4	the	the	DT
cord-276598-tm0yj2sn	975	5	evidence	evidence	NN
cord-276598-tm0yj2sn	975	6	N	n	NN
cord-276598-tm0yj2sn	975	7	-	-	HYPH
cord-276598-tm0yj2sn	975	8	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	975	9	labeling	labeling	NN
cord-276598-tm0yj2sn	975	10	for	for	IN
cord-276598-tm0yj2sn	975	11	analysis	analysis	NN
cord-276598-tm0yj2sn	975	12	of	of	IN
cord-276598-tm0yj2sn	975	13	twenty	twenty	CD
cord-276598-tm0yj2sn	975	14	natural	natural	JJ
cord-276598-tm0yj2sn	975	15	amino	amino	NN
cord-276598-tm0yj2sn	975	16	acids	acid	NNS
cord-276598-tm0yj2sn	975	17	and	and	CC
cord-276598-tm0yj2sn	975	18	small	small	JJ
cord-276598-tm0yj2sn	975	19	peptides	peptide	NNS
cord-276598-tm0yj2sn	975	20	by	by	IN
cord-276598-tm0yj2sn	975	21	using	use	VBG
cord-276598-tm0yj2sn	975	22	matrix	matrix	NN
cord-276598-tm0yj2sn	975	23	-	-	HYPH
cord-276598-tm0yj2sn	975	24	assisted	assist	VBN
cord-276598-tm0yj2sn	975	25	laser	laser	NN
cord-276598-tm0yj2sn	975	26	desorption	desorption	NN
cord-276598-tm0yj2sn	975	27	/	/	SYM
cord-276598-tm0yj2sn	975	28	ionization	ionization	NN
cord-276598-tm0yj2sn	975	29	time	time	NN
cord-276598-tm0yj2sn	975	30	-	-	HYPH
cord-276598-tm0yj2sn	975	31	of	of	IN
cord-276598-tm0yj2sn	975	32	-	-	HYPH
cord-276598-tm0yj2sn	975	33	flight	flight	NN
cord-276598-tm0yj2sn	975	34	mass	mass	NN
cord-276598-tm0yj2sn	975	35	spectrometry	spectrometry	NN
cord-276598-tm0yj2sn	975	36	Structural	Structural	NNP
cord-276598-tm0yj2sn	975	37	Effect	effect	NN
cord-276598-tm0yj2sn	975	38	of	of	IN
cord-276598-tm0yj2sn	975	39	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	975	40	Derivatives	Derivatives	NNPS
cord-276598-tm0yj2sn	975	41	on	on	IN
cord-276598-tm0yj2sn	975	42	the	the	DT
cord-276598-tm0yj2sn	975	43	Thermal	Thermal	NNP
cord-276598-tm0yj2sn	975	44	and	and	CC
cord-276598-tm0yj2sn	975	45	Flame	Flame	NNP
cord-276598-tm0yj2sn	975	46	Retardant	Retardant	NNP
cord-276598-tm0yj2sn	975	47	Behaviors	Behaviors	NNPS
cord-276598-tm0yj2sn	975	48	of	of	IN
cord-276598-tm0yj2sn	975	49	Treated	treat	VBN
cord-276598-tm0yj2sn	975	50	Cotton	Cotton	NNP
cord-276598-tm0yj2sn	975	51	Cellulose	Cellulose	NNP
cord-276598-tm0yj2sn	975	52	Electrochemical	electrochemical	JJ
cord-276598-tm0yj2sn	975	53	determination	determination	NN
cord-276598-tm0yj2sn	975	54	of	of	IN
cord-276598-tm0yj2sn	975	55	the	the	DT
cord-276598-tm0yj2sn	975	56	organophosphate	organophosphate	NN
cord-276598-tm0yj2sn	975	57	compound	compound	NN
cord-276598-tm0yj2sn	975	58	Fenamiphos	Fenamiphos	NNP
cord-276598-tm0yj2sn	975	59	and	and	CC
cord-276598-tm0yj2sn	975	60	its	-PRON-	PRP$
cord-276598-tm0yj2sn	975	61	main	main	JJ
cord-276598-tm0yj2sn	975	62	metabolite	metabolite	NN
cord-276598-tm0yj2sn	975	63	,	,	,
cord-276598-tm0yj2sn	975	64	Fenamiphos	Fenamiphos	NNP
cord-276598-tm0yj2sn	975	65	sulfoxide	sulfoxide	NN
cord-276598-tm0yj2sn	975	66	New	New	NNP
cord-276598-tm0yj2sn	975	67	o	o	NN
cord-276598-tm0yj2sn	975	68	-	-	HYPH
cord-276598-tm0yj2sn	975	69	substituted	substitute	VBN
cord-276598-tm0yj2sn	975	70	diphenylphosphinic	diphenylphosphinic	JJ
cord-276598-tm0yj2sn	975	71	amide	amide	NN
cord-276598-tm0yj2sn	975	72	ligands	ligand	NNS
cord-276598-tm0yj2sn	975	73	:	:	:
cord-276598-tm0yj2sn	975	74	Synthesis	synthesis	NN
cord-276598-tm0yj2sn	975	75	,	,	,
cord-276598-tm0yj2sn	975	76	characterization	characterization	NN
cord-276598-tm0yj2sn	975	77	and	and	CC
cord-276598-tm0yj2sn	975	78	complexation	complexation	NN
cord-276598-tm0yj2sn	975	79	with	with	IN
cord-276598-tm0yj2sn	975	80	Zn	Zn	NNP
cord-276598-tm0yj2sn	975	81	2	2	CD
cord-276598-tm0yj2sn	976	1	+	+	CC
cord-276598-tm0yj2sn	977	1	,	,	,
cord-276598-tm0yj2sn	977	2	Cu	Cu	NNP
cord-276598-tm0yj2sn	977	3	2	2	CD
cord-276598-tm0yj2sn	977	4	+	+	CC
cord-276598-tm0yj2sn	977	5	and	and	CC
cord-276598-tm0yj2sn	977	6	Y	Y	NNP
cord-276598-tm0yj2sn	977	7	3	3	CD
cord-276598-tm0yj2sn	978	1	+	+	CC
cord-276598-tm0yj2sn	979	1	Significant	significant	JJ
cord-276598-tm0yj2sn	979	2	enhanced	enhance	VBN
cord-276598-tm0yj2sn	979	3	uranyl	uranyl	NN
cord-276598-tm0yj2sn	979	4	ions	ion	NNS
cord-276598-tm0yj2sn	979	5	extraction	extraction	NN
cord-276598-tm0yj2sn	979	6	efficiency	efficiency	NN
cord-276598-tm0yj2sn	979	7	with	with	IN
cord-276598-tm0yj2sn	979	8	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	979	9	-	-	HYPH
cord-276598-tm0yj2sn	979	10	functionalized	functionalize	VBN
cord-276598-tm0yj2sn	979	11	ionic	ionic	JJ
cord-276598-tm0yj2sn	979	12	liquids	liquid	NNS
cord-276598-tm0yj2sn	979	13	via	via	IN
cord-276598-tm0yj2sn	979	14	synergistic	synergistic	JJ
cord-276598-tm0yj2sn	979	15	effect	effect	NN
cord-276598-tm0yj2sn	979	16	of	of	IN
cord-276598-tm0yj2sn	979	17	coordination	coordination	NN
cord-276598-tm0yj2sn	979	18	and	and	CC
cord-276598-tm0yj2sn	979	19	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	979	20	bond	bond	NN
cord-276598-tm0yj2sn	980	1	The	the	DT
cord-276598-tm0yj2sn	980	2	tribochemical	tribochemical	JJ
cord-276598-tm0yj2sn	980	3	study	study	NN
cord-276598-tm0yj2sn	980	4	of	of	IN
cord-276598-tm0yj2sn	980	5	novel	novel	JJ
cord-276598-tm0yj2sn	980	6	phosphorous	phosphorous	NN
cord-276598-tm0yj2sn	980	7	-	-	HYPH
cord-276598-tm0yj2sn	980	8	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	980	9	(	(	-LRB-
cord-276598-tm0yj2sn	980	10	P	P	NNP
cord-276598-tm0yj2sn	980	11	-	-	HYPH
cord-276598-tm0yj2sn	980	12	N	N	NNP
cord-276598-tm0yj2sn	980	13	)	)	-RRB-
cord-276598-tm0yj2sn	980	14	type	type	NN
cord-276598-tm0yj2sn	980	15	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	980	16	additives	additive	NNS
cord-276598-tm0yj2sn	980	17	in	in	IN
cord-276598-tm0yj2sn	980	18	water	water	NN
cord-276598-tm0yj2sn	981	1	The	the	DT
cord-276598-tm0yj2sn	982	1	Organophosphate	Organophosphate	NNP
cord-276598-tm0yj2sn	982	2	Pesticides	Pesticides	NNP
cord-276598-tm0yj2sn	982	3	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	982	4	and	and	CC
cord-276598-tm0yj2sn	982	5	insecticidal	insecticidal	JJ
cord-276598-tm0yj2sn	982	6	activity	activity	NN
cord-276598-tm0yj2sn	982	7	of	of	IN
cord-276598-tm0yj2sn	982	8	new	new	JJ
cord-276598-tm0yj2sn	982	9	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	982	10	Organophosphorus	Organophosphorus	NNP
cord-276598-tm0yj2sn	982	11	pesticides	pesticide	NNS
cord-276598-tm0yj2sn	982	12	as	as	IN
cord-276598-tm0yj2sn	982	13	food	food	NN
cord-276598-tm0yj2sn	982	14	chain	chain	NN
cord-276598-tm0yj2sn	982	15	contaminants	contaminant	NNS
cord-276598-tm0yj2sn	982	16	and	and	CC
cord-276598-tm0yj2sn	982	17	type	type	NN
cord-276598-tm0yj2sn	982	18	2	2	CD
cord-276598-tm0yj2sn	982	19	diabetes	diabetes	NN
cord-276598-tm0yj2sn	982	20	:	:	:
cord-276598-tm0yj2sn	982	21	A	a	DT
cord-276598-tm0yj2sn	982	22	review	review	NN
cord-276598-tm0yj2sn	982	23	Current	current	JJ
cord-276598-tm0yj2sn	982	24	issues	issue	NNS
cord-276598-tm0yj2sn	982	25	in	in	IN
cord-276598-tm0yj2sn	982	26	organophosphate	organophosphate	NN
cord-276598-tm0yj2sn	982	27	toxicology	toxicology	NN
cord-276598-tm0yj2sn	982	28	Saligenin	Saligenin	NNP
cord-276598-tm0yj2sn	982	29	Cyclic	Cyclic	NNP
cord-276598-tm0yj2sn	982	30	Phosphoramidates	Phosphoramidates	NNPS
cord-276598-tm0yj2sn	982	31	and	and	CC
cord-276598-tm0yj2sn	982	32	Phosphoramidothionates	Phosphoramidothionates	NNPS
cord-276598-tm0yj2sn	982	33	as	as	IN
cord-276598-tm0yj2sn	982	34	Pesticides	pesticide	NNS
cord-276598-tm0yj2sn	982	35	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	982	36	and	and	CC
cord-276598-tm0yj2sn	982	37	insecticidal	insecticidal	JJ
cord-276598-tm0yj2sn	982	38	activity	activity	NN
cord-276598-tm0yj2sn	982	39	of	of	IN
cord-276598-tm0yj2sn	982	40	new	new	JJ
cord-276598-tm0yj2sn	982	41	3-benzylfuran-2-yl	3-benzylfuran-2-yl	CD
cord-276598-tm0yj2sn	982	42	N	N	NNP
cord-276598-tm0yj2sn	982	43	,	,	,
cord-276598-tm0yj2sn	982	44	N	N	NNP
cord-276598-tm0yj2sn	982	45	,	,	,
cord-276598-tm0yj2sn	982	46	N	N	NNP
cord-276598-tm0yj2sn	982	47	,	,	,
cord-276598-tm0yj2sn	982	48	N	n	CD
cord-276598-tm0yj2sn	982	49	-tetraethyldiamidophosphate	-tetraethyldiamidophosphate	NN
cord-276598-tm0yj2sn	982	50	derivatives	derivative	NNS
cord-276598-tm0yj2sn	982	51	Negatively	negatively	RB
cord-276598-tm0yj2sn	982	52	Correlated	Correlated	NNP
cord-276598-tm0yj2sn	982	53	Cross	Cross	NNP
cord-276598-tm0yj2sn	982	54	-	-	NN
cord-276598-tm0yj2sn	982	55	resistance	resistance	NN
cord-276598-tm0yj2sn	982	56	and	and	CC
cord-276598-tm0yj2sn	982	57	Synergism	synergism	NN
cord-276598-tm0yj2sn	982	58	between	between	IN
cord-276598-tm0yj2sn	982	59	Phosphoramidates	Phosphoramidates	NNP
cord-276598-tm0yj2sn	982	60	and	and	CC
cord-276598-tm0yj2sn	982	61	Phosphorothiolates	Phosphorothiolates	NNPS
cord-276598-tm0yj2sn	982	62	in	in	IN
cord-276598-tm0yj2sn	982	63	Their	-PRON-	PRP$
cord-276598-tm0yj2sn	982	64	Fungicidal	Fungicidal	NNP
cord-276598-tm0yj2sn	982	65	Actions	Actions	NNPS
cord-276598-tm0yj2sn	982	66	on	on	IN
cord-276598-tm0yj2sn	982	67	Rice	Rice	NNP
cord-276598-tm0yj2sn	982	68	Blast	Blast	NNP
cord-276598-tm0yj2sn	982	69	Fungi	Fungi	NNP
cord-276598-tm0yj2sn	983	1	A	a	DT
cord-276598-tm0yj2sn	983	2	minireview	minireview	NN
cord-276598-tm0yj2sn	983	3	on	on	IN
cord-276598-tm0yj2sn	983	4	what	what	WP
cord-276598-tm0yj2sn	983	5	we	-PRON-	PRP
cord-276598-tm0yj2sn	983	6	have	have	VBP
cord-276598-tm0yj2sn	983	7	learned	learn	VBN
cord-276598-tm0yj2sn	983	8	about	about	IN
cord-276598-tm0yj2sn	983	9	urease	urease	NN
cord-276598-tm0yj2sn	983	10	inhibitors	inhibitor	NNS
cord-276598-tm0yj2sn	983	11	of	of	IN
cord-276598-tm0yj2sn	983	12	agricultural	agricultural	JJ
cord-276598-tm0yj2sn	983	13	interest	interest	NN
cord-276598-tm0yj2sn	983	14	since	since	IN
cord-276598-tm0yj2sn	983	15	mid-2000s	mid-2000s	NNP
cord-276598-tm0yj2sn	983	16	Design	Design	NNP
cord-276598-tm0yj2sn	983	17	,	,	,
cord-276598-tm0yj2sn	983	18	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	983	19	,	,	,
cord-276598-tm0yj2sn	983	20	and	and	CC
cord-276598-tm0yj2sn	983	21	Biological	Biological	NNP
cord-276598-tm0yj2sn	983	22	Evaluation	Evaluation	NNP
cord-276598-tm0yj2sn	983	23	of	of	IN
cord-276598-tm0yj2sn	983	24	Phosphoramide	Phosphoramide	NNP
cord-276598-tm0yj2sn	983	25	Derivatives	Derivatives	NNP
cord-276598-tm0yj2sn	983	26	as	as	IN
cord-276598-tm0yj2sn	983	27	Urease	Urease	NNP
cord-276598-tm0yj2sn	983	28	Inhibitors	Inhibitors	NNP
cord-276598-tm0yj2sn	984	1	Recent	recent	JJ
cord-276598-tm0yj2sn	984	2	advances	advance	NNS
cord-276598-tm0yj2sn	984	3	in	in	IN
cord-276598-tm0yj2sn	984	4	design	design	NN
cord-276598-tm0yj2sn	984	5	of	of	IN
cord-276598-tm0yj2sn	984	6	new	new	JJ
cord-276598-tm0yj2sn	984	7	urease	urease	NN
cord-276598-tm0yj2sn	984	8	inhibitors	inhibitor	NNS
cord-276598-tm0yj2sn	984	9	:	:	:
cord-276598-tm0yj2sn	985	1	A	a	DT
cord-276598-tm0yj2sn	985	2	review	review	NN
cord-276598-tm0yj2sn	986	1	A	a	DT
cord-276598-tm0yj2sn	986	2	review	review	NN
cord-276598-tm0yj2sn	986	3	on	on	IN
cord-276598-tm0yj2sn	986	4	the	the	DT
cord-276598-tm0yj2sn	986	5	development	development	NN
cord-276598-tm0yj2sn	986	6	of	of	IN
cord-276598-tm0yj2sn	986	7	urease	urease	NN
cord-276598-tm0yj2sn	986	8	inhibitors	inhibitor	NNS
cord-276598-tm0yj2sn	986	9	as	as	IN
cord-276598-tm0yj2sn	986	10	antimicrobial	antimicrobial	JJ
cord-276598-tm0yj2sn	986	11	agents	agent	NNS
cord-276598-tm0yj2sn	986	12	against	against	IN
cord-276598-tm0yj2sn	986	13	pathogenic	pathogenic	JJ
cord-276598-tm0yj2sn	986	14	bacteria	bacteria	NNS
cord-276598-tm0yj2sn	987	1	The	the	DT
cord-276598-tm0yj2sn	987	2	tribological	tribological	JJ
cord-276598-tm0yj2sn	987	3	study	study	NN
cord-276598-tm0yj2sn	987	4	of	of	IN
cord-276598-tm0yj2sn	987	5	novel	novel	JJ
cord-276598-tm0yj2sn	987	6	phosphorous	phosphorous	NN
cord-276598-tm0yj2sn	987	7	-	-	HYPH
cord-276598-tm0yj2sn	987	8	nitrogen	nitrogen	NN
cord-276598-tm0yj2sn	987	9	type	type	NN
cord-276598-tm0yj2sn	987	10	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	987	11	additives	additive	NNS
cord-276598-tm0yj2sn	987	12	in	in	IN
cord-276598-tm0yj2sn	987	13	rapeseed	rapeseed	NN
cord-276598-tm0yj2sn	987	14	oil	oil	NN
cord-276598-tm0yj2sn	987	15	Halogenated	halogenate	VBN
cord-276598-tm0yj2sn	987	16	flame	flame	NN
cord-276598-tm0yj2sn	987	17	retardants	retardant	NNS
cord-276598-tm0yj2sn	987	18	:	:	:
cord-276598-tm0yj2sn	987	19	Do	do	VB
cord-276598-tm0yj2sn	987	20	the	the	DT
cord-276598-tm0yj2sn	987	21	fire	fire	NN
cord-276598-tm0yj2sn	987	22	safety	safety	NN
cord-276598-tm0yj2sn	987	23	benefits	benefit	NNS
cord-276598-tm0yj2sn	987	24	justify	justify	VBP
cord-276598-tm0yj2sn	987	25	the	the	DT
cord-276598-tm0yj2sn	987	26	risks	risk	NNS
cord-276598-tm0yj2sn	987	27	?	?	.
