id	author	title	date	pages	extension	mime	words	sentences	flesch	summary	cache	txt
cord-276598-tm0yj2sn	Itumoh, Emeka J.	Opening up the Toolbox: Synthesis and Mechanisms of Phosphoramidates	2020-08-13		.txt	text/plain	21015	1241	51	For the low yielding derivatives, the reaction was more selective to three identified by-products, H-phosphonate, trialkyl phosphate, and tetraalkyl diphosphate, as well as some other unidentified Jang and coworkers reported a facile synthetic route to form P-Ns using diphenyl phosphoric acid (dPPA) and an amine in the presence of both a chlorinating agent (Cl 3 CCN) and a base (Et 3 N), which was added to sequester the acid formed during the reaction (Scheme 6c) [99] . proposed a reaction mechanism involving single-electron transfer oxidation of the copper catalyst, which favored the formation of the Cu(II)-amine complex (Scheme 27) [103] . proposed a reaction mechanism involving single-electron transfer oxidation of the copper catalyst, which favored the formation of the Cu(II)-amine complex (Scheme 27) [103] . [105] , the mechanism involves the formation of the (RO) 2 oxidized to form the Cu(III)-amine-phosphonate complex, which undergoes reductive elimination of the copper catalyst to yield the desired P-N.	./cache/cord-276598-tm0yj2sn.txt	./txt/cord-276598-tm0yj2sn.txt