cord-276598-tm0yj2sn	988	1	Thermal	thermal	JJ
cord-276598-tm0yj2sn	988	2	degradation	degradation	NN
cord-276598-tm0yj2sn	988	3	of	of	IN
cord-276598-tm0yj2sn	988	4	cellulose	cellulose	NN
cord-276598-tm0yj2sn	988	5	acetate	acetate	NN
cord-276598-tm0yj2sn	988	6	in	in	IN
cord-276598-tm0yj2sn	988	7	presence	presence	NN
cord-276598-tm0yj2sn	988	8	of	of	IN
cord-276598-tm0yj2sn	988	9	bis	bis	NNP
cord-276598-tm0yj2sn	988	10	-	-	HYPH
cord-276598-tm0yj2sn	988	11	phosphoramidates	phosphoramidates	JJ
cord-276598-tm0yj2sn	988	12	Multiparameter	Multiparameter	NNP
cord-276598-tm0yj2sn	988	13	toxicity	toxicity	NN
cord-276598-tm0yj2sn	988	14	assessment	assessment	NN
cord-276598-tm0yj2sn	988	15	of	of	IN
cord-276598-tm0yj2sn	988	16	novel	novel	JJ
cord-276598-tm0yj2sn	988	17	DOPO	DOPO	NNP
cord-276598-tm0yj2sn	988	18	-	-	HYPH
cord-276598-tm0yj2sn	988	19	derived	derive	VBN
cord-276598-tm0yj2sn	988	20	organophosphorus	organophosphorus	JJ
cord-276598-tm0yj2sn	988	21	flame	flame	NN
cord-276598-tm0yj2sn	988	22	retardants	retardant	NNS
cord-276598-tm0yj2sn	989	1	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	989	2	-	-	HYPH
cord-276598-tm0yj2sn	989	3	Containing	contain	VBG
cord-276598-tm0yj2sn	989	4	Flame	Flame	NNP
cord-276598-tm0yj2sn	989	5	-	-	HYPH
cord-276598-tm0yj2sn	989	6	Retardant	Retardant	NNP
cord-276598-tm0yj2sn	989	7	Flexible	Flexible	NNP
cord-276598-tm0yj2sn	989	8	Polyurethane	Polyurethane	NNP
cord-276598-tm0yj2sn	990	1	Foams	Foams	NNP
cord-276598-tm0yj2sn	990	2	Recent	Recent	NNP
cord-276598-tm0yj2sn	990	3	Advances	Advances	NNPS
cord-276598-tm0yj2sn	990	4	for	for	IN
cord-276598-tm0yj2sn	990	5	Flame	Flame	NNP
cord-276598-tm0yj2sn	990	6	Retardancy	Retardancy	NNP
cord-276598-tm0yj2sn	990	7	of	of	IN
cord-276598-tm0yj2sn	990	8	Textiles	Textiles	NNPS
cord-276598-tm0yj2sn	990	9	Based	base	VBN
cord-276598-tm0yj2sn	990	10	on	on	IN
cord-276598-tm0yj2sn	990	11	Phosphorus	Phosphorus	NNP
cord-276598-tm0yj2sn	991	1	Chemistry	Chemistry	NNP
cord-276598-tm0yj2sn	991	2	Microwave	Microwave	NNP
cord-276598-tm0yj2sn	991	3	Assisted	Assisted	NNP
cord-276598-tm0yj2sn	991	4	Preparation	Preparation	NNP
cord-276598-tm0yj2sn	991	5	of	of	IN
cord-276598-tm0yj2sn	991	6	Self	Self	NNP
cord-276598-tm0yj2sn	991	7	-	-	HYPH
cord-276598-tm0yj2sn	991	8	Extinguishing	extinguish	VBG
cord-276598-tm0yj2sn	991	9	Cotton	Cotton	NNP
cord-276598-tm0yj2sn	991	10	Fabrics	Fabrics	NNPS
cord-276598-tm0yj2sn	991	11	by	by	IN
cord-276598-tm0yj2sn	991	12	Small	Small	NNP
cord-276598-tm0yj2sn	991	13	Molecules	Molecules	NNPS
cord-276598-tm0yj2sn	991	14	Containing	contain	VBG
cord-276598-tm0yj2sn	991	15	Phosphorous	Phosphorous	NNP
cord-276598-tm0yj2sn	991	16	and	and	CC
cord-276598-tm0yj2sn	991	17	Nitrogen	Nitrogen	NNP
cord-276598-tm0yj2sn	991	18	Molecular	Molecular	NNP
cord-276598-tm0yj2sn	991	19	Firefighting	Firefighting	NNP
cord-276598-tm0yj2sn	992	1	-How	-How	:
cord-276598-tm0yj2sn	992	2	Modern	modern	JJ
cord-276598-tm0yj2sn	992	3	Phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	992	4	Chemistry	Chemistry	NNP
cord-276598-tm0yj2sn	992	5	Can	Can	MD
cord-276598-tm0yj2sn	992	6	Help	help	VB
cord-276598-tm0yj2sn	992	7	Solve	solve	VB
cord-276598-tm0yj2sn	992	8	the	the	DT
cord-276598-tm0yj2sn	992	9	Challenge	Challenge	NNP
cord-276598-tm0yj2sn	992	10	of	of	IN
cord-276598-tm0yj2sn	992	11	Flame	Flame	NNP
cord-276598-tm0yj2sn	992	12	Retardancy	Retardancy	NNP
cord-276598-tm0yj2sn	992	13	El	El	NNP
cord-276598-tm0yj2sn	992	14	-	-	HYPH
cord-276598-tm0yj2sn	992	15	Shafei	Shafei	NNP
cord-276598-tm0yj2sn	992	16	,	,	,
cord-276598-tm0yj2sn	992	17	A.	A.	NNP
cord-276598-tm0yj2sn	992	18	Preparation	Preparation	NNP
cord-276598-tm0yj2sn	992	19	,	,	,
cord-276598-tm0yj2sn	992	20	Polymerization	Polymerization	NNP
cord-276598-tm0yj2sn	992	21	,	,	,
cord-276598-tm0yj2sn	992	22	and	and	CC
cord-276598-tm0yj2sn	992	23	Performance	Performance	NNP
cord-276598-tm0yj2sn	992	24	Evaluation	Evaluation	NNP
cord-276598-tm0yj2sn	992	25	of	of	IN
cord-276598-tm0yj2sn	992	26	Halogen	Halogen	NNP
cord-276598-tm0yj2sn	992	27	-	-	HYPH
cord-276598-tm0yj2sn	992	28	Free	Free	NNP
cord-276598-tm0yj2sn	992	29	Radiation	Radiation	NNP
cord-276598-tm0yj2sn	992	30	Curable	Curable	NNP
cord-276598-tm0yj2sn	992	31	Flame	Flame	NNP
cord-276598-tm0yj2sn	992	32	Retardant	Retardant	NNP
cord-276598-tm0yj2sn	992	33	Monomers	Monomers	NNPS
cord-276598-tm0yj2sn	992	34	for	for	IN
cord-276598-tm0yj2sn	992	35	Cotton	cotton	NN
cord-276598-tm0yj2sn	992	36	Substrates	Substrates	NNPS
cord-276598-tm0yj2sn	992	37	Systematically	systematically	RB
cord-276598-tm0yj2sn	992	38	Controlled	control	VBN
cord-276598-tm0yj2sn	992	39	Decomposition	Decomposition	NNP
cord-276598-tm0yj2sn	992	40	Mechanism	Mechanism	NNP
cord-276598-tm0yj2sn	992	41	in	in	IN
cord-276598-tm0yj2sn	992	42	Phosphorus	Phosphorus	NNP
cord-276598-tm0yj2sn	992	43	Flame	Flame	NNP
cord-276598-tm0yj2sn	992	44	Retardants	Retardants	NNPS
cord-276598-tm0yj2sn	992	45	by	by	IN
cord-276598-tm0yj2sn	992	46	Precise	Precise	NNP
cord-276598-tm0yj2sn	992	47	Molecular	Molecular	NNP
cord-276598-tm0yj2sn	992	48	Architecture	Architecture	NNP
cord-276598-tm0yj2sn	992	49	:	:	:
cord-276598-tm0yj2sn	993	1	P	p	NN
cord-276598-tm0yj2sn	993	2	-	-	HYPH
cord-276598-tm0yj2sn	993	3	O	o	NN
cord-276598-tm0yj2sn	994	1	vs	vs	IN
cord-276598-tm0yj2sn	994	2	P	P	NNP
cord-276598-tm0yj2sn	994	3	-	-	HYPH
cord-276598-tm0yj2sn	994	4	N	N	NNP
cord-276598-tm0yj2sn	994	5	Characterization	characterization	NN
cord-276598-tm0yj2sn	994	6	of	of	IN
cord-276598-tm0yj2sn	994	7	chars	char	NNS
cord-276598-tm0yj2sn	994	8	obtained	obtain	VBN
cord-276598-tm0yj2sn	994	9	from	from	IN
cord-276598-tm0yj2sn	994	10	cellulose	cellulose	NN
cord-276598-tm0yj2sn	994	11	treated	treat	VBN
cord-276598-tm0yj2sn	994	12	with	with	IN
cord-276598-tm0yj2sn	994	13	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	994	14	flame	flame	NN
cord-276598-tm0yj2sn	994	15	retardants	retardant	NNS
cord-276598-tm0yj2sn	994	16	Novel	novel	JJ
cord-276598-tm0yj2sn	994	17	intumescent	intumescent	NN
cord-276598-tm0yj2sn	994	18	flame	flame	NN
cord-276598-tm0yj2sn	994	19	retardants	retardant	NNS
cord-276598-tm0yj2sn	994	20	:	:	:
cord-276598-tm0yj2sn	994	21	Synthesis	synthesis	NN
cord-276598-tm0yj2sn	994	22	and	and	CC
cord-276598-tm0yj2sn	994	23	application	application	NN
cord-276598-tm0yj2sn	994	24	in	in	IN
cord-276598-tm0yj2sn	994	25	polycarbonate	polycarbonate	NNP
cord-276598-tm0yj2sn	994	26	A	a	DT
cord-276598-tm0yj2sn	994	27	Method	Method	NNP
cord-276598-tm0yj2sn	994	28	for	for	IN
cord-276598-tm0yj2sn	994	29	the	the	DT
cord-276598-tm0yj2sn	994	30	Analysis	Analysis	NNP
cord-276598-tm0yj2sn	994	31	of	of	IN
cord-276598-tm0yj2sn	994	32	Low	Low	NNP
cord-276598-tm0yj2sn	994	33	-	-	HYPH
cord-276598-tm0yj2sn	994	34	Mass	Mass	NNP
cord-276598-tm0yj2sn	994	35	Molecules	Molecules	NNPS
cord-276598-tm0yj2sn	994	36	by	by	IN
cord-276598-tm0yj2sn	994	37	MALDI	MALDI	NNP
cord-276598-tm0yj2sn	994	38	-	-	HYPH
cord-276598-tm0yj2sn	994	39	TOF	TOF	NNP
cord-276598-tm0yj2sn	994	40	Mass	Mass	NNP
cord-276598-tm0yj2sn	994	41	Spectrometry	Spectrometry	NNP
cord-276598-tm0yj2sn	994	42	Suppression	Suppression	NNP
cord-276598-tm0yj2sn	994	43	of	of	IN
cord-276598-tm0yj2sn	994	44	matrix	matrix	NN
cord-276598-tm0yj2sn	994	45	ions	ion	NNS
cord-276598-tm0yj2sn	994	46	by	by	IN
cord-276598-tm0yj2sn	994	47	N	n	NN
cord-276598-tm0yj2sn	994	48	-	-	HYPH
cord-276598-tm0yj2sn	994	49	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	994	50	labeling	labeling	NN
cord-276598-tm0yj2sn	994	51	using	use	VBG
cord-276598-tm0yj2sn	994	52	matrix	matrix	NN
cord-276598-tm0yj2sn	994	53	-	-	HYPH
cord-276598-tm0yj2sn	994	54	assisted	assist	VBN
cord-276598-tm0yj2sn	994	55	laser	laser	NN
cord-276598-tm0yj2sn	994	56	desorption	desorption	NN
cord-276598-tm0yj2sn	994	57	-	-	HYPH
cord-276598-tm0yj2sn	994	58	ionization	ionization	NN
cord-276598-tm0yj2sn	994	59	time	time	NN
cord-276598-tm0yj2sn	994	60	-	-	HYPH
cord-276598-tm0yj2sn	994	61	of	of	IN
cord-276598-tm0yj2sn	994	62	-	-	HYPH
cord-276598-tm0yj2sn	994	63	flight	flight	NN
cord-276598-tm0yj2sn	994	64	mass	mass	NN
cord-276598-tm0yj2sn	994	65	spectrometry	spectrometry	NN
cord-276598-tm0yj2sn	994	66	Selective	Selective	NNP
cord-276598-tm0yj2sn	994	67	Liquid	Liquid	NNP
cord-276598-tm0yj2sn	994	68	-	-	HYPH
cord-276598-tm0yj2sn	994	69	Liquid	liquid	NN
cord-276598-tm0yj2sn	994	70	Extraction	extraction	NN
cord-276598-tm0yj2sn	994	71	of	of	IN
cord-276598-tm0yj2sn	994	72	Uranium	Uranium	NNP
cord-276598-tm0yj2sn	994	73	by	by	IN
cord-276598-tm0yj2sn	994	74	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	994	75	-	-	HYPH
cord-276598-tm0yj2sn	994	76	Group	Group	NNP
cord-276598-tm0yj2sn	994	77	Bearing	Bearing	NNP
cord-276598-tm0yj2sn	994	78	Ionic	Ionic	NNP
cord-276598-tm0yj2sn	994	79	Liquid	Liquid	NNP
cord-276598-tm0yj2sn	994	80	Selective	selective	JJ
cord-276598-tm0yj2sn	994	81	Micellar	micellar	JJ
cord-276598-tm0yj2sn	994	82	Extraction	extraction	NN
cord-276598-tm0yj2sn	994	83	of	of	IN
cord-276598-tm0yj2sn	994	84	Ultratrace	Ultratrace	NNP
cord-276598-tm0yj2sn	994	85	Levels	Levels	NNP
cord-276598-tm0yj2sn	994	86	of	of	IN
cord-276598-tm0yj2sn	994	87	Uranium	Uranium	NNP
cord-276598-tm0yj2sn	994	88	in	in	IN
cord-276598-tm0yj2sn	994	89	Aqueous	Aqueous	NNP
cord-276598-tm0yj2sn	994	90	Samples	Samples	NNPS
cord-276598-tm0yj2sn	994	91	by	by	IN
cord-276598-tm0yj2sn	994	92	Task	Task	NNP
cord-276598-tm0yj2sn	994	93	Specific	specific	JJ
cord-276598-tm0yj2sn	994	94	Ionic	Ionic	NNP
cord-276598-tm0yj2sn	994	95	Liquid	Liquid	NNP
cord-276598-tm0yj2sn	994	96	Followed	follow	VBN
cord-276598-tm0yj2sn	994	97	by	by	IN
cord-276598-tm0yj2sn	994	98	Its	-PRON-	PRP$
cord-276598-tm0yj2sn	994	99	Detection	detection	NN
cord-276598-tm0yj2sn	994	100	Employing	employ	VBG
cord-276598-tm0yj2sn	994	101	Total	total	JJ
cord-276598-tm0yj2sn	994	102	Reflection	Reflection	NNP
cord-276598-tm0yj2sn	994	103	X	x	NN
cord-276598-tm0yj2sn	994	104	-	-	NN
cord-276598-tm0yj2sn	994	105	ray	ray	NN
cord-276598-tm0yj2sn	994	106	Fluorescence	fluorescence	NN
cord-276598-tm0yj2sn	994	107	Spectrometry	Spectrometry	NNP
cord-276598-tm0yj2sn	994	108	C(sp3)-H	c(sp3)-h	NN
cord-276598-tm0yj2sn	994	109	Bond	Bond	NNP
cord-276598-tm0yj2sn	994	110	Activation	activation	NN
cord-276598-tm0yj2sn	994	111	Induced	induce	VBN
cord-276598-tm0yj2sn	994	112	by	by	IN
cord-276598-tm0yj2sn	994	113	Monohydroborane	Monohydroborane	NNP
cord-276598-tm0yj2sn	994	114	Coordination	Coordination	NNP
cord-276598-tm0yj2sn	994	115	at	at	IN
cord-276598-tm0yj2sn	994	116	an	an	DT
cord-276598-tm0yj2sn	994	117	Iridium(III)-Phosphoramidate	iridium(iii)-phosphoramidate	NN
cord-276598-tm0yj2sn	994	118	Complex	Complex	NNP
cord-276598-tm0yj2sn	994	119	Toward	toward	IN
cord-276598-tm0yj2sn	994	120	anti	anti	JJ
cord-276598-tm0yj2sn	994	121	-	-	JJ
cord-276598-tm0yj2sn	994	122	Markovnikov	markovnikov	JJ
cord-276598-tm0yj2sn	994	123	1-Alkyne	1-Alkyne	NNP
cord-276598-tm0yj2sn	994	124	O	O	NNP
cord-276598-tm0yj2sn	994	125	-	-	HYPH
cord-276598-tm0yj2sn	994	126	Phosphoramidation	phosphoramidation	NN
cord-276598-tm0yj2sn	994	127	:	:	:
cord-276598-tm0yj2sn	995	1	Exploiting	exploit	VBG
cord-276598-tm0yj2sn	995	2	Metal	Metal	NNP
cord-276598-tm0yj2sn	995	3	-	-	HYPH
cord-276598-tm0yj2sn	995	4	Ligand	Ligand	NNP
cord-276598-tm0yj2sn	995	5	Cooperativity	Cooperativity	NNP
cord-276598-tm0yj2sn	995	6	in	in	IN
cord-276598-tm0yj2sn	995	7	a	a	DT
cord-276598-tm0yj2sn	995	8	1,3-N	1,3-n	CD
cord-276598-tm0yj2sn	995	9	,	,	,
cord-276598-tm0yj2sn	995	10	O	o	UH
cord-276598-tm0yj2sn	995	11	-	-	HYPH
cord-276598-tm0yj2sn	995	12	Chelated	chelated	JJ
cord-276598-tm0yj2sn	995	13	Cp*Ir(III	Cp*Ir(III	NNS
cord-276598-tm0yj2sn	995	14	)	)	-RRB-
cord-276598-tm0yj2sn	996	1	Complex	complex	JJ
cord-276598-tm0yj2sn	996	2	1,3-N	1,3-n	CD
cord-276598-tm0yj2sn	996	3	,	,	,
cord-276598-tm0yj2sn	996	4	O	O	NNP
cord-276598-tm0yj2sn	996	5	-	-	HYPH
cord-276598-tm0yj2sn	996	6	Complexes	Complexes	NNPS
cord-276598-tm0yj2sn	996	7	of	of	IN
cord-276598-tm0yj2sn	996	8	late	late	JJ
cord-276598-tm0yj2sn	996	9	transition	transition	NN
cord-276598-tm0yj2sn	996	10	metals	metal	NNS
cord-276598-tm0yj2sn	996	11	.	.	.
cord-276598-tm0yj2sn	997	1	Ligands	ligand	NNS
cord-276598-tm0yj2sn	997	2	with	with	IN
cord-276598-tm0yj2sn	997	3	flexible	flexible	JJ
cord-276598-tm0yj2sn	997	4	bonding	bonding	NN
cord-276598-tm0yj2sn	997	5	modes	mode	NNS
cord-276598-tm0yj2sn	997	6	and	and	CC
cord-276598-tm0yj2sn	997	7	reaction	reaction	NN
cord-276598-tm0yj2sn	997	8	profiles	profile	NNS
cord-276598-tm0yj2sn	997	9	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	997	10	tantalum	tantalum	NN
cord-276598-tm0yj2sn	997	11	complexes	complex	NNS
cord-276598-tm0yj2sn	997	12	for	for	IN
cord-276598-tm0yj2sn	997	13	room	room	NN
cord-276598-tm0yj2sn	997	14	-	-	HYPH
cord-276598-tm0yj2sn	997	15	temperature	temperature	NN
cord-276598-tm0yj2sn	997	16	C	c	NN
cord-276598-tm0yj2sn	997	17	-	-	HYPH
cord-276598-tm0yj2sn	997	18	H	h	NN
cord-276598-tm0yj2sn	997	19	functionalization	functionalization	NN
cord-276598-tm0yj2sn	997	20	:	:	:
cord-276598-tm0yj2sn	998	1	Hydroaminoalkylation	Hydroaminoalkylation	NNP
cord-276598-tm0yj2sn	998	2	catalysis	catalysis	NN
cord-276598-tm0yj2sn	998	3	Copper	Copper	NNP
cord-276598-tm0yj2sn	998	4	-	-	HYPH
cord-276598-tm0yj2sn	998	5	Catalyzed	Catalyzed	NNP
cord-276598-tm0yj2sn	998	6	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	998	7	of	of	IN
cord-276598-tm0yj2sn	998	8	Medium	Medium	NNP
cord-276598-tm0yj2sn	998	9	-	-	:
cord-276598-tm0yj2sn	998	10	and	and	CC
cord-276598-tm0yj2sn	998	11	Large	large	JJ
cord-276598-tm0yj2sn	998	12	-	-	HYPH
cord-276598-tm0yj2sn	998	13	Sized	Sized	NNP
cord-276598-tm0yj2sn	998	14	Nitrogen	Nitrogen	NNP
cord-276598-tm0yj2sn	998	15	Heterocycles	Heterocycles	NNP
cord-276598-tm0yj2sn	998	16	via	via	IN
cord-276598-tm0yj2sn	998	17	N	n	CD
cord-276598-tm0yj2sn	998	18	-	-	HYPH
cord-276598-tm0yj2sn	998	19	Arylation	Arylation	NNP
cord-276598-tm0yj2sn	998	20	of	of	IN
cord-276598-tm0yj2sn	998	21	Phosphoramidates	Phosphoramidates	NNPS
cord-276598-tm0yj2sn	998	22	and	and	CC
cord-276598-tm0yj2sn	998	23	Carbamates	Carbamates	NNP
cord-276598-tm0yj2sn	998	24	Palladium	Palladium	NNP
cord-276598-tm0yj2sn	998	25	-	-	HYPH
cord-276598-tm0yj2sn	998	26	Catalyzed	Catalyzed	NNP
cord-276598-tm0yj2sn	998	27	C	C	NNP
cord-276598-tm0yj2sn	998	28	-	-	HYPH
cord-276598-tm0yj2sn	998	29	H	H	NNP
cord-276598-tm0yj2sn	998	30	Arylation	Arylation	NNP
cord-276598-tm0yj2sn	998	31	Using	use	VBG
cord-276598-tm0yj2sn	998	32	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	998	33	as	as	IN
cord-276598-tm0yj2sn	998	34	a	a	DT
cord-276598-tm0yj2sn	998	35	Directing	Directing	NNP
cord-276598-tm0yj2sn	998	36	Group	Group	NNP
cord-276598-tm0yj2sn	998	37	at	at	IN
cord-276598-tm0yj2sn	998	38	Room	room	NN
cord-276598-tm0yj2sn	998	39	Temperature	Temperature	NNP
cord-276598-tm0yj2sn	999	1	2-(Benzo[d]thiazol-2-yl	2-(benzo[d]thiazol-2-yl	LS
cord-276598-tm0yj2sn	999	2	)	)	-RRB-
cord-276598-tm0yj2sn	1000	1	phenyl-4-nitrophenyl	phenyl-4-nitrophenyl	NNP
cord-276598-tm0yj2sn	1000	2	alkyl	alkyl	NNP
cord-276598-tm0yj2sn	1000	3	/	/	SYM
cord-276598-tm0yj2sn	1000	4	aryl	aryl	NN
cord-276598-tm0yj2sn	1000	5	substituted	substitute	VBN
cord-276598-tm0yj2sn	1000	6	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	1000	7	:	:	:
cord-276598-tm0yj2sn	1001	1	Synthesis	synthesis	NN
cord-276598-tm0yj2sn	1001	2	,	,	,
cord-276598-tm0yj2sn	1001	3	characterization	characterization	NN
cord-276598-tm0yj2sn	1001	4	and	and	CC
cord-276598-tm0yj2sn	1001	5	antimicrobial	antimicrobial	JJ
cord-276598-tm0yj2sn	1001	6	activity	activity	NN
cord-276598-tm0yj2sn	1001	7	evaluation	evaluation	NN
cord-276598-tm0yj2sn	1001	8	Synthesis	synthesis	NN
cord-276598-tm0yj2sn	1001	9	and	and	CC
cord-276598-tm0yj2sn	1001	10	biological	biological	JJ
cord-276598-tm0yj2sn	1001	11	evaluation	evaluation	NN
cord-276598-tm0yj2sn	1001	12	of	of	IN
cord-276598-tm0yj2sn	1001	13	novel	novel	JJ
cord-276598-tm0yj2sn	1001	14	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	1001	15	derivatives	derivative	NNS
cord-276598-tm0yj2sn	1001	16	of	of	IN
cord-276598-tm0yj2sn	1001	17	coumarin	coumarin	NN
cord-276598-tm0yj2sn	1001	18	as	as	IN
cord-276598-tm0yj2sn	1001	19	chitin	chitin	NN
cord-276598-tm0yj2sn	1001	20	synthase	synthase	NN
cord-276598-tm0yj2sn	1001	21	inhibitors	inhibitor	NNS
cord-276598-tm0yj2sn	1001	22	and	and	CC
cord-276598-tm0yj2sn	1001	23	antifungal	antifungal	JJ
cord-276598-tm0yj2sn	1001	24	agents	agent	NNS
cord-276598-tm0yj2sn	1002	1	Convenient	convenient	JJ
cord-276598-tm0yj2sn	1002	2	one	one	CD
cord-276598-tm0yj2sn	1002	3	-	-	HYPH
cord-276598-tm0yj2sn	1002	4	pot	pot	NN
cord-276598-tm0yj2sn	1002	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1002	6	and	and	CC
cord-276598-tm0yj2sn	1002	7	biological	biological	JJ
cord-276598-tm0yj2sn	1002	8	evaluation	evaluation	NN
cord-276598-tm0yj2sn	1002	9	of	of	IN
cord-276598-tm0yj2sn	1002	10	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	1002	11	and	and	CC
cord-276598-tm0yj2sn	1002	12	phosphonates	phosphonates	NNP
cord-276598-tm0yj2sn	1002	13	containing	contain	VBG
cord-276598-tm0yj2sn	1002	14	heterocycles	heterocycles	NNP
cord-276598-tm0yj2sn	1002	15	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1002	16	,	,	,
cord-276598-tm0yj2sn	1002	17	spectral	spectral	JJ
cord-276598-tm0yj2sn	1002	18	characterization	characterization	NN
cord-276598-tm0yj2sn	1002	19	,	,	,
cord-276598-tm0yj2sn	1002	20	and	and	CC
cord-276598-tm0yj2sn	1002	21	proand	proand	NN
cord-276598-tm0yj2sn	1002	22	antioxidant	antioxidant	JJ
cord-276598-tm0yj2sn	1002	23	activity	activity	NN
cord-276598-tm0yj2sn	1002	24	of	of	IN
cord-276598-tm0yj2sn	1002	25	phosphorylated	phosphorylated	JJ
cord-276598-tm0yj2sn	1002	26	derivatives	derivative	NNS
cord-276598-tm0yj2sn	1002	27	of	of	IN
cord-276598-tm0yj2sn	1002	28	cis	cis	NNP
cord-276598-tm0yj2sn	1002	29	-	-	HYPH
cord-276598-tm0yj2sn	1002	30	tramadol	tramadol	NNP
cord-276598-tm0yj2sn	1002	31	.	.	.
cord-276598-tm0yj2sn	1003	1	Phosphorus	Phosphorus	NNP
cord-276598-tm0yj2sn	1003	2	Sulfur	Sulfur	NNP
cord-276598-tm0yj2sn	1003	3	Silicon	Silicon	NNP
cord-276598-tm0yj2sn	1004	1	Relat	Relat	NNP
cord-276598-tm0yj2sn	1004	2	Anti	Anti	NNP
cord-276598-tm0yj2sn	1004	3	-	-	JJ
cord-276598-tm0yj2sn	1004	4	cancer	cancer	NN
cord-276598-tm0yj2sn	1005	1	ProTides	ProTides	NNPS
cord-276598-tm0yj2sn	1005	2	:	:	:
cord-276598-tm0yj2sn	1006	1	Tuning	tune	VBG
cord-276598-tm0yj2sn	1006	2	the	the	DT
cord-276598-tm0yj2sn	1006	3	activity	activity	NN
cord-276598-tm0yj2sn	1006	4	of	of	IN
cord-276598-tm0yj2sn	1006	5	BVDU	BVDU	NNP
cord-276598-tm0yj2sn	1006	6	phosphoramidates	phosphoramidates	NN
cord-276598-tm0yj2sn	1006	7	related	relate	VBN
cord-276598-tm0yj2sn	1006	8	to	to	IN
cord-276598-tm0yj2sn	1006	9	thymectacin	thymectacin	NNP
cord-276598-tm0yj2sn	1006	10	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1006	11	and	and	CC
cord-276598-tm0yj2sn	1006	12	evaluation	evaluation	NN
cord-276598-tm0yj2sn	1006	13	of	of	IN
cord-276598-tm0yj2sn	1006	14	phosphoramidate	phosphoramidate	NNP
cord-276598-tm0yj2sn	1006	15	and	and	CC
cord-276598-tm0yj2sn	1006	16	phosphorothioamidate	phosphorothioamidate	NNP
cord-276598-tm0yj2sn	1006	17	analogues	analogue	NNS
cord-276598-tm0yj2sn	1006	18	of	of	IN
cord-276598-tm0yj2sn	1006	19	amiprophos	amiprophos	NN
cord-276598-tm0yj2sn	1006	20	methyl	methyl	NN
cord-276598-tm0yj2sn	1006	21	as	as	IN
cord-276598-tm0yj2sn	1006	22	potential	potential	JJ
cord-276598-tm0yj2sn	1006	23	antimalarial	antimalarial	JJ
cord-276598-tm0yj2sn	1006	24	agents	agent	NNS
cord-276598-tm0yj2sn	1006	25	Phosphoramidates	Phosphoramidates	NNPS
cord-276598-tm0yj2sn	1006	26	and	and	CC
cord-276598-tm0yj2sn	1006	27	phosphonamidates	phosphonamidates	NNP
cord-276598-tm0yj2sn	1006	28	(	(	-LRB-
cord-276598-tm0yj2sn	1006	29	ProTides	ProTides	NNP
cord-276598-tm0yj2sn	1006	30	)	)	-RRB-
cord-276598-tm0yj2sn	1006	31	with	with	IN
cord-276598-tm0yj2sn	1006	32	antiviral	antiviral	JJ
cord-276598-tm0yj2sn	1006	33	activity	activity	NN
cord-276598-tm0yj2sn	1006	34	Anchimerically	Anchimerically	NNP
cord-276598-tm0yj2sn	1007	1	Activatable	Activatable	NNP
cord-276598-tm0yj2sn	1007	2	Antiviral	Antiviral	NNP
cord-276598-tm0yj2sn	1008	1	ProTides	ProTides	NNPS
cord-276598-tm0yj2sn	1008	2	New	New	NNP
cord-276598-tm0yj2sn	1008	3	and	and	CC
cord-276598-tm0yj2sn	1008	4	Efficient	efficient	JJ
cord-276598-tm0yj2sn	1008	5	Approach	Approach	NNP
cord-276598-tm0yj2sn	1008	6	to	to	IN
cord-276598-tm0yj2sn	1008	7	Aryl	Aryl	NNP
cord-276598-tm0yj2sn	1008	8	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1008	9	Derivatives	Derivatives	NNPS
cord-276598-tm0yj2sn	1008	10	of	of	IN
cord-276598-tm0yj2sn	1008	11	AZT	AZT	NNP
cord-276598-tm0yj2sn	1008	12	/	/	SYM
cord-276598-tm0yj2sn	1008	13	d4	d4	NNP
cord-276598-tm0yj2sn	1008	14	T	T	NNP
cord-276598-tm0yj2sn	1008	15	as	as	IN
cord-276598-tm0yj2sn	1008	16	Anti	Anti	NNP
cord-276598-tm0yj2sn	1008	17	-	-	JJ
cord-276598-tm0yj2sn	1008	18	HIV	HIV	NNP
cord-276598-tm0yj2sn	1009	1	Prodrugs	Prodrugs	NNP
cord-276598-tm0yj2sn	1009	2	Aryloxy	Aryloxy	NNP
cord-276598-tm0yj2sn	1009	3	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1009	4	Triesters	Triesters	NNPS
cord-276598-tm0yj2sn	1009	5	:	:	:
cord-276598-tm0yj2sn	1009	6	A	a	DT
cord-276598-tm0yj2sn	1009	7	Technology	technology	NN
cord-276598-tm0yj2sn	1009	8	for	for	IN
cord-276598-tm0yj2sn	1009	9	Delivering	deliver	VBG
cord-276598-tm0yj2sn	1009	10	Monophosphorylated	Monophosphorylated	NNP
cord-276598-tm0yj2sn	1009	11	Nucleosides	Nucleosides	NNP
cord-276598-tm0yj2sn	1009	12	and	and	CC
cord-276598-tm0yj2sn	1009	13	Sugars	sugar	NNS
cord-276598-tm0yj2sn	1009	14	into	into	IN
cord-276598-tm0yj2sn	1009	15	Cells	cell	NNS
cord-276598-tm0yj2sn	1010	1	The	the	DT
cord-276598-tm0yj2sn	1010	2	ProTide	ProTide	NNP
cord-276598-tm0yj2sn	1010	3	Prodrug	Prodrug	NNP
cord-276598-tm0yj2sn	1010	4	Technology	Technology	NNP
cord-276598-tm0yj2sn	1010	5	:	:	:
cord-276598-tm0yj2sn	1010	6	From	from	IN
cord-276598-tm0yj2sn	1010	7	the	the	DT
cord-276598-tm0yj2sn	1010	8	Concept	Concept	NNP
cord-276598-tm0yj2sn	1010	9	to	to	IN
cord-276598-tm0yj2sn	1010	10	the	the	DT
cord-276598-tm0yj2sn	1010	11	Clinic	Clinic	NNP
cord-276598-tm0yj2sn	1010	12	Current	current	JJ
cord-276598-tm0yj2sn	1010	13	knowledge	knowledge	NN
cord-276598-tm0yj2sn	1010	14	about	about	IN
cord-276598-tm0yj2sn	1010	15	the	the	DT
cord-276598-tm0yj2sn	1010	16	antivirals	antiviral	NNS
cord-276598-tm0yj2sn	1010	17	remdesivir	remdesivir	NNP
cord-276598-tm0yj2sn	1010	18	(	(	-LRB-
cord-276598-tm0yj2sn	1010	19	GS-5734	GS-5734	NNP
cord-276598-tm0yj2sn	1010	20	)	)	-RRB-
cord-276598-tm0yj2sn	1011	1	and	and	CC
cord-276598-tm0yj2sn	1011	2	GS-441524	GS-441524	NNP
cord-276598-tm0yj2sn	1011	3	as	as	IN
cord-276598-tm0yj2sn	1011	4	therapeutic	therapeutic	JJ
cord-276598-tm0yj2sn	1011	5	options	option	NNS
cord-276598-tm0yj2sn	1011	6	for	for	IN
cord-276598-tm0yj2sn	1011	7	coronaviruses	coronaviruse	NNS
cord-276598-tm0yj2sn	1011	8	.	.	.
cord-276598-tm0yj2sn	1012	1	One	one	CD
cord-276598-tm0yj2sn	1012	2	Health	Health	NNP
cord-276598-tm0yj2sn	1012	3	Polyphosphoramidate	Polyphosphoramidate	NNP
cord-276598-tm0yj2sn	1012	4	gene	gene	NN
cord-276598-tm0yj2sn	1012	5	carriers	carrier	NNS
cord-276598-tm0yj2sn	1012	6	:	:	:
cord-276598-tm0yj2sn	1012	7	Effect	effect	NN
cord-276598-tm0yj2sn	1012	8	of	of	IN
cord-276598-tm0yj2sn	1012	9	charge	charge	NN
cord-276598-tm0yj2sn	1012	10	group	group	NN
cord-276598-tm0yj2sn	1012	11	on	on	IN
cord-276598-tm0yj2sn	1012	12	gene	gene	NN
cord-276598-tm0yj2sn	1012	13	transfer	transfer	NN
cord-276598-tm0yj2sn	1012	14	efficiency	efficiency	NN
cord-276598-tm0yj2sn	1012	15	Ternary	Ternary	NNP
cord-276598-tm0yj2sn	1012	16	Complexes	Complexes	NNPS
cord-276598-tm0yj2sn	1013	1	Comprising	comprise	VBG
cord-276598-tm0yj2sn	1013	2	Polyphosphoramidate	Polyphosphoramidate	NNP
cord-276598-tm0yj2sn	1013	3	Gene	Gene	NNP
cord-276598-tm0yj2sn	1013	4	Carriers	Carriers	NNP
cord-276598-tm0yj2sn	1013	5	with	with	IN
cord-276598-tm0yj2sn	1013	6	Different	different	JJ
cord-276598-tm0yj2sn	1013	7	Types	type	NNS
cord-276598-tm0yj2sn	1013	8	of	of	IN
cord-276598-tm0yj2sn	1013	9	Charge	Charge	NNP
cord-276598-tm0yj2sn	1013	10	Groups	Groups	NNPS
cord-276598-tm0yj2sn	1014	1	Improve	improve	VB
cord-276598-tm0yj2sn	1014	2	Transfection	Transfection	NNP
cord-276598-tm0yj2sn	1014	3	Efficiency	Efficiency	NNP
cord-276598-tm0yj2sn	1014	4	Discovery	Discovery	NNP
cord-276598-tm0yj2sn	1014	5	and	and	CC
cord-276598-tm0yj2sn	1014	6	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1014	7	of	of	IN
cord-276598-tm0yj2sn	1014	8	a	a	DT
cord-276598-tm0yj2sn	1014	9	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1014	10	Prodrug	Prodrug	NNP
cord-276598-tm0yj2sn	1014	11	of	of	IN
cord-276598-tm0yj2sn	1014	12	a	a	DT
cord-276598-tm0yj2sn	1014	13	Pyrrolo	Pyrrolo	NNP
cord-276598-tm0yj2sn	1014	14	GS-5734	GS-5734	NNS
cord-276598-tm0yj2sn	1014	15	)	)	-RRB-
cord-276598-tm0yj2sn	1015	1	for	for	IN
cord-276598-tm0yj2sn	1015	2	the	the	DT
cord-276598-tm0yj2sn	1015	3	Treatment	Treatment	NNP
cord-276598-tm0yj2sn	1015	4	of	of	IN
cord-276598-tm0yj2sn	1015	5	Ebola	Ebola	NNP
cord-276598-tm0yj2sn	1015	6	and	and	CC
cord-276598-tm0yj2sn	1015	7	Emerging	Emerging	NNP
cord-276598-tm0yj2sn	1015	8	Viruses	Viruses	NNPS
cord-276598-tm0yj2sn	1015	9	Structure	structure	NN
cord-276598-tm0yj2sn	1015	10	-	-	HYPH
cord-276598-tm0yj2sn	1015	11	reactivity	reactivity	NN
cord-276598-tm0yj2sn	1015	12	correlation	correlation	NN
cord-276598-tm0yj2sn	1015	13	for	for	IN
cord-276598-tm0yj2sn	1015	14	the	the	DT
cord-276598-tm0yj2sn	1015	15	hydrolysis	hydrolysis	NN
cord-276598-tm0yj2sn	1015	16	of	of	IN
cord-276598-tm0yj2sn	1015	17	phosphoramidate	phosphoramidate	NN
cord-276598-tm0yj2sn	1015	18	monoanions	monoanion	NNS
cord-276598-tm0yj2sn	1015	19	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1015	20	solvolysis	solvolysis	NN
cord-276598-tm0yj2sn	1015	21	Tunable	Tunable	NNP
cord-276598-tm0yj2sn	1015	22	pH	pH	NNP
cord-276598-tm0yj2sn	1015	23	-	-	HYPH
cord-276598-tm0yj2sn	1015	24	Sensitive	sensitive	JJ
cord-276598-tm0yj2sn	1015	25	Linker	Linker	NNP
cord-276598-tm0yj2sn	1015	26	for	for	IN
cord-276598-tm0yj2sn	1015	27	Controlled	Controlled	NNP
cord-276598-tm0yj2sn	1015	28	Release	Release	NNP
cord-276598-tm0yj2sn	1015	29	Second	Second	NNP
cord-276598-tm0yj2sn	1015	30	-	-	HYPH
cord-276598-tm0yj2sn	1015	31	Generation	generation	NN
cord-276598-tm0yj2sn	1015	32	Tunable	Tunable	NNP
cord-276598-tm0yj2sn	1015	33	pH	ph	NN
cord-276598-tm0yj2sn	1015	34	-	-	HYPH
cord-276598-tm0yj2sn	1015	35	Sensitive	Sensitive	NNP
cord-276598-tm0yj2sn	1015	36	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1015	37	-	-	HYPH
cord-276598-tm0yj2sn	1015	38	Based	Based	NNP
cord-276598-tm0yj2sn	1015	39	Linkers	Linkers	NNP
cord-276598-tm0yj2sn	1015	40	for	for	IN
cord-276598-tm0yj2sn	1015	41	Controlled	Controlled	NNP
cord-276598-tm0yj2sn	1015	42	Release	Release	NNP
cord-276598-tm0yj2sn	1015	43	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1015	44	derivates	derivate	NNS
cord-276598-tm0yj2sn	1015	45	as	as	IN
cord-276598-tm0yj2sn	1015	46	controlled	control	VBN
cord-276598-tm0yj2sn	1015	47	-	-	HYPH
cord-276598-tm0yj2sn	1015	48	release	release	NN
cord-276598-tm0yj2sn	1015	49	prodrugs	prodrug	NNS
cord-276598-tm0yj2sn	1015	50	of	of	IN
cord-276598-tm0yj2sn	1015	51	l	l	NN
cord-276598-tm0yj2sn	1015	52	-	-	HYPH
cord-276598-tm0yj2sn	1015	53	Dopa	Dopa	NNP
cord-276598-tm0yj2sn	1015	54	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1015	55	derivatives	derivative	NNS
cord-276598-tm0yj2sn	1015	56	of	of	IN
cord-276598-tm0yj2sn	1015	57	acyclovir	acyclovir	NN
cord-276598-tm0yj2sn	1015	58	:	:	:
cord-276598-tm0yj2sn	1015	59	Synthesis	synthesis	NN
cord-276598-tm0yj2sn	1015	60	and	and	CC
cord-276598-tm0yj2sn	1015	61	antiviral	antiviral	JJ
cord-276598-tm0yj2sn	1015	62	activity	activity	NN
cord-276598-tm0yj2sn	1015	63	in	in	IN
cord-276598-tm0yj2sn	1015	64	HIV-1	HIV-1	NNP
cord-276598-tm0yj2sn	1015	65	and	and	CC
cord-276598-tm0yj2sn	1015	66	HSV-1	HSV-1	NNP
cord-276598-tm0yj2sn	1015	67	models	model	NNS
cord-276598-tm0yj2sn	1015	68	in	in	IN
cord-276598-tm0yj2sn	1015	69	vitro	vitro	FW
cord-276598-tm0yj2sn	1015	70	The	the	DT
cord-276598-tm0yj2sn	1015	71	nature	nature	NN
cord-276598-tm0yj2sn	1015	72	of	of	IN
cord-276598-tm0yj2sn	1015	73	the	the	DT
cord-276598-tm0yj2sn	1015	74	"	"	``
cord-276598-tm0yj2sn	1015	75	inorganic	inorganic	JJ
cord-276598-tm0yj2sn	1015	76	phosphate	phosphate	NN
cord-276598-tm0yj2sn	1015	77	"	"	''
cord-276598-tm0yj2sn	1015	78	in	in	IN
cord-276598-tm0yj2sn	1015	79	voluntary	voluntary	JJ
cord-276598-tm0yj2sn	1015	80	muscle	muscle	NN
cord-276598-tm0yj2sn	1015	81	Phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	1015	82	compounds	compound	NNS
cord-276598-tm0yj2sn	1015	83	of	of	IN
cord-276598-tm0yj2sn	1015	84	muscle	muscle	NN
cord-276598-tm0yj2sn	1015	85	and	and	CC
cord-276598-tm0yj2sn	1015	86	liver	liver	NN
cord-276598-tm0yj2sn	1016	1	The	the	DT
cord-276598-tm0yj2sn	1016	2	Aquo	Aquo	NNP
cord-276598-tm0yj2sn	1016	3	Ammono	Ammono	NNP
cord-276598-tm0yj2sn	1016	4	Phosphoric	Phosphoric	NNP
cord-276598-tm0yj2sn	1016	5	Acids	Acids	NNPS
cord-276598-tm0yj2sn	1016	6	.	.	.
cord-276598-tm0yj2sn	1017	1	I.	I.	NNP
cord-276598-tm0yj2sn	1017	2	Preparation	preparation	NN
cord-276598-tm0yj2sn	1017	3	of	of	IN
cord-276598-tm0yj2sn	1017	4	Phenyl	Phenyl	NNP
cord-276598-tm0yj2sn	1017	5	Esters	Esters	NNPS
cord-276598-tm0yj2sn	1017	6	of	of	IN
cord-276598-tm0yj2sn	1017	7	Amidoand	Amidoand	NNP
cord-276598-tm0yj2sn	1017	8	Diamidophosphoric	Diamidophosphoric	NNP
cord-276598-tm0yj2sn	1017	9	Acids	Acids	NNPS
cord-276598-tm0yj2sn	1018	1	The	the	DT
cord-276598-tm0yj2sn	1018	2	Aquo	Aquo	NNP
cord-276598-tm0yj2sn	1018	3	Ammono	Ammono	NNP
cord-276598-tm0yj2sn	1018	4	Phosphoric	Phosphoric	NNP
cord-276598-tm0yj2sn	1018	5	Acids	Acids	NNPS
cord-276598-tm0yj2sn	1018	6	.	.	.
cord-276598-tm0yj2sn	1019	1	II	II	NNP
cord-276598-tm0yj2sn	1019	2	.	.	.
cord-276598-tm0yj2sn	1020	1	Preparation	preparation	NN
cord-276598-tm0yj2sn	1020	2	of	of	IN
cord-276598-tm0yj2sn	1020	3	N	N	NNP
cord-276598-tm0yj2sn	1020	4	-	-	HYPH
cord-276598-tm0yj2sn	1020	5	Substituted	Substituted	NNP
cord-276598-tm0yj2sn	1020	6	Derivatives	Derivatives	NNPS
cord-276598-tm0yj2sn	1020	7	of	of	IN
cord-276598-tm0yj2sn	1020	8	the	the	DT
cord-276598-tm0yj2sn	1020	9	Phenyl	Phenyl	NNP
cord-276598-tm0yj2sn	1020	10	Esters	Esters	NNPS
cord-276598-tm0yj2sn	1020	11	of	of	IN
cord-276598-tm0yj2sn	1020	12	Amido	Amido	NNP
cord-276598-tm0yj2sn	1020	13	-	-	:
cord-276598-tm0yj2sn	1020	14	and	and	CC
cord-276598-tm0yj2sn	1020	15	Diamidophosphoric	Diamidophosphoric	NNP
cord-276598-tm0yj2sn	1020	16	Acids	Acids	NNPS
cord-276598-tm0yj2sn	1020	17	174	174	CD
cord-276598-tm0yj2sn	1020	18	.	.	.
cord-276598-tm0yj2sn	1021	1	Studies	study	NNS
cord-276598-tm0yj2sn	1021	2	on	on	IN
cord-276598-tm0yj2sn	1021	3	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	1021	4	.	.	.
cord-276598-tm0yj2sn	1022	1	Part	Part	NNP
cord-276598-tm0yj2sn	1022	2	II	II	NNP
cord-276598-tm0yj2sn	1022	3	.	.	.
cord-276598-tm0yj2sn	1023	1	The	the	DT
cord-276598-tm0yj2sn	1023	2	reaction	reaction	NN
cord-276598-tm0yj2sn	1023	3	of	of	IN
cord-276598-tm0yj2sn	1023	4	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	1023	5	phosphites	phosphites	NNP
cord-276598-tm0yj2sn	1023	6	with	with	IN
cord-276598-tm0yj2sn	1023	7	polyhalogen	polyhalogen	NNP
cord-276598-tm0yj2sn	1023	8	compounds	compound	NNS
cord-276598-tm0yj2sn	1023	9	in	in	IN
cord-276598-tm0yj2sn	1023	10	presence	presence	NN
cord-276598-tm0yj2sn	1023	11	of	of	IN
cord-276598-tm0yj2sn	1023	12	bases	basis	NNS
cord-276598-tm0yj2sn	1023	13	.	.	.
cord-276598-tm0yj2sn	1024	1	A	a	DT
cord-276598-tm0yj2sn	1024	2	new	new	JJ
cord-276598-tm0yj2sn	1024	3	method	method	NN
cord-276598-tm0yj2sn	1024	4	for	for	IN
cord-276598-tm0yj2sn	1024	5	the	the	DT
cord-276598-tm0yj2sn	1024	6	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	1024	7	of	of	IN
cord-276598-tm0yj2sn	1024	8	amines	amine	NNS
cord-276598-tm0yj2sn	1024	9	129	129	CD
cord-276598-tm0yj2sn	1024	10	.	.	.
cord-276598-tm0yj2sn	1025	1	Studies	study	NNS
cord-276598-tm0yj2sn	1025	2	on	on	IN
cord-276598-tm0yj2sn	1025	3	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	1025	4	.	.	.
cord-276598-tm0yj2sn	1026	1	Part	part	NN
cord-276598-tm0yj2sn	1026	2	III	III	NNP
cord-276598-tm0yj2sn	1026	3	.	.	.
cord-276598-tm0yj2sn	1027	1	Further	further	JJ
cord-276598-tm0yj2sn	1027	2	observations	observation	NNS
cord-276598-tm0yj2sn	1027	3	on	on	IN
cord-276598-tm0yj2sn	1027	4	the	the	DT
cord-276598-tm0yj2sn	1027	5	reaction	reaction	NN
cord-276598-tm0yj2sn	1027	6	of	of	IN
cord-276598-tm0yj2sn	1027	7	phosphites	phosphites	NNP
cord-276598-tm0yj2sn	1027	8	with	with	IN
cord-276598-tm0yj2sn	1027	9	polyhalogen	polyhalogen	NNP
cord-276598-tm0yj2sn	1027	10	compounds	compound	NNS
cord-276598-tm0yj2sn	1027	11	in	in	IN
cord-276598-tm0yj2sn	1027	12	presence	presence	NN
cord-276598-tm0yj2sn	1027	13	of	of	IN
cord-276598-tm0yj2sn	1027	14	bases	basis	NNS
cord-276598-tm0yj2sn	1027	15	and	and	CC
cord-276598-tm0yj2sn	1027	16	its	-PRON-	PRP$
cord-276598-tm0yj2sn	1027	17	application	application	NN
cord-276598-tm0yj2sn	1027	18	to	to	IN
cord-276598-tm0yj2sn	1027	19	the	the	DT
cord-276598-tm0yj2sn	1027	20	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	1027	21	of	of	IN
cord-276598-tm0yj2sn	1027	22	alcohols	alcohol	NNS
cord-276598-tm0yj2sn	1027	23	220	220	CD
cord-276598-tm0yj2sn	1027	24	.	.	.
cord-276598-tm0yj2sn	1028	1	Studies	study	NNS
cord-276598-tm0yj2sn	1028	2	on	on	IN
cord-276598-tm0yj2sn	1028	3	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	1028	4	.	.	.
cord-276598-tm0yj2sn	1029	1	Part	Part	NNP
cord-276598-tm0yj2sn	1029	2	IV	IV	NNP
cord-276598-tm0yj2sn	1029	3	.	.	.
cord-276598-tm0yj2sn	1030	1	Further	further	JJ
cord-276598-tm0yj2sn	1030	2	studies	study	NNS
cord-276598-tm0yj2sn	1030	3	on	on	IN
cord-276598-tm0yj2sn	1030	4	the	the	DT
cord-276598-tm0yj2sn	1030	5	use	use	NN
cord-276598-tm0yj2sn	1030	6	of	of	IN
cord-276598-tm0yj2sn	1030	7	dibenzyl	dibenzyl	NNP
cord-276598-tm0yj2sn	1030	8	chlorophosphonate	chlorophosphonate	NNP
cord-276598-tm0yj2sn	1030	9	and	and	CC
cord-276598-tm0yj2sn	1030	10	the	the	DT
cord-276598-tm0yj2sn	1030	11	examination	examination	NN
cord-276598-tm0yj2sn	1030	12	of	of	IN
cord-276598-tm0yj2sn	1030	13	certain	certain	JJ
cord-276598-tm0yj2sn	1030	14	alternative	alternative	JJ
cord-276598-tm0yj2sn	1030	15	phosphorylation	phosphorylation	NN
cord-276598-tm0yj2sn	1030	16	methods	method	NNS
cord-276598-tm0yj2sn	1031	1	The	the	DT
cord-276598-tm0yj2sn	1031	2	Reaction	reaction	NN
cord-276598-tm0yj2sn	1031	3	of	of	IN
cord-276598-tm0yj2sn	1031	4	Phosphorus	Phosphorus	NNP
cord-276598-tm0yj2sn	1031	5	-	-	HYPH
cord-276598-tm0yj2sn	1031	6	containing	contain	VBG
cord-276598-tm0yj2sn	1031	7	Enzyme	Enzyme	NNP
cord-276598-tm0yj2sn	1031	8	Inhibitors	Inhibitors	NNP
cord-276598-tm0yj2sn	1031	9	with	with	IN
cord-276598-tm0yj2sn	1031	10	Amines	Amines	NNPS
cord-276598-tm0yj2sn	1031	11	and	and	CC
cord-276598-tm0yj2sn	1031	12	Amino	amino	NN
cord-276598-tm0yj2sn	1031	13	Acid	acid	NN
cord-276598-tm0yj2sn	1031	14	Derivatives1	Derivatives1	NNP
cord-276598-tm0yj2sn	1032	1	The	the	DT
cord-276598-tm0yj2sn	1032	2	Formation	Formation	NNP
cord-276598-tm0yj2sn	1032	3	of	of	IN
cord-276598-tm0yj2sn	1032	4	P	P	NNP
cord-276598-tm0yj2sn	1032	5	-	-	HYPH
cord-276598-tm0yj2sn	1032	6	N	N	NNP
cord-276598-tm0yj2sn	1032	7	and	and	CC
cord-276598-tm0yj2sn	1032	8	P	P	NNP
cord-276598-tm0yj2sn	1032	9	-	-	HYPH
cord-276598-tm0yj2sn	1032	10	N	N	NNP
cord-276598-tm0yj2sn	1032	11	-	-	HYPH
cord-276598-tm0yj2sn	1032	12	P	P	NNP
cord-276598-tm0yj2sn	1032	13	Bonds	Bonds	NNPS
cord-276598-tm0yj2sn	1032	14	by	by	IN
cord-276598-tm0yj2sn	1032	15	Elimination	Elimination	NNP
cord-276598-tm0yj2sn	1032	16	of	of	IN
cord-276598-tm0yj2sn	1032	17	Phenol	Phenol	NNP
cord-276598-tm0yj2sn	1032	18	in	in	IN
cord-276598-tm0yj2sn	1032	19	a	a	DT
cord-276598-tm0yj2sn	1032	20	Basic	basic	JJ
cord-276598-tm0yj2sn	1032	21	Condensation	Condensation	NNP
cord-276598-tm0yj2sn	1032	22	Deoxygenation	Deoxygenation	NNP
cord-276598-tm0yj2sn	1032	23	of	of	IN
cord-276598-tm0yj2sn	1032	24	Nitro	Nitro	NNP
cord-276598-tm0yj2sn	1032	25	Groups	Groups	NNPS
cord-276598-tm0yj2sn	1032	26	by	by	IN
cord-276598-tm0yj2sn	1032	27	Trivalent	Trivalent	NNP
cord-276598-tm0yj2sn	1032	28	Phosphorus	Phosphorus	NNP
cord-276598-tm0yj2sn	1032	29	.	.	.
cord-276598-tm0yj2sn	1033	1	Indoles	Indoles	NNP
cord-276598-tm0yj2sn	1033	2	from	from	IN
cord-276598-tm0yj2sn	1033	3	o	o	NN
cord-276598-tm0yj2sn	1033	4	-	-	HYPH
cord-276598-tm0yj2sn	1033	5	Nitrostyrenes	Nitrostyrenes	NNPS
cord-276598-tm0yj2sn	1034	1	The	the	DT
cord-276598-tm0yj2sn	1034	2	Reactivity	Reactivity	NNP
cord-276598-tm0yj2sn	1034	3	of	of	IN
cord-276598-tm0yj2sn	1034	4	Organophosphorus	Organophosphorus	NNP
cord-276598-tm0yj2sn	1034	5	Compounds	Compounds	NNPS
cord-276598-tm0yj2sn	1034	6	.	.	.
cord-276598-tm0yj2sn	1035	1	Part	part	NN
cord-276598-tm0yj2sn	1035	2	XX1	XX1	NNP
cord-276598-tm0yj2sn	1035	3	.	.	.
cord-276598-tm0yj2sn	1036	1	P=	p=	NN
cord-276598-tm0yj2sn	1037	1	O	o	UH
cord-276598-tm0yj2sn	1037	2	Nucleophilicity	Nucleophilicity	NNP
cord-276598-tm0yj2sn	1037	3	in	in	IN
cord-276598-tm0yj2sn	1037	4	Phosphonates	Phosphonates	NNP
cord-276598-tm0yj2sn	1037	5	and	and	CC
cord-276598-tm0yj2sn	1037	6	Phosphoramidates	Phosphoramidates	NNP
cord-276598-tm0yj2sn	1037	7	Reduction	Reduction	NNP
cord-276598-tm0yj2sn	1037	8	of	of	IN
cord-276598-tm0yj2sn	1037	9	nitro	nitro	NN
cord-276598-tm0yj2sn	1037	10	-	-	HYPH
cord-276598-tm0yj2sn	1037	11	and	and	CC
cord-276598-tm0yj2sn	1037	12	nitroso	nitroso	NNS
cord-276598-tm0yj2sn	1037	13	-	-	HYPH
cord-276598-tm0yj2sn	1037	14	compounds	compound	NNS
cord-276598-tm0yj2sn	1037	15	by	by	IN
cord-276598-tm0yj2sn	1037	16	tervalent	tervalent	NN
cord-276598-tm0yj2sn	1037	17	phosphorus	phosphorus	NN
cord-276598-tm0yj2sn	1037	18	reagents	reagent	NNS
cord-276598-tm0yj2sn	1037	19	.	.	.
cord-276598-tm0yj2sn	1038	1	Part	part	NN
cord-276598-tm0yj2sn	1038	2	V.	V.	NNP
cord-276598-tm0yj2sn	1038	3	Reduction	Reduction	NNP
cord-276598-tm0yj2sn	1038	4	of	of	IN
cord-276598-tm0yj2sn	1038	5	alkyl	alkyl	NN
cord-276598-tm0yj2sn	1038	6	-	-	:
cord-276598-tm0yj2sn	1038	7	and	and	CC
cord-276598-tm0yj2sn	1038	8	methoxy	methoxy	NNS
cord-276598-tm0yj2sn	1038	9	-	-	HYPH
cord-276598-tm0yj2sn	1038	10	nitrobenzenes	nitrobenzene	NNS
cord-276598-tm0yj2sn	1038	11	,	,	,
cord-276598-tm0yj2sn	1038	12	and	and	CC
cord-276598-tm0yj2sn	1038	13	nitrobenzene	nitrobenzene	NN
cord-276598-tm0yj2sn	1038	14	by	by	IN
cord-276598-tm0yj2sn	1038	15	trialkyl	trialkyl	NNP
cord-276598-tm0yj2sn	1038	16	phosphites	phosphites	NNP
cord-276598-tm0yj2sn	1038	17	Phase	Phase	NNP
cord-276598-tm0yj2sn	1038	18	-	-	HYPH
cord-276598-tm0yj2sn	1038	19	Transfer	Transfer	NNP
cord-276598-tm0yj2sn	1038	20	-	-	HYPH
cord-276598-tm0yj2sn	1038	21	Catalysed	Catalysed	NNP
cord-276598-tm0yj2sn	1038	22	Phosphorylation	Phosphorylation	NNP
cord-276598-tm0yj2sn	1038	23	of	of	IN
cord-276598-tm0yj2sn	1038	24	Amines	Amines	NNPS
cord-276598-tm0yj2sn	1038	25	in	in	IN
cord-276598-tm0yj2sn	1038	26	an	an	DT
cord-276598-tm0yj2sn	1038	27	Aqueous	Aqueous	NNP
cord-276598-tm0yj2sn	1038	28	System	System	NNP
cord-276598-tm0yj2sn	1038	29	Selective	Selective	NNP
cord-276598-tm0yj2sn	1038	30	N	n	CD
cord-276598-tm0yj2sn	1038	31	-	-	HYPH
cord-276598-tm0yj2sn	1038	32	Alkylation	alkylation	NN
cord-276598-tm0yj2sn	1038	33	of	of	IN
cord-276598-tm0yj2sn	1038	34	Diethyl	Diethyl	NNP
cord-276598-tm0yj2sn	1038	35	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1038	36	:	:	:
cord-276598-tm0yj2sn	1038	37	Tetrabutylaminium	Tetrabutylaminium	NNP
cord-276598-tm0yj2sn	1038	38	Bromide	Bromide	NNP
cord-276598-tm0yj2sn	1038	39	as	as	IN
cord-276598-tm0yj2sn	1038	40	Catalyst	Catalyst	NNP
cord-276598-tm0yj2sn	1038	41	for	for	IN
cord-276598-tm0yj2sn	1038	42	Nucleophilic	Nucleophilic	NNP
cord-276598-tm0yj2sn	1038	43	Substitution	Substitution	NNP
cord-276598-tm0yj2sn	1038	44	in	in	IN
cord-276598-tm0yj2sn	1038	45	a	a	DT
cord-276598-tm0yj2sn	1038	46	Homogeneous	Homogeneous	NNP
cord-276598-tm0yj2sn	1038	47	Medium	Medium	NNP
cord-276598-tm0yj2sn	1038	48	A	A	NNP
cord-276598-tm0yj2sn	1038	49	Convenient	convenient	JJ
cord-276598-tm0yj2sn	1038	50	Method	method	NN
cord-276598-tm0yj2sn	1038	51	for	for	IN
cord-276598-tm0yj2sn	1038	52	the	the	DT
cord-276598-tm0yj2sn	1038	53	Protection	Protection	NNP
cord-276598-tm0yj2sn	1038	54	of	of	IN
cord-276598-tm0yj2sn	1038	55	Amino	Amino	NNP
cord-276598-tm0yj2sn	1038	56	Groups	Groups	NNPS
cord-276598-tm0yj2sn	1038	57	as	as	IN
cord-276598-tm0yj2sn	1038	58	Diethyl	Diethyl	NNP
cord-276598-tm0yj2sn	1038	59	Phosphoramidates	Phosphoramidates	NNP
cord-276598-tm0yj2sn	1038	60	Direct	direct	JJ
cord-276598-tm0yj2sn	1038	61	conversion	conversion	NN
cord-276598-tm0yj2sn	1038	62	of	of	IN
cord-276598-tm0yj2sn	1038	63	diethyl	diethyl	JJ
cord-276598-tm0yj2sn	1038	64	hydrogen	hydrogen	NN
cord-276598-tm0yj2sn	1038	65	phosphate	phosphate	NN
cord-276598-tm0yj2sn	1038	66	into	into	IN
cord-276598-tm0yj2sn	1038	67	diethyl	diethyl	NN
cord-276598-tm0yj2sn	1038	68	phosphoramides	phosphoramides	NNP
cord-276598-tm0yj2sn	1038	69	Zur	Zur	NNP
cord-276598-tm0yj2sn	1038	70	Umsetzung	Umsetzung	NNP
cord-276598-tm0yj2sn	1038	71	des	des	NNP
cord-276598-tm0yj2sn	1039	1	Zweikomponentensystems	Zweikomponentensystems	NNP
cord-276598-tm0yj2sn	1039	2	Trialkylphosphit/	trialkylphosphit/	CD
cord-276598-tm0yj2sn	1040	1	Tetrachlorkohlenstoff	Tetrachlorkohlenstoff	NNP
cord-276598-tm0yj2sn	1040	2	mit	mit	VBP
cord-276598-tm0yj2sn	1040	3	wasserstoffhaltigen	wasserstoffhaltigen	NNP
cord-276598-tm0yj2sn	1040	4	Nucleophilen	Nucleophilen	NNP
cord-276598-tm0yj2sn	1040	5	2	2	CD
cord-276598-tm0yj2sn	1040	6	.	.	.
cord-276598-tm0yj2sn	1041	1	Die	die	VB
cord-276598-tm0yj2sn	1041	2	Reaktion	Reaktion	NNP
cord-276598-tm0yj2sn	1041	3	mit	mit	NNP
cord-276598-tm0yj2sn	1041	4	Ammoniak	Ammoniak	NNP
cord-276598-tm0yj2sn	1041	5	und	und	IN
cord-276598-tm0yj2sn	1042	1	Aminen	Aminen	NNP
cord-276598-tm0yj2sn	1042	2	Directed	Directed	NNP
cord-276598-tm0yj2sn	1042	3	Arbuzov	Arbuzov	NNP
cord-276598-tm0yj2sn	1042	4	-	-	HYPH
cord-276598-tm0yj2sn	1042	5	type	type	NN
cord-276598-tm0yj2sn	1042	6	reactions	reaction	NNS
cord-276598-tm0yj2sn	1042	7	of	of	IN
cord-276598-tm0yj2sn	1042	8	2-cyano-1,1-dimethylethyl	2-cyano-1,1-dimethylethyl	NNP
cord-276598-tm0yj2sn	1042	9	deoxynucleoside	deoxynucleoside	NNP
cord-276598-tm0yj2sn	1042	10	phosphites	phosphites	NNP
cord-276598-tm0yj2sn	1042	11	A	a	DT
cord-276598-tm0yj2sn	1042	12	facile	facile	JJ
cord-276598-tm0yj2sn	1042	13	one	one	CD
cord-276598-tm0yj2sn	1042	14	-	-	HYPH
cord-276598-tm0yj2sn	1042	15	pot	pot	NN
cord-276598-tm0yj2sn	1042	16	transformation	transformation	NN
cord-276598-tm0yj2sn	1042	17	of	of	IN
cord-276598-tm0yj2sn	1042	18	alkyl	alkyl	JJ
cord-276598-tm0yj2sn	1042	19	bromides	bromide	NNS
cord-276598-tm0yj2sn	1042	20	into	into	IN
cord-276598-tm0yj2sn	1042	21	Diethyl	Diethyl	NNP
cord-276598-tm0yj2sn	1042	22	N	N	NNP
cord-276598-tm0yj2sn	1042	23	-	-	HYPH
cord-276598-tm0yj2sn	1042	24	Alkylphosphoroamidates	Alkylphosphoroamidates	NNP
cord-276598-tm0yj2sn	1042	25	Preparation	Preparation	NNP
cord-276598-tm0yj2sn	1042	26	of	of	IN
cord-276598-tm0yj2sn	1042	27	sterically	sterically	RB
cord-276598-tm0yj2sn	1042	28	hindered	hinder	VBN
cord-276598-tm0yj2sn	1042	29	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	1042	30	A	a	DT
cord-276598-tm0yj2sn	1042	31	phosphoryl	phosphoryl	NN
cord-276598-tm0yj2sn	1042	32	radical	radical	RB
cord-276598-tm0yj2sn	1042	33	-	-	HYPH
cord-276598-tm0yj2sn	1042	34	initiated	initiate	VBN
cord-276598-tm0yj2sn	1042	35	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	1042	36	-	-	HYPH
cord-276598-tm0yj2sn	1042	37	Todd	Todd	NNP
cord-276598-tm0yj2sn	1042	38	-	-	HYPH
cord-276598-tm0yj2sn	1042	39	type	type	NN
cord-276598-tm0yj2sn	1042	40	reaction	reaction	NN
cord-276598-tm0yj2sn	1042	41	under	under	IN
cord-276598-tm0yj2sn	1042	42	open	open	JJ
cord-276598-tm0yj2sn	1042	43	air	air	NN
cord-276598-tm0yj2sn	1042	44	A	a	DT
cord-276598-tm0yj2sn	1042	45	New	New	NNP
cord-276598-tm0yj2sn	1042	46	Approach	Approach	NNP
cord-276598-tm0yj2sn	1042	47	to	to	IN
cord-276598-tm0yj2sn	1042	48	the	the	DT
cord-276598-tm0yj2sn	1042	49	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	1042	50	-	-	HYPH
cord-276598-tm0yj2sn	1042	51	Todd	Todd	NNP
cord-276598-tm0yj2sn	1042	52	Reaction	Reaction	NNP
cord-276598-tm0yj2sn	1042	53	Efficient	Efficient	NNP
cord-276598-tm0yj2sn	1042	54	and	and	CC
cord-276598-tm0yj2sn	1042	55	Convenient	convenient	JJ
cord-276598-tm0yj2sn	1042	56	One	one	CD
cord-276598-tm0yj2sn	1042	57	-	-	HYPH
cord-276598-tm0yj2sn	1042	58	Pot	Pot	NNP
cord-276598-tm0yj2sn	1042	59	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1042	60	of	of	IN
cord-276598-tm0yj2sn	1042	61	Phosphoramidates	Phosphoramidates	NNPS
cord-276598-tm0yj2sn	1042	62	and	and	CC
cord-276598-tm0yj2sn	1042	63	Phosphates	Phosphates	NNPS
cord-276598-tm0yj2sn	1042	64	Trichloroisocyanuric	Trichloroisocyanuric	NNP
cord-276598-tm0yj2sn	1042	65	Acid	Acid	NNP
cord-276598-tm0yj2sn	1042	66	as	as	IN
cord-276598-tm0yj2sn	1042	67	an	an	DT
cord-276598-tm0yj2sn	1042	68	Efficient	Efficient	NNP
cord-276598-tm0yj2sn	1042	69	Reagent	reagent	NN
cord-276598-tm0yj2sn	1042	70	for	for	IN
cord-276598-tm0yj2sn	1042	71	the	the	DT
cord-276598-tm0yj2sn	1042	72	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1042	73	of	of	IN
cord-276598-tm0yj2sn	1042	74	Phosphoroamidates	Phosphoroamidates	NNP
cord-276598-tm0yj2sn	1042	75	via	via	IN
cord-276598-tm0yj2sn	1042	76	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	1042	77	-	-	HYPH
cord-276598-tm0yj2sn	1042	78	Todd	Todd	NNP
cord-276598-tm0yj2sn	1042	79	Reaction	Reaction	NNP
cord-276598-tm0yj2sn	1042	80	under	under	IN
cord-276598-tm0yj2sn	1042	81	Base	Base	NNP
cord-276598-tm0yj2sn	1042	82	-	-	HYPH
cord-276598-tm0yj2sn	1042	83	Free	Free	NNP
cord-276598-tm0yj2sn	1042	84	Conditions	condition	NNS
cord-276598-tm0yj2sn	1042	85	Efficient	efficient	JJ
cord-276598-tm0yj2sn	1042	86	Amidation	Amidation	NNP
cord-276598-tm0yj2sn	1042	87	and	and	CC
cord-276598-tm0yj2sn	1042	88	Esterification	Esterification	NNP
cord-276598-tm0yj2sn	1042	89	of	of	IN
cord-276598-tm0yj2sn	1042	90	Phosphoric	Phosphoric	NNP
cord-276598-tm0yj2sn	1042	91	Acid	acid	NN
cord-276598-tm0yj2sn	1043	1	Using	use	VBG
cord-276598-tm0yj2sn	1043	2	Cl3CCN/	cl3ccn/	PRP
cord-276598-tm0yj2sn	1044	1	Ph3P	Ph3P	NNP
cord-276598-tm0yj2sn	1045	1	Neues	Neues	NNP
cord-276598-tm0yj2sn	1045	2	Verfahren	Verfahren	NNP
cord-276598-tm0yj2sn	1045	3	zur	zur	NNP
cord-276598-tm0yj2sn	1045	4	Darstellung	Darstellung	NNP
cord-276598-tm0yj2sn	1045	5	von	von	NNP
cord-276598-tm0yj2sn	1045	6	Phosphorsäureesteramiden	Phosphorsäureesteramiden	NNP
cord-276598-tm0yj2sn	1045	7	,	,	,
cord-276598-tm0yj2sn	1045	8	Phosphinsäureamiden	Phosphinsäureamiden	NNP
cord-276598-tm0yj2sn	1045	9	,	,	,
cord-276598-tm0yj2sn	1045	10	Phosphinsäureestern	Phosphinsäureestern	NNP
cord-276598-tm0yj2sn	1045	11	und	und	IN
cord-276598-tm0yj2sn	1045	12	gemischt	gemischt	NNP
cord-276598-tm0yj2sn	1045	13	substituierten	substituierten	NNP
cord-276598-tm0yj2sn	1046	1	Phosphorsäuretriestern	Phosphorsäuretriestern	NNP
cord-276598-tm0yj2sn	1046	2	Reinvestigation	Reinvestigation	NNP
cord-276598-tm0yj2sn	1046	3	of	of	IN
cord-276598-tm0yj2sn	1046	4	the	the	DT
cord-276598-tm0yj2sn	1046	5	iodine	iodine	NN
cord-276598-tm0yj2sn	1046	6	-	-	HYPH
cord-276598-tm0yj2sn	1046	7	mediated	mediate	VBN
cord-276598-tm0yj2sn	1046	8	phosphoramidation	phosphoramidation	NN
cord-276598-tm0yj2sn	1046	9	reaction	reaction	NN
cord-276598-tm0yj2sn	1046	10	of	of	IN
cord-276598-tm0yj2sn	1046	11	amines	amine	NNS
cord-276598-tm0yj2sn	1046	12	and	and	CC
cord-276598-tm0yj2sn	1046	13	P(OR)3	p(or)3	CD
cord-276598-tm0yj2sn	1046	14	and	and	CC
cord-276598-tm0yj2sn	1046	15	its	-PRON-	PRP$
cord-276598-tm0yj2sn	1046	16	synthetic	synthetic	JJ
cord-276598-tm0yj2sn	1046	17	applications	application	NNS
cord-276598-tm0yj2sn	1046	18	Iodine	iodine	NN
cord-276598-tm0yj2sn	1046	19	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	1046	20	solvent	solvent	NN
cord-276598-tm0yj2sn	1046	21	-	-	HYPH
cord-276598-tm0yj2sn	1046	22	free	free	JJ
cord-276598-tm0yj2sn	1046	23	cross	cross	JJ
cord-276598-tm0yj2sn	1046	24	-	-	JJ
cord-276598-tm0yj2sn	1046	25	dehydrogenative	dehydrogenative	JJ
cord-276598-tm0yj2sn	1046	26	coupling	coupling	NN
cord-276598-tm0yj2sn	1046	27	of	of	IN
cord-276598-tm0yj2sn	1046	28	arylamines	arylamine	NNS
cord-276598-tm0yj2sn	1046	29	and	and	CC
cord-276598-tm0yj2sn	1046	30	H	H	NNP
cord-276598-tm0yj2sn	1046	31	-	-	HYPH
cord-276598-tm0yj2sn	1046	32	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	1046	33	for	for	IN
cord-276598-tm0yj2sn	1046	34	the	the	DT
cord-276598-tm0yj2sn	1046	35	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1046	36	of	of	IN
cord-276598-tm0yj2sn	1046	37	N	n	NN
cord-276598-tm0yj2sn	1046	38	-	-	HYPH
cord-276598-tm0yj2sn	1046	39	arylphosphoramidates	arylphosphoramidate	NNS
cord-276598-tm0yj2sn	1046	40	under	under	IN
cord-276598-tm0yj2sn	1046	41	atmospheric	atmospheric	JJ
cord-276598-tm0yj2sn	1046	42	conditions	condition	NNS
cord-276598-tm0yj2sn	1046	43	Cross	Cross	NNP
cord-276598-tm0yj2sn	1046	44	-	-	HYPH
cord-276598-tm0yj2sn	1046	45	Hetero	Hetero	NNP
cord-276598-tm0yj2sn	1046	46	-	-	HYPH
cord-276598-tm0yj2sn	1046	47	Dehydrogenative	Dehydrogenative	NNP
cord-276598-tm0yj2sn	1046	48	Coupling	Coupling	NNP
cord-276598-tm0yj2sn	1046	49	Reaction	reaction	NN
cord-276598-tm0yj2sn	1046	50	of	of	IN
cord-276598-tm0yj2sn	1046	51	Phosphites	Phosphites	NNP
cord-276598-tm0yj2sn	1046	52	:	:	:
cord-276598-tm0yj2sn	1046	53	A	a	DT
cord-276598-tm0yj2sn	1046	54	Catalytic	Catalytic	NNP
cord-276598-tm0yj2sn	1046	55	Metal	metal	NN
cord-276598-tm0yj2sn	1046	56	-	-	HYPH
cord-276598-tm0yj2sn	1046	57	Free	Free	NNP
cord-276598-tm0yj2sn	1046	58	Phosphorylation	Phosphorylation	NNP
cord-276598-tm0yj2sn	1046	59	of	of	IN
cord-276598-tm0yj2sn	1046	60	Amines	Amines	NNPS
cord-276598-tm0yj2sn	1046	61	and	and	CC
cord-276598-tm0yj2sn	1046	62	Alcohols	Alcohols	NNP
cord-276598-tm0yj2sn	1046	63	Phosphoramidate	Phosphoramidate	NNP
cord-276598-tm0yj2sn	1046	64	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1046	65	via	via	IN
cord-276598-tm0yj2sn	1046	66	copper	copper	NN
cord-276598-tm0yj2sn	1046	67	-	-	HYPH
cord-276598-tm0yj2sn	1046	68	catalysed	catalyse	VBN
cord-276598-tm0yj2sn	1046	69	aerobic	aerobic	JJ
cord-276598-tm0yj2sn	1046	70	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	1046	71	coupling	coupling	NN
cord-276598-tm0yj2sn	1046	72	of	of	IN
cord-276598-tm0yj2sn	1046	73	amines	amine	NNS
cord-276598-tm0yj2sn	1046	74	and	and	CC
cord-276598-tm0yj2sn	1046	75	H	H	NNP
cord-276598-tm0yj2sn	1046	76	-	-	HYPH
cord-276598-tm0yj2sn	1046	77	phosphonates	phosphonates	NNP
cord-276598-tm0yj2sn	1046	78	Copper	copper	NN
cord-276598-tm0yj2sn	1046	79	-	-	HYPH
cord-276598-tm0yj2sn	1046	80	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	1046	81	aerobic	aerobic	JJ
cord-276598-tm0yj2sn	1046	82	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	1046	83	cross	cross	NN
cord-276598-tm0yj2sn	1046	84	-	-	NN
cord-276598-tm0yj2sn	1046	85	coupling	coupling	NN
cord-276598-tm0yj2sn	1046	86	of	of	IN
cord-276598-tm0yj2sn	1046	87	arylamines	arylamine	NNS
cord-276598-tm0yj2sn	1046	88	and	and	CC
cord-276598-tm0yj2sn	1046	89	dialkylphosphites	dialkylphosphite	NNS
cord-276598-tm0yj2sn	1046	90	leading	lead	VBG
cord-276598-tm0yj2sn	1046	91	to	to	IN
cord-276598-tm0yj2sn	1046	92	N	N	NNP
cord-276598-tm0yj2sn	1046	93	-	-	HYPH
cord-276598-tm0yj2sn	1046	94	arylphosphoramidates	arylphosphoramidate	NNS
cord-276598-tm0yj2sn	1046	95	Fe	Fe	NNP
cord-276598-tm0yj2sn	1046	96	3	3	CD
cord-276598-tm0yj2sn	1046	97	O	o	NN
cord-276598-tm0yj2sn	1046	98	4	4	CD
cord-276598-tm0yj2sn	1046	99	@MgO	@MgO	NNS
cord-276598-tm0yj2sn	1046	100	nanoparticles	nanoparticle	NNS
cord-276598-tm0yj2sn	1046	101	as	as	IN
cord-276598-tm0yj2sn	1046	102	an	an	DT
cord-276598-tm0yj2sn	1046	103	efficient	efficient	JJ
cord-276598-tm0yj2sn	1046	104	recyclable	recyclable	JJ
cord-276598-tm0yj2sn	1046	105	catalyst	catalyst	NN
cord-276598-tm0yj2sn	1046	106	for	for	IN
cord-276598-tm0yj2sn	1046	107	the	the	DT
cord-276598-tm0yj2sn	1046	108	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1046	109	of	of	IN
cord-276598-tm0yj2sn	1046	110	phosphoroamidates	phosphoroamidate	NNS
cord-276598-tm0yj2sn	1046	111	via	via	IN
cord-276598-tm0yj2sn	1046	112	the	the	DT
cord-276598-tm0yj2sn	1046	113	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	1046	114	-	-	HYPH
cord-276598-tm0yj2sn	1046	115	Todd	Todd	NNP
cord-276598-tm0yj2sn	1046	116	reaction	reaction	NN
cord-276598-tm0yj2sn	1047	1	A	a	DT
cord-276598-tm0yj2sn	1047	2	single	single	JJ
cord-276598-tm0yj2sn	1047	3	-	-	HYPH
cord-276598-tm0yj2sn	1047	4	step	step	NN
cord-276598-tm0yj2sn	1047	5	one	one	CD
cord-276598-tm0yj2sn	1047	6	pot	pot	NN
cord-276598-tm0yj2sn	1047	7	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1047	8	of	of	IN
cord-276598-tm0yj2sn	1047	9	O	o	NN
cord-276598-tm0yj2sn	1047	10	,	,	,
cord-276598-tm0yj2sn	1047	11	O	o	UH
cord-276598-tm0yj2sn	1047	12	-dialkyl	-dialkyl	NNP
cord-276598-tm0yj2sn	1047	13	N	N	NNP
cord-276598-tm0yj2sn	1047	14	,	,	,
cord-276598-tm0yj2sn	1047	15	N	N	NNP
cord-276598-tm0yj2sn	1047	16	-	-	HYPH
cord-276598-tm0yj2sn	1047	17	dialkylphosphoramidates	dialkylphosphoramidate	NNS
cord-276598-tm0yj2sn	1047	18	from	from	IN
cord-276598-tm0yj2sn	1047	19	dialkylphosphites	dialkylphosphites	NNP
cord-276598-tm0yj2sn	1047	20	Copper	Copper	NNP
cord-276598-tm0yj2sn	1047	21	-	-	HYPH
cord-276598-tm0yj2sn	1047	22	Catalyzed	Catalyzed	NNP
cord-276598-tm0yj2sn	1047	23	Oxidative	Oxidative	NNP
cord-276598-tm0yj2sn	1047	24	Cross	Cross	NNP
cord-276598-tm0yj2sn	1047	25	-	-	HYPH
cord-276598-tm0yj2sn	1047	26	Coupling	Coupling	NNP
cord-276598-tm0yj2sn	1047	27	of	of	IN
cord-276598-tm0yj2sn	1047	28	H	H	NNP
cord-276598-tm0yj2sn	1047	29	-	-	HYPH
cord-276598-tm0yj2sn	1047	30	Phosphonates	Phosphonates	NNPS
cord-276598-tm0yj2sn	1047	31	and	and	CC
cord-276598-tm0yj2sn	1047	32	Amides	Amides	NNPS
cord-276598-tm0yj2sn	1047	33	to	to	IN
cord-276598-tm0yj2sn	1047	34	N	N	NNP
cord-276598-tm0yj2sn	1047	35	-	-	HYPH
cord-276598-tm0yj2sn	1047	36	Acylphosphoramidates	Acylphosphoramidates	NNP
cord-276598-tm0yj2sn	1047	37	Stereospecific	Stereospecific	NNP
cord-276598-tm0yj2sn	1047	38	Aerobic	Aerobic	NNP
cord-276598-tm0yj2sn	1047	39	Oxidative	Oxidative	NNP
cord-276598-tm0yj2sn	1047	40	Dehydrocoupling	Dehydrocoupling	NNP
cord-276598-tm0yj2sn	1047	41	of	of	IN
cord-276598-tm0yj2sn	1047	42	P(O)-H	P(O)-H	NNP
cord-276598-tm0yj2sn	1047	43	Bonds	Bonds	NNP
cord-276598-tm0yj2sn	1047	44	with	with	IN
cord-276598-tm0yj2sn	1047	45	Amines	amine	NNS
cord-276598-tm0yj2sn	1047	46	Catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	1047	47	by	by	IN
cord-276598-tm0yj2sn	1047	48	Copper	Copper	NNP
cord-276598-tm0yj2sn	1047	49	Copper	Copper	NNP
cord-276598-tm0yj2sn	1047	50	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	1047	51	tandem	tandem	NN
cord-276598-tm0yj2sn	1047	52	Chan	Chan	NNP
cord-276598-tm0yj2sn	1047	53	-	-	HYPH
cord-276598-tm0yj2sn	1047	54	Lam	Lam	NNP
cord-276598-tm0yj2sn	1047	55	type	type	NN
cord-276598-tm0yj2sn	1047	56	C	C	NNP
cord-276598-tm0yj2sn	1047	57	-	-	HYPH
cord-276598-tm0yj2sn	1047	58	N	N	NNP
cord-276598-tm0yj2sn	1047	59	and	and	CC
cord-276598-tm0yj2sn	1047	60	Staudinger	Staudinger	NNP
cord-276598-tm0yj2sn	1047	61	-	-	HYPH
cord-276598-tm0yj2sn	1047	62	phosphite	phosphite	NNP
cord-276598-tm0yj2sn	1047	63	N	N	NNP
cord-276598-tm0yj2sn	1047	64	-	-	HYPH
cord-276598-tm0yj2sn	1047	65	P	p	NN
cord-276598-tm0yj2sn	1047	66	coupling	coupling	NN
cord-276598-tm0yj2sn	1047	67	for	for	IN
cord-276598-tm0yj2sn	1047	68	the	the	DT
cord-276598-tm0yj2sn	1047	69	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1047	70	of	of	IN
cord-276598-tm0yj2sn	1047	71	N	N	NNP
cord-276598-tm0yj2sn	1047	72	-	-	HYPH
cord-276598-tm0yj2sn	1047	73	arylphosphoramidates	arylphosphoramidate	NNS
cord-276598-tm0yj2sn	1047	74	Organophotocatalytic	Organophotocatalytic	NNP
cord-276598-tm0yj2sn	1047	75	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1047	76	of	of	IN
cord-276598-tm0yj2sn	1047	77	Phosphoramidates	Phosphoramidates	NNP
cord-276598-tm0yj2sn	1047	78	LiI	lii	NN
cord-276598-tm0yj2sn	1047	79	/	/	SYM
cord-276598-tm0yj2sn	1047	80	TBHP	tbhp	RB
cord-276598-tm0yj2sn	1048	1	Mediated	Mediated	NNP
cord-276598-tm0yj2sn	1048	2	Oxidative	Oxidative	NNP
cord-276598-tm0yj2sn	1048	3	Cross	Cross	NNP
cord-276598-tm0yj2sn	1048	4	-	-	HYPH
cord-276598-tm0yj2sn	1048	5	Coupling	Coupling	NNP
cord-276598-tm0yj2sn	1048	6	of	of	IN
cord-276598-tm0yj2sn	1048	7	P(O)-H	P(O)-H	NNP
cord-276598-tm0yj2sn	1048	8	Compounds	compound	NNS
cord-276598-tm0yj2sn	1048	9	with	with	IN
cord-276598-tm0yj2sn	1048	10	Phenols	Phenols	NNPS
cord-276598-tm0yj2sn	1048	11	and	and	CC
cord-276598-tm0yj2sn	1048	12	Various	various	JJ
cord-276598-tm0yj2sn	1048	13	Nucleophiles	Nucleophiles	NNPS
cord-276598-tm0yj2sn	1048	14	:	:	:
cord-276598-tm0yj2sn	1049	1	Direct	Direct	NNP
cord-276598-tm0yj2sn	1049	2	Access	Access	NNP
cord-276598-tm0yj2sn	1049	3	to	to	IN
cord-276598-tm0yj2sn	1049	4	the	the	DT
cord-276598-tm0yj2sn	1049	5	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1049	6	of	of	IN
cord-276598-tm0yj2sn	1049	7	Organophosphates	Organophosphates	NNP
cord-276598-tm0yj2sn	1049	8	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1049	9	of	of	IN
cord-276598-tm0yj2sn	1049	10	Phosphoramidates	Phosphoramidates	NNPS
cord-276598-tm0yj2sn	1049	11	:	:	:
cord-276598-tm0yj2sn	1050	1	A	a	DT
cord-276598-tm0yj2sn	1050	2	Facile	facile	JJ
cord-276598-tm0yj2sn	1050	3	Approach	approach	NN
cord-276598-tm0yj2sn	1051	1	Based	base	VBN
cord-276598-tm0yj2sn	1051	2	on	on	IN
cord-276598-tm0yj2sn	1051	3	the	the	DT
cord-276598-tm0yj2sn	1051	4	C	C	NNP
cord-276598-tm0yj2sn	1051	5	-	-	HYPH
cord-276598-tm0yj2sn	1051	6	N	N	NNP
cord-276598-tm0yj2sn	1051	7	Bond	Bond	NNP
cord-276598-tm0yj2sn	1051	8	Formation	Formation	NNP
cord-276598-tm0yj2sn	1051	9	via	via	IN
cord-276598-tm0yj2sn	1051	10	Ir	Ir	NNP
cord-276598-tm0yj2sn	1051	11	-	-	HYPH
cord-276598-tm0yj2sn	1051	12	Catalyzed	Catalyzed	NNP
cord-276598-tm0yj2sn	1051	13	Direct	Direct	NNP
cord-276598-tm0yj2sn	1051	14	C	c	NN
cord-276598-tm0yj2sn	1051	15	-	-	HYPH
cord-276598-tm0yj2sn	1051	16	H	h	NN
cord-276598-tm0yj2sn	1051	17	Amidation	Amidation	NNP
cord-276598-tm0yj2sn	1051	18	Ruthenium(iv	Ruthenium(iv	NNP
cord-276598-tm0yj2sn	1051	19	)	)	-RRB-
cord-276598-tm0yj2sn	1051	20	porphyrin	porphyrin	NN
cord-276598-tm0yj2sn	1051	21	catalyzed	catalyze	VBD
cord-276598-tm0yj2sn	1051	22	phosphoramidation	phosphoramidation	NN
cord-276598-tm0yj2sn	1051	23	of	of	IN
cord-276598-tm0yj2sn	1051	24	aldehydes	aldehyde	NNS
cord-276598-tm0yj2sn	1051	25	with	with	IN
cord-276598-tm0yj2sn	1051	26	phosphoryl	phosphoryl	NNP
cord-276598-tm0yj2sn	1051	27	azides	azides	NNP
cord-276598-tm0yj2sn	1051	28	as	as	IN
cord-276598-tm0yj2sn	1051	29	a	a	DT
cord-276598-tm0yj2sn	1051	30	nitrene	nitrene	JJ
cord-276598-tm0yj2sn	1051	31	source	source	NN
cord-276598-tm0yj2sn	1051	32	Iridium	Iridium	NNP
cord-276598-tm0yj2sn	1051	33	-	-	HYPH
cord-276598-tm0yj2sn	1051	34	Catalyzed	Catalyzed	NNP
cord-276598-tm0yj2sn	1051	35	Phosphoramidation	Phosphoramidation	NNP
cord-276598-tm0yj2sn	1051	36	of	of	IN
cord-276598-tm0yj2sn	1051	37	Arene	Arene	NNP
cord-276598-tm0yj2sn	1051	38	C	C	NNP
cord-276598-tm0yj2sn	1051	39	-	-	HYPH
cord-276598-tm0yj2sn	1051	40	H	H	NNP
cord-276598-tm0yj2sn	1051	41	Bonds	Bonds	NNP
cord-276598-tm0yj2sn	1051	42	with	with	IN
cord-276598-tm0yj2sn	1051	43	Phosphoryl	Phosphoryl	NNP
cord-276598-tm0yj2sn	1051	44	Azide	Azide	NNP
cord-276598-tm0yj2sn	1051	45	Catalyst	Catalyst	NNP
cord-276598-tm0yj2sn	1052	1	free	free	JJ
cord-276598-tm0yj2sn	1052	2	,	,	,
cord-276598-tm0yj2sn	1052	3	one	one	CD
cord-276598-tm0yj2sn	1052	4	pot	pot	NN
cord-276598-tm0yj2sn	1052	5	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1052	6	of	of	IN
cord-276598-tm0yj2sn	1052	7	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	1052	8	under	under	IN
cord-276598-tm0yj2sn	1052	9	environment	environment	NN
cord-276598-tm0yj2sn	1052	10	friendly	friendly	JJ
cord-276598-tm0yj2sn	1052	11	conditions	condition	NNS
cord-276598-tm0yj2sn	1053	1	An	an	DT
cord-276598-tm0yj2sn	1053	2	efficient	efficient	JJ
cord-276598-tm0yj2sn	1053	3	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1053	4	of	of	IN
cord-276598-tm0yj2sn	1053	5	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	1053	6	from	from	IN
cord-276598-tm0yj2sn	1053	7	halides	halide	NNS
cord-276598-tm0yj2sn	1053	8	in	in	IN
cord-276598-tm0yj2sn	1053	9	aqueous	aqueous	JJ
cord-276598-tm0yj2sn	1053	10	ethanol	ethanol	NN
cord-276598-tm0yj2sn	1053	11	Transition	transition	NN
cord-276598-tm0yj2sn	1053	12	-	-	HYPH
cord-276598-tm0yj2sn	1053	13	metal	metal	NN
cord-276598-tm0yj2sn	1053	14	-	-	HYPH
cord-276598-tm0yj2sn	1053	15	free	free	JJ
cord-276598-tm0yj2sn	1053	16	amination	amination	NN
cord-276598-tm0yj2sn	1053	17	phosphoryl	phosphoryl	NNS
cord-276598-tm0yj2sn	1053	18	azide	azide	NN
cord-276598-tm0yj2sn	1053	19	for	for	IN
cord-276598-tm0yj2sn	1053	20	the	the	DT
cord-276598-tm0yj2sn	1053	21	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1053	22	of	of	IN
cord-276598-tm0yj2sn	1053	23	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	1053	24	Practical	Practical	NNP
cord-276598-tm0yj2sn	1053	25	and	and	CC
cord-276598-tm0yj2sn	1053	26	reliable	reliable	JJ
cord-276598-tm0yj2sn	1053	27	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1053	28	of	of	IN
cord-276598-tm0yj2sn	1053	29	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	1053	30	N	N	NNP
cord-276598-tm0yj2sn	1053	31	-	-	HYPH
cord-276598-tm0yj2sn	1053	32	arylphosphoramidates	arylphosphoramidate	NNS
cord-276598-tm0yj2sn	1053	33	with	with	IN
cord-276598-tm0yj2sn	1053	34	nitroarenes	nitroarene	NNS
cord-276598-tm0yj2sn	1053	35	as	as	IN
cord-276598-tm0yj2sn	1053	36	substrates	substrate	NNS
cord-276598-tm0yj2sn	1053	37	Synthesis	Synthesis	NNP
cord-276598-tm0yj2sn	1053	38	of	of	IN
cord-276598-tm0yj2sn	1053	39	N	N	NNP
cord-276598-tm0yj2sn	1053	40	,	,	,
cord-276598-tm0yj2sn	1053	41	N	N	NNP
cord-276598-tm0yj2sn	1053	42	-	-	HYPH
cord-276598-tm0yj2sn	1053	43	disubstituted	disubstitute	VBN
cord-276598-tm0yj2sn	1053	44	phosphoramidatesvia	phosphoramidatesvia	NNP
cord-276598-tm0yj2sn	1053	45	a	a	DT
cord-276598-tm0yj2sn	1053	46	Lewis	Lewis	NNP
cord-276598-tm0yj2sn	1053	47	acid	acid	NN
cord-276598-tm0yj2sn	1053	48	-	-	HYPH
cord-276598-tm0yj2sn	1053	49	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	1053	50	phosphorimidate	phosphorimidate	NN
cord-276598-tm0yj2sn	1053	51	rearrangement	rearrangement	NN
cord-276598-tm0yj2sn	1053	52	Reaction	reaction	NN
cord-276598-tm0yj2sn	1053	53	of	of	IN
cord-276598-tm0yj2sn	1053	54	sodium	sodium	NN
cord-276598-tm0yj2sn	1053	55	salts	salt	NNS
cord-276598-tm0yj2sn	1053	56	of	of	IN
cord-276598-tm0yj2sn	1053	57	dialkylphosphorous	dialkylphosphorous	JJ
cord-276598-tm0yj2sn	1053	58	acids	acid	NNS
cord-276598-tm0yj2sn	1053	59	with	with	IN
cord-276598-tm0yj2sn	1053	60	carboxylic	carboxylic	JJ
cord-276598-tm0yj2sn	1053	61	acid	acid	NN
cord-276598-tm0yj2sn	1053	62	nitriles	nitrile	NNS
cord-276598-tm0yj2sn	1053	63	Study	Study	NNP
cord-276598-tm0yj2sn	1053	64	on	on	IN
cord-276598-tm0yj2sn	1053	65	the	the	DT
cord-276598-tm0yj2sn	1053	66	Atherton	Atherton	NNP
cord-276598-tm0yj2sn	1053	67	-	-	HYPH
cord-276598-tm0yj2sn	1053	68	Todd	Todd	NNP
cord-276598-tm0yj2sn	1053	69	reaction	reaction	NN
cord-276598-tm0yj2sn	1053	70	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1053	71	Cesium	cesium	NN
cord-276598-tm0yj2sn	1053	72	Effect	effect	NN
cord-276598-tm0yj2sn	1053	73	:	:	:
cord-276598-tm0yj2sn	1053	74	High	high	JJ
cord-276598-tm0yj2sn	1053	75	Chemoselectivity	Chemoselectivity	NNP
cord-276598-tm0yj2sn	1053	76	in	in	IN
cord-276598-tm0yj2sn	1053	77	Direct	Direct	NNP
cord-276598-tm0yj2sn	1053	78	N	N	NNP
cord-276598-tm0yj2sn	1053	79	-	-	HYPH
cord-276598-tm0yj2sn	1053	80	Alkylation	alkylation	NN
cord-276598-tm0yj2sn	1053	81	of	of	IN
cord-276598-tm0yj2sn	1053	82	Amines	Amines	NNPS
cord-276598-tm0yj2sn	1053	83	Improved	Improved	NNP
cord-276598-tm0yj2sn	1053	84	Cs	Cs	NNP
cord-276598-tm0yj2sn	1053	85	2	2	CD
cord-276598-tm0yj2sn	1053	86	CO	CO	NNP
cord-276598-tm0yj2sn	1053	87	3	3	CD
cord-276598-tm0yj2sn	1053	88	Promoted	promote	VBN
cord-276598-tm0yj2sn	1053	89	O	o	NN
cord-276598-tm0yj2sn	1053	90	-	-	HYPH
cord-276598-tm0yj2sn	1053	91	Alkylation	alkylation	NN
cord-276598-tm0yj2sn	1053	92	of	of	IN
cord-276598-tm0yj2sn	1053	93	Acids	acid	NNS
cord-276598-tm0yj2sn	1053	94	Abnormally	abnormally	RB
cord-276598-tm0yj2sn	1053	95	high	high	JJ
cord-276598-tm0yj2sn	1053	96	nucleophilicity	nucleophilicity	NN
cord-276598-tm0yj2sn	1053	97	of	of	IN
cord-276598-tm0yj2sn	1053	98	micellar	micellar	NN
cord-276598-tm0yj2sn	1053	99	-	-	HYPH
cord-276598-tm0yj2sn	1053	100	bound	bind	VBN
cord-276598-tm0yj2sn	1053	101	azide	azide	NN
cord-276598-tm0yj2sn	1053	102	ion	ion	NN
cord-276598-tm0yj2sn	1053	103	One	one	CD
cord-276598-tm0yj2sn	1053	104	-	-	HYPH
cord-276598-tm0yj2sn	1053	105	Pot	pot	NN
cord-276598-tm0yj2sn	1053	106	Procedure	Procedure	NNP
cord-276598-tm0yj2sn	1053	107	for	for	IN
cord-276598-tm0yj2sn	1053	108	Diazo	Diazo	NNP
cord-276598-tm0yj2sn	1053	109	Transfer	Transfer	NNP
cord-276598-tm0yj2sn	1053	110	and	and	CC
cord-276598-tm0yj2sn	1053	111	Azide−Alkyne	Azide−Alkyne	NNP
cord-276598-tm0yj2sn	1053	112	Cycloaddition	Cycloaddition	NNP
cord-276598-tm0yj2sn	1053	113	:	:	:
cord-276598-tm0yj2sn	1053	114	Triazole	Triazole	NNP
cord-276598-tm0yj2sn	1053	115	Linkages	Linkages	NNP
cord-276598-tm0yj2sn	1053	116	from	from	IN
cord-276598-tm0yj2sn	1053	117	Amines	amine	NNS
cord-276598-tm0yj2sn	1053	118	We	-PRON-	PRP
cord-276598-tm0yj2sn	1054	1	gratefully	gratefully	RB
cord-276598-tm0yj2sn	1054	2	acknowledge	acknowledge	VB
cord-276598-tm0yj2sn	1054	3	Ebonyi	Ebonyi	NNP
cord-276598-tm0yj2sn	1054	4	State	State	NNP
cord-276598-tm0yj2sn	1054	5	University	University	NNP
cord-276598-tm0yj2sn	1054	6	Abakaliki	Abakaliki	NNP
cord-276598-tm0yj2sn	1054	7	and	and	CC
cord-276598-tm0yj2sn	1054	8	Tertiary	Tertiary	NNP
cord-276598-tm0yj2sn	1054	9	Education	Education	NNP
cord-276598-tm0yj2sn	1054	10	Trust	Trust	NNP
cord-276598-tm0yj2sn	1054	11	Fund	Fund	NNP
cord-276598-tm0yj2sn	1054	12	(	(	-LRB-
cord-276598-tm0yj2sn	1054	13	TETFund	TETFund	NNP
cord-276598-tm0yj2sn	1054	14	)	)	-RRB-
cord-276598-tm0yj2sn	1054	15	Nigeria	Nigeria	NNP
cord-276598-tm0yj2sn	1054	16	for	for	IN
cord-276598-tm0yj2sn	1054	17	E.J.I	E.J.I	NNP
cord-276598-tm0yj2sn	1054	18	's	's	POS
cord-276598-tm0yj2sn	1054	19	PhD	phd	NN
cord-276598-tm0yj2sn	1054	20	Scholarship	Scholarship	NNP
cord-276598-tm0yj2sn	1054	21	and	and	CC
cord-276598-tm0yj2sn	1054	22	The	the	DT
cord-276598-tm0yj2sn	1054	23	MacDiarmid	MacDiarmid	NNP
cord-276598-tm0yj2sn	1054	24	Institute	Institute	NNP
cord-276598-tm0yj2sn	1054	25	for	for	IN
cord-276598-tm0yj2sn	1054	26	Advanced	Advanced	NNP
cord-276598-tm0yj2sn	1054	27	Materials	Materials	NNPS
cord-276598-tm0yj2sn	1054	28	and	and	CC
cord-276598-tm0yj2sn	1054	29	Nanotechnology	Nanotechnology	NNP
cord-276598-tm0yj2sn	1054	30	,	,	,
cord-276598-tm0yj2sn	1054	31	Wellington	Wellington	NNP
cord-276598-tm0yj2sn	1054	32	,	,	,
cord-276598-tm0yj2sn	1054	33	New	New	NNP
cord-276598-tm0yj2sn	1054	34	Zealand	Zealand	NNP
cord-276598-tm0yj2sn	1054	35	for	for	IN
cord-276598-tm0yj2sn	1054	36	financial	financial	JJ
cord-276598-tm0yj2sn	1054	37	support	support	NN
cord-276598-tm0yj2sn	1054	38	.	.	.
cord-276598-tm0yj2sn	1055	1	The	the	DT
cord-276598-tm0yj2sn	1055	2	authors	author	NNS
cord-276598-tm0yj2sn	1055	3	declare	declare	VBP
cord-276598-tm0yj2sn	1055	4	no	no	DT
cord-276598-tm0yj2sn	1055	5	conflict	conflict	NN
cord-276598-tm0yj2sn	1055	6	of	of	IN
cord-276598-tm0yj2sn	1055	7	interest	interest	NN
cord-276598-tm0yj2sn	1055	8	.	.	.
cord-276598-tm0yj2sn	1056	1	Dialkyl	Dialkyl	NNP
cord-276598-tm0yj2sn	1056	2	chlorophosphate	chlorophosphate	NNP
cord-276598-tm0yj2sn	1056	3	(	(	-LRB-
cord-276598-tm0yj2sn	1056	4	dACP	dACP	NNP
cord-276598-tm0yj2sn	1056	5	)	)	-RRB-
cord-276598-tm0yj2sn	1056	6	,	,	,
cord-276598-tm0yj2sn	1056	7	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	1056	8	phosphoriodidate	phosphoriodidate	NNP
cord-276598-tm0yj2sn	1056	9	(	(	-LRB-
cord-276598-tm0yj2sn	1056	10	dAPPI	dappi	NN
cord-276598-tm0yj2sn	1056	11	)	)	-RRB-
cord-276598-tm0yj2sn	1056	12	,	,	,
cord-276598-tm0yj2sn	1056	13	H	h	NN
cord-276598-tm0yj2sn	1056	14	-	-	HYPH
cord-276598-tm0yj2sn	1056	15	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	1056	16	(	(	-LRB-
cord-276598-tm0yj2sn	1056	17	H	h	NN
cord-276598-tm0yj2sn	1056	18	-	-	HYPH
cord-276598-tm0yj2sn	1056	19	P	P	NNP
cord-276598-tm0yj2sn	1056	20	)	)	-RRB-
cord-276598-tm0yj2sn	1056	21	,	,	,
cord-276598-tm0yj2sn	1056	22	phosphoramidate	phosphoramidate	NNP
cord-276598-tm0yj2sn	1056	23	(	(	-LRB-
cord-276598-tm0yj2sn	1056	24	P	P	NNP
cord-276598-tm0yj2sn	1056	25	-	-	HYPH
cord-276598-tm0yj2sn	1056	26	N	N	NNP
cord-276598-tm0yj2sn	1056	27	)	)	-RRB-
cord-276598-tm0yj2sn	1056	28	,	,	,
cord-276598-tm0yj2sn	1056	29	trichloroisocyanuric	trichloroisocyanuric	NN
cord-276598-tm0yj2sn	1056	30	acid	acid	NN
cord-276598-tm0yj2sn	1056	31	(	(	-LRB-
cord-276598-tm0yj2sn	1056	32	tCiC	tCiC	NNP
cord-276598-tm0yj2sn	1056	33	-	-	HYPH
cord-276598-tm0yj2sn	1056	34	A	a	NN
cord-276598-tm0yj2sn	1056	35	)	)	-RRB-
cord-276598-tm0yj2sn	1056	36	,	,	,
cord-276598-tm0yj2sn	1056	37	1,3,5-triazinane-2,4,6-trione	1,3,5-triazinane-2,4,6-trione	CD
cord-276598-tm0yj2sn	1056	38	(	(	-LRB-
cord-276598-tm0yj2sn	1056	39	tAtO	tAtO	NNP
cord-276598-tm0yj2sn	1056	40	)	)	-RRB-
cord-276598-tm0yj2sn	1056	41	,	,	,
cord-276598-tm0yj2sn	1056	42	N	N	NNP
cord-276598-tm0yj2sn	1056	43	-	-	HYPH
cord-276598-tm0yj2sn	1056	44	acylphosphoramidates	acylphosphoramidates	NNP
cord-276598-tm0yj2sn	1057	1	(	(	-LRB-
cord-276598-tm0yj2sn	1057	2	AcP	AcP	NNP
cord-276598-tm0yj2sn	1057	3	-	-	HYPH
cord-276598-tm0yj2sn	1057	4	N	N	NNP
cord-276598-tm0yj2sn	1057	5	)	)	-RRB-
cord-276598-tm0yj2sn	1057	6	,	,	,
cord-276598-tm0yj2sn	1057	7	diphenylphosphine	diphenylphosphine	JJ
cord-276598-tm0yj2sn	1057	8	oxide	oxide	NN
cord-276598-tm0yj2sn	1057	9	(	(	-LRB-
cord-276598-tm0yj2sn	1057	10	dPPO	dPPO	NNP
cord-276598-tm0yj2sn	1057	11	)	)	-RRB-
cord-276598-tm0yj2sn	1057	12	,	,	,
cord-276598-tm0yj2sn	1057	13	phosphonic	phosphonic	NNP
cord-276598-tm0yj2sn	1057	14	acid	acid	NN
cord-276598-tm0yj2sn	1057	15	(	(	-LRB-
cord-276598-tm0yj2sn	1057	16	PP	PP	NNP
cord-276598-tm0yj2sn	1057	17	-	-	HYPH
cord-276598-tm0yj2sn	1057	18	A	A	NNP
cord-276598-tm0yj2sn	1057	19	)	)	-RRB-
cord-276598-tm0yj2sn	1057	20	,	,	.
cord-276598-tm0yj2sn	1058	1	N	n	NN
cord-276598-tm0yj2sn	1058	2	-	-	HYPH
cord-276598-tm0yj2sn	1058	3	bromosuccinimide	bromosuccinimide	NNP
cord-276598-tm0yj2sn	1058	4	(	(	-LRB-
cord-276598-tm0yj2sn	1058	5	NBS	NBS	NNP
cord-276598-tm0yj2sn	1058	6	)	)	-RRB-
cord-276598-tm0yj2sn	1058	7	,	,	,
cord-276598-tm0yj2sn	1058	8	diphenyl	diphenyl	NNP
cord-276598-tm0yj2sn	1058	9	phosphoric	phosphoric	JJ
cord-276598-tm0yj2sn	1058	10	acid	acid	NN
cord-276598-tm0yj2sn	1058	11	(	(	-LRB-
cord-276598-tm0yj2sn	1058	12	dPPA	dPPA	NNP
cord-276598-tm0yj2sn	1058	13	)	)	-RRB-
cord-276598-tm0yj2sn	1058	14	,	,	,
cord-276598-tm0yj2sn	1058	15	triphenylphosphine	triphenylphosphine	NNP
cord-276598-tm0yj2sn	1058	16	(	(	-LRB-
cord-276598-tm0yj2sn	1058	17	tPP	tPP	NNP
cord-276598-tm0yj2sn	1058	18	)	)	-RRB-
cord-276598-tm0yj2sn	1058	19	,	,	,
cord-276598-tm0yj2sn	1058	20	diisopropylchlorophosphate	diisopropylchlorophosphate	NNP
cord-276598-tm0yj2sn	1058	21	(	(	-LRB-
cord-276598-tm0yj2sn	1058	22	dPrCP	dPrCP	NNP
cord-276598-tm0yj2sn	1058	23	)	)	-RRB-
cord-276598-tm0yj2sn	1058	24	,	,	,
cord-276598-tm0yj2sn	1058	25	tetraethylpyrophosphate	tetraethylpyrophosphate	NNP
cord-276598-tm0yj2sn	1058	26	(	(	-LRB-
cord-276598-tm0yj2sn	1058	27	tEPyP	tEPyP	NNP
cord-276598-tm0yj2sn	1058	28	)	)	-RRB-
cord-276598-tm0yj2sn	1058	29	,	,	,
cord-276598-tm0yj2sn	1058	30	triphenylphosphate	triphenylphosphate	NNP
cord-276598-tm0yj2sn	1058	31	(	(	-LRB-
cord-276598-tm0yj2sn	1058	32	tPPO	tPPO	NNP
cord-276598-tm0yj2sn	1058	33	)	)	-RRB-
cord-276598-tm0yj2sn	1058	34	,	,	,
cord-276598-tm0yj2sn	1058	35	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine	CD
cord-276598-tm0yj2sn	1058	36	(	(	-LRB-
cord-276598-tm0yj2sn	1058	37	DBU	DBU	NNP
cord-276598-tm0yj2sn	1058	38	)	)	-RRB-
cord-276598-tm0yj2sn	1058	39	,	,	.
cord-276598-tm0yj2sn	1059	1	matrix	matrix	NN
cord-276598-tm0yj2sn	1059	2	-	-	HYPH
cord-276598-tm0yj2sn	1059	3	assisted	assist	VBN
cord-276598-tm0yj2sn	1059	4	laser	laser	NN
cord-276598-tm0yj2sn	1059	5	desorption	desorption	NN
cord-276598-tm0yj2sn	1059	6	-	-	HYPH
cord-276598-tm0yj2sn	1059	7	ionization	ionization	NN
cord-276598-tm0yj2sn	1059	8	time	time	NN
cord-276598-tm0yj2sn	1059	9	-	-	HYPH
cord-276598-tm0yj2sn	1059	10	of	of	IN
cord-276598-tm0yj2sn	1059	11	-	-	HYPH
cord-276598-tm0yj2sn	1059	12	flight	flight	NN
cord-276598-tm0yj2sn	1059	13	mass	mass	NN
cord-276598-tm0yj2sn	1059	14	spectrometry	spectrometry	NN
cord-276598-tm0yj2sn	1059	15	(	(	-LRB-
cord-276598-tm0yj2sn	1059	16	MALDI	MALDI	NNP
cord-276598-tm0yj2sn	1059	17	-	-	HYPH
cord-276598-tm0yj2sn	1059	18	TOF	TOF	NNP
cord-276598-tm0yj2sn	1059	19	MS	MS	NNP
cord-276598-tm0yj2sn	1059	20	)	)	-RRB-
cord-276598-tm0yj2sn	1059	21	,	,	,
cord-276598-tm0yj2sn	1059	22	task	task	NN
cord-276598-tm0yj2sn	1059	23	specific	specific	JJ
cord-276598-tm0yj2sn	1059	24	ionic	ionic	JJ
cord-276598-tm0yj2sn	1059	25	liquid	liquid	NN
cord-276598-tm0yj2sn	1059	26	(	(	-LRB-
cord-276598-tm0yj2sn	1059	27	TSIL	TSIL	NNP
cord-276598-tm0yj2sn	1059	28	)	)	-RRB-
cord-276598-tm0yj2sn	1059	29	,	,	,
cord-276598-tm0yj2sn	1059	30	phosphorodiamidate	phosphorodiamidate	NNP
cord-276598-tm0yj2sn	1059	31	(	(	-LRB-
cord-276598-tm0yj2sn	1059	32	N	N	NNP
cord-276598-tm0yj2sn	1059	33	-	-	HYPH
cord-276598-tm0yj2sn	1059	34	P	P	NNP
cord-276598-tm0yj2sn	1059	35	-	-	HYPH
cord-276598-tm0yj2sn	1059	36	N	N	NNP
cord-276598-tm0yj2sn	1059	37	)	)	-RRB-
cord-276598-tm0yj2sn	1059	38	,	,	,
cord-276598-tm0yj2sn	1059	39	phenyl	phenyl	NNP
cord-276598-tm0yj2sn	1059	40	dichlorophosphate	dichlorophosphate	VBP
cord-276598-tm0yj2sn	1059	41	(	(	-LRB-
cord-276598-tm0yj2sn	1059	42	PdCP	PdCP	NNP
cord-276598-tm0yj2sn	1059	43	)	)	-RRB-
cord-276598-tm0yj2sn	1059	44	,	,	,
cord-276598-tm0yj2sn	1059	45	diphenylchlorophosphate	diphenylchlorophosphate	NNP
cord-276598-tm0yj2sn	1059	46	(	(	-LRB-
cord-276598-tm0yj2sn	1060	1	dPCP	dPCP	NNP
cord-276598-tm0yj2sn	1060	2	)	)	-RRB-
cord-276598-tm0yj2sn	1060	3	,	,	,
cord-276598-tm0yj2sn	1060	4	tert	tert	NN
cord-276598-tm0yj2sn	1060	5	-	-	HYPH
cord-276598-tm0yj2sn	1060	6	butyl	butyl	NN
cord-276598-tm0yj2sn	1060	7	hydroperoxide	hydroperoxide	NN
cord-276598-tm0yj2sn	1060	8	(	(	-LRB-
cord-276598-tm0yj2sn	1060	9	TBHP	TBHP	NNP
cord-276598-tm0yj2sn	1060	10	)	)	-RRB-
cord-276598-tm0yj2sn	1060	11	.	.	.
cord-276598-tm0yj2sn	1061	1	There	there	EX
cord-276598-tm0yj2sn	1061	2	were	be	VBD
cord-276598-tm0yj2sn	1061	3	no	no	DT
cord-276598-tm0yj2sn	1061	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	1061	5	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	1061	6	for	for	IN
cord-276598-tm0yj2sn	1061	7	the	the	DT
cord-276598-tm0yj2sn	1061	8	reaction	reaction	NN
cord-276598-tm0yj2sn	1061	9	in	in	IN
cord-276598-tm0yj2sn	1061	10	the	the	DT
cord-276598-tm0yj2sn	1061	11	report	report	NN
cord-276598-tm0yj2sn	1061	12	by	by	IN
cord-276598-tm0yj2sn	1061	13	Wang	Wang	NNP
cord-276598-tm0yj2sn	1061	14	et	et	NNP
cord-276598-tm0yj2sn	1061	15	al	al	NNP
cord-276598-tm0yj2sn	1061	16	.	.	.
cord-276598-tm0yj2sn	1062	1	[	[	-LRB-
cord-276598-tm0yj2sn	1062	2	104	104	CD
cord-276598-tm0yj2sn	1062	3	]	]	-RRB-
cord-276598-tm0yj2sn	1062	4	.	.	.
cord-276598-tm0yj2sn	1063	1	However	however	RB
cord-276598-tm0yj2sn	1063	2	,	,	,
cord-276598-tm0yj2sn	1063	3	the	the	DT
cord-276598-tm0yj2sn	1063	4	results	result	NNS
cord-276598-tm0yj2sn	1063	5	of	of	IN
cord-276598-tm0yj2sn	1063	6	the	the	DT
cord-276598-tm0yj2sn	1063	7	reagent	reagent	NN
cord-276598-tm0yj2sn	1063	8	screening	screening	NN
cord-276598-tm0yj2sn	1063	9	for	for	IN
cord-276598-tm0yj2sn	1063	10	the	the	DT
cord-276598-tm0yj2sn	1063	11	reaction	reaction	NN
cord-276598-tm0yj2sn	1063	12	had	have	VBD
cord-276598-tm0yj2sn	1063	13	suggested	suggest	VBN
cord-276598-tm0yj2sn	1063	14	that	that	IN
cord-276598-tm0yj2sn	1063	15	other	other	JJ
cord-276598-tm0yj2sn	1063	16	transition	transition	NN
cord-276598-tm0yj2sn	1063	17	metal	metal	NN
cord-276598-tm0yj2sn	1063	18	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	1063	19	(	(	-LRB-
cord-276598-tm0yj2sn	1063	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1063	21	,	,	,
cord-276598-tm0yj2sn	1063	22	CoBr2	CoBr2	NNS
cord-276598-tm0yj2sn	1063	23	)	)	-RRB-
cord-276598-tm0yj2sn	1063	24	and	and	CC
cord-276598-tm0yj2sn	1063	25	other	other	JJ
cord-276598-tm0yj2sn	1063	26	Cu	Cu	NNP
cord-276598-tm0yj2sn	1063	27	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	1063	28	(	(	-LRB-
cord-276598-tm0yj2sn	1063	29	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1063	30	,	,	,
cord-276598-tm0yj2sn	1063	31	Cu(OAc)2·H2O	Cu(OAc)2·H2O	NNP
cord-276598-tm0yj2sn	1063	32	)	)	-RRB-
cord-276598-tm0yj2sn	1063	33	were	be	VBD
cord-276598-tm0yj2sn	1063	34	inactive	inactive	JJ
cord-276598-tm0yj2sn	1063	35	or	or	CC
cord-276598-tm0yj2sn	1063	36	inefficient	inefficient	JJ
cord-276598-tm0yj2sn	1063	37	for	for	IN
cord-276598-tm0yj2sn	1063	38	the	the	DT
cord-276598-tm0yj2sn	1063	39	catalysis	catalysis	NN
cord-276598-tm0yj2sn	1063	40	.	.	.
cord-276598-tm0yj2sn	1064	1	It	-PRON-	PRP
cord-276598-tm0yj2sn	1064	2	was	be	VBD
cord-276598-tm0yj2sn	1064	3	further	further	RB
cord-276598-tm0yj2sn	1064	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	1064	5	that	that	IN
cord-276598-tm0yj2sn	1064	6	although	although	IN
cord-276598-tm0yj2sn	1064	7	a	a	DT
cord-276598-tm0yj2sn	1064	8	CuCl	CuCl	NNP
cord-276598-tm0yj2sn	1064	9	catalyst	catalyst	NN
cord-276598-tm0yj2sn	1064	10	enabled	enable	VBD
cord-276598-tm0yj2sn	1064	11	reaction	reaction	NN
cord-276598-tm0yj2sn	1064	12	,	,	,
cord-276598-tm0yj2sn	1064	13	it	-PRON-	PRP
cord-276598-tm0yj2sn	1064	14	was	be	VBD
cord-276598-tm0yj2sn	1064	15	not	not	RB
cord-276598-tm0yj2sn	1064	16	as	as	RB
cord-276598-tm0yj2sn	1064	17	effective	effective	JJ
cord-276598-tm0yj2sn	1064	18	as	as	IN
cord-276598-tm0yj2sn	1064	19	CuBr	CuBr	NNP
cord-276598-tm0yj2sn	1064	20	and	and	CC
cord-276598-tm0yj2sn	1064	21	conducting	conduct	VBG
cord-276598-tm0yj2sn	1064	22	the	the	DT
cord-276598-tm0yj2sn	1064	23	reaction	reaction	NN
cord-276598-tm0yj2sn	1064	24	under	under	IN
cord-276598-tm0yj2sn	1064	25	anaerobic	anaerobic	JJ
cord-276598-tm0yj2sn	1064	26	conditions	condition	NNS
cord-276598-tm0yj2sn	1064	27	(	(	-LRB-
cord-276598-tm0yj2sn	1064	28	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1064	29	,	,	,
cord-276598-tm0yj2sn	1064	30	under	under	IN
cord-276598-tm0yj2sn	1064	31	N2	N2	NNP
cord-276598-tm0yj2sn	1064	32	)	)	-RRB-
cord-276598-tm0yj2sn	1064	33	did	do	VBD
cord-276598-tm0yj2sn	1064	34	not	not	RB
cord-276598-tm0yj2sn	1064	35	lead	lead	VB
cord-276598-tm0yj2sn	1064	36	to	to	IN
cord-276598-tm0yj2sn	1064	37	the	the	DT
cord-276598-tm0yj2sn	1064	38	desired	desire	VBN
cord-276598-tm0yj2sn	1064	39	product	product	NN
cord-276598-tm0yj2sn	1064	40	.	.	.
cord-276598-tm0yj2sn	1065	1	In	in	IN
cord-276598-tm0yj2sn	1065	2	the	the	DT
cord-276598-tm0yj2sn	1065	3	Fe3O4@MgO	Fe3O4@MgO	NNP
cord-276598-tm0yj2sn	1065	4	nanoparticle	nanoparticle	NN
cord-276598-tm0yj2sn	1065	5	-	-	HYPH
cord-276598-tm0yj2sn	1065	6	mediated	mediate	VBN
cord-276598-tm0yj2sn	1065	7	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1065	8	of	of	IN
cord-276598-tm0yj2sn	1065	9	P	p	NN
cord-276598-tm0yj2sn	1065	10	-	-	HYPH
cord-276598-tm0yj2sn	1065	11	Ns	Ns	NNP
cord-276598-tm0yj2sn	1065	12	as	as	IN
cord-276598-tm0yj2sn	1065	13	per	per	IN
cord-276598-tm0yj2sn	1065	14	the	the	DT
cord-276598-tm0yj2sn	1065	15	procedure	procedure	NN
cord-276598-tm0yj2sn	1065	16	reported	report	VBN
cord-276598-tm0yj2sn	1065	17	by	by	IN
cord-276598-tm0yj2sn	1065	18	Habibi	Habibi	NNP
cord-276598-tm0yj2sn	1065	19	et	et	NNP
cord-276598-tm0yj2sn	1065	20	al	al	NNP
cord-276598-tm0yj2sn	1065	21	.	.	.
cord-276598-tm0yj2sn	1066	1	[	[	-LRB-
cord-276598-tm0yj2sn	1066	2	105	105	CD
cord-276598-tm0yj2sn	1066	3	]	]	-RRB-
cord-276598-tm0yj2sn	1066	4	,	,	,
cord-276598-tm0yj2sn	1066	5	the	the	DT
cord-276598-tm0yj2sn	1066	6	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1066	7	involves	involve	VBZ
cord-276598-tm0yj2sn	1066	8	the	the	DT
cord-276598-tm0yj2sn	1066	9	formation	formation	NN
cord-276598-tm0yj2sn	1066	10	of	of	IN
cord-276598-tm0yj2sn	1066	11	the	the	DT
cord-276598-tm0yj2sn	1067	1	(	(	-LRB-
cord-276598-tm0yj2sn	1067	2	RO)2P(O)Cl	RO)2P(O)Cl	NNP
cord-276598-tm0yj2sn	1067	3	(	(	-LRB-
cord-276598-tm0yj2sn	1067	4	dACP	dacp	NN
cord-276598-tm0yj2sn	1067	5	;	;	:
cord-276598-tm0yj2sn	1067	6	R	r	NN
cord-276598-tm0yj2sn	1067	7	=	=	NN
cord-276598-tm0yj2sn	1067	8	alkyl	alkyl	NN
cord-276598-tm0yj2sn	1067	9	)	)	-RRB-
cord-276598-tm0yj2sn	1068	1	intermediate	intermediate	JJ
cord-276598-tm0yj2sn	1068	2	from	from	IN
cord-276598-tm0yj2sn	1068	3	the	the	DT
cord-276598-tm0yj2sn	1068	4	reaction	reaction	NN
cord-276598-tm0yj2sn	1068	5	of	of	IN
cord-276598-tm0yj2sn	1068	6	dialkyl	dialkyl	NNP
cord-276598-tm0yj2sn	1068	7	H	H	NNP
cord-276598-tm0yj2sn	1068	8	-	-	HYPH
cord-276598-tm0yj2sn	1068	9	phosphonate	phosphonate	NNP
cord-276598-tm0yj2sn	1068	10	(	(	-LRB-
cord-276598-tm0yj2sn	1068	11	(	(	-LRB-
cord-276598-tm0yj2sn	1068	12	OR)2P(O)H	or)2p(o)h	CD
cord-276598-tm0yj2sn	1068	13	,	,	,
cord-276598-tm0yj2sn	1068	14	R	r	NN
cord-276598-tm0yj2sn	1068	15	=	=	NN
cord-276598-tm0yj2sn	1068	16	alkyl	alkyl	NN
cord-276598-tm0yj2sn	1068	17	)	)	-RRB-
cord-276598-tm0yj2sn	1068	18	with	with	IN
cord-276598-tm0yj2sn	1068	19	CCl4	CCl4	NNP
cord-276598-tm0yj2sn	1068	20	(	(	-LRB-
cord-276598-tm0yj2sn	1068	21	Scheme	scheme	NN
cord-276598-tm0yj2sn	1068	22	28	28	CD
cord-276598-tm0yj2sn	1068	23	)	)	-RRB-
cord-276598-tm0yj2sn	1068	24	.	.	.
cord-276598-tm0yj2sn	1069	1	Following	follow	VBG
cord-276598-tm0yj2sn	1069	2	,	,	,
cord-276598-tm0yj2sn	1069	3	the	the	DT
cord-276598-tm0yj2sn	1069	4	amine	amine	NN
cord-276598-tm0yj2sn	1069	5	in	in	IN
cord-276598-tm0yj2sn	1069	6	the	the	DT
cord-276598-tm0yj2sn	1069	7	presence	presence	NN
cord-276598-tm0yj2sn	1069	8	of	of	IN
cord-276598-tm0yj2sn	1069	9	Fe3O4@MgO	Fe3O4@MgO	NNP
cord-276598-tm0yj2sn	1069	10	nanoparticles	nanoparticle	NNS
cord-276598-tm0yj2sn	1069	11	couples	couple	NNS
cord-276598-tm0yj2sn	1069	12	with	with	IN
cord-276598-tm0yj2sn	1069	13	the	the	DT
cord-276598-tm0yj2sn	1069	14	dACP	dacp	NN
cord-276598-tm0yj2sn	1069	15	by	by	IN
cord-276598-tm0yj2sn	1069	16	nucleophilic	nucleophilic	JJ
cord-276598-tm0yj2sn	1069	17	substitution	substitution	NN
cord-276598-tm0yj2sn	1069	18	to	to	TO
cord-276598-tm0yj2sn	1069	19	give	give	VB
cord-276598-tm0yj2sn	1069	20	the	the	DT
cord-276598-tm0yj2sn	1069	21	P	P	NNP
cord-276598-tm0yj2sn	1069	22	-	-	HYPH
cord-276598-tm0yj2sn	1069	23	N	n	CD
cord-276598-tm0yj2sn	1069	24	product	product	NN
cord-276598-tm0yj2sn	1069	25	,	,	,
cord-276598-tm0yj2sn	1069	26	eliminating	eliminate	VBG
cord-276598-tm0yj2sn	1069	27	HCl	HCl	NNP
cord-276598-tm0yj2sn	1069	28	.	.	.
cord-276598-tm0yj2sn	1070	1	Scheme	scheme	NN
cord-276598-tm0yj2sn	1070	2	28	28	CD
cord-276598-tm0yj2sn	1070	3	.	.	.
cord-276598-tm0yj2sn	1071	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	1071	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1071	3	for	for	IN
cord-276598-tm0yj2sn	1071	4	the	the	DT
cord-276598-tm0yj2sn	1071	5	Fe3O4@MgO	Fe3O4@MgO	NNP
cord-276598-tm0yj2sn	1071	6	nanoparticle	nanoparticle	NN
cord-276598-tm0yj2sn	1071	7	-	-	HYPH
cord-276598-tm0yj2sn	1071	8	mediated	mediate	VBN
cord-276598-tm0yj2sn	1071	9	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1071	10	of	of	IN
cord-276598-tm0yj2sn	1071	11	phosphoramidates	phosphoramidates	NNP
cord-276598-tm0yj2sn	1071	12	.	.	.
cord-276598-tm0yj2sn	1072	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	1072	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1072	3	for	for	IN
cord-276598-tm0yj2sn	1072	4	the	the	DT
cord-276598-tm0yj2sn	1072	5	copper	copper	NN
cord-276598-tm0yj2sn	1072	6	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	1072	7	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	1072	8	cross	cross	NN
cord-276598-tm0yj2sn	1072	9	-	-	NN
cord-276598-tm0yj2sn	1072	10	coupling	coupling	NN
cord-276598-tm0yj2sn	1072	11	of	of	IN
cord-276598-tm0yj2sn	1072	12	disubstituted	disubstituted	JJ
cord-276598-tm0yj2sn	1072	13	H	h	NN
cord-276598-tm0yj2sn	1072	14	-	-	HYPH
cord-276598-tm0yj2sn	1072	15	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	1072	16	and	and	CC
cord-276598-tm0yj2sn	1072	17	amines	amine	NNS
cord-276598-tm0yj2sn	1072	18	to	to	TO
cord-276598-tm0yj2sn	1072	19	produce	produce	VB
cord-276598-tm0yj2sn	1072	20	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	1072	21	.	.	.
cord-276598-tm0yj2sn	1073	1	There	there	EX
cord-276598-tm0yj2sn	1073	2	were	be	VBD
cord-276598-tm0yj2sn	1073	3	no	no	DT
cord-276598-tm0yj2sn	1073	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	1073	5	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	1073	6	for	for	IN
cord-276598-tm0yj2sn	1073	7	the	the	DT
cord-276598-tm0yj2sn	1073	8	reaction	reaction	NN
cord-276598-tm0yj2sn	1073	9	in	in	IN
cord-276598-tm0yj2sn	1073	10	the	the	DT
cord-276598-tm0yj2sn	1073	11	report	report	NN
cord-276598-tm0yj2sn	1073	12	by	by	IN
cord-276598-tm0yj2sn	1073	13	Wang	Wang	NNP
cord-276598-tm0yj2sn	1073	14	et	et	NNP
cord-276598-tm0yj2sn	1073	15	al	al	NNP
cord-276598-tm0yj2sn	1073	16	.	.	.
cord-276598-tm0yj2sn	1074	1	[	[	-LRB-
cord-276598-tm0yj2sn	1074	2	104	104	CD
cord-276598-tm0yj2sn	1074	3	]	]	-RRB-
cord-276598-tm0yj2sn	1074	4	.	.	.
cord-276598-tm0yj2sn	1075	1	However	however	RB
cord-276598-tm0yj2sn	1075	2	,	,	,
cord-276598-tm0yj2sn	1075	3	the	the	DT
cord-276598-tm0yj2sn	1075	4	results	result	NNS
cord-276598-tm0yj2sn	1075	5	of	of	IN
cord-276598-tm0yj2sn	1075	6	the	the	DT
cord-276598-tm0yj2sn	1075	7	reagent	reagent	NN
cord-276598-tm0yj2sn	1075	8	screening	screening	NN
cord-276598-tm0yj2sn	1075	9	for	for	IN
cord-276598-tm0yj2sn	1075	10	the	the	DT
cord-276598-tm0yj2sn	1075	11	reaction	reaction	NN
cord-276598-tm0yj2sn	1075	12	had	have	VBD
cord-276598-tm0yj2sn	1075	13	suggested	suggest	VBN
cord-276598-tm0yj2sn	1075	14	that	that	IN
cord-276598-tm0yj2sn	1075	15	other	other	JJ
cord-276598-tm0yj2sn	1075	16	transition	transition	NN
cord-276598-tm0yj2sn	1075	17	metal	metal	NN
cord-276598-tm0yj2sn	1075	18	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	1075	19	(	(	-LRB-
cord-276598-tm0yj2sn	1075	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1075	21	,	,	,
cord-276598-tm0yj2sn	1075	22	CoBr	CoBr	NNP
cord-276598-tm0yj2sn	1075	23	2	2	CD
cord-276598-tm0yj2sn	1075	24	)	)	-RRB-
cord-276598-tm0yj2sn	1075	25	and	and	CC
cord-276598-tm0yj2sn	1075	26	other	other	JJ
cord-276598-tm0yj2sn	1075	27	Cu	Cu	NNP
cord-276598-tm0yj2sn	1075	28	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	1075	29	(	(	-LRB-
cord-276598-tm0yj2sn	1075	30	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1075	31	,	,	,
cord-276598-tm0yj2sn	1075	32	Cu(OAc	Cu(OAc	NNS
cord-276598-tm0yj2sn	1075	33	)	)	-RRB-
cord-276598-tm0yj2sn	1075	34	2	2	CD
cord-276598-tm0yj2sn	1075	35	·	·	NFP
cord-276598-tm0yj2sn	1075	36	H	h	NN
cord-276598-tm0yj2sn	1075	37	2	2	CD
cord-276598-tm0yj2sn	1075	38	O	o	NN
cord-276598-tm0yj2sn	1075	39	)	)	-RRB-
cord-276598-tm0yj2sn	1075	40	were	be	VBD
cord-276598-tm0yj2sn	1075	41	inactive	inactive	JJ
cord-276598-tm0yj2sn	1075	42	or	or	CC
cord-276598-tm0yj2sn	1075	43	inefficient	inefficient	JJ
cord-276598-tm0yj2sn	1075	44	for	for	IN
cord-276598-tm0yj2sn	1075	45	the	the	DT
cord-276598-tm0yj2sn	1075	46	catalysis	catalysis	NN
cord-276598-tm0yj2sn	1075	47	.	.	.
cord-276598-tm0yj2sn	1076	1	It	-PRON-	PRP
cord-276598-tm0yj2sn	1076	2	was	be	VBD
cord-276598-tm0yj2sn	1076	3	further	further	RB
cord-276598-tm0yj2sn	1076	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	1076	5	that	that	IN
cord-276598-tm0yj2sn	1076	6	although	although	IN
cord-276598-tm0yj2sn	1076	7	a	a	DT
cord-276598-tm0yj2sn	1076	8	CuCl	CuCl	NNP
cord-276598-tm0yj2sn	1076	9	catalyst	catalyst	NN
cord-276598-tm0yj2sn	1076	10	enabled	enable	VBD
cord-276598-tm0yj2sn	1076	11	reaction	reaction	NN
cord-276598-tm0yj2sn	1076	12	,	,	,
cord-276598-tm0yj2sn	1076	13	it	-PRON-	PRP
cord-276598-tm0yj2sn	1076	14	was	be	VBD
cord-276598-tm0yj2sn	1076	15	not	not	RB
cord-276598-tm0yj2sn	1076	16	as	as	RB
cord-276598-tm0yj2sn	1076	17	effective	effective	JJ
cord-276598-tm0yj2sn	1076	18	as	as	IN
cord-276598-tm0yj2sn	1076	19	CuBr	CuBr	NNP
cord-276598-tm0yj2sn	1076	20	and	and	CC
cord-276598-tm0yj2sn	1076	21	conducting	conduct	VBG
cord-276598-tm0yj2sn	1076	22	the	the	DT
cord-276598-tm0yj2sn	1076	23	reaction	reaction	NN
cord-276598-tm0yj2sn	1076	24	under	under	IN
cord-276598-tm0yj2sn	1076	25	anaerobic	anaerobic	JJ
cord-276598-tm0yj2sn	1076	26	conditions	condition	NNS
cord-276598-tm0yj2sn	1076	27	(	(	-LRB-
cord-276598-tm0yj2sn	1076	28	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1076	29	,	,	,
cord-276598-tm0yj2sn	1076	30	under	under	IN
cord-276598-tm0yj2sn	1076	31	N	n	CD
cord-276598-tm0yj2sn	1076	32	2	2	CD
cord-276598-tm0yj2sn	1076	33	)	)	-RRB-
cord-276598-tm0yj2sn	1076	34	did	do	VBD
cord-276598-tm0yj2sn	1076	35	not	not	RB
cord-276598-tm0yj2sn	1076	36	lead	lead	VB
cord-276598-tm0yj2sn	1076	37	to	to	IN
cord-276598-tm0yj2sn	1076	38	the	the	DT
cord-276598-tm0yj2sn	1076	39	desired	desire	VBN
cord-276598-tm0yj2sn	1076	40	product	product	NN
cord-276598-tm0yj2sn	1076	41	.	.	.
cord-276598-tm0yj2sn	1077	1	In	in	IN
cord-276598-tm0yj2sn	1077	2	the	the	DT
cord-276598-tm0yj2sn	1077	3	Fe	Fe	NNP
cord-276598-tm0yj2sn	1077	4	3	3	CD
cord-276598-tm0yj2sn	1077	5	O	o	NN
cord-276598-tm0yj2sn	1077	6	4	4	CD
cord-276598-tm0yj2sn	1077	7	@MgO	@mgo	NN
cord-276598-tm0yj2sn	1077	8	nanoparticle	nanoparticle	NN
cord-276598-tm0yj2sn	1077	9	-	-	HYPH
cord-276598-tm0yj2sn	1077	10	mediated	mediate	VBN
cord-276598-tm0yj2sn	1077	11	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1077	12	of	of	IN
cord-276598-tm0yj2sn	1077	13	P	p	NN
cord-276598-tm0yj2sn	1077	14	-	-	HYPH
cord-276598-tm0yj2sn	1077	15	Ns	Ns	NNP
cord-276598-tm0yj2sn	1077	16	as	as	IN
cord-276598-tm0yj2sn	1077	17	per	per	IN
cord-276598-tm0yj2sn	1077	18	the	the	DT
cord-276598-tm0yj2sn	1077	19	procedure	procedure	NN
cord-276598-tm0yj2sn	1077	20	reported	report	VBN
cord-276598-tm0yj2sn	1077	21	by	by	IN
cord-276598-tm0yj2sn	1077	22	Habibi	Habibi	NNP
cord-276598-tm0yj2sn	1077	23	et	et	NNP
cord-276598-tm0yj2sn	1077	24	al	al	NNP
cord-276598-tm0yj2sn	1077	25	.	.	.
cord-276598-tm0yj2sn	1078	1	[	[	-LRB-
cord-276598-tm0yj2sn	1078	2	105	105	CD
cord-276598-tm0yj2sn	1078	3	]	]	-RRB-
cord-276598-tm0yj2sn	1078	4	,	,	,
cord-276598-tm0yj2sn	1078	5	the	the	DT
cord-276598-tm0yj2sn	1078	6	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1078	7	involves	involve	VBZ
cord-276598-tm0yj2sn	1078	8	the	the	DT
cord-276598-tm0yj2sn	1078	9	formation	formation	NN
cord-276598-tm0yj2sn	1078	10	of	of	IN
cord-276598-tm0yj2sn	1078	11	the	the	DT
cord-276598-tm0yj2sn	1078	12	(	(	-LRB-
cord-276598-tm0yj2sn	1078	13	RO	ro	NN
cord-276598-tm0yj2sn	1078	14	)	)	-RRB-
cord-276598-tm0yj2sn	1078	15	2	2	CD
cord-276598-tm0yj2sn	1078	16	oxidized	oxidize	VBN
cord-276598-tm0yj2sn	1078	17	to	to	TO
cord-276598-tm0yj2sn	1078	18	form	form	VB
cord-276598-tm0yj2sn	1078	19	the	the	DT
cord-276598-tm0yj2sn	1078	20	Cu(III)-amine	Cu(III)-amine	NNP
cord-276598-tm0yj2sn	1078	21	-	-	HYPH
cord-276598-tm0yj2sn	1078	22	phosphonate	phosphonate	JJ
cord-276598-tm0yj2sn	1078	23	complex	complex	NN
cord-276598-tm0yj2sn	1078	24	,	,	,
cord-276598-tm0yj2sn	1078	25	which	which	WDT
cord-276598-tm0yj2sn	1078	26	undergoes	undergo	VBZ
cord-276598-tm0yj2sn	1078	27	reductive	reductive	JJ
cord-276598-tm0yj2sn	1078	28	elimination	elimination	NN
cord-276598-tm0yj2sn	1078	29	of	of	IN
cord-276598-tm0yj2sn	1078	30	the	the	DT
cord-276598-tm0yj2sn	1078	31	copper	copper	NN
cord-276598-tm0yj2sn	1078	32	catalyst	catalyst	NN
cord-276598-tm0yj2sn	1078	33	to	to	TO
cord-276598-tm0yj2sn	1078	34	yield	yield	VB
cord-276598-tm0yj2sn	1078	35	the	the	DT
cord-276598-tm0yj2sn	1078	36	desired	desire	VBN
cord-276598-tm0yj2sn	1078	37	P	p	NN
cord-276598-tm0yj2sn	1078	38	-	-	HYPH
cord-276598-tm0yj2sn	1078	39	N.	n.	NN
cord-276598-tm0yj2sn	1079	1	Although	although	IN
cord-276598-tm0yj2sn	1079	2	this	this	DT
cord-276598-tm0yj2sn	1079	3	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1079	4	seems	seem	VBZ
cord-276598-tm0yj2sn	1079	5	plausible	plausible	JJ
cord-276598-tm0yj2sn	1079	6	,	,	,
cord-276598-tm0yj2sn	1079	7	it	-PRON-	PRP
cord-276598-tm0yj2sn	1079	8	could	could	MD
cord-276598-tm0yj2sn	1079	9	not	not	RB
cord-276598-tm0yj2sn	1079	10	easily	easily	RB
cord-276598-tm0yj2sn	1079	11	explain	explain	VB
cord-276598-tm0yj2sn	1079	12	the	the	DT
cord-276598-tm0yj2sn	1079	13	formation	formation	NN
cord-276598-tm0yj2sn	1079	14	of	of	IN
cord-276598-tm0yj2sn	1079	15	the	the	DT
cord-276598-tm0yj2sn	1079	16	side	side	NN
cord-276598-tm0yj2sn	1079	17	products	product	NNS
cord-276598-tm0yj2sn	1079	18	.	.	.
cord-276598-tm0yj2sn	1080	1	Proposed	propose	VBN
cord-276598-tm0yj2sn	1080	2	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1080	3	for	for	IN
cord-276598-tm0yj2sn	1080	4	the	the	DT
cord-276598-tm0yj2sn	1080	5	copper	copper	NN
cord-276598-tm0yj2sn	1080	6	catalyzed	catalyze	VBN
cord-276598-tm0yj2sn	1080	7	oxidative	oxidative	JJ
cord-276598-tm0yj2sn	1080	8	cross	cross	NN
cord-276598-tm0yj2sn	1080	9	-	-	NN
cord-276598-tm0yj2sn	1080	10	coupling	coupling	NN
cord-276598-tm0yj2sn	1080	11	of	of	IN
cord-276598-tm0yj2sn	1080	12	disubstituted	disubstituted	JJ
cord-276598-tm0yj2sn	1080	13	H	h	NN
cord-276598-tm0yj2sn	1080	14	-	-	HYPH
cord-276598-tm0yj2sn	1080	15	phosphonates	phosphonate	NNS
cord-276598-tm0yj2sn	1080	16	and	and	CC
cord-276598-tm0yj2sn	1080	17	amines	amine	NNS
cord-276598-tm0yj2sn	1080	18	to	to	TO
cord-276598-tm0yj2sn	1080	19	produce	produce	VB
cord-276598-tm0yj2sn	1080	20	phosphoramidates	phosphoramidate	NNS
cord-276598-tm0yj2sn	1080	21	.	.	.
cord-276598-tm0yj2sn	1081	1	There	there	EX
cord-276598-tm0yj2sn	1081	2	were	be	VBD
cord-276598-tm0yj2sn	1081	3	no	no	DT
cord-276598-tm0yj2sn	1081	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	1081	5	mechanisms	mechanism	NNS
cord-276598-tm0yj2sn	1081	6	for	for	IN
cord-276598-tm0yj2sn	1081	7	the	the	DT
cord-276598-tm0yj2sn	1081	8	reaction	reaction	NN
cord-276598-tm0yj2sn	1081	9	in	in	IN
cord-276598-tm0yj2sn	1081	10	the	the	DT
cord-276598-tm0yj2sn	1081	11	report	report	NN
cord-276598-tm0yj2sn	1081	12	by	by	IN
cord-276598-tm0yj2sn	1081	13	Wang	Wang	NNP
cord-276598-tm0yj2sn	1081	14	et	et	NNP
cord-276598-tm0yj2sn	1081	15	al	al	NNP
cord-276598-tm0yj2sn	1081	16	.	.	.
cord-276598-tm0yj2sn	1082	1	[	[	-LRB-
cord-276598-tm0yj2sn	1082	2	104	104	CD
cord-276598-tm0yj2sn	1082	3	]	]	-RRB-
cord-276598-tm0yj2sn	1082	4	.	.	.
cord-276598-tm0yj2sn	1083	1	However	however	RB
cord-276598-tm0yj2sn	1083	2	,	,	,
cord-276598-tm0yj2sn	1083	3	the	the	DT
cord-276598-tm0yj2sn	1083	4	results	result	NNS
cord-276598-tm0yj2sn	1083	5	of	of	IN
cord-276598-tm0yj2sn	1083	6	the	the	DT
cord-276598-tm0yj2sn	1083	7	reagent	reagent	NN
cord-276598-tm0yj2sn	1083	8	screening	screening	NN
cord-276598-tm0yj2sn	1083	9	for	for	IN
cord-276598-tm0yj2sn	1083	10	the	the	DT
cord-276598-tm0yj2sn	1083	11	reaction	reaction	NN
cord-276598-tm0yj2sn	1083	12	had	have	VBD
cord-276598-tm0yj2sn	1083	13	suggested	suggest	VBN
cord-276598-tm0yj2sn	1083	14	that	that	IN
cord-276598-tm0yj2sn	1083	15	other	other	JJ
cord-276598-tm0yj2sn	1083	16	transition	transition	NN
cord-276598-tm0yj2sn	1083	17	metal	metal	NN
cord-276598-tm0yj2sn	1083	18	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	1083	19	(	(	-LRB-
cord-276598-tm0yj2sn	1083	20	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1083	21	,	,	,
cord-276598-tm0yj2sn	1083	22	CoBr2	CoBr2	NNS
cord-276598-tm0yj2sn	1083	23	)	)	-RRB-
cord-276598-tm0yj2sn	1083	24	and	and	CC
cord-276598-tm0yj2sn	1083	25	other	other	JJ
cord-276598-tm0yj2sn	1083	26	Cu	Cu	NNP
cord-276598-tm0yj2sn	1083	27	catalysts	catalyst	NNS
cord-276598-tm0yj2sn	1083	28	(	(	-LRB-
cord-276598-tm0yj2sn	1083	29	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1083	30	,	,	,
cord-276598-tm0yj2sn	1083	31	Cu(OAc)2·H2O	Cu(OAc)2·H2O	NNP
cord-276598-tm0yj2sn	1083	32	)	)	-RRB-
cord-276598-tm0yj2sn	1083	33	were	be	VBD
cord-276598-tm0yj2sn	1083	34	inactive	inactive	JJ
cord-276598-tm0yj2sn	1083	35	or	or	CC
cord-276598-tm0yj2sn	1083	36	inefficient	inefficient	JJ
cord-276598-tm0yj2sn	1083	37	for	for	IN
cord-276598-tm0yj2sn	1083	38	the	the	DT
cord-276598-tm0yj2sn	1083	39	catalysis	catalysis	NN
cord-276598-tm0yj2sn	1083	40	.	.	.
cord-276598-tm0yj2sn	1084	1	It	-PRON-	PRP
cord-276598-tm0yj2sn	1084	2	was	be	VBD
cord-276598-tm0yj2sn	1084	3	further	further	RB
cord-276598-tm0yj2sn	1084	4	suggested	suggest	VBN
cord-276598-tm0yj2sn	1084	5	that	that	IN
cord-276598-tm0yj2sn	1084	6	although	although	IN
cord-276598-tm0yj2sn	1084	7	a	a	DT
cord-276598-tm0yj2sn	1084	8	CuCl	CuCl	NNP
cord-276598-tm0yj2sn	1084	9	catalyst	catalyst	NN
cord-276598-tm0yj2sn	1084	10	enabled	enable	VBD
cord-276598-tm0yj2sn	1084	11	reaction	reaction	NN
cord-276598-tm0yj2sn	1084	12	,	,	,
cord-276598-tm0yj2sn	1084	13	it	-PRON-	PRP
cord-276598-tm0yj2sn	1084	14	was	be	VBD
cord-276598-tm0yj2sn	1084	15	not	not	RB
cord-276598-tm0yj2sn	1084	16	as	as	RB
cord-276598-tm0yj2sn	1084	17	effective	effective	JJ
cord-276598-tm0yj2sn	1084	18	as	as	IN
cord-276598-tm0yj2sn	1084	19	CuBr	CuBr	NNP
cord-276598-tm0yj2sn	1084	20	and	and	CC
cord-276598-tm0yj2sn	1084	21	conducting	conduct	VBG
cord-276598-tm0yj2sn	1084	22	the	the	DT
cord-276598-tm0yj2sn	1084	23	reaction	reaction	NN
cord-276598-tm0yj2sn	1084	24	under	under	IN
cord-276598-tm0yj2sn	1084	25	anaerobic	anaerobic	JJ
cord-276598-tm0yj2sn	1084	26	conditions	condition	NNS
cord-276598-tm0yj2sn	1084	27	(	(	-LRB-
cord-276598-tm0yj2sn	1084	28	e.g.	e.g.	RB
cord-276598-tm0yj2sn	1084	29	,	,	,
cord-276598-tm0yj2sn	1084	30	under	under	IN
cord-276598-tm0yj2sn	1084	31	N2	N2	NNP
cord-276598-tm0yj2sn	1084	32	)	)	-RRB-
cord-276598-tm0yj2sn	1084	33	did	do	VBD
cord-276598-tm0yj2sn	1084	34	not	not	RB
cord-276598-tm0yj2sn	1084	35	lead	lead	VB
cord-276598-tm0yj2sn	1084	36	to	to	IN
cord-276598-tm0yj2sn	1084	37	the	the	DT
cord-276598-tm0yj2sn	1084	38	desired	desire	VBN
cord-276598-tm0yj2sn	1084	39	product	product	NN
cord-276598-tm0yj2sn	1084	40	.	.	.
cord-276598-tm0yj2sn	1085	1	In	in	IN
cord-276598-tm0yj2sn	1085	2	the	the	DT
cord-276598-tm0yj2sn	1085	3	Fe3O4@MgO	Fe3O4@MgO	NNP
cord-276598-tm0yj2sn	1085	4	nanoparticle	nanoparticle	NN
cord-276598-tm0yj2sn	1085	5	-	-	HYPH
cord-276598-tm0yj2sn	1085	6	mediated	mediate	VBN
cord-276598-tm0yj2sn	1085	7	synthesis	synthesis	NN
cord-276598-tm0yj2sn	1085	8	of	of	IN
cord-276598-tm0yj2sn	1085	9	P	p	NN
cord-276598-tm0yj2sn	1085	10	-	-	HYPH
cord-276598-tm0yj2sn	1085	11	Ns	Ns	NNP
cord-276598-tm0yj2sn	1085	12	as	as	IN
cord-276598-tm0yj2sn	1085	13	per	per	IN
cord-276598-tm0yj2sn	1085	14	the	the	DT
cord-276598-tm0yj2sn	1085	15	procedure	procedure	NN
cord-276598-tm0yj2sn	1085	16	reported	report	VBN
cord-276598-tm0yj2sn	1085	17	by	by	IN
cord-276598-tm0yj2sn	1085	18	Habibi	Habibi	NNP
cord-276598-tm0yj2sn	1085	19	et	et	NNP
cord-276598-tm0yj2sn	1085	20	al	al	NNP
cord-276598-tm0yj2sn	1085	21	.	.	.
cord-276598-tm0yj2sn	1086	1	[	[	-LRB-
cord-276598-tm0yj2sn	1086	2	105	105	CD
cord-276598-tm0yj2sn	1086	3	]	]	-RRB-
cord-276598-tm0yj2sn	1086	4	,	,	,
cord-276598-tm0yj2sn	1086	5	the	the	DT
cord-276598-tm0yj2sn	1086	6	mechanism	mechanism	NN
cord-276598-tm0yj2sn	1086	7	involves	involve	VBZ
cord-276598-tm0yj2sn	1086	8	the	the	DT
cord-276598-tm0yj2sn	1086	9	formation	formation	NN
cord-276598-tm0yj2sn	1086	10	of	of	IN
cord-276598-tm0yj2sn	1086	11	the	the	DT
cord-276598-tm0yj2sn	1086	12	 	 	_SP